CN106149353B - A kind of multifunctional nano automatically cleaning clothes finishing agent and preparation method thereof - Google Patents
A kind of multifunctional nano automatically cleaning clothes finishing agent and preparation method thereof Download PDFInfo
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- CN106149353B CN106149353B CN201610520450.2A CN201610520450A CN106149353B CN 106149353 B CN106149353 B CN 106149353B CN 201610520450 A CN201610520450 A CN 201610520450A CN 106149353 B CN106149353 B CN 106149353B
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- mixed liquor
- automatically cleaning
- cleaning clothes
- auxiliary material
- mixing speed
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic System; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/325—Amines
- D06M13/332—Di- or polyamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/12—Processes in which the treating agent is incorporated in microcapsules
Abstract
The invention discloses a kind of multifunctional nano automatically cleaning clothes finishing agents, using nano titanium oxide dispersion, lotus leaf extract liquor as major ingredient mixed liquor；Using efficient crosslinking agent, dispersant as auxiliary material mixed liquor；With the liquid flux that latency micro capsule curing agent is persistently enhancing adhesive.The invention also discloses the preparation methods of multifunctional nano automatically cleaning clothes finishing agent, it is first to pour into main material mixture in reaction kettle, 600 900r/min of mixing speed, stir 3 5min, then reaction kettle mixing speed is improved to 1000 1300r/min, auxiliary material mixed liquor is slowly added in 2 3min, and it is 300 500r/min finally to adjust mixing speed, it is slowly added to latency microcapsules liquid flux within 3 5min, ultimately forms Multi-function self-cleaning clothes finishing agent.Reagent of the present invention has the function of to prevent and degrade composite self-cleaning, and treatment effect is made persistently to cure, wash resistant, and nontoxic, of low cost.
Description
Technical field
Intersect technical field the present invention relates to chemical technology, textile technology, and in particular to a kind of multifunctional nano from
Clean clothes finishing agent and preparation method thereof.
Background technology
With the raising that people pursue quality of the life, the requirement to clothes is not limited solely to the quality of clothes, simultaneously
Also focus on other functions of clothes, such as automatically cleaning, antimildew and antibacterial.Washing clothes one is to being the one big negative of people's daily life
Load, the especially quickening of modern life rhythm, working clan is After Hours more tired, and some clothings are not suitable for often washing,
So the automatically cleaning of clothes just has great importance, automatically cleaning garment material is a main trend of garment development.Currently, sharp
Automatically cleaning final finishing is carried out to clothes with nanotechnology and has relevant report at present, but is confined to single decomposition clothes at present
The realization of upper greasy dirt function lacks the prophylactic function for adhering to clothes for preventing greasy dirt.In addition existing reagent and fiber at present
Adhesion can only maintain the short period, cannot be cured for a long time in clothes content, cause its treatment effect to lack persistence, especially
It is that washing fastness is poor.
Invention content
In view of the deficiencies of the prior art, the present invention provides one kind having multiple self-cleaning function, lasting curing characteristics, resistance to
Washing property, nontoxic multifunctional nano automatically cleaning clothes finishing agent and preparation method thereof, and preparation method is simple, it is of low cost.
In order to achieve the above object, the present invention is achieved by the following technical programs：
A kind of multifunctional nano automatically cleaning clothes finishing agent：
1) using nano titanium oxide dispersion, lotus leaf extract liquor as major ingredient mixed liquor；
2) using efficient crosslinking agent, dispersant as auxiliary material mixed liquor；
3) it is the liquid flux for persistently enhancing adhesive with latency micro capsule curing agent.
Preferably, the volume ratio of the nano titanium oxide dispersion and lotus leaf extract liquor is 1:5-1:15.
Preferably, the efficient crosslinking agent is the efficient crosslinking agents of water solubility PU, and the dispersant is to have to lyophobic dust
There is the lignin sulfonic acid sodium salt efficiently acted on.
Preferably, the volume ratio of the efficient crosslinking agents of the water solubility PU and lignin sulfonic acid sodium salt is 3:1-10:1.
Preferably, the liquid flux is diethylenetriamine latency liquid micro capsule curing agent, the diethylenetriamine
The latent time of latency liquid micro capsule curing agent is more than 1 month, and purity is more than 90% or more.
