CN107382451A - The fertilizer granules of Fluxapyroxad-containsterilization and application - Google Patents

The fertilizer granules of Fluxapyroxad-containsterilization and application Download PDF

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Publication number
CN107382451A
CN107382451A CN201710525904.XA CN201710525904A CN107382451A CN 107382451 A CN107382451 A CN 107382451A CN 201710525904 A CN201710525904 A CN 201710525904A CN 107382451 A CN107382451 A CN 107382451A
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CN
China
Prior art keywords
fertilizer
fluxapyroxad
containsterilization
fertilizer granules
granules
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Withdrawn
Application number
CN201710525904.XA
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Chinese (zh)
Inventor
景辉
石葡萄
赵萍
张美翠
罗水凌
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SHAANXI BIAOZHENG CROPS SCIENCE CO Ltd
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SHAANXI BIAOZHENG CROPS SCIENCE CO Ltd
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Priority to CN201710525904.XA priority Critical patent/CN107382451A/en
Publication of CN107382451A publication Critical patent/CN107382451A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05DINORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D9/00Other inorganic fertilisers
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/561,2-Diazoles; Hydrogenated 1,2-diazoles
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Plant Pathology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Fertilizers (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention belongs to technical field of pesticide preparations, it is related to fertilizer granules and the application of a kind of Fluxapyroxad-containsterilization, the fertilizer granules of Fluxapyroxad-containsterilization are to be prepared by fluxapyroxad, carrier fertilizer, dispersing aid, sustained release agent, binding agent and filler according to existing process.There is obvious sterilization getting fat effect, the fertilizer granules and the application that are not likely to produce poisoning and can effectively avoid medicament from remaining exceeded Fluxapyroxad-containsterilization the invention provides a kind of.

