CN104434568A - Strippable water-based non-irritation nail polish - Google Patents
Strippable water-based non-irritation nail polish Download PDFInfo
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- CN104434568A CN104434568A CN201410704551.6A CN201410704551A CN104434568A CN 104434568 A CN104434568 A CN 104434568A CN 201410704551 A CN201410704551 A CN 201410704551A CN 104434568 A CN104434568 A CN 104434568A
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Abstract
The invention relates to the field of synthetic production of cosmetics and aims to provide strippable water-based non-irritation nail polish. The strippable water-based non-irritation nail polish comprises deionized water, water-soluble modified polyurethane, chitosan, a wetting agent, a dispersing agent, an antifoaming agent, a rheological agent, water-soluble environment-friendly color paste and other additives. Water is used as a solvent, and no or only a small amount of absolute ethyl alcohol is added to be used as an additive, so that the nail polish has no paint smell of traditional oil-soluble nail polish or alcohol smell of alcohol-soluble nail polish and contains no alkali-associative thickener, and the whole nail polish system is neutral and causes no damage to the skin, nails and clothes.
Description
Technical field
The invention relates to cosmetics synthesis production field, the particularly non-stimulated nial polish of a kind of strippable water-soluble.
Background technology
Nial polish, also known as " nail varuish ", is the large series products of one in color make-up.The personage that likes to be beautiful is spread upon on fingernail, fingernail can be made colourful and gloss becomes clear, and therefore nial polish is all a very welcome makeups product in the women of all age group.The nial polish brand existed in the market is various, very different.But on the whole, current nial polish can be divided into oil-soluble and the large class of water solublity two according to primary solvent composition.
Oil-soluble nial polish is time-honored conventional nails oil, occupies the overwhelming majority of nial polish on market.Oil-soluble nial polish mainly with resins such as oil-soluble nitrocellulose, polyvinyl pyrrolidone, novolac resin, Lauxite, polyurethane, polyacrylic acid for film former, with organic compound such as phthalic acid ester, formaldehyde, acetone or ethyl acetate for solvent, add the filler such as thickening agent, oil-soluble mill base simultaneously and mix together.This class nial polish possesses high gloss, high durability degree and the advantage of water-tolerant.But there is following shortcoming in oil-soluble nial polish:
1, the solvent that oil-soluble nial polish uses is all harmful volatile organic compound, cause nial polish the smell is awful pungent, and long-term suction can damage human respiratory and nervous system, healthy irreversible injury is caused to manicure fan.
2, high, the good endurance of oil-soluble nial polish coating intensity is not easily peeled off, thus the time that the fingernail oil film containing organic solvent can keep a couple of days even more of a specified duration on fingernail, fitness guru claims light nial polish preferably to remove in 7 days, dark nial polish should be removed in 3 days, fingernail can hinder the breathing of fingernail under covering fingernail oil film for a long time, and the nervous system that toxin can enter human body through fingernail damages.The method removing oil-soluble nial polish typically uses the cleaner circulated on the market, and the Main Ingredients and Appearance of cleaner is generally industrial banana oil, can cause secondary injury to human body.
Generally speaking, traditional oils dissolubility nial polish abnormal smells from the patient is pungent, corrosivity is strong, larger to the injury of fingernail and human body.
Water-soluble nail polish is the novel nial polish of a class occurred in recent years.Water-soluble nail polish refers to that water solublity or alcohol insoluble film former add the nial polish that the filler such as watersoluble pigment, thickening agent is uniformly mixed with water or low-molecular-weight alcohols for solvent.Now this type of nial polish majority is solvent with ethanol, is aided with a small amount of water and makes as secondary solvent.So this kind of nial polish does not have oil-soluble nial polish such pungent " paint-like flavour ", the substitute is " alcohol smell " of ethanol, so this kind of nial polish can only be referred to as low stimulation nial polish, do not reach completely non-stimulated level.And current many businessmans can use cheap industrial alcohol to prepare this kind of nial polish as solvent, also can be introduced in nial polish containing the poisonous chemical substance such as methanol, hydrogen chloride in industrial alcohol, and then health is damaged.In addition, because water-soluble nail polish is still in developmental stage, the immature factors such as film former kind, filler auxiliary agent kind, material proportion constrain the effect that this kind of nial polish does not reach traditional oils dissolubility nial polish in outward appearance, paintability etc., and this is also one of shortcoming of water-soluble nail polish.
