CN102311683A - Ink-jet printing pigment ink used on coating-free medium - Google Patents
Ink-jet printing pigment ink used on coating-free medium Download PDFInfo
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- CN102311683A CN102311683A CN201110285844A CN201110285844A CN102311683A CN 102311683 A CN102311683 A CN 102311683A CN 201110285844 A CN201110285844 A CN 201110285844A CN 201110285844 A CN201110285844 A CN 201110285844A CN 102311683 A CN102311683 A CN 102311683A
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Abstract
The invention discloses an ink-jet printing pigment ink used on a coating-free medium. The ink comprises, by mass, 10 to 30 parts of aqueous pigment color paste, 1 part to 30 parts of an aqueous resin, 1 part to 9 parts of a drying solvent, 11 to 30 parts of a wetting agent and 10 to 49 parts of water. The pigment ink provided in the invention can be directly printed on the coating-free medium without being heated by a heating device and has the advantages of erasability, high glossiness, a fine and hierarchical printing effect, and brilliant and rich colors.
Description
Technical field
The present invention relates to a kind of paint ink, be specifically related to a kind of ink-jet printing dyestuff ink on the coating media that need not heat, directly be used to not have.
Background technology
General ink-jet paint ink directly is printed on does not have sticking power preferably on the enamelled paper that does not have coating media, not anti-wiping, and also the picture of printing is lackluster.Therefore, the popular paint ink generally can only be printed cated medium in the market, and cated medium (like RC printing paper) cost is all very high; Another kind of paint ink commonly used is after heating, to be printed on the enamelled paper of no coating media, therefore heating unit need be installed on PRN device, increases to print cost.
Therefore,, research and develop a kind of anti-wiping, high gloss, need not heat the paint ink that just can directly be printed on the no coating media and become the technical barrier that this area be badly in need of to solve to the demand in market.
Summary of the invention
The object of the present invention is to provide a kind of ink-jet printing dyestuff ink that is used to not have on the coating media, it need not, and heating can directly be printed on the no coating media through heating unit, and has advantages such as anti-wiping, high gloss.
The technical scheme that the present invention adopted is:
A kind of ink-jet printing dyestuff ink that is used to not have on the coating media contains water-based pigment colour paste 10 ~ 30 mass parts, water-base resin 1 ~ 30 mass parts, urges dried solvent 1 ~ 9 mass parts, wetting agent 11 ~ 30 mass parts, water 10 ~ 49 mass parts.
Preferably, described water-based pigment colour paste is a Pigment black series, Pigment blue series, Pigment red series, the combination of more than one in the Pigment Yellow 73 series; Wherein,
Pigment black series comprises at least a among C.I.P.B.11, C.I.P.B .13, C.I.P.B .15, C.I.P.B .16, the C.I.P.B.L7;
Pigment blue series comprises C.I.P.B.1, C.I. P.B.10, C.I. pigment blue 1 7:1, C.I. pigment Blue 15: at least a in 4;
Pigment red series comprises at least a among C.I.P.R.3, C.I.P.R.48:4, C.I.P.R.53:1, C.I.P.R.60:1, C.I.P.R.122, C.I.P.R.175, the C.I.P.R.258;
Pigment Yellow 73 series comprises at least a among C.I.P.Y.1, C.I.P.Y.63, C.I.P.Y.74, C.I.P.Y.83, C.I.P.Y.173, C.I.P.Y.177, C.I.P.Y.182, the C.I.P.Y.185.
Preferably, the average diameter grain of said water-based pigment colour paste is 100nm ~ 170nm.
Preferably, said water-base resin is at least a in vinyl resin, vinyl chloride-vinyl acetate resin, Synolac, urethane resin, Vinylite, the maleic acid resin etc.
It is preferably, said that to urge dried solvent be at least a in ethanol, propyl alcohol, Virahol, the isopropylcarbinol etc.
Preferably, said wetting agent is at least a in glycol ether, triglycol, Tetraglycol 99, USP Kosher, terepthaloyl moietie, polyoxyethylene glycol, triglycol monobutyl ether, the diethylene glycol monomethyl ether etc.
Preferably; Said a kind of ink-jet printing dyestuff ink that is used to not have on the coating media; The tensio-active agent that also contains 0.1 ~ 2 mass parts, said tensio-active agent are one or more among E1010 of EFKA3600, BYK346, Surfynol 440, Surfynol 466, Nissin company etc.
