CN107517988A - A kind of complex composition containing gold alloy hydride and benziothiazolinone - Google Patents

A kind of complex composition containing gold alloy hydride and benziothiazolinone Download PDF

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Publication number
CN107517988A
CN107517988A CN201710996530.XA CN201710996530A CN107517988A CN 107517988 A CN107517988 A CN 107517988A CN 201710996530 A CN201710996530 A CN 201710996530A CN 107517988 A CN107517988 A CN 107517988A
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benziothiazolinone
gold alloy
alloy hydride
composition containing
complex composition
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不公告发明人
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Huizhou City Without Age Health Health Technology Co Ltd
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Huizhou City Without Age Health Health Technology Co Ltd
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a kind of complex composition containing gold alloy hydride and benziothiazolinone, effective active composition is made up of gold alloy hydride and benziothiazolinone, and the weight ratio of gold alloy hydride and benziothiazolinone is 30:1~1:1.The disease excellents such as built composition for preventing and controlling cucumber bacterial angular leaf spot of the present invention, bacterial wilt of tomato, lasting period length, to Crop securify.There is significant synergistic function after gold alloy hydride and benziothiazolinone compounding, Pesticide use amount can be reduced, use cost is reduced, mitigate the pollution to environment, delay the drug-fast generation of pathogen, increase the Pesticide use life-span.

