CN111939101B - Strippable base coat for nail care and protection and preparation method thereof - Google Patents
Strippable base coat for nail care and protection and preparation method thereof Download PDFInfo
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- CN111939101B CN111939101B CN202010935894.9A CN202010935894A CN111939101B CN 111939101 B CN111939101 B CN 111939101B CN 202010935894 A CN202010935894 A CN 202010935894A CN 111939101 B CN111939101 B CN 111939101B
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/88—Polyamides
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q3/00—Manicure or pedicure preparations
- A61Q3/02—Nail coatings
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Abstract
The invention relates to the technical field of nail care, in particular to a strippable primer for nail care, which comprises the following raw materials in percentage by weight: 10-40% of high molecular resin; 0-1% of keratin; 0-1% of anti-UV auxiliary agent; 20-75% of alcohols; 1-20% of water and 0-20% of reinforced filler. The first coat capable of peeling the nail care provided by the invention is safer and more convenient to coat, does not need UV light irradiation, can be rapidly and naturally cured at normal temperature, can achieve long-acting protection for 5-15 days, and has the advantages of good durability, good protection effect after curing and good peeling effect; when the base coat needs to be stripped, the nail can be easily stripped and removed by directly soaking the nail in warm water (40-45 ℃) for 5-10 min without nail washing water, so that the nail is effectively protected.
Description
Technical Field
The invention relates to the technical field of nail care, in particular to a strippable primer for nail care and a preparation method thereof.
Background
At present, nail polish mainly comprises three types of water-based nail polish, nitro-based nail polish and UV phototherapy adhesive in the market, and the UV phototherapy adhesive has the advantages of good adhesive force, long holding time, high glossiness and the like compared with other two types of nail polish, and is a mainstream product in the nail art.
With the continuous acceleration of life rhythm, a plurality of women like to change own nails, a strippable coating appears in the market at present, the strippable coating is generally prepared by adding a strippable component into a formula of nail polish gel, a user can strip the whole nail without nail polish water when needing to remove the coating, the use is convenient, but the strippable coating in the market at present has the phenomena of incomplete stripping, stripping of the nail polish without nail polish effect reaching more than three days, and the like, and the experience feeling of customers is poor, so common merchants do not recommend the use of the coating, but recommend the customers to use the UV coating to achieve the purpose of long-time protection, but the UV coating can last for a long time, but the customers need to polish and remove the liquid medicine in professional nail shops when removing the UV coating, the nail polish can be damaged very much, and the UV coating has certain smell and small molecular chemicals when not being cured, the use of UV lamps in curing has unhealthy factors.
Chinese patent CN102228411B discloses a two-in-one water-soluble nail-beautifying and protecting film solution, which is prepared by preparing a modified water-based resin and a water-soluble compound into a base material, and then mixing the base material with a water-based dispersant and a color-developing substance; the solution has the advantages of no color, no odor, environmental protection, safety, rapid drying, no fear of hot water soaking and friction, high hardness, strong adhesive force and the like; however, the nail-beautifying nail-protecting film solution has poor durability and protection performance for at most 3 days, needs ester or alcohol dissolving solution to wash off, has great damage to nails and poor safety; chinese patent CN105560082B discloses an improved strippable nail polish gel, which comprises UV curable resin A, UV cured tree B, reactive diluent, defoamer, color paste and photoinitiator, although the strippable nail polish gel has fast curing capability after being coated with a film and irradiated by 395nm UV-LED lamp, and is easy to strip, the strippable nail polish gel has larger damage to enamel of nails and poor nail protection effect, and therefore, a nail polish primer which is safer and more convenient to coat, good in nail protection effect, natural curing and good in stripping effect is urgently needed.
Disclosure of Invention
Aiming at the defects in the prior art, the invention aims to provide the non-UV nail-care strippable base coat which is safer, more convenient and faster in coating, is quickly and naturally cured, has better protection effect after curing and is easy to strip.
