CN107619840A - Abandoned mine injects biomass with losing coal cometabolism methane phase technique - Google Patents

Abandoned mine injects biomass with losing coal cometabolism methane phase technique Download PDF

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Publication number
CN107619840A
CN107619840A CN201711094807.6A CN201711094807A CN107619840A CN 107619840 A CN107619840 A CN 107619840A CN 201711094807 A CN201711094807 A CN 201711094807A CN 107619840 A CN107619840 A CN 107619840A
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China
Prior art keywords
coal
biomass
cometabolism
losing
mine
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Pending
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CN201711094807.6A
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Chinese (zh)
Inventor
郭红玉
夏大平
张宏图
苏现波
董志伟
高志祥
贾建波
张怀文
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Henan University of Technology
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Henan University of Technology
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Priority to CN201711094807.6A priority Critical patent/CN107619840A/en
Publication of CN107619840A publication Critical patent/CN107619840A/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

Abstract

Abandoned mine injects biomass with losing coal cometabolism methane phase technique, comprises the following steps:(1)Selection will scrap or written-off colliery;(2)Selection loses the more working face of coal or barrier pillar as testing site;(3)Wall-rock crack and roadway engineering are handled, form a relatively independent closing space;(4)Establish two passages being connected with ground;(5)After Coal mine closure, biomass by presetting the closing space under passage injection well;(6)As the closed-in time extends, mine water is progressively completely soaked something lost coal and biomass, passes through aerogenesis overflow channel, monitoring gas production rate, aerogenesis total amount and gas component;(7)Biomass is evaluated with losing coal cometabolism methane phase effect.The present invention utilizes the methanogen floras that is widely present in abandoned mine water, promotes biomass and lose coal cometabolism to produce methane, improves and loses coal utilization rate and biomass gas generating amount, realize turn waste into wealth, the purpose of energy-saving and emission-reduction.