Description

A kind of complex composition containing gold alloy hydride and benziothiazolinone
Technical field
The present invention relates to pesticide complex composition and its application field, specifically using gold alloy hydride and benziothiazolinone to have The binary complex of active component compounding is imitated, is mainly used in the preventing and treating of disease on crops.
Background technology
Gold alloy hydride (aureonucleomycin) is that Shanghai pesticide research is developed, and is passed through by the mutation of streptomyces aureus Suzhou A kind of microbial source fungicide that cultivation and fermentation forms, there is the excellent effect that prevents to disease caused by various bacteria, and it is right People and animals and Environmental security.
Benziothiazolinone (benziothiazolinone) belongs to isothiazole heterocyclic compound, is that a kind of efficient, less toxic, broad spectrum activity kills Microbial inoculum, its mechanism of action are：Reacted with bacterium, the anion binding of the cell membrane surface of mould or with sulfydryl, destroy protein With the synthesis system of cell membrane, so as to suppress bacterium, mould breeding, pathogen cell metabolism is disturbed, makes its physiologic derangement, Ultimately result in pathogen death.The compound is to the rot on crops, canker, anthracnose, scab, leaf spot, frost The diseases such as mildew have good prevention effect, and fool proof to crops.
The long-time continuous use of agricultural chemicals single variety, resistance risk and dosage increase risk are easily produced, and then increased Cost and carrying capacity of environment, and the compounded combination with notable synergistic function is gone out by the compound screening of different pesticide species Thing, Pesticide use amount can not only be reduced, use cost is reduced, reduces resistance risk, moreover it is possible to reduces potential environmental risk, increases The Pesticide use life-span.
The present inventor is during further investigation gold alloy hydride and benziothiazolinone compounded formula, surprisingly golden core Mycin and benziothiazolinone are compounded, to the multiple diseases on crops in the range of certain compound proportion, especially to cucumber Bacterial angular leaf spot, bacterial wilt of tomato have significant synergistic function, after further study, complete the present invention.
The content of the invention
It is an object of the invention to provide a kind of component is reasonable, obvious synergy, bactericidal effect are outstanding, the lasting period Length, drug cost is low, pathogen can be delayed to develop immunity to drugs, and to the pesticide complex composition of Crop securify.
Another object of the present invention is to provide a kind of complex composition preparation formulation containing gold alloy hydride and benziothiazolinone.
It is withered in preventing and treating cucumber bacterial angular leaf spot, tomato green grass or young crops it is still another object of the present invention to provide above-mentioned complex composition Purposes in disease.
Technical scheme：To achieve the above object, the present invention provides a kind of answering containing gold alloy hydride and benziothiazolinone With composition, effective active composition is made up of gold alloy hydride and benziothiazolinone, and the weight ratio of gold alloy hydride and benziothiazolinone is 30:1~ 1:1, the preferably weight ratio of gold alloy hydride and benziothiazolinone is 20:1~1:1, the weight ratio of most preferably gold alloy hydride and benziothiazolinone is 5:1。
In complex composition of the present invention, the gross weight percentage composition of gold alloy hydride and benziothiazolinone is 1%~85%, preferably golden Caryomycin and the gross weight percentage composition of benziothiazolinone are 5%~70%.
Complex composition of the present invention can be prepared into any formulation used in suitable agricultural production, and relatively good formulation has Suspending agent, wettable powder etc..
In various application forms prepared by complex composition of the present invention, in addition to effective active composition, in addition in agricultural chemicals Allow to use and the various auxiliary elements of acceptable.
Described auxiliary element include but is not limited to wetting agent, dispersant, antifreezing agent, thickener, defoamer, preservative and Filler etc., all it is to commonly use in pesticidal preparations or allow the composition used, is not particularly limited, specific composition and dosage are according to formula It is required that determined by testing.
The production technology of the various application forms of complex composition belongs to existing known technology, will not be repeated here.
Compared with prior art, the advantage of the invention is that：
1st, gold alloy hydride and benziothiazolinone compounding have significant synergistic function, are used alone and significantly improve than single dose To the prevention effect of disease on crops.
