CN107459952B - A kind of wet glue of wallpaper - Google Patents
A kind of wet glue of wallpaper Download PDFInfo
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- CN107459952B CN107459952B CN201710765855.7A CN201710765855A CN107459952B CN 107459952 B CN107459952 B CN 107459952B CN 201710765855 A CN201710765855 A CN 201710765855A CN 107459952 B CN107459952 B CN 107459952B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J143/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Adhesives based on derivatives of such polymers
- C09J143/04—Homopolymers or copolymers of monomers containing silicon
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of wet glue of wallpaper, belong to building material technical field.The present invention first will be after diatomite ball milling, crushing, sieving, with dehydrated alcohol and butyl titanate mixing ultrasonic disperse, obtain dispersion liquid, under constant temperature stirring, deionized water is slowly added dropwise into dispersion liquid, to completion of dropwise addition, continue constant temperature to be stirred to react, modification infusorial earth slurries, then by gained modification infusorial earth slurries, oleic acid, xylitol, lipase, silicone acrylic emulsion, agar solution, deionized water and antifreezing agent are stirred, up to the wet glue of wallpaper, there are also mussel foot mucoprotein, peach colloidal solution and the mould proof powder of coconut husk are added in the wet glue of wallpaper.The wet glue of wallpaper of the present invention have excellent performance, can be permanently effective prevent wallpaper mouldy, extend the service life of wallpaper.
Description
Technical field
The invention discloses a kind of wet glue of wallpaper, belong to building material technical field.
Background technique
Wallpaper is as a kind of indoor hardware fitting, and because it is with color multiplicity, pattern is abundant, and luxurious style is easy for construction
With a variety of advantages such as affordable, by it is more and more finishing owners favors.Wallpaper net had once done portion to Middle Eastern
Investigation about society to wallpaper cognition and behaviour in service: it is 1.79% with the family that wallpaper carries out Integral decoration metope, specifies table
Show and is ready to carry out the crowd of indoor decoration close to 63% using wallpaper.It is most popular that wallpaper has become today's society home decoration
Decorative material for wall surface, and the selection of Wall paper adhesive and the link the most key using even more wallpaper decoration effect.People are selecting wall
When paper, the quality of wallpaper can be focused on mostly, but often ignore the selection of Wall paper adhesive.In fact, the quality of Wall paper adhesive, more directly
Connect the paving effect for influencing wallpaper.The harmful substances such as formaldehyde, the benzene that may significantly contain in Wall paper adhesive, even more room
The main source of interior air pollution has the effect of carcinogenesis teratogenesis shape, it is possible to cause leukaemia.So-called Wall paper adhesive is by wallpaper
The colloid being sticked on wall.It is divided into two major classes by its material and application.The first kind is the glue pasted suitable for general paper base wallpaper
Glutinous agent, the second class are that there is high wet tack, high level cadre to be suitable for the adhesive that various substrate wallpapers are pasted by force.Again by its physical aspect
It is divided into three kinds of rubber powder type, modulation type, finished product type forms.With the development of Wall paper adhesive, the common Wall paper adhesive in market mainly has at present
Amylan, glutinous rice glue, function glue etc..Wall paper adhesive, emphasis are fallen on glue, be guarantee for clinging wallpaper wallpaper stickup and
Service life is most basic function.Also to require product environmentally friendly simultaneously.Environmental protection cannot be pursued and ignore viscous force, or chased after
It seeks viscous force and ignores environmental protection.
The wet glue of wallpaper is a kind of adhesive for being specifically used to paste wallpaper, and primary raw material is the organic polymer of starch
Polymer.The characteristics of wet glue, is that adhesion strength is strong, and environmentally friendly, is suitble to the wallpaper of adherent cloth and middle and high end, but easily moldy metamorphism.
The commercially available wet glue of wallpaper is generally all with organic mould proof system, itself can quilt during resisting the microbial attacks such as bacterium, mould
Gradually use up, glue film be easy to it is mouldy, wallpaper can large area it is mouldy.
Summary of the invention
The present invention solves the technical problem of: it is easy for the current wet glue of wallpaper mouldy, causes wallpaper also can be big
The mouldy problem of area provides a kind of wet glue of wallpaper.
