CN107384000A - A kind of anti-oxidant component for ink - Google Patents

A kind of anti-oxidant component for ink Download PDF

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Publication number
CN107384000A
CN107384000A CN201710652230.XA CN201710652230A CN107384000A CN 107384000 A CN107384000 A CN 107384000A CN 201710652230 A CN201710652230 A CN 201710652230A CN 107384000 A CN107384000 A CN 107384000A
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China
Prior art keywords
parts
vitamin
ink
modifying agent
degree
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CN201710652230.XA
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Chinese (zh)
Inventor
邵素丽
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Jieshou City Xinwang Printing Research Center
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Jieshou City Xinwang Printing Research Center
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Priority to CN201710652230.XA priority Critical patent/CN107384000A/en
Publication of CN107384000A publication Critical patent/CN107384000A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Medicines Containing Plant Substances (AREA)

Abstract

A kind of anti-oxidant component for ink, it is made up of the component of following parts by weight:10 20 parts of 2,6 di-tert-butyl, 4 sylvan, 10 20 parts of catechol, 8 12 parts of caryophyllus oil, 5 10 parts of graphene, 48 parts of Vitamin C palmitate, 4 parts of vitamin E2,0.3 0.8 parts of vitamin C, 0.2 0.4 parts of oxalic acid, 13 parts of nitromethane, 24 parts of modifying agent.The present invention selects common 2, the sylvan of 6 di-tert-butyl 4, catechol, caryophyllus oil ink antioxidant, adds graphene, Vitamin C palmitate, oxalic acid, nitromethane, vitamin E, vitamin C, modifying agent, antioxidant effect is more preferable, material more natural environmental-protective.