2nd, gold alloy hydride and benziothiazolinone two kinds of active components compounding, reduce Pesticide use amount, reduce use cost, subtract The light pollution to environment.
3rd, gold alloy hydride and benziothiazolinone two kinds of active components compounding, the mechanism of action is different, action site increase, delays Pathogen drug-fast generation, add the service life of agricultural chemicals.
Embodiment
Essence for a better understanding of the present invention, present disclosure is described further with reference to embodiment, But limitation of the present invention can not be considered as, it is as described below to be only used for explaining the present invention, for without departing from spirit of the invention and principle Modification, replacement or the improvement made, belong to the scope of protection of present invention.
Embodiment one
Following material is weight percentage：Gold alloy hydride 25%, benziothiazolinone 5%, polyoxyethylene polyoxypropylene base ether Block copolymer 7%, polyether-modified polysiloxane 5%, carboxyethyl cellulose 2%, potassium sorbate 0.5%, silicone oil 0.3%th, methyl propylene diglycol 2%, deionized water complements to 100%.Above-mentioned material is mixed in proportion, through high speed shear Be uniformly dispersed, in sand mill be sanded after, you can be made 30% gold alloy hydride benziothiazolinone suspending agent.
It is used to prevent and treat cucumber bacterial angular leaf spot using above-mentioned 30% gold alloy hydride benziothiazolinone suspending agent：30% gold medal core is mould Plain benziothiazolinone suspending agent carries out first time dispenser, 7d by 100g a.i./ha dosages in cucumber bacterial angular leaf spot early period of origination After carry out second of dispenser, 14d is 86.31% to the preventive effect of cucumber bacterial angular leaf spot after second of dispenser；25% gold medal core Mycin suspending agent carries out first time dispenser by 200g a.i./ha dosages in cucumber bacterial angular leaf spot early stage, is carried out after 7d Second of dispenser, 14d is 63.69% to the preventive effect of cucumber bacterial angular leaf spot after second of dispenser；5% benziothiazolinone suspending agent First time dispenser is carried out in cucumber bacterial angular leaf spot early stage by 30g a.i./ha dosages, second of dispenser is carried out after 7d, 14d is 61.78% to the preventive effect of cucumber bacterial angular leaf spot after second of dispenser.It can be seen that gold alloy hydride and benziothiazolinone binary Obvious synergy after compounding, lasting period length, the preventive effect of cucumber bacterial angular leaf spot is individually made significantly better than each single dose With, meanwhile, do not find to produce poisoning to cucumber after using 30% gold alloy hydride benziothiazolinone suspending agent during experiment.
Embodiment two
Following material is weight percentage：Gold alloy hydride 50%, benziothiazolinone 5%, alkylphenol-polyethenoxy base ether phosphorus Acid esters 10%, butanedioic acid sulfonate 8%, white carbon 5%, kaolin complements to 100%.Above-mentioned material is mixed in proportion, machine After tool crushing again after air-flow crushing is well mixed, you can 55% gold alloy hydride benziothiazolinone wettable powder is made.
Control of plant bacterial wilt is used for using above-mentioned 55% gold alloy hydride benziothiazolinone wettable powder：55% gold medal core is mould Plain benziothiazolinone wettable powder is by 150g a.i./ha dosages after bacterial wilt of tomato early period of origination progress first time dispenser, 7d Second of dispenser is carried out, 14d is 82.91% to the preventive effect of bacterial wilt of tomato after second of dispenser；50% gold alloy hydride is wettable Property pulvis carry out first time dispenser in bacterial wilt of tomato early stage by 200g a.i./ha dosages, applied for the second time after 7d Medicine, 14d is 58.38% to the preventive effect of bacterial wilt of tomato after second of dispenser；5% benziothiazolinone wettable powder presses 30g A.i./ha dosages carry out first time dispenser in bacterial wilt of tomato early stage, second of dispenser are carried out after 7d, in second of dispenser 14d is 67.74% to the preventive effect of bacterial wilt of tomato afterwards.It can be seen that synergistic function after gold alloy hydride and benziothiazolinone binary built Significantly, the lasting period is grown, and the preventive effect of bacterial wilt of tomato is used alone significantly better than each single dose, meanwhile, do not sent out during experiment Poisoning is produced to tomato after now using 55% gold alloy hydride benziothiazolinone wettable powder.
The gold alloy hydride of embodiment three and benziothiazolinone compounding are tried the Toxicity Determination of cucumber bacterial angular leaf spot pathogen Test
Test method：With reference to《Farm-chemical indoor determination test rule bactericide NY/T 1156.16-2008》, use is muddy Nephelometry.