The above object of the present invention is achieved by the following technical solutions:
the strippable primer for nail care and protection comprises the following raw materials in parts by weight:
10-40% of high molecular resin; 0-1% of keratin; 0-1% of anti-UV auxiliary agent; 20-75% of alcohols; 1-20% of water and 0-20% of reinforced filler.
Preferably, the nail-care and nail-protection base coat comprises the following raw materials in percentage by weight:
10-30% of high molecular resin; 0.1-1% of keratin; 0.1-1% of anti-UV auxiliary agent; 20-55% of alcohols; 1-20% of water and 5-20% of reinforced filler.
Preferably, the nail-care and nail-protection base coat comprises the following raw materials in percentage by weight: 10-20% of high molecular resin; 0.1-0.2% of keratin; 0.1 to 0.2 percent of anti-UV additive; 40-55% of alcohols; 1-5% of water and 5-10% of reinforced filler.
Preferably, the molecular weight of the polymeric resin is greater than 1000 daltons.
Preferably, the polymer resin is a polyester resin, an acrylate, a polyamide resin or a polyurethane resin.
Preferably, the polymer resin is an alcohol-soluble polyamide resin.
Preferably, the keratin is a water-soluble keratin.
Preferably, the alcohol is selected from one of ethanol, propanol and n-butanol.
Preferably, the reinforcing filler is selected from one or both of silica and mica powder.
The invention also aims to provide a preparation method of the strippable base coat for nail care, which comprises the following steps:
s1, mixing the alcohols and water in the weight ratio to form a mixed solution A;
s2, adding the polymer resin, the keratin, the anti-UV auxiliary agent and the reinforced filler into the mixed solution A, and uniformly stirring to obtain transparent or semitransparent liquid, thus obtaining the nail-care and nail-protection base coat.
The invention creatively provides the strippable base coat for nail care and protection, which is safer and more convenient to coat, can be quickly and naturally cured, and has better protection effect and stripping effect after curing. The high polymer resin can be well dissolved in water or alcohols, the glass transition temperature of the high polymer resin is 38-45 ℃, the high polymer resin can be selected from polyester resin, acrylate, polyamide resin or polyurethane resin, the high polymer resin is safe and non-toxic, the high polymer resin is added into the base coat, has very good normal-temperature adhesive force (not sticking to skin) on the nail, does not damage the nail, does not need to shine a UV lamp, can be cured under the normal-temperature condition, can achieve long-term protection for 5-15 days, and has good durability; wherein the keratin can provide better nutrition protection for the nails, and reduce the loss of the nutrient components of the nails; the anti-UV additive is a water-soluble or alcohol-soluble anti-UV agent and can protect the nails from being influenced by UV illumination; the base coat also comprises the enhanced filler, so that good film-forming cohesion can be provided by the enhanced filler and the high polymer resin, and the curing capability and stripping effect of the base coat are improved;
moreover, the techniques for peelable basecoats according to the prior art are generally of the emulsion or UV type, the emulsion type being poorly protective, for up to three days; UV-type removal is difficult, damaging the enamel of the nail; tests prove that the primer does not damage nails, is safe, non-toxic and free of UV irradiation, can be quickly cured at normal temperature, can achieve long-acting protection for 5-15 days, can be easily stripped and removed by directly soaking the nails in warm water (40-45 ℃) for 5-10 min when the primer needs to be stripped, does not need nail washing water for removal, and effectively protects the nails.
In summary, the invention includes at least one of the following beneficial technical effects:
the invention provides a first coat capable of peeling for nail care and a preparation method thereof, the method is simple, the first coat is safe and nontoxic, the first coat is safer and more convenient to coat, the nail care effect is good, and the first coat is naturally cured and is easy to peel; the primer coat can be cured at normal temperature without UV irradiation, can achieve long-acting protection for 5-15 days, can be easily stripped and removed in warm water (40-45 ℃) without damage after 5-15 days, and has high safety.