The preparation method of above-mentioned paint ink comprises the steps:
(1) takes by weighing each component by the prescription consumption, mix successively, stir;
(2) filter with the filter material of aperture, obtain ink-jet printing dyestuff ink less than 1.0 microns.
Beneficial effect of the present invention is:
(1) through in paint ink, adding the water-base resin through selecting, the paint ink of gained can directly be printed on the medium of band coating not without heating, and the sense that has levels of printing effect exquisiteness; Color is beautiful abundant; Be rich in gloss, anti-preferably erasibility arranged, high gloss effect;
(2) the dried solvent of urging that paint ink of the present invention is selected for use can volatilize step by step; Guarantee that after prining on the no coating media, sagging is not piled China ink; Not shrinkage cavity; Print the overlapping placement of the back specimen page phenomenon that can not stick together, make its back rapid drying of prining, guarantee not dried head after long-term standby is placed simultaneously again.
Embodiment
A kind of ink-jet printing dyestuff ink that is used to not have on the coating media contains water-based pigment colour paste 10 ~ 30 mass parts, water-base resin 1 ~ 30 mass parts, urges dried solvent 1 ~ 9 mass parts, wetting agent 11 ~ 30 mass parts, water 10 ~ 49 mass parts.
Preferably, described water-based pigment colour paste is a Pigment black series, Pigment blue series, Pigment red series, the combination of more than one in the Pigment Yellow 73 series; Wherein,
Pigment black series comprises at least a among C.I.P.B.11, C.I.P.B .13, C.I.P.B .15, C.I.P.B .16, the C.I.P.B.L7;
Pigment blue series comprises C.I.P.B.1, C.I. P.B.10, C.I. pigment blue 1 7:1, C.I. pigment Blue 15: at least a in 4;
Pigment red series comprises at least a among C.I.P.R.3, C.I.P.R.48:4, C.I.P.R.53:1, C.I.P.R.60:1, C.I.P.R.122, C.I.P.R.175, the C.I.P.R.258;
Pigment Yellow 73 series comprises at least a among C.I.P.Y.1, C.I.P.Y.63, C.I.P.Y.74, C.I.P.Y.83, C.I.P.Y.173, C.I.P.Y.177, C.I.P.Y.182, the C.I.P.Y.185.
Preferably, the average diameter grain of said water-based pigment colour paste is 100nm ~ 170nm.
Preferably, said water-base resin is at least a in vinyl resin, vinyl chloride-vinyl acetate resin, Synolac, urethane resin, Vinylite, the maleic acid resin etc.
It is preferably, said that to urge dried solvent be at least a in ethanol, propyl alcohol, Virahol, the isopropylcarbinol etc.
Preferably, said wetting agent is at least a in glycol ether, triglycol, Tetraglycol 99, USP Kosher, terepthaloyl moietie, polyoxyethylene glycol, triglycol monobutyl ether, the diethylene glycol monomethyl ether etc.
Preferably; Said a kind of ink-jet printing dyestuff ink that is used to not have on the coating media; The tensio-active agent that also contains 0.1 ~ 2 mass parts, said tensio-active agent are one or more among E1010 of EFKA3600, BYK346, Surfynol 440, Surfynol 466, Nissin company etc.
The preparation method of above-mentioned paint ink comprises the steps:
(1) takes by weighing each component by the prescription consumption, mix successively, stir;
(2) filter with the filter material of aperture, obtain ink-jet printing dyestuff ink less than 1.0 microns.
Below in conjunction with embodiment the present invention is further described, but is not limited thereto.
Embodiment 1
A kind of ink-jet printing dyestuff ink that is used to not have on the coating media, contain the component of following mass parts:
18 parts of black pigment mill bases (Pigment black C.I.P.B.11), 6 parts of glycol ethers, 10 parts of propyl alcohol, 20 parts of vinyl resins, 1 part of BYK346,45 parts of deionized waters.
Embodiment 2
A kind of ink-jet printing dyestuff ink that is used to not have on the coating media, contain the component of following mass parts:
15 parts of blue pigments mill bases (C.I. pigment blue 1 7:1), 6 parts of triglycol monobutyl ethers, 20 parts of ethanol, 10 parts of vinyl resins, 10 parts of Synolac, 3,600 1 parts of EFKA, 38 parts of deionized waters.
Embodiment 3
A kind of ink-jet printing dyestuff ink that is used to not have on the coating media, contain the component of following mass parts:
25 parts of red pigment mill bases (Pigment red C.I.P.R.3), 6 parts of triglycol monobutyl ethers, 20 parts of ethanol, 10 parts of vinyl resins, 10 parts of Synolac, 440 1.5 parts of Surfynol, 27.5 parts of deionized waters.