Statistical analysis is carried out with DPS statistical analysis softwares, calculates the EC of each medicament50, and mixture is calculated according to the abundant methods of Sun Yun Co-toxicity coefficient (CTC values), co-toxicity coefficient (CTC) >=120 shows as synergistic effect；Co-toxicity coefficient (CTC)≤80 shows as short of money Anti- effect；80 ＜ co-toxicity coefficients (CTC) ＜ 120 show as summation action.
The gold alloy hydride of table 1 and benziothiazolinone compound the Toxicity Determination to cucumber bacterial angular leaf spot pathogen
Medicament title and proportioning (weight ratio) EC50(mg/L) ATI TTI CTC
Gold alloy hydride 3.17 100.00
Benziothiazolinone 1.78 178.09
Gold alloy hydride：Benziothiazolinone (30:1) 2.95 107.46 102.52 104.82
Gold alloy hydride：Benziothiazolinone (20:1) 2.36 134.32 103.72 129.50
Gold alloy hydride：Benziothiazolinone (15:1) 2.13 148.83 104.88 141.91
Gold alloy hydride：Benziothiazolinone (10:1) 1.89 167.72 107.10 156.60
Gold alloy hydride：Benziothiazolinone (7:1) 1.66 190.96 109.76 173.98
Gold alloy hydride：Benziothiazolinone (5:1) 1.54 205.84 113.02 182.13
Gold alloy hydride：Benziothiazolinone (3:1) 1.62 195.68 119.52 163.72
Gold alloy hydride：Benziothiazolinone (1:1) 1.69 187.57 139.05 134.89
As it can be seen from table 1 gold alloy hydride and benziothiazolinone are 20:1~1:It is malicious altogether when being compounded in the range of 1 (by weight) Coefficient (CTC) is all higher than 120, illustrates to show synergistic function to cucumber bacterial angular leaf spot pathogen；Gold alloy hydride and Benziothiazolinone is with 5:1 (by weight) compounding, synergistic function is the most notable, and co-toxicity coefficient (CTC) reaches maximum, is 182.13. It can be seen that gold alloy hydride and benziothiazolinone compounding have reasonability and feasibility.
Example IV gold alloy hydride and benziothiazolinone compounding are tested the Toxicity Determination of bacterial wilt of tomato pathogen
Test method：With reference to《Farm-chemical indoor determination test rule bactericide NY/T 1156.16-2008》, use is muddy Nephelometry.
Statistical analysis is carried out with DPS statistical analysis softwares, calculates the EC of each medicament50, and mixture is calculated according to the abundant methods of Sun Yun Co-toxicity coefficient (CTC values), co-toxicity coefficient (CTC) >=120 shows as synergistic effect；Co-toxicity coefficient (CTC)≤80 shows as short of money Anti- effect；80 ＜ co-toxicity coefficients (CTC) ＜ 120 show as summation action.
The gold alloy hydride of table 2 and benziothiazolinone compound the Toxicity Determination to bacterial wilt of tomato pathogen
Medicament title and proportioning (weight ratio) EC50(mg/L) ATI TTI CTC
Gold alloy hydride 3.64 100.00
Benziothiazolinone 1.96 185.71
Gold alloy hydride：Benziothiazolinone (30:1) 3.17 114.83 102.76 111.75
Gold alloy hydride：Benziothiazolinone (20:1) 2.51 145.02 104.08 139.34
Gold alloy hydride：Benziothiazolinone (15:1) 2.19 166.21 105.36 157.75
Gold alloy hydride：Benziothiazolinone (10:1) 1.96 185.71 107.79 172.29
Gold alloy hydride：Benziothiazolinone (7:1) 1.72 211.63 110.71 191.16
Gold alloy hydride：Benziothiazolinone (5:1) 1.56 233.33 114.29 204.16
Gold alloy hydride：Benziothiazolinone (3:1) 1.67 217.96 121.43 179.49
Gold alloy hydride：Benziothiazolinone (1:1) 1.79 203.35 142.86 142.34
From table 2 it can be seen that gold alloy hydride and benziothiazolinone are 20:1~1:It is malicious altogether when being compounded in the range of 1 (by weight) Coefficient (CTC) is all higher than 120, illustrates to show synergistic function to bacterial wilt of tomato pathogen；Gold alloy hydride and benziothiazolinone With 5:1 (by weight) compounding, synergistic function is the most notable, and co-toxicity coefficient (CTC) reaches maximum, is 204.16.It can be seen that gold Caryomycin and benziothiazolinone compounding have reasonability and feasibility.
Embodiment five
Following material is weight percentage：Gold alloy hydride 21%, benziothiazolinone 3%, polyoxyethylene polyoxypropylene base ether Block copolymer 7%, polyether-modified polysiloxane 5%, carboxyethyl cellulose 2%, potassium sorbate 0.5%, silicone oil 0.3%th, methyl propylene diglycol 2%, deionized water complements to 100%.Above-mentioned material is mixed in proportion, through high speed shear Be uniformly dispersed, in sand mill be sanded after, you can be made 24% gold alloy hydride benziothiazolinone suspending agent.
Embodiment six
Following material is weight percentage：Gold alloy hydride 9%, benziothiazolinone 3%, alkylphenol-polyethenoxy base ether phosphoric acid Ester 10%, butanedioic acid sulfonate 8%, white carbon 5%, kaolin complements to 100%.Above-mentioned material is mixed in proportion, machinery After crushing again after air-flow crushing is well mixed, you can 11% gold alloy hydride benziothiazolinone wettable powder is made.
In summary, a kind of complex composition containing gold alloy hydride and benziothiazolinone of the present invention, synergistic function Significantly, it is used alone compared to each single dose, preventive effect significantly improves, and can effectively prevent and treat cucumber bacterial angular leaf spot, bacterial wilt of tomato etc. Disease, lasting period length, to Crop securify, is worth the popularization and application in agricultural production.

