CN107447534A - 一种数码直喷弱溶剂双面打印广告布及其制备工艺 - Google Patents
一种数码直喷弱溶剂双面打印广告布及其制备工艺 Download PDFInfo
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Abstract
本发明及一种数码直喷弱溶剂双面打印广告布,包括涤纶化纤布层,涤纶化纤布层的一面设有增白防水涂层,增白防水涂层的表面设有三氧化二锑阻燃涂层,三氧化二锑阻燃涂层的表面设有弱溶剂墨水吸收涂层,涤纶化纤布层的另一面设有热升华墨水吸收涂层。发明还涉及一种广告布的制备工艺。本发明中的广告布,在实际应用中,具有良好柔软性、耐皱性、抗阻燃性能,而且一面可打印水性墨水,另一面可打印弱溶剂墨水。
Description
技术领域
本发明涉及一种广告布,尤其涉及一种数码直喷弱溶剂双面打印广告布。
背景技术
目前市场上的广告布主要包括单面打印的化纤布广告布和PVC广告布两大类广告布产品。在实际使用中存在以下问题:(1)传统的PVC广告布,打印后不能折叠,使用后不易降解,污染环境,并含有对人体有害的增塑剂及重金属物质;(2)新型的化纤布类广告布,一般只能满足单面打印,无法同时满足客户对不同墨水的需求;(3)现有的广告布抗阻燃性能差。因此针对上述问题,有必要研制一种数码直喷弱溶剂双面打印广告布,同时建立相应的制备工艺。
发明内容
本发明所要解决的技术问题是:针对现有技术的不足,提供一种具有良好柔软性、耐皱性、抗阻燃性能,而且一面可打印水性墨水,另一面可打印弱溶剂墨水的双面打印广告布。
为解决上述技术问题,本发明的技术方案是:
一种数码直喷弱溶剂双面打印广告布,包括涤纶化纤布层,所述涤纶化纤布层的一面设有增白防水涂层,所述增白防水涂层的表面设有复合阻燃涂层,所述复合阻燃涂层的表面设有弱溶剂墨水吸收涂层,所述涤纶化纤布层的另一面设有热升华墨水吸收涂层。
作为一种改进的技术方案,所述增白防水涂层为增白剂、防水剂和增稠剂复合涂布在所述涤纶化纤布层的一面所形成的涂层。
作为一种优选的技术方案,所述增白剂为双苯乙烯型衍生物,所述防水剂为含氟防水剂或无氟防水剂,所述增稠剂为PTF增稠剂。
作为一种改进的技术方案,所述复合阻燃涂层为水性丙烯酸乳液、三氧化二锑、多聚磷酸酯、无机填料和消泡剂复合涂布在的所述增白防水涂层的表面所形成的涂层。
作为一种改进的技术方案,所述弱溶剂墨水吸收涂层为水性聚丙烯酸乳液、聚乙烯蜡、二氧化硅、消泡剂和碳酸钙复合涂布在所述复合阻燃涂层的表面所形成的涂层。
作为一种优选的技术方案,所述消泡剂为矿物油类、有机硅类或聚醚类。
作为一种改进的技术方案,所述热升华墨水吸收涂层为热升华涂料、水和增稠剂复合涂布在所述涤纶化纤布层的另一面所形成的涂层。
本发明所要解决的另一个技术问题是:针对现有技术的不足,提供一种具有良好柔软性、耐皱性、抗阻燃性能,而且一面可打印水性墨水,另一面可打印弱溶剂墨水的双面打印广告布的制备工艺。
为解决上述技术问题,本发明的技术方案是:
一种数码直喷弱溶剂双面打印广告布的制备工艺,所述制备工艺包括以下步骤:
(1)增白防水涂层涂料的配置及涂布
按照重量份计将水500-1000份、增白剂1-8份、防水剂10-60份和增稠剂5-20份混匀,调pH7-8,得到粘度为20000-50000cps的增白防水涂料,利用底板刮刀涂布方式将增白防水涂料涂布在涤纶化纤布层的一面,经过干燥固化处理,形成增白防水涂层;
