CN107474729A - A kind of mould proof anti-fouling agent in Ceramic Tiles surface - Google Patents
A kind of mould proof anti-fouling agent in Ceramic Tiles surface Download PDFInfo
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- CN107474729A CN107474729A CN201710620314.5A CN201710620314A CN107474729A CN 107474729 A CN107474729 A CN 107474729A CN 201710620314 A CN201710620314 A CN 201710620314A CN 107474729 A CN107474729 A CN 107474729A
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- mould proof
- agent
- ceramic tiles
- mould
- proof anti
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1675—Polyorganosiloxane-containing compositions
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/43—Compounds containing sulfur bound to nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/45—Heterocyclic compounds having sulfur in the ring
- C08K5/46—Heterocyclic compounds having sulfur in the ring with oxygen or nitrogen in the ring
- C08K5/47—Thiazoles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/541—Silicon-containing compounds containing oxygen
- C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond
- C08K5/5419—Silicon-containing compounds containing oxygen containing at least one Si—O bond containing at least one Si—C bond
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Plant Pathology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of mould proof anti-fouling agent in Ceramic Tiles surface, and it is with water as solvent, and its mould proof antifouling active ingredient accounts for the 15~20% of gross mass, and the mould proof antifouling active ingredient includes mould inhibitor, silicones, silane coupler and curing agent.The present invention promotes ceramic base material to assign its fungicidal properties in the bonding force and curing rate of silicones, while by adding mould inhibitor by the silane coupler in mould proof antifouling active ingredient and curing agent.Active ingredient accounts for the 15~20% of gross mass in the present invention, substantially increases its permeability and levelability.
Description
Technical field
Ceramic brick surface inorganic agent field of the present invention, more particularly to a kind of mould proof anti-fouling agent in Ceramic Tiles surface.
Background technology
Ceramic Tiles smooth appearance is attractive in appearance, however its have one it is fatal the shortcomings that, be exactly anti-pollution ability.Ceramic Tiles make
Used time, easily contaminated thing (such as ink, paint, tea, cement, rubber etc.) polluted.Therefore Ceramic Tiles how are effectively improved to prevent
Dirty ability, strengthen Ceramic Tiles competitiveness in the market, it has also become the problem of each manufacturer is extremely urgent.
The defects of for Ceramic Tiles antifouling property difference, probably there are three kinds of methods to improve its antifouling capacity：1st, ceramic tile is adjusted
Formula, high temp glass is mutually increased, kaolin residue is brilliant to be reduced；2nd, cover-coat enamel formula is adjusted, reduces cover-coat enamel apparent porosity；3、
Anti-fouling agent is applied in ceramic brick surface.Due to many disadvantages of first two method, in the market mainly to be applied in ceramic brick surface
The mode of anti-fouling agent is come antifouling.However, existing anti-fouling agent antifouling capacity on the market is not good enough, while function is single, often in ceramics
Other performance of the ceramic brick surface in addition to antifouling property just can not be assigned after coating one layer of anti-fouling agent on brick, thus greatly limit
The application of anti-fouling agent.
The content of the invention
It is an object of the invention to for above-mentioned the deficiencies in the prior art, there is provided a kind of Ceramic Tiles surface is mould proof antifouling
Agent, it is with excellent antifouling and fungicidal properties.
The technical solution used in the present invention is：A kind of mould proof anti-fouling agent in Ceramic Tiles surface, with water as solvent, it is anti-for it
Mould antifouling active ingredient accounts for the 15~20% of gross mass, and it is even that the mould proof antifouling active ingredient includes mould inhibitor, silicones, silane
Join agent and curing agent.
As the further improvement of such scheme, the mould proof antifouling active ingredient includes mould inhibitor by mass percentage
25~35%, silicones 30~50%, silane coupler 10~20% and curing agent 10~20%.
As the further improvement of such scheme, it is sub- that the mould inhibitor is selected from N- (trichloromethylthio) phthalyl
Amine, N- (trichloromethylthio) -4- cyclohexene -1,2- dicarboximide, N- (fluorine dichloromethyl is thio) phthalimide,
Benzimidazole methyl carbamate, 2-alkyl-4-isothiazolin-3-ones, 1,2- BITs and its N- alkyl derivatives
Thing, 5,6- dichloro benzo oxazolines ketone, 2- (4- thiazolyls) benzimidazole, Striazine derivative, 2-mercaptobenzothiazole, 8- hydroxyls
At least one of base quinoline.
