CN104886050B - A kind of Thief zone height attachment agricultural chemicals synergist and preparation method thereof - Google Patents
A kind of Thief zone height attachment agricultural chemicals synergist and preparation method thereof Download PDFInfo
- Publication number
- CN104886050B CN104886050B CN201510319439.5A CN201510319439A CN104886050B CN 104886050 B CN104886050 B CN 104886050B CN 201510319439 A CN201510319439 A CN 201510319439A CN 104886050 B CN104886050 B CN 104886050B
- Authority
- CN
- China
- Prior art keywords
- pesticide
- agricultural chemicals
- thief zone
- zone height
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of Thief zone height attachment agricultural chemicals synergist and preparation method thereof, be calculated in mass percent including：10 15% emulsifying agents, 1 5% anti-drift auxiliary agent, 2.5 5% bleeding agents, 2.5 5% spreader-stickers and 0.5 2.5% plant growth regulator, surplus is water.Each component is taken by proportioning, under 30 DEG C of constant temperature, magnetic agitations, anti-drift auxiliary agent and plant growth regulator are added in water, after after abundant dissolving, emulsifying agent is then added, is subsequently added into bleeding agent, be eventually adding spreader-sticker, be stirred well to solution clear.Agricultural chemicals synergist of the present invention and preparation method, the permeability and conductive performance of pesticide solution can not only be increased, improve adhesion, wetting and spreading property that pesticide liquid drops in target surface, improve the evaporation rate of spray liquid simultaneously, the drift and loss of pesticide solution are reduced, promotes plant growth；The purpose of pesticide reduction is reached, pesticide efficacy is improved, environmental pollution is reduced, can be widely applied to agriculture field.
Description
Technical field
The present invention relates to insecticides adjuvant field, specifically a kind of Thief zone height attachment agricultural chemicals synergist and its preparation side
Method.
Background technology
At this stage, China's agricultural chemicals pesticide application technology is based on spray-on process, and spray-on process is a kind of efficient, safe, economic dispenser
Mode, but during spray-on process dispenser, a large amount of drifts of droplet of pesticide solution formation cause agricultural chemicals effective into environment
Utilization rate is very low, and pesticide liquid drops in target surface and easily causes spring and tumble, and these situations cause most of pesticide active ingredient
Loss, cause environmental pollution and economic loss.
Agricultural chemicals synergist (referred to as builder) is the auxiliary agent used in spray-on process dispenser or similar application technology
General name, by being properly added agricultural chemicals synergist, adhesion, wetting and spreadability that pesticide liquid drops in target surface can be improved
Can, pesticide efficacy can be not only improved, and the purpose of pesticide reduction can be reached.
The use of agricultural chemicals synergist can reach following purpose：
1st, increase pesticide liquid drops in adhesion and the wettability of target surface (plant leaf surface or insect surface)；
2nd, the evaporation rate of spray liquid is improved；
3rd, the against weather of spraying precipitum is improved；
4th, the permeability and conductive performance of increase pesticide solution；
5th, the pH of adjustment spray liquid and precipitum of spraying；
6th, the uniformity of spraying precipitum is improved；
7th, the compatibility of mixture is solved；
8th, the security of crop is contributed to；
9th, increase the deposition of pesticide solution, reduce the drift and loss of pesticide solution.
Realize one or several in object above, pesticide efficacy can be improved, reduction environmental pollution and warp
Ji loss.
The permeance property of builder is improved, builder can be lifted to wax layer surface by adding surfactant
The compatibilization of chemical composition, destroys the wax coat of target surface, increases the osmotic efficiency of pesticide active ingredient；Synergy is improved to help
The adhesion property of agent, that is, solid-liquid interface interaction force is improved, surface-active can be strengthened by adding surfactant
Electrostatic interaction or hydrophobic interaction between agent molecule and the surface of solids.Therefore, suitable surfactant kind is selected
Class, can strengthen the dissolution and solid-liquid interface interaction force to wax coat, from the efficiency of substantial lifting builder.
