CN107459952A - A kind of wet glue of wallpaper - Google Patents

A kind of wet glue of wallpaper Download PDF

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Publication number
CN107459952A
CN107459952A CN201710765855.7A CN201710765855A CN107459952A CN 107459952 A CN107459952 A CN 107459952A CN 201710765855 A CN201710765855 A CN 201710765855A CN 107459952 A CN107459952 A CN 107459952A
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wallpaper
parts
wet glue
agar
silicone acrylic
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CN201710765855.7A
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CN107459952B (en
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殷小祥
张琳
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Jiangmen Heng Jian Industrial Co., Ltd.
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Changzhou Minnesota European Packaging Material Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J143/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Adhesives based on derivatives of such polymers
    • C09J143/04Homopolymers or copolymers of monomers containing silicon
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The invention discloses a kind of wet glue of wallpaper, belong to building material technical field.The present invention is first by after diatomite ball milling, crushing, sieving, with absolute ethyl alcohol and butyl titanate mixing ultrasonic disperse, obtain dispersion liquid, under constant temperature stirring, deionized water is slowly added dropwise into dispersion liquid, treats completion of dropwise addition, continue constant temperature stirring reaction, modification infusorial earth slurries, then by gained modification infusorial earth slurries, oleic acid, xylitol, lipase, silicone acrylic emulsion, agar solution, deionized water and antifreezing agent are stirred, the wet glue of wallpaper is produced, mussel foot mucoprotein, peach colloidal solution and the mould proof powder of coconut husk are added also in the wet glue of wallpaper.The wet glue of wallpaper of the present invention has excellent performance, the service life for preventing that wallpaper is mouldy, extending wallpaper that can be permanently effective.

Description

A kind of wet glue of wallpaper
Technical field
The invention discloses a kind of wet glue of wallpaper, belong to building material technical field.
Background technology
Wallpaper is as a kind of indoor hardware fitting, and because it has color various, pattern enriches, and luxurious style is easy for construction With a variety of advantages such as affordable, favored by more and more finishing owners.Wallpaper net had once done portion to Middle Eastern On society to wallpaper cognition and the investigation of behaviour in service:The family that Integral decoration metope is carried out with wallpaper is 1.79%, specifies table Show and be ready to carry out the crowd of indoor decoration close to 63% using wallpaper.It is most popular that wallpaper has turned into today's society home decoration Decorative material for wall surface, and the selection of Wall paper adhesive and the use even more the most key link of wallpaper decoration effect.People are from wall When paper, the quality of wallpaper can be focused on mostly, but often ignore the selection of Wall paper adhesive.In fact, the quality of Wall paper adhesive, more directly Connect the paving effect for having influence on wallpaper.The harmful substances, even more room such as the formaldehyde that may significantly contain in Wall paper adhesive, benzene The main source of interior air pollution, there is the effect of carcinogenesis teratogenesis shape, it is possible to trigger leukaemia.So-called Wall paper adhesive, it is by wallpaper The colloid being bonded on wall.It is divided into two major classes by its material and application.The first kind applies to the glue that general paper substrate wallpaper is pasted Glutinous agent, the second class are that there is high wet tack, high level cadre to be applied to the adhesive that various substrate wallpapers are pasted by force.By its physical aspect again It is divided into three kinds of rubber powder type, modulation type, finished product type forms.With the development of Wall paper adhesive, the common Wall paper adhesive in market mainly has at present Amylan, glutinous rice glue, function glue etc..Wall paper adhesive, emphasis fall on glue, be ensure for clinging wallpaper wallpaper stickup and Service life is most basic function.Also to require that product is environmentally friendly simultaneously.Environmental protection can not be pursued and ignore viscous force, or chased after Seek viscous force and ignore environmental protection.
The wet glue of wallpaper is a kind of adhesive for being specifically used to paste wallpaper, and its primary raw material is the organic polymer of starch Polymer.The characteristics of wet glue is that adhesion is strong, and environmentally friendly, the wallpaper of suitable adherent cloth and middle and high end, but easily moldy metamorphism. The commercially available wet glue of wallpaper is typically all with organic mould proof system, and itself can quilt during the microbial attacks such as bacterium, mould are resisted Gradually use up, glued membrane be easy to it is mouldy, wallpaper can large area it is mouldy.