Description

A kind of anti-oxidant component for ink
Technical field
The present invention relates to printing technology, and in particular to a kind of anti-oxidant component for ink.
Background technology
Ink is the important materials for printing, and it is shown pattern, word on stock by printing or air brushing.Oil Ink includes main component and auxiliary element, and they equably mix and form a kind of stickiness colloidal fluid through repeat-rolling.By Link stuff, pigment, filler, auxiliary agent and solvent etc. form.For books and periodicals, packing and decorating, building decoration and electronic circuit sheet material etc. Various printings.As social demand increases, ink kind and yield also respective extension and growth.
To improve ink performance and some additional materials in press or in ink formulations.Also known as adjuvant, additives. Conventional ink addition agent have drier, diluent, viscosity reductant, thin dose, antioxidant, anti-gelatinizing agent, defoamer, surface-active Agent, anti-pinhole agent, slipping agent, plasticizer, preservative and spices etc..
Antioxidant is commonly called as antidesiccant, anti skinning agent, anti-drier.When employed in ink formulations some dryness oil plants and Some inorganic pigments such as lead chromate yellow, barba hispanica etc., because these materials are also easy to produce oxidation polymerization effect or with dry effect is urged, cause There is black face skinning during storage in ink, sometimes even solid to use;In printing process, air drying type Ink also have because downtime is long and skinning is solid on machine.In order to overcome these problems, can be added in this kind of ink suitable The antioxidant of amount, to delay the oxidation polymerization of drying oil.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of anti-oxidant component for ink.
The technical problems to be solved by the invention are realized using following technical scheme:
A kind of anti-oxidant component for ink, it is made up of the component of following parts by weight:2,6- di-tert-butyl -4- methyl Phenol 10-20 parts, catechol 10-20 parts, caryophyllus oil 8-12 parts, graphene 5-10 parts, Vitamin C palmitate 4-8 parts, dimension life Plain E2-4 parts, vitamin C 0.3-0.8 parts, oxalic acid 0.2-0.4 parts, nitromethane 1-3 parts, modifying agent 2-4 parts.
The above-mentioned anti-oxidant component for ink, the component of preferably following parts by weight are made:2,6- di-tert-butyl -4- first 15 parts of base phenol, 15 parts of catechol, 10 parts of caryophyllus oil, 8 parts of graphene, 6 parts of Vitamin C palmitate, 3 parts of vitamin E, dimension life Plain C0.5 parts, 0.3 part of oxalic acid, 2 parts of nitromethane, 3 parts of modifying agent.
The modifying agent, it is made up of the component of following parts by weight:Apple 8-16 parts, grape 10-15 parts, lemon 3-6 parts, Pomegranate shell 5-10 parts, tea seed shell 4-8 parts, green tea bar 5-10 parts, eggplant 2-5 parts, olive oil 1-3 parts.
The modifying agent, the component of preferably following parts by weight are made:12 parts of apple, 13 parts of grape, 5 parts of lemon, pomegranate 8 parts of shell, 6 parts of tea seed shell, 8 parts of green tea bar, 3 parts of eggplant, 2 parts of olive oil.
Preparation method for the anti-oxidant component of ink is to comprise the following steps:
A, 2,6- di-tert-butyl -4- sylvans, catechol, caryophyllus oil are mixed and heated to 150-180 degree, at the uniform velocity stirred 20-30 minutes;
B, graphene, Vitamin C palmitate are mixed, is heated to 70-80 degree, at the uniform velocity stir 20-30 minutes;
C, the mixture of step a mixture and step b is cooled to 30-40 degree, adds oxalic acid, nitromethane, changes Good dose of mixing, keeping temperature, 30 minute hour of stirring reaction;
D, vitamin E, vitamin C are added in step c mixtures, it is 7 to be neutralized to pH, quick to stir (1440r/ Min), milky product is obtained, carries out production and application.
