CN105963155A - Nail polish capable of indicating stripping time and easy to remove - Google Patents

Nail polish capable of indicating stripping time and easy to remove Download PDF

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Publication number
CN105963155A
CN105963155A CN201610414273.XA CN201610414273A CN105963155A CN 105963155 A CN105963155 A CN 105963155A CN 201610414273 A CN201610414273 A CN 201610414273A CN 105963155 A CN105963155 A CN 105963155A
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China
Prior art keywords
solution
ethanol
acid
nail polish
nial polish
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Granted
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CN201610414273.XA
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CN105963155B (en
Inventor
梁中远
宋胜梅
董川
双少敏
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Shanxi University
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Shanxi University
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Publication of CN105963155A publication Critical patent/CN105963155A/en
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/23Sulfur; Selenium; Tellurium; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25Silicon; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/466Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/4973Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8129Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers or esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers, e.g. polyvinylmethylether
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q3/00Manicure or pedicure preparations
    • A61Q3/02Nail coatings

Abstract

The invention provides nail polish capable of indicating stripping time and easy to remove. The nail polish is prepared from an acid-base indicator solution, ethanol, a proper quantity of a color developing agent solution, filler, pearl powder, a film-forming agent PVB and a film-forming agent PVP. According to a preparation method, the acid-base indicator solution is prepared firstly and then added into ethanol, pH is regulated with an ethanol solution of a color developing agent, and an indicator is made to develop color; the film-forming agent PVB is added into the solution, and the mixture is stirred to be completely dissolved; the filler is added, the mixture is stirred to be uniform, the pearl powder is added, the mixture is stirred to be uniform, the film-forming agent PVP is added lastly, the mixture is stirred to be uniform, and the nail polish is prepared. The preparation method is simple, the nail polish is safe in use, a plasticizer harmful to a human body is not contained, a toxic, low-toxicity and irritant solvent is not used, harm to the body can be reduced obviously, and nanoscale silicon dioxide enables the nail polish to have a certain ultraviolet resisting function. Particularly, the nail polish has the function of indicating stripping time and is convenient for people to clean and change.

