CN101665639A - Aqueous ink - Google Patents
Aqueous ink Download PDFInfo
- Publication number
- CN101665639A CN101665639A CN 200910186146 CN200910186146A CN101665639A CN 101665639 A CN101665639 A CN 101665639A CN 200910186146 CN200910186146 CN 200910186146 CN 200910186146 A CN200910186146 A CN 200910186146A CN 101665639 A CN101665639 A CN 101665639A
- Authority
- CN
- China
- Prior art keywords
- parts
- water
- color ink
- water color
- ink
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 51
- 229920005749 polyurethane resin Polymers 0.000 claims abstract description 10
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229960002887 deanol Drugs 0.000 claims abstract description 4
- 239000012972 dimethylethanolamine Substances 0.000 claims abstract description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 18
- 239000003973 paint Substances 0.000 claims description 2
- 239000000049 pigment Substances 0.000 abstract description 3
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 abstract 1
- 239000002904 solvent Substances 0.000 description 7
- 238000001035 drying Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical class OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 239000001055 blue pigment Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 239000001052 yellow pigment Substances 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention relates to an aqueous ink comprising following components by weight proportion: 30-35 parts of waterborne polyurethane resin, 30-35 parts of aqueous pigment, 3-5 parts of propanediol, 1-1.5 parts of dimethylethanolamine and 20-30 parts of water. The aqueous ink of the invention has excellent printing adaptability, is suitable for high-speed printing, meanwhile, has high temperature resistance, excellent gloss, and excellent adhesion force and water resistance.
Description
Technical field
The invention belongs to ink area, particularly a kind of water color ink.
Background technology
Water color ink abbreviates ink as, and water color ink is the different of solvent with the oil-based ink key distinction, and water color ink is solvent with water, and VOC content is extremely low, and environmental pollution is little; Oil-based ink is a solvent with organic solvent (toluene, dimethylbenzene, industrial spirit etc.).In the soft packaging industry, because it is main mode that solvent type ink all adopts the volatility drying, the boiling point of solvent is low more, just volatile more and discharge the toxic gas contaminate environment, also there is residual toxic substance on its surface after being completed for printing, and the solvent that water color ink uses is water and the ethanol got rid of from the VOC list etc., can reduce the discharging of VOC greatly.
At present, water color ink generally adopts maleated rosin fat, polyacrylic resin and modified acrylic acid emulsion etc. as low-melting ink vehicle.There are more problem in rosin, toxilic acid modified resin on glossiness, water resisting property and stability; Acrylic copolymer resin still has gap with solvent type ink on glossiness and printing adaptability.Though existing water color ink has solved most of former difficult points that pre-exist, as be difficult to use, the storage of printing ink, the limitation and the problems such as corona treatment and surface tension of base material, but still exist some technological difficulties to need to be resolved hurrily: such as 1), time of drying be still water color ink use in sixty-four dollar question, unless printing press is furnished with enough drying plants, otherwise print speed will be subjected to the constraint of time of drying; 2) water resisting property of water color ink remains further to be improved; 3) resistance to elevated temperatures also needs further improvement.
Summary of the invention
Technical problem to be solved by this invention is in order to overcome the deficiencies in the prior art, a kind of water color ink of suitable high speed printing to be provided.
For solving above technical problem, a kind of technical scheme that the present invention takes is:
A kind of water color ink, this water color ink comprises the component of following weight proportion: 20～30 parts in 30～35 parts of waterborne polyurethane resins, 30～35 parts of water-based paints, 3～5 parts of propylene glycol, 1～1.5 part of dimethylethanolamine and water.
According to an aspect of the present invention, described water color ink also includes 0.5～1 part sterilant.
According to the present invention, the preferred number-average molecular weight scope of described waterborne polyurethane resin is 10,000 to 200,000, more preferably 10 to 150,000.
Owing to take technique scheme, the present invention compared with prior art has following advantage:
1, has good printing adaptability, be fit to high speed printing;
2, has higher heat resistance;
3, have excellent gloss, fabulous bonding force and good water tolerance.
Embodiment
Below the specific embodiment of the present invention is described, but be not limited to these embodiment.
Embodiment 1
A kind of water color ink, this water color ink is made up of the component of following weight proportion: 30 parts in 30 parts of waterborne polyurethane resins (number-average molecular weight 100,000), 35 parts of water-based magenta pigments, 3.8 parts of propylene glycol, 1.2 parts of dimethylethanolamines and water.