The content of the invention
The present invention solves the technical problem of:It is easily mouldy for the current wet glue of wallpaper, cause wallpaper also can be big A kind of the problem of area is mouldy, there is provided wet glue of wallpaper.
In order to solve the above-mentioned technical problem, the technical solution adopted in the present invention is:
A kind of wet glue of wallpaper, is made up of the raw material of following parts by weight:40~50 parts of oleic acid, 40~50 parts of xylitols, 8~10 Part lipase, 20~30 parts of silicone acrylic emulsions, 20~30 parts of diatomite, 20~30 parts of butyl titanates, 40~50 parts of absolute ethyl alcohols, 40~50 parts of agar solutions, 50~60 parts of deionized waters, 10~20 parts of antifreezing agents;
The preparation process of the wet glue of wallpaper is:Each raw material is weighed by raw material composition, first by after diatomite ball milling, crushing, sieving, With absolute ethyl alcohol and butyl titanate mixing ultrasonic disperse, dispersion liquid is obtained, under constant temperature stirring, into dispersion liquid slowly Deionized water is added dropwise, treats completion of dropwise addition, continues constant temperature stirring reaction, obtains modification infusorial earth slurries, then by gained modification infusorial earth Slurries, oleic acid, xylitol, lipase, silicone acrylic emulsion, agar solution, deionized water and antifreezing agent are stirred, and it is wet to produce wallpaper Glue.
In the silicone acrylic emulsion model silicone acrylic emulsion LR-7220, silicone acrylic emulsion LR-750 or silicone acrylic emulsion LR-720A Any one.
The configuration process of the agar solution:It is 1 in mass ratio:50 add agar solution and water in beaker, heating stirring, i.e., Obtain agar solution.
The antifreezing agent is isopropanol, propane diols, any one in diethylene glycol (DEG) or ethylene glycol.
0.3~0.4 times of mussel foot mucoprotein of agar solution quality can also be added in the wet glue of wallpaper.
0.3~0.4 times of peach colloidal solution of agar solution quality can also be added in the wet glue of wallpaper;The configuration of institute's number peach colloidal solution Cheng Wei:It is 1 in mass ratio by peach gum and water:50 heating stirrings, produce peach colloidal solution.
0.03~0.04 times of mould proof powder of coconut husk of agar solution quality can also be added in the wet glue of wallpaper.
The beneficial effects of the invention are as follows:
(1)The present invention has adsorbed the modification infusorial earth of nano titanium oxide caused by hydrolysis by addition, and titanium dioxide is through light Irradiation, water and oxygen generation hydroxy radical and oxygen radical in catalytic air, the hydroxy radical and oxygen radical of generation can be with The microorganism being attached on the wet glue of wallpaper is killed, effectively prevents that wallpaper is mouldy;By adding silicone acrylic emulsion, silicone acrylic emulsion can be Diatomaceous apparent gap forms one layer of hydrophobic membrane, and outside moisture can not stop in hydrophobic membrane surface attachment, and such microorganism is just It cannot get the moisture required in metabolic process, survived on Wall paper adhesive that just can not be after hardening, so as to further enhance wall The anti-mold effect of the wet glue of paper;By adding oleic acid, xylitol, lipase, lipase-catalyzed oleic acid and ester of xylitol metaplasia into oil Sourwood sugar alcohol ester, during long-term use, even if a small amount of moisture in system be present, it can also be hydrolyzed and disappear by the oleic acid ester of xylitol Consumption, and oleic acid ester of xylitol hydrolysate can not be absorbed by the micro-organisms utilization again, microorganism absorbs just can not less than nutritional ingredient Existence, it becomes possible to the permanently effective service life for preventing that wallpaper is mouldy, extending wallpaper;
(2)The present invention is by adding agar solution, and microorganism can not decompose agar solution, and microorganism is in the environment of nonnutritive composition It can not survive, therefore effectively prevent that wallpaper is mouldy, and agar solution has certain adhesiveness, is also beneficial to improve wallpaper and wall The adhesion of wall;By adding a small amount of mussel foot mucoprotein, DOPA group can form discontinuous microcosmic life in mussel foot mucoprotein Thing support, such biological support form macromolecule network polymers again, further enhancing the adhesion of wallpaper and wall.
