CN106365670B - One kind can absorb water ceramic tile - Google Patents
One kind can absorb water ceramic tile Download PDFInfo
- Publication number
- CN106365670B CN106365670B CN201610814084.1A CN201610814084A CN106365670B CN 106365670 B CN106365670 B CN 106365670B CN 201610814084 A CN201610814084 A CN 201610814084A CN 106365670 B CN106365670 B CN 106365670B
- Authority
- CN
- China
- Prior art keywords
- ceramic tile
- water
- parts
- mixed
- absorbing resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B16/00—Use of organic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of organic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B16/04—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B30/00—Compositions for artificial stone, not containing binders
Abstract
It can absorb water ceramic tile the invention discloses one kind, belong to building materials field, it is desirable to provide a kind of ceramic tile that water suction impact resistance is good, there are micro- stomata in surface and inside, contain water-absorbing resin in micro- stomata, the preparation method is as follows: step 1: raw material being prepared and is sufficiently mixed in kneader；Step 2: in 1-5 parts of mixtures being added in above-mentioned steps 1 of coupling agent, mixed processing is carried out by way of ultrasonic blending；Step 3, the water-absorbent resin powder for taking 1-5 parts of dryings, are impregnated with 15 parts of water, are made containing water-absorbing resin；Step 4: the principle after above-mentioned steps 2 and step 3 being mixed in the method to be clashed with airflow milling, obtains mixed raw material；Step 5: preparing ceramic tile with the raw material that step 4 mixes；Step 6: carry out drying and processing is carried out to the ceramic tile after step 5.
Description
Technical field
The present invention relates to a kind of construction materials, are specifically that one kind can absorb water ceramic tile.
Background technique
Higher and higher to the needs of construction material under modern society, the resource of consumption also about arrives more, causes serious
Environmental pollution, wherein ceramic tile occupies very big ratio in construction material and its product, on residential households, office and other places
Area's tool has been widely used, and annual digestion amount is also very huge.But existing ceramic tile is due to surface smoother, to water
Adsorption capacity is very weak, and the water of ceramic tile surface is caused to be difficult completely except clean, and to easily lead to ceramic tile dirty, influences beauty.Meanwhile
Existing ceramic tile is substantially to be prepared by inorganic material, and the brittleness of ceramic tile is big, be used for a long time and under the collision of enormous power very
It is easy cracking.Breakage needs further exist for replacing, and leads to the waste of resource.
Summary of the invention
It is an object of the invention to: in view of the above problems, a kind of ceramic tile is provided, by adding water-absorbing resin to be added to
Drying process is passed through in inside simultaneously, so that the surface of ceramic tile and inside form the microcellular structure containing water-absorbing resin, Neng Gouyou
The micro-moisture on its surface of washing one's hands of effect, and preferable impact resistance in time, it is not easy to crack in use process.
The technical solution adopted by the invention is as follows:
It can absorb water ceramic tile the invention discloses one kind, which is characterized in that there are micro- gas in the water suction ceramic tile surface and inside
Water-absorbing resin is contained in micro- stomata in hole.
As an improvement, it is described absorb water ceramic tile the preparation method is as follows:
Step 1: the principle of following parts by weight is subjected to mixed preparing and is sufficiently mixed in kneader:
20 parts of flint, 10 parts of zinc oxide, 40 parts of whiting, 5 parts of tin oxide, 220 parts of magnesite, barium titanate
40 parts, 20 parts of talcum powder；
Step 2: in 1-5 parts of mixtures being added in above-mentioned steps 1 of coupling agent, by way of ultrasonic blending into
Row mixed processing；
Step 3, the water-absorbent resin powder for taking 1-5 parts of dryings, are impregnated with 5-20 parts of water, are made and are set containing water suction
Rouge；
Step 4:: the principle after above-mentioned steps 2 and step 3 is mixed in the method to be clashed with airflow milling, is mixed
Close raw material；
Step 5: preparing ceramic tile with the raw material that step 4 mixes；
Step 6: carry out drying and processing is carried out to the ceramic tile after step 5.