The preparation method of above-mentioned modifying agent is, by apple, grape, lemon, pomegranate shell, tea seed shell, green tea bar, eggplant, Olive oil mixes, and is smashed with beating crusher, the mixture after smashing is put into fermentation tank, carries out first time sealing and fermenting, Fermentation temperature is 25-30 degree, fermentation time 5-6 hours, opens lid, and stirring allows it to contact oxygen, after stirring 10 minutes, is carried out Second of sealing and fermenting, fermentation temperature is 35-40 degree, and fermentation time is 15-20 hours, and mixture is squeezed after the completion of fermentation The processing of juice filtered juice, that is, obtain modifying agent.
The beneficial effects of the invention are as follows:
The present invention selects common 2,6- di-tert-butyl -4- sylvans, catechol, caryophyllus oil ink antioxidant, then Graphene, Vitamin C palmitate are added, oxalic acid, nitromethane, vitamin E, vitamin C, modifying agent, antioxidant effect is more It is good, material more natural environmental-protective.
Embodiment
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, tie below Specific embodiment is closed, the present invention is expanded on further.
Embodiment 1
A kind of anti-oxidant component for ink, it is made up of the component of following parts by weight:2,6- di-tert-butyl -4- methyl 10 parts of phenol, 10 parts of catechol, 8 parts of caryophyllus oil, 5 parts of graphene, 4 parts of Vitamin C palmitate, vitamin E2 part, vitamin C0.3 parts, 0.2 part of oxalic acid, 1 part of nitromethane, 2 parts of modifying agent.
The modifying agent, it is made up of the component of following parts by weight:8 parts of apple, 10 parts of grape, 3 parts of lemon, pomegranate shell 5 Part, 4 parts of tea seed shell, 5 parts of green tea bar, 2 parts of eggplant, 1 part of olive oil.
Preparation method for the anti-oxidant component of ink is to comprise the following steps:
A, 2,6- di-tert-butyl -4- sylvans, catechol, caryophyllus oil are mixed and heated to 150 degree, at the uniform velocity stir 20 points Clock;
B, graphene, Vitamin C palmitate are mixed, is heated to 70 degree, at the uniform velocity stirred 20 minutes;
C, the mixture of step a mixture and step b is cooled to 30 degree, adds oxalic acid, nitromethane, modifying agent Mixing, keeping temperature, 30 minute hour of stirring reaction;
D, vitamin E, vitamin C are added in step c mixtures, it is 7 to be neutralized to pH, quick to stir (1440r/ Min), milky product is obtained, carries out production and application.
The preparation method of above-mentioned modifying agent is, by apple, grape, lemon, pomegranate shell, tea seed shell, green tea bar, eggplant, Olive oil mixes, and is smashed with beating crusher, the mixture after smashing is put into fermentation tank, carries out first time sealing and fermenting, Fermentation temperature is 25 degree, fermentation time 5 hours, opens lid, and stirring allows it to contact oxygen, after stirring 10 minutes, carries out second Secondary sealing and fermenting, fermentation temperature are 35 degree, and fermentation time is 15 hours, at the filtered juice that to mixture squeeze the juice after the completion of fermentation Reason, that is, obtain modifying agent.
Embodiment 2
A kind of anti-oxidant component for ink, it is made up of the component of following parts by weight:2,6- di-tert-butyl -4- methyl 20 parts of phenol, 0 part of Catechol 2,12 parts of caryophyllus oil, 10 parts of graphene, 8 parts of Vitamin C palmitate, 4 parts of vitamin E, vitamin C0.8 parts, 0.4 part of oxalic acid, 3 parts of nitromethane, 4 parts of modifying agent.
The modifying agent, it is made up of the component of following parts by weight:16 parts of apple, 15 parts of grape, 6 parts of lemon, pomegranate shell 10 parts, 8 parts of tea seed shell, 10 parts of green tea bar, 5 parts of eggplant, 3 parts of olive oil.
Preparation method for the anti-oxidant component of ink is to comprise the following steps:
A, 2,6- di-tert-butyl -4- sylvans, catechol, caryophyllus oil are mixed and heated to 180 degree, at the uniform velocity stir 30 points Clock;
B, graphene, Vitamin C palmitate are mixed, is heated to 80 degree, at the uniform velocity stirred 30 minutes;
C, the mixture of step a mixture and step b is cooled to 40 degree, adds oxalic acid, nitromethane, modifying agent Mixing, keeping temperature, 30 minute hour of stirring reaction;
