CN105542602A - Double-component coating for renovating exterior wall tile - Google Patents
Double-component coating for renovating exterior wall tile Download PDFInfo
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- CN105542602A CN105542602A CN201610030440.0A CN201610030440A CN105542602A CN 105542602 A CN105542602 A CN 105542602A CN 201610030440 A CN201610030440 A CN 201610030440A CN 105542602 A CN105542602 A CN 105542602A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1675—Polyorganosiloxane-containing compositions
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention provides a double-component coating for renovating an exterior wall tile. The double-component coating comprises a component A and a component B at a weight ratio of (55-60):(40-45), wherein the component A comprises the following substances in parts by weight: 30-40 parts of crylic acid waterproof emulsion, 5-10 parts of organic silicon emulsion, 0.1-0.3 part of a thickening agent, 0.5-1.5 parts of a dispersing agent, 0.05-0.15 part of a moistening agent, 0.1-0.3 part of an adhesion promoter, 0.4-0.6 part of a mildew preventive, 0.4-0.6 part of a defoaming agent, 1-1.5 parts of a filming additive, 2.0-3.0 parts of a cosolvent and 4-5 parts of water; the crylic acid waterproof emulsion is acrylate latex; the component B comprises the following substances in parts by weight: 5-10 parts of titanium dioxide, 8-15 parts of quartz powder and 20-25 parts of white cement. The double-component coating provided by the invention is high in adhesion property, hardness, waterproof property and color retention property, can directly coat base materials with smooth surfaces, in a rolling or brushing manner, such as a ceramic tile and stone, is not only easy to construct, but also capable of keeping a wall body bright and attractive for a long time, and is particularly applicable to renovation of the exterior wall tile; no water is needed, and the component A and the component B only need to be sufficiently mixed and uniformly stirred.
Description
Technical field
The present invention relates to a kind of coating, particularly relate to a kind of coating carrying out renovating for External Wall, more specifically relate to a kind of two-component coating carrying out renovating for External Wall ceramic tile.
Background technology
Along with the high speed development of Chinese Urbanization's, modern architecture is a feast for the eyes, in order to make buildings can bring certain view to city, usually can decorate the exterior wall of buildings.Because ceramic tiles of exterior wall finish has colourful decorative effect, and price is suitable, construction easy, and therefore for a long time, the decoration of skin is based on clay facing tile always.But As time goes on, these clay facing tiles through wind all the year round, Exposure to Sunlight, the elemental destruction such as drench with rain, many skins can be made to be run ragged, even there is segmentation crack, this not only has influence on urban, and there will be wall leakage on rainy day, makes upholstery occur situation impaired in various degree, therefore, the innovation of ceramic tiles of exterior wall finish gets more and more.Traditional outdoor tile renovation mode mainly comprises two kinds: 1, destroy ceramic tile, batch putty, roller coating finish paint; 2, do not destroy ceramic tile, directly criticize Puttying at ceramic tile surface, roller coating finish paint; To take a lot of work effort owing to destroying ceramic tile, construction intensity is large, and putty layer easily absorbs water, and can cause film volumetric expansion, play drum, cracking, the film accumulation of salt in the surface soil also can be caused to turn white, grow dim, make high-grade ceramic tile finishing become the low grade finishing of batch Puttying; Therefore, in recent years, a kind ofly directly can be coated in old ceramic tile surface, the coating that makes old ceramic tile again shine beautiful brilliance arises at the historic moment, but this coating in use all occurs many problems, this is due to the smooth densification of ceramic tile surface, coating is absorbed few, sticking power is low, and coating is easily peeled off, and coating scattering and disappearing of moisture in drying process is lacked, dope viscosity rises slow, also easy sagging during construction; In addition, the water-repellancy of coating is low, hardness inadequate, is also current this product Problems existing; Therefore, seeking that a kind of sticking power is good, water resistance is good, hardness is high and construction is easy to coating and carrys out External Wall ceramic tile and renovate, is the problem that those skilled in the art endeavours to study.
Summary of the invention
For overcoming above Problems existing, the object of this invention is to provide the two-component coating of a kind of outdoor tile renovation, this coating has high adhesive force, high strength and high water resistance.