Builder species is a lot, mainly including following several：
Coagent, including surfactant such as wetting agent, bleeding agent, non-harmful various oil etc.；
Spraying improvement auxiliary agent, including adhesive, film forming agent, spreader-sticker and foaming agent；
Practicality improves auxiliary agent, including emulsifying agent, dispersant, stabilizer etc..
The application of builder is not limited to use one of which, can optimize group to variety classes builder
Close, play its different characteristics, prepare more practical builder.
The content of the invention
In view of this, it is an object of the invention to provide a kind of Thief zone height attachment agricultural chemicals synergist and its preparation side
Method, the builder prepared using this method can aid in improving the permeability and conductive performance of pesticide solution, strengthen agriculture
Decoction drops in the adhesion, wetting and spreading property of target surface, reaches the purpose for improving pesticide efficacy.
To achieve the above objectives, the present invention is adopted the technical scheme that：
A kind of Thief zone height attachment agricultural chemicals synergist, it is characterised in that：It is calculated in mass percent, including：10-15% breasts
Agent, the anti-drift auxiliary agents of 1-5%, 2.5-5% bleeding agents, 2.5-5% spreader-stickers and 0.5-2.5% plant growth regulator, surplus
Supplied with water.
On the basis of above-mentioned technical proposal, the emulsifying agent is Triton X-100.
On the basis of above-mentioned technical proposal, the anti-drift auxiliary agent is polyvinylpyrrolidone.
On the basis of above-mentioned technical proposal, the bleeding agent is hypertonic azone or JFC.
On the basis of above-mentioned technical proposal, the spreader-sticker is organic silicon surfactant.
On the basis of above-mentioned technical proposal, the organic silicon surfactant is silwet L-77 or Silwet 618
Or Silwet 408.
On the basis of above-mentioned technical proposal, the plant growth regulator is butyric acid potassium.
The preparation method of above-mentioned Thief zone height attachment agricultural chemicals synergist, it is characterised in that：Comprise the following steps：
Each component is taken by proportioning, under 30 DEG C of constant temperature, under magnetic stirring, anti-drift auxiliary agent and plant growth are added in water
Conditioning agent, after after abundant dissolving, then adds emulsifying agent, is subsequently added into bleeding agent, be eventually adding spreader-sticker, be stirred well to molten
Liquid clear.
On the basis of above-mentioned technical proposal, the stir speed (S.S.) of the magnetic agitation is 50-300r/min.
On the basis of above-mentioned technical proposal, it is calculated in mass percent, the Triton X-100 mass percents are preferred
For 15%, the polyvinylpyrrolidone mass percent is preferably 2.5%, and the hypertonic azone mass percent is preferably
2.5%, the JFC mass percents are preferably 4%, and the silwet L-77 mass percents are preferably 2.5%, described
Silwet618 mass percents are preferably 3%, and the mass percents of Silwet 408 are preferably 3%, the butyric acid potassium
Mass percent is preferably 1%.
Thief zone height attachment agricultural chemicals synergist of the present invention and preparation method thereof, can not only increase pesticide solution
Permeability and conductive performance, improve pesticide liquid and drop in the adhesion, wetting and spreading property of target surface, while improving spray liquid
Evaporation rate, reduce pesticide solution drift and loss, promote plant growth；The purpose of pesticide reduction is reached, agriculture is improved
Medicine effective rate of utilization, reduces environmental pollution, can be widely applied to agriculture field.
Embodiment
Thief zone height attachment agricultural chemicals synergist of the present invention, is calculated in mass percent, including：10-15% is emulsified
Agent, the anti-drift auxiliary agents of 1-5%, 2.5-5% bleeding agents, 2.5-5% spreader-stickers and 0.5-2.5% plant growth regulator, surplus with
Water is supplied.
On the basis of above-mentioned technical proposal, the emulsifying agent is Triton X-100.