In order to solve the above-mentioned technical problem, the technical scheme adopted by the invention is that:
A kind of wet glue of wallpaper, is made of the raw material of following parts by weight: 40~50 parts of oleic acid, 40~50 parts of xylitols, 8
~10 parts of lipase, 20~30 parts of silicone acrylic emulsions, 20~30 parts of diatomite, 20~30 parts of butyl titanates, 40~50 parts it is anhydrous
Ethyl alcohol, 40~50 parts of agar solutions, 50~60 parts of deionized waters, 10~20 parts of antifreezing agents；
The preparation process of the wet glue of wallpaper are as follows: each raw material is weighed by raw material composition, first by diatomite ball milling, crushing, mistake
After sieve, with dehydrated alcohol and butyl titanate mixing ultrasonic disperse, dispersion liquid is obtained, under constant temperature stirring, to dispersion liquid
In deionized water is slowly added dropwise, to completion of dropwise addition, continue constant temperature and be stirred to react, obtain modification infusorial earth slurries, then gained is modified
Diatomite slurries, oleic acid, xylitol, lipase, silicone acrylic emulsion, agar solution, deionized water and antifreezing agent are stirred to get wall
The wet glue of paper.
In the silicone acrylic emulsion model silicone acrylic emulsion LR-7220, silicone acrylic emulsion LR-750 or silicone acrylic emulsion LR-720A
Any one.
The configuration process of the agar solution: agar and water being added in beaker for 1:50 in mass ratio, heating stirring to get
Agar solution.
The antifreezing agent is isopropanol, propylene glycol, any one in diethylene glycol (DEG) or ethylene glycol.
0.3~0.4 times of mussel foot mucoprotein of agar solution quality is added in the wet glue of wallpaper.
0.3~0.4 times of peach colloidal solution of agar solution quality is added in the wet glue of wallpaper；The configuration process of institute's number peach colloidal solution are as follows:
It is in mass ratio 1:50 heating stirring to get peach colloidal solution by peach gum and water.
0.03~0.04 times of mould proof powder of coconut husk of agar solution quality is added in the wet glue of wallpaper.
The beneficial effects of the present invention are:
(1) present invention has adsorbed the modification infusorial earth for the nano-titanium dioxide that hydrolysis generates, titanium dioxide warp by addition
The irradiation of light, water and oxygen in catalytic air generate hydroxy radical and oxygen radical, the hydroxy radical and oxygen radical of generation
The microorganism being attached on the wet glue of wallpaper can be killed, effectively prevents wallpaper mouldy；By adding silicone acrylic emulsion, silicone acrylic emulsion
One layer of hydrophobic membrane can be formed in the apparent gap of diatomite, outside moisture can not adhere in hydrophobic film surface to stop, life micro- in this way
Object just cannot get required moisture in metabolic process, can not just survive on Wall paper adhesive after hardening, to further strengthen
The anti-mold effect of the wet glue of wallpaper；By the way that oleic acid, xylitol, lipase, lipase-catalyzed oleic acid and ester of xylitol metaplasia is added
At the oleic acid ester of xylitol, in the long-term use, even if there are a small amount of moisture in system, can also be hydrolyzed by the oleic acid ester of xylitol
And consume, and oleic acid ester of xylitol hydrolysate cannot be absorbed by the micro-organisms utilization again, microorganism absorbs just less than nutritional ingredient
It can not survive, it will be able to which permanently effective prevents wallpaper mouldy, extends the service life of wallpaper；
(2) present invention can not decompose agar solution, ring of the microorganism in nonnutritive ingredient by addition agar solution, microorganism
It can not survive under border, therefore effectively prevent wallpaper mouldy, and agar solution has certain adhesiveness, be also beneficial to improve wallpaper
With the binding force of wall；By the way that a small amount of mussel foot mucoprotein is added, DOPA group be will form discontinuous micro- in mussel foot mucoprotein
Biological support is seen, such biological support constitutes macromolecule network polymers again, further enhances the combination of wallpaper and wall
Power.
