CN107550793A - Natural plant essence liquid and preparation method - Google Patents
Natural plant essence liquid and preparation method Download PDFInfo
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- CN107550793A CN107550793A CN201710937747.3A CN201710937747A CN107550793A CN 107550793 A CN107550793 A CN 107550793A CN 201710937747 A CN201710937747 A CN 201710937747A CN 107550793 A CN107550793 A CN 107550793A
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Abstract
The present invention relates to daily use chemicals technical field, especially a kind of natural plant essence liquid and preparation method thereof, including deionized water, baeckea frutescen extraction concentrated essence liquid, birch essential oil, 1,3 dihydroxy butane, Nexbase 2004, cyclomethicone, glycerine, polyoxyethylene carboxylate, cocoyl glucoside, isopropyl hexadecanoate, Sweet Almond Oil, median chain triglyceride oil, isomery dodecane, lauryl sodium sulfate, lauryl alcohol, methyl oleate, Glycerin, mixed triester with caprylic acid capric acid, eugenol, benzene oxygen second, palmityl alcohol.A kind of natural plant essence liquid provided by the invention and preparation method thereof, it make use of the essential oil and extract solution of baeckea frutescen, the active ingredient of baeckea frutescen plant is sufficiently extracted, obtained skin care item, there is good antibacterial, inflammation-diminishing function to skin, and there is no excitant, play good skin care effect.
Description
Technical field
The present invention relates to cosmetic technical field, is a kind of natural plant essence liquid and preparation method thereof, especially a kind of
The substrate liquid extremely preparation method of eye mask is used as by the use of this Essence.
Background technology
With the continuous improvement of living standard, maintenance of the people to healthy especially skin is increasingly taken seriously.Skin
Tissue is human body maximum tissue organ, is covered in human body surface, all harmful substances of barrier nature are to caused by viable organism
Detrimental effect.But with the increase at age, the gradual aging of function of skin histology organ, from the point of view of Aesthetic View, have a strong impact on
Enthusiasm of the people to life；From the point of view of physiology, effective protection of human internal organs is influenceed.The main original of skin aging
Because being that the various quantity of nutrient matter and quality needed in metabolic processes can not obtain physiology sexual satisfaction from diet,
So as to cause the quantity of the synthesis material of the life inhereditary material carrier DNA in life cells core to gradually decrease, it is ultimately resulted in
The kinds of protein and quantity for adjusting empty synthesis are reduced, and cellular metabolic activity declines therewith, and the life-span shortens relatively.The excessive aging of skin
The performance of phenomenon is：Cutis laxa, wrinkle increase intensification, pore increase, the thicker turmoil of dermatoglyph, skin elasticity decline etc..
At present, the most moisturizing of product for skin care on the market, limited efficacy.And natural plants can effectively achieve this mesh really
's.
As a kind of natural plants, baeckea frutescen has a variety of medical values, for example with dispelling wind and eliminating dampness, removing toxic substances, diuresis, stops
Bitterly, it is antipruritic to wait medical value, also there is the skin-protecting functions such as treatment eczema, pemphigus, the ringworm of the foot.
In traditional medicine adornment skin care item, it is typically necessary and adds the chemical agents such as antibacterial and sterilization, anti-inflammatory, to prevent skin
Disease, there is certain excitant to skin.
The medicine adornment skin care item of plant extracts have been engendered now, are mainly extracted effective components in plants, are utilized plant
The natural active principle of thing, reduces the excitant to skin.Plants essential oil has its unique composition and bioactivity, thus it
Medicine, antibacterial, cosmetics, additive etc. all have been widely used.But in plant extract, simply extract wherein essential oil
Partial active ingredient, plant medical value itself is not made full use of.Such as baeckea frutescen, presently mainly extract effective ingredient and add
To utilize.
The content of the invention
It is an object of the invention to provide a kind of skin care item for making full use of baeckea frutescen medical value.
To achieve the above object, the technical solution adopted by the present invention is：
A kind of natural plant essence liquid, by following material by weight：10 parts of deionized water, baeckea frutescen extraction are dense
Contracting Essence 15-19 parts, birch essential oil 6-9.7 parts, 1,3- dihydroxy butane 5-8 parts, Nexbase 2004 4.5-7.8 parts, ring first
Radical siloxane 4-7.5 parts, glycerine 6.5-8.8 parts, polyoxyethylene carboxylate 2.3-4.3 parts, cocoyl glucoside 1.6-3.2
Part, isopropyl hexadecanoate 1.4-2.1 parts, Sweet Almond Oil 1.3-2.2 parts, median chain triglyceride oil 1.5-2.8 parts, isomery 12
Alkane 0.2-0.5 parts, lauryl sodium sulfate 0.2-0.4 parts, lauryl alcohol 0.7-1.3 parts, methyl oleate 0.1-0.3 parts, the pungent last of the ten Heavenly stems
Acid glyceride 0.1-0.3 parts, eugenol 0.15-0.25 parts, Phenoxyethanol 0.1-0.4 parts, palmityl alcohol 0.1-0.4 parts.
