CN106883673A - A kind of aqueous aluminum foil ink and preparation method thereof - Google Patents
A kind of aqueous aluminum foil ink and preparation method thereof Download PDFInfo
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- CN106883673A CN106883673A CN201710179760.7A CN201710179760A CN106883673A CN 106883673 A CN106883673 A CN 106883673A CN 201710179760 A CN201710179760 A CN 201710179760A CN 106883673 A CN106883673 A CN 106883673A
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- aqueous aluminum
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Epoxy Resins (AREA)
Abstract
The invention discloses a kind of aqueous aluminum foil ink and preparation method thereof, the aqueous aluminum foil ink includes according to the raw material of weight portion：54 58 parts of aqueous epoxy resins, 11 15 parts of waterborne polyurethane resin, 0.8 1.2 parts of antioxidant, 23 parts of scraping-resistant agent, 23 parts of levelling agent, 22 25 parts of water, 1.3 1.7 parts of defoamer.Benzene, the environment-friendly epoxy resin and polyurethane resin of ketones solvent, VOC content are low using being free of for the present invention, and environmental pollution is small, without harmful organic volatile compounds in ink, printed matter free from extraneous odour, without hazard residue, and energy meet the requirement of environmental protection, good fluidity, glossiness are high, levelability is good, printing drying property is good, it is adapted to high-speed press printing, is printed on the machine simple to operate, safety, 180 DEG C of heatproof does not fall the effect of ink, shallow net metastatic is good, is particularly well-suited to the printing of heatproof aluminium foil.
Description
Technical field
The present invention relates to a kind of ink, specifically a kind of aqueous aluminum foil ink and preparation method thereof.
Background technology
Since reform and opening-up, growing with China's printing industry, the quantity of ink of domestic demand is increasing, ink
Kind is more and more, and quality scale more and more higher, environmental consciousness is more and more stronger.At present, printing industry constantly prints to top grade packaging
Brush and environmental printing direction are developed.But the ink substantially solvent-based inks for largely being used in China, printing process at present,
The organic volatile of these solvent-based inks is not processed, and is directly discharged into workshop air, and not only production environment is caused necessarily
Influence, to workman health will also have greatly harm.Because these solvent-based inks contain the organic of 50-60% waving
Volatile material, in addition, also generally plus the diluent needed for adjusting ink viscosity in actual production process, then dry in printing
When dry, the total content even as high as 70-80% of the volatile component that ink is come out.
Water-based ink is referred to as ink, and it is mainly ground by water-soluble resin, organic pigment, solvent and related auxiliaries through compound
Mill is processed, and it is strict that water-based ink is particularly well-suited to the requirement of the sanitary conditions such as cigarette, wine, food, beverage, medicine, toy for children
Packaging Printing Product., with water (45-50%) as solvent, VOC content is extremely low, and environmental pollution is small for water-based ink；Solvent-borne type oil
Ink is with organic solvent (toluene, dimethylbenzene, industrial alcohol etc.) as solvent.In Flexible-Packaging Industry, because solvent-based ink is used
Volatility dry based on mode, the boiling point of solvent is lower, more volatile and discharge toxic gas pollution environment, in printing
After the completion of its surface also have the noxious material of residual, and the solvent that water-based ink is used is water and the second excluded from VOC lists
Alcohol etc., can substantially reduce the discharge of VOC.
The content of the invention
It is an object of the invention to provide a kind of good fluidity, glossiness aqueous aluminum foil ink high and preparation method thereof,
To solve the problems, such as to be proposed in above-mentioned background technology.
To achieve the above object, the present invention provides following technical scheme：
A kind of aqueous aluminum foil ink, includes according to the raw material of weight portion：Aqueous epoxy resins 54-58 parts, waterborne polyurethane resin
11-15 parts, antioxidant 0.8-1.2 parts, scraping-resistant agent 2-3 parts, levelling agent 2-3 parts, water 22-25 parts, defoamer 1.3-1.7 parts.
As further scheme of the invention：The aqueous aluminum foil ink, includes according to the raw material of weight portion：Water-base epoxy
Resin 55-57 parts, waterborne polyurethane resin 12-14 parts, antioxidant 0.9-1.1 parts, scraping-resistant agent 2.2-2.8 parts, levelling agent
2.2-2.8 parts, water 23-24 parts, defoamer 1.4-1.6 parts.