Preferably, the volume ratio of the major ingredient mixed liquor, auxiliary material mixed liquor and liquid flux is 100：1：3-100：5：15.
The preparation method of multifunctional nano automatically cleaning clothes finishing agent, includes the following steps：
1) nano titanium oxide dispersion, lotus leaf extract liquor are poured into proportion in reaction kettle, is stirred to form major ingredient
Mixed liquor, mixing speed 600-900r/min stir 3-5min, so that it is uniformly distributed and form fine particle；
2) reaction kettle mixing speed is improved to 1000-1300r/min, efficient crosslinking agent, dispersant is mixed in proportion
Even obtained auxiliary material mixed liquor, is slowly added into 2-3min in reaction kettle, during which maintains mixing speed constant, keeps auxiliary material mixed
Object is closed to be evenly distributed in major ingredient mixed liquor；
3) adjustment reaction kettle mixing speed is 300-500r/min, and liquid flux is slowly added in 3-5min, is during which tieed up
Mixing speed is held, makes that liquid flux is uniform, undamaged is distributed in the mixed liquor of the major ingredient and auxiliary material made to get more
Function nano automatically cleaning clothes finishing agent.
Advantageous effect of the present invention：The present invention uses nano-titanium dioxide, lotus leaf extract liquor for main material mixed liquor, assigns from clear
Clean clothes prevent and decompose complex function, wherein lotus leaf extracts liquid energy and forms one layer of greasy-dirt separation film, Neng Gouyou in clothing surface
Effect prevents the substances such as greasy dirt from adhering on clothes, and nano-titanium dioxide then surprisingly adheres to small part the objects such as the greasy dirt on clothes
Matter is decomposed；Using efficient crosslinking agent, dispersant as auxiliary material mixed liquor, can effectively improve its adhesion performance with clothing fibers and
Dispersing uniformity；It is the liquid flux for enhancing adhesive with latency micro capsule curing agent, makes curing agent when inner is long
Between slowly discharge, to the adhesion fastness of long-term continual Contrast agent and clothes, to promote its persistence.This is sent out
Bright nano self-cleaning clothes finishing agent is covered with paint, lacquer, colour wash, etc. onto garment material, does not change the characteristic of fabric, function-stable, resistance to cleaning, tool
There is prevention, decompose multi-efficiency, have a extensive future, there is prodigious application value.
Specific implementation mode
In order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below in conjunction with the embodiment of the present invention,
Technical scheme in the embodiment of the invention is clearly and completely described, it is clear that described embodiment is the present invention one
Divide embodiment, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art are not making
The every other embodiment obtained under the premise of creative work, shall fall within the protection scope of the present invention.
Embodiment 1：
A kind of multifunctional nano automatically cleaning clothes finishing agent, using nano titanium oxide dispersion, lotus leaf extract liquor as major ingredient
Mixed liquor is persistently to enhance adhesive with latency micro capsule curing agent using efficient crosslinking agent, dispersant as auxiliary material mixed liquor
Liquid flux.Wherein, the volume ratio of nano titanium oxide dispersion and lotus leaf extract liquor is 1:8；Efficient crosslinking agent is water solubility
The efficient crosslinking agents of PU, dispersant are the lignin sulfonic acid sodium salt for having efficiently effect to lyophobic dust, volume ratio 5:1；
Liquid flux is diethylenetriamine latency liquid micro capsule curing agent, and latent time is 3 months, purity 95%.Major ingredient
The volume ratio of mixed liquor, auxiliary material mixed liquor and liquid flux is 100：2：4.
The preparation method of multifunctional nano automatically cleaning clothes finishing agent, includes the following steps：
1) nano titanium oxide dispersion, lotus leaf extract liquor are poured into proportion in reaction kettle, is stirred to form major ingredient
Mixed liquor, mixing speed 800r/min stir 4min, so that it is uniformly distributed and form fine particle；
2) reaction kettle mixing speed is improved to 1200r/min, and efficient crosslinking agent, dispersant are mixed in proportion to obtain
Auxiliary material mixed liquor, be slowly added into reaction kettle in 3min, during which maintain mixing speed it is constant, keep auxiliary material mixture uniform
It is distributed in major ingredient mixed liquor；
3) adjustment reaction kettle mixing speed is 400r/min, and liquid flux is slowly added in 4min, during which maintains stirring
Speed, makes that liquid flux is uniform, undamaged be distributed in the mixed liquor of the major ingredient and auxiliary material made is received to get multi-functional
Rice automatically cleaning clothes finishing agent.
