CN107385897A - 一种耐高温强碱的纺织染色活性剂 - Google Patents

一种耐高温强碱的纺织染色活性剂 Download PDF

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CN107385897A
CN107385897A CN201710741442.5A CN201710741442A CN107385897A CN 107385897 A CN107385897 A CN 107385897A CN 201710741442 A CN201710741442 A CN 201710741442A CN 107385897 A CN107385897 A CN 107385897A
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activating agent
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李蓉妹
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Rugao Futong Textile Chemicals Co Ltd
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Abstract

本发明涉及一种耐高温强碱的纺织染色活性剂；属于纺织印染技术领域。本发明的制作工艺，包括以下步骤：将去离子水升温至65‑70℃，加入抗静电乳化润滑油搅拌至融化，然后加入耐碱活性剂OEP‑70搅拌均匀，再滴加入脂肪醇聚氧乙烯醚JFC‑2搅拌均匀，加入过一硫酸氢钾搅拌10分钟以上即可。本发明制备的强力高温耐碱活性剂没有刺激性气味，能够达到医用级，从而能用于医用卫生材料的生产制备；而且该绿色医用级强力高温耐碱活性剂的渗透效果明显优于耐碱活性剂OEP‑70、脂肪醇聚氧乙烯醚JFC‑2的效果，而且去除油脂及蜡质更彻底，残留更少，从而能给企业降低成本、提高印染质量，是理想地绿色高效助剂。