Detailed Description
The present invention is further explained with reference to the following specific examples, but it should be noted that the following examples are only illustrative of the present invention and should not be construed as limiting the present invention, and all technical solutions similar or equivalent to the present invention are within the scope of the present invention. Unless otherwise specified, the technical means used in the examples are conventional means well known to those skilled in the art, and the raw materials used are commercially available products.
In the following examples, some of the raw materials and manufacturers are shown in table 1:
TABLE 1
| Raw materials | Manufacturer and model |
| Alcohol-soluble polyamide resin | Pasteur Laropal A81 |
| Water-soluble keratin | Sai' an Wen bamboo Biotech Co., Ltd |
| Ethanol | Jiangyin gold ancient Special chemical Co Ltd |
| Mica powder | Lingshou county baofeng mica processing Co., Ltd |
Example 1
The strippable primer for nail care and protection comprises the following raw materials in parts by weight: 30% of alcohol-soluble polyamide resin; 50% of ethanol and 20% of water.
The preparation method of the strippable base coat for nail care and protection comprises the following steps:
s1, mixing ethanol and water in the weight ratio to form a mixed solution A;
s2, adding alcohol-soluble polyamide resin into the mixed solution A, and uniformly stirring to obtain transparent or semitransparent liquid, so as to obtain the nail-care and nail-protection base coat.
In this example, the alcohol soluble polyamide resin is a type of Pasteur alcohol soluble resin 1015K, with a molecular weight greater than 1000 daltons.
Example 2
The strippable primer for nail care and protection comprises the following raw materials in parts by weight: 40% of alcohol-soluble polyamide resin; 50% of ethanol and 10% of water.
The preparation method of the strippable base coat for nail care and protection comprises the following steps:
s1, mixing ethanol and water in the weight ratio to form a mixed solution A;
s2, adding alcohol-soluble polyamide resin into the mixed solution A, and uniformly stirring to obtain transparent or semitransparent liquid, so as to obtain the nail-care and nail-protection base coat.
In this example, the alcohol soluble polyamide resin is a type of Pasteur alcohol soluble resin 1015K, with a molecular weight greater than 1000 daltons.
Example 3
The strippable primer for nail care and protection comprises the following raw materials in parts by weight: 20% of alcohol-soluble polyamide resin; 75% of ethanol and 5% of water.
The preparation method of the strippable base coat for nail care and protection comprises the following steps:
s1, mixing ethanol and water in the weight ratio to form a mixed solution A;
s2, adding alcohol-soluble polyamide resin into the mixed solution A, and uniformly stirring to obtain transparent or semitransparent liquid, so as to obtain the nail-care and nail-protection base coat.
In this example, the alcohol soluble polyamide resin is a type of Pasteur alcohol soluble resin 1015K, with a molecular weight greater than 1000 daltons.
Example 4
The strippable primer for nail care and protection comprises the following raw materials in parts by weight:
10% of acrylic ester; 0.1% of water-soluble keratin; ultraviolet absorber UV 3260.1%; 74.8 percent of ethanol; 5% of water and 10% of mica powder.
The preparation method of the strippable base coat for nail care and protection comprises the following steps:
s1, mixing ethanol and water in the weight ratio to form a mixed solution A;
s2, adding acrylic ester, water-soluble keratin, an ultraviolet absorbent UV326 and mica powder into the mixed solution A, and uniformly stirring to obtain transparent or semitransparent liquid, thus obtaining the nail-care and nail-protection base coat.
Example 5
The strippable primer for nail care and protection comprises the following raw materials in parts by weight:
20% of alcohol-soluble polyamide resin; 1% of water-soluble keratin; ultraviolet absorber UV 3260.2%; 72.8 percent of ethanol; 1% of water and 5% of mica powder.