For realizing above object, the two-component coating of outdoor tile renovation of the present invention, comprises the component A by weight 55-60:40-45 and B component;
Wherein component A comprises following material and parts by weight:
Polyacrylic water-proof emulsion 30 ~ 40 parts, organic silicon emulsion 5 ~ 10 parts, thickening material 0.1-0.3 part, dispersion agent 0.5-1.5 part, wetting agent 0.05-0.15 part, adhesion promoter 0.1-0.3 part, mould inhibitor 0.4-0.6 part, defoamer 0.4-0.6 part, film coalescence aid 1 ~ 1.5 part, solubility promoter 2.0-3.0 part and water 4-5 part, polyacrylic water-proof emulsion is esters of acrylic acid latex;
B component comprises following material and parts by weight:
Titanium dioxide 5 ~ 10 parts, silica powder 8 ~ 15 parts and white cement 20 ~ 25 parts.
The model that the preferred French Arkema of aforesaid propylene esters of gallic acid latex produces is the synthetic latex of ENCOR413.
The trade mark of the preferred Germany's watt gram Company of above-mentioned organic silicon emulsion to be SREP BS45 resin emulsion or the trade mark be in the emulsion of the silicone-modified polysiloxane of SREP BS1306 one or both.
The emulsion of the trade mark of the preferred Germany's watt gram Company of above-mentioned organic silicon emulsion to be SREP BS45 resin emulsion and the trade mark the be silicone-modified polysiloxane of SREP BS1306, both ratios are 4-8:1-3.
In order to better improve the workability of coating, above-mentioned component A also includes rheological agent, and the parts by weight of rheological agent in component A are 0.4-0.6, the preferred nonionic polyurethane of rheological agent.
In order to make coating system transport and storage process more stable, above-mentioned component A also includes sanitas, and the weight fraction of sanitas in component A is 0.1-0.2, the preferred isothiazolinone of sanitas.
In order to better improve resistance to acids and bases and the ageing-resistant performance of coating, above-mentioned B component also includes mica, and mica is 2-3 part at the parts by weight in B component, the preferred wet method sericite of mica powder.
The trade mark of the preferred German bright rib Company of above-mentioned defoamer to be the defoamer of DEEFO 1015 or the trade mark be in the defoamer of AGITAN 109 one or both.
The preferred silane coupling agent of above-mentioned adhesion promoter.
The preferred modified polyorganosiloxane of above-mentioned wetting agent.
The preferred ammonium salt dispersion agent of above-mentioned dispersion agent.
The preferred alcohol ester 12 of above-mentioned film coalescence aid.
The preferred ethylene glycol of above-mentioned solubility promoter.
The two-component coating of outdoor tile renovation of the present invention, in component A, adopt polyacrylic water-proof emulsion and organic silicon emulsion as filmogen, coordinate the auxiliary agent that some can increase system stability and improve workability again, utilize that these two kinds of filmogen water resistancees are good, good weatherability, ventilation property are good and the feature of stain resistant, in conjunction with white cement and the silica powder of B component, solve the problem that coating waterproofing resistant, poor adhesive force and hardness are inadequate very well.The coating of two-component coating of the present invention has high adhesive force, high rigidity, high water resistance and high tint retention, without the need to adding water during use, only need the abundant mixing and stirring of A, B two component, can directly roller coating or brush on the ganoid base material such as ceramic tile, stone material, not only construction easily, and body of wall can be made beautiful lastingly, be particularly suitable for External Wall ceramic tile and renovate.
Specific embodiment
Below by specific embodiment, technical scheme of the present invention is described further; but these embodiments are not for limiting the scope of the invention; under the prerequisite not departing from theory of the present invention; to the equivalent replacement of each component or the adjustment of each component proportion, protection scope of the present invention all should be belonged to.
One, embodiment
Embodiment 1
1, fill a prescription
2, prepare
Successively the water of component A, isothiazolinone, Natvosol, defoamer AGITAN 109, dispersion agent, modified polyorganosiloxane, silane coupling agent, organic silicon emulsion SREP BS1306CN, organic silicon emulsion SREP BS45 are dropped in dispersion cylinder according to above-mentioned weight part, fully stir 10 minutes under rotating speed is 700 revs/min of conditions, add polyacrylic water-proof emulsion ENCOR413 again, mould inhibitor, defoamer DEEFO 1015, alcohol ester 12, ethylene glycol, nonionic polyurethane, packs after stirring in Pneumatic blender;
Successively the rutile titanium white powder of B component, quartz sand, white cement and wet method sericite in powder are dropped into a mixing bowl according to above-mentioned weight part, stir, until mix, allow raw material be down to room temperature, then pack.