(2)复合阻燃涂层涂料的配置及涂布
按照重量份计将水性聚丙烯酸乳液50-70份、无机填料10-15份、三氧化二锑10-30份、多聚磷酸酯10-30份、消泡剂0.2-1份混匀,调pH6-8,得到粘度为8000-15000cps的复合阻燃涂料,利用底板刮刀涂布方式将复合阻燃涂料涂布在增白防水涂层的表面,经过干燥固化处理,形成复合阻燃涂层;
(3)弱溶剂墨水吸收涂层涂料的配置及涂布
按照重量份计将水性聚丙烯酸乳液50-70份、聚乙烯蜡5-10份、二氧化硅5-10份、碳酸钙5-10份、消泡剂0.2-1份混匀,调pH7-8,得到粘度为2000-5000cps的弱溶剂墨水吸收涂料,利用底板刮刀涂布方式将弱溶剂墨水吸收涂料涂布在复合阻燃涂层的表面,经过干燥固化处理,形成弱溶剂墨水吸收涂层;
(4)热升华墨水吸收涂层涂料的配置及涂布
按照重量分数计将水50-100份、热升华涂料20-30份、增稠剂2-5份混匀,调pH6-8,得到粘度为20000-30000cps的热升华墨水吸收涂料,利用底板刮刀涂方式将热升华墨水吸收涂料涂布在涤纶化纤布层的另一面,经过干燥固化处理,形成热升华墨水吸收涂层,最后经过收卷、质量检测,分切包装得到数码直喷弱溶剂双面打印广告布,最后经过收卷、质量检测,分切包装得到数码直喷弱溶剂双面打印广告布。
作为一种改进的技术方案,步骤(1)中底板刮刀涂布时利用3-4mm靴型刀进行涂布,干燥固化处理的温度为120-180℃,涂布车速为40-50m/min;
步骤(2)中底板刮刀涂布时利用4-8mm E型刀,干燥固化处理的温度为120-170℃,涂布车速为15-20m/min;
步骤(3)中底板刮刀涂布时利用4-8mm E型刀,干燥固化处理的温度为60-130℃,涂布车速为10-20m/min;
步骤(4)中底板刮刀涂布时利用3-4mm靴型刀,干燥固化处理的温度为60-150℃,涂布车速为15-20m/min。
采用了上述技术方案后,本发明的有益效果是:
(1)本发明中的广告布,采用底板刮涂方式在涤纶化纤布层的表面涂布增白防水涂层,由于增白防水涂层为增白剂、防水剂和增稠剂复合形成的涂层,通过对增白防水涂料的增稠处理,控制涂料的粘度,利用特定形状的刮刀控制防水料在涤纶化纤布层的渗透程度,最终实现单面防水性能,由于防水涂层的涂布可降低其他涂层涂料进入坯布的量,使产品具有良好的柔软性及耐褶皱性,方便了客户的使用,产品打印后,客户可以任意折叠,不会对画面及产品造成损害;
(2)本发明中的广告布,在增白防水涂层的表面涂布有复合阻燃涂层,由于复合阻燃涂层的涂料为聚丙烯酸乳液、无机填料、三氧化二锑、多聚磷酸酯、消泡剂混合而成,三氧化二锑和多聚磷酸酯的联合应用使广告布具有较好的阻燃性能;
(3)本产品采取刮涂方式涂布弱溶剂墨水吸收涂层,省料,生产成本更低;本产品同时兼容不同性能的墨水,防水面可以打印弱溶剂、Latex、UV墨水,不防水的一面可以吸收热升华墨水;本发明中的广告布涂布弱溶剂墨水吸收涂层可完美的还原墨水的色彩,为印品提供高质量的图案;热升华墨水吸收涂层的涂布可使墨水升华进入基材纤维内部,然后固色,其打印色彩超级鲜艳,而且耐水洗。
附图说明
图1为本发明数码直喷弱溶剂双面打印广告布的剖面图;
其中,1-涤纶化纤布层,2-增白防水涂层,3-复合阻燃涂层,4-弱溶剂墨水吸收涂层,5-热升华墨水吸收涂层。
具体实施方式
