CN107502056B - Stamp-pad ink and preparation method thereof - Google Patents
Stamp-pad ink and preparation method thereof Download PDFInfo
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- CN107502056B CN107502056B CN201710725693.4A CN201710725693A CN107502056B CN 107502056 B CN107502056 B CN 107502056B CN 201710725693 A CN201710725693 A CN 201710725693A CN 107502056 B CN107502056 B CN 107502056B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses stamp-pad ink and a preparation method thereof, wherein the stamp-pad ink comprises the following raw materials in parts by weight: 5-15 parts of water-soluble polymer, 1-3 parts of edible pigment, 80-93 parts of saturated alcohol and 0.5-3 parts of antioxidant; the saturated alcohol is selected from one or more of ethanol, isopropanol, n-butanol and glycerol. The stamp-pad ink disclosed by the invention adopts water-soluble polymers as a connecting agent, and marks formed by the stamp-pad ink are firmly attached to the surface of skin, are not easy to rub flowers and are easy to clean.
Description
Technical Field
The invention relates to stamp-pad ink and a preparation method thereof, in particular to stamp-pad ink for human and animal skins and a preparation method thereof.
Background
The stamp-pad ink is used as stamp-pad ink and can be applied to paper, skin, etc. by stamping. The stamp-pad ink applicable to the skin is mainly applied to two aspects, on one hand, the stamp-pad ink can be applied to the skin of a human body, particularly in places such as large-scale exhibition halls, amusement parks and the like, and the stamp-pad ink covered on the arms of tourists can replace tickets to be used as entry evidences, so that the tourists can conveniently go in and out for many times, and the phenomenon of one ticket and multiple persons can be avoided; on the other hand, the kit can be applied to animal skins, particularly can be used as a qualified inspection mark in quarantine inspection in a slaughtering link, and has an important role in quality safety supervision of products such as livestock and poultry. The stamp-pad ink applied to the two aspects needs to have the characteristics of healthy formula, easiness in coloring, bright color, firmness in coloring and the like, and meanwhile, the stamp-pad ink can be washed clean by water without affecting the beauty and health of skin.
The patent with application numbers CN201110241392.7 and CN201210072406.1 respectively disclose a red stamp-pad ink for stamping pig carcasses and a meat inspection stamp-pad ink, which are difficult to transfer the pigment in the stamp-pad ink to the skin of animals in practical application, and after the stamp-pad ink is air-dried on the skin surface, the adhesion fastness of the pigment on the skin surface is limited, which is easy to rub and lead to the difficulty of identifying the stamp-pad ink and the failure of inspection, and are not suitable for application on the skin of human body and animals.
Disclosure of Invention
The invention provides stamp-pad ink and a preparation method thereof, which at least solve the problems that the stamp-pad ink in the prior art has limited adhesion fastness of marks formed on the surface of skin and is easy to rub flowers.
The invention provides stamp-pad ink which comprises the following raw materials in parts by weight: 5-15 parts of water-soluble polymer, 1-3 parts of edible pigment, 80-93 parts of saturated alcohol and 0.5-3 parts of antioxidant; the saturated alcohol is selected from one or more of ethanol, isopropanol, n-butanol and glycerol.
Further, the water-soluble polymer is selected from one or more of polyvinylpyrrolidone, carboxymethyl cellulose, polyacrylamide, hydrolyzed polyacrylamide and polyethylene glycol.
Furthermore, the water-soluble polymer is polyvinylpyrrolidone, and the molecular weight of the polyvinylpyrrolidone is 5000-50000.
Further, the stamp-pad ink comprises the following raw materials in parts by weight: 5-15 parts of water-soluble polymer, 1-3 parts of edible pigment, 60-80 parts of ethanol, 2-4 parts of glycerol, 10-20 parts of n-butyl alcohol and 0.5-3 parts of antioxidant.
Further, the edible pigment is selected from one or more of carmine, lemon yellow, amaranth, cochineal, beta-carotene and monascus red.
Further, the antioxidant is selected from one or more of ascorbic acid, citric acid and vitamin E.
Further, the stamp-pad ink also comprises 0.1-1 part of fluorescent pigment.
Further, the fluorescent pigment is selected from one or more of rhodamine B, acid rhodamine B, rhodamine 6G and rhodamine 123.
Another object of the present invention is to provide a method for preparing the stamp-pad ink, wherein the method comprises the steps of:
step 1: adding the edible pigment into saturated alcohol, mixing and stirring uniformly, and heating to 30-100 ℃ until the edible pigment is completely dissolved;
step 2: and (3) adding polyvinylpyrrolidone and an antioxidant into the solution obtained in the step (1), stirring and dissolving, cooling to 10-30 ℃, and filtering to obtain the stamp-pad ink.