Those skilled in the art improve nial polish formula:
CN 102908266A (date of publication is on February 6th, 2013) discloses a kind of Environmental-friendnail nail enamel and preparation method thereof, and described Environmental-friendnail nail enamel comprises emulsion, film former, aqueous, environmental protective mill base and deionized water; Wherein, the monomer that prepared by described emulsion comprises butyl acrylate, styrene, methacrylic acid and vinyl hydroxy silicone oil; Described initiator is azodiisobutyronitrile.Although this patent claims that its nial polish is environment-friendly type nial polish, true really not so.First, the principles of chemistry that this nial polish generates fingernail oil film are that the free yl polymerizating monomer (i.e. butyl acrylate, styrene, methacrylic acid and vinyl hydroxy silicone oil) in the middle of emulsion issues raw Raolical polymerizable in the initiation of radical initiator azodiisobutyronitrile, and then generation polymeric film, be attached on fingernail and be fingernail oil film.The initiator azodiisobutyronitrile toxicity that it uses is very large, should be stored in 20 DEG C of dry places, and run into water and can decompose and release nitrogen and organic cyanide, the latter is very large to harm.This chemical substance should not be applied in makeups product.And in this patent disclosure nial polish, deionized water is important composition composition, azodiisobutyronitrile decomposition has a good chance.Secondly, above-mentioned several polymerization single polymerization monomers can not reach 100% in initiator initiated polymerization efficiency, that is will remain these polymerization single polymerization monomers, such as butyl acrylate in fingernail oil film (polymeric film), itself is easily sucked by people, or absorbs health harmful through skin.Its steam or mist have stimulation to eyes, mucosa and respiratory tract.Poisoning manifestations has burn feeling, pants, laryngitis, breathe hard, have a headache, nausea and vomiting.This kind of polymerization single polymerization monomer is also not suitable as the raw material having the makeups product contacted with human body.In sum, this nial polish is difficult to the definition meeting Environmental-friendnail nail enamel.In addition, this nial polish light color series of products, easy layering within a short period of time, at the bottom of its titanium white powder pigment used can be deposited in bottle, have a strong impact on serviceability, this point is also the common fault of most of domestic nial polish.
CN 102552059A (date of publication is on July 11st, 2012) discloses a kind of low stimulation nial polish, this nial polish based on alcohols solvent and alcohols film former, then is equipped with the additives such as thickening agent, suspending agent, plasticizer, paint box essence and is uniformly mixed and forms.The alcohols solvent that this nial polish uses refers to and the low alcohol that molecular weight is less than 103 is mainly ethanol.These alcoholic solvents addition in nial polish is 30% ~ 85% (mass fraction), illustrate that alcoholic solution is nial polish main component, these low-molecular-weight alcohols highly volatiles, by causing, nial polish abnormal smells from the patient is in use very large, and wherein several alcohols (isopropyl alcohol, n-butyl alcohol and isobutanol) abnormal smells from the patient has very strong zest, contact skin also has certain burn sense and injury.In addition, each alcoholic solvent that product uses mostly is other product of technical grade, wherein containing a certain amount of methanol and formaldehyde, and these two kinds of compounds also highly volatile, and have very large injury to human body, to sum up this nial polish is still very large to the zest of human body.In addition, also there is the problem of titanium dioxide sedimentation in the light series of products short time in this nial polish, has a strong impact on serviceability, and this problems demand solves.
Summary of the invention
Main purpose of the present invention is to overcome deficiency of the prior art, provides a kind of strippable water-soluble of health environment-friendly non-stimulated nial polish.For solving the problems of the technologies described above, solution of the present invention is:
There is provided a kind of strippable water-soluble non-stimulated nial polish, comprise deionized water, with the gross mass of the non-stimulated nial polish of strippable water-soluble for benchmark, it consists of:
Wherein, and the modified polyurethane resin of described water-soluble modified polyurethane employing containing polyhydroxy functional groups (commercially available, Wan Hua
9230);
Other auxiliary agents described adopt at least one material in essence, pearl essence, fluorescent material, glitter powder, antiseptic, brightener, flatting silica and dehydrated alcohol.
