CN107541860A - The preparation method and applications of bacteria cellulose and lignin composite cellulosic membrane - Google Patents
The preparation method and applications of bacteria cellulose and lignin composite cellulosic membrane Download PDFInfo
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- CN107541860A CN107541860A CN201710834139.XA CN201710834139A CN107541860A CN 107541860 A CN107541860 A CN 107541860A CN 201710834139 A CN201710834139 A CN 201710834139A CN 107541860 A CN107541860 A CN 107541860A
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- facial mask
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- bacteria cellulose
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Abstract
The invention discloses the preparation method and applications of a kind of bacteria cellulose and lignin fibre composite cellulosic membrane；The present invention had both possessed the advantages of bacteria cellulose fibre uniqueness by bacteria cellulose made of spun lacing skill of handling needles high-pressure injection and lignin composite cellulosic membrane：Purity, crystallinity are high, mechanical strength is high, good biocompatibility, it is permeable, permeability is excellent, water retainability is good, but also with the chemical property of the stabilization after high-temperature process of lignin fibre, and nontoxic, tasteless, pollution-free, "dead" fine quality, belong to green product, and it is strong with good toughness, dispersiveness and superpower water absorbing capacity, there is very outstanding thickening cracking resistance；And composite fibre facial mask made of facial mask basic unit is made as with the composite cellulosic membrane, thin layer is frivolous, moisturizing permeability more preferably, skin-friendly and hold liquid properties and be obtained for further raising；The present invention is adapted to various composite fibre facial masks to use.
Description
Technical field
The present invention relates to a kind of production and processing technical field of compound cellulose composite fibre material, particularly a kind of bacterium
The preparation method and applications of cellulose and lignin composite cellulosic membrane.
Background technology
Mask product has many kinds on the market now, and the facial mask export of various functions effect is not poor, but the fine or not area of facial mask
It is point main to be still embodied in whether its function effect fully achieve, and function effect of mask product be mainly manifested in it is following
Several aspects：Whether facial mask basic unit has suitable tensile strength and toughness first, can cause overall facial mask it is not only frivolous, it is ventilative but also
It is durable；Secondly facial mask basic unit whether have it is relatively large hold water, can guarantee that the moisturizing degree and usage time of overall mask product
Long enough, so as to which the function of mask product be better achieved；Be finally facial mask basic unit skin-friendly whether relatively preferably, Ke Yibao
Facial mask function stoste of the card when in use in mask product can be absorbed by the skin and under the guiding of facial mask base layer fiber well
Percdation enters in skin, reaches the maximum effect of facial mask function stoste.Therefore, the material of facial mask basic unit is comparatively just very heavy
Want.
And bacteria cellulose fibre refers to the cellulose by Microbe synthesis, compared with the cellulose of plant origin, bacterium
Cellulose has the advantages of many unique：Purity, crystallinity are high, and mechanical strength is high, good biocompatibility, permeable, permeability
It is excellent, guarantor's fluidity is good etc..The advantages of these are unique just because of bacteria cellulose, make it in food, papermaking, weaving and medical treatment
Etc. it is of great interest.In recent years, even more due to the good biocompatibility of bacteria cellulose, protect fluidity, permeable
Gas permeability and be widely used in mask product as face mask substrate material.
In addition, lignin fibre, which is natural timber, passes through the organic fiber that chemical treatment obtains, outward appearance is flocculence, in white
Color or canescence.By screening, dividing, high-temperature process, bleaching, chemical treatment, neutralize, be sieved into different length and fineness degree
Fiber is chemically non-at typical condition to adapt to the needs of different application material because treatment temperature is up to more than 250 DEG C
Often stable material, is not in general solvent, acid, caustic corrosion, has nontoxic, tasteless, pollution-free, "dead" excellent product
Matter, environment is not influenceed, it is harmless, belong to green product, this is not available for other minerals fibers.Fiber is micro-
It is with sigmoid to see structure, and rough, porous, infall is flat, there is good toughness, dispersiveness and chemistry
Stability, water absorbing capacity is strong, there is very outstanding thickening cracking resistance.
The content of the invention
For overcome the deficiencies in the prior art, the present invention provides the preparation of a kind of bacteria cellulose and lignin composite fibre
The application of method and its composite fibre in mask product.