Embodiment
It is 1 in mass ratio:50~1:100 add agar and water in beaker, and 20~30min is stirred with glass bar Afterwards, 2~4h of swelling is stood, then beaker immigration digital display is tested the speed constant temperature blender with magnetic force, in 95~98 DEG C of temperature, rotating speed 300 Under the conditions of~500r/min, heating stirring dissolves 10~20min, produces agar solution;Count in parts by weight, take 40~50 parts successively Oleic acid, 40~50 parts of xylitols, 8~10 parts of lipase, 20~30 parts of silicone acrylic emulsions, 20~30 parts of diatomite, 20~30 parts of titaniums Sour four butyl esters, 40~50 parts of absolute ethyl alcohols, 40~50 parts of agar solutions, 50~60 parts of deionized waters, 10~20 parts of antifreezing agents, first will Diatomite is poured into ball mill, is 15 by ball material mass ratio:1~20:1 add zirconium oxide ball milling pearl, in rotating speed be 200~ Under the conditions of 300r/min after 4~6h of ball mill grinding, 200~300 mesh sieves are crossed, obtain diatomite powder, then by diatomite powder, anhydrous Ethanol and butyl titanate are added in beaker, and beaker then is moved into ultrasonic disperse instrument, in supersonic frequency be 60~75kHz conditions Under, 30~40min of ultrasonic disperse, dispersion liquid is obtained, then dispersion liquid is transferred to three-necked flask, and three-necked flask immigration digital display is tested the speed Constant temperature blender with magnetic force, in temperature be 45~55 DEG C, under the conditions of rotating speed is 300~500r/min, by dropping funel with 3~ Deionized water is added dropwise into three-necked flask for 5mL/min speed, and it is complete to treat that deionized water drips, and continuation constant temperature stirring reaction 45~ 60min, modification infusorial earth slurry is obtained, then gained modification infusorial earth slurry is all added in batch mixer, then successively to batch mixing Oleic acid, xylitol, lipase, silicone acrylic emulsion, agar solution, deionized water and antifreezing agent are added in machine, in rotating speed be 1100~ High-speed stirred mixes 20~40min under the conditions of 1200r/min, then agar solution 0.3~0.4 times of mussel of quality is added into batch mixer Sufficient mucoprotein, 0.03~0.04 times of mould proof powder of coconut husk of 0.3~0.4 times of peach colloidal solution of agar solution quality and agar solution quality, in rotating speed 30~50min is mixed to continue high-speed stirred under the conditions of 1100~1200r/min, produces the wet glue of wallpaper.The silicone acrylic emulsion type Number be silicone acrylic emulsion LR-7220, silicone acrylic emulsion LR-750 and silicone acrylic emulsion LR-720A in any one.The antifreezing agent is Any one in isopropanol, propane diols, diethylene glycol (DEG) or ethylene glycol.The configuration process of institute's number peach colloidal solution is:By 1:50 peach gums with Water heating stirring, produces peach colloidal solution.
Example 1
It is 1 in mass ratio:100 add agar and water in beaker, after being stirred 30min with glass bar, stand swelling 4h, then Beaker immigration digital display is tested the speed constant temperature blender with magnetic force, in 98 DEG C of temperature, under the conditions of rotating speed is 500r/min, heating stirring dissolving 20min, produce agar solution;Count in parts by weight, take 50 parts of oleic acid, 50 parts of xylitols, 10 parts of lipase, 30 parts of breasts of silicon third successively Liquid, 30 parts of diatomite, 30 parts of butyl titanates, 50 parts of absolute ethyl alcohols, 50 parts of agar solutions, 60 parts of deionized waters, 20 parts of antifreezing agents, First diatomite is poured into ball mill, is 20 by ball material mass ratio:1 add zirconium oxide ball milling pearl, in rotating speed be 300r/min bars Under part after ball mill grinding 6h, 300 mesh sieves are crossed, obtain diatomite powder, then diatomite powder, absolute ethyl alcohol and butyl titanate are added Enter in beaker, beaker is then moved into ultrasonic disperse instrument, under the conditions of supersonic frequency is 75kHz, ultrasonic disperse 40min, score Dispersion liquid, then dispersion liquid is transferred to three-necked flask, and three-necked flask immigration digital display is tested the speed constant temperature blender with magnetic force, in temperature be 55 DEG C, under the conditions of rotating speed is 500r/min, deionized water is added dropwise into three-necked flask with 5mL/min speed by dropping funel, treated Deionized water drip it is complete, continue constant temperature stirring reaction 60min, obtain modification infusorial earth slurry, then gained modification infusorial earth is starched Material is all added in batch mixers, then adds oleic acid into batch mixer successively, xylitol, lipase, silicone acrylic emulsion, agar solution, Deionized water and antifreezing agent, high-speed stirred mixes 40min under the conditions of rotating speed is 1200r/min, then fine jade is added into batch mixer 0.4 times of mussel foot mucoprotein of fat liquid quality, 0.04 times of mould proof powder of coconut husk of 0.4 times of peach colloidal solution of agar solution quality and agar solution quality, Continue high-speed stirred under the conditions of rotating speed is 1200r/min and mix 50min, produce the wet glue of wallpaper.The silicone acrylic emulsion model Silicone acrylic emulsion LR-7220.The antifreezing agent is isopropanol.The configuration process of institute's number peach colloidal solution is:By 1:50 peach gums heat with water Stirring, produces peach colloidal solution.