As further improvement, in described water-soluble modified polyurethane, hydroxyl molar content is 1.5 ± 0.1%.
As further improvement, described chitosan adopts the chitosan with high deacetylation degree of deacetylation between 85% ~ 95%.
Implementation of the present invention: present invention employs the film forming substrate of the water miscible polyurethane resin through special modification as nial polish; The simple environmental protection of this resin manufacturing processes, containing a large amount of activity hydroxies (hydroxyl molar content is 1.5 ± 0.1%) on modified molecular resin main chain, and the crude product that these resin commodity are commercial synthesis obtains through purification, residual monomer and catalyst, initiator are removed all further, VOC content is extremely low, and not containing volatile harmful compound.This modified polyurethane is directly dissolved in deionized water and makes base solution by the present invention; Add the preparation of various auxiliary agent on this basis again, so fundamentally solve toxicity problem, meet the concept of health environment-friendly.Chitosan with high deacetylation degree adds in nail polish system as the important filler of one by the present invention first; Have active hydroxyl and amino in chitosan macromole, they have stronger chemical reaction ability, give a lot of excellent chemical property of chitosan and physiologically active.
Compared with prior art, the invention has the beneficial effects as follows:
1, the present invention take water as solvent, can not add or only add on a small quantity dehydrated alcohol as adjuvant, so there is no " paint-like flavour " of traditional oils dissolubility nial polish or " alcohol smell " of alcohol dissolubility nial polish, and not containing alkali association thickener, the whole system of nial polish is neutral, does not hinder skin, fingernail and medicated clothing;
2, chitosan with high deacetylation degree adds in nial polish as important filler by the present invention, reduces the sedimentation of mill base and other fillers, and can Adsorption of Heavy Metals, and has certain bacteriostasis;
3, fingernail oil film of the present invention is easily peeled off, and can accomplish nial polish noresidue, be convenient to user and frequently change color and do not hinder fingernail after stripping with water cleaning fingernail;
4, the present invention adds special-effect (as pearly-lustre, fluorescence etc.), namely there is color multiformity and glossiness, and reach the level of oil-soluble nial polish, and touch medicated clothing and dissolved corrosion can not occur fade, use ethanol can by pollution place washes clean.
Accompanying drawing explanation
Fig. 1 is nial polish film forming mechanism schematic diagram of the present invention.
Detailed description of the invention
Below in conjunction with accompanying drawing and detailed description of the invention, the present invention is described in further detail:
The non-stimulated nial polish of health environment-friendly must possess following characteristics: 1, nial polish base material is that environment-protecting asepsis wanted by adopted resin, this comprises nontoxic and residual not poisonous in the resin system material such as catalyst, initiator of polymerization single polymerization monomer itself, so just can not injure fingernail, can not fingernail be permeated and injury is produced to the keratin structure of nail surface; 2, should not contain the solvent (alcohols) of poisonous (acetone, ethyl acetate etc.) or micro-toxicity in nail polish system, can not produce like this and can be breathed the toxic chemical substance of suction and then damage human body; The fillers such as the auxiliary rheological agents 3, added in nail polish system, mill base should be the products of low VOC, and can not contain heavy metal and a small amount of virose Organic substance; 4, fingernail oil film is easy to remove from fingernail, and does not injure the keratin on fingernail.
For reaching the target of the non-stimulated nial polish of above-mentioned health environment-friendly, the present invention proposes the non-stimulated nial polish of a kind of strippable water-soluble, and with the gross mass of the non-stimulated nial polish of strippable water-soluble for benchmark, it consists of:
As the water-soluble modified polyurethane of the film forming substrate of nial polish, adopt the modified polyurethane resin containing polyhydroxy functional groups, wherein, hydroxyl molar content is 1.5 ± 0.1%.The simple environmental protection of this resin manufacturing processes, containing a large amount of activity hydroxies (hydroxyl molar content is 1.5 ± 0.1%) on modified molecular resin main chain, and the crude product that these resin commodity are commercial synthesis obtains through purification, residual monomer and catalyst, initiator are removed all further, VOC content is extremely low, and not containing volatile harmful compound.This modified polyurethane is directly dissolved in deionized water and makes base solution by the present invention, adds the preparation of various auxiliary agent on this basis again, so fundamentally solve toxicity problem, meets the concept of health environment-friendly.Deionized water is the exclusive solvents of this nail polish system, does not contain the solvent of high poison (acetone, ethyl acetate etc.) and low toxicity (alcohols), thus solvent aspect, also solve toxicity problem, meet the concept of health environment-friendly in system.
