CN107375982A - A kind of air freshener for being applicable northern house - Google Patents

A kind of air freshener for being applicable northern house Download PDF

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CN107375982A
CN107375982A CN201710579660.3A CN201710579660A CN107375982A CN 107375982 A CN107375982 A CN 107375982A CN 201710579660 A CN201710579660 A CN 201710579660A CN 107375982 A CN107375982 A CN 107375982A
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extract
weight
parts
layer
raw material
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CN107375982B (en
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王婧宁
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/01Deodorant compositions
    • A61L9/013Deodorant compositions containing animal or plant extracts, or vegetable material
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/14Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
    • A01N43/16Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N63/00Biocides, pest repellants or attractants, or plant growth regulators containing microorganisms, viruses, microbial fungi, animals or substances produced by, or obtained from, microorganisms, viruses, microbial fungi or animals, e.g. enzymes or fermentates
    • A01N63/10Animals; Substances produced thereby or obtained therefrom
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/40Liliopsida [monocotyledons]
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/01Deodorant compositions

Abstract

The present invention provides a kind of air freshener for being applicable northern house, and the paste air freshener is from top to bottom divided into first layer, the second layer, third layer, the 4th layer, layer 5;The preparing raw material of the first layer includes the extract of Pistacia weinmannifolia leaf, the extract of Buddha's hand blade, cumquat juice, refined jasmine oil;The preparing raw material of the second layer includes beeswax, spirulina extract, the extract of asparagus, the achene extract of dandelion, ginkgo biloba p.e, Semen sojae atricolor extract, Bitter Orang P.E, pachyman;The preparing raw material of the third layer includes hyaluronic acid, the extract of pseudo-ginseng, the extract of betel nut, the extract of grape pip, lavender extract, Semen Myristicae extract;Described 4th layer of preparing raw material includes locust bean gum, grape skin extract, theobromine, false Soviet Union's extract, bigarabe leaf essential oil;The preparing raw material of the layer 5 includes aeroge, Lavender, hill gooseberry's essential oil, milkwort extract.