Description

一种耐高温强碱的纺织染色活性剂
技术领域
本发明涉及一种耐高温强碱的纺织染色活性剂；属于纺织印染技术领域。
背景技术
目前，在制备纺织品卫生材料的前道漂染工序中，通常会使用到非离子活性剂、阴离子活性剂等助剂存在不耐高温、不耐碱，在高温失去渗透性能等缺陷。渗透速率为1%水溶液20℃时4-6S。活性剂在液碱（氢氧化钠）工作液里升温120℃中失去渗透作用。在漂染工序中使用此类助剂，给企业造成沉重经济负担，增加了生产成本、降低产品质量、造成去除油脂及蜡质不彻底、削弱了产品的竞争力。而上述非离子活性剂、阴离子活性剂中通常含有APEO、甲醛、苯、偶氮、有机锡化合物、能释放环境激素的物质、臭氧层消耗物质等。在前道漂染工序中使用多种助剂，会使产品药棉、纱布上附着有毒的化学残留，存在危害人体正常激素的化学物资，对环境潜在危害太大，属不安全产品。
耐碱活性剂OEP-70，是一种无色至微黄色粘稠物，pH值6-8（1%水溶液），渗透力：≤8秒（10g OEP-70/L，120gNaOH/L），耐碱性：耐200gNaOH/L。耐碱活性剂OEP-70具有极佳的抗浓碱、耐高温、耐氧化剂、耐还原剂、耐硬水性，并对双氧水具有较好的稳定作用；渗透力优越；在强碱条件下具有卓越的乳化、脱脂、净洗、分散能力；是前处理助剂（耐碱精练剂等）的理想原料。应用于制造印染前处理抗强碱精练剂和活性剂；用于复配净洗剂、匀染剂、乳化剂和活性剂。但是，由于OEP-70为粘度较高的粘稠液，加热到40℃左右可溶于水，在室温时短时间内较难化开。另外。耐碱活性剂OEP-70具备强烈刺激性气味，用于煮炼漂棉纱时，残留严重。
脂肪醇聚氧乙烯醚JFC-2(penetrantJFC-2)，化学名称仲辛醇聚氧乙烯醚结构式C8H17(CH2CH2O)nH,n=1-6；黄色透明黏稠液体，pH=6-8。5%水溶液加热至50℃以上即呈混浊状，降低温度仍可澄清，浊点40-50℃。低温时由凝冻现象。稳定性好，耐酸碱、硬水及重金属等。无毒。渗透力(1%水溶液)不低于标准品。用于上浆、退浆、煮炼、漂白、碳化及氯化等工序，又可作染色浴及整理浴的渗透助剂，以及皮革涂层的活性剂等。
发明内容
本发明的目的在于，解决耐碱活性剂OEP-70粘度大、刺激性气味强、残留严重的问题，提供一种高效、环保、节能、安全、无毒的耐高温强碱的纺织染色活性剂的制作工艺。
技术方案
一种耐高温强碱的纺织染色活性剂，包括以下步骤：
将300份去离子水升温至65-70℃，加入250-260份抗静电乳化润滑油搅拌至融化，然后加入200份耐碱活性剂OEP-70搅拌均匀，再滴加入350-360份脂肪醇聚氧乙烯醚JFC-2搅拌均匀，加入30-35份过一硫酸氢钾搅拌10分钟以上即可。
控制脂肪醇聚氧乙烯醚JFC-2在20-25min之间滴加完毕。
整个过程在保持去离子水温度恒定的条件下进行。
所述份为重量份；
所述抗静电乳化润滑油是指专利号为201310653893.5的专利产品。
上述制作工艺，优选的，以300份去离子水、250份抗静电乳化润滑油、200份耐碱活性剂OEP-70、350份脂肪醇聚氧乙烯醚JFC-2、30份过一硫酸氢钾为原料。
上述制作工艺，优选的，去离子水温度为68℃。
本发明的优点：该强力高温耐碱活性剂没有刺激性气味，能够达到医用级，从而能用于医用卫生材料的生产制备；而且该绿色医用级强力高温耐碱活性剂的渗透效果明显优于耐碱活性剂OEP-70、脂肪醇聚氧乙烯醚JFC-2的效果，而且去除油脂及蜡质更彻底，残留更少，从而能给企业降低成本、提高印染质量，是理想地绿色高效助剂。
具体实施方式
实施例1
以950kg地沟油、427kg碱、21kg脂肪醇类乳化剂和23kg甲醇为原料；地沟油92℃条件下搅拌31min；将碱一次性加入，然后搅拌103min，再升温至126℃；加乳化剂，然后搅拌保温107min；加甲醇，继续保温110min；即得抗静电乳化润滑油，即专利号为201310653893.5的专利产品。
实施例2
在反应釜中加入去离子水300kg，然后升温至68℃；在保持去离子水温度为68℃的条件下，进行以下操作：向去离子水中加入步骤1制备的抗静电乳化润滑油250kg(发明专利号ZL201310653893.5)，搅拌30分钟均匀融化后再缓慢加入200kg耐碱活性剂OEP-70，搅拌均匀后再滴加入350kg脂肪醇聚氧乙烯醚JFC-2（20-25min之间滴加完毕），搅拌均匀后再缓慢加入过一硫酸氢钾30kg搅拌10分钟即可。所获得产品无刺激性气味。
实施例3
在反应釜中加入去离子水300kg，然后升温至68℃；在保持去离子水温度为68℃的条件下，进行以下操作：向去离子水中加入步骤1制备的抗静电乳化润滑油260kg(发明专利号ZL201310653893.5)，搅拌30分钟均匀融化后再缓慢加入200kg耐碱活性剂OEP-70，搅拌均匀后再滴加入350kg脂肪醇聚氧乙烯醚JFC-2（20-25min之间滴加完毕），搅拌均匀后再缓慢加入过一硫酸氢钾30kg搅拌10分钟即可。所获得产品无刺激性气味。
实施例4
在反应釜中加入去离子水300kg，然后升温至68℃；在保持去离子水温度为68℃的条件下，进行以下操作：向去离子水中加入步骤1制备的抗静电乳化润滑油250kg(发明专利号ZL201310653893.5)，搅拌30分钟均匀融化后再缓慢加入200kg耐碱活性剂OEP-70，搅拌均匀后再滴加入360kg脂肪醇聚氧乙烯醚JFC-2（20-25min之间滴加完毕），搅拌均匀后再缓慢加入过一硫酸氢钾30kg搅拌10分钟即可。所获得产品无刺激性气味。
实施例5