The technical solution adopted for the present invention to solve the technical problems is：Bacteria cellulose and lignin composite cellulosic membrane
Preparation method, bacteria cellulose fibre and lignin fibre are sufficiently mixed composite fibre is made, it is high by using the spun lacing skill of handling needles
Pressure injection composite fibre, is made bacteria cellulose and lignin composite cellulosic membrane, wherein：
The bacteria cellulose fibre is by the use of acetobacter xylinum fermentation liquid as nutrient solution, by static breeding method, through standing
When fermenting 60 to 72 hours, the bacteria cellulose mycelia cultivated in nutrient solution is process；
The lignin fibre be take the natural timber after screening, dividing, be placed on 230 to 280 DEG C at a temperature of carry out it is high
Temperature processing, manufactured flocculence lignin fibre is process after bleaching, neutralisation treatment again.
Bacteria cellulose and lignin composite fibre facial mask, the composite fibre facial mask is with bacteria cellulose and lignin
Composite cellulosic membrane is as facial mask basic unit, and complex superposition has facial mask function stoste permeable formation outside facial mask basic unit, and facial mask function stoste is oozed
Penetrated into the middle part of permeable layers in facial mask basic unit, the outside of facial mask function stoste permeable formation is adsorbed and be wrapped in the appearance of facial mask basic unit
Face, both collectively form composite fibre facial mask at mutual complex superposition.
The beneficial effects of the invention are as follows：Bacteria cellulose and lignin composite fibre made by the present invention, due to both having
The advantages of for bacteria cellulose fibre uniqueness：Purity, crystallinity are high, and mechanical strength is high, and good biocompatibility is permeable, ventilative
Excellent performance, water retainability is good, but also with the chemical property of the stabilization after high-temperature process of lignin fibre, Yi Jiwu
Malicious, tasteless, pollution-free, "dead" fine quality, belongs to green product, and with good toughness, dispersiveness and
Superpower water absorbing capacity is strong, there is very outstanding thickening cracking resistance；And because bacteria cellulose fibre has superfinishing fine-structure mesh
Shape structure, and lignin fibre easily forms a kind of three-D space structure between other fibrous materials, works as bacteria cellulose fibre
When being mixed with lignin fibre, form that a kind of network structure is more fine and hair by being thoroughly mixed rear can
The complex fiber material reached；And answered with the composite fibre by bacteria cellulose made of spun lacing skill of handling needles high-pressure injection with lignin
Facial mask basic unit made of condensating fiber film, because bacteria cellulose fibre has hyperfine reticular fiber structure and superpower specific retention
Power, water imbibition bacteria cellulose carrier can be used as, the facial mask function stoste of surrounding is adsorbed, reach emulsification and thickening facial mask
The effect of function stoste, the thickener that may replace traditional chemical synthesis use in facial mask production as thickener, and overall
Facial mask thin layer is frivolous, moisturizing permeability more preferably, skin-friendly and hold and fluid be obtained for further raising.
Brief description of the drawings
The present invention is further described with reference to the accompanying drawings and examples：
Fig. 1 is facial mask structure schematic diagram of the present invention；
Fig. 2 be in Fig. 1 A-A to structure cut-away enlarged view；
Fig. 3 is Fig. 2 structure expanded schematic diagram.
Wherein in figure：1. composite cellulosic membrane facial mask；2. composite cellulosic membrane facial mask basic unit；3. facial mask function stoste permeable formation；
21. bacteria cellulose fibre divides film layer；22. lignin fibre divides film layer.
Embodiment
The preparation method of bacteria cellulose and lignin composite cellulosic membrane, bacteria cellulose fibre and lignin fibre are filled
Divide and be mixed and made into composite fibre, by using spun lacing skill of handling needles high-pressure injection composite fibre, bacteria cellulose is made and is answered with lignin
Condensating fiber film, wherein：
The bacteria cellulose fibre is to take acetobacter xylinum fermentation liquid as nutrient solution, by static breeding method, through quiet
When putting fermentation 60 to 72 hours, the bacteria cellulose mycelia cultivated in nutrient solution is process；
The lignin fibre be take the natural timber after screening, dividing, be placed on 230 to 280 DEG C at a temperature of carry out it is high
Temperature processing, manufactured flocculence lignin fibre is process after bleaching, neutralisation treatment again.
Bacteria cellulose and lignin composite fibre facial mask, the composite fibre facial mask is with bacteria cellulose and lignin
Composite cellulosic membrane is as facial mask basic unit, and complex superposition has facial mask function stoste permeable formation outside facial mask basic unit, and facial mask function stoste is oozed
Penetrated into the middle part of permeable layers in facial mask basic unit, the outside of facial mask function stoste permeable formation is adsorbed and be wrapped in the appearance of facial mask basic unit
Face, both collectively form composite fibre facial mask at mutual complex superposition.