As the further improvement of such scheme, the silane coupler is methyl trifluoro propyl dimethoxysilane.
As the further improvement of such scheme, the curing agent is selected from ethylenediamine or N-Nitrosodiethylamine.
As the further improvement of such scheme, the mould proof anti-fouling agent also includes the emulsifying agent for accounting for gross mass 0.5~5%.
As the further improvement of such scheme, the hydrophilic lipophilic balance of the emulsifying agent is 11~12.
The beneficial effects of the invention are as follows：
The present invention promotes ceramic base material in silicones by the silane coupler in mould proof antifouling active ingredient and curing agent
Bonding force and curing rate, while assign its fungicidal properties by adding mould inhibitor.Active ingredient accounts for gross mass in the present invention
15~20%, substantially increase its permeability and levelability.
The present invention has to ink, rubber print, red ink paste and oil pen shows excellent antifouling property, and it burns till
Product inherent quality and the key technical indexes such as presentation quality meet national standard GB/T 4100-2006《Ceramic Tiles》, national standard
GB6566-2010《Radioactive material radionuclides limitation》、HJ/T 297-2006《Environmental labelling product technical requirements Ceramic Tiles》
With EN 101：1992《The assay method of ceramic floor brick and walltile surface Mohs scratch hardness》Technical requirement.
Embodiment
The present invention is specifically described with reference to embodiment, in order to art personnel to the present invention
Understand.It is necessary that herein the present invention will be further described it is emphasized that embodiment is only intended to, it is impossible to be interpreted as to this
The limitation of invention protection domain, art person skilled in the art, the non-intrinsically safe made according to foregoing invention content to the present invention
The modifications and adaptations of property, should still fall within protection scope of the present invention.Simultaneously following mentioned raw materials are unspecified, are
Commercially available prod；The processing step or preparation method not referred in detail be processing step known to a person skilled in the art or
Preparation method.
Embodiment 1
A kind of mould proof anti-fouling agent in Ceramic Tiles surface, it accounts for gross mass with water as solvent, its mould proof antifouling active ingredient
15%, the mould proof antifouling active ingredient includes mould inhibitor, silicones, silane coupler and curing agent.The mould proof anti-fouling agent is also
Emulsifying agent including accounting for gross mass 0.5%.
Wherein, the mould proof antifouling active ingredient includes mould inhibitor 35%, silicones 30%, silane by mass percentage
Coupling agent 15% and curing agent 20%；The mould inhibitor is selected from N- (trichloromethylthio) phthalimide, N- (three chloromethanes
Base is thio) mixture of -4- cyclohexene -1,2- dicarboximide and N- (fluorine dichloromethyl is thio) phthalimide；Institute
It is methyl trifluoro propyl dimethoxysilane to state silane coupler；The curing agent is ethylenediamine；The hydrophilic parent of the emulsifying agent
Oily equilibrium valve is 11.
Embodiment 2
A kind of mould proof anti-fouling agent in Ceramic Tiles surface, it accounts for gross mass with water as solvent, its mould proof antifouling active ingredient
20%, the mould proof antifouling active ingredient includes mould inhibitor, silicones, silane coupler and curing agent.The mould proof anti-fouling agent is also
Emulsifying agent including accounting for gross mass 5%.
Wherein, the mould proof antifouling active ingredient includes mould inhibitor 25%, silicones 50%, silane by mass percentage
Coupling agent 10% and curing agent 15%；The mould inhibitor is selected from 2- (4- thiazolyls) benzimidazole, Striazine derivative, 2- sulfydryls
The mixture of benzothiazole and 8-hydroxyquinoline；The silane coupler is methyl trifluoro propyl dimethoxysilane；It is described solid
Agent is N-Nitrosodiethylamine；The hydrophilic lipophilic balance of the emulsifying agent is 12.