Triton X-100 (Triton X-100) are a kind of nonionic surfactant, Triton X-100
(emulsifying agent) mass percent is preferably 15%.Adding emulsifying agent can be such that the performance of builder of the present invention more stablizes.
On the basis of above-mentioned technical proposal, the anti-drift auxiliary agent is polyvinylpyrrolidone, preferably polyvinyl pyrrole
Alkanone K30.
Polyvinylpyrrolidone (Mn=60000, K30) is water-soluble nonionic high-molecular compound, nontoxic corrosion-free
Property.Polyvinylpyrrolidone (the anti-drift auxiliary agent) mass percent is preferably 2.5%.
Polyvinylpyrrolidone (PVP), which has, drops resistive, can effectively reduce the frictional resistance of fluid, drop in pesticide liquid
Target surface is more easy-adhesion and sprawls；There is thickening property simultaneously, assign auxiliary agent good physical mechanical stability；It is prior
It is that the polyvinylpyrrolidone of HMW can prevent the drift and loss of pesticide solution, improve the deposition of pesticide solution,
So as to reduce pollution of the agricultural chemicals to environment, use cost is reduced.The addition of polyvinylpyrrolidone can not only improve spray liquid
Evaporation rate simultaneously reduce pesticide solution drift and loss.
On the basis of above-mentioned technical proposal, the bleeding agent is hypertonic azone or JFC.
Hypertonic azone chemical name is Azone, and JFC chemical names are fatty alcohol polyoxy second
Alkene ether.The addition of bleeding agent can significantly reduce the surface tension of agricultural chemicals drop, increase the permeability and conductibility of pesticide solution
Energy.Promote infiltration of the insecticide to polypide, promote infiltration of the herbicide to weeds wax coat, improve wettability, promote target
Absorption to pesticide active ingredient, improves pesticide efficacy and reduction pesticide dosage, so as to reduce pollution of the agricultural chemicals to environment, reduces
Use cost.
Hypertonic azone (bleeding agent) mass percent is preferably that 2.5%, JFC (bleeding agent) mass percent is preferably
4%.
On the basis of above-mentioned technical proposal, the spreader-sticker is organic silicon surfactant, and it is first to be entered by chlorosilane
Water-filling solution generates polysiloxanes, then the colorless oil clear viscous liquid being condensed with polyethers, the organosilicone surfactant
Agent is preferably silwet L-77 or Silwet618 or Silwet 408.
Organic silicon surfactant can effectively increase pesticide solution in crop and have coverage rate on pest body and sprawl
Face, reaches more preferable spray effect, and pesticide efficacy is greatly improved, while reducing residues of pesticides.
Organic silicon surfactant can promote agricultural chemicals to be attached on plant leaf blade, be organized by stomata rapid osmotic to blade face
It is interior, improve wettability.
Because organic silicon surfactant time of penetration is short, pesticide solution can be made to stick to the wax coat of harmful organism body surface
On, rapidly permeated into by the air duct and stomata of harmful organism inside harmful organism, in harmful organisms endocrine resistance egg
Before white enzyme decomposing pesticide decoction, the concentration of pesticide solution has reached the lethal dose of harmful organism, is not likely to produce resistance.
The addition increase pesticide liquid of organic silicon surfactant drops in the wetability on blade face or insect while increasing agricultural chemicals medicine
The permeability and conductive performance of liquid.Silwet L-77 (spreader-sticker) mass percent is preferably 2.5%, the Silwet
618 (spreader-sticker) mass percents are preferably 3%, and Silwet 408 (spreader-sticker) mass percent is preferably 3%.
On the basis of above-mentioned technical proposal, the plant growth regulator is butyric acid potassium.
Butyric acid potassium is a kind of growth-promoting root class plant growth regulator, while may act on plant respectively grows vigorous portion
Position.Via foliage spray, passed to by positions such as blades in plant, and concentrate on growing point position, promoted cell division, have
Long-term effect and metastatic feature, stability are good, use safety.Butyric acid potassium (plant growth regulator) the quality percentage
Number is preferably 1%.