Preferably, the coupling agent of the step 2 is gamma-aminopropyl-triethoxy-silane, γ-glycidyl ether oxygen propyl
Trimethoxy silane, γ-methacryloxypropyl trimethoxy silane, isopropyl three (dioctylphyrophosphoric acid acyloxy) titanium
Acid esters, isopropyl three (dioctyl phosphoric acid acyloxy) titanate esters, two oleic acid acyloxy of isopropyl (dioctyl phosphoric acid acyloxy) titanium
The one or more of acid esters.
Wherein, the water-absorbing resin of the step 3 includes but is not limited to polyacrylic acid sodium salt, polyacrylic acid-acrylamide, gathers
Vinyl alcohol, the one or more of carboxymethylated cellulosic.
Preferably, the drying temperature is 200-500 DEG C, drying time 5-10h.
For the ceramic tile provided by the invention that absorbs water, disclose its partial use, including but not limited to bedroom, parlor,
The application of office.
In conclusion by adopting the above-described technical solution, the beneficial effects of the present invention are:
1, ceramic tile provided by the invention has preferable water imbibition, can quickly absorb the moisture of ceramic tile surface attachment, simultaneously
For the moisture being drawn onto inside ceramic tile, can slowly evaporate.
2, ceramic tile provided by the invention has preferable impact resistance, not easy to crack, long service life.
Specific embodiment
The present invention is described in detail below.
Specific embodiment 1: it can absorb water ceramic tile present embodiment discloses one kind, the water suction ceramic tile surface and inside have
Micro- stomata contains water-absorbing resin in micro- stomata, the preparation method is as follows:
Step 1: the principle of following parts by weight is subjected to mixed preparing and is sufficiently mixed in kneader:
20 parts of flint, 10 parts of zinc oxide, 40 parts of whiting, 5 parts of tin oxide, 220 parts of magnesite, barium titanate
40 parts, 20 parts of talcum powder；
Step 2: in 1-5 parts of mixtures being added in above-mentioned steps 1 of coupling agent, by way of ultrasonic blending into
Row mixed processing；
Step 3, the water-absorbent resin powder for taking 1-5 parts of dryings, are impregnated with 5-20 parts of water, are made and are set containing water suction
Rouge；
Step 4:: the principle after above-mentioned steps 2 and step 3 is mixed in the method to be clashed with airflow milling, is mixed
Close raw material；
Step 5: preparing ceramic tile with the raw material that step 4 mixes；
Step 6: carry out drying and processing is carried out to the ceramic tile after step 5.
Wherein, the coupling agent, to absorb resin, the process conditions in step 6 as shown in table 1.
The ceramic tile that absorbs water described above has a good application prospect in bedroom, parlor, office.
By testing ceramic tile provided in this embodiment, a small amount of moisture on ceramic tile can in 1 minute quick quilt
Blot, soaking effect is good, overhanging beam impact flexibility of the ceramic tile at ISO180-2000/A, 25 DEG C can achieve 30KJ/m2 with
On, impact resistance is strong.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention
Made any modifications, equivalent replacements, and improvements etc., should all be included in the protection scope of the present invention within mind and principle.
Table 1.
Claims (5)
- The ceramic tile 1. one kind can absorb water, which is characterized in that there are micro- stomata in the water suction ceramic tile surface and inside, in micro- stomata Contain water-absorbing resin；It is described water suction ceramic tile the preparation method is as follows:Step 1: the principle of following parts by weight is subjected to mixed preparing and is sufficiently mixed in kneader:20 parts of flint, 10 parts of zinc oxide, 40 parts of whiting, 5 parts of tin oxide, 220 parts of magnesite, barium titanate 40 Part, 20 parts of talcum powder；Step 2: will be added in coupling reaction tank, open agitating device, stirring rotate silicon white powder, by silane coupling agent with After water, dehydrated alcohol are configured to solution according to 1:1:0.5, in the mixture after being sprayed directly on step 1, agitating device is controlled Rotation speed is 4000 revs/min -6000 revs/min, so that the temperature of mixture reaches 120 degrees Celsius, is reacted 10-20 minutes Afterwards, 10-30 minutes obtained coupling modifiers are dried at 100-150 DEG C cross mixture；Step 3: taking the water-absorbent resin powder of 1-5 parts of dryings, impregnated, be made containing water-absorbing resin with 15 parts of water；Step 4: the principle after above-mentioned steps 2 and step 3 being mixed in the method to be clashed with airflow milling, it is former to obtain mixing Material；Step 5: preparing ceramic tile with the raw material that step 4 mixes；Step 6: drying and processing is carried out to the ceramic tile after step 5.