为了使本发明的目的、技术方案及优点更加清楚明白,以下结合附图和实施例,对本发明进行进一步详细说明。应当理解,此处所描述的具体实施例仅仅用以解释本发明,并不用于限定本发明。
实施例1
一种数码直喷弱溶剂双面打印广告布,如图1所示,包括涤纶化纤布层1,涤纶化纤布层1的一面设有增白防水涂层2,增白防水涂层2的表面设有复合阻燃涂层3,复合阻燃涂层3的表面设有弱溶剂墨水吸收涂层4,涤纶化纤布层1的另一面设有热升华墨水吸收涂层5。其中增白防水涂层2的涂布量为40-50gsm;复合阻燃涂层3的涂布量为40-50gsm;弱溶剂墨水吸收涂层4的涂布量为20-30gsm;热升华墨水吸收涂层5的涂布量为40-50gsm。
其中增白防水涂层2为增白剂(双苯乙烯型衍生物)、防水剂(八碳氟系防水防油剂)和增稠剂(PTF增稠剂)复合涂布在涤纶化纤布层1的表面所形成的涂层;
弱溶剂墨水吸收涂层4为水性聚丙烯酸乳液、聚乙烯蜡、二氧化硅、无机填料和消泡剂复合涂布在复合阻燃涂层的表面所形成的涂层。
热升华墨水吸收涂层5为热升华涂料、水和增稠剂复合涂布在涤纶化纤布层的一面所形成的热升华墨水吸收涂层。
其制备工艺,包括以下步骤:
(1)增白防水涂层涂料的配置及涂布
按照重量份计将水500份、增白剂1.5份、防水剂12份和增稠剂5份混匀,调pH7.2,得到粘度为20000cps的增白防水涂料,利用3mm靴型刀按照40gsm的涂布湿量将增白防水涂料涂布在涤纶化纤布层的一面,利用8节烘箱进行干燥固化处理,其中烘箱温度依次设置为120℃、150℃、160℃、160℃、170℃、180℃、180℃、180℃,涂布车速为40m/min;
(2)复合阻燃涂层涂料的配置及涂布
按照重量份计将水性聚丙烯酸乳液50份、无机填料10份(高岭土3份、钙粉5份、二氧化硅2份)、三氧化二锑10份、多聚磷酸酯10份、消泡剂0.2份(矿物油类)混匀,调pH6.8,得到粘度为8000cps的复合阻燃涂料,利用4mm E型刀按照40gsm的涂布湿量将复合阻燃涂料涂布在增白防水涂层的表面,用8节烘箱进行干燥固化处理,其中烘箱温度依次设置为120℃、170℃、170℃、170℃、170℃、170℃、170℃、150℃,涂布车速为15m/min;
(3)弱溶剂墨水吸收涂层涂料的配置及涂布
按照重量份计将水性聚丙烯酸乳液50份、聚乙烯蜡5份、二氧化硅5份、碳酸钙5份、消泡剂0.2份(有机硅类)混匀,调pH7.2,得到粘度为2000cps的弱溶剂墨水吸收涂料,利用4mm E型刀按照20gsm的涂布湿量将弱溶剂墨水吸收涂料涂布在复合阻燃涂层的表面,用8节烘箱进行干燥固化处理,其中烘箱的温度依次设置为60℃、80℃、100℃、120℃、130℃、130℃、130℃、100℃,涂布车速为20m/min;
(4)热升华墨水吸收涂层涂料的配置及涂布
按照重量分数计将水50份、热升华涂料20份、增稠剂2份混匀,调pH6.8,得到粘度为20000cps的热升华墨水吸收涂料,利用3mm靴型刀按照40gsm的涂布湿量将热升华墨水吸收涂料涂布在涤纶化纤布层的另一面,再利用8节烘箱进行干燥固化处理,其中烘箱温度依次设置为60℃、80℃、90℃、150℃、150℃、150℃、150℃、150℃,涂布车速为18m/min。涂布结束后最后经过收卷、质量检测,分切包装得到数码直喷弱溶剂双面打印广告布。
实施例2
