CN107417458A - A kind of environment-friendly type fertilizer - Google Patents

A kind of environment-friendly type fertilizer Download PDF

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Publication number
CN107417458A
CN107417458A CN201710543812.4A CN201710543812A CN107417458A CN 107417458 A CN107417458 A CN 107417458A CN 201710543812 A CN201710543812 A CN 201710543812A CN 107417458 A CN107417458 A CN 107417458A
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Prior art keywords
parts
environment
friendly type
type fertilizer
soil
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汪知明
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Hefei United Environmental Protection Technology Co Ltd
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Hefei United Environmental Protection Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B7/00Fertilisers based essentially on alkali or ammonium orthophosphates
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity

Abstract

The invention provides a kind of environment-friendly type fertilizer, including following component:It is attapulgite modified, growth regulator, modified edible fungi residue, plant treatment agents, ammonium sulfate, urea, potassium sulfate, urea phosphate, calcium phosphate, montmorillonite, tea seed episperm, peat soil, blast furnace cinder, borax, it is wherein attapulgite modified, growth regulator, modified edible fungi residue and plant treatment agents be all handle by special process made from, this Fertilizer nutrient is enriched, contain a variety of a great number of elements and micronutrient element necessary to crop, the high conversion rate of heavy metal, the yield of crops can be increased, realize the double benefit of high yield and repairing heavy metal in soil.

Description

A kind of environment-friendly type fertilizer
Technical field
The invention belongs to technical field of fertilizers, and in particular to a kind of environment-friendly type fertilizer.
Background technology
Plant growth needs various nutrient elements, wherein, grand nutrition element required for plant growth include carbon, hydrogen, Oxygen, nitrogen, phosphorus, potassium, calcium, magnesium and sulphur, micronutrient element include boron, copper, iron, manganese, molybdenum, zinc and chlorine etc..Fertilizer is the grain of crop Food, the nutrient needed for plant growth will be supplemented by applying fertilizer.With fertilising for many years, soil hardening, acid are caused Change, the problems such as heavy metal accumulation.In addition with the fast development of economy and the progress of industrial technology, work, agricultural production are to environment Harmful effect constantly aggravate, solid waste constantly to soil surface stack and topple over, harmful waste water constantly permeates into soil, Pernicious gas and floating dust in air are also constantly dropped in soil with rainwater, also result in the heavy metal pollution of soil.Wherein, Heavy metal pollution of soil turns into the protrusion environmental problem that can not be ignored, and farmland soil heavy metals pollution has huge harmfulness, Heavy metal in soil pollution can not only cause crop production reduction and quality decline, can also be by soil-plant system, through food chain Enter people's human body, be detrimental to health and life security, the report of the harm of the heavy metal pollution such as cobalt rice, antimony poison, blood antimony in recent years is repeatly See not fresh, there is very big harm to realize.Heavy metal pollution of soil has hysteresis quality, chronicity and the biology of disguised harm The features such as biological concentration of chain heavy metal, if these decide that difficulty will be brought by recognizing heavy metal pollution of soil and administer hysteresis With the serious consequence of expectation.Such as 20th century in Japan's generation because Cd pollutions in farmland cause " itai-itai " environmental hazard to be exactly most allusion quotation The example of type.China's Farmland Soil Pollution is on the rise, and the report of the heavy metals exceeding standard such as soil, rice, vegetables sees report again and again End, relevant information show that China in 1998 is accounted for the 1/ of total area under cultivation by nearly 20,000,000 hectares of the cultivated area of heavy metal pollution 5.Cause annual more than 1,000 ten thousand tons of grain drop in production, contaminated grain adds up to economic loss up to 20,000,000,000 yuan ten thousand tons up to more than 1200. The problems such as ecological negative effect, agricultural product security, health and Green Trade Barrier for being triggered by heavy metal pollution, has caused wide General concern.Therefore under such major premise, how study reduces heavy metal pollution, improved soil, improves the utilization rate of fertilizer, from And reach Ecological Sustainable Development, the edible safety of crop is lifted, to agricultural planting, there is important meaning in terms of ecological environment Justice.
