CN107408744B - 用于先进的金属-空气蓄电池的催化剂体系 - Google Patents

用于先进的金属-空气蓄电池的催化剂体系 Download PDF

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CN107408744B
CN107408744B CN201580068150.9A CN201580068150A CN107408744B CN 107408744 B CN107408744 B CN 107408744B CN 201580068150 A CN201580068150 A CN 201580068150A CN 107408744 B CN107408744 B CN 107408744B
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metal
air battery
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battery according
transition metal
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CN107408744A (zh
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A.萨利希-霍金
B.库马
M.阿萨迪
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University of Illinois System
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CN201580068150.9A 2014-12-14 2015-12-14 用于先进的金属-空气蓄电池的催化剂体系 Active CN107408744B (zh)

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US201462091585P 2014-12-14 2014-12-14
US62/091,585 2014-12-14
PCT/US2015/065546 WO2016100204A2 (en) 2014-12-14 2015-12-14 Catalyst system for advanced metal-air batteries

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US (1) US10978703B2 (https=)
EP (1) EP3231034B1 (https=)
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Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10868332B2 (en) 2016-04-01 2020-12-15 NOHMs Technologies, Inc. Modified ionic liquids containing phosphorus
US20200058927A1 (en) * 2016-10-17 2020-02-20 The Board Of Trustees Of The University Of Illinois Protected Anodes and Methods for Making and Using Same
EP3336961A1 (fr) * 2016-12-16 2018-06-20 Gemalto Sa Procede de fabrication d'un objet electronique comprenant un corps et une batterie a membrane poreuse
US11189870B2 (en) * 2017-04-13 2021-11-30 Toyota Motor Engineering & Manufacturing North America, Inc. Lithium air battery
JP7296893B2 (ja) 2017-07-17 2023-06-23 ノームズ テクノロジーズ インコーポレイテッド リン含有電解質
CN108365175A (zh) * 2018-02-08 2018-08-03 成都理工大学 一种三维互连的混合网络结构、制备方法及用途
US11784370B2 (en) 2018-03-13 2023-10-10 Illinois Institute Of Technology Transition metal phosphides for high efficient and long cycle life metal-air batteries
US10472034B1 (en) * 2019-02-25 2019-11-12 Teledyne Instruments, Inc. Hybrid energy harvesting system for thermal-powered underwater vehicle
US11041236B2 (en) * 2019-03-01 2021-06-22 Honda Motor Co., Ltd. Method for direct patterned growth of atomic layer metal dichalcogenides with pre-defined width
US12565709B2 (en) 2019-03-19 2026-03-03 Illinois Institute Of Technology Methods and devices using tri-transition metal phosphides for efficient electrocatalytic reactions
IL286505B2 (en) * 2019-03-22 2025-03-01 Aspen Aerogels Inc A cathode made of carbon aerogel for use in lithium-air batteries
US11929512B2 (en) 2019-04-30 2024-03-12 The Board Of Trustees Of The Leland Stanford Junior University Oxidized surface layer on transition metal nitrides: active catalysts for the oxygen reduction reaction
WO2021059325A1 (ja) * 2019-09-24 2021-04-01 Dic株式会社 硫化モリブデン粉体及びその製造方法
JP7716739B2 (ja) * 2020-06-19 2025-08-01 国立大学法人岩手大学 レドックスメディエーター能を付与したリチウム－空気二次電池用イオン液体電解質とリチウム－空気二次電池
CN112053746A (zh) * 2020-09-10 2020-12-08 上海大学 一种锕系元素离子在离子液体中还原电位的模拟分析方法
WO2024005885A2 (en) * 2022-04-01 2024-01-04 Aspen Aerogels, Inc. Synthesis of transition metal hydroxides, oxides, and nanoparticles thereof
CN115959648B (zh) * 2022-12-21 2024-05-28 北方民族大学 一种高缺陷碳膜的简易制备方法及其在co2还原流动池中的应用
CN119702011B (zh) * 2025-01-08 2025-10-24 福州大学 单原子金属掺杂的疏水性二硫化钼催化剂的制备与应用