一种数码直喷弱溶剂双面打印广告布,如图1所示,包括涤纶化纤布层1,涤纶化纤布层1的一面设有增白防水涂层2,增白防水涂层2的表面设有复合阻燃涂层3,复合阻燃涂层3的表面设有弱溶剂墨水吸收涂层4,涤纶化纤布层1的另一面设有热升华墨水吸收涂层5。其中增白防水涂层2为增白剂、防水剂和增稠剂复合涂布在涤纶化纤布层1的表面所形成的涂层;
弱溶剂墨水吸收涂层4为水性聚丙烯酸乳液、聚乙烯蜡、二氧化硅、无机填料和消泡剂复合涂布在复合阻燃涂层的表面所形成的涂层。
热升华墨水吸收涂层5为热升华涂料、水和增稠剂复合涂布在涤纶化纤布层的一面所形成的热升华墨水吸收涂层。
其制备方法包括以下步骤:
(1)增白防水涂层涂料的配置及涂布
按照重量份计将800份、增白剂(双苯乙烯型衍生物)4份、防水剂(六碳氟系防水防油剂)50份和增稠剂(PTF增稠剂)15份混匀,调pH7.5,得到粘度为40000cps的增白防水涂料,利用4mm靴型刀按照45gsm的涂布湿量将增白防水涂料涂布在涤纶化纤布层的一面,利用8节烘箱进行干燥固化处理,其中烘箱温度依次设置为120℃、150℃、160℃、160℃、170℃、180℃、180℃、180℃,涂布车速为45m/min;
(2)复合阻燃涂层涂料的配置及涂布
按照重量份计将水性聚丙烯酸乳液63份、无机填料13份(高岭土5份、二氧化硅5份、钙粉3份)、三氧化二锑20份、多聚磷酸酯20份、消泡剂0.5份(有机硅类)混匀,调pH7.3,得到粘度为10000cps的复合阻燃涂料,利用6mm E型刀按照45gsm的涂布湿量将复合阻燃涂料涂布在增白防水涂层的表面,用8节烘箱进行干燥固化处理,其中烘箱温度依次设置为120℃、170℃、170℃、170℃、170℃、170℃、170℃、150℃,涂布车速为18m/min;
(3)弱溶剂墨水吸收涂层涂料的配置及涂布
按照重量份计将水性聚丙烯酸乳液63份、聚乙烯蜡8份、二氧化硅8份、碳酸钙8份、消泡剂0.8份(聚醚类)混匀,调pH7.5,得到粘度为3000cps的弱溶剂墨水吸收涂料,利用6mmE型刀按照25gsm的涂布湿量将弱溶剂墨水吸收涂料涂布在复合阻燃涂层的表面,用8节烘箱进行干燥固化处理,其中烘箱的温度依次设置为60℃、80℃、100℃、120℃、130℃、130℃、130℃、100℃,涂布车速为20m/min
(4)热升华墨水吸收涂层涂料的配置及涂布
按照重量分数计将水80份、热升华涂料25份、增稠剂3.5份(PTF增稠剂)混匀,调pH7.5,得到粘度为25000cps的热升华墨水吸收涂料,利用4mm靴型刀按照45gsm的涂布湿量将热升华墨水吸收涂料涂布在涤纶化纤布层的另一面,再利用9节烘箱进行干燥固化处理,其中烘箱温度依次设置为60℃、80℃、90℃、150℃、150℃、150℃、150℃、150℃,涂布车速为18m/min。最后经过收卷、质量检测,分切包装得到数码直喷弱溶剂双面打印广告布。
实施例3
一种数码直喷弱溶剂双面打印广告布,如图1所示,包括涤纶化纤布层1,涤纶化纤布层1的一面设有增白防水涂层2,增白防水涂层2的表面设有复合阻燃涂层3,复合阻燃涂层3的表面设有弱溶剂墨水吸收涂层4,涤纶化纤布层1的另一面设有热升华墨水吸收涂层5。其中增白防水涂层2为增白剂、防水剂和增稠剂复合涂布在涤纶化纤布层1的表面所形成的涂层;
弱溶剂墨水吸收涂层4为水性聚丙烯酸乳液、聚乙烯蜡、二氧化硅、无机填料和消泡剂复合涂布在复合阻燃涂层的表面所形成的涂层。
热升华墨水吸收涂层5为热升华涂料、水和增稠剂复合涂布在涤纶化纤布层的一面所形成的热升华墨水吸收涂层。
其制备方法包括以下步骤:
(1)增白防水涂层涂料的配置及涂布