The preparation method of the strippable base coat for nail care and protection comprises the following steps:
s1, mixing ethanol and water in the weight ratio to form a mixed solution A;
s2, adding alcohol-soluble polyamide resin, water-soluble keratin, an ultraviolet absorbent UV326 and mica powder into the mixed solution A, and uniformly stirring to obtain transparent or semitransparent liquid, thus obtaining the nail-care and nail-protection primer coat.
In this example, the alcohol soluble polyamide resin is a type of Pasteur alcohol soluble resin 1015K, with a molecular weight greater than 1000 daltons.
Example 6
The strippable primer for nail care and protection comprises the following raw materials in parts by weight:
40% of alcohol-soluble polyamide resin; 0.2% of water-soluble keratin; ultraviolet absorber UV 3260.5%; 20% of ethanol; 20% of water and 19.3% of mica powder.
The preparation method of the strippable base coat for nail care and protection comprises the following steps:
s1, mixing ethanol and water in the weight ratio to form a mixed solution A;
s2, adding alcohol-soluble polyamide resin, water-soluble keratin, an ultraviolet absorbent UV326 and mica powder into the mixed solution A, and uniformly stirring to obtain transparent or semitransparent liquid, thus obtaining the nail-care and nail-protection primer coat.
In this example, the alcohol soluble polyamide resin is a type of Pasteur alcohol soluble resin 1015K, with a molecular weight greater than 1000 daltons.
Example 7
The strippable primer for nail care and protection comprises the following raw materials in parts by weight:
28.5 percent of alcohol-soluble polyamide resin; 0.5% of water-soluble keratin; ultraviolet absorber UV 3261%; 40% of ethanol; 20% of water and 10% of mica powder.
The preparation method of the strippable base coat for nail care and protection comprises the following steps:
s1, mixing ethanol and water in the weight ratio to form a mixed solution A;
s2, adding alcohol-soluble polyamide resin, water-soluble keratin, an ultraviolet absorbent UV326 and mica powder into the mixed solution A, and uniformly stirring to obtain transparent or semitransparent liquid, thus obtaining the nail-care and nail-protection primer coat.
In this example, the alcohol soluble polyamide resin is a type of Pasteur alcohol soluble resin 1015K, with a molecular weight greater than 1000 daltons.
Example 8
The strippable primer for nail care and protection comprises the following raw materials in parts by weight:
25% of alcohol-soluble polyamide resin; 0.1% of water-soluble keratin; ultraviolet absorber UV 3260.2%; 55% of ethanol; 7.7 percent of water and 12 percent of mica powder.
The preparation method of the strippable base coat for nail care and protection comprises the following steps:
s1, mixing ethanol and water in the weight ratio to form a mixed solution A;
s2, adding alcohol-soluble polyamide resin, water-soluble keratin, an ultraviolet absorbent UV326 and mica powder into the mixed solution A, and uniformly stirring to obtain transparent or semitransparent liquid, thus obtaining the nail-care and nail-protection primer coat.
In this example, the alcohol soluble polyamide resin is a type of Pasteur alcohol soluble resin 1015K, with a molecular weight greater than 1000 daltons.
Comparative example 1
The same as example 8, except that mica powder was not contained, the weight ratio of ethanol was 67%, and the other parameters and methods were the same as example 8.
Comparative example 2
The strippable primer for nail care and protection comprises the following raw materials in parts by weight:
50% of alcohol-soluble polyamide resin; 0.1% of water-soluble keratin; ultraviolet absorber UV 3260.2%; 27.7 percent of ethanol; 10% of water and 12% of mica powder. The preparation method of the nail-care strippable base coat is the same as that of the example 8.