Specific embodiment
Agar and water are added in beaker for 1:50~1:100 in mass ratio, are stirred 20~30min with glass bar
Afterwards, 2~4h of swelling is stood, then beaker immigration digital display is tested the speed constant temperature blender with magnetic force, 95~98 DEG C of Yu Wendu, revolving speed 300
Under the conditions of~500r/min, heating stirring dissolves 10~20min to get agar solution；According to parts by weight, 40~50 parts are successively taken
Oleic acid, 40~50 parts of xylitols, 8~10 parts of lipase, 20~30 parts of silicone acrylic emulsions, 20~30 parts of diatomite, 20~30 parts of titaniums
Sour four butyl esters, 40~50 parts of dehydrated alcohols, 40~50 parts of agar solutions, 50~60 parts of deionized waters, 10~20 parts of antifreezing agents first will
Diatomite pours into ball mill, by ball material mass ratio be 15:1~20:1 be added zirconium oxide ball milling pearl, in revolving speed be 200~
Under the conditions of 300r/min after 4~6h of ball mill grinding, 200~300 meshes are crossed, obtain diatomite powder, then by diatomite powder, anhydrous
Ethyl alcohol and butyl titanate are added in beaker, and beaker is then moved to ultrasonic disperse instrument, in supersonic frequency be 60~75kHz condition
Under, 30~40min of ultrasonic disperse obtains dispersion liquid, then dispersion liquid is transferred to three-necked flask, and three-necked flask immigration digital display is tested the speed
Constant temperature blender with magnetic force, in temperature be 45~55 DEG C, under the conditions of revolving speed is 300~500r/min, by dropping funel with 3~
Deionized water is added dropwise into three-necked flask for 5mL/min rate, dripped to deionized water it is complete, continue constant temperature be stirred to react 45~
60min obtains modification infusorial earth slurry, then gained modification infusorial earth slurry is all added in batch mixer, then successively to mixing
Oleic acid, xylitol, lipase, silicone acrylic emulsion, agar solution, deionized water and antifreezing agent are added in machine, in revolving speed be 1100~
High-speed stirred mixes 20~40min under the conditions of 1200r/min, then 0.3~0.4 times of mussel of agar solution quality is added into batch mixer
Sufficient mucoprotein, 0.03~0.04 times of mould proof powder of coconut husk of 0.3~0.4 times of peach colloidal solution of agar solution quality and agar solution quality, in revolving speed
30~50min is mixed to continue high-speed stirred under the conditions of 1100~1200r/min to get the wet glue of wallpaper.The silicone acrylic emulsion type
Number for any one in silicone acrylic emulsion LR-7220, silicone acrylic emulsion LR-750 and silicone acrylic emulsion LR-720A.The antifreezing agent is
Any one in isopropanol, propylene glycol, diethylene glycol (DEG) or ethylene glycol.The configuration process of institute's number peach colloidal solution are as follows: by 1:50 peach gum with
Water heating stirring is to get peach colloidal solution.