Description

The fertilizer granules of Fluxapyroxad-containsterilization and application
Technical field
The invention belongs to technical field of pesticide preparations, is related to a kind of medicine fertilizer and application, more particularly to a kind of fluorine-containing azoles bacterium acyl The fertilizer granules of amine and application.
Background technology
Fluxapyroxad (Fluxapyroxad;No. CAS:907204-31-3;Chemical name:3- (difluoromethyl) -1- methyl - N- (3', 4', 5'- trifluoro [1,1'- biphenyl] -2- bases) -1H- pyrazole-4-carboxamides) it is the benzamide type that BASF AG develops Bactericide, it is succinate dehydrogenase inhibitors, it can suppress the respiration of fungi, suppress spore-germination, germ tube elongation, bacterium Silk growth and sporogenesis, fluxapyroxad are splendid to the control effect of money pinta and brown spot, have to various lawn diseases Prevention and treatment effect well.It is mainly used in various crop (cereal, legume vegetable, oilseed crop, peanut, the operatic circle, core Fruit root and tuberous vegetable, fruit type vegetable and cotton) foliage-spray and seed treatment.Inquire about by agricultural chemicals Information Network, do not have Fluxapyroxad Related product is registered, the simply suspending agent currently done experiment.Granule is a kind of new sustained release agent Type, high-toxic pesticide low toxicityization can be made, can control the rate of release of active ingredient in granule, lasting period length, to operator and Transporter's safety, effect on environment are small.Granule is the boundless a kind of novel form of application prospect.
In traditional agriculture production technology, it is separated using fertilizer and above-mentioned bactericide, twice or is used for multiple times The way of above-mentioned bactericide and fertilizer, add the labor intensity and work number of peasant, unfavorable agricultural development.By medicine fertilizer particle Agent applied once can complete two procedures of applying fertilizer and sterilize simultaneously, avoid the situation that conventional dispenser and fertilising can not take into account, section Save time and manually, improve production efficiency.Fertilizer granules are made in fluxapyroxad and Fertilizer combination and there is no report.
The content of the invention
In order to solve above-mentioned technical problem present in background technology, the invention provides one kind, and there is obvious sterilization to increase Fertilizer effect, it is not likely to produce poisoning and can effectively avoids medicament from remaining the fertilizer granules of exceeded Fluxapyroxad-containsterilization and answer With positive impetus is played in the increasing both production and income to reduction countryside tax system and agricultural.
To achieve these goals, the present invention adopts the following technical scheme that:
A kind of fertilizer granules of Fluxapyroxad-containsterilization, it is characterised in that:The fertilizer granules of the Fluxapyroxad-containsterilization It is to be prepared by fluxapyroxad, carrier fertilizer, dispersing aid, sustained release agent, binding agent and filler according to existing process.
The fertilizer granules of above-mentioned Fluxapyroxad-containsterilization be by mass percent be 0.1%~5% fluxapyroxad, 50%~70% carrier fertilizer, 0.5%~3% dispersing aid, 0.1%~2% sustained release agent, 0.1%~5% bonding Agent and surplus are that filler is prepared according to existing process.
Above-mentioned carrier fertilizer is macroelement fertilizer, secondary nutrients, trace-element fertilizer, organic fertilizer, amino acid Mixing more than one or both of fertilizer.
Above-mentioned dispersing aid is conventional natural dispersive agent or synthetic dispersing agent etc.;The sustained release agent be polyvinyl alcohol or Ah Draw primary glue;The binding agent is polyethylene glycol or industrial gelatine;The filler be calcium bicarbonate and white kaolinic mixture or Person's brick slag etc..
A kind of fertilizer granules of foregoing Fluxapyroxad-containsterilization melt disease, lawn maculopathy, grass in preventing and treating lawn leaf Application when level ground red thread and black scurf of potato.
It is an advantage of the invention that:
The invention provides a kind of fertilizer granules of Fluxapyroxad-containsterilization and application, passes through microbiocidal composition fluorine azoles bacterium acyl The combination of sciences of amine and fertilizer and a kind of fertilizer granules developed, using current newest slow release method effectively ensure agricultural chemicals, The science release of fertilizer, extend the lasting period of product, it is ensured that sterilization, fertilising double effectses, improve drug effect and agricultural chemicals utilization rate, subtract The waste of few agricultural chemicals, fertilizer, effective, science, rationally utilizes resource, environmental protection is had great significance, and uses reducing The countryside tax system of person and the increasing both production and income of agricultural also function to positive impetus.Meanwhile medicine fertilizer particle provided by the present invention In agent, the content of agricultural chemicals is relatively low, is not likely to produce poisoning, and medicament will not be caused to remain the problem of exceeded;Fertilizer granules make With conveniently, also applied fertilizer while dispenser, reduce labor intensity, reach the purpose for seeing time and labour saving;After fertilising, promote The growth of crop is entered, has improved the immunity of crop, enhanced the ability for resisting pest and disease damage, improve prevention effect indirectly; The slow releasing function of granule, extends the lasting period, has directionality during dispenser, drift is small, and environmental pollution is small;It is not attached to plant On the cauline leaf of thing, avoid direct contact with and produce poisoning etc., specifically, fertilizer granules of the invention have advantages below:
1st, the optimal spraying time for preventing and treating the diseases such as black scurf of potato uses when being potato sowing.The medicine fertilizer of the present invention Granule directly spreads fertilizer over the fields as base manure, can effectively prevent the generation of various diseases, avoids the dispenser after morbidity from being unable to reach reason Think prevention effect, meet the requirement of base manure again, get twice the result with half the effort.
2nd, preventing and treating Diseases of Turfgrass is used when disease occurs, and both supplemented with corresponding fertilizer, improves lawn resistance pest and disease damage Ability, prevented and treated disease again, killed two birds with one stone.
3rd, after applied once, play dual parts of sterilization and fertilising, save dispenser cost.Fluxapyroxad medicine fertilizer particle After agent is applied, can effectively prevent and treat crop disease, while play a part of basal dressing again, save individually apply by several times bactericide and The auxiliary agent and packing cost of fertilizer, save labor cost.The multiple regional labours in China are in short supply, and the product can have for planting household Effect saves labor cost.
4th, fertilizer granules belong to environmentally friendly formulation, and the release of granule can reduce the usage amount of wettable powder, and use into Regular dosage form is suitable with wettable powder etc. for this.
Embodiment
The fluxapyroxad fertilizer granules of embodiment 1 0.1%