Example 2
It is 1 in mass ratio:100 add agar and water in beaker, after being stirred 30min with glass bar, stand swelling 4h, then Beaker immigration digital display is tested the speed constant temperature blender with magnetic force, in 98 DEG C of temperature, under the conditions of rotating speed is 500r/min, heating stirring dissolving 20min, produce agar solution;Count in parts by weight, take 50 parts of oleic acid, 50 parts of xylitols, 10 parts of lipase, 30 parts of breasts of silicon third successively Liquid, 30 parts of butyl titanates, 50 parts of absolute ethyl alcohols, 50 parts of agar solutions, 60 parts of deionized waters, 20 parts of antifreezing agents, then successively to Oleic acid, xylitol, lipase, silicone acrylic emulsion, agar solution, deionized water and antifreezing agent are added in batch mixer, is in rotating speed High-speed stirred mixes 40min under the conditions of 1200r/min, then agar solution 0.4 times of mussel foot mucoprotein of quality is added into batch mixer, 0.04 times of mould proof powder of coconut husk of 0.4 times of peach colloidal solution of agar solution quality and agar solution quality, continue under the conditions of rotating speed is 1200r/min High-speed stirred mixes 50min, produces the wet glue of wallpaper.The silicone acrylic emulsion model silicone acrylic emulsion LR-7220.The antifreezing agent is Isopropanol.The configuration process of institute's number peach colloidal solution is:By 1:50 peach gums and water heating stirring, produce peach colloidal solution.
Example 3
It is 1 in mass ratio:100 add agar and water in beaker, after being stirred 30min with glass bar, stand swelling 4h, then Beaker immigration digital display is tested the speed constant temperature blender with magnetic force, in 98 DEG C of temperature, under the conditions of rotating speed is 500r/min, heating stirring dissolving 20min, produce agar solution;Count in parts by weight, take 30 parts of silicone acrylic emulsions, 30 parts of diatomite, 30 parts of butyl titanates, 50 successively Part absolute ethyl alcohol, 50 parts of agar solutions, 60 parts of deionized waters, 20 parts of antifreezing agents, first pour into diatomite in ball mill, by ball material matter Amount is than being 20:1 adds zirconium oxide ball milling pearl, after ball mill grinding 6h under the conditions of rotating speed is 300r/min, crosses 300 mesh sieves, obtains silicon Diatomaceous earth powder, then diatomite powder, absolute ethyl alcohol and butyl titanate are added in beaker, beaker is then moved into ultrasonic disperse Instrument, under the conditions of supersonic frequency is 75kHz, ultrasonic disperse 40min, dispersion liquid is obtained, then dispersion liquid is transferred to three-necked flask, and will Three-necked flask moves into digital display and tested the speed constant temperature blender with magnetic force, is 55 DEG C in temperature, under the conditions of rotating speed is 500r/min, passes through dropping liquid Deionized water is added dropwise into three-necked flask with 5mL/min speed for funnel, and it is complete to treat that deionized water drips, and continues constant temperature stirring reaction 60min, modification infusorial earth slurry is obtained, then gained modification infusorial earth slurry is all added in batch mixer, then successively to batch mixing Silicone acrylic emulsion, agar solution, deionized water and antifreezing agent are added in machine, high-speed stirred mixes under the conditions of rotating speed is 1200r/min 40min, then agar solution 0.4 times of mussel foot mucoprotein of quality, 0.4 times of peach colloidal solution of agar solution quality and agar are added into batch mixer 0.04 times of mould proof powder of coconut husk of liquid quality, continue high-speed stirred mixing 50min under the conditions of rotating speed is 1200r/min, produce wallpaper Wet glue.The silicone acrylic emulsion model silicone acrylic emulsion LR-7220.The antifreezing agent is isopropanol.The configuration of institute's number peach colloidal solution Cheng Wei:By 1:50 peach gums and water heating stirring, produce peach colloidal solution.