Thief zone height attachment agricultural chemicals synergist as described above, its preparation method comprises the following steps：
Each component is taken by proportioning, under 30 DEG C of constant temperature, under magnetic stirring, anti-drift auxiliary agent and plant growth are added in water
Conditioning agent, after after abundant dissolving, then adds emulsifying agent, is subsequently added into bleeding agent, be eventually adding spreader-sticker, be stirred well to molten
Liquid clear.
The stir speed (S.S.) of the magnetic agitation is 50-300r/min, more preferably preferably 100-140r/min, 120r/
min。
On the basis of above-mentioned technical proposal, it is calculated in mass percent, the Triton X-100 mass percents are preferred
For 15%, the polyvinylpyrrolidone mass percent is preferably 2.5%, and the hypertonic azone mass percent is preferably
2.5%, the JFC mass percents are preferably 4%, and the silwet L-77 mass percents are preferably 2.5%, described
Silwet618 mass percents are preferably 3%, and the mass percents of Silwet 408 are preferably 3%, the butyric acid potassium
Mass percent is preferably 1%.
In the pesticidal preparations field control effectiveness test for adding Thief zone height attachment agricultural chemicals synergist of the present invention, same
Deng under the conditions of, pesticide dosage is being reduced in the case of 33.33% after addition builder, and its killing rate and ovicidal rate all reach
Pesticide efficacy during non-decrement, while adding agricultural chemicals lasting effect after builder strengthens.Therefore, can be with according to above-mentioned result of the test
Deduce, in the case of identical drug effect, addition Thief zone height attachment agricultural chemicals synergist of the present invention, which can reduce agricultural chemicals, to be made
Consumption, it is ensured that the safety of operator and environment, reduces cost and residues of pesticides.
From above technical scheme, Thief zone height attachment agricultural chemicals synergist of the present invention can not only increase agricultural chemicals
The permeability and conductive performance of decoction, improve adhesive ability and wetability that pesticide liquid drops in target surface, while improving spraying
The evaporation rate of liquid, reduces the drift and loss of pesticide solution, promotes plant growth；The purpose of pesticide reduction is reached, is improved
Pesticide efficacy, reduces environmental pollution, can be widely applied to agriculture field.
It is embodiment below.
The embodiment of the invention discloses a kind of Thief zone height attachment agricultural chemicals synergist and preparation method thereof.Art technology
Personnel can use for reference present disclosure, be suitably modified technological parameter realization.In particular, all similar replacements and change
Dynamic apparent to those skilled in the art, they are considered as being included in the invention.The present invention product and
Method is described by preferred embodiment, and related personnel can substantially not depart from present invention, spirit and scope
It is interior that product as described herein is modified or suitably changed with combining, to realize and apply the technology of the present invention.
For a further understanding of the present invention, a kind of Thief zone height attachment agricultural chemicals provided with reference to embodiment the present invention
Builder and preparation method thereof is described in detail.
Embodiment 1：Prepare Thief zone height attachment builder one of the present invention
It is calculated in mass percent, under 30 DEG C of constant temperature, under 120r/min mixing speeds, 1% poly- second is added in water
Alkene pyrrolidone K30 and 0.5% butyric acid potassium, after after abundant dissolving, then add 10%Triton X-100, are subsequently added into
2.5% hypertonic azone or JFC, is eventually adding 2.5% organic silicon surfactant silwet L-77 or Silwet 408, fully
Stir to solution clear.
Embodiment 2：Prepare Thief zone height attachment builder two of the present invention
It is calculated in mass percent, under 30 DEG C of constant temperature, under 50r/min mixing speeds, 5% polyethylene is added in water
Pyrrolidones K30 and 2.5% butyric acid potassium, after after abundant dissolving, then add 15%Triton X-100, are subsequently added into
5% hypertonic azone or JFC, is eventually adding 5% organic silicon surfactant silwet L-77 or Silwet 408, is sufficiently stirred for
To solution clear.
