CN107513328A - 一种透明膨胀型防火涂料及其制备方法 - Google Patents
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Abstract
本发明公开了一种透明膨胀型防火涂料及其制备方法,该透明膨胀型防火涂料由以下质量份的原料组成:阻燃剂:20~50份;粘结剂:15~25份;发泡剂:9~15份;助剂:0~5份;填料:0~15份;溶剂:10~30份。其制备方法包括以下步骤:将溶剂和粘结剂加入反应釜,边搅拌边加入阻燃剂、发泡剂、助剂和填料,充分混合均匀,得到透明膨胀型防火涂料。本发明的膨胀型透明防火涂料的阻燃效率高,可以长期应用于潮湿环境中,且不会有阻燃剂析出,透明度不会衰减。本发明的制备方法工艺简单,生产成本低,便于工业化生产。
Description
技术领域
本发明涉及一种透明膨胀型防火涂料及其制备方法,属于防火涂料技术领域。
背景技术
膨胀型透明防火涂料是一种功能性涂料,在发生火灾时能够在被涂物表面形成厚度相当于漆膜厚度几十倍甚至上百倍的致密碳层,起到隔热隔氧保护基材的作用,且不影响被涂物外观,密度低,易施工,成本低,被广泛用于工业及民用建筑、宾馆、影院、古建筑室内的木质装修用的可燃基材的防火保护和装饰场所的防火保护。
国内有很多关于膨胀型透明防火涂料制备的专利,如公开号为CN 104046201 A的中国专利公开了一种由聚磷酸酯、甲醚化氨基树脂、多聚磷酸、丁二醇、季戊四醇和聚乙二醇制备膨胀型透明防火涂料的方法,得到的防火涂料由于没有骨架填料,碳层强度低,很容易吹破,防火效率较低,且由于多聚磷酸的水溶性好,遇水或者湿气容易发粘析出;公开号为CN 103627291 A的中国专利公开了一种由甲醛、尿素、双氰胺、异丙醇、钛白粉、甲酸、季戊四醇、氢氧化钠等材料制备膨胀型透明防火涂料的方法,由于尿素、甲酸、氢氧化钠等材料水溶性都很高,在潮湿或遇水的情况下很容易析出,致使漆膜出现雾状不透明,从而失去透明性和阻燃性;公开号为CN 103073935 A的中国专利公开了一种由酸源树脂、甲醚化氨基树脂、季戊四醇三丙烯酸酯、引发剂、流平剂和有机硅树脂制备透明防火涂料的方法,得到的防火涂料由于没有骨架填料支撑,碳层强度低,易被氧化,防火效率低。
发明内容
本发明的目的在于提供一种透明膨胀型防火涂料及其制备方法。
本发明所采取的技术方案是:
一种透明膨胀型防火涂料,其由以下质量份的原料组成:
阻燃剂:20~50份;
粘结剂:15~25份;
发泡剂:9~15份;
助剂:0~5份;
填料:0~15份;
溶剂:10~30份。
所述阻燃剂为亚磷酸酯、烷基亚磷酸酯、烷基磷酸酯、硫代磷酸酯、二硫代焦磷酸酯、季戊四醇磷酸酯、磷酸三苯酯、三氯乙基磷酸酯、磷酸三异丙基苯酯中的至少一种。
所述粘结剂为丙烯酸树脂、苯乙烯丙烯酸树脂、醋酸乙烯树脂、改性醋酸乙烯树脂、聚氨酯树脂、三聚氰胺甲醛树脂、环氧树脂、醇酸树脂中的至少一种。
所述发泡剂为三聚氰胺、双氰胺、聚磷酸铵、氯化石蜡、磷酸铵盐、硼酸铵中的至少一种。