Embodiment 4
A kind of ink-jet printing dyestuff ink that is used to not have on the coating media, contain the component of following mass parts:
15 parts of yellow ultramarine mill bases (Pigment Yellow 73 C.I.P.Y.173), 6 parts of terepthaloyl moietie, 3 parts of ethanol, 10 parts of vinyl resins, 10 parts of Synolac, 440 1.5 parts of Surfynol, 54.5 parts of deionized waters.
Embodiment 5
A kind of ink-jet printing dyestuff ink that is used to not have on the coating media, contain the component of following mass parts:
15 parts of Pigment red C.I.P.R.3,15 parts of C.I.P.R.48:4,5 parts of USP Kosher, 15 parts of Virahols, 10 parts of vinyl resins, 10 parts of urethane resins, 30 parts of deionized waters.
Embodiment 6
A kind of ink-jet printing dyestuff ink that is used to not have on the coating media, contain the component of following mass parts:
10 parts of black pigment mill bases (Pigment black C.I.P.B.L7), 10 parts of triglycols, 15 parts of isopropylcarbinols, 10 parts of Vinylites, 55 parts of deionized waters.
Implement 7
A kind of ink-jet printing dyestuff ink that is used to not have on the coating media, contain the component of following mass parts:
20 parts of red pigment mill bases (Pigment red C.I.P.R.48:4), 10 parts of USP Kosher, 10 parts of ethanol, 30 parts of vinyl resins, 2 parts of EFKA3600,30 parts of deionized waters.
Embodiment 8
A kind of ink-jet printing dyestuff ink that is used to not have on the coating media, contain the component of following mass parts:
10 parts of Pigment blue C.I.P.B.1. pigment Blue 15: 4 10 parts, 10 parts of terepthaloyl moietie, 10 parts of propyl alcohol, 20 parts of vinyl resins, 2 parts of the E1010 of Nissin company, 40 parts of deionized waters.
Embodiment 9
A kind of ink-jet printing dyestuff ink that is used to not have on the coating media, contain the component of following mass parts:
10 parts of Pigment Yellow 73 C.I.P.Y.1,10 parts of Pigment Yellow 73 C.I.P.Y.83,10 parts of Pigment Yellow 73 C.I.P.Y.185,5 parts of USP Kosher, 15 parts of Virahols, 20 parts of vinyl chloride-vinyl acetate resins, 30 parts of deionized waters.
Embodiment 10
A kind of ink-jet printing dyestuff ink that is used to not have on the coating media, contain the component of following mass parts:
10 parts of Pigment black C.I.P.B .13,10 parts of Pigment black C.I.P.B .15,8 parts of Tetraglycol 99s, 10 parts of Virahols, 15 parts of Synolac, 50 parts of deionized waters.
The average diameter grain of used dispersible pigment color paste is 100 nm ~ 170nm among the above embodiment.Respectively component of each prescription of the foregoing description 1 ~ 10 is mixed in order one by one, stir with the speed of 1600r/min, leave standstill, the PP membrane filtration with 1 micron removes impurities and bacteria, and obtains paint ink of the present invention.The paint ink for preparing is filled in the print cartridge, need heat, directly on no coating media, get final product with printer prints.
The paint ink that embodiment 1 ~ 10 is prepared is filled in the print cartridge, does not heat, and directly on print media, tests following index with Epson ME300 stamping machine:
(1) glossiness: adopt Micro Tri Gloss-BYK Gardner surveying instrument to detect;
(2) density: adopt X-Ritem 8200 surveying instruments to detect;
(3) scuff resistance: electricity consumption kinetic friction experimental machine is tested, and it is the A level that printed matter surface does not have vestige; It is the B level that printed matter surface has slight trace; It is C that sharp trace appears in printed matter surface;
(4) tested media: art paper, gold foil paper, silver paper, PVC overlay paper, ET paper, ivory board, wove paper, bark paper etc.
Test result is seen table 1.
Test result shows: the paint ink that the embodiment of the invention 1 ~ 10 prepares need not the heating of process heating unit and can directly be printed on the no coating media; Have good glossiness and erasibility; The sense that has levels of printing effect exquisiteness; Color is beautiful abundant, and month not dried head of nozzle is placed in standby.
Claims (8)
1. an ink-jet printing dyestuff ink that is used to not have on the coating media is characterized in that, contains water-based pigment colour paste 10 ~ 30 mass parts, water-base resin 1 ~ 30 mass parts, urges dried solvent 1 ~ 9 mass parts, wetting agent 11 ~ 30 mass parts, water 10 ~ 49 mass parts.