Example 1
Agar and water are added in beaker for 1:100 in mass ratio, after being stirred 30min with glass bar, stand swelling
4h, then beaker immigration digital display is tested the speed constant temperature blender with magnetic force, 98 DEG C of Yu Wendu, under the conditions of revolving speed is 500r/min, heating is stirred
Dissolution 20min is mixed to get agar solution；According to parts by weight, 50 parts of oleic acid, 50 parts of xylitols, 10 parts of lipase, 30 parts are successively taken
Silicone acrylic emulsion, 30 parts of diatomite, 30 parts of butyl titanates, 50 parts of dehydrated alcohols, 50 parts of agar solutions, 60 parts of deionized waters, 20 parts
Antifreezing agent first pours into diatomite in ball mill, is that zirconium oxide ball milling pearl is added in 20:1 by ball material mass ratio, is in revolving speed
Under the conditions of 300r/min after ball mill grinding 6h, 300 meshes are crossed, obtain diatomite powder, then by diatomite powder, dehydrated alcohol and titanium
Sour four butyl esters are added in beaker, and beaker is then moved to ultrasonic disperse instrument, under the conditions of supersonic frequency is 75kHz, ultrasonic disperse
40min, obtains dispersion liquid, then dispersion liquid is transferred to three-necked flask, and three-necked flask immigration digital display is tested the speed constant temperature blender with magnetic force,
It is 55 DEG C in temperature, under the conditions of revolving speed is 500r/min, is added dropwise and is gone into three-necked flask with 5mL/min rate by dropping funel
Ionized water, drips complete to deionized water, continues constant temperature and is stirred to react 60min, obtain modification infusorial earth slurry, then gained is modified
Diatomite slurry is all added in batch mixers, is then successively added oleic acid into batch mixer, xylitol, lipase, silicone acrylic emulsion,
Agar solution, deionized water and antifreezing agent, high-speed stirred mixes 40min under the conditions of revolving speed is 1200r/min, then into batch mixer
0.4 times of mussel foot mucoprotein of agar solution quality is added, 0.04 times of coconut husk of 0.4 times of peach colloidal solution of agar solution quality and agar solution quality is anti-
Mould powder continues high-speed stirred under the conditions of revolving speed is 1200r/min and mixes 50min to get the wet glue of wallpaper.The silicone acrylic emulsion type
Number be silicone acrylic emulsion LR-7220.The antifreezing agent is isopropanol.The configuration process of institute's number peach colloidal solution are as follows: by 1:50 peach gum and water
Heating stirring is to get peach colloidal solution.
Example 2
Agar and water are added in beaker for 1:100 in mass ratio, after being stirred 30min with glass bar, stand swelling
4h, then beaker immigration digital display is tested the speed constant temperature blender with magnetic force, 98 DEG C of Yu Wendu, under the conditions of revolving speed is 500r/min, heating is stirred
Dissolution 20min is mixed to get agar solution；According to parts by weight, 50 parts of oleic acid, 50 parts of xylitols, 10 parts of lipase, 30 parts are successively taken
Silicone acrylic emulsion, 30 parts of butyl titanates, 50 parts of dehydrated alcohols, 50 parts of agar solutions, 60 parts of deionized waters, 20 parts of antifreezing agents, then
Oleic acid, xylitol, lipase, silicone acrylic emulsion, agar solution, deionized water and antifreezing agent are successively added into batch mixer, in revolving speed
40min is mixed for high-speed stirred under the conditions of 1200r/min, then 0.4 times of mussel of agar solution quality viscous egg enough is added into batch mixer
It is white, 0.04 times of mould proof powder of coconut husk of 0.4 times of peach colloidal solution of agar solution quality and agar solution quality, under the conditions of revolving speed is 1200r/min
Continue high-speed stirred mixing 50min to get the wet glue of wallpaper.The silicone acrylic emulsion model silicone acrylic emulsion LR-7220.It is described antifreeze
Agent is isopropanol.The configuration process of institute's number peach colloidal solution are as follows: by 1:50 peach gum and water heating stirring to get peach colloidal solution.