Its preparation method of the natural plant essence liquid, comprises the following steps：
(1) take part deionization (amounts of most half, preferably shorter than half), according to formula take 1,3- dihydroxy butane,
Nexbase 2004, cyclomethicone, cocoyl glucoside, lauryl sodium sulfate, lauryl alcohol, eugenol, Phenoxyethanol,
Palmityl alcohol is scattered in deionized water, is thoroughly mixed to have obtained basic mixed liquor；
(2) by polyoxyethylene carboxylate, isomery dodecane, isopropyl hexadecanoate, median chain triglyceride oil, oleic acid first
After ester weighs according to formula, it is added in above-mentioned mixed liquor, and carries out heating water bath；
Wherein, cyclomethicone and isomery dodecane be respectively using an inventive point for being the present invention, though because both
Similar effect is so played in cosmetics, in the prior art also it is few both share, reason is that both fold together
The effect that adds is simultaneously good not as effect is used alone, but it is surprisingly found by the inventors that, by having been used cyclohexyl methyl silicon first
" the basic mixed liquor " of the step of oxygen alkane (1), isomery dodecane is then used alone again and continues waters mixing in step (2),
It can so cause cyclomethicone to be surrounded by several esters without being had an effect with isomery dodecane, and can play point
Other lubrication, the effect of moisturizing；
(3) birch essential oil, Sweet Almond Oil, be mixed to get mixed oil liquid；
Wherein described birch essential oil, it is necessary to which being handled by following steps to use：CHAGA is crushed to 50-100
Mesh, dry to water content and be less than 0.5%, then add the birch essential oil of 5-10 times of parts by weight, be heated to 55 degrees Celsius, keep
10-25 minutes, after being cooled to room temperature；Through overtesting, although CHAGA also has inoxidizability, it is, however, preferable that in heating
Before, the weak solution (25~50mg/L) of hydroquinones is added, the specially 2-3% of birch essential oil total weight parts so can be with non-
Often playing protection essential oil well will not be oxidized.
The heating for dissolving of essential oil is have passed through, the nutritional ingredient in CHAGA can be caused very well to incorporate birch essential oil
In, still, this heating means easily cause product to aoxidize, and by test of many times, inventor has obtained a kind of be more highly preferred to
Mode of heating：35 degrees Celsius of holding 2-3 minutes are heated to, temperature is brought up into 40 degrees Celsius within 1-2 minutes is kept for 5 minutes,
Then temperature is brought up into 47 degrees Celsius within 1-2 minutes to be kept for 5 minutes, temperature is then brought up to 55 within 1-2 minutes and taken the photograph
Family name's degree is kept for remaining time, and the heat time is 10-25 minutes altogether for holding.Such mode has two benefits, and first so that birch
Extraction of the another name for oil for CHAGA business composition is very complete；Second so that the oxidized probability of essential oil substantially reduces, can be with
It is almost less than pH value 7.1 to reach acidity, plus the addition of the weak solution of hydroquinones, can keep neutral, effect is very good.
(5) glycerine, Glycerin, mixed triester with caprylic acid capric acid and remaining deionized water mixing, and carry out heating water bath obtain glycerine mixing it is molten
Liquid；
(6) mixed oil liquid is added drop-wise in glycerine mixed solution, and is stirred, and after stirring 10~30 minutes, is sequentially added
Basic mixed liquor and baeckea frutescen extraction concentrated essence liquid stirs, and produces natural plant essence liquid.
Wherein, baeckea frutescen extraction concentrated essence liquid, preparation method include procedure below：
(1) the debris soil on baeckea frutescen branch is cleaned out, retains leaf, and cleaned up with clear water, dried, then
It is put into hydrogen peroxide and is cleaned and sterilized again, the mass concentration of hydrogen peroxide is 3%；
(2) the baeckea frutescen branch after sterilization is taken out after draining away the water, is dried to moisture content below 5%, then will drying
Branch crush, the grain diameter after crushing is not more than 1mm；
(3) the baeckea frutescen particle after crushing, to 300 mesh, obtains ultra micro baeckea frutescen powder using ultramicro grinding；
(4) water is added, the quality of water is ultra micro baeckea frutescen powder times, and regulation pH adds cellulase and carries out enzyme 4.5~6.5
Solution, it is incubated 26-31 DEG C；
(5) according to every 100kg ultra micros baeckea frutescen powder, with the ethanol solution 500kg that purity is 95%, the appearance of sealing is put into together
In device, heating water bath, the temperature of heating is 35-40 DEG C, after being incubated 6-8 hours, is being heated up to 60-65 DEG C simultaneously, stirring is peeled off
20 minutes；
(6) solution after being peeled off with the filter membrane of 500 mesh to stirring filters, after slag-liquid separation, the use of filter residue again
Alcohol solution dipping, filtering, the filtrate being filtrated to get twice merge；
(7) filtrate is put into container, and for heating water bath to 50-60 DEG C, baeckea frutescen essential oil is pooled to the surface of liquid, collects baeckea frutescen
Essential oil；
(8) remaining filtrate uses Ultra filtration membrane processing method, sets ultrafiltration granularity as 0.01 μm, will remove baeckea frutescen essence
Filtrate pressurization after oil, tiny residue is retained by the 0.01 μm of ultrafiltration of low pressure macropore and obtains low pressure macropore permeate；
(9) by low pressure macropore permeate, the ultrafiltration through membranes through 0.00l μm of high pressure aperture retain again, separate high pressure aperture is saturating
Cross the trapped fluid of liquid and high pressure aperture；
(10) extract solution is concentrated, amalgamation liquid concentration extracts concentrated essence liquid until baeckea frutescen.
Wherein, the method in described step (5) can obtain the extraordinary product of effect, but pass through inventor
Long-term improvement and experiment, obtained a kind of more preferred method, be the present invention an inventive point, it is specific as follows：According to
Per 100kg ultra micro baeckea frutescen powder, with the ethanol solution 500kg that purity is 95%, it is put into together in the container of sealing, heating water bath,
The temperature of heating is 35-40 DEG C, after being incubated 6-8 hours, is being heated up to 60-65 DEG C simultaneously, and stirring is peeled off 20 minutes；Wherein, water
Bathe heating time and mode further refine, the active ingredient of baeckea frutescen powder can be caused it is further proposed that, that is, the temperature heated
For 35 degree of wait 1-2 hours, 40 DEG C are then risen within 1-2 minutes, after being incubated 4-7 hours, in 5 minutes, is heated up to 60
DEG C kept for 5 minutes, 65 DEG C are then heated within 1-2 minutes and is kept for 10 minutes, it is a kind of within this 20 minutes time to keep stirring
Mix.The final products of the step of have passed through improvement (5), by 6 groups, the Blind Test of every group of 15 people, the concentration of fragrance matter improves
2.3%.