Description

A kind of nial polish being prone to remove that can indicate stripping opportunity
Technical field:
The present invention relates to nial polish, particularly belong to a kind of nial polish being prone to remove that can indicate stripping opportunity.
Background technology:
The most common nial polish many uses nitrocellulose is film former, and phthalate ester is plasticizer, acetoneand ethyl acetate For solvent, its major defect is: the nitrocellulose as nial polish film former is inflammable and explosive dangerous goods, produces and makes recruitment Journey has the biggest danger;The plasticizers such as phthalate ester can affect the fertility of people, is detrimental to health;Acetone and acetic acid second Ester makees solvent, has certain toxicity and zest;Nial polish wants after coating to remove, it is necessary to containing multiple organic solvent Cleaner is wiped, in-convenience in use, often washing first can health risk.
The development trend of nial polish is: film former stabilisation, does not use the inflammable and explosive film former such as nitrocellulose;Nontoxic solvent, Do not use the low toxicity zest solvent such as acetone, ethyl acetate;Without plasticizer;Organic solvent is not used to get final product removal after smearing.
Patent application CN1260167A is with nitrocellulose as film former, although can obtain good film-forming property, wear-resisting nial polish, But nitrocellulose is inflammable and explosive, stores and use process hazard big, being unfavorable for sustainable development.Patent application CN 102397198 A is with ethyl acetate, acetone etc. as solvent, and the allotment of such formula is proper can obtain high glaze, strong adhesive force and strong resistance to water Nial polish, but have a disadvantage in that 1, there is penetrating odor, strong pungent abnormal smells from the patient can cause uncomfortable after sucking;2、 After using, fingernail and skin irritation to human body are relatively big, and life-time service has bigger injury;3, contact chemical fibre class medicated clothing and general Plastics all can cause dissolubility to corrode.Patent CN 100346770 C stirs with additives such as water, Watery film-fomer, pigment and spice Mix and mix.Such formula allotment proper obtain low abnormal smells from the patient, low irritant, high glaze, will not to chemical fibre clothes and plastics The nial polish of dissolubility corrosion, but have a disadvantage in that 1, poor water resistance, meet the water capacity easy to fall off;2, adhesive force is bad, with There is a big difference for organic solvent type nial polish ratio.
Patent application CN 105476879 A of this seminar uses PVB and PVP to be film former, and ethanol is solvent, prepares The most strippable nial polish of immersion in water.But this nial polish splitting time under different water temperature conditions is different, and user is not known When road is most preferably to peel off checkout time, so can cause user waste of time, have suitable inconvenience.
Summary of the invention:
It is an object of the invention to provide a kind of nial polish being prone to remove that can indicate stripping opportunity and preparation method thereof.This fingernail Oil does not use nitrocellulose as film former, makes production accumulating safer;Without the zest solvents such as acetoneand ethyl acetate, nothing Penetrating odor and toxicity;Nial polish has certain water proofing property after being coated on fingernail, will not be wiped when daily washing one's hands Remove, dissolve;Meanwhile, this nial polish should have the function on instruction stripping opportunity, i.e. nial polish and is coated on fingernail and soaks one in water Will indicate after fixing time and completely strip the best opportunity removing nial polish, to be convenient for people to clean conversion.
A kind of nial polish being prone to remove that can indicate stripping opportunity that the present invention provides, its component counts by weight and includes: acid Neutralization indicator solution 1-10, ethanol 75-90, chromogenic reagent solution is appropriate, filler 0.5-1.5, pearl essence 0.3-0.5, film former PVB 6-20, film former PVP 0.3-3.
Described nial polish, can also include the spice of 0.01-0.03, such as: meta-methoxy cinnamic acid etc. in its component.
The described water that acid-base indicator solution is acid-base indicator and/or the solution of ethanol.
Described acid-base indicator is methyl orange (to dimethylaminoazobenzene sodium sulfonate), bromophenol blue (3,3 ', 5,5 '-tetrabromo-benzene Phenolsulfonphthalein), Congo red (diphenyl-4,4 '-two (azo-2-)-1-amino naphthalenes-4-sodium sulfonate), bromocresol green (3,3 ', 5, 5 '-tetrabromo metacresol sulphonyl phthalein), thymolphthalein (3,3-double (4-hydroxyl-5-isopropyl-2-aminomethyl phenyl)-Phthalides).
Described filler is nanometer grade silica;
Described chromogenic reagent solution is the ethanol solution of the developer of 1mol/L;Described developer is soluble in ethanol and/or water Acid or alkali, such as sulphuric acid or sodium hydroxide;
The preparation method of a kind of nial polish that the present invention provides, comprises the steps: first preparating acid neutralization indicator solution, by above-mentioned Composition weight number proportioning, then acid-base indicator solution is joined in ethanol, regulate pH with the ethanol solution of developer, make finger Show that agent develops the color.Adding in above-mentioned solution by film former PVB again, stirring is completely dissolved to it.Add filler afterwards, stir 10 Minute, add pearl essence, stir 30-40min, be eventually adding film former PVP, stir 20 minutes, can be prepared by product. Can also select to add spice, after adding spice, continue stirring 5 minutes.
The present invention is with ethanol as solvent, PVB and PVP is film former, and use acid-base indicator is colorant, is allowed to become at regulation pH Nial polish it is prepared as after color.After nial polish is coated with and wipes, being immersed in the water by finger, the PVP in film former dissolves, and makes nial polish PH change, and then cause acid-base indicator variable color or fade, thus illustrating that nial polish can be peeled off.