The present invention, first by the chitosan with high deacetylation degree of deacetylation between 85% ~ 95%, adds in nail polish system as the important filler of one, and this is also the essential distinction that the present invention invents with in the past all nial polishs.
Chitosan (chitosan), also known as chitosan, is that the chitin (chitin) extensively existed by nature obtains through deacetylation, and chemical name is Chitosan (1-4)-2-amino-B-D glucose.The premium properties such as the biological functionality of this natural polymer and the compatibility, blood compatibility, safety, microbic resolvability, by all trades and professions extensive concern, achieve major progress at the applied research of the numerous areas such as medicine, food, chemical industry, cosmetics, water treatment, METAL EXTRACTION and recovery, biochemistry and biomedical engineering.Have active hydroxyl and amino in chitosan macromole, they have stronger chemical reaction ability.Give a lot of excellent chemical property of chitosan and physiologically active, such as:
Active hydroxyl and amino is had easily with other activated hydroxy compound, strong hydrogen bond action to occur in chitosan macromole, generation cross-linking effect;
Containing group NH in solution after chitosan dissolves
2 +, these groups, by carrying out anti-bacteria in conjunction with negatron, make chitosan have certain biocidal property;
Another remarkable characteristic of chitosan is absorbability.Many low-molecular-weight metal ions, cholesterol, triglyceride, cholic acid and organic mercury etc., can be adsorbed by chitosan.Particularly chitosan not only can adsorb magnesium, potassium, and can adsorb zinc, calcium, hydrargyrum and uranium.
The Main Function adding chitosan with high deacetylation degree in this nail polish system has four:
1, the polyurethane resin containing many activity hydroxies of chitosan and special modification produces strong hydrogen bond action, make polyurethane resin be cross-linked to form cross-linked network system, after treating that aqueous solvent vapors away, just define fingernail oil film, give the film forming mechanism that nial polish is special, can with reference to figure 1.
2, the existence of the active group of chitosan reduces the effect between polyurethane and nail surface keratin, and then the characteristic that imparting nial polish is easily peeled off, macro manifestations is: fingernail oil film itself has certain intensity, and do not return sticky, but can (such as constantly shell dynamic from fingernail oil film root to it with other fingernails under certain mechanism, departing from after fingernail until nial polish membrane portions) full wafer torn, and the keratin of fingernail can not be injured, simultaneously can not residual polyalcohol on fingernail.
3, crosslinked in nail polish system of chitosan serves certain thickening effect, and the cross-linking system of the chitosan filler larger to proportions such as the titanium dioxide in nial polish, pearl essences serves the effect stoping its sedimentation, solves the common fault of most domestic nial polish.
4, chitosan can adsorb many metal ions such as zinc, arsenic, aluminum and organic mercury etc., can play purification nial polish and get rid of heavy metal injury fingernail, and also can resist the injury of extraneous heavy metal to fingernail as fingernail oil film as nial polish substrate composition.In addition, chitosan has bacteriostasis, effectively can reduce the microbial contamination of nial polish, improves quality and the safety and Health of nial polish.
Other auxiliary agents in the present invention, adopt at least one material in essence, pearl essence, fluorescent material, glitter powder, antiseptic, brightener, flatting silica and dehydrated alcohol.
The following examples can make professional and technical personnel's comprehend the present invention of this specialty, but do not limit the present invention in any way.The various raw materials used in the present invention, such as chitosan, wetting agent, dispersant, defoamer, auxiliary rheological agents, various water-soluble environment protective mill base, other auxiliary agents various etc., be all commercially available general goods auxiliary agent; Modified polyurethane resin containing polyhydroxy functional groups is also marketable material, adopts ten thousand China
9230.
Embodiment 1
Join in container by the material proportion (mass fraction) of embodiment in table 11 by described material, add deionized water to quality 100%, high-speed stirred evenly obtains transparent pink colour nial polish.