Example 4
Count in parts by weight, take 50 parts of oleic acid, 50 parts of xylitols, 10 parts of lipase, 30 parts of silicone acrylic emulsions, 30 portions of diatoms successively Soil, 30 parts of butyl titanates, 50 parts of absolute ethyl alcohols, 60 parts of deionized waters, 20 parts of antifreezing agents, first pour into ball mill by diatomite In, it is 20 by ball material mass ratio:1 adds zirconium oxide ball milling pearl, after ball mill grinding 6h under the conditions of rotating speed is 300r/min, mistake 300 mesh sieves, diatomite powder is obtained, then diatomite powder, absolute ethyl alcohol and butyl titanate are added in beaker, then by beaker Ultrasonic disperse instrument is moved to, under the conditions of supersonic frequency is 75kHz, ultrasonic disperse 40min, obtains dispersion liquid, then dispersion liquid is transferred to Three-necked flask, and three-necked flask immigration digital display is tested the speed constant temperature blender with magnetic force, it is 55 DEG C in temperature, rotating speed is 500r/min bars Under part, deionized water is added dropwise into three-necked flask with 5mL/min speed by dropping funel, it is complete to treat that deionized water drips, after Continuous constant temperature stirring reaction 60min, modification infusorial earth slurry is obtained, then gained modification infusorial earth slurry is all added in batch mixer, Oleic acid, xylitol, lipase, silicone acrylic emulsion, deionized water and antifreezing agent are then added into batch mixer successively, is in rotating speed High-speed stirred mixes 40min under the conditions of 1200r/min, then agar solution 0.4 times of mussel foot mucoprotein of quality is added into batch mixer, 0.04 times of mould proof powder of coconut husk of 0.4 times of peach colloidal solution of agar solution quality and agar solution quality, continue under the conditions of rotating speed is 1200r/min High-speed stirred mixes 50min, produces the wet glue of wallpaper.The silicone acrylic emulsion model silicone acrylic emulsion LR-7220.The antifreezing agent is Isopropanol.The configuration process of institute's number peach colloidal solution is:By 1:50 peach gums and water heating stirring, produce peach colloidal solution.
Comparative example:The wet glue of wallpaper of Suzhou building materials Co., Ltd production.
The wet glue of the gained wallpaper of example 1 to 4 and comparative example product are subjected to performance detection, specific detection according to GB/T21866 Method is as follows:
Configuration concentration is the 20% mould aqueous solution.Made wet glue is coated on putty plate by constructing operation, uniformly sprayed after drying The aqueous solution of upper mould mixed liquor.It is placed in 37 DEG C or so of mold incubator, observes mouldy situation.After 28d, on putty plate It is 0 grade not have the mould proof grade of fungus growth, and it is I grade to have the mould proof grade of fungus growth less than 10% area, and growth area surpasses It is II grade to cross 10%.Specific testing result is as shown in table 1:
Table 1
Detection content Example 1 Example 2 Example 3 Example 4 Comparative example
Mould proof grade 0
From the testing result of table 1, the mould proof grade of the present invention gained wet glue of wallpaper is high, effectively solves the wet glue of current wallpaper The problem of easily mouldy.