D, vitamin E, vitamin C are added in step c mixtures, it is 7 to be neutralized to pH, quick to stir (1440r/ Min), milky product is obtained, carries out production and application.
The preparation method of above-mentioned modifying agent is, by apple, grape, lemon, pomegranate shell, tea seed shell, green tea bar, eggplant, Olive oil mixes, and is smashed with beating crusher, the mixture after smashing is put into fermentation tank, carries out first time sealing and fermenting, Fermentation temperature is 30 degree, fermentation time 6 hours, opens lid, and stirring allows it to contact oxygen, after stirring 10 minutes, carries out second Secondary sealing and fermenting, fermentation temperature are 40 degree, and fermentation time is 20 hours, at the filtered juice that to mixture squeeze the juice after the completion of fermentation Reason, that is, obtain modifying agent.
Control group 1
A kind of anti-oxidant component for ink, it is made up of the component of following parts by weight:2,6- di-tert-butyl -4- methyl 10 parts of phenol, 10 parts of catechol, 8 parts of caryophyllus oil, 5 parts of graphene, 4 parts of Vitamin C palmitate, vitamin E2 part, vitamin C0.3 parts, 0.2 part of oxalic acid, 1 part of nitromethane.
Preparation method for the anti-oxidant component of ink is to comprise the following steps:
A, 2,6- di-tert-butyl -4- sylvans, catechol, caryophyllus oil are mixed and heated to 150 degree, at the uniform velocity stir 20 points Clock;
B, graphene, Vitamin C palmitate are mixed, is heated to 70 degree, at the uniform velocity stirred 20 minutes;
C, the mixture of step a mixture and step b is cooled to 30 degree, adds oxalic acid, nitromethane mixing, protect Hold temperature, 30 minute hour of stirring reaction;
D, vitamin E, vitamin C are added in step c mixtures, it is 7 to be neutralized to pH, quick to stir (1440r/ Min), milky product is obtained, carries out production and application.
Control group 2
A kind of anti-oxidant component for ink, it is made up of the component of following parts by weight:2,6- di-tert-butyl -4- methyl 20 parts of phenol, 0 part of Catechol 2,12 parts of caryophyllus oil, 10 parts of graphene, 8 parts of Vitamin C palmitate, 4 parts of vitamin E, vitamin C0.8 parts, 0.4 part of oxalic acid, 3 parts of nitromethane, 4 parts of modifying agent.
The modifying agent, it is made up of the component of following parts by weight:16 parts of apple, 15 parts of grape, 6 parts of lemon, pomegranate shell 10 parts, 8 parts of tea seed shell, 10 parts of green tea bar, 5 parts of eggplant, 3 parts of olive oil.
Preparation method for the anti-oxidant component of ink is to comprise the following steps:
A, 2,6- di-tert-butyl -4- sylvans, catechol, caryophyllus oil are mixed and heated to 120 degree, at the uniform velocity stir 20 points Clock;
B, graphene, Vitamin C palmitate are mixed, is heated to 80 degree, at the uniform velocity stirred 10 minutes;
C, the mixture of step a mixture and step b is cooled to 40 degree, adds oxalic acid, nitromethane, modifying agent Mixing, keeping temperature, react 30 minute hour;
D, vitamin E, vitamin C are added in step c mixtures, is well mixed, obtains milky product, carrying out production makes With.
The preparation method of above-mentioned modifying agent is, by apple, grape, lemon, pomegranate shell, tea seed shell, green tea bar, eggplant, Olive oil mixes, and is smashed with beating crusher, the mixture after smashing is put into fermentation tank, carries out first time sealing and fermenting, Fermentation temperature is 30 degree, fermentation time 6 hours, opens lid, and stirring allows it to contact oxygen, after stirring 10 minutes, carries out second Secondary sealing and fermenting, fermentation temperature are 40 degree, and fermentation time is 20 hours, at the filtered juice that to mixture squeeze the juice after the completion of fermentation Reason, that is, obtain modifying agent.
Experimental performance is tested after table 1 adds ink for the present invention with control group
Experiment proves that the smooth exquisiteness of the present invention, antioxygenic property are good.
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its Equivalent thereof.

