CN106365670A - Water-absorbable ceramic tile - Google Patents
Water-absorbable ceramic tile Download PDFInfo
- Publication number
- CN106365670A CN106365670A CN201610814084.1A CN201610814084A CN106365670A CN 106365670 A CN106365670 A CN 106365670A CN 201610814084 A CN201610814084 A CN 201610814084A CN 106365670 A CN106365670 A CN 106365670A
- Authority
- CN
- China
- Prior art keywords
- water
- ceramic tile
- parts
- absorbing resin
- mixed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B16/00—Use of organic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of organic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B16/04—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B30/00—Compositions for artificial stone, not containing binders
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention discloses a water-absorbable ceramic tile, belongs to the field of building materials, and aims to provide the ceramic tile with high water absorption and impact resistance performance. Micro air holes are formed in the surface and the interior of the ceramic tile, and water-absorbing resin is arranged in the micro air holes. A preparation method of the water-absorbable ceramic file includes step 1, blending raw materials in a kneading machine for intensive mixing; step 2, adding 1-5 parts of coupling agents into the mixture obtained from the step 1, and performing mixed processing through sound wave blending; step 3, selecting 1-5 parts of dry water-absorbing resin powder, and soaking the water-absorbing resin powder in 15 parts of water to obtain the water-absorbing resin; step 4, mixing products of the step 2 and the step 3 according to a jet mill collision method to obtain a mixed raw material; step 5, making the ceramic tile from the mixed raw material of the step 4; step 6, drying the ceramic tile obtained after the step 5.
Description
Technical field
The present invention relates to a kind of construction material, it is specifically that one kind can absorb water ceramic tile.
Background technology
Under modern society, the more and more higher that needs to construction material, the resource of consumption also about arrives more, causes serious
Environmental pollution, wherein in construction material and its product, ceramic tile occupies very big ratio, on residential households, office and other places
Area's tool has been widely used, and annual digestion amount is also very huge.But existing ceramic tile is due to surface smoother, to water
Absorbability is very weak, leads to the water of ceramic tile surface to be difficult to remove completely clean, and is easily caused that ceramic tile is dirty, impact is attractive in appearance.Meanwhile,
Existing ceramic tile is substantially to be prepared by inorganic material, and the fragility of ceramic tile is big, permanent using and under the collision of enormous power very
Easily ftracture.Breakage, needs further exist for changing, leads to the waste of resource.
Content of the invention
It is an object of the invention to: for above-mentioned problem, provide a kind of ceramic tile, be added to by adding water-absorbing resin
Internal, simultaneously through dried so that the surface of ceramic tile and be internally formed containing water-absorbing resin microcellular structure, Neng Gouyou
The micro-moisture on its surface of washing one's hands of effect, and preferable resistance to impact in time, not easy to crack during use.
The technical solution used in the present invention is as follows:
The invention discloses a kind of ceramic tile that absorbs water is it is characterised in that there are micro- pore, institute in described water suction ceramic tile surface and inside
The micro- pore stated is contained within water-absorbing resin.
As improvement, described absorbed water ceramic tile preparation method is as follows:
Step 1: the principle of following weight portion is carried out mixed preparing and is sufficiently mixed in kneader:
20 parts of flint, 10 parts of zinc oxide, 40 parts of whiting, 5 parts of stannum oxide, 220 parts of magnesite, Barium metatitanate. 40
Part, 20 parts of Pulvis Talci；
Step 2: be added in the mixture in above-mentioned steps 1 with coupling agent 1-5 part, mixed by way of ultrasonic blending
Conjunction is processed；
Step 3, take 1-5 part be dried water-absorbent resin powder, soaked with the water of 5-20 part, made containing water-absorbing resin；
Step 4:: the principle after above-mentioned steps 2 and step 3 is mixed in the method being clashed with airflow milling, obtains mixing former
Material；
Step 5: prepare ceramic tile with the raw material of step 4 mixing；
Step 6: drying and processing is carried out to the ceramic tile after step 5.
Preferably, the coupling agent of described step 2 is gamma-aminopropyl-triethoxy-silane, γ-glycidyl ether oxygen propyl
Trimethoxy silane, γ-methacryloxypropyl trimethoxy silane, isopropyl three (dioctylphyrophosphoric acid acyloxy) titanium
Acid esters, sec.-propyl three (dioctyl phosphoric acid acyloxy) titanic acid ester, isopropyl two Oleic acid acyloxy (dioctyl phosphoric acid acyloxy) titanium
One or more of acid esters.