Embodiment 3：Prepare Thief zone height attachment builder three of the present invention
It is calculated in mass percent, under 30 DEG C of constant temperature, under 300r/min mixing speeds, 2.5% is added in water poly-
Vinylpyrrolidone K30 and 1% butyric acid potassium, after after abundant dissolving, then add 12.5%Triton X-100, then add
Enter 4% hypertonic azone or JFC, be eventually adding 3% organic silicon surfactant silwet L-77 or Silwet 618, fully stir
Mix to solution clear.
Embodiment 4：Prepare Thief zone height attachment builder four of the present invention
It is calculated in mass percent, under 30 DEG C of constant temperature, under 140r/min mixing speeds, 2.5% is added in water poly-
Vinylpyrrolidone K30 and 1.5% butyric acid potassium, after after abundant dissolving, then add 15%Triton X-100, then add
Enter 2.5% hypertonic azone or JFC, be eventually adding 3% organic silicon surfactant silwet L-77 or Silwet 618, fully
Stir to solution clear.
Embodiment 5：Prepare Thief zone height attachment builder five of the present invention
It is calculated in mass percent, under 30 DEG C of constant temperature, under 120r/min mixing speeds, 2% poly- second is added in water
Alkene pyrrolidone K30 and 1% butyric acid potassium, after after abundant dissolving, then add 11%Triton X-100, are subsequently added into
2.5% hypertonic azone, is eventually adding 3% organic silicon surfactant Silwet 618, is stirred well to solution clear.
Embodiment 6：Prepare Thief zone height attachment builder six of the present invention
It is calculated in mass percent, under 30 DEG C of constant temperature, under 120r/min mixing speeds, 3% poly- second is added in water
Alkene pyrrolidone K30 and 1% butyric acid potassium, after after abundant dissolving, then add 13%Triton X-100, are subsequently added into
4%JFC, is eventually adding 2.5% organic silicon surfactant silwet L-77, is stirred well to solution clear.
Detection 1：Thief zone height attachment agricultural chemicals synergist surface and interfacial property detection
Thief zone height attachment agricultural chemicals synergist surface and interfacial property detection include：Surface tension of liquid, drop are in stone
Deposition of the contact angle and drop on stencil plate surface in paraffin plate surface.Selected builder is builder five and builder
Six, dilute 200 times respectively and detected, and contrasted with water.
Table 1 dilutes builder surface and interfacial property after 200 times
As it can be seen from table 1 after addition builder, the surface tension of water is significantly reduced, and illustrates decoction energy of wetting itself
Power strengthens.Meanwhile, by taking contact angle as an example, drop initial contact angle is reduced after 20-30 °, balance than water droplet after addition builder
Contact angle reduction is more notable, illustrates that decoction spreading ability itself strengthens.Compare, add in paraffin plate surface deposition with water
Droplet deposition amount increase after builder, illustrates that decoction adhesion property itself strengthens.To dilution 200 times after builder surface and
Show after interfacial property detection, after addition builder, drop can not only improve it in target surface wetting and spreading performance, and
And strengthen it in target surface adhesion property.
Detection 2：Add pesticide solution surface and interfacial property detection after Thief zone height attachment agricultural chemicals synergist
Choice experiment room self-control pesticidal preparations (14.5% high chlorine spiral shell worm ethyl ester SC) addition Thief zone height attachment agricultural chemicals increases
Imitate auxiliary agent；Its pesticidal preparations dilutes 3000 times, the 4000 times of addition builder dilutions 200 of contrast experiment's Pesticides preparation diluent
Times.
Surface and interfacial property detection include：Surface tension of liquid, drop are in target surface contact angle, drop in target table
The adhesion of face deposition (selected target surface is respectively paraffin plate, Apple Leaves, apple skin) and drop on Apple Leaves surface
Power.