Description

Abandoned mine injects biomass with losing coal cometabolism methane phase technique
Technical field
The invention belongs to coal bed gas bioengineering field, and abandoned mine injection biomass is with losing coal cometabolism methane phase work Skill.
Background technology
The China's coal-mine rate of extraction is relatively low, and particularly mining conditions difference or mining type select improperly mine, lose Stay resource quantity huge, secondary recovery difficulty is big.Spontaneous combustion and Gas caused by coal are lost, not only waste of resource and pollution ring Border, the safety in production to colliery cause serious threat, it has also become the main object that colliery is taken precautions against natural calamities.Biomass is primarily referred to as agriculture and forestry The lignocellulosics such as stalk, trees in production process in addition to grain, fruit, farming industry leftover bits and pieces, agricultural are discarded The materials such as fowl and animal excrement and discarded object during thing and Animal husbandry production.The utilization ways of biomass are more, but utilization rate is low, Not only waste of resource, deteriorate ecological environment, such as the thing such as smog, flue dust and carbon monoxide caused by the burning of substantial amounts of agricultural stalk Matter seriously endangers the health of people.Many researchs have confirmed that methanogen floras is widely present in abandoned mine water, in coal Hydrogen content is relatively low, and biomass hydrogen content is higher, and coal combines the gas production that can significantly improve biological methane with biomass, exceedes Single coal or biomass are as substrate aerogenesis sum.The present invention provides one kind in abandoned mine injection biomass with losing coal association With metabolism methane phase technique, two kinds of resources being difficult by of something lost coal and biomass can be passed through methanogen floras in mine water Metabolic conversion be clean energy resource-biological methane, realization is turned waste into wealth, and economic benefit and social benefit are notable.
The content of the invention
Present invention aims at offer one kind in abandoned mine injection biomass with losing coal cometabolism methane phase technique, The biomass of something lost coal and injection in colliery is converted into clean energy resource-biological methane.
In order to realize purpose, the present invention adopts the following technical scheme that:Abandoned mine injects biomass with losing coal cometabolism Methane phase technique, it is characterised in that:Comprise the following steps:
(1)Selection will scrap or written-off colliery, and degree of metamorphism is that middle low coal rank is optimal;
(2)Selection loses the more working face of coal or barrier pillar as testing site;
(3)Wall-rock crack and roadway engineering are handled, form a relatively independent closing space, meets to accommodate biomass Ability, the basic demand that mine water can smoothly penetrate into, gas can be assembled;
(4)Two passages being connected with ground are established, one of passage is used for aerogenesis overflow channel, and another passage is used to give birth to Material conveys;
(5)After Coal mine closure, biomass is passed through the closing space under default passage injection well;
(6)As the closed-in time extends, mine water is progressively completely soaked something lost coal and biomass, passes through aerogenesis overflow channel, prison Control gas production rate, aerogenesis total amount and gas component;
(7)Contrasted with biomass or something lost coal as the aerogenesis total amount of single substrate, evaluation biomass is with losing the production of coal cometabolism Methane effect.
Described step(2)The more working face or barrier pillar of coal is lost in middle selection, solid coal seam or does not have wherein In the girdle for having extraction value is also included within.
Described step(3)As long as middle treatment measures satisfaction accommodates the ability of biomass, mine water can smoothly penetrate into, gas The basic demand that body can be assembled;As long as solid coal seam can reach in above-mentioned requirements are also included within.
Described step(4)Middle to establish two passages being connected with ground, one of them is used for aerogenesis overflow channel, another The individual biomass that is used for conveys.
Described step(5)Biomass is injected into testing site by middle realization.
Described step(7)It is middle biomass-something lost coal mix gas production can exceed single creature matter gas production with it is single Coal gas production sum is lost as evaluation criterion, the index that evaluation criterion includes has gas production rate, aerogenesis total amount and gas component.
Using microorganism species present in mine water, coal is converted into together with biomass the gas based on methane, only Meet that this category feature belongs to the protection domain of this patent.
Using above-mentioned technical proposal, the present invention has great originality, utilizes the production being widely present in abandoned mine water Methane flora, promote biomass and lose coal cometabolism generation methane, improve and lose coal utilization rate and biomass gas generating amount, realize Turn waste into wealth, the purposes of energy-saving and emission-reduction.
Embodiment
Technique of the abandoned mine injection biomass of the present invention with losing coal cometabolism methane phase, includes following step successively Suddenly:(1)The colliery that will be scrapped is selected, degree of metamorphism is lignite;(2)Selection loses the more barrier pillar of coal as testing site;(3) Slip casting is carried out to wall-rock crack, enclosing tunnel engineering, testing site is met that receiving stalk, mine water smoothly penetrate into, produced The gas such as methane the basic demand such as can assemble;(4)Two passages being connected with ground are established, one of them overflows for aerogenesis Go out passage, another is conveyed for biomass;(5)After Coal mine closure, biomass by presetting the examination under passage injection well Test a little;(6)60 more than d are waited, pass through aerogenesis overflow channel, monitoring gas production rate, aerogenesis total amount and gas component;(7)In phase The aerogenesis that single lignite and stalk are carried out respectively with the conditions of as substrate is tested, and can biomass-something lost coal mixing aerogenesis be surpassed Above-mentioned aerogenesis sum is crossed as evaluation criterion, evaluation biomass and the cometabolism methane phase technique for losing coal.
Described step(2)The more working face or barrier pillar of coal is lost in middle selection, solid coal seam or does not have wherein In the girdle for having extraction value is also included within.
Described step(3)As long as middle treatment measures satisfaction accommodates the ability of biomass, mine water can smoothly penetrate into, gas Body such as can assemble at the basic demand.As long as solid coal seam can reach in above-mentioned requirements are also included within.
Described step(4)Middle to establish two passages being connected with ground, one of them is used for aerogenesis overflow channel, another The individual biomass that is used for conveys.
Described step(5)Biomass is injected into testing site by middle realization.
Described step(7)It is middle biomass-something lost coal mix gas production can exceed single creature matter gas production with it is single Coal gas production sum is lost as evaluation criterion, including the index such as gas production rate, aerogenesis total amount and gas component.
The present invention can make full use of existing equipment and condition in abandoned mine, and biomass is carried out into biology turn with losing coal Change, improve methane yield, eliminate the environmental problem that crop straw burning is brought, improve the utilization rate for losing coal.