The content of the invention
In view of the defects of above-mentioned prior art, the technical problem to be solved in the present invention is to provide a kind of environment-friendly type fertilizer, Ask the utilization rate of the fertilizer high, without heavy metal, and be advantageous to improved soil, it is environmentally friendly.
In view of above-mentioned technical problems to be solved, the present invention provides following technical scheme:A kind of environment-friendly type fertilizer, including Following parts by weight of component:Attapulgite modified 15-25 parts, growth regulator 20-30 parts, modified edible fungi residue 25-30 parts, plant Thing inorganic agent 25-30 parts, ammonium sulfate 10-20 parts, urea 30-50 parts, potassium sulfate 15-20 parts, urea phosphate 25-30 parts, calcium phosphate 10-15 parts, montmorillonite 10-15 parts, tea seed episperm 15-25 parts, peat soil 10-15 parts, blast furnace cinder 15-20 parts, borax 4-8 parts.
Preferably, it is described attapulgite modified, it is that molar concentration is added into attapulgite original soil is 0.5mol/L- 2.5mol/L hydrochloric acid solution, vibrate at room temperature, staticly settle after filter, then adopt be washed with deionized to pH value be 7, And dried in 110 DEG C of -130 DEG C of baking ovens, it is made after ground, mistake 20-40 mesh sieves.
It is further preferred that the mass ratio of the attapulgite original soil and hydrochloric acid solution is 1:20-1:10.
Preferably, the growth regulator, it is by 1 by biogas residue, pig manure and Chinese medicine ground-slag:(0.35-0.4):(0.65- 0.75) mass ratio mixing, drying, crushes, crosses 20-40 mesh sieves, after 1-1.5mol/L soaking with sodium hydroxide 35-40min, Oxalic acid is added, regulation pH value is 6.5, temperature is risen into 100-110 DEG C with 1.2-1.5 DEG C/min speed, magnetic stirring apparatus stirs Mix, add 0.25-0.3 times of hydrogen peroxide of oxalic acid quality, medicinal extract of the infusion into water content for 25-30wt%, after dry, pulverize It is made.
Preferably, the modified edible fungi residue, it is by collecting bacterium bag, removing polybag and the part gone mouldy, dry It is dry, crush, after adding winestone acid soak 25-30min, be placed at 65-70 DEG C the 10-15min that flows back, zeolite powder added, with 4-5 DEG C/temperature rises to 100-110 DEG C, magnetic stirrer 1.1-1.3h by min speed, filter, drying, crushed 20-40 Mesh sieve is made.
It is further preferred that the quality of the zeolite powder is 0.4-0.5 times of bacteria residue quality.
Preferably, the plant treatment agents, it is by mass mixings such as cattail, reed and blue-green algaes, drying, crosses 20-40 mesh sieves, 1 is pressed with starch:The mass ratio of (0.3-0.35) mixes to obtain mixed material, at 5-6.5 DEG C, adds the 1.5- of mixed material quality 2 times of acrylic acid, after soaking 45-55min, heating recovery acrylic acid, at 75-80 DEG C, add 2-3 times of mixed material quality Epoxy resin, magnetic stirrer 35-55min, filter, drying, you can.
Preferably, the preparation method of the environment-friendly type fertilizer comprises the following steps:
(1) ammonium sulfate, urea, potassium sulfate, urea phosphate and calcium phosphate are subjected to melt process under respective fusing point respectively, Dry, mixed after crushed 20-40 mesh sieves respectively, vibrate 10-15min under 150-200 times/min vibration frequency, obtain thing Expect A;
(2) by montmorillonite, tea seed episperm, peat soil, blast furnace cinder and borax, under nitrogen protection, forged at 290-300 DEG C 40-50min is burnt, 20-40 mesh sieves is crushed, obtains material B;
(3) attapulgite modified, growth regulator, modified edible fungi residue and plant treatment agents are mixed, adds water to stir Reconcile, heating is brewed into the paste that water content is 15-20wt%, obtains material C;
(4) material A and material B are mixed, are granulated by comminutor, dried, in 110-160 times/min vibration frequency 6-8min is vibrated, material C is coated uniformly on the particle after vibration, drying.