Numbering 1 is 3000 times of pesticidal preparations solution of dilution, and numbering 2 is 4000 times of 200 times of pesticidal preparations addition dilutions of dilution
Builder five, numbering 3 is 4000 times of pesticidal preparations addition 200 times of builders six of dilution of dilution.
Pesticide solution surface and interfacial property detection after the addition builder of table 2
From Table 2, it can be seen that the surface tension of pesticidal preparations is substantially reduced after addition builder, its corresponding target
Surface balance contact angle also reduces, and illustrates that the addition of builder improves the wetting and spreading ability of pesticidal preparations.Meanwhile, addition
Pesticidal preparations deposition on target surface is significantly improved after builder, and adhesion (Gu-liquid interfacial interaction power) increases
By force, illustrate that the addition of builder improves the adhesion property of pesticidal preparations.
Field control effectiveness test
Test agricultural chemicals：14.5% high chlorine spiral shell worm ethyl ester SC；
Test builder：Embodiment five and the builder of embodiment six and according to embodiment five and the method system of embodiment six
Standby builder；
Controlling object：Small heart-eating peach worm
Environmental condition：Experimental field physical features is gentle, and preferably, rich water quality management is normal, and growing way is more consistent, test sample for retain water and nutrients
It is golden short life to plant, age of tree life in 9 years, and seeding row spacing is 2 × 4m.
Set up blank control group (water), test group 1 (14.5% high chlorine spiral shell worm ethyl ester SC dilutes 3000 times), test group 2
(14.5% high chlorine spiral shell worm ethyl ester SC dilutes 4000 times of addition dilutions, 200 times of builders five), (14.5% is high for test group 3
Chlorine spiral shell worm ethyl ester SC dilutes 4000 times of addition dilutions, 200 times of builders six).Using stretcher type power sprayer spraying (ZL-
22-160 types), accomplish uniformly to spray leave dual sides during dispenser.This experiment is repeated 3 times, and once, investigation is applied for experiment dispenser every time
5 days, the ovicidal effect of 10 days after medicine, the prevention effect of 5 days, 10 days, 15 days and 30 days, does not have rainfall during dispenser after dispenser,
Other medicaments were not used simultaneously.
Ovicidal effect (%)=[each phase worm's ovum number before (each phase worm's ovum number after each phase worm's ovum number-dispenser before dispenser)/dispenser]
× 100%；Prevention effect (%)=[(blank increases wormed fruit rate-newly-increased wormed fruit rate newly)/blank increases wormed fruit rate newly] × 100, wherein
Each phase wormed fruit rate before each phase wormed fruit rate-dispenser after newly-increased wormed fruit rate (%)=dispenser.The results are shown in Table 3 and table 4, wherein table 3 be
Liaoning Province's Xingcheng City fruit tree research test result, table 4 is the test result in Shanxi Province Linfen plant protection unit.
Prevention effect (fruit tree research institute) of the pesticidal preparations to small heart-eating peach worm after the addition builder of table 3
Ovicidal effect and prevention effect (Linfen plant protection of the pesticidal preparations to small heart-eating peach worm after the addition builder of table 4
Stand)
From table 3 and table 4 as can be seen that after addition builder, pesticidal preparations are still protected in the case of decrement 33.33%
Higher prevention effect has been held, and the lasting period is up to 30 days；Meanwhile, ovicidal effect is significantly improved after addition builder.
Illustrate that builder not only shows excellent characteristic when surface and interfacial property are detected, while the also table in field control effectiveness test
Reveal the wetting of color, the ability sprawled, adhere to and permeated, pesticide efficacy is improved with this, reduce pesticide dosage and spraying
Number of times, reduction environmental pollution and financial burden.