The Bactericide fertilizer granule of the present invention is made up of the following raw material:Fluxapyroxad, nitrogenous fertilizer (carrier fertilizer), corn form sediment Powder (dispersing aid), vinyl alcohol (sustained release agent), polyethylene glycol (binding agent) and kaolin (filler).With Bactericide fertilizer granule Gross weight meter, wherein:Fluxapyroxad 0.1%, carrier fertilizer 50%, dispersing aid 0.5%, sustained release agent 0.1%, binding agent 0.1%, remaining is filler.
The fluxapyroxad fertilizer granules of embodiment 2 5%
The Bactericide fertilizer granule of the present invention is made up of the following raw material:Fluxapyroxad, organic fertilizer, cornstarch, ethene Alcohol, gum arabic and brick slag.With Bactericide fertilizer granule gross weight meter, wherein:Fluxapyroxad 5%, carrier fertilizer 60%, dispersing aid 3%, sustained release agent 2%, binding agent 10%, remaining is filler.
The fluxapyroxad fertilizer granules of embodiment 33%
The Bactericide fertilizer granule of the present invention is made up of the following raw material:Fluxapyroxad, a great number of elements, sweet potato starch, Ah Draw primary glue, polyethylene glycol and brick slag.With Bactericide fertilizer granule gross weight meter, wherein:Fluxapyroxad 3%, carrier fertilizer 70%, dispersing aid 2%, sustained release agent 1%, binding agent 5%, remaining is filler.
In order to preferably verify the practical application effect of the present invention, illustrate sterilization of the present invention with field efficacy example below The field control effectiveness test effect of fertilizer granules.
Biological Examples 1
(1) test medicine:0.5% fluxapyroxad fertilizer granules
(2) comparison medicament:25% fluxapyroxad suspending agent
(3) controlling object:Black scurf of potato
(4) application method:0.5% fluxapyroxad fertilizer granules directly spread fertilizer over the fields as base manure;The fluorine of comparison medicament 25% Azoles bacterium amide suspending agents mix soil when potato sowing, mix fertilizer and spread fertilizer over the fields.Result of the test is shown in Table 1.
The fluxapyroxad fertilizer granules of table 1 0.5% prevent and treat black scurf of potato
From result of the test table 1 as can be seen that the fluxapyroxad fertilizer granules of the present invention have to black scurf of potato Good prevention effect, preventive effect reaches more than 80%, and also gradually increases with the increase prevention effect of dosage, identical to have Prevention effect is better than the fluxapyroxad suspending agent of comparison medicament 25% in the case of effectiveness amount, is not found to Ma Ling during experiment Potato has poisoning generation, and succession crop is not influenceed;In terms of yield, using the rate of growth of fertilizer granules apparently higher than only Using the rate of growth of fertilizer.
Biological Examples 2
(1) test medicine:0.1% fluxapyroxad fertilizer granules
(2) comparison medicament:25% fluxapyroxad suspending agent
(3) controlling object:Lawn leaf melts disease, maculopathy
(4) application method:Lawn leaf melts disease or maculopathy early stage uses 0.1% fluxapyroxad fertilizer granules, Spread fertilizer over the fields;The spraying of the fluxapyroxad suspending agent of comparison medicament 25% uses.Result of the test is shown in Table 2.
The fluxapyroxad fertilizer granules of table 2 01% preventing and treating lawn leaf melts disease and maculopathy
From result of the test table 2 as can be seen that the fluxapyroxad fertilizer granules of the present invention melt disease or macula lutea to lawn leaf Disease has good prevention effect, and also gradually increases with the increase prevention effect of dosage, in the case of identical effective dose Prevention effect is better than the fluxapyroxad suspending agent of comparison medicament 25%, does not find there is poisoning generation to lawn during experiment; In terms of product appearance, after fertilizer granules, lawn is healthy and strong, neat, attractive in appearance.
Biological Examples 3
(1) test medicine:5% fluxapyroxad fertilizer granules
(2) comparison medicament:25% fluxapyroxad suspending agent, nitrogenous fertilizer
(3) controlling object:Lawn red thread
(4) application method:Lawn red thread early stage uses 3% fluxapyroxad fertilizer granules, spreads fertilizer over the fields;Comparison medicine The spraying of the fluxapyroxad suspending agent of agent 25% uses.Result of the test is shown in Table 3.
The fluxapyroxad fertilizer granules of table 3 5% prevent and treat lawn red thread
From result of the test table 3 as can be seen that the fluxapyroxad fertilizer granules of the present invention have very to lawn red thread Good prevention effect, and also gradually increase with the increase prevention effect of dosage, prevention effect in the case of identical effective dose Better than the fluxapyroxad suspending agent of comparison medicament 25%, do not find there is poisoning generation to lawn during experiment;Outside product In terms of sight, after fertilizer granules, lawn is healthy and strong, neat, attractive in appearance.
The production technology of the fertilizer granules preparation method of the present invention is ripe, can produce pledge according to product standard It is qualified to measure, the fertilizer granules of effect stability.To verify product quality stability, the heat storage stability experiment of product has been carried out: Stored 14 days under the conditions of 54 DEG C ± 2 DEG C, determine the resolution ratio of active ingredient, moisture, pH value etc..Result of the test table shows, produces Quality has good stability, and indices meet standard and require (result of the test is shown in Table 4).
The fluxapyroxad fertilizer granules heat storage stability result of the test of table 4 0.5%
Above-mentioned table of field test results is bright, and a kind of fertilizer granules of fungicide compound of the invention spread fertilizer over the fields use, with Control treatment compares, and has higher prevention effect to disease.Except controlling disease, also there is the effect of fertilising, using this After the medicine fertilizer particle of invention, crop growing state is vigorous, and leaf color is dark green, and respectively processing is higher than control group yield for embodiment.
From interpretation of result, fertilizer granules of the invention, the effect of fertilizer is on the one hand played, has improved crop yield, On the other hand the prevention effect to disease is enhanced, it is only necessary to which dispenser once, reaches the purpose of time and labour saving.Of course, it is possible to root According to the composition and proportioning in the fertilizer granules of Fluxapyroxad-containsterilization provided by the present invention, other agent are made according to existing process Type.
In summary, fertilizer granules provided by the invention, active height, good drug efficacy, fertilizer efficiency are notable, possess medicine, fertilizer Double effects, the effect of sterilization, getting fat can be given full play to, the features such as being not likely to produce resistance, and to crop safety, using letter Just, dosage is few, lasting period length, has effectively saved the Productive statistics of peasant, has improved crop yield, protected beneficial to environment Shield, benefit are more preferable.
It should be pointed out that above embodiment is only illustrative of the invention and is not intended to limit the scope of the invention, this The protection domain of invention should be defined by claim limited range.Come for those skilled in the art Say, do not departing from the spirit and scope of the present invention, some improvement can also be made, these improvement also should be regarded as the protection of the present invention Scope.