Reference picture 1, Fig. 2, Fig. 3, bacteria cellulose and lignin composite cellulosic membrane made by the present invention, had both possessed thin
The advantages of fungin fiber uniqueness：Purity, crystallinity are high, and mechanical strength is high, good biocompatibility, permeable, permeability is excellent
Different, water retainability is good, but also with the chemical property of the stabilization after high-temperature process of lignin fibre, and nontoxic, tasteless,
Pollution-free, "dead" fine quality, belong to green product, and there is good toughness, dispersiveness and superpower suction
Outlet capacity is strong, there is very outstanding thickening cracking resistance；And because bacteria cellulose fibre has hyperfine network structure, and
Lignin fibre easily forms a kind of three-D space structure between other fibrous materials, when bacteria cellulose fibre and lignin are fine
When dimension mixes, a kind of more fine and flourishing compound fibre of network structure is formed by being thoroughly mixed rear can
Tie up material；And bacteria cellulose made of spun lacing skill of handling needles high-pressure injection and lignin composite cellulosic membrane system are passed through with the composite fibre
Into facial mask basic unit, can conduct because bacteria cellulose fibre has hyperfine reticular fiber structure and superpower moisture holding capacity
Water imbibition bacteria cellulose carrier, the facial mask function stoste of surrounding is adsorbed, reach emulsification and thickening facial mask function stoste
Effect, the thickener that may replace traditional chemical synthesis uses as thickener in facial mask production, and overall facial mask thin layer
Frivolous, moisturizing permeability more preferably, skin-friendly and hold and fluid be obtained for further raising.
Reference picture 1, Fig. 2, Fig. 3, composite fibre facial mask of the present invention are with bacteria cellulose and lignin composite fibre
Film is as facial mask basic unit, and bacteria cellulose fibre of the present invention is to take acetobacter xylinum fermentation liquid as nutrient solution,
By static breeding method, during through standing for fermentation 60 to 72 hours, turned out in nutrient solution substantial amounts of just into silk but last film forming
The ripe bacteria cellulose mycelia in end through made of processing, bacteria cellulose filament now has and bacteria cellulose
The exclusive hyperfine reticular fiber structure of fiber, its unique nanometer tridimensional network make it possess excellent physicochemical characteristic,
And surface has substantial amounts of hydroxyl hydrogen bond, the hydrophobic main chain of bacteria cellulose filament surfaces can be with the moisture in surrounding liquid environment
Son improves the fluid volume of polymer in itself, reduces the freedom of organic or inorganic particle in liquid environment by hydrogen bond association
Activity space, it is stained with denseness so as to improve the system of liquid environment；The present invention is exactly this characteristic using bacteria cellulose filament,
By bacteria cellulose filament fully adsorb and be wrapped in by bacteria cellulose made of spun lacing skill of handling needles high-pressure injection with it is wooden
The outer surface of facial mask basic unit made of plain composite cellulosic membrane, form a bacteria cellulose filament adsorption layer, the bacteria cellulose
Filament adsorption layer can strengthen the structural stability of composite cellulosic membrane, and and can is entered as thickener to facial mask function stoste permeable formation
Row is adsorbed and thickened so that facial mask function stoste permeable formation can well adsorb and be wrapped in the appearance of composite facial mask basic unit
Face, complex superposition has facial mask function stoste permeable formation outside facial mask basic unit, and facial mask is penetrated into the middle part of facial mask function stoste permeable formation
In basic unit, the outside of facial mask function stoste permeable formation is adsorbed and is wrapped in the outer surface of facial mask basic unit, both mutual complex superpositions
Composite fibre facial mask is collectively formed, the facial mask has the denominator of bacteria cellulose fibre and lignin fibre, and film layer is frivolous,
Skin-friendly, gas permeability and performance of keeping humidity are improved, and composite facial mask basic unit may additionally facilitate absorption of the skin to facial mask function stoste,
The beauty work(of facial mask function stoste in percdation skin, can be given full play under the common guiding of bacteria cellulose and lignin
Effect.
In a word, embodiment of the invention only describes one of which bacteria cellulose and lignin composite cellulosic membrane
Preparation method and applications Technological improvement plan, the Technological improvement plan of any other equivalent substitute is all in its protection domain
Within.