In summary result of the test, the Thief zone height attachment pesticide synergistic prepared according to embodiment five and embodiment six
After auxiliary agent is added in pesticidal preparations, reducing the surface tension of medicament strengthens its wetting and spreading ability, reduces drop and exists
Target surface contact angle, while enhancing the interaction of drop and target surface, adhesion enhancing improves target surface and sunk
Accumulated amount.Effect embodies high wettability, high osmosis and the high tack of builder above, therefore in the effect experiment of crop field
Premium properties is shown, after pesticide reduction 33.33%, its ovicidal effect and prevention effect and the agricultural chemicals without builder
Decoction has reached the purpose of pesticide reduction, has improved pesticide efficacy compared to being obviously improved.Meanwhile, synergy is helped
Plant growth regulator is also added in agent --- butyric acid potassium, promote plant growth, lift fruit-setting rate, reach volume increase mesh
's.
The explanation of above example is only intended to understand the method and core concept of the present invention.It should be pointed out that for this skill
For the those of ordinary skill in art field, without departing from the principles of the present invention, some change can also be carried out to the present invention
Enter and modify, these are improved and modification also falls within the scope of the invention as claimed.
The content not being described in detail in this specification belongs to prior art known to professional and technical personnel in the field.
Claims (1)
1. the Thief zone height attachment agricultural chemicals synergist of separation is being prepared by 14.5% high 4000 times of chlorine spiral shell worm ethyl ester SC dilutions
Purposes in medicament obtained from the Thief zone height attachment agricultural chemicals synergist of 200 times of addition dilution, it is characterised in that：Institute
State Thief zone height attachment agricultural chemicals synergist to be made up of preparation method, the preparation method is made up of following steps：
It is calculated in mass percent, under 30 DEG C of constant temperature, under 120r/min mixing speeds, 2% polyethylene pyrrole is added in water
Pyrrolidone K30 and 1% butyric acid potassium, after after abundant dissolving, then add 11%Triton X-100, are subsequently added into 2.5%
Hypertonic azone, is eventually adding 3% organic silicon surfactant Silwet 618, is stirred well to solution clear.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510319439.5A CN104886050B (en) | 2015-06-11 | 2015-06-11 | A kind of Thief zone height attachment agricultural chemicals synergist and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510319439.5A CN104886050B (en) | 2015-06-11 | 2015-06-11 | A kind of Thief zone height attachment agricultural chemicals synergist and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104886050A CN104886050A (en) | 2015-09-09 |
| CN104886050B true CN104886050B (en) | 2017-10-13 |
Family
ID=54019370
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510319439.5A Active CN104886050B (en) | 2015-06-11 | 2015-06-11 | A kind of Thief zone height attachment agricultural chemicals synergist and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104886050B (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106719622B (en) * | 2016-11-25 | 2020-10-27 | 广东省农业科学院植物保护研究所 | Pesticide synergistic decrement agent |
| CN106719738B (en) * | 2016-12-09 | 2018-07-24 | 陕西先农生物科技有限公司 | A kind of composition pesticide and preparation method thereof of Spirotetramat-contaipesticidal and Buprofezin |
| CN107094760A (en) * | 2017-05-05 | 2017-08-29 | 安徽扬子化工有限公司 | A kind of insecticide used additives |
| CN108782553A (en) * | 2017-05-05 | 2018-11-13 | 沧州鸿源农化有限公司 | A kind of unmanned plane anti-drift builder composition |
| CN110583636A (en) * | 2018-06-13 | 2019-12-20 | 江苏龙灯化学有限公司 | Pesticide adjuvant suitable for agriculture and application thereof |
| CN108935458A (en) * | 2018-07-06 | 2018-12-07 | 南开大学 | Corn field herbicide synergistic auxiliary and preparation method and application thereof |