Compared with prior art, the beneficial effects of the invention are as follows:This Fertilizer nutrient is enriched, containing a variety of big necessary to crop Secondary element and micronutrient element, nitrogen, phosphorus, potassium total nutrient >=72%, rich in various nutrient elements, the present invention can effectively reduce soil The activity of metal ion in earth, change form of the heavy metal in soil, the heavy metal in soil is changed into soil from available state It is difficult to the invalid state that absorbs with crop, reduces the absorption of crop heavy metal, so as to reaches the mesh of repairing heavy metal in soil pollution , it is changed into judging quota of the number turnover as soil remediation of invalid state, conversion of the present invention to soil vanadium metal using available state Rate reaches 90.21-90.25%, and the present invention reaches 90.92-90.95% to the conversion ratio of zinc in soil metal, and the present invention is to soil The conversion ratio of cobalt metal reaches 90.83-90.95%, and not only heavy metal repairing effect is notable for fertilizer of the invention, also has abundant Nutrition, effectively facilitate the growth of crop, by taking corn as an example, per mu yield can increase production 10.3-10.6% relative to control group, real The now double benefit of high yield and repairing heavy metal in soil.
Embodiment
The embodiment of the present invention is described in further detail below, but the invention is not limited in these realities Mode is applied, any improvement or replacement on the present embodiment essence spirit, it is claimed to still fall within the claims in the present invention Scope.
The environment-friendly type fertilizer of the present invention, including following component:Attapulgite modified, growth regulator, modified edible fungi Slag, plant treatment agents, ammonium sulfate, urea, potassium sulfate, urea phosphate, calcium phosphate, montmorillonite, tea seed episperm, peat soil, blast furnace cinder And borax.
The wherein attapulgite modified acidification that carried out on the basis of concave convex rod original soil obtains, so effective to increase Big attapulgite specific surface area, enhances the exchange capacity of its ion, modified attapulgite, surface is loose, and presents It is obvious concavo-convex, there is flourishing inner duct and larger external surface area, make attapulgite that there is excellent absorption property.
Wherein growth regulator is prepared by the processing of biogas residue, pig manure and Chinese medicine slag, contains abundant nitrogen, phosphorus, potassium and big Outside the element of amount, also contain the trace elements such as the boron to be played an important role to plant growth, copper, iron, manganese, cobalt, also substantial amounts of ammonia The nutriment such as base acid and beneficial microbe, outside the supply for meeting nutrition needed for plant growth, moreover it is possible to keep the soil texture to dredge Pine, improve soil texture.
Wherein modified edible fungi residue is rich in the nutriments such as bioactive substance, organic acid, protein, amino acid, The nutritional need of plant growth can be supplemented, the macromolecular such as proteins and peptides in modified bacteria residue has stronger heavy metal Accumulation ability, bacteria residue surface reactive material is activated, Heavy Metals and its eco-toxicity can be changed, have remediating heavy metal dirty The purpose of dye.
Wherein plant treatment agents have cattail, reed and the blue-green algae of enrichment by using heavy metal, by starch, The modification of acrylic acid and epoxy resin, the larger grafted moiety of specific surface area is obtained, effectively adsorbs heavy metal, meanwhile, also have The total negative electrical charge number for enhancing fertilizer of effect, significantly improve the adsorption capacity of heavy metal.
Embodiment 1
A kind of environment-friendly type fertilizer, it is made up of following raw material by weight:Attapulgite modified 15kg, growth regulator 20kg, modified edible fungi residue 25kg, plant treatment agents 25kg, ammonium sulfate 10kg, urea 30kg, potassium sulfate 15kg, urea phosphate 25kg, calcium phosphate 10kg, montmorillonite 10kg, tea seed episperm 15kg, peat soil 10kg, blast furnace cinder 15kg, borax 4kg.
It is above-mentioned attapulgite modified, it is that the molar concentration that 20 times of concave convex rod original soils are added into attapulgite original soil is 0.5mol/L hydrochloric acid solution, vibrate at room temperature, staticly settle after filter, then adopt be washed with deionized to pH value be 7, And dried in 110 DEG C of baking ovens, it is made after ground, 20 mesh sieves excessively.