- 2. the ceramic tile according to claim 1 that absorbs water, which is characterized in that in step 2, coupling agent is three second of γ-aminopropyl It is oxysilane, γ-glycidyl ether oxygen propyl trimethoxy silicane, γ-methacryloxypropyl trimethoxy silane, different Propyl three (dioctylphyrophosphoric acid acyloxy) titanate esters, isopropyl three (dioctyl phosphoric acid acyloxy) titanate esters, two oil of isopropyl The one or more of sour acyloxy (dioctyl phosphoric acid acyloxy) titanate esters.
- 3. the ceramic tile according to claim 1 that absorbs water, which is characterized in that in step 3, water-absorbing resin includes but is not limited to poly- The one or more of acrylic acid sodium salt, polyacrylic acid-acrylamide, polyvinyl alcohol, carboxymethylated cellulosic.
- 4. the ceramic tile according to claim 1 that absorbs water, which is characterized in that in step 6, drying temperature is 200-500 DEG C, dries The dry time is 5-10h.
- 5. it is of any of claims 1-4 absorb water ceramic tile bedroom, parlor, office application.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610814084.1A CN106365670B (en) | 2016-09-09 | 2016-09-09 | One kind can absorb water ceramic tile |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610814084.1A CN106365670B (en) | 2016-09-09 | 2016-09-09 | One kind can absorb water ceramic tile |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106365670A CN106365670A (en) | 2017-02-01 |
| CN106365670B true CN106365670B (en) | 2019-04-12 |
Family
ID=57899580
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610814084.1A Expired - Fee Related CN106365670B (en) | 2016-09-09 | 2016-09-09 | One kind can absorb water ceramic tile |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106365670B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108342134A (en) * | 2018-01-09 | 2018-07-31 | 河北晨阳工贸集团有限公司 | Aqueous ceramic paint and preparation method thereof and ceramics and preparation method thereof |
| CN113563116B (en) * | 2021-07-21 | 2022-12-02 | 佛山欧神诺陶瓷有限公司 | Composite ceramic tile and preparation method and application thereof |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MX251840B (en) * | 2003-02-10 | 2007-11-26 | Nippon Catalytic Chem Ind | Particulate water-absorbing agent. |
| WO2008015946A1 (en) * | 2006-07-31 | 2008-02-07 | Nippon Shokubai Co., Ltd. | Production method of water absorbent resin powder and package of water absorbent resin powder |
| SA08290556B1 (en) * | 2007-09-07 | 2012-05-16 | نيبون شوكوباي كو. ، ليمتد | Binding Mehtod of Water Absorbent Resins |
| CN202969205U (en) * | 2012-11-28 | 2013-06-05 | 廖云翔 | Water absorbing floor tile |
-
2016
- 2016-09-09 CN CN201610814084.1A patent/CN106365670B/en not_active Expired - Fee Related
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| Publication number | Publication date |
|---|---|
| CN106365670A (en) | 2017-02-01 |
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| Date | Code | Title | Description |
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| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20190318 Address after: 336000 Yifeng County Industrial Park, Yichun City, Jiangxi Province Applicant after: Jiangxi Century Xingui Ceramics Co.,Ltd. Address before: 610000 Wuhou District Wuhou new town administrative committee, Chengdu, Sichuan, 2 Wuyi East Road 15, 1 units, 2 level 231. Applicant before: CHENGDU JIUSHIDU INDUSTRIAL PRODUCTS DESIGN Co.,Ltd. |
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| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20190412 Termination date: 20210909 |
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| CF01 | Termination of patent right due to non-payment of annual fee |