按照重量份计将水1000份、增白剂8份(双苯乙烯型衍生物)、防水剂(C8无氟防水剂)55份和增稠剂20份(PTF增稠剂)混匀,调pH8,得到粘度为50000cps的增白防水涂料,利用4mm靴型刀按照50gsm的涂布湿量将增白防水涂料涂布在涤纶化纤布层的一面,利用8节烘箱进行干燥固化处理,其中烘箱温度依次设置为120℃、150℃、160℃、160℃、170℃、180℃、180℃、180℃,涂布车速为50m/min;
(2)复合阻燃涂层涂料的配置及涂布
按照重量份计将水性聚丙烯酸乳液70份、无机填料15份(钙粉3份、二氧化硅3份、高岭土9份)、三氧化二锑20份、多聚磷酸酯30份、消泡剂1份(聚醚类)混匀,调pH7.8,得到粘度为12000cps的复合阻燃涂料,利用7mm E型刀按照50gsm的涂布湿量将复合阻燃涂料涂布在增白防水涂层的表面,用8节烘箱进行干燥固化处理,其中烘箱温度依次设置为120℃、170℃、170℃、170℃、170℃、170℃、170℃、150℃,涂布车速为20m/min;
(3)弱溶剂墨水吸收涂层涂料的配置及涂布
按照重量份计将水性聚丙烯酸乳液68份、聚乙烯蜡10份、二氧化硅10份、碳酸钙9份、消泡剂1份(有机硅类)混匀,调pH8,得到粘度为4000cps的弱溶剂墨水吸收涂料,利用7mm E型刀按照30gsm的涂布湿量将弱溶剂墨水吸收涂料涂布在复合阻燃涂层的表面,用8节烘箱进行干燥固化处理,其中烘箱的温度依次设置为60℃、80℃、100℃、120℃、130℃、130℃、130℃、100℃,涂布车速为20m/min;
(4)热升华墨水吸收涂层涂料的配置及涂布
按照重量分数计将水98份、热升华涂料30份、增稠剂5份(PTF增稠剂)混匀,调pH7.8,得到粘度为30000cps的热升华墨水吸收涂料,利用4mm靴型刀按照50gsm的涂布湿量将热升华墨水吸收涂料涂布在涤纶化纤布层的另一面,再利用8节烘箱进行干燥固化处理,其中烘箱温度依次设置为60℃、80℃、90℃、150℃、150℃、150℃、150℃、150℃,涂布车速为20m/min。最后经过收卷、质量检测,分切包装得到数码直喷弱溶剂双面打印广告布。
本发明利用白度颜色测定仪和分别对实施例1,2,3中的产品进行白度及阻燃性能进行了测试,同时按照《纺织织物表面抗湿性测定沾水试验》对上述实施例1,2,3中所得的产品的防水性能指标进行测试,具体结果详见表1。
表1
实施例 | 白度 | 防水等级 | 阻燃性能 | 具体应用 |
实施例1 | 115 | 2级 | 德国B1 | 外打灯广告布 |
实施例2 | 140 | 5级 | 德国B1 | 内打灯广告布 |
实施例3 | 150 | 5级以上 | NFPA701德国B1 | 内打灯广告布帐篷布 |
以上所述仅为本发明的较佳实施例而已,并不用以限制本发明,凡在本发明的精神和原则之内所作的任何修改、等同替换和改进等,均应包含在本发明的保护范围之内。
Claims (9)
1.一种数码直喷弱溶剂双面打印广告布,包括涤纶化纤布层,所述涤纶化纤布层的一面设有增白防水涂层,所述增白防水涂层的表面设有复合阻燃涂层,所述复合阻燃涂层的表面设有弱溶剂墨水吸收涂层,所述涤纶化纤布层的另一面设有热升华墨水吸收涂层。
2.根据权利要求1所述的一种数码直喷弱溶剂双面打印广告布,其特征在于:所述增白防水涂层为增白剂、防水剂和增稠剂复合涂布在所述涤纶化纤布层的一面所形成的涂层。