Manufacture method of the present invention is simple, and product uses safety, without harmful plasticizer, do not use poisonous, low toxicity with And zest solvent, can obviously reduce the injury to fingernail, the use of nanometer grade silica makes nial polish have certain resisting The function of ultraviolet.Particularly relate to have after nail polish soaks several minutes in water and fade or the instruction function of variable color, at this moment can depend on According to nial polish fade or discoloration completely removes, it is simple to clean conversion, the most attractive in appearance of fingernail can be kept at any time.
Detailed description of the invention:
Embodiment 1:
First methyl orange is configured to the aqueous solution of 1g/L, then 0.5ml methyl orange solution is joined in 20ml ethanol, then drip Add the ethanol solution of the sulphuric acid of 1mol/L, to the aobvious redness of methyl orange.Again 2g film former PVB is added in above-mentioned solution, stirring It is completely dissolved to it.Add filler 0.2g nanometer grade silica afterwards, stir 10 minutes, add 0.1g pearl essence, stir Mixing 30-40min, be eventually adding 0.2g film former PVP, stir 20 minutes, gained is red nail polish.
Red nail polish is coated onto on fingernail, after being completely dried, finger is immersed in tap water, after nial polish becomes yellow i.e. Can completely strip.
Embodiment 2:
First 1g bromophenol blue is dissolved in the water of 1L: in the solution of ethanol=8:2 (volume ratio), then by 0.5ml bromophenol blue solution Join in 20ml ethanol, then drip the ethanol solution of the sulphuric acid of 1mol/L, to bromophenol blue displaing yellow.Again by 2g film former PVB adds in above-mentioned solution, and stirring is completely dissolved to it.Add filler 0.2g nanometer grade silica afterwards, stir 10 minutes, Adding 0.1g pearl essence, stir 30-40min, be eventually adding 0.2g film former PVP, stir 20 minutes, gained is yellow Nial polish.
Yellow nial polish is coated onto on fingernail, after being completely dried, finger is immersed in tap water, after nial polish becomes blueness i.e. Can completely strip.
Embodiment 3:
First Congo red is configured to the aqueous solution of 1g/L, then goes 0.5ml Congo red solution to join in 20ml ethanol, then drip Add the ethanol solution of the sulphuric acid of 1mol/L, show purple to Congo red.Again 2g film former PVB is added in above-mentioned solution, stirring It is completely dissolved to it.Add filler 0.2g nanometer grade silica afterwards, stir 10 minutes, add 0.1g pearl essence, stir Mixing 30-40min, be eventually adding 0.2g film former PVP, stir 20 minutes, gained is purple nail polish.
Purple nail polish is coated onto on fingernail, after being completely dried, finger is immersed in tap water, after nial polish becomes redness i.e. Can completely strip.
Embodiment 4:
First thymolphthalein is configured to the ethanol solution of 1g/L, then goes 0.5ml thymolphthalein solution to join in 20ml ethanol, Then the ethanol solution of the sodium hydroxide of 1mol/L is dripped, to the aobvious blueness of thymolphthalein.Again 2g film former PVB is added above-mentioned In solution, stirring is completely dissolved to it.Add filler 0.2g nanometer grade silica afterwards, stir 10 minutes, add 0.1g Pearl essence, stirs 30-40min, is eventually adding 0.2g film former PVP, stirs 20 minutes, and gained is blue nail polish.
Blue nail polish is coated onto on fingernail, after being completely dried, finger is immersed in tap water, can be complete after nial polish fades Whole stripping.
Embodiment 5:
First methyl orange is configured to the aqueous solution of 1g/L, then 0.5ml methyl orange solution is joined in 20ml ethanol, then drip Add the ethanol solution of the sulphuric acid of 1mol/L, to the aobvious redness of methyl orange.Again 2g film former PVB is added in above-mentioned solution, stirring It is completely dissolved to it.Add filler 0.2g nanometer grade silica afterwards, stir 10 minutes, add 0.1g pearl essence, stir Mix 30-40min, be eventually adding 0.2g film former PVP, stir 20 minutes, add 0.0025g meta-methoxy cinnamic acid, Stir 5 minutes.Gained is fragrant red nail polish.
Red nail polish is coated onto on fingernail, after being completely dried, finger is immersed in tap water, after nial polish becomes yellow i.e. Can completely strip.
Embodiment 6:
First 0.1g bromophenol blue is dissolved in the water of 1L: in the solution of ethanol=8:2 (volume ratio), then by molten for 0.5ml bromophenol blue Liquid joins in 20ml ethanol, then drips the ethanol solution of the sulphuric acid of 1mol/L, to bromophenol blue displaing yellow.Again by 2g film forming Agent PVB adds in above-mentioned solution, and stirring is completely dissolved to it.Add filler 0.2g nanometer grade silica afterwards, stir 10 Minute, add 0.1g pearl essence, stir 30-40min, be eventually adding 0.2g film former PVP, stir 20 minutes, then add Enter 0.0025g meta-methoxy cinnamic acid, stir 5 minutes.Gained is fragrant yellow nial polish.
Yellow nial polish is coated onto on fingernail, after being completely dried, finger is immersed in tap water, after nial polish becomes blueness i.e. Can completely strip.
Embodiment 7:
First Congo red is configured to the aqueous solution of 1g/L, then goes 0.5ml Congo red solution to join in 20ml ethanol, then drip Add the ethanol solution of the sulphuric acid of 1mol/L, show purple to Congo red.Again 2g film former PVB is added in above-mentioned solution, stirring It is completely dissolved to it.Add filler 0.2g nanometer grade silica afterwards, stir 10 minutes, add 0.1g pearl essence, stir Mix 30-40min, be eventually adding 0.2g film former PVP, stir 20 minutes, add 0.0025g meta-methoxy cinnamic acid, Stir 5 minutes.Gained is fragrant purple nail polish.
Purple nail polish is coated onto on fingernail, after being completely dried, finger is immersed in tap water, after nial polish becomes redness i.e. Can completely strip.
Embodiment 8:
First thymolphthalein is configured to the ethanol solution of 1g/L, then goes 0.5ml thymolphthalein solution to join in 20ml ethanol, Then the ethanol solution of the sodium hydroxide of 1mol/L is dripped, to the aobvious blueness of thymolphthalein.Again 2g film former PVB is added above-mentioned In solution, stirring is completely dissolved to it.Add filler 0.2g nanometer grade silica afterwards, stir 10 minutes, add 0.1g Pearl essence, stirs 30-40min, is eventually adding 0.2g film former PVP, stirs 20 minutes, add methoxy between 0.0025g Base cinnamic acid, stirs 5 minutes.Gained is fragrant blue nail polish.
Blue nail polish is coated onto on fingernail, after being completely dried, finger is immersed in tap water, can be complete after nial polish fades Whole stripping.