| CN111887254A (en) * | 2020-08-20 | 2020-11-06 | 广东省农业科学院植物保护研究所 | High-permeability and high-adhesion pesticide synergistic additive and preparation method thereof |
| CN115812703A (en) * | 2021-12-24 | 2023-03-21 | 中国农业大学 | Application of water-soluble packaging bag in pesticide application reduction and efficiency improvement |
| CN114271271A (en) * | 2022-01-06 | 2022-04-05 | 海南省农业科学院热带果树研究所 | Application of surfactant in litchi drug reduction |
| CN116019118A (en) * | 2022-12-18 | 2023-04-28 | 中国农业科学院棉花研究所 | Preparation of novel chemical pesticide synergist and application of novel chemical pesticide synergist in cotton aphid prevention and control |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102511476B (en) * | 2011-09-29 | 2013-11-20 | 海南利蒙特生物农药有限公司 | Spray assistant and preparation method thereof |
| CN103493804B (en) * | 2013-09-30 | 2014-12-17 | 浙江海正化工股份有限公司 | Compound pesticide wetting agent and application of compound pesticide wetting agent in preparation of pesticide preparations |
| CN103719077B (en) * | 2014-01-02 | 2016-06-08 | 广西田园生化股份有限公司 | Amino acid water-based herbicide for low-volume spraying |
-
2015
- 2015-06-11 CN CN201510319439.5A patent/CN104886050B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN104886050A (en) | 2015-09-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104886050B (en) | A kind of Thief zone height attachment agricultural chemicals synergist and preparation method thereof | |
| CN105076132A (en) | Oil-based type pesticide synergistic auxiliary and preparation method therefor | |
| CN101773113B (en) | Hot fogging concentrate containing propiconazole and chlorpyrifos and preparation method thereof | |
| CN114532347A (en) | Herbicide composition containing pyriminobac and application thereof | |
| CN110896959A (en) | Composite insecticidal and acaricidal nano-water agent containing efficient cyhalothrin and chlorpyrifos and application thereof | |
| AU2012210146B2 (en) | Pesticide composition comprising sulphur, an acaricide and an agrochemical excipient | |
| CN109169737A (en) | A kind of herbicide synergistic composition and its preparation method and application | |
| CN108770843A (en) | A kind of spray adjuvants and preparation method thereof and include its spray liquid | |
| CN102172250A (en) | Preparation method and application of eauveria-spinosad suspending agent | |
| CN110037014B (en) | Compound synergist containing lecithin and D-limonene and preparation method and application thereof | |
| CN108293990B (en) | Special synergist for pesticide spray and preparation method and application thereof | |
| CN103918678A (en) | Seed coating agent with functions of repelling birds and rats | |
| CN105901012A (en) | Suspended seed coating prepared from pyraclostrobin, penflufen and clothianidin | |
| CN102511477B (en) | Pyrethrin hot fogging agent and preparation method and application thereof | |
| CN107646837A (en) | A kind of green and environment-friendly pesticide spray adjuvantses composition | |
| CN107646838A (en) | A kind of edible glue class pesticide spray assistant composition | |
| CN104996418A (en) | Synergist in water-based pesticide and preparation method for synergist | |
| CN112772671B (en) | Dinotefuran-containing compound insecticidal composition and application thereof | |
| CN1481683A (en) | Phytocide composite | |
| CN101213975B (en) | Miticide composition containing fenpyroximate active ingredient and uses thereof | |
| WO2016070632A1 (en) | Insect-killing mite-killing agent composition with synergistic effect | |
| CN108391666A (en) | A kind of Pesticidal combination containing ethyl pleocidin and paichongding | |
| CN103798252B (en) | A kind of mesotrione complex weedicide | |
| CN108402053A (en) | A kind of phonetic binary herbicide of ring and its application | |
| CN102484991A (en) | Synergic farm pesticide composition of ivermectin and tea saponin |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20180518 Address after: No. 55 Yuai Road, Guilin, the Guangxi Zhuang Autonomous Region Patentee after: Guilin Jiqi Biochemical Co., Ltd. Address before: 100193 West Road, Old Summer Palace, Haidian District, Haidian District, Beijing Patentee before: China Agricultural University |
|
| TR01 | Transfer of patent right |