Wherein, the water-absorbing resin of described step 3 includes but is not limited to polyacrylic acid sodium salt, polyacrylic acid-acrylamide, gathers
Vinyl alcohol, carboxymethylated cellulosic one or more.
Preferably, described drying temperature be 200-500 DEG C, drying time be 5-10h.
For the present invention provide absorbed water ceramic tile, disclose its partial use, including but not limited to bedroom, parlor,
The application of office.
In sum, due to employing technique scheme, the beneficial effects of the present invention is:
1st, the ceramic tile that the present invention provides has preferable water absorption, can quickly absorb the moisture of ceramic tile surface attachment, simultaneously for
It is drawn onto the moisture within ceramic tile, can slowly evaporate.
2nd, the ceramic tile that the present invention provides has preferable resistance to impact, not easy to crack, long service life.
Specific embodiment
The present invention is described in detail below.
Specific embodiment 1: the ceramic tile present embodiment discloses one kind can absorb water, described water suction ceramic tile surface and inside have
Micro- pore, described micro- pore is contained within water-absorbing resin, and preparation method is as follows:
Step 1: the principle of following weight portion is carried out mixed preparing and is sufficiently mixed in kneader:
20 parts of flint, 10 parts of zinc oxide, 40 parts of whiting, 5 parts of stannum oxide, 220 parts of magnesite, Barium metatitanate. 40
Part, 20 parts of Pulvis Talci；
Step 2: be added in the mixture in above-mentioned steps 1 with coupling agent 1-5 part, mixed by way of ultrasonic blending
Conjunction is processed；
Step 3, take 1-5 part be dried water-absorbent resin powder, soaked with the water of 5-20 part, made containing water-absorbing resin；
Step 4:: the principle after above-mentioned steps 2 and step 3 is mixed in the method being clashed with airflow milling, obtains mixing former
Material；
Step 5: prepare ceramic tile with the raw material of step 4 mixing；
Step 6: drying and processing is carried out to the ceramic tile after step 5.
Wherein, described coupling agent, to absorb resin, the process conditions in step 6 as shown in table 1.
Absorbed water ceramic tile described above has good application prospect in bedroom, parlor, office.
By testing to the ceramic tile that the present embodiment provides, a small amount of moisture on ceramic tile can in 1 minute quick quilt
Blot, soaking effect is good, overhanging beam impact flexibility at iso180-2000/a, 25 DEG C for the ceramic tile can reach 30kj/m2 with
On, resistance to impact is strong.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all essences in the present invention
Any modification, equivalent and improvement made within god and principle etc., should be included within the scope of the present invention.
Table 1.
Claims (6)
1. a kind of ceramic tile that absorbs water is it is characterised in that there is micro- pore described water suction ceramic tile surface and inside, described micro- pore
It is contained within water-absorbing resin.
2. the ceramic tile that absorbs water according to claim 1 is it is characterised in that preparation method is as follows:
Step 1: the principle of following weight portion is carried out mixed preparing and is sufficiently mixed in kneader:
20 parts of flint, 10 parts of zinc oxide, 40 parts of whiting, 5 parts of stannum oxide, 220 parts of magnesite, Barium metatitanate. 40
Part, 20 parts of Pulvis Talci；
Step 2: will be added in coupling reaction tank, open agitating device, stirring makes silicon white powder rotate, by silane coupler with
Water, dehydrated alcohol are configured to after solution according to 1:1:0.5, are sprayed directly in the mixture after step 1, control agitating device
Rotary speed be 4000 revs/min -6000 revs/min so that the temperature of mixture reaches 120 degrees Celsius, react 10-20 minute
Afterwards, dry the prepared coupling modifier of 10-30 minute at 100-150 DEG C and cross mixture；
Step 3, take 1-5 part be dried water-absorbent resin powder, soaked with 15 parts of water, made containing water-absorbing resin；
Step 4:: the principle after above-mentioned steps 2 and step 3 is mixed in the method being clashed with airflow milling, obtains mixing former
Material；
Step 5: prepare ceramic tile with the raw material of step 4 mixing；
Step 6: drying and processing is carried out to the ceramic tile after step 5.