As further scheme of the invention：The aqueous aluminum foil ink, includes according to the raw material of weight portion：Aqueous ring
56 parts of oxygen tree fat, 13 parts of waterborne polyurethane resin, 1 part of antioxidant, 2.5 parts of scraping-resistant agent, 2.5 parts of levelling agent, 23.5 parts of water, disappear
1.5 parts of infusion.
The preparation method of the aqueous aluminum foil ink, comprises the following steps that：
（1）After mixer is cleaned up, aqueous epoxy resins are put into mixer, then after waterborne polyurethane resin is added,
Antioxidant, upper dispersator, rate of dispersion is added to be controlled to 140-160r/min, mixing time is 50-70min,
Appearance milky white after stirring, without particle；
（2）Continue to be stirred after scraping-resistant agent, levelling agent are slowly added to successively, mixing time is 25-35min, is sufficiently stirred for
Flowing is uniform after uniform, without clustering phenomena；
（3）After scattered material is stood into 25-35min, thermometer detection temperature is used, when ink temperature is below 38 DEG C,
Be slow added into water, and stir, during detection temperature, temperature be no more than 55 DEG C；
（4）Continue to stir 4-6min after finally defoamer is added, that is, obtain aqueous aluminum foil ink.
Compared with prior art, the beneficial effects of the invention are as follows：
The present invention is low using benzene, the environment-friendly epoxy resin and polyurethane resin of ketones solvent, VOC content is free of, dirty to environment
Dye is small, without harmful organic volatile compounds in ink, printed matter free from extraneous odour, and without hazard residue, and can meet the requirement of environmental protection, mobility
It is good, glossiness is high, levelability is good, printing drying property is good, is adapted to high-speed press and prints, be printed on the machine it is simple to operate,
Safety, 180 DEG C of heatproof does not fall the effect of ink, and shallow net metastatic is good, is particularly well-suited to the printing of heatproof aluminium foil.
Specific embodiment
The technical scheme of this patent is described in more detail with reference to specific embodiment.
Embodiment 1
A kind of aqueous aluminum foil ink, includes according to the raw material of weight portion：54 parts of aqueous epoxy resins, waterborne polyurethane resin 11
Part, 0.8 part of antioxidant, 2 parts of scraping-resistant agent, 2 parts of levelling agent, 22 parts of water, 1.3 parts of defoamer.
The preparation method of the aqueous aluminum foil ink, comprises the following steps that：
（1）After mixer is cleaned up, aqueous epoxy resins are put into mixer, then after waterborne polyurethane resin is added,
Antioxidant, upper dispersator, rate of dispersion is added to be controlled to 140r/min, mixing speed can not be too fast, during stirring
Between be 50min, appearance milky white after stirring, without particle；
（2）Continue to be stirred after scraping-resistant agent, levelling agent are slowly added to successively, mixing time is 25min, is stirred
Flow afterwards uniformly, without clustering phenomena；
（3）After scattered material is stood into 25min, thermometer detection temperature is used, when ink temperature is below 38 DEG C, then delayed
It is slow to add water, and stir, during detection temperature, temperature is no more than 55 DEG C；
（4）Continue to stir 4min after finally defoamer is added, that is, obtain aqueous aluminum foil ink.
Embodiment 2
A kind of aqueous aluminum foil ink, includes according to the raw material of weight portion：55 parts of aqueous epoxy resins, waterborne polyurethane resin 12
Part, 0.9 part of antioxidant, 2.2 parts of scraping-resistant agent, 2.2 parts of levelling agent, 23 parts of water, 1.4 parts of defoamer.
The preparation method of the aqueous aluminum foil ink, comprises the following steps that：
（1）After mixer is cleaned up, aqueous epoxy resins are put into mixer, then after waterborne polyurethane resin is added,
Antioxidant, upper dispersator, rate of dispersion is added to be controlled to 145r/min, mixing speed can not be too fast, during stirring
Between be 55min, appearance milky white after stirring, without particle；
（2）Continue to be stirred after scraping-resistant agent, levelling agent are slowly added to successively, mixing time is 28min, is stirred
Flow afterwards uniformly, without clustering phenomena；
（3）After scattered material is stood into 28min, thermometer detection temperature is used, when ink temperature is below 38 DEG C, then delayed
It is slow to add water, and stir, during detection temperature, temperature is no more than 55 DEG C；
（4）Continue to stir 4.5min after finally defoamer is added, that is, obtain aqueous aluminum foil ink.
Embodiment 3
A kind of aqueous aluminum foil ink, includes according to the raw material of weight portion：56 parts of aqueous epoxy resins, waterborne polyurethane resin 13
Part, 1 part of antioxidant, 2.5 parts of scraping-resistant agent, 2.5 parts of levelling agent, 23.5 parts of water, 1.5 parts of defoamer.