Embodiment 2：
A kind of multifunctional nano automatically cleaning clothes finishing agent, using nano titanium oxide dispersion, lotus leaf extract liquor as major ingredient
Mixed liquor is persistently to enhance adhesive with latency micro capsule curing agent using efficient crosslinking agent, dispersant as auxiliary material mixed liquor
Liquid flux.Wherein, the volume ratio of nano titanium oxide dispersion and lotus leaf extract liquor is 1:5；Efficient crosslinking agent is water solubility
The efficient crosslinking agents of PU, dispersant are the lignin sulfonic acid sodium salt for having efficiently effect to lyophobic dust, volume ratio 3:1；
Liquid flux is diethylenetriamine latency liquid micro capsule curing agent, 3 months latent times, purity 95%.Major ingredient is mixed
The volume ratio for closing liquid, auxiliary material mixed liquor and liquid flux is 100：1：3.
The preparation method of multifunctional nano automatically cleaning clothes finishing agent, includes the following steps：
1) nano titanium oxide dispersion, lotus leaf extract liquor are poured into proportion in reaction kettle, is stirred to form major ingredient
Mixed liquor, mixing speed 700r/min stir 3min, so that it is uniformly distributed and form fine particle；
2) reaction kettle mixing speed is improved to 1200r/min, and efficient crosslinking agent, dispersant are mixed in proportion to obtain
Auxiliary material mixed liquor, be slowly added into reaction kettle in 3min, during which maintain mixing speed it is constant, keep auxiliary material mixture uniform
It is distributed in major ingredient mixed liquor；
3) adjustment reaction kettle mixing speed is 300r/min, and liquid flux is slowly added in 4min, during which maintains stirring
Speed, makes that liquid flux is uniform, undamaged be distributed in the mixed liquor of the major ingredient and auxiliary material made is received to get multi-functional
Rice automatically cleaning clothes finishing agent.
Embodiment 3：
A kind of multifunctional nano automatically cleaning clothes finishing agent, using nano titanium oxide dispersion, lotus leaf extract liquor as major ingredient
Mixed liquor is persistently to enhance adhesive with latency micro capsule curing agent using efficient crosslinking agent, dispersant as auxiliary material mixed liquor
Liquid flux.Wherein, the volume ratio of nano titanium oxide dispersion and lotus leaf extract liquor is 1:15；Efficient crosslinking agent is water solubility
The efficient crosslinking agents of PU, dispersant are the lignin sulfonic acid sodium salt for having efficiently effect to lyophobic dust, volume ratio 10:1；
Liquid flux is diethylenetriamine latency liquid micro capsule curing agent, and latent time is 2 months, purity 92%.Major ingredient
The volume ratio of mixed liquor, auxiliary material mixed liquor and liquid flux is 100：5：15.
The preparation method of multifunctional nano automatically cleaning clothes finishing agent, includes the following steps：
1) nano titanium oxide dispersion, lotus leaf extract liquor are poured into proportion in reaction kettle, is stirred to form major ingredient
Mixed liquor, mixing speed 900r/min stir 3min, so that it is uniformly distributed and form fine particle；
2) reaction kettle mixing speed is improved to 1300r/min, and efficient crosslinking agent, dispersant are mixed in proportion to obtain
Auxiliary material mixed liquor, be slowly added into reaction kettle in 2min, during which maintain mixing speed it is constant, keep auxiliary material mixture uniform
It is distributed in major ingredient mixed liquor；
3) adjustment reaction kettle mixing speed is 500r/min, and liquid flux is slowly added in 3min, during which maintains stirring
Speed, makes that liquid flux is uniform, undamaged be distributed in the mixed liquor of the major ingredient and auxiliary material made is received to get multi-functional
Rice automatically cleaning clothes finishing agent.