Embodiment 2
Join in container by the material proportion (mass fraction) of embodiment in table 12 by described material, add deionized water to quality 100%, high-speed stirred evenly obtains large red nial polish.
Embodiment 3
Join in container by the material proportion (mass fraction) of embodiment in table 13 by described material, add deionized water to quality 100%, high-speed stirred evenly obtains lavandula angustifolia nial polish.
Embodiment 4
Join in container by the material proportion (mass fraction) of embodiment in table 14 by described material, add deionized water to quality 100%, high-speed stirred evenly obtains carmetta nial polish.
Embodiment 5
Join in container by the material proportion (mass fraction) of embodiment in table 15 by described material, add deionized water to quality 100%, high-speed stirred evenly obtains phototropic nial polish.
Embodiment 6
Join in container by the material proportion (mass fraction) of embodiment in table 16 by described material, add deionized water to quality 100%, high-speed stirred evenly obtains warm color changeable nail enamel.
Embodiment 7
Join in container by the material proportion (mass fraction) of embodiment in table 17 by described material, add deionized water to quality 100%, high-speed stirred evenly obtains pearly-lustre nial polish.
Embodiment 8
Join in container by the material proportion (mass fraction) of embodiment in table 18 by described material, add deionized water to quality 100%, high-speed stirred evenly obtains illusion-colour nial polish.
Embodiment 9
Join in container by the material proportion (mass fraction) of embodiment in table 19 by described material, add deionized water to quality 100%, high-speed stirred evenly obtains luminous nail polish.
Embodiment 10
Join in container by the material proportion (mass fraction) of embodiment in table 1 10 by described material, add deionized water to quality 100%, high-speed stirred evenly obtains dumb light nial polish.
Embodiment 11
Join in container by the material proportion (mass fraction) of embodiment in table 1 11 by described material, add deionized water to quality 100%, high-speed stirred evenly obtains bright black nial polish.
Embodiment 12
Join in container by the material proportion (mass fraction) of embodiment in table 1 12 by described material, add deionized water to quality 100%, high-speed stirred evenly obtains NINGMENGXIANG nial polish.
The material proportion table of table 1 embodiment 1-12
Note: in table 1, all material proportions are mass fraction.
Finally, it should be noted that above what enumerate is only specific embodiments of the invention.Obviously, the invention is not restricted to above embodiment, a lot of distortion can also be had.All distortion that those of ordinary skill in the art can directly derive or associate from content disclosed by the invention, all should think protection scope of the present invention.
Claims (3)
1. the non-stimulated nial polish of strippable water-soluble, comprises deionized water, it is characterized in that, with the gross mass of the non-stimulated nial polish of strippable water-soluble for benchmark, it consists of:
Wherein, described water-soluble modified polyurethane adopts the modified polyurethane resin containing polyhydroxy functional groups;
Other auxiliary agents described adopt at least one material in essence, pearl essence, fluorescent material, glitter powder, antiseptic, brightener, flatting silica and dehydrated alcohol.
2. the non-stimulated nial polish of a kind of strippable water-soluble according to claim 1, is characterized in that, in described water-soluble modified polyurethane, hydroxyl molar content is 1.5 ± 0.1%.
3. the non-stimulated nial polish of a kind of strippable water-soluble according to claim 1, is characterized in that, described chitosan adopts the chitosan with high deacetylation degree of deacetylation between 85% ~ 95%.