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4414080A (en) 1982-05-10 1983-11-08 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Photoelectrochemical electrodes
JP2008066202A (ja) * 2006-09-08 2008-03-21 National Institute Of Advanced Industrial & Technology 空気電池
AU2008247280A1 (en) 2007-05-04 2008-11-13 Principle Energy Solutions, Inc. Production of hydrocarbons from carbon and hydrogen sources
WO2011013005A1 (en) * 2009-07-31 2011-02-03 Revolt Technology Ltd. Metal-air battery with ion exchange material
JP2011096492A (ja) 2009-10-29 2011-05-12 Sony Corp リチウム空気電池
US8236452B2 (en) * 2009-11-02 2012-08-07 Nanotek Instruments, Inc. Nano-structured anode compositions for lithium metal and lithium metal-air secondary batteries
CN102473986A (zh) * 2010-03-10 2012-05-23 丰田自动车株式会社 非水电解质和金属空气电池
US20130143319A1 (en) * 2010-03-16 2013-06-06 The Board of Trustees of the University of Illinois et al Use of Functional Nanoelectrodes for Intracellular Delivery of Chemical and Biomolecular Species
US9012345B2 (en) 2010-03-26 2015-04-21 Dioxide Materials, Inc. Electrocatalysts for carbon dioxide conversion
CN102934279B (zh) * 2010-06-08 2015-05-13 雷蒙特亚特特拉维夫大学有限公司 可再充电的碱金属-空气电池
JP5678499B2 (ja) * 2010-07-15 2015-03-04 トヨタ自動車株式会社 リチウム空気電池
KR101239966B1 (ko) * 2010-11-04 2013-03-06 삼성전자주식회사 리튬 공기 전지용 양극, 그 제조방법 및 이를 채용한 리튬 공기 전지
CA2724307A1 (fr) * 2010-12-01 2012-06-01 Hydro-Quebec Batterie lithium-air
US8658016B2 (en) 2011-07-06 2014-02-25 Liquid Light, Inc. Carbon dioxide capture and conversion to organic products
JP5519858B2 (ja) * 2011-07-19 2014-06-11 パナソニック株式会社 直接酸化型燃料電池システム
WO2013046403A1 (ja) 2011-09-29 2013-04-04 トヨタ自動車株式会社 金属空気電池
AU2013231005A1 (en) 2012-03-06 2014-09-04 Liquid Light, Inc. Reducing carbon dioxide to products
JP5664622B2 (ja) * 2012-09-25 2015-02-04 トヨタ自動車株式会社 金属空気電池
US9190696B2 (en) * 2013-05-16 2015-11-17 Nanotek Instruments, Inc. Lithium secondary batteries containing lithium salt-ionic liquid solvent electrolyte

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
"Ruthenium cluster-like chalcogenide as a methanol tolerant cathode catalyst in air-breathing laminar flow fuel cells";Whipple, Devin T.; Jayashree, Ranga S.; Egas, Daniela; et al.;《ELECTROCHIMICA ACTA》;20090715;第54卷(第18期);第4384-4388页 *

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CA2970798C (en) 2020-09-08
EP3231034B1 (en) 2023-04-19
US20170373311A1 (en) 2017-12-28
EP3231034A2 (en) 2017-10-18
CA2970798A1 (en) 2016-06-23
KR20170125807A (ko) 2017-11-15
WO2016100204A3 (en) 2016-08-18
JP2018508094A (ja) 2018-03-22
KR102544961B1 (ko) 2023-06-19
WO2016100204A2 (en) 2016-06-23
US10978703B2 (en) 2021-04-13
JP6739432B2 (ja) 2020-08-12
CN107408744A (zh) 2017-11-28

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