Embodiment 4：
A kind of multifunctional nano automatically cleaning clothes finishing agent, using nano titanium oxide dispersion, lotus leaf extract liquor as major ingredient
Mixed liquor is persistently to enhance adhesive with latency micro capsule curing agent using efficient crosslinking agent, dispersant as auxiliary material mixed liquor
Liquid flux.Wherein, the volume ratio of nano titanium oxide dispersion and lotus leaf extract liquor is 1:10；Efficient crosslinking agent is water solubility
The efficient crosslinking agents of PU, dispersant are the lignin sulfonic acid sodium salt for having efficiently effect to lyophobic dust, volume ratio 6:1；
Liquid flux is diethylenetriamine latency liquid micro capsule curing agent, and latent time is 4 months, purity 97%.Major ingredient
The volume ratio of mixed liquor, auxiliary material mixed liquor and liquid flux is 100：3：10.
The preparation method of multifunctional nano automatically cleaning clothes finishing agent, includes the following steps：
1) nano titanium oxide dispersion, lotus leaf extract liquor are poured into proportion in reaction kettle, is stirred to form major ingredient
Mixed liquor, mixing speed 600r/min stir 5min, so that it is uniformly distributed and form fine particle；
2) reaction kettle mixing speed is improved to 1000r/min, and efficient crosslinking agent, dispersant are mixed in proportion to obtain
Auxiliary material mixed liquor, be slowly added into reaction kettle in 3min, during which maintain mixing speed it is constant, keep auxiliary material mixture uniform
It is distributed in major ingredient mixed liquor；
3) adjustment reaction kettle mixing speed is 300r/min, and liquid flux is slowly added in 5min, during which maintains stirring
Speed, makes that liquid flux is uniform, undamaged be distributed in the mixed liquor of the major ingredient and auxiliary material made is received to get multi-functional
Rice automatically cleaning clothes finishing agent.
Embodiment 5：
A kind of multifunctional nano automatically cleaning clothes finishing agent, using nano titanium oxide dispersion, lotus leaf extract liquor as major ingredient
Mixed liquor is persistently to enhance adhesive with latency micro capsule curing agent using efficient crosslinking agent, dispersant as auxiliary material mixed liquor
Liquid flux.Wherein, the volume ratio of nano titanium oxide dispersion and lotus leaf extract liquor is 1:12；Efficient crosslinking agent is water solubility
The efficient crosslinking agents of PU, dispersant are the lignin sulfonic acid sodium salt for having efficiently effect to lyophobic dust, volume ratio 8:1；
Liquid flux is diethylenetriamine latency liquid micro capsule curing agent, and latent time is 3 months, purity 90%.Major ingredient
The volume ratio of mixed liquor, auxiliary material mixed liquor and liquid flux is 100：4：15.
The preparation method of multifunctional nano automatically cleaning clothes finishing agent, includes the following steps：
1) nano titanium oxide dispersion, lotus leaf extract liquor are poured into proportion in reaction kettle, is stirred to form major ingredient
Mixed liquor, mixing speed 700r/min stir 4min, so that it is uniformly distributed and form fine particle；
2) reaction kettle mixing speed is improved to 1100r/min, and efficient crosslinking agent, dispersant are mixed in proportion to obtain
Auxiliary material mixed liquor, be slowly added into reaction kettle in 3min, during which maintain mixing speed it is constant, keep auxiliary material mixture uniform
It is distributed in major ingredient mixed liquor；
3) adjustment reaction kettle mixing speed is 400r/min, and liquid flux is slowly added in 5min, during which maintains stirring
Speed, makes that liquid flux is uniform, undamaged be distributed in the mixed liquor of the major ingredient and auxiliary material made is received to get multi-functional
Rice automatically cleaning clothes finishing agent is to get multifunctional nano automatically cleaning clothes finishing agent.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations；Although with reference to the foregoing embodiments
Invention is explained in detail, it will be understood by those of ordinary skill in the art that：It still can be to aforementioned each implementation
Technical solution recorded in example is modified or equivalent replacement of some of the technical features；And these modification or
It replaces, the spirit and scope for various embodiments of the present invention technical solution that it does not separate the essence of the corresponding technical solution.