Claims (5)

1. the nial polish being prone to remove that can indicate stripping opportunity, it is characterised in that component is counted by weight and included: acid Neutralization indicator solution 1-10, ethanol 75-90, chromogenic reagent solution is appropriate, filler 0.5-1.5, pearl essence 0.3-0.5, film former PVB 6-20, film former PVP 0.3-3;
The described water that acid-base indicator solution is acid-base indicator and/or the solution of ethanol;
Described acid-base indicator is methyl orange, bromophenol blue, Congo red, bromocresol green or thymolphthalein;
Described chromogenic reagent solution is the ethanol solution of developer;Described developer is soluble in ethanol and/or the acid of water or alkali.
A kind of nial polish being prone to remove that can indicate stripping opportunity the most as claimed in claim 1, it is characterised in that described Developer is sulphuric acid or sodium hydroxide.
A kind of nial polish being prone to remove that can indicate stripping opportunity the most as claimed in claim 1, it is characterised in that described Filler is nanometer grade silica.
4. a kind of nial polish being prone to remove that can indicate stripping opportunity as described in claim 1,2 or 3, it is characterised in that Described nial polish, its component also includes the spice of 0.01-0.03.
The preparation method of a kind of nial polish being prone to remove that can indicate stripping opportunity the most as claimed in claim 1, its feature exists In, comprise the steps: first preparating acid neutralization indicator solution, by described composition weight number proportioning, by acid-base indicator solution Join in ethanol, regulate pH with the ethanol solution of developer, make indicator develop the color;Again film former PVB is added above-mentioned solution In, stirring is completely dissolved to it;Add filler afterwards, stir 10 minutes, add pearl essence, stir 30-40min, Rear addition film former PVP, stirs 20 minutes, can be prepared by product.
CN201610414273.XA 2016-06-14 2016-06-14 A kind of nail polish for being easy to remove that can indicate removing opportunity Expired - Fee Related CN105963155B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111939101A (en) * 2020-09-08 2020-11-17 广州至然科技应用有限公司 Strippable base coat for nail care and protection and preparation method thereof

Citations (4)

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Publication number Priority date Publication date Assignee Title
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CN101795944A (en) * 2007-07-05 2010-08-04 陶氏环球技术公司 Dissolvable film with measuring ability
CN102793637A (en) * 2011-05-25 2012-11-28 财团法人纺织产业综合研究所 Skin care product with prompt function and use method thereof
CN105476879A (en) * 2016-01-06 2016-04-13 山西大学 Nail polish and preparation method thereof

Patent Citations (4)

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Publication number Priority date Publication date Assignee Title
CN101478876A (en) * 2006-03-28 2009-07-08 佐治亚-太平洋消费产品有限合伙公司 Anti-microbial hand towel with time-delay chromatic transfer indicator and absorbency rate delay
CN101795944A (en) * 2007-07-05 2010-08-04 陶氏环球技术公司 Dissolvable film with measuring ability
CN102793637A (en) * 2011-05-25 2012-11-28 财团法人纺织产业综合研究所 Skin care product with prompt function and use method thereof
CN105476879A (en) * 2016-01-06 2016-04-13 山西大学 Nail polish and preparation method thereof

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111939101A (en) * 2020-09-08 2020-11-17 广州至然科技应用有限公司 Strippable base coat for nail care and protection and preparation method thereof
CN111939101B (en) * 2020-09-08 2021-03-30 广州至然科技应用有限公司 Strippable base coat for nail care and protection and preparation method thereof

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