Example 3
Agar and water are added in beaker for 1:100 in mass ratio, after being stirred 30min with glass bar, stand swelling
4h, then beaker immigration digital display is tested the speed constant temperature blender with magnetic force, 98 DEG C of Yu Wendu, under the conditions of revolving speed is 500r/min, heating is stirred
Dissolution 20min is mixed to get agar solution；According to parts by weight, 30 parts of silicone acrylic emulsions, 30 parts of diatomite, 30 parts of metatitanic acids four are successively taken
Butyl ester, 50 parts of dehydrated alcohols, 50 parts of agar solutions, 60 parts of deionized waters, 20 parts of antifreezing agents, first pour into diatomite in ball mill,
It is that zirconium oxide ball milling pearl is added in 20:1 by ball material mass ratio, under the conditions of revolving speed is 300r/min after ball mill grinding 6h, crosses 300 mesh
Sieve obtains diatomite powder, then diatomite powder, dehydrated alcohol and butyl titanate is added in beaker, then moves to beaker
Ultrasonic disperse instrument, under the conditions of supersonic frequency is 75kHz, ultrasonic disperse 40min obtains dispersion liquid, then dispersion liquid is transferred to three mouthfuls
Flask, and three-necked flask immigration digital display is tested the speed constant temperature blender with magnetic force, it is 55 DEG C in temperature, revolving speed is 500r/min condition
Under, deionized water is added dropwise into three-necked flask with 5mL/min rate by dropping funel, complete, continuation is dripped to deionized water
Constant temperature is stirred to react 60min, obtains modification infusorial earth slurry, then gained modification infusorial earth slurry is all added in batch mixer, with
Silicone acrylic emulsion, agar solution, deionized water and antifreezing agent is successively added into batch mixer afterwards, under the conditions of revolving speed is 1200r/min
High-speed stirred mixes 40min, then 0.4 times of mussel foot mucoprotein of agar solution quality is added into batch mixer, and 0.4 times of agar solution quality
0.04 times of mould proof powder of coconut husk of peach colloidal solution and agar solution quality continues high-speed stirred mixing under the conditions of revolving speed is 1200r/min
50min is to get the wet glue of wallpaper.The silicone acrylic emulsion model silicone acrylic emulsion LR-7220.The antifreezing agent is isopropanol.Institute's number
The configuration process of peach colloidal solution are as follows: by 1:50 peach gum and water heating stirring to get peach colloidal solution.
Example 4
According to parts by weight, 50 parts of oleic acid, 50 parts of xylitols, 10 parts of lipase, 30 parts of silicone acrylic emulsions, 30 parts of silicon are successively taken
Diatomaceous earth, 30 parts of butyl titanates, 50 parts of dehydrated alcohols, 60 parts of deionized waters, 20 parts of antifreezing agents, first pour into ball mill for diatomite
In, it is that zirconium oxide ball milling pearl is added in 20:1 by ball material mass ratio, under the conditions of revolving speed is 300r/min after ball mill grinding 6h, mistake
300 meshes obtain diatomite powder, then diatomite powder, dehydrated alcohol and butyl titanate are added in beaker, then by beaker
Ultrasonic disperse instrument is moved to, under the conditions of supersonic frequency is 75kHz, ultrasonic disperse 40min obtains dispersion liquid, then dispersion liquid is transferred to
Three-necked flask, and three-necked flask immigration digital display is tested the speed constant temperature blender with magnetic force, it is 55 DEG C in temperature, revolving speed is 500r/min item
Under part, deionized water is added dropwise into three-necked flask with 5mL/min rate by dropping funel, dripped to deionized water it is complete, after
Continuous constant temperature is stirred to react 60min, obtains modification infusorial earth slurry, then gained modification infusorial earth slurry is all added in batch mixer,
Oleic acid, xylitol, lipase, silicone acrylic emulsion, deionized water and antifreezing agent are successively then added into batch mixer, is in revolving speed
High-speed stirred mixes 40min under the conditions of 1200r/min, then 0.4 times of mussel foot mucoprotein of agar solution quality is added into batch mixer,
0.04 times of mould proof powder of coconut husk of 0.4 times of peach colloidal solution of agar solution quality and agar solution quality continues under the conditions of revolving speed is 1200r/min
High-speed stirred mixes 50min to get the wet glue of wallpaper.The silicone acrylic emulsion model silicone acrylic emulsion LR-7220.The antifreezing agent is
Isopropanol.The configuration process of institute's number peach colloidal solution are as follows: by 1:50 peach gum and water heating stirring to get peach colloidal solution.
Comparative example: the wet glue of wallpaper of Suzhou building materials Co., Ltd production.
The wet glue of 1 to 4 gained wallpaper of example and comparative example product are subjected to performance detection according to GB/T21866, it is specific to detect
Method is as follows:
The mould aqueous solution that configuration concentration is 20%.Made wet glue is coated on putty plate by constructing operation, it is equal after dry
The even aqueous solution for spraying mould mixed liquor.It is placed in 37 DEG C or so of mold incubator, observes mouldy situation.After 28d, putty
Not having the mould proof grade of fungus growth on plate is 0 grade, and having the mould proof grade of fungus growth less than 10% area is I grade, aufwuchsplate
Product is II grade more than 10%.Specific testing result is as shown in table 1:
Table 1
| Detection content | Example 1 | Example 2 | Example 3 | Example 4 | Comparative example |
| Mould proof grade | 0 | Ⅰ | Ⅰ | Ⅰ | Ⅱ |
By 1 testing result of table it is found that the mould proof grade of the present invention gained wet glue of wallpaper is high, the current wallpaper of effective solution
Wet glue is easy mouldy problem.