Embodiment 3
A kind of mould proof anti-fouling agent in Ceramic Tiles surface, it accounts for gross mass with water as solvent, its mould proof antifouling active ingredient
18%, the mould proof antifouling active ingredient includes mould inhibitor, silicones, silane coupler and curing agent.The mould proof anti-fouling agent is also
Emulsifying agent including accounting for gross mass 3%.
Wherein, the mould proof antifouling active ingredient includes mould inhibitor 30%, silicones 40%, silane by mass percentage
Coupling agent 20% and curing agent 10%；The mould inhibitor is 2-alkyl-4-isothiazolin-3-ones；The silane coupler is first
Base trifluoro propyl dimethoxysilane；The curing agent is N-Nitrosodiethylamine；The hydrophilic lipophilic balance of the emulsifying agent
For 11.
The ceramic brick product that mould proof anti-fouling agent using the gained of above-described embodiment 1~3 is burnt till carries out properties detection,
It meets national standard GB/T 4100-2006《Ceramic Tiles》, national standard GB6566-2010《Radioactive material radionuclides limitation》、HJ/
T297-2006《Environmental labelling product technical requirements Ceramic Tiles》With EN 101：1992《Ceramic floor brick and walltile surface Mohs
The assay method of scratch hardness》Technical requirement.Wherein：
1. surface quality without collide with, crackle and slag, without other open defects, high-class product；
2. water absorption rate：0.02%, breakdown strength：2502N；
3. the modulus of rupture：42Mpa；
4. soluble lead content：＜ 0.78mg/kg, (standard≤20) are qualified；
5. solubility is every cadmium content：＜ 0.05mg/kg, (standard≤5) are qualified；
6. Mohs intensity：6 grades；
Above-described embodiment is the preferred embodiments of the present invention, all with similar technique of the invention and the equivalence changes made,
The protection category of the present invention all should be belonged to.
Claims (7)
- A kind of 1. mould proof anti-fouling agent in Ceramic Tiles surface, it is characterised in that：With water as solvent, its mould proof antifouling active ingredient accounts for always The 15~20% of quality, the mould proof antifouling active ingredient include mould inhibitor, silicones, silane coupler and curing agent.
- A kind of 2. mould proof anti-fouling agent in Ceramic Tiles surface according to claim 1, it is characterised in that：Described mould proof antifouling have Imitate composition includes mould inhibitor 25~35%, silicones 30~50%, silane coupler 10~20% and consolidates by mass percentage Agent 10~20%.
- A kind of 3. mould proof anti-fouling agent in Ceramic Tiles surface according to claim 1 or 2, it is characterised in that：The mould inhibitor Selected from N- (trichloromethylthio) phthalimide, N- (trichloromethylthio) -4- cyclohexene -1,2- dicarboximide, N- (fluorine dichloromethyl is thio) phthalimide, benzimidazole methyl carbamate, 2-alkyl-4-isothiazolin-3-ones, 1,2- BIT and its N- alkyl derivatives, 5,6- dichloro benzo oxazolines ketone, 2- (4- thiazolyls) benzimidazole, At least one of Striazine derivative, 2-mercaptobenzothiazole, 8-hydroxyquinoline.
- A kind of 4. mould proof anti-fouling agent in Ceramic Tiles surface according to claim 1 or 2, it is characterised in that：The silane is even Connection agent is methyl trifluoro propyl dimethoxysilane.
- A kind of 5. mould proof anti-fouling agent in Ceramic Tiles surface according to claim 1 or 2, it is characterised in that：The curing agent Selected from ethylenediamine or N-Nitrosodiethylamine.
- A kind of 6. mould proof anti-fouling agent in Ceramic Tiles surface according to claim 1, it is characterised in that：The mould proof anti-fouling agent is also Emulsifying agent including accounting for gross mass 0.5~5%.