Claims (2)
1. the preparation method of bacteria cellulose and lignin composite cellulosic membrane, it is characterised in that by bacteria cellulose fibre and wooden
Cellulose fiber, which is sufficiently mixed, is made composite fibre, by spun lacing skill of handling needles high-pressure injection composite fibre, be made bacteria cellulose with it is wooden
Plain composite cellulosic membrane, wherein：
The bacteria cellulose fibre is by the use of acetobacter xylinum fermentation liquid as nutrient solution, by static breeding method, through standing
When fermenting 60 to 72 hours, the bacteria cellulose mycelia cultivated in nutrient solution is process；
The lignin fibre be take the natural timber after screening, dividing, be placed on 230 to 280 DEG C at a temperature of carry out it is high
Temperature processing, manufactured flocculence lignin fibre is process after bleaching, neutralisation treatment again.
2. bacteria cellulose and lignin composite fibre facial mask, it is characterised in that the composite fibre facial mask is with bacteria cellulose
With lignin composite cellulosic membrane as facial mask basic unit, complex superposition has facial mask function stoste permeable formation, facial mask work(outside facial mask basic unit
It can be penetrated into the middle part of stoste permeable formation in facial mask basic unit, the outside of facial mask function stoste permeable formation is adsorbed and be wrapped in facial mask base
The outer surface of layer, both collectively form composite fibre facial mask at mutual complex superposition.
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| CN201710834139.XA CN107541860A (en) | 2017-09-15 | 2017-09-15 | The preparation method and applications of bacteria cellulose and lignin composite cellulosic membrane |
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| CN201710834139.XA CN107541860A (en) | 2017-09-15 | 2017-09-15 | The preparation method and applications of bacteria cellulose and lignin composite cellulosic membrane |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110101595A (en) * | 2019-06-20 | 2019-08-09 | 福清市火麒麟食用菌技术开发有限公司 | A kind of preparation method of silk ball fungin facial mask |
| CN111549386A (en) * | 2019-02-12 | 2020-08-18 | 大江生医股份有限公司 | Vegetable and berry fruit fermentation product rayon fiber mask for moisturizing and resisting aging |
| CN113913971A (en) * | 2020-07-10 | 2022-01-11 | 南京理工大学 | Method for in-situ growth of bacterial cellulose in wood fiber |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103481600A (en) * | 2012-06-12 | 2014-01-01 | 钟春燕 | Preparation method of bacterial cellulose composite membrane material |
| CN104120507A (en) * | 2014-07-22 | 2014-10-29 | 南京工业大学 | Preparation method of lignin-based electrostatic blended materials |
| CN104800089A (en) * | 2014-01-29 | 2015-07-29 | 娇芃生技股份有限公司 | Biological fiber composite dressing |
| CN104963094A (en) * | 2015-07-08 | 2015-10-07 | 江南大学 | Non-woven cloth prepared by composite fibers by means of bacterial cellulose produced by microorganisms and preparation method thereof |
-
2017
- 2017-09-15 CN CN201710834139.XA patent/CN107541860A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103481600A (en) * | 2012-06-12 | 2014-01-01 | 钟春燕 | Preparation method of bacterial cellulose composite membrane material |
| CN104800089A (en) * | 2014-01-29 | 2015-07-29 | 娇芃生技股份有限公司 | Biological fiber composite dressing |
| CN104120507A (en) * | 2014-07-22 | 2014-10-29 | 南京工业大学 | Preparation method of lignin-based electrostatic blended materials |
| CN104963094A (en) * | 2015-07-08 | 2015-10-07 | 江南大学 | Non-woven cloth prepared by composite fibers by means of bacterial cellulose produced by microorganisms and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 郭明辉等: "壳聚糖木质素复合材料研究进展", 《世界林业研究》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111549386A (en) * | 2019-02-12 | 2020-08-18 | 大江生医股份有限公司 | Vegetable and berry fruit fermentation product rayon fiber mask for moisturizing and resisting aging |
| CN110101595A (en) * | 2019-06-20 | 2019-08-09 | 福清市火麒麟食用菌技术开发有限公司 | A kind of preparation method of silk ball fungin facial mask |
| CN113913971A (en) * | 2020-07-10 | 2022-01-11 | 南京理工大学 | Method for in-situ growth of bacterial cellulose in wood fiber |
| CN113913971B (en) * | 2020-07-10 | 2024-03-12 | 南京理工大学 | Method for in-situ growth of bacterial cellulose in wood fiber |
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