Above-mentioned water color ink prepares by the following method: join waterborne polyurethane resin, propylene glycol, dimethylethanolamine, water in a mixing bowl in proportion, add the water-based magenta pigment while stirring, on homogenizer, stir and went up sand mill in 15～30 minutes then and disperse, treat that fineness reaches promptly to get ink product below 5 microns.
Embodiment 2
A kind of water color ink, this water color ink is made up of the component of following weight proportion: 35 parts in 30 parts of waterborne polyurethane resins (number-average molecular weight 150,000), 30 parts of water-based yellow pigments, 3.8 parts of propylene glycol, 1.2 parts of dimethylethanolamines and water.
The water color ink of present embodiment can be according to the method preparation identical with embodiment.
Embodiment 3
A kind of water color ink, this water color ink is made up of the component of following weight proportion: 30 parts in 35 parts of waterborne polyurethane resins (number-average molecular weight 100,000), 30 parts of water-based phthalocyanine blue pigments, 3 parts of propylene glycol, 1.2 parts of dimethylethanolamines, 0.8 part in sterilant and water.
The water color ink of present embodiment can be according to the method preparation identical with embodiment.
Performance to the water color ink of embodiment 1-3 is tested, and the results are shown in Table 1.
Table 1
As seen from Table 1, water color ink of the present invention has excellent gloss, fabulous bonding force and water tolerance, and its suitable high speed printing can be applicable to high-end liquid foodstuff and juice packages fields such as brick pillow bag, roof bag, Lilezhen.
More than the present invention has been done detailed description; its purpose is to allow the personage that is familiar with this art can understand content of the present invention and is implemented; can not limit protection scope of the present invention with this; all equivalences of doing according to spirit of the present invention change or modify, and all should be encompassed in protection scope of the present invention.
Claims (4)
1, a kind of water color ink is characterized in that: this water color ink comprises the component of following weight proportion: 20～30 parts in 30～35 parts of waterborne polyurethane resins, 30～35 parts of water-based paints, 3～5 parts of propylene glycol, 1～1.5 part of dimethylethanolamine and water.
2, water color ink according to claim 1 is characterized in that: described water color ink also includes 0.5～1 part sterilant.
3, water color ink according to claim 1 is characterized in that: the number-average molecular weight of described waterborne polyurethane resin is between 10,000 to 200,000.
4, water color ink according to claim 3 is characterized in that: the number-average molecular weight of described waterborne polyurethane resin is between 100,000 to 150,000.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200910186146 CN101665639B (en) | 2009-09-28 | 2009-09-28 | Aqueous ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200910186146 CN101665639B (en) | 2009-09-28 | 2009-09-28 | Aqueous ink |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101665639A true CN101665639A (en) | 2010-03-10 |
| CN101665639B CN101665639B (en) | 2012-02-01 |
Family
ID=41802428
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200910186146 Active CN101665639B (en) | 2009-09-28 | 2009-09-28 | Aqueous ink |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101665639B (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102161850A (en) * | 2011-05-24 | 2011-08-24 | 刘静 | Fabric pattern transfer ink and preparation method thereof |
| CN102311683A (en) * | 2011-09-23 | 2012-01-11 | 传美讯电子科技（珠海）有限公司 | Ink-jet printing pigment ink used on coating-free medium |
| CN102807787A (en) * | 2012-08-23 | 2012-12-05 | 句容市给力包装制品厂 | High-performance ink |
| CN102807786A (en) * | 2012-08-23 | 2012-12-05 | 句容市给力包装制品厂 | Water-based ink |
| CN105038395A (en) * | 2015-08-13 | 2015-11-11 | 合肥龙发包装有限公司 | Ink |
| CN106700726A (en) * | 2017-01-03 | 2017-05-24 | 胡庆福 | Self-inking stamp ink composition and preparation method thereof |
| CN107699042A (en) * | 2017-11-27 | 2018-02-16 | 湖南新力华纳米科技有限公司 | A kind of water nano metallic printing ink and preparation method |
| CN110183900A (en) * | 2019-05-30 | 2019-08-30 | 山东英诺新材料有限公司 | A kind of preparation method of flexible package water-based ink |