- A kind of 7. mould proof anti-fouling agent in Ceramic Tiles surface according to claim 6, it is characterised in that：The parent of the emulsifying agent Hydrophile-lipophile balance value is 11~12.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710620314.5A CN107474729A (en) | 2017-07-26 | 2017-07-26 | A kind of mould proof anti-fouling agent in Ceramic Tiles surface |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710620314.5A CN107474729A (en) | 2017-07-26 | 2017-07-26 | A kind of mould proof anti-fouling agent in Ceramic Tiles surface |
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| Publication Number | Publication Date |
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| CN107474729A true CN107474729A (en) | 2017-12-15 |
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| CN201710620314.5A Pending CN107474729A (en) | 2017-07-26 | 2017-07-26 | A kind of mould proof anti-fouling agent in Ceramic Tiles surface |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111233373A (en) * | 2020-02-25 | 2020-06-05 | 清远戈兰迪高分子材料有限公司 | Mildew-proof building material, preparation method thereof and bathroom product |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101613574A (en) * | 2009-07-28 | 2009-12-30 | 佛山市柯林瓷砖护理用品有限公司 | Water-based polished tile anti-fouling liquid |
| CN102911597A (en) * | 2012-10-23 | 2013-02-06 | 江苏博特新材料有限公司 | Environment-friendly coating for protecting bare concrete and preparation method thereof |
| CN103013289A (en) * | 2012-11-28 | 2013-04-03 | 天长市开林化工有限公司 | Preparation method of coating for renovating building exterior wall tiles |
| CN103897444A (en) * | 2014-03-04 | 2014-07-02 | 北京远科宏大石油技术开发有限公司 | Lightweight high-temperature and high-emissivity ceramic paint |
| CN104356833A (en) * | 2014-11-26 | 2015-02-18 | 江苏博腾新材料股份有限公司 | Antifouling water-based latex coating |
| CN105542602A (en) * | 2016-01-18 | 2016-05-04 | 广东龙湖科技股份有限公司 | Double-component coating for renovating exterior wall tile |
| CN105694692A (en) * | 2014-11-27 | 2016-06-22 | 合众（佛山）化工有限公司 | A preparing method of waterborne two-component high-temperature resistant super-wear-resistant matte varnish |
| CN106398519A (en) * | 2016-10-12 | 2017-02-15 | 贵州卓霖节能环保科技发展有限公司 | High-permeability waterproof coating and preparation method and application thereof |
| CN106893426A (en) * | 2017-04-27 | 2017-06-27 | 贵州无界建筑设计装饰工程有限公司 | A kind of coating for bathroom and preparation method thereof |
-
2017
- 2017-07-26 CN CN201710620314.5A patent/CN107474729A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101613574A (en) * | 2009-07-28 | 2009-12-30 | 佛山市柯林瓷砖护理用品有限公司 | Water-based polished tile anti-fouling liquid |
| CN102911597A (en) * | 2012-10-23 | 2013-02-06 | 江苏博特新材料有限公司 | Environment-friendly coating for protecting bare concrete and preparation method thereof |
| CN103013289A (en) * | 2012-11-28 | 2013-04-03 | 天长市开林化工有限公司 | Preparation method of coating for renovating building exterior wall tiles |
| CN103897444A (en) * | 2014-03-04 | 2014-07-02 | 北京远科宏大石油技术开发有限公司 | Lightweight high-temperature and high-emissivity ceramic paint |
| CN104356833A (en) * | 2014-11-26 | 2015-02-18 | 江苏博腾新材料股份有限公司 | Antifouling water-based latex coating |
| CN105694692A (en) * | 2014-11-27 | 2016-06-22 | 合众（佛山）化工有限公司 | A preparing method of waterborne two-component high-temperature resistant super-wear-resistant matte varnish |
| CN105542602A (en) * | 2016-01-18 | 2016-05-04 | 广东龙湖科技股份有限公司 | Double-component coating for renovating exterior wall tile |
| CN106398519A (en) * | 2016-10-12 | 2017-02-15 | 贵州卓霖节能环保科技发展有限公司 | High-permeability waterproof coating and preparation method and application thereof |
| CN106893426A (en) * | 2017-04-27 | 2017-06-27 | 贵州无界建筑设计装饰工程有限公司 | A kind of coating for bathroom and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111233373A (en) * | 2020-02-25 | 2020-06-05 | 清远戈兰迪高分子材料有限公司 | Mildew-proof building material, preparation method thereof and bathroom product |
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Application publication date: 20171215 |
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