Claims (7)

1. abandoned mine injects biomass with losing coal cometabolism methane phase technique, it is characterised in that:Comprise the following steps:
(1)Selection will scrap or written-off colliery, and degree of metamorphism is that middle low coal rank is optimal;
(2)Selection loses the more working face of coal or barrier pillar as testing site;
(3)Wall-rock crack and roadway engineering are handled, form a relatively independent closing space, meets to accommodate biomass Ability, the basic demand that mine water can smoothly penetrate into, gas can be assembled;
(4)Two passages being connected with ground are established, one of passage is used for aerogenesis overflow channel, and another passage is used to give birth to Material conveys;
(5)After Coal mine closure, biomass is passed through the closing space under default passage injection well;
(6)As the closed-in time extends, mine water is progressively completely soaked something lost coal and biomass, passes through aerogenesis overflow channel, prison Control gas production rate, aerogenesis total amount and gas component;
(7)Contrasted with biomass or something lost coal as the aerogenesis total amount of single substrate, evaluation biomass is with losing the production of coal cometabolism Methane effect.
2. abandoned mine injection biomass according to claim 1 exists with losing coal cometabolism methane phase technique, its feature In:
Described step(2)The more working face or barrier pillar of coal is lost in middle selection, solid coal seam or does not open wherein Adopt value girdle be also included within.
3. abandoned mine injection biomass according to claim 1 exists with losing coal cometabolism methane phase technique, its feature In:Described step(3)As long as middle treatment measures satisfaction accommodates the ability of biomass, mine water can smoothly penetrate into, gas energy The basic demand enough assembled;As long as solid coal seam can reach in above-mentioned requirements are also included within.
4. abandoned mine injection biomass according to claim 1 exists with losing coal cometabolism methane phase technique, its feature In:Described step(4)Middle to establish two passages being connected with ground, one of them is used for aerogenesis overflow channel, another use Conveyed in biomass.
5. abandoned mine injection biomass according to claim 1 exists with losing coal cometabolism methane phase technique, its feature In:Described step(5)Biomass is injected into testing site by middle realization.
6. abandoned mine injection biomass according to claim 1 exists with losing coal cometabolism methane phase technique, its feature In:Described step(7)It is middle that can biomass-something lost coal mixing gas production be exceeded single creature matter gas production and single something lost coal production For tolerance sum as evaluation criterion, the index that evaluation criterion includes has gas production rate, aerogenesis total amount and gas component.
7. abandoned mine injection biomass according to claim 1 exists with losing coal cometabolism methane phase technique, its feature In:Using microorganism species present in mine water, coal is converted into together with biomass the gas based on methane, as long as meeting This category feature belongs to the protection domain of this patent.
CN201711094807.6A 2017-11-06 2017-11-06 Abandoned mine injects biomass with losing coal cometabolism methane phase technique Pending CN107619840A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110017163A (en) * 2019-02-26 2019-07-16 新汶矿业集团有限责任公司生产服务分公司 Utilize the method for microbial treatment coal mine gas

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5424195A (en) * 1990-06-20 1995-06-13 Secretary Of The Interior Method for in situ biological conversion of coal to methane
US20080193993A1 (en) * 2005-04-22 2008-08-14 Gunter Schulze Method and Plant for Producing Biogas from Bio-Organic Residual Matters
CN102517368A (en) * 2011-12-15 2012-06-27 河南理工大学 Method for preparing biogas by degrading coal with microorganisms
CN105420283A (en) * 2015-12-18 2016-03-23 太原理工大学 Method for filling abandoned roadway and preparing biomass energy sources by using garbage

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5424195A (en) * 1990-06-20 1995-06-13 Secretary Of The Interior Method for in situ biological conversion of coal to methane
US20080193993A1 (en) * 2005-04-22 2008-08-14 Gunter Schulze Method and Plant for Producing Biogas from Bio-Organic Residual Matters
CN102517368A (en) * 2011-12-15 2012-06-27 河南理工大学 Method for preparing biogas by degrading coal with microorganisms
CN105420283A (en) * 2015-12-18 2016-03-23 太原理工大学 Method for filling abandoned roadway and preparing biomass energy sources by using garbage

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
苏现波等: "煤制生物甲烷实验方案设计及优选", 《天然气工业》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110017163A (en) * 2019-02-26 2019-07-16 新汶矿业集团有限责任公司生产服务分公司 Utilize the method for microbial treatment coal mine gas

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