Claims (7)

  1. A kind of 1. wet glue of wallpaper, it is characterised in that:It is made up of the raw material of following parts by weight:40~50 parts of oleic acid, 40~50 Part xylitol, 8~10 parts of lipase, 20~30 parts of silicone acrylic emulsions, 20~30 parts of diatomite, 20~30 parts of butyl titanates, 40 ~50 parts of absolute ethyl alcohols, 40~50 parts of agar solutions, 50~60 parts of deionized waters, 10~20 parts of antifreezing agents;
    The preparation process of the wet glue of wallpaper is:Each raw material is weighed by raw material composition, first by after diatomite ball milling, crushing, sieving, With absolute ethyl alcohol and butyl titanate mixing ultrasonic disperse, dispersion liquid is obtained, under constant temperature stirring, into dispersion liquid slowly Deionized water is added dropwise, treats completion of dropwise addition, continues constant temperature stirring reaction, obtains modification infusorial earth slurries, then by gained modification infusorial earth Slurries, oleic acid, xylitol, lipase, silicone acrylic emulsion, agar solution, deionized water and antifreezing agent are stirred, and it is wet to produce wallpaper Glue.
  2. A kind of 2. wet glue of wallpaper according to claim 1, it is characterised in that:The silicone acrylic emulsion model silicone acrylic emulsion Any one in LR-7220, silicone acrylic emulsion LR-750 or silicone acrylic emulsion LR-720A.
  3. A kind of 3. wet glue of wallpaper according to claim 1, it is characterised in that:The configuration process of the agar solution:By quality Than for 1:50 add agar solution and water in beaker, heating stirring, produce agar solution.
  4. A kind of 4. wet glue of wallpaper according to claim 1, it is characterised in that:The antifreezing agent is isopropanol, propane diols, two Any one in glycol or ethylene glycol.
  5. A kind of 5. wet glue of wallpaper according to claim 1, it is characterised in that:Agar can also be added in the wet glue of wallpaper 0.3~0.4 times of mussel foot mucoprotein of liquid quality.
  6. A kind of 6. wet glue of wallpaper according to claim 1, it is characterised in that:Agar can also be added in the wet glue of wallpaper 0.3~0.4 times of peach colloidal solution of liquid quality;The configuration process of institute's number peach colloidal solution is:It is 1 in mass ratio by peach gum and water:50 heating are stirred Mix, produce peach colloidal solution.
  7. A kind of 7. wet glue of wallpaper according to claim 1, it is characterised in that:Agar can also be added in the wet glue of wallpaper 0.03~0.04 times of mould proof powder of coconut husk of liquid quality.
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108914706A (en) * 2018-07-26 2018-11-30 武汉菡美洛建筑材料有限公司 A kind of Environment-friendlywallpaper wallpaper of formaldehyde adsorption
CN109231851A (en) * 2018-08-09 2019-01-18 苗霞明 A kind of mould-proof agent for glass
CN114262590A (en) * 2020-09-16 2022-04-01 志光家具(象州)有限公司 Special glue for veneer pasting

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CN104592825A (en) * 2014-12-26 2015-05-06 三棵树涂料股份有限公司 Artistic coating and preparation method thereof
CN105567118A (en) * 2015-12-16 2016-05-11 张树发 Dehydrated wall paper wet glue and preparation method thereof
CN107022325A (en) * 2017-04-27 2017-08-08 无锡市福享天下科技有限公司 Senior wallpaper wall paper adhesive

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104592825A (en) * 2014-12-26 2015-05-06 三棵树涂料股份有限公司 Artistic coating and preparation method thereof
CN105567118A (en) * 2015-12-16 2016-05-11 张树发 Dehydrated wall paper wet glue and preparation method thereof
CN107022325A (en) * 2017-04-27 2017-08-08 无锡市福享天下科技有限公司 Senior wallpaper wall paper adhesive

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108914706A (en) * 2018-07-26 2018-11-30 武汉菡美洛建筑材料有限公司 A kind of Environment-friendlywallpaper wallpaper of formaldehyde adsorption
CN108914706B (en) * 2018-07-26 2020-06-16 山东汇高智慧纺织科技有限公司 Environment-friendly wallpaper capable of adsorbing formaldehyde
CN109231851A (en) * 2018-08-09 2019-01-18 苗霞明 A kind of mould-proof agent for glass
CN114262590A (en) * 2020-09-16 2022-04-01 志光家具(象州)有限公司 Special glue for veneer pasting

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