Put into practice for many years in addition, inventor passes through, obtained following processing step, i.e., between step (9) and step (10),
Can also preferably, increase a silica gel column chromatography the step of, step is as follows：By high pressure aperture permeate, through silica gel column chromatography
Vacuum state infiltration absorption, obtains eluent, then merges eluent with the trapped fluid of high pressure aperture, obtain extract solution；Obtain
Extract solution it is extremely high in purity, and due to being physical method, can't have any shadow to the quality of product in itself
Ring, still, inventor has found in multiple experimentation, due in the work by " silica gel column chromatography vacuum state infiltration absorption "
When skill, have very more polar molecules and remain in silicagel column, this also often use this suction in this area
Subsidiary formula method carries out precious raw material disposal, because having very big loss late, causes production cost to sharply increase, the present inventor
By constantly research and development and practice, preferred method is obtained, this method can be reduced because polar molecule adsorption silica gel post
It is loss to cause so that production cost reduces, and specific way is as follows：Firstly, it is necessary to the use environment of the silicagel column to using is entered
Row transformation, preferable silica gel are pH value 6.5-6.9 (consistent with baeckea frutescen extract solution, to avoid that neutralization reaction occurs), and moisture is less than
3%, specific surface area is 320-350 square metres every gram；Before by this technique, high pressure aperture permeate is heated to 70-78
Degree Celsius, such benefit is on the premise of avoiding the volatilization of volatility effect material, silicagel column to be passed through more quickly, by above-mentioned two
The setting of individual key technology point so that final loss of effective components rate substantially reduces, while can effectively go the removal of impurity.
By detection, cymol (English：P-Cymene content) improves 0.036%, pulls aromatic content and carries
It is high by 0.012%.
Further, since the extract that the inventive method step (10) obtains has the taste of some slant acidities, although very light,
It it is the problem of as cosmetic field being still one very big, inventor has found to add the green tea extraction of 0.02-0.035 parts by weight
The kudzu root extract of thing and 0.06-0.075 parts by weight, this is the vast improvement of the present invention so that product of the present invention is specific
Fresh taste, the slightly pungent taste in baeckea frutescen extract is got rid of, final products have very pure and fresh taste, and
Has the effect of improving a lot for the shelf-life., can be with it is highly preferred that add the propane diols of 0.001-0.0015 parts by weight simultaneously
Preferably so that green-tea extract merges with final extract, inventor tests general ten several fusion agents, the effect of propane diols
Fruit is optimal.Preferably, green-tea extract uses commercially available product, and wherein kudzu root extract requires that the root of kudzu vine is always yellow
The standard of ketone (total flavon) 80%.
The product of the present invention, in actual use, optimally, the use of eye mask substrate liquid is configured to, it is specific to use
Method is as follows：The water-soluble collagen of convention amount is added in Essence, target usage amount is so that final eye mask substrate liquid
Viscosity be 2.3 × 10-3~3.4 × 10-3Pa·s.It mitigates for the wrinkle of eye part skin and prevents allergic reaction to have
Extraordinary effect.
A kind of natural plant essence liquid provided by the invention and preparation method thereof, make use of the essential oil and extract solution of baeckea frutescen,
The active ingredient of baeckea frutescen plant is sufficiently extracted, obtained skin care item, there is good antibacterial, anti-inflammatory work(to skin
Can, and there is no excitant, play good skin care effect.
Embodiment
In order to deepen the understanding of the present invention, with reference to embodiment, the invention will be further described, and the embodiment is only
For explaining the present invention, it is not intended to limit the scope of the present invention..
Embodiment 1
A kind of natural plant essence liquid, by following material by weight：10 parts of deionized water, baeckea frutescen extraction are dense
16.7 parts of contracting Essence, 8 parts of birch essential oil, 1,3- 8 parts of dihydroxy butane, 6 parts of Nexbase 2004,4 parts of cyclomethicone are sweet
8.8 parts of oil, 4 parts of polyoxyethylene carboxylate, 3.2 parts of cocoyl glucoside, 1.6 parts of isopropyl hexadecanoate, Sweet Almond Oil 2.2
Part, 1.5 parts of median chain triglyceride oil, 0.5 part of isomery dodecane, 0.2 part of lauryl sodium sulfate, 1 part of lauryl alcohol, oleic acid first
0.2 part of ester, 0.2 part of Glycerin, mixed triester with caprylic acid capric acid, 0.15 part of eugenol, -0.4 part of Phenoxyethanol, 0.1 part of palmityl alcohol.
Its preparation method of the natural plant essence liquid, comprises the following steps：
(1) part deionization is taken, 1,3- dihydroxy butane, Nexbase 2004, cyclomethicone, cocounut oil are taken according to formula
Base glucoside, lauryl sodium sulfate, lauryl alcohol, eugenol, Phenoxyethanol, palmityl alcohol are scattered in deionized water, fully
It is stirred to have obtained basic mixed liquor；
(2) by polyoxyethylene carboxylate, isomery dodecane, isopropyl hexadecanoate, median chain triglyceride oil, oleic acid first
After ester weighs according to formula, it is added in above-mentioned mixed liquor, and carries out heating water bath；
(3) birch essential oil, Sweet Almond Oil, be mixed to get mixed oil liquid；
(5) glycerine, Glycerin, mixed triester with caprylic acid capric acid and remaining deionized water mixing, and carry out heating water bath obtain glycerine mixing it is molten
Liquid；
(6) mixed oil liquid is added drop-wise in glycerine mixed solution, and is stirred, and after stirring 10~30 minutes, is sequentially added
Basic mixed liquor and baeckea frutescen extraction concentrated essence liquid stirs, and produces natural plant essence liquid.