By component A during use: B component=55:45 carries out mixing.
Embodiment 2
1, fill a prescription
2, prepare
Method is identical with embodiment 1.
Embodiment 3
1, fill a prescription
2, prepare
Method is identical with embodiment 1.
Two, comparative example
1, fill a prescription
2, prepare
Successively water, isothiazolinone, Natvosol, defoamer AGITAN 109, dispersion agent, modified polyorganosiloxane, organic silicon emulsion SREP BS16, titanium dioxide, mica powder and coarse whiting are dropped in dispersion cylinder according to above-mentioned weight part, fully stir 15 minutes under rotating speed is 1000 revs/min of conditions, add commercially available polyacrylic water-proof emulsion again, mould inhibitor, defoamer DEEFO 1015, alcohol ester 12, ethylene glycol, nonionic polyurethane, packs after stirring in Pneumatic blender.
Three, performance test
Carry out all-round property testing according to the film of GB/T9755-2014 " exterior wall coating material of synthetic resin emulsion " to the film of embodiment 1-3 and comparative example, result is as follows:
Carry out hardness test according to GBT6739-2006 " paint and varnish pencil method measures hardness of paint film " to the film of embodiment 1-3 and the film of comparative example, result is as follows:
Test the watertightness of the film of embodiment 1-3 and cohesive strength according to GBT23445-2009 " polymer cement waterproof paint ", result is as follows:
As can be seen from the above results, the water resistance (water-permeable) of the two component film of the present invention, contamination resistance, enduring quality (discolouration), are greatly improved with hardness compared with single-component film, and cohesive strength also reaches very high level.
Claims (10)
1. a two-component coating for outdoor tile renovation, comprises the component A by weight 55-60:40-45 and B component; Wherein component A comprises following material and parts by weight: polyacrylic water-proof emulsion 30 ~ 40 parts, organic silicon emulsion 5 ~ 10 parts, thickening material 0.1-0.3 part, dispersion agent 0.5-1.5 part, wetting agent 0.05-0.15 part, adhesion promoter 0.1-0.3 part, mould inhibitor 0.4-0.6 part, defoamer 0.4-0.6 part, film coalescence aid 1 ~ 1.5 part, solubility promoter 2.0-3.0 part and water 4-5 part, and polyacrylic water-proof emulsion is esters of acrylic acid latex; B component comprises following material and parts by weight: titanium dioxide 5 ~ 10 parts, silica powder 8 ~ 15 parts and white cement 20 ~ 25 parts.
2. the two-component coating of outdoor tile renovation according to claim 1, is characterized in that: described esters of acrylic acid latex is the model that French Arkema produces is the synthetic latex of ENCOR413.
3. the two-component coating of outdoor tile according to claim 1 and 2 renovation, is characterized in that: described organic silicon emulsion is one or both in the emulsion of Germany's trade mark SREP BS45 resin emulsion of watt gram Company or the silicone-modified polysiloxane of trade mark SREP BS1306.
4. the two-component coating of outdoor tile renovation according to claim 3, it is characterized in that: described organic silicon emulsion is the emulsion of Germany's trade mark SREP BS45 resin emulsion of watt gram Company and the silicone-modified polysiloxane of trade mark SREP BS1306, and both ratios are 4-8:1-4.
5. the two-component coating of outdoor tile renovation according to claim 4, it is characterized in that: described component A also includes rheological agent, the parts by weight of rheological agent in component A are 0.4-0.6, and rheological agent is nonionic polyurethane.
6. the two-component coating of outdoor tile renovation according to claim 5, it is characterized in that: described component A also includes sanitas, the weight fraction of sanitas in component A is 0.1-0.2, and sanitas is isothiazolinone.
7. the two-component coating of outdoor tile renovation according to claim 6, it is characterized in that: described B component also includes mica, mica is 2-3 part at the parts by weight in B component, and mica powder is wet method sericite.
8. the two-component coating of outdoor tile renovation according to claim 7, is characterized in that: described adhesion promoter is silane coupling agent.