Above-mentioned growth regulator, it is by 1 by biogas residue, pig manure and Chinese medicine ground-slag:0.35:0.65 mass ratio mixing, drying, Crush, cross 20 mesh sieves, after 1mol/L soaking with sodium hydroxide 35min, add oxalic acid, regulation pH value be 6.5, with 1.2 DEG C/ Temperature is risen to 100 DEG C by min speed, magnetic stirrer, adds 0.25 times of hydrogen peroxide of oxalic acid quality, infusion into containing Water is 25wt% medicinal extract, is made after dry, pulverize.
Above-mentioned modified edible fungi residue, it is the crushing by collecting bacterium bag, removing polybag and the part gone mouldy, dry, After adding winestone acid soak 25min, the 10min that flows back is placed at 65 DEG C, adds zeolite powder, the quality of zeolite powder is bacteria residue quality 0.4 times, temperature is risen to 100 DEG C, magnetic stirrer 1.1h with 4 DEG C/min speed, filtered, drying, crushed 20 mesh Sieve series obtains.
Above-mentioned plant treatment agents, it is by mass mixings such as cattail, reed and blue-green algaes, drying, crosses 20 mesh sieves, 1 is pressed with starch: 0.3 mass ratio mixes to obtain mixed material, at 5 DEG C, adds 1.5 times of acrylic acid of mixed material quality, soaks 45min Afterwards, heating recovery acrylic acid, at 75 DEG C, 2 times of epoxy resin of mixed material quality, magnetic stirrer are added 35min, filter, drying, you can.
The preparation method of above-mentioned environment-friendly type fertilizer comprises the following steps:
(1) ammonium sulfate, urea, potassium sulfate, urea phosphate and calcium phosphate are subjected to melt process under respective fusing point respectively, Dry, mixed after crushed 20 mesh sieves respectively, vibrate 10min under 150 times/min vibration frequency, obtain material A;
(2) by montmorillonite, tea seed episperm, peat soil, blast furnace cinder and borax, under nitrogen protection, calcined at 290 DEG C 40min, 20 mesh sieves are crushed, obtain material B;
(3) attapulgite modified, growth regulator, modified edible fungi residue and plant treatment agents are mixed, adds water to stir Reconcile, heating is brewed into the paste that water content is 15wt%, obtains material C;
(4) material A and material B are mixed, are granulated by comminutor, dried, vibrated in 110 times/min vibration frequency 6min, material C is coated uniformly on the particle after vibration, drying.
Embodiment 2
A kind of environment-friendly type fertilizer, it is made up of following raw material by weight:Attapulgite modified 25kg, growth regulator 30kg, modified edible fungi residue 30kg, plant treatment agents 30kg, ammonium sulfate 20kg, urea 50kg, potassium sulfate 20kg, urea phosphate 30kg, calcium phosphate 15kg, montmorillonite 15kg, tea seed episperm 25kg, peat soil 15kg, blast furnace cinder 20kg, borax 8kg.
It is wherein attapulgite modified, it is that the molar concentration that 10 times of attapulgite original soils are added into attapulgite original soil is 2.5mol/L hydrochloric acid solution, vibrate at room temperature, staticly settle after filter, then adopt be washed with deionized to pH value be 7, And dried in 130 DEG C of baking ovens, it is made after ground, 40 mesh sieves excessively.
Wherein growth regulator, it is by 1 by biogas residue, pig manure and Chinese medicine ground-slag:0.4:0.75 mass ratio mixing, drying, Crush, cross 40 mesh sieves, after 1.5mol/L soaking with sodium hydroxide 40min, add oxalic acid, regulation pH value be 6.5, with 1.5 DEG C/ Temperature is risen to 110 DEG C by min speed, magnetic stirrer, adds 0.3 times of hydrogen peroxide of oxalic acid quality, infusion into containing Water is 30wt% medicinal extract, is made after dry, pulverize.
Wherein modified edible fungi residue, it is the crushing by collecting bacterium bag, removing polybag and the part gone mouldy, dry, After adding winestone acid soak 30min, the 15min that flows back is placed at 70 DEG C, adds zeolite powder, the quality of zeolite powder is bacteria residue quality 0.5 times, temperature is risen to 110 DEG C, magnetic stirrer 1.3h with 5 DEG C/min speed, filtered, drying, crushed 40 mesh Sieve series obtains.