Claims (6)
1. a kind of multifunctional nano automatically cleaning clothes finishing agent, it is characterised in that：
1) using nano titanium oxide dispersion, lotus leaf extract liquor as major ingredient mixed liquor；
2) using efficient crosslinking agent, dispersant as auxiliary material mixed liquor；
3) it is the liquid flux for persistently enhancing adhesive with latency micro capsule curing agent；
The efficient crosslinking agent is the efficient crosslinking agents of water solubility PU, and dispersant is to have the wooden of efficiently effect to lyophobic dust
Plain sulfonate sodium；The liquid flux is diethylenetriamine latency liquid micro capsule curing agent.
2. multifunctional nano automatically cleaning clothes finishing agent according to claim 1, it is characterised in that：The nanometer titanium dioxide
The volume ratio of titanium dispersion liquid and lotus leaf extract liquor is 1:5-1:15.
3. multifunctional nano automatically cleaning clothes finishing agent according to claim 1, it is characterised in that：The water solubility PU high
The volume ratio for imitating crosslinking agent and lignin sulfonic acid sodium salt is 3:1-10:1.
4. multifunctional nano automatically cleaning clothes finishing agent according to claim 1, it is characterised in that：The diethylenetriamine
The latent time of latency liquid micro capsule curing agent is more than 1 month, and purity is more than 90% or more.
5. multifunctional nano automatically cleaning clothes finishing agent according to claim 1, it is characterised in that：The major ingredient mixing
The volume ratio of liquid, auxiliary material mixed liquor and liquid flux is 100：1：3-100：5：15.
6. according to the preparation method of any multifunctional nano automatically cleaning clothes finishing agents of claim 1-5, feature exists
In including the following steps：
1) nano titanium oxide dispersion, lotus leaf extract liquor are poured into proportion in reaction kettle, is stirred to form major ingredient mixing
Liquid, mixing speed 600-900r/min stir 3-5min, so that it is uniformly distributed and form fine particle；
2) reaction kettle mixing speed is improved to 1000-1300r/min, and efficient crosslinking agent, dispersant are mixed in proportion
The auxiliary material mixed liquor arrived, is slowly added into 2-3min in reaction kettle, during which maintains mixing speed constant, makes auxiliary material mixed liquor
It is evenly distributed in major ingredient mixed liquor；
3) adjustment reaction kettle mixing speed is 300-500r/min, and liquid flux is slowly added in 3-5min, during which maintains to stir
Speed is mixed, makes that liquid flux is uniform, undamaged is distributed in the mixed liquor of the major ingredient and auxiliary material made to get multi-functional
Nano self-cleaning clothes finishing agent.
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| CN201610520450.2A CN106149353B (en) | 2016-07-01 | 2016-07-01 | A kind of multifunctional nano automatically cleaning clothes finishing agent and preparation method thereof |
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| CN106149353A CN106149353A (en) | 2016-11-23 |
| CN106149353B true CN106149353B (en) | 2018-07-17 |
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| CN110670346A (en) * | 2019-09-03 | 2020-01-10 | 无锡德冠生物科技有限公司 | Biomass three-proofing finishing agent and preparation method thereof |
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| WO2005083013A1 (en) * | 2004-01-30 | 2005-09-09 | Millennium Chemicals | Coating composition having surface depolluting properties |
| CA2749152C (en) * | 2009-01-08 | 2018-06-26 | The University Of Western Ontario | Self-cleaning coatings |
| CN101498099B (en) * | 2009-02-20 | 2011-08-24 | 西安工程大学 | Preparation of ultra water-repellent and oil-repellent fabric |
| CN101880961B (en) * | 2009-07-21 | 2012-08-29 | 上海工程技术大学 | Series modified nano titanium dioxide photo-catalyst textile finishing agent and preparation method |
| KR100959925B1 (en) * | 2009-09-24 | 2010-05-26 | 김태진 | High reflection coating composition having self-cleaning function |
| CN101736594B (en) * | 2009-12-29 | 2012-07-04 | 浙江三元电子科技有限公司 | Manufacture method of antibacterial ultraviolet resisting electromagnetic shielding fabric |
| CN103485187A (en) * | 2013-09-16 | 2014-01-01 | 苏州志向纺织科研股份有限公司 | Finishing process for self-cleaning anti-bacterial and odor-resistant multifunctional dacron fabric |
| CN104409545B (en) * | 2014-11-14 | 2016-08-17 | 无锡中洁能源技术有限公司 | A kind of self-cleaning type back film of solar cell and preparation method thereof |
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