Further, the heating temperature in the step 1 is 70-90 ℃.
Compared with the prior art, the invention has the following beneficial effects:
1. according to the invention, the water-soluble polymer is used as a connecting material, and the edible pigment in the stamp-pad ink can be better bonded by utilizing the viscosity of the water-soluble polymer, so that the transfer effect of the edible pigment transferred from the stamp pad to the skin of an animal is improved, and the stamp-pad ink is easy to color;
2. according to the invention, the water-soluble polymer is adopted, so that after the stamp-pad ink is dried in the air, the water-soluble polymer can form a polymer film, the edible pigment is fixed in the polymer film and is adhered to the surface of the skin, the adhesion firmness degree of the stamp-pad ink on the surface of the skin is improved, and the stamp-pad ink has the characteristic of firm coloring;
3. the stamp-pad ink has low toxicity of the raw materials, and is suitable for human skin and skin of livestock and poultry products;
4. the water-soluble polymer is used as the main component of the mark formed after the stamp-pad ink is solidified, and when the mark is not needed, the characteristic that the water-soluble polymer is easy to dissolve in water is utilized, so that the mark can be removed by water washing without damaging the skin.
Detailed Description
In order to make the technical solutions of the present invention better understood by those skilled in the art, the technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments.
Unless otherwise specified, the material ratios and percentages used in the examples and comparative examples of the present invention are in weight units, the water-soluble polymer used is of pharmaceutical grade, and the saturated alcohol and the edible pigment are of food grade.
Example 1
The polyvinyl pyrrolidone-containing emulsion comprises 5 parts of polyvinyl pyrrolidone, 1 part of carmine, 80 parts of ethanol, 2 parts of glycerol, 11 parts of n-butanol and 1 part of vitamin E, wherein the molecular weight of the polyvinyl pyrrolidone is 30000-45000.
The preparation method of the embodiment 1 of the invention comprises the following steps:
step 1: adding carmine into a mixed solution of ethanol, glycerol and n-butanol, mixing and stirring uniformly, and heating to 70 ℃ until the carmine is completely dissolved;
step 2: and (3) adding polyvinylpyrrolidone and vitamin E into the solution obtained in the step (1), stirring to dissolve, cooling to 25 ℃, and filtering to obtain the stamp-pad ink of the embodiment 1 of the invention.
Example 2
The polyvinyl pyrrolidone-containing oil comprises, by weight, 10 parts of polyvinyl pyrrolidone, 2 parts of carmine, 70 parts of ethanol, 3 parts of glycerol, 13.5 parts of n-butanol and 1 part of vitamin E, wherein the molecular weight of the polyvinyl pyrrolidone is 30000-45000.
The preparation method of the embodiment 1 of the invention comprises the following steps:
step 1: adding carmine into a mixed solution of ethanol, glycerol and n-butanol, mixing and stirring uniformly, and heating to 80 ℃ until the carmine is completely dissolved;
step 2: and (3) adding polyvinylpyrrolidone and vitamin E into the solution obtained in the step (1), stirring and dissolving, cooling to 20 ℃, and filtering to obtain the stamp-pad ink of the embodiment 2 of the invention.
Example 3
The polyvinyl pyrrolidone-containing oil comprises 15 parts of polyvinyl pyrrolidone, 3 parts of carmine, 60 parts of ethanol, 4 parts of glycerol, 15 parts of n-butanol and 0.5 part of ascorbic acid, wherein the molecular weight of the polyvinyl pyrrolidone is 30000-45000.
The preparation method of the embodiment 1 of the invention comprises the following steps:
step 1: adding carmine into a mixed solution of ethanol, glycerol and n-butanol, mixing and stirring uniformly, and heating to 90 ℃ until the carmine is completely dissolved;
step 2: and (3) adding polyvinylpyrrolidone and vitamin E into the solution obtained in the step (1), stirring and dissolving, cooling to 20 ℃, and filtering to obtain the stamp-pad ink of the embodiment 3 of the invention.
Example 4
The composition of the embodiment 1 of the invention comprises 15 parts of polyacrylamide, 3 parts of carmine, 60 parts of ethanol, 4 parts of glycerol, 15 parts of n-butanol, 0.5 part of ascorbic acid and 1230.5 parts of rhodamine, wherein the molecular weight of the polyacrylamide is 10000-20000.