Claims (8)

  1. A kind of 1. complex composition containing gold alloy hydride and benziothiazolinone, it is characterised in that：Effective active composition by gold alloy hydride and Benziothiazolinone forms, and the weight ratio of gold alloy hydride and benziothiazolinone is 30:1~1:1.
  2. A kind of 2. complex composition containing gold alloy hydride and benziothiazolinone according to claim 1, it is characterised in that：Golden core is mould Element and the weight ratio of benziothiazolinone are 20:1~1:1.
  3. A kind of 3. complex composition containing gold alloy hydride and benziothiazolinone according to claim 1, it is characterised in that：Golden core is mould Element and the weight ratio of benziothiazolinone are 5:1.
  4. A kind of 4. complex composition containing gold alloy hydride and benziothiazolinone according to claim 1, it is characterised in that：Compounding group Gold alloy hydride and the gross weight percentage composition of benziothiazolinone are 1%~85% in compound.
  5. A kind of 5. complex composition containing gold alloy hydride and benziothiazolinone according to claim 1, it is characterised in that：It is described multiple Formulation with composition is suspending agent, wettable powder.
  6. 6. a kind of complex composition containing gold alloy hydride and benziothiazolinone according to claim 5, it is characterised in that described multiple When suspending agent is made in formulation with composition, weight percentage is：Gold alloy hydride 25%, benziothiazolinone 5%, polyoxyethylene polyoxy Propenyl ether block copolymer 7%, polyether-modified polysiloxane 5%, carboxyethyl cellulose 2%, potassium sorbate 0.5%, Silicone oil 0.3%, methyl propylene diglycol 2%, deionized water complements to 100%.
  7. 7. a kind of complex composition containing gold alloy hydride and benziothiazolinone according to claim 5, it is characterised in that described multiple When wettable powder is made in formulation with composition, weight percentage is：Gold alloy hydride 50%, benziothiazolinone 5%, alkyl phenol gather Oxyethylene group ether phosphate 10%, butanedioic acid sulfonate 8%, white carbon 5%, kaolin complements to 100%.
  8. 8. a kind of complex composition containing gold alloy hydride and benziothiazolinone described in claim 1 is to prevent and treat the bacillary angle spot of cucumber Purposes in disease, bacterial wilt of tomato.
CN201710996530.XA 2017-10-24 2017-10-24 A kind of complex composition containing gold alloy hydride and benziothiazolinone Withdrawn CN107517988A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112075438A (en) * 2020-09-01 2020-12-15 陕西西大华特科技实业有限公司 Bactericidal composition containing benziothiazolinone and shenqinmycin and application thereof
CN114521566A (en) * 2022-02-21 2022-05-24 广西壮族自治区农业科学院 Synergistic composition for preventing and treating soft rot of taro

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN87100250A (en) * 1987-03-18 1988-10-05 上海市农药研究所 Preparation method of new antibiotic aureonucleomycin and agricultural bactericide
CN105340913A (en) * 2015-10-31 2016-02-24 海利尔药业集团股份有限公司 Sterilization composition containing benziothiazolinone and kasugamycin

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN87100250A (en) * 1987-03-18 1988-10-05 上海市农药研究所 Preparation method of new antibiotic aureonucleomycin and agricultural bactericide
CN105340913A (en) * 2015-10-31 2016-02-24 海利尔药业集团股份有限公司 Sterilization composition containing benziothiazolinone and kasugamycin

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112075438A (en) * 2020-09-01 2020-12-15 陕西西大华特科技实业有限公司 Bactericidal composition containing benziothiazolinone and shenqinmycin and application thereof
CN114521566A (en) * 2022-02-21 2022-05-24 广西壮族自治区农业科学院 Synergistic composition for preventing and treating soft rot of taro

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