所述助剂为润湿分散剂、消泡剂、流平剂、杀菌剂、增稠剂、防冻剂、酸催化剂、pH调节剂中的至少一种。
所述填料为纳米硅微粉、纳米有机土、纳米氧化锌、纳米二氧化钛、纳米硅酸铝中的至少一种。
所述溶剂为水、乙二醇乙醚、乙二醇丁醚、甲苯、二甲苯、正丁醇、异丁醇、乙酸乙酯、乙酸丁酯、丙酮、N,N-二甲基甲酰胺中的至少一种。
上述透明膨胀型防火涂料的制备方法包括以下步骤:将溶剂和粘结剂加入反应釜,边搅拌边加入阻燃剂、发泡剂、助剂和填料,充分混合均匀,得到透明膨胀型防火涂料。
本发明的有益效果是:本发明的膨胀型透明防火涂料的阻燃效率高,可以长期应用于潮湿环境中,且不会有阻燃剂析出,透明度不会衰减。本发明的制备方法工艺简单,生产成本低,便于工业化生产。
具体实施方式
一种透明膨胀型防火涂料,其由以下质量份的原料组成:
阻燃剂:20~50份;
粘结剂:15~25份;
发泡剂:9~15份;
助剂:0~5份;
填料:0~15份;
溶剂:10~30份。
优选的,所述阻燃剂为亚磷酸酯、烷基亚磷酸酯、烷基磷酸酯、硫代磷酸酯、二硫代焦磷酸酯、季戊四醇磷酸酯、磷酸三苯酯、三氯乙基磷酸酯、磷酸三异丙基苯酯中的至少一种。
优选的,所述粘结剂为丙烯酸树脂、苯乙烯丙烯酸树脂、醋酸乙烯树脂、改性醋酸乙烯树脂、聚氨酯树脂、三聚氰胺甲醛树脂、环氧树脂、醇酸树脂中的至少一种。
优选的,所述发泡剂为三聚氰胺、双氰胺、聚磷酸铵、氯化石蜡、磷酸铵盐、硼酸铵中的至少一种。
优选的,所述助剂为润湿分散剂、消泡剂、流平剂、杀菌剂、增稠剂、防冻剂、酸催化剂、pH调节剂中的至少一种。
优选的,所述填料为纳米硅微粉、纳米有机土、纳米氧化锌、纳米二氧化钛、纳米硅酸铝中的至少一种。
优选的,所述溶剂为水、乙二醇乙醚、乙二醇丁醚、甲苯、二甲苯、正丁醇、异丁醇、乙酸乙酯、乙酸丁酯、丙酮、N,N-二甲基甲酰胺中的至少一种。
上述透明膨胀型防火涂料的制备方法包括以下步骤:将溶剂和粘结剂加入反应釜,边搅拌边加入阻燃剂、发泡剂、助剂和填料,充分混合均匀,得到透明膨胀型防火涂料。
优选的,上述透明膨胀型防火涂料的制备方法包括以下步骤:将溶剂和粘结剂加入反应釜,边搅拌边加入阻燃剂、发泡剂、助剂和填料,待物料的温度上升到50~70℃,恒温搅拌3~5h,将物料冷却至室温,打包包装,得到透明膨胀型防火涂料。
下面结合具体实施例对本发明作进一步的解释和说明。
实施例1:
一种膨胀型透明防火涂料,其原料配方组成如下表1:
表1膨胀型透明防火涂料的配方组成
原料 | 用量(质量份) |
季戊四醇磷酸酯 | 50 |
三聚氰胺甲醛树脂 | 20 |
双氰胺 | 15 |
酸催化剂AS-1040 | 2 |
纳米钛白粉 | 3 |
二甲苯 | 10 |
实施例2:
一种膨胀型透明防火涂料,其原料配方组成如下表2:
表2膨胀型透明防火涂料的配方组成
实施例3:
一种膨胀型透明防火涂料,其原料配方组成如下表3:
表3膨胀型透明防火涂料的配方组成
原料 | 用量(质量份) |
磷酸三异丙基苯酯 | 35 |
季戊四醇磷酸酯 | 8 |
聚氨酯树脂 | 25 |