Embodiment 2
A kind of natural plant essence liquid, by following material by weight：10 parts of deionized water, baeckea frutescen extraction are dense
15 parts of contracting Essence, 6 parts of birch essential oil, 1,3- 5 parts of dihydroxy butane, 4.5 parts of Nexbase 2004,6.5 parts of cyclomethicone,
7 parts of glycerine, 4.3 parts of polyoxyethylene carboxylate, 2 parts of cocoyl glucoside, 2.1 parts of isopropyl hexadecanoate, Sweet Almond Oil 1.3
Part, 2 parts of median chain triglyceride oil, 0.4 part of isomery dodecane, 0.4 part of lauryl sodium sulfate, 1.3 parts of lauryl alcohol, oleic acid first
0.1 part of ester, 0.3 part of Glycerin, mixed triester with caprylic acid capric acid, 0.22 part of eugenol, 0.3 part of Phenoxyethanol, 0.2 part of palmityl alcohol.
Its preparation method of the natural plant essence liquid is same as Example 1.
Embodiment 3
A kind of natural plant essence liquid, by following material by weight：10 parts of deionized water, baeckea frutescen extraction are dense
19 parts of contracting Essence, 9.7 parts of birch essential oil, 1,3- 6.8 parts of dihydroxy butane, 7.8 parts of Nexbase 2004, cyclomethicone
7.5 parts, 6.5 parts of glycerine, 2.3 parts of polyoxyethylene carboxylate, 1.6 parts of cocoyl glucoside, 1.4 parts of isopropyl hexadecanoate,
2 parts of Sweet Almond Oil, 2.8 parts of median chain triglyceride oil, 0.2 part of isomery dodecane, 0.3 part of lauryl sodium sulfate, lauryl alcohol
0.7 part, 0.3 part of methyl oleate, 0.1 part of Glycerin, mixed triester with caprylic acid capric acid, 0.25 part of eugenol, 0.1 part of Phenoxyethanol, 0.4 part of palmityl alcohol.
Its preparation method of the natural plant essence liquid is same as Example 1.
Embodiment 4
Baeckea frutescen extracts the preparation method of concentrated essence liquid and essential oil, including procedure below：
(1) the debris soil on baeckea frutescen branch is cleaned out, retains leaf, and cleaned up with clear water, dried, then
It is put into hydrogen peroxide and is cleaned and sterilized again, the mass concentration of hydrogen peroxide is 3%；
(2) the baeckea frutescen branch after sterilization is taken out after draining away the water, is dried to moisture content below 5%, then will drying
Branch crush, the grain diameter after crushing is not more than 1mm；
(3) the baeckea frutescen particle after crushing, to 300 mesh, obtains ultra micro baeckea frutescen powder using ultramicro grinding；
(4) water is added, the quality of water is ultra micro baeckea frutescen powder times, and regulation pH adds cellulase and carries out enzyme 4.5~6.5
Solution, it is incubated 26-31 DEG C；
(5) according to every 100kg ultra micros baeckea frutescen powder, with the ethanol solution 500kg that purity is 95%, the appearance of sealing is put into together
In device, heating water bath, the temperature of heating is 40 DEG C, after being incubated 8 hours, is being heated up to 65 DEG C simultaneously, stirring is peeled off 20 minutes；Its
In, the time of heating water bath and mode further refine, the active ingredient of baeckea frutescen powder can be caused it is further proposed that, that is, heat
Temperature is 35 degree and waited 2 hours, and 40 DEG C were then risen in 2 minutes, after being incubated 7 hours, in 5 minutes, is heated up to 60 DEG C
Kept for 5 minutes, 65 DEG C were then heated in 2 minutes and is kept for 10 minutes, one kind is kept stirring within this 20 minutes time.
(6) solution after being peeled off with the filter membrane of 500 mesh to stirring filters, after slag-liquid separation, the use of filter residue again
Alcohol solution dipping, filtering, the filtrate being filtrated to get twice merge；
(7) filtrate is put into container, and for heating water bath to 50-60 DEG C, baeckea frutescen essential oil is pooled to the surface of liquid, collects baeckea frutescen
Essential oil；
(8) remaining filtrate uses Ultra filtration membrane processing method, sets ultrafiltration granularity as 0.01 μm, will remove baeckea frutescen essence
Filtrate pressurization after oil, tiny residue is retained by the 0.01 μm of ultrafiltration of low pressure macropore and obtains low pressure macropore permeate；
(9) by low pressure macropore permeate, the ultrafiltration through membranes through 0.00l μm of high pressure aperture retain again, separate high pressure aperture is saturating
Cross the trapped fluid of liquid and high pressure aperture；
(10) by high pressure aperture permeate, permeate and adsorb through silica gel column chromatography vacuum state, obtain eluent, then will elution
Liquid merges with the trapped fluid of high pressure aperture, obtains extract solution；Wherein silica gel is pH value 6.9, moisture 2.5%, specific surface area 350
Square metre every gram；Before by this technique, high pressure aperture permeate is heated to 78 degrees Celsius,
(11) extract solution is concentrated, amalgamation liquid concentration extracts concentrated essence liquid until baeckea frutescen.
(12) green-tea extract, the Pueraria lobota of 0.075 parts by weight of 0.035 parts by weight are added in baeckea frutescen extracts concentrated essence liquid
The propane diols of root extract and 0.0015 parts by weight, stir and can obtain final baeckea frutescen extraction concentrated essence liquid.4-1's
In embodiment, we are also added into the propane diols of 0.0015 parts by weight so that the homogeneity of product is very good.