Test examples and Property measurements
Selecting Miss Candy health oil (15ml, from Youfen network technologies, Inc. in Hangzhou) as control group I (without UV lamp irradiation); selecting a brand Color Rose water-based nail polish (10ml, Nippon snow lotus cosmetics Co., Ltd., Yiwu) as a control group II (without UV lamp irradiation), and selecting a brand Sweet Color nail polish (micro phototherapy) (12ml, from Lilai Ribes chemical Co., Ltd., Shanghai) as a control group III (UV lamp irradiation for 2 min); taking the first coat strippable primer for nail care prepared in the examples 1 to 8 and the comparative examples 1 to 2 of the invention as an experimental group 1 to 10 without UV lamp irradiation; products of a control group I, a control group II, a control group III and experimental groups 1-10 are coated on the surfaces of fingernails of the volunteers (10 volunteers are selected for each group), the volunteers perform daily life after coating, the edge dropping time (peeling and edge lifting phenomena) of the products of each group is observed during the period, and the average value of the edge dropping time is taken;
observing the curing time of each group according to a finger-touch method (curing the surface of each group of samples by pressing with a finger for a period of time, using tack-free as a standard for complete curing, and using the shortest time for each group of samples to be completely cured); the prepared products of each group are smeared on the surfaces of fingernails of the volunteers and are placed in warm water (40-45 degrees) for soaking for 5-10 min, 5 volunteers are selected for each group, and whether complete stripping can be carried out or not is observed in the period, and the results are shown in table 1.
TABLE 1
| Group of | Time to edge drop | Curing time | Soaking in warm water of 40-45 deg.C |
| Control group I | 3 days | 1 minute and 10 seconds | Can not be completely peeled off within 10min |
| Control group II | 1 day | 1 minute and 20 seconds | Can not be completely peeled off within 10min |
| Control group III | 1 day | 2 minutes and 40 seconds | Can not be completely peeled off within 10min |
| Experimental group 1 | 6 days | 50 seconds | Peeling off completely for 10min |
| Experimental group 2 | 5 days | 55 seconds | Peeling off completely for 10min |
| Experimental group 3 | 7 days | 53 seconds | Peeling off completely for 8min |
| Experimental group 4 | 10 days | 49 seconds | 6min complete stripping |
| Experimental group 5 | 11 days | 45 seconds | 6min complete stripping |
| Experimental group 6 | 14 days | 48 seconds | Peeling off completely for 5min |
| Experimental group 7 | 12 days | 42 seconds | Completely stripping within 6min |
| Experimental group 8 | 15 days | 40 seconds | Completely stripping within 5min |
| Experimental group 9 | 5 days | 1 minute | Less incomplete stripping in 10min |
| Experimental group 10 | 7 days | 1 minute | Peeling off completely for 10min |
As can be seen from the data in Table 1, compared with the control groups I-III, the nail-care and nail-protection articles prepared in the embodiments 1-8 of the present invention have the advantages of the edge peeling time of 15 days at most, longer protection time, no need of UV lamp irradiation, curing at normal temperature, only 40-50s of curing time, and easy peeling of the base coat.
The control groups I-III adopt emulsion type or UV type, and the emulsion type has poor protection performance for at most three days; UV-type stripping is difficult and can damage the enamel of the nail;
the experimental group 9 does not contain mica powder, the curing time is prolonged, the curing effect and the stripping effect are poor, the effect of the mica powder on the performance of the base coat is shown, the enhanced filler (mica powder) can cooperate with the high polymer resin to provide good film-forming cohesion, and the curing capability and the stripping effect of the base coat are improved; experiment group 10 changes the proportion of alcohol-soluble polyamide resin and ethanol, does not affect the edge dropping time, but the curing time is prolonged, which shows that the proper proportion of the base coat affects the curing time.
The data prove that the base coat does not damage the nails, is safe, non-toxic and free of UV irradiation, can be quickly cured at normal temperature, can achieve long-acting protection for 5-15 days, can be easily stripped and removed by directly soaking the nails in warm water (40-45 ℃) for 5-10 min when the base coat needs to be stripped, does not need nail washing water for removal, and effectively protects the nails.