Claims (7)
1. a kind of wet glue of wallpaper, it is characterised in that: be made of the raw material of following parts by weight: 40~50 parts of oleic acid, 40~50
Part xylitol, 8~10 parts of lipase, 20~30 parts of silicone acrylic emulsions, 20~30 parts of diatomite, 20~30 parts of butyl titanates, 40
~50 parts of dehydrated alcohols, 40~50 parts of agar solutions, 50~60 parts of deionized waters, 10~20 parts of antifreezing agents；
The preparation process of the wet glue of wallpaper are as follows: each raw material is weighed by raw material composition, first by after diatomite ball milling, crushing, sieving,
With dehydrated alcohol and butyl titanate mixing ultrasonic disperse, dispersion liquid is obtained, under constant temperature stirring, slowly into dispersion liquid
Deionized water is added dropwise, to completion of dropwise addition, continues constant temperature and is stirred to react, obtains modification infusorial earth slurries, then by gained modification infusorial earth
Slurries, oleic acid, xylitol, lipase, silicone acrylic emulsion, agar solution, deionized water and antifreezing agent are stirred wet to get wallpaper
Glue.
2. the wet glue of a kind of wallpaper according to claim 1, it is characterised in that: the silicone acrylic emulsion model silicone acrylic emulsion
Any one in LR-7220, silicone acrylic emulsion LR-750 or silicone acrylic emulsion LR-720A.
3. the wet glue of a kind of wallpaper according to claim 1, it is characterised in that: the configuration process of the agar solution: pressing quality
Than agar and water are added in beaker for 1:50, heating stirring is to get agar solution.
4. the wet glue of a kind of wallpaper according to claim 1, it is characterised in that: the antifreezing agent be isopropanol, propylene glycol, two
Any one in glycol or ethylene glycol.
5. the wet glue of a kind of wallpaper according to claim 1, it is characterised in that: agar solution quality is added in the wet glue of wallpaper
0.3~0.4 times of mussel foot mucoprotein.
6. the wet glue of a kind of wallpaper according to claim 1, it is characterised in that: agar solution quality is added in the wet glue of wallpaper
0.3~0.4 times of peach colloidal solution；The configuration process of institute's number peach colloidal solution are as follows: by peach gum and water be in mass ratio 1:50 heating stirring to get
Peach colloidal solution.
7. the wet glue of a kind of wallpaper according to claim 1, it is characterised in that: agar solution quality is added in the wet glue of wallpaper
0.03~0.04 times of mould proof powder of coconut husk.
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| CN201710765855.7A CN107459952B (en) | 2017-08-30 | 2017-08-30 | A kind of wet glue of wallpaper |
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| CN107459952B true CN107459952B (en) | 2019-05-03 |
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| CN108914706B (en) * | 2018-07-26 | 2020-06-16 | 山东汇高智慧纺织科技有限公司 | Environment-friendly wallpaper capable of adsorbing formaldehyde |
| CN109231851A (en) * | 2018-08-09 | 2019-01-18 | 苗霞明 | A kind of mould-proof agent for glass |
| CN114262590A (en) * | 2020-09-16 | 2022-04-01 | 志光家具（象州）有限公司 | Special glue for veneer pasting |
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| CN104592825B (en) * | 2014-12-26 | 2018-10-26 | 三棵树涂料股份有限公司 | A kind of art coatings and preparation method thereof |
| CN105567118A (en) * | 2015-12-16 | 2016-05-11 | 张树发 | Dehydrated wall paper wet glue and preparation method thereof |
| CN107022325A (en) * | 2017-04-27 | 2017-08-08 | 无锡市福享天下科技有限公司 | Senior wallpaper wall paper adhesive |
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| CN107459952A (en) | 2017-12-12 |
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