After this method crushes baeckea frutescen branch, first digested, then extract essential oil again, finally obtain the liquid that skims the cream off milk,
Fully the active principle in baeckea frutescen can be extracted.The product of the present invention, in actual use, optimally, is configured to
Eye mask substrate liquid uses, and specific application method is as follows：The water-soluble collagen of convention amount, eye mask base are added in Essence
The viscosity of bottom liquid is 2.3 × 10-3Pa·s.It mitigates for the wrinkle of eye part skin and prevents allergic reaction with very good
Effect.
Embodiment 5
Baeckea frutescen extracts the preparation method of concentrated essence liquid and essential oil, including procedure below：
(1) the debris soil on baeckea frutescen branch is cleaned out, retains leaf, and cleaned up with clear water, dried, then
It is put into hydrogen peroxide and is cleaned and sterilized again, the mass concentration of hydrogen peroxide is 3%；
(2) the baeckea frutescen branch after sterilization is taken out after draining away the water, is dried to moisture content below 5%, then will drying
Branch crush, the grain diameter after crushing is not more than 1mm；
(3) the baeckea frutescen particle after crushing, to 300 mesh, obtains ultra micro baeckea frutescen powder using ultramicro grinding；
(4) water is added, the quality of water is ultra micro baeckea frutescen powder times, and regulation pH adds cellulase and carries out enzyme 4.5~6.5
Solution, it is incubated 26-31 DEG C；
(5) according to every 100kg ultra micros baeckea frutescen powder, with the ethanol solution 500kg that purity is 95%, the appearance of sealing is put into together
In device, heating water bath, the temperature of heating is 35-40 DEG C, after being incubated 6-8 hours, is being heated up to 60-65 DEG C simultaneously, stirring is peeled off
20 minutes；
(6) solution after being peeled off with the filter membrane of 500 mesh to stirring filters, after slag-liquid separation, the use of filter residue again
Alcohol solution dipping, filtering, the filtrate being filtrated to get twice merge；
(7) filtrate is put into container, and for heating water bath to 50-60 DEG C, baeckea frutescen essential oil is pooled to the surface of liquid, collects baeckea frutescen
Essential oil；
(8) remaining filtrate uses Ultra filtration membrane processing method, sets ultrafiltration granularity as 0.01 μm, will remove baeckea frutescen essence
Filtrate pressurization after oil, tiny residue is retained by the 0.01 μm of ultrafiltration of low pressure macropore and obtains low pressure macropore permeate；
(9) by low pressure macropore permeate, the ultrafiltration through membranes through 0.00l μm of high pressure aperture retain again, separate high pressure aperture is saturating
Cross the trapped fluid of liquid and high pressure aperture；
(10) by high pressure aperture permeate, permeate and adsorb through silica gel column chromatography vacuum state, obtain eluent, then will elution
Liquid merges with the trapped fluid of high pressure aperture, obtains extract solution；Wherein, silica gel is pH value 6.5, moisture 2%, specific surface area 320
Square metre every gram；Before by this technique, high pressure aperture permeate is heated to 70 degrees Celsius, adds the green of 0.02 parts by weight
The kudzu root extract of 0.075 parts by weight of tea extraction,
(11) extract solution is concentrated, amalgamation liquid concentration extracts concentrated essence liquid until baeckea frutescen.
After this method crushes baeckea frutescen branch, first digested, then extract essential oil again, finally obtain the liquid that skims the cream off milk,
Fully the active principle in baeckea frutescen can be extracted.
(12) green-tea extract, the root of kudzu vine of 0.06 parts by weight of 0.02 parts by weight are added in baeckea frutescen extracts concentrated essence liquid
The propane diols of extract and 0.001 parts by weight, stir and can obtain final baeckea frutescen extraction concentrated essence liquid.
Embodiment 6
Baeckea frutescen extracts the preparation method of concentrated essence liquid and essential oil, including procedure below：
(1) the debris soil on baeckea frutescen branch is cleaned out, retains leaf, and cleaned up with clear water, dried, then
It is put into hydrogen peroxide and is cleaned and sterilized again, the mass concentration of hydrogen peroxide is 3%；
(2) the baeckea frutescen branch after sterilization is taken out after draining away the water, is dried to moisture content below 5%, then will drying
Branch crush, the grain diameter after crushing is not more than 1mm；
(3) the baeckea frutescen particle after crushing, to 300 mesh, obtains ultra micro baeckea frutescen powder using ultramicro grinding；
(4) water is added, the quality of water is ultra micro baeckea frutescen powder times, and regulation pH adds cellulase and digested, protected 6.5
Warm 26-31 DEG C；
(5) according to every 100kg ultra micros baeckea frutescen powder, with the ethanol solution 500kg that purity is 95%, the appearance of sealing is put into together
In device, heating water bath, the temperature of heating is 35 DEG C, after being incubated 6 hours, is being heated up to 60 DEG C simultaneously, stirring is peeled off 20 minutes；Its
In, the time of heating water bath and mode further refine, the active ingredient of baeckea frutescen powder can be caused it is further proposed that, that is, heat
Temperature is 35 degree and waited 1 hour, and 40 DEG C were then risen in 1 minute, after being incubated 4 hours, in 5 minutes, is heated up to 60 DEG C
Kept for 5 minutes, 65 DEG C were then heated in 1 minute and is kept for 10 minutes, one kind is kept stirring within this 20 minutes time.