The foregoing embodiments are merely illustrative of the principles and utilities of the present invention and are not intended to limit the invention. Any person skilled in the art can modify or change the above-mentioned embodiments without departing from the spirit and scope of the present invention. Accordingly, it is intended that all equivalent modifications or changes which can be made by those skilled in the art without departing from the spirit and technical spirit of the present invention be covered by the claims of the present invention.
Claims (5)
1. The strippable base coat for nail care and protection is characterized by comprising the following raw materials in parts by weight:
10-30% of high molecular resin; 0.1-1% of keratin; 0.1-1% of anti-UV auxiliary agent; 20-55% of alcohols; 1-20% of water and 5-20% of reinforced filler;
the high polymer resin is alcohol-soluble polyamide resin;
the reinforced filler is selected from mica powder;
the alcohol is selected from one of ethanol, propanol and n-butanol.
2. The bottom peel-off coat for nail care according to claim 1, which is characterized by comprising the following raw materials in percentage by weight: 10-20% of high molecular resin; 0.1-0.2% of keratin; 0.1 to 0.2 percent of anti-UV additive; 40-55% of alcohols; 1-5% of water and 5-10% of reinforced filler.
3. The nail care peelable primer coating according to claim 1 or claim 2, wherein the polymeric resin has a molecular weight of greater than 1000 daltons.
4. The nail care peelable bottom coat according to claim 1 or claim 2, wherein the keratin protein is a water-soluble keratin protein.
5. A process for preparing a primer strippable from nail care products according to any one of claims 1 to 4, which comprises the steps of:
s1, mixing the alcohols and water in the weight ratio to form a mixed solution A;
s2, adding the polymer resin, the keratin, the anti-UV auxiliary agent and the reinforced filler into the mixed solution A, and uniformly stirring to obtain transparent or semitransparent liquid, thus obtaining the nail-care strippable base coat.
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| CN202010935894.9A CN111939101B (en) | 2020-09-08 | 2020-09-08 | Strippable base coat for nail care and protection and preparation method thereof |
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| CN202010935894.9A CN111939101B (en) | 2020-09-08 | 2020-09-08 | Strippable base coat for nail care and protection and preparation method thereof |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4822423A (en) * | 1985-03-15 | 1989-04-18 | Shiseido Company Ltd. | Nail cosmetic composition |
| CN102552059A (en) * | 2012-02-16 | 2012-07-11 | 金华市科荣化工有限公司 | Nail polish with low stimulation |
| CN105963155A (en) * | 2016-06-14 | 2016-09-28 | 山西大学 | Nail polish capable of indicating stripping time and easy to remove |
| KR20170079367A (en) * | 2015-12-30 | 2017-07-10 | 주식회사 퓨라엠 | Conveniently removable aqueous enamel composition and a process for the preparation thereof |
| CN109998945A (en) * | 2019-04-17 | 2019-07-12 | 中山市美源化妆品有限公司 | A kind of aqueous, environmental protective nail polish and its manufacturing method |
-
2020
- 2020-09-08 CN CN202010935894.9A patent/CN111939101B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4822423A (en) * | 1985-03-15 | 1989-04-18 | Shiseido Company Ltd. | Nail cosmetic composition |
| CN102552059A (en) * | 2012-02-16 | 2012-07-11 | 金华市科荣化工有限公司 | Nail polish with low stimulation |
| KR20170079367A (en) * | 2015-12-30 | 2017-07-10 | 주식회사 퓨라엠 | Conveniently removable aqueous enamel composition and a process for the preparation thereof |
| CN105963155A (en) * | 2016-06-14 | 2016-09-28 | 山西大学 | Nail polish capable of indicating stripping time and easy to remove |
| CN109998945A (en) * | 2019-04-17 | 2019-07-12 | 中山市美源化妆品有限公司 | A kind of aqueous, environmental protective nail polish and its manufacturing method |
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