3.根据权利要求2所述的一种数码直喷弱溶剂双面打印广告布,其特征在于:所述增白剂为双苯乙烯型衍生物,所述防水剂为含氟防水剂或无氟防水剂,所述增稠剂为PTF增稠剂。
4.根据权利要求1所述的一种数码直喷弱溶剂双面打印广告布,其特征在于:所述复合阻燃涂层为水性丙烯酸乳液、三氧化二锑、多聚磷酸酯、无机填料和消泡剂复合涂布在的所述增白防水涂层的表面所形成的涂层。
5.根据权利要求1所述的一种数码直喷弱溶剂双面打印广告布,其特征在于:所述弱溶剂墨水吸收涂层为水性聚丙烯酸乳液、聚乙烯蜡、二氧化硅、消泡剂和碳酸钙复合涂布在所述复合阻燃涂层的表面所形成的涂层。
6.根据权利要求5所述的一种数码直喷弱溶剂双面打印广告布,其特征在于:所述消泡剂为矿物油类、有机硅类或聚醚类。
7.根据权利要求1所述的一种数码直喷弱溶剂双面打印广告布,其特征在于:所述热升华墨水吸收涂层为热升华涂料、水和增稠剂复合涂布在所述涤纶化纤布层的另一面所形成的涂层。
8.根据权利要求1所述的一种数码直喷弱溶剂双面打印广告布的制备工艺,其特征在于所述制备工艺包括以下步骤:
(1)增白防水涂层涂料的配置及涂布
按照重量份计将水500-1000份、增白剂1-8份、防水剂10-60份和增稠剂5-20份混匀,调pH7-8,得到粘度为20000-50000cps的增白防水涂料,利用底板刮刀涂布方式将增白防水涂料涂布在涤纶化纤布层的一面,经过干燥固化处理,形成增白防水涂层;
(2)复合阻燃涂层涂料的配置及涂布
按照重量份计将水性聚丙烯酸乳液50-70份、无机填料10-15份、三氧化二锑10-30份、多聚磷酸酯10-30份、消泡剂0.2-1份混匀,调pH6-8,得到粘度为8000-15000cps的复合阻燃涂料,利用底板刮刀涂布方式将复合阻燃涂料涂布在增白防水涂层的表面,经过干燥固化处理,形成复合阻燃涂层;
(3)弱溶剂墨水吸收涂层涂料的配置及涂布
按照重量份计将水性聚丙烯酸乳液50-70份、聚乙烯蜡5-10份、二氧化硅5-10份、碳酸钙5-10份、消泡剂0.2-1份混匀,调pH7-8,得到粘度为2000-5000cps的弱溶剂墨水吸收涂料,利用底板刮刀涂布方式将弱溶剂墨水吸收涂料涂布在复合阻燃涂层的表面,经过干燥固化处理,形成弱溶剂墨水吸收涂层;
(4)热升华墨水吸收涂层涂料的配置及涂布
按照重量分数计将水50-100份、热升华涂料20-30份、增稠剂2-5份混匀,调pH6-8,得到粘度为20000-30000cps的热升华墨水吸收涂料,利用底板刮刀涂方式将热升华墨水吸收涂料涂布在涤纶化纤布层的另一面,经过干燥固化处理,形成热升华墨水吸收涂层,最后经过收卷、质量检测,分切包装得到数码直喷弱溶剂双面打印广告布。
9.根据权利要求8所述的一种数码直喷弱溶剂双面打印广告布的制备工艺,其特征在于:
步骤(1)中底板刮刀涂布时利用3-4mm靴型刀进行涂布,干燥固化处理的温度为120-180℃,涂布车速为40-50m/min;
步骤(2)中底板刮刀涂布时利用4-8mm E型刀,干燥固化处理的温度为120-170℃,涂布车速为15-20m/min;
步骤(3)中底板刮刀涂布时利用4-8mm E型刀,干燥固化处理的温度为60-130℃,涂布车速为10-20m/min;
步骤(4)中底板刮刀涂布时利用3-4mm靴型刀,干燥固化处理的温度为60-150℃,涂布车速为15-20m/min。
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