聚磷酸铵 | 9 |
增稠剂黄原胶 | 1.5 |
去离子水 | 21.5 |
实施例4:
一种膨胀型透明防火涂料,其原料配方组成如下表4:
表4膨胀型透明防火涂料的配方组成
原料 | 用量(质量份) |
磷酸三苯酯 | 15 |
季戊四醇磷酸酯 | 15 |
聚醋酸乙烯丙烯酸酯 | 25 |
双氰胺 | 10 |
纳米钛白粉 | 15 |
乙醇 | 5 |
乙酸丁酯 | 15 |
实施例5:
一种膨胀型透明防火涂料,其原料配方组成如下表5:
表5膨胀型透明防火涂料的配方组成
原料 | 用量(质量份) |
二硫代焦磷酸酯 | 20 |
聚氨酯树脂 | 20 |
磷酸铵盐 | 12 |
增稠剂黄原胶 | 5 |
纳米氧化锌 | 13 |
乙酸丁酯 | 30 |
测试例:
对实施例1~5制备的膨胀型透明防火涂料进行性能测试,得到的性能数据如下表6所示。
表6实施例1~5的膨胀型透明防火涂料的性能测试数据
注:测试标准为:GB14907-2002。
上述实施例为本发明较佳的实施方式,但本发明的实施方式并不受上述实施例的限制,其他的任何未背离本发明的精神实质与原理下所作的改变、修饰、替代、组合、简化,均应为等效的置换方式,都包含在本发明的保护范围之内。
Claims (8)
1.一种透明膨胀型防火涂料,其特征在于:其由以下质量份的原料组成:
阻燃剂:20~50份;
粘结剂:15~25份;
发泡剂:9~15份;
助剂:0~5份;
填料:0~15份;
溶剂:10~30份。
2.根据权利要求1所述的透明膨胀型防火涂料,其特征在于:所述阻燃剂为亚磷酸酯、烷基亚磷酸酯、烷基磷酸酯、硫代磷酸酯、二硫代焦磷酸酯、季戊四醇磷酸酯、磷酸三苯酯、三氯乙基磷酸酯、磷酸三异丙基苯酯中的至少一种。
3.根据权利要求1所述的透明膨胀型防火涂料,其特征在于:所述粘结剂为丙烯酸树脂、苯乙烯丙烯酸树脂、醋酸乙烯树脂、改性醋酸乙烯树脂、聚氨酯树脂、三聚氰胺甲醛树脂、环氧树脂、醇酸树脂中的至少一种。
4.根据权利要求1所述的透明膨胀型防火涂料,其特征在于:所述发泡剂为三聚氰胺、双氰胺、聚磷酸铵、氯化石蜡、磷酸铵盐、硼酸铵中的至少一种。
5.根据权利要求1所述的透明膨胀型防火涂料,其特征在于:所述助剂为润湿分散剂、消泡剂、流平剂、杀菌剂、增稠剂、防冻剂、酸催化剂、pH调节剂中的至少一种。
6.根据权利要求1所述的透明膨胀型防火涂料,其特征在于:所述填料为纳米硅微粉、纳米有机土、纳米氧化锌、纳米二氧化钛、纳米硅酸铝中的至少一种。
7.根据权利要求1所述的透明膨胀型防火涂料,其特征在于:所述溶剂为水、乙二醇乙醚、乙二醇丁醚、甲苯、二甲苯、正丁醇、异丁醇、乙酸乙酯、乙酸丁酯、丙酮、N,N-二甲基甲酰胺中的至少一种。
8.权利要求1~7中任意一项所述的透明膨胀型防火涂料的制备方法,其特征在于:包括以下步骤:将溶剂和粘结剂加入反应釜,边搅拌边加入阻燃剂、发泡剂、助剂和填料,充分混合均匀,得到透明膨胀型防火涂料。
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