3. the ceramic tile that absorbs water according to claim 2 is it is characterised in that the coupling agent of described step 2 is γ-aminopropyl three
Ethoxysilane, γ-glycidyl ether oxygen propyl trimethoxy silicane, γ-methacryloxypropyl trimethoxy silane,
Isopropyl three (dioctylphyrophosphoric acid acyloxy) titanate esters, sec.-propyl three (dioctyl phosphoric acid acyloxy) titanic acid ester, isopropyl two
One or more of Oleic acid acyloxy (dioctyl phosphoric acid acyloxy) titanate esters.
4. the ceramic tile that absorbs water according to claim 1 is it is characterised in that the water-absorbing resin of described step 3 includes but do not limit
In polyacrylic acid sodium salt, polyacrylic acid-acrylamide, polyvinyl alcohol, carboxymethylated cellulosic one or more.
5. the ceramic tile that absorbs water according to claim 1 is it is characterised in that described drying temperature is 200-500 DEG C, dries
Time is 5-10h.
6. the absorbed water ceramic tile described in claim 1-5 bedroom, parlor, office application.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610814084.1A CN106365670B (en) | 2016-09-09 | 2016-09-09 | One kind can absorb water ceramic tile |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610814084.1A CN106365670B (en) | 2016-09-09 | 2016-09-09 | One kind can absorb water ceramic tile |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106365670A true CN106365670A (en) | 2017-02-01 |
| CN106365670B CN106365670B (en) | 2019-04-12 |
Family
ID=57899580
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610814084.1A Expired - Fee Related CN106365670B (en) | 2016-09-09 | 2016-09-09 | One kind can absorb water ceramic tile |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106365670B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108342134A (en) * | 2018-01-09 | 2018-07-31 | 河北晨阳工贸集团有限公司 | Aqueous ceramic paint and preparation method thereof and ceramics and preparation method thereof |
| CN113563116A (en) * | 2021-07-21 | 2021-10-29 | 佛山欧神诺陶瓷有限公司 | Composite ceramic tile and preparation method and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1747751A (en) * | 2003-02-10 | 2006-03-15 | 株式会社日本触媒 | Water-absorbent resin composition and its production process |
| CN101490139A (en) * | 2006-07-31 | 2009-07-22 | 株式会社日本触媒 | Production method of water absorbent resin powder and package of water absorbent resin powder |
| CN101765622A (en) * | 2007-09-07 | 2010-06-30 | 株式会社日本触媒 | Binding method of water absorbent resin |
| CN202969205U (en) * | 2012-11-28 | 2013-06-05 | 廖云翔 | Water absorbing floor tile |
-
2016
- 2016-09-09 CN CN201610814084.1A patent/CN106365670B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1747751A (en) * | 2003-02-10 | 2006-03-15 | 株式会社日本触媒 | Water-absorbent resin composition and its production process |
| CN101490139A (en) * | 2006-07-31 | 2009-07-22 | 株式会社日本触媒 | Production method of water absorbent resin powder and package of water absorbent resin powder |
| CN101765622A (en) * | 2007-09-07 | 2010-06-30 | 株式会社日本触媒 | Binding method of water absorbent resin |
| CN202969205U (en) * | 2012-11-28 | 2013-06-05 | 廖云翔 | Water absorbing floor tile |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108342134A (en) * | 2018-01-09 | 2018-07-31 | 河北晨阳工贸集团有限公司 | Aqueous ceramic paint and preparation method thereof and ceramics and preparation method thereof |
| CN113563116A (en) * | 2021-07-21 | 2021-10-29 | 佛山欧神诺陶瓷有限公司 | Composite ceramic tile and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106365670B (en) | 2019-04-12 |
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| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20190318 Address after: 336000 Yifeng County Industrial Park, Yichun City, Jiangxi Province Applicant after: Jiangxi Century Xingui Ceramics Co.,Ltd. Address before: 610000 Wuhou District Wuhou new town administrative committee, Chengdu, Sichuan, 2 Wuyi East Road 15, 1 units, 2 level 231. Applicant before: CHENGDU JIUSHIDU INDUSTRIAL PRODUCTS DESIGN Co.,Ltd. |
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| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20190412 Termination date: 20210909 |
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| CF01 | Termination of patent right due to non-payment of annual fee |