(6) solution after being peeled off with the filter membrane of 500 mesh to stirring filters, after slag-liquid separation, the use of filter residue again
Alcohol solution dipping, filtering, the filtrate being filtrated to get twice merge；
(7) filtrate is put into container, and for heating water bath to 60 DEG C, baeckea frutescen essential oil is pooled to the surface of liquid, collects baeckea frutescen essence
Oil；
(8) remaining filtrate uses Ultra filtration membrane processing method, sets ultrafiltration granularity as 0.01 μm, will remove baeckea frutescen essence
Filtrate pressurization after oil, tiny residue is retained by the 0.01 μm of ultrafiltration of low pressure macropore and obtains low pressure macropore permeate；
(9) by low pressure macropore permeate, the ultrafiltration through membranes through 0.00l μm of high pressure aperture retain again, separate high pressure aperture is saturating
Cross the trapped fluid of liquid and high pressure aperture；
(10) by high pressure aperture permeate, permeate and adsorb through silica gel column chromatography vacuum state, obtain eluent, then will elution
Liquid merges with the trapped fluid of high pressure aperture, obtains extract solution；
(11) extract solution is concentrated, amalgamation liquid concentration extracts concentrated essence liquid until baeckea frutescen.
After this method crushes baeckea frutescen branch, first digested, then extract essential oil again, finally obtain the liquid that skims the cream off milk,
Fully the active principle in baeckea frutescen can be extracted.
Embodiment 7
Baeckea frutescen extracts the preparation method of concentrated essence liquid and essential oil, including procedure below：
(1) the debris soil on baeckea frutescen branch is cleaned out, retains leaf, and cleaned up with clear water, dried, then
It is put into hydrogen peroxide and is cleaned and sterilized again, the mass concentration of hydrogen peroxide is 3%；
(2) the baeckea frutescen branch after sterilization is taken out after draining away the water, is dried to moisture content below 5%, then will drying
Branch crush, the grain diameter after crushing is not more than 1mm；
(3) the baeckea frutescen particle after crushing, to 300 mesh, obtains ultra micro baeckea frutescen powder using ultramicro grinding；
(4) water is added, the quality of water is ultra micro baeckea frutescen powder times, and regulation pH adds cellulase and digested, protected 4.5
Warm 26-31 DEG C；
(5) according to every 100kg ultra micros baeckea frutescen powder, with the ethanol solution 500kg that purity is 95%, the appearance of sealing is put into together
In device, heating water bath, the temperature of heating is 35 DEG C, after being incubated 6 hours, is being heated up to 60 DEG C simultaneously, stirring is peeled off 20 minutes；Its
In, the time of heating water bath and mode further refine, the active ingredient of baeckea frutescen powder can be caused it is further proposed that, that is, heat
Temperature is 35 degree and waited 1 hour, and 40 DEG C were then risen in 1 minute, after being incubated 4 hours, in 5 minutes, is heated up to 60 DEG C
Kept for 5 minutes, 65 DEG C were then heated in 1 minute and is kept for 10 minutes, one kind is kept stirring within this 20 minutes time.
(6) solution after being peeled off with the filter membrane of 500 mesh to stirring filters, after slag-liquid separation, the use of filter residue again
Alcohol solution dipping, filtering, the filtrate being filtrated to get twice merge；
(7) filtrate is put into container, and for heating water bath to 60 DEG C, baeckea frutescen essential oil is pooled to the surface of liquid, collects baeckea frutescen essence
Oil；
(8) remaining filtrate uses Ultra filtration membrane processing method, sets ultrafiltration granularity as 0.01 μm, will remove baeckea frutescen essence
Filtrate pressurization after oil, tiny residue is retained by the 0.01 μm of ultrafiltration of low pressure macropore and obtains low pressure macropore permeate；
(9) by low pressure macropore permeate, the ultrafiltration through membranes through 0.00l μm of high pressure aperture retain again, separate high pressure aperture is saturating
Cross the trapped fluid of liquid and high pressure aperture；
(10) by high pressure aperture permeate, permeate and adsorb through silica gel column chromatography vacuum state, obtain eluent, then will elution
Liquid merges with the trapped fluid of high pressure aperture, obtains extract solution；
(11) extract solution is concentrated, amalgamation liquid concentration extracts concentrated essence liquid until baeckea frutescen.
After this method crushes baeckea frutescen branch, first digested, then extract essential oil again, finally obtain the liquid that skims the cream off milk,
Fully the active principle in baeckea frutescen can be extracted.
Embodiment 8
A kind of natural plant essence liquid, by following material by weight：10 parts of deionized water, baeckea frutescen extraction are dense
16.7 parts of contracting Essence, 8 parts of birch essential oil, 1,3- 8 parts of dihydroxy butane, 6 parts of Nexbase 2004,4 parts of cyclomethicone are sweet
8.8 parts of oil, 4 parts of polyoxyethylene carboxylate, 3.2 parts of cocoyl glucoside, 1.6 parts of isopropyl hexadecanoate, Sweet Almond Oil 2.2
Part, 1.5 parts of median chain triglyceride oil, 0.5 part of isomery dodecane, 0.2 part of lauryl sodium sulfate, 1 part of lauryl alcohol, oleic acid first
0.2 part of ester, 0.2 part of Glycerin, mixed triester with caprylic acid capric acid, 0.15 part of eugenol, -0.4 part of Phenoxyethanol, 0.1 part of palmityl alcohol.