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105147536A (en) * | 2015-10-16 | 2015-12-16 | 湖北东盛特种涂料科技有限公司 | Aqueous strippable nail enamel and preparation method thereof |
| CN105287247A (en) * | 2015-10-16 | 2016-02-03 | 湖北东盛特种涂料科技有限公司 | Cationic waterborne acrylate-type environmental-friendly water-based nail polish and preparation method thereof |
| CN105534742A (en) * | 2016-01-20 | 2016-05-04 | 上海应用技术学院 | Strippable nail polish gel and preparation process thereof |
| CN105534741A (en) * | 2016-01-20 | 2016-05-04 | 上海应用技术学院 | Strippable nail polish gel and synthesis method thereof |
| CN105640801A (en) * | 2016-01-20 | 2016-06-08 | 上海应用技术学院 | Strippable nail polish glue and synthetic method |
| CN105686972A (en) * | 2016-02-23 | 2016-06-22 | 上海应用技术学院 | Soak-off gel and preparation method thereof |
| CN105997570A (en) * | 2016-06-12 | 2016-10-12 | 茌平县红粉天使化妆品科技有限公司 | Waterborne nail polish and preparation method thereof |
| CN107502359A (en) * | 2017-08-18 | 2017-12-22 | 中山市绿浪助剂有限公司 | A kind of microbe soil restoration agent |
| CN107550776A (en) * | 2017-09-08 | 2018-01-09 | 常州创索新材料科技有限公司 | A kind of preparation of balsamine pigment water-based nail polish |
| CN112618398A (en) * | 2021-01-11 | 2021-04-09 | 金华市科维思日化有限公司 | Silky smooth abrasive sand nail polish and preparation method thereof |
| CN112826753A (en) * | 2021-01-11 | 2021-05-25 | 金华市科维思日化有限公司 | Environment-friendly high-stability water-based frosted nail polish and preparation method thereof |
| CN112933000A (en) * | 2021-03-18 | 2021-06-11 | 电子科技大学中山学院 | Antibacterial nail polish and preparation method thereof |
| CN113384489A (en) * | 2021-06-16 | 2021-09-14 | 宇虹颜料股份有限公司 | Processing method of water-based nail polish preparation |
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Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105287247A (en) * | 2015-10-16 | 2016-02-03 | 湖北东盛特种涂料科技有限公司 | Cationic waterborne acrylate-type environmental-friendly water-based nail polish and preparation method thereof |
| CN105147536A (en) * | 2015-10-16 | 2015-12-16 | 湖北东盛特种涂料科技有限公司 | Aqueous strippable nail enamel and preparation method thereof |
| CN105534741B (en) * | 2016-01-20 | 2018-09-14 | 上海应用技术学院 | A kind of peelable nail polish glue and its synthetic method |
| CN105534742A (en) * | 2016-01-20 | 2016-05-04 | 上海应用技术学院 | Strippable nail polish gel and preparation process thereof |
| CN105534741A (en) * | 2016-01-20 | 2016-05-04 | 上海应用技术学院 | Strippable nail polish gel and synthesis method thereof |
| CN105640801A (en) * | 2016-01-20 | 2016-06-08 | 上海应用技术学院 | Strippable nail polish glue and synthetic method |
| CN105534742B (en) * | 2016-01-20 | 2018-10-23 | 上海应用技术学院 | A kind of peelable nail polish glue and preparation process |
| CN105686972A (en) * | 2016-02-23 | 2016-06-22 | 上海应用技术学院 | Soak-off gel and preparation method thereof |
| CN105686972B (en) * | 2016-02-23 | 2019-01-15 | 上海应用技术学院 | Strippable property nail polish glue and preparation method thereof |
| CN105997570B (en) * | 2016-06-12 | 2020-02-18 | 北京氢爽生物科技有限公司 | Water-based nail polish and preparation method thereof |
| CN105997570A (en) * | 2016-06-12 | 2016-10-12 | 茌平县红粉天使化妆品科技有限公司 | Waterborne nail polish and preparation method thereof |
| CN107502359A (en) * | 2017-08-18 | 2017-12-22 | 中山市绿浪助剂有限公司 | A kind of microbe soil restoration agent |
| CN107550776A (en) * | 2017-09-08 | 2018-01-09 | 常州创索新材料科技有限公司 | A kind of preparation of balsamine pigment water-based nail polish |
| CN112618398A (en) * | 2021-01-11 | 2021-04-09 | 金华市科维思日化有限公司 | Silky smooth abrasive sand nail polish and preparation method thereof |
| CN112826753A (en) * | 2021-01-11 | 2021-05-25 | 金华市科维思日化有限公司 | Environment-friendly high-stability water-based frosted nail polish and preparation method thereof |
| CN112933000A (en) * | 2021-03-18 | 2021-06-11 | 电子科技大学中山学院 | Antibacterial nail polish and preparation method thereof |
| CN113384489A (en) * | 2021-06-16 | 2021-09-14 | 宇虹颜料股份有限公司 | Processing method of water-based nail polish preparation |
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