The preparation method of the aqueous aluminum foil ink, comprises the following steps that：
（1）After mixer is cleaned up, aqueous epoxy resins are put into mixer, then after waterborne polyurethane resin is added,
Antioxidant, upper dispersator, rate of dispersion is added to be controlled to 150r/min, mixing speed can not be too fast, during stirring
Between be 60min, appearance milky white after stirring, without particle；
（2）Continue to be stirred after scraping-resistant agent, levelling agent are slowly added to successively, mixing time is 30min, is stirred
Flow afterwards uniformly, without clustering phenomena；
（3）After scattered material is stood into 30min, thermometer detection temperature is used, when ink temperature is below 38 DEG C, then delayed
It is slow to add water, and stir, during detection temperature, temperature is no more than 55 DEG C；
（4）Continue to stir 5min after finally defoamer is added, that is, obtain aqueous aluminum foil ink.
Embodiment 4
A kind of aqueous aluminum foil ink, includes according to the raw material of weight portion：57 parts of aqueous epoxy resins, waterborne polyurethane resin 14
Part, 1.1 parts of antioxidant, 2.8 parts of scraping-resistant agent, 2.8 parts of levelling agent, 24 parts of water, 1.6 parts of defoamer.
The preparation method of the aqueous aluminum foil ink, comprises the following steps that：
（1）After mixer is cleaned up, aqueous epoxy resins are put into mixer, then after waterborne polyurethane resin is added,
Antioxidant, upper dispersator, rate of dispersion is added to be controlled to 155r/min, mixing speed can not be too fast, during stirring
Between be 65min, appearance milky white after stirring, without particle；
（2）Continue to be stirred after scraping-resistant agent, levelling agent are slowly added to successively, mixing time is 32min, is stirred
Flow afterwards uniformly, without clustering phenomena；
（3）After scattered material is stood into 32min, thermometer detection temperature is used, when ink temperature is below 38 DEG C, then delayed
It is slow to add water, and stir, during detection temperature, temperature is no more than 55 DEG C；
（4）Continue to stir 5.5min after finally defoamer is added, that is, obtain aqueous aluminum foil ink.
Embodiment 5
A kind of aqueous aluminum foil ink, includes according to the raw material of weight portion：58 parts of aqueous epoxy resins, waterborne polyurethane resin 15
Part, 1.2 parts of antioxidant, 3 parts of scraping-resistant agent, 3 parts of levelling agent, 25 parts of water, 1.7 parts of defoamer.
The preparation method of the aqueous aluminum foil ink, comprises the following steps that：
（1）After mixer is cleaned up, aqueous epoxy resins are put into mixer, then after waterborne polyurethane resin is added,
Antioxidant, upper dispersator, rate of dispersion is added to be controlled to 160r/min, mixing speed can not be too fast, during stirring
Between be 70min, appearance milky white after stirring, without particle；
（2）Continue to be stirred after scraping-resistant agent, levelling agent are slowly added to successively, mixing time is 35min, is stirred
Flow afterwards uniformly, without clustering phenomena；
（3）After scattered material is stood into 35min, thermometer detection temperature is used, when ink temperature is below 38 DEG C, then delayed
It is slow to add water, and stir, during detection temperature, temperature is no more than 55 DEG C；
（4）Continue to stir 6min after finally defoamer is added, that is, obtain aqueous aluminum foil ink.
The present invention is low using benzene, the environment-friendly epoxy resin and polyurethane resin of ketones solvent, VOC content is free of, to ring
Border pollution is small, without harmful organic volatile compounds in ink, printed matter free from extraneous odour, and without hazard residue, and can meet the requirement of environmental protection, flowing
Property good, glossiness is high, levelability is good, printing drying property it is good, be adapted to high-speed press printing, be printed on the machine side simple to operate
Just, safety, 180 DEG C of heatproof does not fall the effect of ink, and shallow net metastatic is good, is particularly well-suited to the printing of heatproof aluminium foil.
The better embodiment to this patent is explained in detail above, but this patent is not limited to above-mentioned embodiment party
Formula, in the ken that one skilled in the relevant art possesses, can also be on the premise of this patent objective not be departed from
Various changes can be made.