Its preparation method of the natural plant essence liquid, comprises the following steps：
(1) part deionization is taken, 1,3- dihydroxy butane, Nexbase 2004, cyclomethicone, cocounut oil are taken according to formula
Base glucoside, lauryl sodium sulfate, lauryl alcohol, eugenol, Phenoxyethanol, palmityl alcohol are scattered in deionized water, fully
It is stirred to have obtained basic mixed liquor；
(2) by polyoxyethylene carboxylate, isomery dodecane, isopropyl hexadecanoate, median chain triglyceride oil, oleic acid first
After ester weighs according to formula, it is added in above-mentioned mixed liquor, and carries out heating water bath；
(3) birch essential oil, Sweet Almond Oil, be mixed to get mixed oil liquid；
(5) glycerine, Glycerin, mixed triester with caprylic acid capric acid and remaining deionized water mixing, and carry out heating water bath obtain glycerine mixing it is molten
Liquid；
(6) mixed oil liquid is added drop-wise in glycerine mixed solution, and is stirred, and after stirring 10~30 minutes, is sequentially added
Basic mixed liquor and baeckea frutescen extraction concentrated essence liquid stirs, and produces natural plant essence liquid.
Birch essential oil wherein described in step (3), it is necessary to which being handled by following steps to use：CHAGA is crushed to
50 mesh, dry to water content and be less than 0.5%, then add the birch essential oil of 5 times of parts by weight, it is Celsius to be heated to 55 in 10 minutes
Degree, kept for 15 minutes, after being cooled to room temperature；Before heating, the weak solution (25~50mg/L) of hydroquinones is added, is specially
The 2% of birch essential oil total weight parts.
Embodiment 9
Such as the step of embodiment 8, the birch essential oil wherein described in step (3), it is necessary to which being handled by following steps can just make
With：CHAGA is crushed to 50 mesh, dries to water content and is less than 0.5%, then adds the birch essential oil of 5 times of parts by weight, heating
Kept for 3 minutes to 35 degrees Celsius, temperature is brought up into 40 degrees Celsius in 2 minutes is kept for 5 minutes, then by temperature in 2 minutes
Degree brings up to 47 degrees Celsius and kept for 5 minutes, and temperature then is brought up into 55 degrees Celsius in 2 minutes and kept for 1 minute, is kept altogether
Heat time is 20 minutes.Such mode has two benefits, and first so that birch essential oil is done business the extraction of composition for CHAGA
It is negated often complete；Second so that the oxidized probability of essential oil substantially reduces, and it is almost less than pH value 7.1 that can reach acidity, is added
The addition of the weak solution of upper hydroquinones, it can keep neutral, effect is very good.
Embodiment 10
Such as the step of embodiment 8, the birch essential oil wherein described in step (3), it is necessary to which being handled by following steps can just make
With：CHAGA is crushed to 50 mesh, dries to water content and is less than 0.5%, then adds the birch essential oil of 10 times of parts by weight, heating
Kept for 3 minutes to 35 degrees Celsius, temperature is brought up into 40 degrees Celsius in 2 minutes is kept for 5 minutes, then by temperature in 2 minutes
Degree brings up to 47 degrees Celsius and kept for 5 minutes, and temperature then is brought up into 55 degrees Celsius in 2 minutes and kept for 5 minutes, is kept altogether
Heat time is 10-25 minutes.
Effect detection
Illustrate the effect of product of the present invention by normal individual trial experiment：From the product obtained by embodiment.
Subjects select：Each half of men and women, 29-67 year every ten years old be an age bracket, be divided into four age brackets, Mei Genian
Each men and women of age section one, health, no skin disease and allergies.
Experiment number：200 people, every one group of 25 people, approached and sex identical crowd for age bracket.
Evaluation index：Canthus, under-eye skin elasticity, hydrauture, transdermal dehydration, wrinkle, pore, skin smoothness.
Test zone：Face, including canthus, now, cheek region.
Test period：Using preceding and using after 19 days.
Skin elasticity is tested：Skin elasticity is also to judge one of important symbol of skin aging, and test position is selected in eye.
Because eye part skin is most thin, without sebum secretion, and eye motion is frequent, more facial other easy agings in position, therefore tests
Now.Because canthus also easily produces wrinkle, canthus is also main detection position.Using MPA580 elasticity testers, at canthus
With a constant negative pressure is applied at under-eye skin, by test skin reply deformation size investigate use cosmetics after skin elasticity
Change, evaluate the senile-resistant efficacies of cosmetics.
The measure index of elasticity is R2, R2=(e (a)-e (a+b)/e (a)：When i.e. without negative pressure the springback capacity of skin and have it is negative
The ratio between maximum tension amount during pressure, ratio illustrate that skin elasticity is better closer to 1.Visible, the skin by front and rear test comparison
Elasticity all has significantly improvement.
The skin elasticity of table 1 tests table
Moisture measurement：By can not only be directly acquainted with epiderm skin cuticula moisture content to the measure of moisture of skin
Situation, the degree of skin aging can also be reflected indirectly.Moisture measurement is selected in the trigonum of decree line, investigates pressure object and uses
The change of hydrauture before and after product of the present invention, evaluate cosmetics anti-aging the effect of.It is that skin is relatively dried that hydrauture, which is less than 50,
50-60 is drying, abundant for moisture more than 60.Visible by front and rear test comparison, skin is aqueous all to have significantly improvement,
Major part can reach the sufficient degree of moisture.
The skin elasticity of table 2 tests table
Wrinkle ready visual contrast：The whole cheek chosen now to canthus is analyzed area, investigates experimenter and uses the present invention
The visual sense organ of wrinkle before and after product, evaluate the senile-resistant efficacy of cosmetics.Elimination by estimating visible wrinkle is effective.
The wrinkle of skin of table 3 estimates table
Skin smoothness：By determining the change using regular period skin smoothness after product of the present invention, and use
Front and rear facial smoothness contrast, senile-resistant efficacy that is directly perceived, quantitatively evaluating cosmetics.Smoothness evaluation is by calculating epidermis
Peak dot/valley point realize that peak dot/valley point ratio is more smooth closer to 1 explanation skin.Visible, the skin by front and rear test comparison
Skin smoothness, which all has, significantly to be improved.