Claims (6)

1. a kind of anti-oxidant component for ink, it is made up of the component of following parts by weight:2,6- di-tert-butyl -4- sylvans 10-20 parts, catechol 10-20 parts, caryophyllus oil 8-12 parts, graphene 5-10 parts, Vitamin C palmitate 4-8 parts, vitamin E2-4 parts, vitamin C 0.3-0.8 parts, oxalic acid 0.2-0.4 parts, nitromethane 1-3 parts, modifying agent 2-4 parts.
2. the anti-oxidant component according to claim 1 for ink, it is characterised in that the group of preferred following parts by weight Part is made:2,6- 15 parts of di-tert-butyl -4- sylvans, 15 parts of catechol, 10 parts of caryophyllus oil, 8 parts of graphene, Vitamin C palm 6 parts of acid esters, 3 parts of vitamin E, 0.5 part of vitamin C, 0.3 part of oxalic acid, 2 parts of nitromethane, 3 parts of modifying agent.
3. the anti-oxidant component according to claim 1 or 2 for ink, it is characterised in that the modifying agent, by following The component of parts by weight is made:Apple 8-16 parts, grape 10-15 parts, lemon 3-6 parts, pomegranate shell 5-10 parts, tea seed shell 4-8 Part, green tea bar 5-10 parts, eggplant 2-5 parts, olive oil 1-3 parts.
4. the anti-oxidant component according to claim 3 for ink, it is characterised in that the modifying agent, it is preferably following The component of parts by weight is made:12 parts of apple, 13 parts of grape, 5 parts of lemon, 8 parts of pomegranate shell, 6 parts of tea seed shell, 8 parts of green tea bar, 3 parts of eggplant, 2 parts of olive oil.
5. the preparation method of the as requested 1 or 2 anti-oxidant components for ink, it is characterised in that comprise the following steps:
A, 2,6- di-tert-butyl -4- sylvans, catechol, caryophyllus oil are mixed and heated to 150-180 degree, at the uniform velocity stir 20- 30 minutes;
B, graphene, Vitamin C palmitate are mixed, is heated to 70-80 degree, at the uniform velocity stir 20-30 minutes;
C, the mixture of step a mixture and step b is cooled to 30-40 degree, adds oxalic acid, nitromethane, modifying agent Mixing, keeping temperature, 30 minute hour of stirring reaction;
D, vitamin E, vitamin C are added in step c mixtures, it is 7 to be neutralized to pH, quick to stir (1440r/min), is obtained Milky product, carry out production and application.
6. a kind of preparation method for preparing any one of claim 3 or 4 modifying agent, it is characterised in that comprise the following steps: Apple, grape, lemon, pomegranate shell, tea seed shell, green tea bar, eggplant, olive oil are mixed, is smashed, will beaten with beating crusher Mixture after broken is put into fermentation tank, carries out first time sealing and fermenting, fermentation temperature is 25-30 degree, and fermentation time 5-6 is small When, lid is opened, stirring allows it to contact oxygen, after stirring 10 minutes, carries out second and is sealed by fermentation, fermentation temperature 35-40 Degree, fermentation time is 15-20 hours, carries out filtered juice processing of squeezing the juice to mixture after the completion of fermentation, that is, obtains modifying agent.
CN201710652230.XA 2017-08-02 2017-08-02 A kind of anti-oxidant component for ink Pending CN107384000A (en)

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CN103564562A (en) * 2013-07-12 2014-02-12 宁夏光彩生物科技有限公司 Fruit and vegetable fermented liquid, fruit and vegetable fermented beverage and preparation method of liquid and beverage
CN105086610A (en) * 2015-10-08 2015-11-25 苏州市永津彩印包装有限公司 High-quality anti-gelling printing ink
CN106509864A (en) * 2016-08-31 2017-03-22 应晓科 Production method of antioxidant enzyme
CN106675780A (en) * 2017-01-05 2017-05-17 天津融信蓝海生物科技有限公司 Compound antioxidant and grease containing same
CN106700732A (en) * 2016-11-21 2017-05-24 芜湖市创源新材料有限公司 Polymerization inhibition flowing type waterborne polyurethane gravure printing fluorescent ink and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102056997A (en) * 2008-05-06 2011-05-11 马拉德克里科聚合物公司 Anionic latex as a carrier for active ingredients and methods for making and using the same
CN103564562A (en) * 2013-07-12 2014-02-12 宁夏光彩生物科技有限公司 Fruit and vegetable fermented liquid, fruit and vegetable fermented beverage and preparation method of liquid and beverage
CN105086610A (en) * 2015-10-08 2015-11-25 苏州市永津彩印包装有限公司 High-quality anti-gelling printing ink
CN106509864A (en) * 2016-08-31 2017-03-22 应晓科 Production method of antioxidant enzyme
CN106700732A (en) * 2016-11-21 2017-05-24 芜湖市创源新材料有限公司 Polymerization inhibition flowing type waterborne polyurethane gravure printing fluorescent ink and preparation method thereof
CN106675780A (en) * 2017-01-05 2017-05-17 天津融信蓝海生物科技有限公司 Compound antioxidant and grease containing same

Non-Patent Citations (1)

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Application publication date: 20171124