9. the two-component coating of outdoor tile renovation according to claim 8, is characterized in that: described wetting agent is modified polyorganosiloxane.
10. the two-component coating of outdoor tile renovation according to claim 9, is characterized in that: described film coalescence aid is alcohol ester 12.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610030440.0A CN105542602B (en) | 2016-01-18 | 2016-01-18 | A kind of two-component coating of outdoor tile renovation |
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|---|---|---|---|
| CN201610030440.0A CN105542602B (en) | 2016-01-18 | 2016-01-18 | A kind of two-component coating of outdoor tile renovation |
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| CN105542602A true CN105542602A (en) | 2016-05-04 |
| CN105542602B CN105542602B (en) | 2017-11-24 |
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| CN201610030440.0A Active CN105542602B (en) | 2016-01-18 | 2016-01-18 | A kind of two-component coating of outdoor tile renovation |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107474729A (en) * | 2017-07-26 | 2017-12-15 | 广东金牌陶瓷有限公司 | A kind of mould proof anti-fouling agent in Ceramic Tiles surface |
| CN109337495A (en) * | 2018-09-28 | 2019-02-15 | 合众（佛山）化工有限公司 | A kind of refurbishing old ceramic tiles water paint of fluorine silicon anchorage |
| CN109535989A (en) * | 2018-10-31 | 2019-03-29 | 韶关市合众化工有限公司 | A kind of low surface tension durable antibiotic ceramic tile retreading water paint |
| CN109626865A (en) * | 2018-12-27 | 2019-04-16 | 广东美涂士建材股份有限公司 | With the outdoor tile renovation interfacial agents and preparation method compared with high bond strength |
| CN110685457A (en) * | 2019-10-24 | 2020-01-14 | 深圳市美施美克新材料有限公司 | Rapid renovation process for indoor ceramic tile glaze thin-pasting ultrathin aluminum-wood composite board |
| CN113088147A (en) * | 2021-04-07 | 2021-07-09 | 广州昊特建材有限公司 | Bi-component primer-free exterior wall paint and preparation and application methods thereof |
| CN116622269A (en) * | 2023-05-30 | 2023-08-22 | 广东好仕迪新材料科技有限公司 | Preparation method of composite base coating material with high adhesive force and cracking resistance |
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| CN102212301A (en) * | 2011-01-17 | 2011-10-12 | 立邦涂料（中国）有限公司 | Renovating coating for waterborne ceramic tiles and preparation method thereof |
| CN103289491A (en) * | 2013-07-01 | 2013-09-11 | 卢枝军 | Decorative coating constructed on ceramic tile directly and preparation method thereof |
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2016
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| CN102212301A (en) * | 2011-01-17 | 2011-10-12 | 立邦涂料（中国）有限公司 | Renovating coating for waterborne ceramic tiles and preparation method thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107474729A (en) * | 2017-07-26 | 2017-12-15 | 广东金牌陶瓷有限公司 | A kind of mould proof anti-fouling agent in Ceramic Tiles surface |
| CN109337495A (en) * | 2018-09-28 | 2019-02-15 | 合众（佛山）化工有限公司 | A kind of refurbishing old ceramic tiles water paint of fluorine silicon anchorage |
| CN109535989A (en) * | 2018-10-31 | 2019-03-29 | 韶关市合众化工有限公司 | A kind of low surface tension durable antibiotic ceramic tile retreading water paint |
| CN109626865A (en) * | 2018-12-27 | 2019-04-16 | 广东美涂士建材股份有限公司 | With the outdoor tile renovation interfacial agents and preparation method compared with high bond strength |
| CN110685457A (en) * | 2019-10-24 | 2020-01-14 | 深圳市美施美克新材料有限公司 | Rapid renovation process for indoor ceramic tile glaze thin-pasting ultrathin aluminum-wood composite board |
| CN113088147A (en) * | 2021-04-07 | 2021-07-09 | 广州昊特建材有限公司 | Bi-component primer-free exterior wall paint and preparation and application methods thereof |
| CN116622269A (en) * | 2023-05-30 | 2023-08-22 | 广东好仕迪新材料科技有限公司 | Preparation method of composite base coating material with high adhesive force and cracking resistance |
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| Publication number | Publication date |
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| CN105542602B (en) | 2017-11-24 |
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