The preparation method of the embodiment 1 of the invention comprises the following steps:
step 1: adding carmine and rhodamine 123 into a mixed solution of ethanol, glycerol and n-butanol, uniformly mixing and stirring, and heating to 90 ℃ until the carmine is completely dissolved;
step 2: and (3) adding polyvinylpyrrolidone and vitamin E into the solution obtained in the step (1), stirring and dissolving, cooling to 20 ℃, and filtering to obtain the stamp-pad ink of the embodiment 3 of the invention.
Example 5
The composition of the embodiment 1 of the invention comprises 15 parts of polyvinylpyrrolidone, 3 parts of cochineal, 60 parts of ethanol, 4 parts of glycerol, 15 parts of n-butanol and 0.5 part of ascorbic acid, wherein the molecular weight of the polyvinylpyrrolidone is 10000-25000.
The preparation method of the embodiment 1 of the invention comprises the following steps:
step 1: adding cochineal red into a mixed solution of ethanol, glycerol and n-butanol, mixing and stirring uniformly, and heating to 90 deg.C until the cochineal red is completely dissolved;
step 2: and (3) adding polyvinylpyrrolidone and vitamin E into the solution obtained in the step (1), stirring and dissolving, cooling to 20 ℃, and filtering to obtain the stamp-pad ink of the embodiment 3 of the invention.
Comparative example 1
The composition of the embodiment 1 of the invention comprises 3 parts of carmine, 60 parts of ethanol, 4 parts of glycerol, 15 parts of n-butanol and 0.5 part of ascorbic acid.
The preparation method of the embodiment 1 of the invention comprises the following steps:
step 1: adding carmine into a mixed solution of ethanol, glycerol and n-butanol, mixing and stirring uniformly, and heating to 90 ℃ until the carmine is completely dissolved;
step 2: and (3) adding vitamin E into the solution obtained in the step (1), stirring and dissolving, cooling to 20 ℃, and filtering to obtain the stamp-pad ink of the comparative example 1.
Comparative example 2
The composition of the embodiment 1 of the invention comprises 15 parts of polyvinylpyrrolidone, 3 parts of carmine, 60 parts of ethanol, 4 parts of glycerol, 15 parts of n-butanol and 0.5 part of ascorbic acid.
The preparation method of the embodiment 1 of the invention comprises the following steps:
step 1: adding carmine into a mixed solution of ethanol, glycerol and n-butanol, mixing and stirring uniformly, and heating to 90 ℃ until the carmine is completely dissolved;
step 2: and (3) adding polyvinylpyrrolidone and vitamin E into the solution obtained in the step (1), stirring and dissolving, and directly filtering to obtain the stamp-pad ink of the comparative example 2.
In order to examine the adhesion fastness of the stamp-pad ink provided by the present invention, the stamp-pad inks of examples 1 to 5 and comparative examples 1 to 2 were applied to pigskin with a stamp, and naturally dried in the open air, and the physical properties of the marks formed after the stamp-pad ink solidified were measured, and the measurement results are shown in the following table.
| Name (R) | State of impress when just covered | State of impress after air drying | 278nm ultraviolet radiation |
| Example 1 | Uniform and bright color | Smooth and smooth surface and difficult peeling | Without change |
| Example 2 | Uniform and bright color | Smooth and smooth surface and difficult peeling | Without change |
| Example 3 | Uniform and bright color | Smooth and smooth surface and difficult peeling | Without change |
| Example 4 | Uniform and bright color | Smooth and smooth surface and difficult peeling | Has green fluorescence |
| Example 5 | Uniform and bright color | Smooth and smooth surface and difficult peeling | Without change |
| Comparative example 1 | Uniform and light color | Rough surface and color loss | Without change |
| Comparative example 2 | Uneven and bright color | Has rough and cracked surface and is not easy to peel off | Without change |
As shown in the above table, in examples 1 to 5 of the present invention, the water-soluble organic polymer material such as polyvinylpyrrolidone and polyacrylamide is added to make the stamp-pad ink itself sticky, so that the stamp-pad ink can stably carry the edible pigment during stamping, thereby ensuring that the formed stamp-pad ink has a uniform and bright color. Meanwhile, after the marks of embodiments 1 to 5 are air-dried, the water-soluble organic polymer material is coagulated to form a polymer film with a smooth surface, so that the edible pigment is protected and prevented from falling off. In contrast, in comparative example 1 in which no water-soluble organic polymer material was added, the amount of edible pigment carried during stamping was small, the color was light, and after the stamp was dried, the edible pigment was not protected by the polymer film, so that the edible pigment was easily peeled off from the skin surface. In contrast to example 2, when the temperature is high, the temperature is reduced again by suction filtration, resulting in solid precipitation in the stamp pad, uneven stamp pad system, uneven color in the formed stamp pad, and a polymer film with a rough surface can be formed after the stamp pad is air-dried.