Wherein plant treatment agents, it is by mass mixings such as cattail, reed and blue-green algaes, drying, crosses 40 mesh sieves, 1 is pressed with starch: 0.35 mass ratio mixes to obtain mixed material, at 6.5 DEG C, adds 2 times of acrylic acid of mixed material quality, soaks 55min Afterwards, heating recovery acrylic acid, at 80 DEG C, 3 times of epoxy resin of mixed material quality, magnetic stirrer are added 55min, filter, drying, you can.
The preparation method of above-mentioned environment-friendly type fertilizer comprises the following steps:
(1) ammonium sulfate, urea, potassium sulfate, urea phosphate and calcium phosphate are subjected to melt process under respective fusing point respectively, Dry, mixed after crushed 40 mesh sieves respectively, vibrate 15min under 200 times/min vibration frequency, obtain material A;
(2) by montmorillonite, tea seed episperm, peat soil, blast furnace cinder and borax, under nitrogen protection, calcined at 300 DEG C 50min, 40 mesh sieves are crushed, obtain material B;
(3) attapulgite modified, growth regulator, modified edible fungi residue and plant treatment agents are mixed, adds water to stir Reconcile, heating is brewed into the paste that water content is 20wt%, obtains material C;
(4) material A and material B are mixed, are granulated by comminutor, dried, vibrated in 160 times/min vibration frequency 8min, material C is coated uniformly on the particle after vibration, drying.
Testing inspection
In order to further illustrate the application value of the present invention, inventor have chosen the corn trials field of 3 pieces of heavy metal pollution, It is one of during maize planting using common fertilizer as a comparison case 1, another 2 pieces use the embodiment of the present invention 1 and real respectively The fertilizer of example 2 is applied as experimental group, after testing, total content of vanadium average value on 3 pieces of ground is 812.8mg/kg, total Zn content average value For 3.58mg/kg, total cobalt content average value is during 279.5mg/kg, plantation to the total vanadium, total zinc, total cobalt content of 3 blocks of soil Sampling analysis is carried out, is counted with reference to corn yield, as a result as shown in table 1:
Table 1
There are data in above-mentioned table can be seen that, the present invention can effectively reduce the activity of metal ion in soil, change heavy metal Form in soil, from available state is changed into soil by the heavy metal in soil and/or crop is difficult to the invalid state that absorbs, reduces The absorption of crop heavy metal, so as to reach the purpose of repairing heavy metal in soil pollution, turning for invalid state is changed into available state Variability is the judging quota of soil remediation, and the present invention reaches 90.21-90.25% to the conversion ratio of soil vanadium metal, and the present invention is right The conversion ratio of zinc in soil metal reaches 90.92-90.95%, and the present invention reaches 90.83- to the conversion ratio of cobalt in soil metal 90.95%, not only heavy metal repairing effect is notable for fertilizer of the invention, also has abundant nutrition, effectively facilitates the life of crop Long, by taking corn as an example, per mu yield can increase production 10.3-10.6%, realize high yield and repairing heavy metal in soil relative to control group Double benefit.
Embodiment described above, simply the present invention better embodiment, be not to limit the scope of the present invention, therefore The equivalent change or modification that all construction, feature and principles according to described in scope of the present invention patent are done, all should include this hair In bright patent claim.

Claims (8)

1. a kind of environment-friendly type fertilizer, it is characterised in that including following parts by weight of component:Attapulgite modified 15-25 parts, growth are adjusted Save agent 20-30 parts, modified edible fungi residue 25-30 parts, plant treatment agents 25-30 parts, ammonium sulfate 10-20 parts, urea 30-50 Part, potassium sulfate 15-20 parts, urea phosphate 25-30 parts, calcium phosphate 10-15 parts, montmorillonite 10-15 parts, tea seed episperm 15-25 parts, peat Native 10-15 parts, blast furnace cinder 15-20 parts, borax 4-8 parts.
2. environment-friendly type fertilizer according to claim 1, it is characterised in that:Described is attapulgite modified, is to concave convex rod In native original soil add molar concentration be 0.5mol/L-2.5mol/L hydrochloric acid solution, vibrate at room temperature, staticly settle after mistake Filter, then adopts that to be washed with deionized to pH value be 7, and is dried in 110 DEG C of -130 DEG C of baking ovens, ground, cross 20-40 mesh sieves After be made.