The skin smoothness of table 4 tests table
By generality normal individual trial, the effect for the eye mask that the experiment explanation present invention passes through：Selected from 25-65 year crowd
Each 150 of the masculinity and femininity of health, 300 people altogether, the experiment product of product of the present invention is generally sent, by probation
The feedback capture of person is as follows：
As can be seen here, product of the invention is tried out and experimentally achieves extraordinary effect on a large scale in men and women, to face
The total effective rate of skin reaches 96.7%.
Claims (4)
1. a kind of its preparation method of natural plant essence liquid, it is characterised in that preparation method comprises the following steps：
(1) part deionization (amounts of most half, preferably shorter than half) is taken, 1,3- dihydroxy butane, hydrogenation are taken according to formula
Poly decene, cyclomethicone, cocoyl glucoside, lauryl sodium sulfate, lauryl alcohol, eugenol, Phenoxyethanol, palm
Alcohol is scattered in deionized water, is thoroughly mixed to have obtained basic mixed liquor；
(2) polyoxyethylene carboxylate, isomery dodecane, isopropyl hexadecanoate, median chain triglyceride oil, methyl oleate are pressed
After being weighed according to formula, it is added in above-mentioned mixed liquor, and carries out heating water bath；
(3) birch essential oil, Sweet Almond Oil, be mixed to get mixed oil liquid；
(5) glycerine, Glycerin, mixed triester with caprylic acid capric acid and the mixing of remaining deionized water, and carry out heating water bath and obtain glycerine mixed solution；
(6) mixed oil liquid is added drop-wise in glycerine mixed solution, and is stirred, and after stirring 10~30 minutes, sequentially adds basis
Mixed liquor and baeckea frutescen extraction concentrated essence liquid stir, and produce natural plant essence liquid；
Wherein, 10 parts of deionized water, baeckea frutescen extraction concentrated essence liquid 15-19 parts, birch essential oil 6-9.7 parts, 1,3- dihydroxy fourth
Alkane 5-8 parts, Nexbase 2004 4.5-7.8 parts, cyclomethicone 4-7.5 parts, glycerine 6.5-8.8 parts, aliphatic acid polyethenoxy
Ester 2.3-4.3 parts, cocoyl glucoside 1.6-3.2 parts, isopropyl hexadecanoate 1.4-2.1 parts, Sweet Almond Oil 1.3-2.2 parts,
Median chain triglyceride oil 1.5-2.8 parts, isomery dodecane 0.2-0.5 parts, lauryl sodium sulfate 0.2-0.4 parts, lauryl alcohol
0.7-1.3 parts, methyl oleate 0.1-0.3 parts, Glycerin, mixed triester with caprylic acid capric acid 0.1-0.3 parts, eugenol 0.15-0.25 parts, Phenoxyethanol
0.1-0.4 parts, palmityl alcohol 0.1-0.4 parts.
2. its preparation method of natural plant essence liquid as claimed in claim 1, it is characterised in that wherein described baeckea frutescen extraction is dense
The preparation method of contracting Essence includes procedure below：
(1) the debris soil on baeckea frutescen branch is cleaned out, retains leaf, and cleaned up with clear water, dried, be then placed in
Cleaned and sterilized again in hydrogen peroxide, the mass concentration of hydrogen peroxide is 3%；
(2) the baeckea frutescen branch after sterilization is taken out after draining away the water, moisture content is dried to below 5%, then by the tree of drying
Branch crushes, and the grain diameter after crushing is not more than 1mm；
(3) the baeckea frutescen particle after crushing, to 300 mesh, obtains ultra micro baeckea frutescen powder using ultramicro grinding；
(4) water is added, the quality of water is ultra micro baeckea frutescen powder times, and regulation pH adds cellulase and digested, protected 4.5~6.5
Warm 26-31 DEG C；
(5) according to every 100kg ultra micros baeckea frutescen powder, with the ethanol solution 500kg that purity is 95%, the container of sealing is put into together
Interior, heating water bath, the temperature of heating is 35-40 DEG C, after being incubated 6-8 hours, is being heated up to 60-65 DEG C simultaneously, stirring peels off 20
Minute；
(6) solution after being peeled off with the filter membranes of 500 mesh to stirring filters, after slag-liquid separation, filter residue again use ethanol
Solution soaks, and filtering, the filtrate being filtrated to get twice merges；
(7) filtrate is put into container, and for heating water bath to 50-60 DEG C, baeckea frutescen essential oil is pooled to the surface of liquid, collects baeckea frutescen essence
Oil；
(8) remaining filtrate uses Ultra filtration membrane processing method, sets ultrafiltration granularity as 0.01 μm, after baeckea frutescen essential oil is removed
Filtrate pressurization, tiny residue is retained by the 0.01 μm of ultrafiltration of low pressure macropore and obtains low pressure macropore permeate；
(9) by low pressure macropore permeate, the ultrafiltration through membranes through 0.00l μm of high pressure aperture retain again, separate to obtain high pressure aperture permeate
With the trapped fluid of high pressure aperture；
(10) extract solution is concentrated, amalgamation liquid concentration extracts concentrated essence liquid until baeckea frutescen.
3. its preparation method of natural plant essence liquid as claimed in claim 3, it is characterised in that
Between step (9) and step (10), preferably it can also increase following steps：By high pressure aperture permeate, through silica gel
The infiltration absorption of column chromatography vacuum state, obtains eluent, then merges eluent with the trapped fluid of high pressure aperture, extracted
Liquid.
4. a kind of Essence obtained using such as claim 2-4 methods prepares the preparation method of eye mask substrate liquid, its feature exists
In：The water-soluble collagen of convention amount is added in Essence.
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