Claims (5)

  1. A kind of 1. fertilizer granules of Fluxapyroxad-containsterilization, it is characterised in that:The fertilizer granules of the Fluxapyroxad-containsterilization are It is prepared by fluxapyroxad, carrier fertilizer, dispersing aid, sustained release agent, binding agent and filler according to existing process.
  2. 2. the fertilizer granules of Fluxapyroxad-containsterilization according to claim 1, it is characterised in that:The Fluxapyroxad-containsterilization Fertilizer granules be by mass percent be 0.1%~5% fluxapyroxad, 50%~70% carrier fertilizer, 0.5% ~3% dispersing aid, 0.1%~2% sustained release agent, 0.1%~5% binding agent and surplus are filler according to existing work Skill is prepared.
  3. 3. the fertilizer granules of Fluxapyroxad-containsterilization according to claim 1 or 2, it is characterised in that:The carrier fertilizer One or both of macroelement fertilizer, secondary nutrients, trace-element fertilizer, organic fertilizer, amino acid fertilizer with On mixing.
  4. A kind of 4. fertilizer granules the answering when preventing and treating black scurf of potato of Fluxapyroxad-containsterilization as claimed in claim 3 With.
  5. 5. a kind of fertilizer granules of Fluxapyroxad-containsterilization as claimed in claim 3 preventing and treating lawn leaf melt disease, maculopathy with And application during red thread.
CN201710525904.XA 2017-06-30 2017-06-30 The fertilizer granules of Fluxapyroxad-containsterilization and application Withdrawn CN107382451A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109438072A (en) * 2018-12-19 2019-03-08 深圳诺普信农化股份有限公司 A kind of sustained release fertilizer granules containing fluorine azoles ring bacterium amine and its application
CN112250508A (en) * 2020-11-03 2021-01-22 中诚国联(河南)生物科技有限公司 Preparation method and application of pesticide-fertilizer granules containing thifluzamide and azoxystrobin

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CN103044136A (en) * 2012-12-17 2013-04-17 广东中迅农科股份有限公司 Sterilizing granule containing trifloxystrobin and preparation method thereof
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CN103044136A (en) * 2012-12-17 2013-04-17 广东中迅农科股份有限公司 Sterilizing granule containing trifloxystrobin and preparation method thereof
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CN104909885A (en) * 2015-05-29 2015-09-16 河南科技学院 Compound pesticide-fertilizer composition capable of controlling powdery mildew of Cedrela sinensis, and production method and application thereof
CN106748305A (en) * 2017-02-21 2017-05-31 山东康德源农业科技有限公司 A kind of medicine fertilizer with preventing and treating root-knot nematode function and preparation method and application

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109438072A (en) * 2018-12-19 2019-03-08 深圳诺普信农化股份有限公司 A kind of sustained release fertilizer granules containing fluorine azoles ring bacterium amine and its application
CN112250508A (en) * 2020-11-03 2021-01-22 中诚国联(河南)生物科技有限公司 Preparation method and application of pesticide-fertilizer granules containing thifluzamide and azoxystrobin

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