3. environment-friendly type fertilizer according to claim 2, it is characterised in that:The matter of the attapulgite original soil and hydrochloric acid solution Amount is than being 1:20-1:10.
4. environment-friendly type fertilizer according to claim 1, it is characterised in that:The growth regulator, be by biogas residue, pig manure and Chinese medicine ground-slag presses 1:0.35-0.4:0.65-0.75 mass ratio mixing, drying, crushes, crosses 20-40 mesh sieves, use 1-1.5mol/L Soaking with sodium hydroxide 35-40min after, add oxalic acid, regulation pH value is 6.5, with 1.2-1.5 DEG C/min speed by temperature liter To 100-110 DEG C, magnetic stirrer adds 0.25-0.3 times of hydrogen peroxide of oxalic acid quality, infusion into water content be 25- 30wt% medicinal extract, it is made after dry, pulverize.
5. environment-friendly type fertilizer according to claim 1, it is characterised in that:The modified edible fungi residue, it is to pass through collection Bacterium bag, polybag and the part gone mouldy are removed, is dried, is crushed, after adding winestone acid soak 25-30min, is placed in 65-70 DEG C Lower backflow 10-15min, zeolite powder is added, temperature is risen to 100-110 DEG C with 4-5 DEG C/min speed, magnetic stirrer 1.1-1.3h, filter, drying, crushed 20-40 mesh sieves and be made.
6. environment-friendly type fertilizer according to claim 5, it is characterised in that:The quality of the zeolite powder is bacteria residue quality 0.4-0.5 times.
7. environment-friendly type fertilizer according to claim 1, it is characterised in that:The plant treatment agents, be by cattail, reed and The mass mixings such as blue-green algae, drying, 20-40 mesh sieves are crossed, 1 is pressed with starch:0.3-0.35 mass ratio mixes to obtain mixed material, in 5- At 6.5 DEG C, 1.5-2 times of acrylic acid of mixed material quality is added, after soaking 45-55min, heating recovery acrylic acid, in 75- At 80 DEG C, 2-3 times of epoxy resin of mixed material quality is added, magnetic stirrer 35-55min, is filtered, drying, i.e., Can.
8. environment-friendly type fertilizer according to claim 1, it is characterised in that:The preparation method of the environment-friendly type fertilizer include with Lower step:
(1) ammonium sulfate, urea, potassium sulfate, urea phosphate and calcium phosphate are subjected to melt process under respective fusing point respectively, done It is dry, mixed after crushed 20-40 mesh sieves respectively, vibrate 10-15min under 150-200 times/min vibration frequency, obtain material A;
(2) by montmorillonite, tea seed episperm, peat soil, blast furnace cinder and borax, under nitrogen protection, calcined at 290-300 DEG C 40-50min, 20-40 mesh sieves are crushed, obtain material B;
(3) attapulgite modified, growth regulator, modified edible fungi residue and plant treatment agents are mixed, add water stirring to reconcile, Heating is brewed into the paste that water content is 15-20wt%, obtains material C;
(4) material A and material B are mixed, are granulated by comminutor, dried, vibrated in 110-160 times/min vibration frequency 6-8min, material C is coated uniformly on the particle after vibration, drying.
CN201710543812.4A 2017-07-05 2017-07-05 A kind of environment-friendly type fertilizer Withdrawn CN107417458A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108164349A (en) * 2018-03-16 2018-06-15 重庆市林业科学研究院 A kind of nutrient matrix cultivated for Ornamental Bamboo and preparation method thereof
CN108329070A (en) * 2018-03-09 2018-07-27 淮阴工学院 Germ bran organic fertilizer and its preparation method and application

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108329070A (en) * 2018-03-09 2018-07-27 淮阴工学院 Germ bran organic fertilizer and its preparation method and application
CN108164349A (en) * 2018-03-16 2018-06-15 重庆市林业科学研究院 A kind of nutrient matrix cultivated for Ornamental Bamboo and preparation method thereof

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Application publication date: 20171201