| CN111410865A (en) * | 2020-05-19 | 2020-07-14 | 英科·卡乐油墨(苏州)有限公司 | Water-based laminating inner printing ink |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7988777B2 (en) * | 2005-02-18 | 2011-08-02 | Seiko Epson Corporation | Aqueous ink composition and urethane resin composition for aqueous ink composition |
| CN101284966B (en) * | 2008-05-29 | 2010-07-14 | 西安理工大学 | Polyurethane based water-based ink and method for preparing same |
| CN101429359A (en) * | 2008-12-08 | 2009-05-13 | 山西鹰鲲科技有限公司 | Water-based plastic composite inner-printing ink |
-
2009
- 2009-09-28 CN CN 200910186146 patent/CN101665639B/en active Active
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102161850A (en) * | 2011-05-24 | 2011-08-24 | 刘静 | Fabric pattern transfer ink and preparation method thereof |
| CN102311683A (en) * | 2011-09-23 | 2012-01-11 | 传美讯电子科技（珠海）有限公司 | Ink-jet printing pigment ink used on coating-free medium |
| CN102807787A (en) * | 2012-08-23 | 2012-12-05 | 句容市给力包装制品厂 | High-performance ink |
| CN102807786A (en) * | 2012-08-23 | 2012-12-05 | 句容市给力包装制品厂 | Water-based ink |
| CN102807787B (en) * | 2012-08-23 | 2015-01-07 | 句容市给力包装制品厂 | High-performance ink |
| CN105038395A (en) * | 2015-08-13 | 2015-11-11 | 合肥龙发包装有限公司 | Ink |
| CN106700726A (en) * | 2017-01-03 | 2017-05-24 | 胡庆福 | Self-inking stamp ink composition and preparation method thereof |
| CN107699042A (en) * | 2017-11-27 | 2018-02-16 | 湖南新力华纳米科技有限公司 | A kind of water nano metallic printing ink and preparation method |
| CN110183900A (en) * | 2019-05-30 | 2019-08-30 | 山东英诺新材料有限公司 | A kind of preparation method of flexible package water-based ink |
| CN111410865A (en) * | 2020-05-19 | 2020-07-14 | 英科·卡乐油墨(苏州)有限公司 | Water-based laminating inner printing ink |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101665639B (en) | 2012-02-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101665639B (en) | Aqueous ink | |
| KR101939326B1 (en) | Solvent-based inkjet ink | |
| CN102382516B (en) | Water-based plastic printing ink and preparation method thereof | |
| EP3403840A1 (en) | Pretreatment solution, ink set and method for producing printed matter | |
| CN101033352B (en) | Water-based ink for ink-jet printing | |
| CN101429359A (en) | Water-based plastic composite inner-printing ink | |
| JP2010018730A (en) | Solvent-based inkjet ink composition | |
| CN105504974B (en) | A kind of flexographic plate printing water lottery ticket ink and preparation method thereof | |
| WO2015111644A1 (en) | Ink composition for aqueous ink jet | |
| CN103374251A (en) | Ink for ink jet recording and recording method | |
| CN103146258A (en) | Special water-based ink for printing tipping paper for cigarette and preparation method thereof | |
| CN105504981A (en) | Water-based ink for intaglio printing process of aluminum foil and preparation method of water-based ink | |
| CN107556815A (en) | A kind of water-based printing ink and preparation method thereof | |
| JP2016222754A (en) | Ink composition for aqueous inkjet | |
| CN103146257A (en) | Special water-based ink for printing polyvinyl chloride (PVC) foam wallpaper and preparation method thereof | |
| US20190085191A1 (en) | Water-based inks for thermoforming applications | |
| CN102652158A (en) | Ink | |
| EP3334788B1 (en) | Polystyrene varnishes, printing inks, coatings and overprints | |
| CN104893415A (en) | Environment-friendly water-borne glass ink and preparation method thereof | |
| JP2007063527A (en) | Ink composition for inkjet | |
| JP6248025B2 (en) | Surface-treated calcium carbonate, method for producing the same, printing ink composition and printed matter | |
| KR102233072B1 (en) | Black ink composition | |
| CN104151943A (en) | Grafting self-dispersive carbon black dispersion liquid and preparation method thereof | |
| CN104449035A (en) | Water-based ink with condensation prevention capacity | |
| CN108165090A (en) | Water-base gravure plastic film table print dumb light ink and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20240426 Address after: 432000 No. 6, Fazhan 3rd road, Saifu Industrial Park, Changjiang Bu street, Yingcheng City, Xiaogan City, Hubei Province Patentee after: Inkkale ink (Hubei) Co.,Ltd. Country or region after: China Address before: 215321 No. 5 South Binjiang Road, Zhang Pu town, Kunshan City, Jiangsu Province Patentee before: Yingke Kale Ink (Suzhou) Co.,Ltd. Country or region before: China |