在反应釜中加入去离子水300kg，然后升温至68℃；在保持去离子水温度为68℃的条件下，进行以下操作：向去离子水中加入步骤1制备的抗静电乳化润滑油250kg(发明专利号ZL201310653893.5)，搅拌30分钟均匀融化后再缓慢加入200kg耐碱活性剂OEP-70，搅拌均匀后再滴加入350kg脂肪醇聚氧乙烯醚JFC-2（20-25min之间滴加完毕），搅拌均匀后再缓慢加入过一硫酸氢钾35kg搅拌10分钟即可。所获得产品无刺激性气味。
实施例6
在反应釜中加入去离子水300kg，然后升温至65℃；在保持去离子水温度为68℃的条件下，进行以下操作：向去离子水中加入步骤1制备的抗静电乳化润滑油260kg(发明专利号ZL201310653893.5)，搅拌30分钟均匀融化后再缓慢加入200kg耐碱活性剂OEP-70，搅拌均匀后再滴加入350kg脂肪醇聚氧乙烯醚JFC-2（20-25min之间滴加完毕），搅拌均匀后再缓慢加入过一硫酸氢钾30kg搅拌10分钟即可。所获得产品无刺激性气味。
实施例7
在反应釜中加入去离子水300kg，然后升温至70℃；在保持去离子水温度为68℃的条件下，进行以下操作：向去离子水中加入步骤1制备的抗静电乳化润滑油260kg(发明专利号ZL201310653893.5)，搅拌30分钟均匀融化后再缓慢加入200kg耐碱活性剂OEP-70，搅拌均匀后再滴加入350kg脂肪醇聚氧乙烯醚JFC-2（20-25min之间滴加完毕），搅拌均匀后再缓慢加入过一硫酸氢钾30kg搅拌10分钟即可。所获得产品无刺激性气味。
对比例1
在反应釜中加入去离子水300kg，然后升温至68℃；在保持去离子水温度为68℃的条件下，进行以下操作：向去离子水中缓慢加入200kg耐碱活性剂OEP-70，搅拌均匀后滴加入350kg脂肪醇聚氧乙烯醚JFC-2（20-25min之间滴加完毕），搅拌均匀后再加入步骤1制备的抗静电乳化润滑油250kg(发明专利号ZL201310653893.5)，搅拌30分钟均匀融化后再缓慢加入过一硫酸氢钾30kg搅拌10分钟即可。所获得产品无刺激性气味。
对比例2
在反应釜中加入去离子水300kg，然后升温至68℃；在保持去离子水温度为68℃的条件下，进行以下操作：向去离子水中加入200kg耐碱活性剂OEP-70，搅拌均匀后再滴加入350kg脂肪醇聚氧乙烯醚JFC-2（20-25min之间滴加完毕），搅拌均匀后再缓慢加入过一硫酸氢钾30kg搅拌10分钟即可。所获得产品有刺激性气味。
对比例3
在反应釜中加入去离子水300kg，然后升温至68℃；在保持去离子水温度为68℃的条件下，进行以下操作：向去离子水中加入步骤1制备的抗静电乳化润滑油260kg(发明专利号ZL201310653893.5)，搅拌30分钟均匀融化后再缓慢加入200kg耐碱活性剂OEP-70，搅拌均匀后再缓慢加入过一硫酸氢钾30kg搅拌10分钟即可。所获得产品有刺激性气味。
对比例4
在反应釜中加入去离子水300kg，然后升温至68℃；在保持去离子水温度为68℃的条件下，进行以下操作：向去离子水中加入步骤1制备的抗静电乳化润滑油260kg(发明专利号ZL201310653893.5)，搅拌30分钟均匀融化后再缓慢加入200kg耐碱活性剂OEP-70，搅拌均匀后再滴加入350kg脂肪醇聚氧乙烯醚JFC-2（20-25min之间滴加完毕），搅拌10分钟即可。所获得产品无刺激性气味。
对比例5
在反应釜中加入去离子水300kg，然后升温至68℃；在保持去离子水温度为68℃的条件下，进行以下操作：向去离子水中缓慢加入200kg耐碱活性剂OEP-70，搅拌均匀即可。所获得产品有刺激性气味。
对比例6
在反应釜中加入去离子水300kg，然后升温至68℃；在保持去离子水温度为68℃的条件下，进行以下操作：向去离子水中缓慢滴加入350kg脂肪醇聚氧乙烯醚JFC-2（20-25min之间滴加完毕），搅拌10分钟即可。所获得产品有刺激性气味。
效果实验
检测实施例2-7、对比例1-6制备的产品的粘稠度、渗透力、耐碱性、耐高温性。
检测方法：
粘稠度的检测方法:粘度计。
渗透力的检测方法：取10g活性剂溶于1000ml水中，取10个3.5cm*3.5cm大小的圆形帆布片，放入水中，开始计时得t1，圆形帆布片开始沉入水下时停止计时得t2，t2-t1即为渗透力；取测试10次的平均值。
耐碱性的检测方法：取10g活性剂溶于1000ml水中，逐步加入氢氧化钠，边观察水的情况，边慢慢搅拌，若水中出现浑浊现象，则停止加氢氧化钠，记录所加入的氢氧化钠的量，从而得出活性剂的耐碱性。
耐高温性的检测方法：取10g活性剂溶于1000ml水中，逐步加温，然后取3.5*3.5cm的圆形帆布片，记录下在不同温度的渗透时间，若渗透时间开始明显变缓慢，则停止加温，记录温度，从而得出活性剂的耐高温性。

Claims (3)

1.一种耐高温强碱的纺织染色活性剂，其特征在于，包括以下步骤：
将300份去离子水升温至65-70℃，加入250-260份抗静电乳化润滑油搅拌至融化，然后加入200份耐碱活性剂OEP-70搅拌均匀，再滴加入350-360份脂肪醇聚氧乙烯醚JFC-2搅拌均匀，加入30-35份过一硫酸氢钾搅拌10分钟以上即可；
控制脂肪醇聚氧乙烯醚JFC-2在20-25min之间滴加完毕；
整个过程在保持去离子水温度恒定的条件下进行；
所述份为重量份；
所述抗静电乳化润滑油是指专利号为201310653893.5的专利产品。
2.根据权利要求1所述的一种耐高温强碱的纺织染色活性剂，其特征在于，以300份去离子水、250份抗静电乳化润滑油、200份耐碱活性剂OEP-70、350份脂肪醇聚氧乙烯醚JFC-2、30份过一硫酸氢钾为原料。
3.根据权利要求1或2所述的一种耐高温强碱的纺织染色活性剂，其特征在于，去离子水温度为68℃。
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