2. according to the said a kind of ink-jet printing dyestuff ink that is used to not have on the coating media of claim, it is characterized in that described water-based pigment colour paste is a Pigment black series, Pigment blue series, Pigment red series, the combination of more than one in the Pigment Yellow 73 series; Wherein,
Pigment black series comprises at least a among C.I.P.B.11, C.I.P.B .13, C.I.P.B .15, C.I.P.B .16, the C.I.P.B.L7;
Pigment blue series comprises C.I.P.B.1, C.I. P.B.10, C.I. pigment blue 1 7:1, C.I. pigment Blue 15: at least a in 4;
Pigment red series comprises at least a among C.I.P.R.3, C.I.P.R.48:4, C.I.P.R.53:1, C.I.P.R.60:1, C.I.P.R.122, C.I.P.R.175, the C.I.P.R.258;
Pigment Yellow 73 series comprises at least a among C.I.P.Y.1, C.I.P.Y.63, C.I.P.Y.74, C.I.P.Y.83, C.I.P.Y.173, C.I.P.Y.177, C.I.P.Y.182, the C.I.P.Y.185.
3. according to claim 1 or 2 said a kind of ink-jet printing dyestuff inks that are used to not have on the coating media, it is characterized in that the average diameter grain of said water-based pigment colour paste is 100nm ~ 170nm.
4. according to the said a kind of ink-jet printing dyestuff ink that is used to not have on the coating media of claim 1; It is characterized in that said water-base resin is at least a in vinyl resin, vinyl chloride-vinyl acetate resin, Synolac, urethane resin, Vinylite, the maleic acid resin etc.
5. according to the said a kind of ink-jet printing dyestuff ink that is used to not have on the coating media of claim 1, it is characterized in that said to urge dried solvent be at least a in ethanol, propyl alcohol, Virahol, the isopropylcarbinol etc.
6. according to the said a kind of ink-jet printing dyestuff ink that is used to not have on the coating media of claim 1; It is characterized in that said wetting agent is at least a in glycol ether, triglycol, Tetraglycol 99, USP Kosher, terepthaloyl moietie, polyoxyethylene glycol, triglycol monobutyl ether, the diethylene glycol monomethyl ether etc.
7. according to the said a kind of ink-jet printing dyestuff ink that is used to not have on the coating media of claim 1; It is characterized in that; The tensio-active agent that also contains 0.1 ~ 2 mass parts, said tensio-active agent are at least a among E1010 of EFKA3600, BYK346, Surfynol 440, Surfynol 466, Nissin company etc.
8. the preparation method of each said paint ink of claim 1 ~ 7 comprises the steps:
(1) takes by weighing each component by the prescription consumption, mix successively, stir;
(2) filter with the filter material of aperture, obtain ink-jet printing dyestuff ink less than 1.0 microns.
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| CN201110285844A CN102311683A (en) | 2011-09-23 | 2011-09-23 | Ink-jet printing pigment ink used on coating-free medium |
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| CN201110285844A CN102311683A (en) | 2011-09-23 | 2011-09-23 | Ink-jet printing pigment ink used on coating-free medium |
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| CN103589242A (en) * | 2013-11-05 | 2014-02-19 | 英科.卡乐油墨(苏州)有限公司 | Children watercolor pen dedicated ink capable of being scrubbed |
| CN103709832A (en) * | 2013-12-26 | 2014-04-09 | 深圳市桑泰防伪材料有限公司 | Water-based ink, preparation method thereof and water-sense anti-counterfeiting material |
| CN104530822A (en) * | 2014-12-17 | 2015-04-22 | 浙江理工大学 | Quick-drying type water-based ink and preparation method thereof |
| CN106046940A (en) * | 2016-07-19 | 2016-10-26 | 青岛良友科技发展有限公司 | Environment-friendly inkjet printing ink composition for common printing media and raw wallpaper, as well as preparation method and application thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103589242A (en) * | 2013-11-05 | 2014-02-19 | 英科.卡乐油墨(苏州)有限公司 | Children watercolor pen dedicated ink capable of being scrubbed |
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| CN106046940A (en) * | 2016-07-19 | 2016-10-26 | 青岛良友科技发展有限公司 | Environment-friendly inkjet printing ink composition for common printing media and raw wallpaper, as well as preparation method and application thereof |
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Application publication date: 20120111 |