In addition, the fluorescent dye rhodamine 123 is added in the embodiment 4, so that the stamp formed by the mimeograph can generate fluorescence under the irradiation of 278nm ultraviolet rays, the anti-counterfeiting recognition capability of the stamp is further improved, the worker can confirm the authenticity of the stamp by only simply irradiating, and the recognition difficulty is reduced.
In particular, the embodiment of the invention adopts low-toxicity raw materials, is healthy in materials, and uses the total alcohol solvent to replace moisture in the conventional stamp-pad ink, thereby improving the lipophilicity of the stamp-pad ink and the drying speed on the skin. The stamp-pad ink in the embodiment of the invention also has the characteristics of low production cost, easily obtained raw materials and simple process.
Finally, it should be noted that the above-mentioned embodiments are only used for illustrating the technical solutions of the present invention and not for limiting the same, and although the present invention is described in detail with reference to the above-mentioned embodiments, it should be understood by those skilled in the art that the modifications and equivalents of the specific embodiments of the present invention can be made by those skilled in the art after reading the present specification, but these modifications and variations do not depart from the scope of the claims of the present application.
Claims (6)
1. The stamp-pad ink is characterized by comprising the following raw materials in parts by weight: 5-15 parts of water-soluble polymer, 1-3 parts of edible pigment, 80-93 parts of saturated alcohol and 0.5-3 parts of antioxidant; the saturated alcohol is selected from one or more of ethanol, isopropanol, n-butanol and glycerol;
the water-soluble polymer is selected from one or more of polyacrylamide and polyethylene glycol;
the edible pigment is selected from one or more of carmine, lemon yellow, amaranth, beta-carotene and monascus red;
the antioxidant is selected from one or more of ascorbic acid, citric acid, and vitamin E.
2. The stamp-pad ink according to claim 1, comprising the following raw materials in parts by weight: 5-15 parts of water-soluble polymer, 1-3 parts of edible pigment, 60-80 parts of ethanol, 2-4 parts of glycerol, 10-20 parts of n-butyl alcohol and 0.5-3 parts of antioxidant.
3. The stamp-pad ink according to claim 1, further comprising 0.1 to 1 part by weight of a fluorescent pigment.
4. The stamp-pad ink according to claim 3, wherein the fluorescent dye is one or more selected from rhodamine B, rhodamine 6G, and rhodamine 123.
5. A method of preparing the stamp-pad ink of claim 1, comprising the steps of:
step 1: adding the edible pigment into saturated alcohol, mixing and stirring uniformly, and heating to 30-100 ℃ until the edible pigment is completely dissolved;
step 2: and (3) adding a water-soluble polymer and an antioxidant into the solution obtained in the step (1), stirring and dissolving, cooling to 10-30 ℃, and filtering to obtain the stamp-pad ink.
6. The method for preparing stamp-pad ink according to claim 5, wherein the heating temperature in step 1 is 70-90 ℃.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710725693.4A CN107502056B (en) | 2017-08-22 | 2017-08-22 | Stamp-pad ink and preparation method thereof |
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| CN201710725693.4A CN107502056B (en) | 2017-08-22 | 2017-08-22 | Stamp-pad ink and preparation method thereof |
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| CN107502056A CN107502056A (en) | 2017-12-22 |
| CN107502056B true CN107502056B (en) | 2021-03-23 |
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| CN113337153A (en) * | 2021-06-18 | 2021-09-03 | 浙江科力印业新技术发展有限公司 | Environment-friendly second-drying glass stamp-pad ink and preparation method thereof |
| CN116376349B (en) * | 2023-04-11 | 2024-02-02 | 北京国印网安科技有限公司 | Stamp-pad ink based on high molecular crosslinking and preparation method thereof |
| CN118027745B (en) * | 2024-02-19 | 2024-07-19 | 东莞市唐德医疗科技有限公司 | Ethyl violet composite medical skin marker ink and preparation method thereof |
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| US4620875A (en) * | 1984-04-10 | 1986-11-04 | Ricoh Company, Ltd. | Aqueous ink composition |
| DE4426941A1 (en) * | 1994-07-29 | 1996-02-01 | Bayer Ag | Cationic 1,3,4-thiadiazole dyes |
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| CN1118311A (en) * | 1994-09-10 | 1996-03-13 | 李荣裕 | Manufacture of colour seal |
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