Claims (4)
1. a kind of aqueous aluminum foil ink, it is characterised in that the raw material according to weight portion includes：Aqueous epoxy resins 54-58 parts, water
11-15 parts of polyurethane resin of property, antioxidant 0.8-1.2 parts, scraping-resistant agent 2-3 parts, levelling agent 2-3 parts, water 22-25 parts, froth breaking
Agent 1.3-1.7 parts.
2. aqueous aluminum foil ink according to claim 1, it is characterised in that the raw material according to weight portion includes：Aqueous ring
55-57 parts of oxygen tree fat, waterborne polyurethane resin 12-14 parts, antioxidant 0.9-1.1 parts, scraping-resistant agent 2.2-2.8 parts, levelling agent
2.2-2.8 parts, water 23-24 parts, defoamer 1.4-1.6 parts.
3. aqueous aluminum foil ink according to claim 1, it is characterised in that the raw material according to weight portion includes：Aqueous ring
56 parts of oxygen tree fat, 13 parts of waterborne polyurethane resin, 1 part of antioxidant, 2.5 parts of scraping-resistant agent, 2.5 parts of levelling agent, 23.5 parts of water, disappear
1.5 parts of infusion.
4. the preparation method of a kind of aqueous aluminum foil ink as described in claim 1-3 is any, it is characterised in that specific steps are such as
Under：
（1）After mixer is cleaned up, aqueous epoxy resins are put into mixer, then after waterborne polyurethane resin is added,
Antioxidant, upper dispersator, rate of dispersion is added to be controlled to 140-160r/min, mixing time is 50-70min,
Appearance milky white after stirring, without particle；
（2）Continue to be stirred after scraping-resistant agent, levelling agent are slowly added to successively, mixing time is 25-35min, is sufficiently stirred for
Flowing is uniform after uniform, without clustering phenomena；
（3）After scattered material is stood into 25-35min, thermometer detection temperature is used, when ink temperature is below 38 DEG C,
Be slow added into water, and stir, during detection temperature, temperature be no more than 55 DEG C；
（4）Continue to stir 4-6min after finally defoamer is added, that is, obtain aqueous aluminum foil ink.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710179760.7A CN106883673A (en) | 2017-03-23 | 2017-03-23 | A kind of aqueous aluminum foil ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710179760.7A CN106883673A (en) | 2017-03-23 | 2017-03-23 | A kind of aqueous aluminum foil ink and preparation method thereof |
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| Publication Number | Publication Date |
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| CN106883673A true CN106883673A (en) | 2017-06-23 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201710179760.7A Pending CN106883673A (en) | 2017-03-23 | 2017-03-23 | A kind of aqueous aluminum foil ink and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112480740A (en) * | 2020-11-27 | 2021-03-12 | 成都普瑞斯特新材料有限公司 | High-performance water-based beer label ink and preparation method thereof |
| CN116200071A (en) * | 2022-12-21 | 2023-06-02 | 英科卡乐油墨(湖北)有限公司 | Water-based flexographic printing ink suitable for laminated paperboard |
| CN116333562A (en) * | 2023-04-20 | 2023-06-27 | 朱杰 | Paint with high color consistency and application method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1702124A (en) * | 2005-06-06 | 2005-11-30 | 贺文海 | Aqueous aluminum foil ink |
| CN101407655A (en) * | 2008-11-14 | 2009-04-15 | 上海维凯化学品有限公司 | Environment-friendly type aqueous aluminum foil protecting agent and preparation thereof |
-
2017
- 2017-03-23 CN CN201710179760.7A patent/CN106883673A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1702124A (en) * | 2005-06-06 | 2005-11-30 | 贺文海 | Aqueous aluminum foil ink |
| CN101407655A (en) * | 2008-11-14 | 2009-04-15 | 上海维凯化学品有限公司 | Environment-friendly type aqueous aluminum foil protecting agent and preparation thereof |
Non-Patent Citations (2)
| Title |
|---|
| 凌云星等: "《油墨技术手册（上）》", 31 May 2009, 印刷工业出版社 * |
| 李荣兴: "《油墨 上》", 31 December 1986, 印刷工业出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112480740A (en) * | 2020-11-27 | 2021-03-12 | 成都普瑞斯特新材料有限公司 | High-performance water-based beer label ink and preparation method thereof |
| CN116200071A (en) * | 2022-12-21 | 2023-06-02 | 英科卡乐油墨(湖北)有限公司 | Water-based flexographic printing ink suitable for laminated paperboard |
| CN116333562A (en) * | 2023-04-20 | 2023-06-27 | 朱杰 | Paint with high color consistency and application method thereof |
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Application publication date: 20170623 |