Description

A kind of air freshener for being applicable northern house
Technical field
The present invention relates to a kind of air purifying preparation, more particularly to a kind of air freshener for being applicable northern house.
Technical background
The air in the north is because the reason such as pollution sources and diffusion conditions so that northern air is more far short of what is expected than south.Such as: Northern dry weather;Vegetation cover rate is low;The north enters morning in winter, and day and night temperature is generally more than south, and cools quickly.So The microthermal climate in the north is more, and haze frequency is higher.South, the time that pollutant is detained in an atmosphere are less than plus northern precipitation It is relatively longer, it is easier to accumulate.
Current air freshener has following several:Volatile liquid air freshener, granular pattern air freshener, spraying Type air freshener and aerial fog type air freshener etc., above-mentioned volatile liquid air freshener and granular pattern air freshener Two kinds of air fresheners, a certain position only need to be rested on, without injection.And aerosol type air freshener and aerial fog type are with fresh air Agent, it is required to be sprayed by hand, aerosol can be just distributed in air, play a part of improving air.
Current market sales of air freshener species is a lot, and traditional is all by chemistry such as ether, dimethyl ether, propane Composition forms, and these materials are not only unable to decomposing harmful substances, can only be by erupting the perfume (or spice) of disperse using this air freshener Gas temporarily covers foreign flavor indoors, but can not really improve the quality of air, difficult because its composition is unable to resolving harmful gas With real fresh air.And after volatile solvent of the human body suction with certain fragrance gas, it is attracted quickly and invades god Through system, the nervous symptoms such as long-term use can cause neural paralysis, sensory nerve abnormal, body immunity is reduced.
When in house due to using the decoration materials such as rock, a kind of dangerous substance of colorless and odorless can be progressively discharged:Radon. All contain radon, and granite, brick sand, cement and gypsum etc in rock, soil, surface water and air, particularly containing radiation The lithotome of property element, is easiest to disengage radon.Due to entering morning in winter, what radon within doors can not be quickly sheds in the north.
For the above situation, the present invention provides a kind of air freshener for being applicable northern house, for the distinctive sky in the north Compression ring border, can effectively solve the air conditions in northern house.
The content of the invention
The present invention provides a kind of air freshener for being applicable northern house, and the paste air freshener is from top to bottom divided into First layer, the second layer, third layer, the 4th layer, layer 5;
The preparing raw material of the first layer includes the extract of Pistacia weinmannifolia leaf, the extract of Buddha's hand blade, cumquat juice, jasmine Jasmine essential oil;
The preparing raw material of the second layer includes beeswax, spirulina extract, the extract of asparagus, the achene of dandelion Extract, ginkgo biloba p.e, Semen sojae atricolor extract, Bitter Orang P.E, pachyman;
The preparing raw material of the third layer includes hyaluronic acid, the extract of pseudo-ginseng, the extract of betel nut, grape pip Extract, lavender extract, Semen Myristicae extract;
Described 4th layer of preparing raw material includes locust bean gum, grape skin extract, theobromine, false Soviet Union's extract, bigarabe Leaf essential oil;
The preparing raw material of the layer 5 includes aeroge, Lavender, hill gooseberry's essential oil, milkwort extract;
The aeroge is to be prepared using cellulose, plant extract mixtures as preparing raw material;The plant extract Thing mixture is Lombardy poplar tree extract, needle juniper extract, Acer palmatum extract, the mixture of licorice.
As one embodiment of the present invention, calculate in parts by weight, the preparing raw material of the first layer includes 1-8 weights Measure the extract of Pistacia weinmannifolia leaf, the extract of Buddha's hand blade of 1-5 parts by weight, the cumquat juice of 1-10 parts by weight, 1-3 weights of part Measure the refined jasmine oil of part.
As one embodiment of the present invention, it is characterised in that calculate in parts by weight, the preparation of the first layer is former The extract of Pistacia weinmannifolia leaf of the material comprising 3 parts by weight, the extract of the Buddha's hand blade of 2 parts by weight, the cumquat juice of 8 parts by weight, 2 The refined jasmine oil of parts by weight.
As one embodiment of the present invention, calculate in parts by weight, the preparing raw material of the second layer includes 1-10 The beeswax of parts by weight, the spirulina extract of 1-8 parts by weight, the extract of asparagus of 5-15 parts by weight, the Pu of 5-8 parts by weight The achene extract of public English, the ginkgo biloba p.e of 2-5 parts by weight, the Semen sojae atricolor extract of 0.1-1 parts by weight, 0.1-5 parts by weight Bitter Orang P.E, the pachyman of 10-15 parts by weight.
As one embodiment of the present invention, calculate in parts by weight, the preparing raw material of the second layer includes 7 weight Part beeswax, the spirulina extracts of 3 parts by weight, the extract of asparagus of 7 parts by weight, 6 parts by weight dandelion achene Extract, the ginkgo biloba p.e of 4 parts by weight, the Semen sojae atricolor extract of 0.7 parts by weight, the Bitter Orang P.E of 0.8 parts by weight, 12 The pachyman of parts by weight.
As one embodiment of the present invention, calculate in parts by weight, the preparing raw material of the third layer includes 1-5 weights Measure the hyaluronic acid of part, the extract of pseudo-ginseng of 5-10 parts by weight, the extracts of betel nut of 1-4 parts by weight, 2-8 parts by weight The extract of grape pip, the lavender extract of 0.5-5 parts by weight, 0.8-1.5 Semen Myristicae extracts.
As one embodiment of the present invention, calculate in parts by weight, the preparing raw material of the third layer includes 3 weight Part hyaluronic acid, the extracts of pseudo-ginseng of 7 parts by weight, the extracts of betel nut of 2 parts by weight, the grape pip of 6 parts by weight Extract, the lavender extract of 1.3 parts by weight, 0.9 Semen Myristicae extract.
As one embodiment of the present invention, calculate in parts by weight, described 4th layer of preparing raw material includes 1-5 weights The amount locust bean gum of part, the grape skin extract of 6-8 parts by weight, the theobromine of 1-15 parts by weight, the false Soviet Union of 10-15 parts by weight carry Take thing, the bigarabe leaf essential oil of 7-9 parts by weight.
As one embodiment of the present invention, calculate in parts by weight, described 4th layer of preparing raw material includes 3 weight The locust bean gum of part, the grape skin extract of 7 parts by weight, the theobromine of 7 parts by weight, false Soviet Union's extract of 12 parts by weight, 8 weight The bigarabe leaf essential oil of part.
As one embodiment of the present invention, calculate in parts by weight, the preparing raw material of the layer 5 includes 1-7 weights The amount aeroge of part, the Lavender of 1-6 parts by weight, hill gooseberry's essential oil of 0.1-8 parts by weight, the polygala of 1-8 parts by weight carry Take thing.
Embodiment
Participate in the election of the detailed description of the invention below for being preferable to carry out method and including embodiment this hair can be more easily understood Bright content.Unless otherwise defined, all technologies used herein and scientific terminology have common with art of the present invention The identical implication that technical staff is generally understood that.When contradiction be present, the definition in this specification is defined.
As used herein term " by ... prepare " it is synonymous with "comprising".Term "comprising" used herein, " comprising ", " having ", " containing " or its any other deformation, it is intended that cover including for non-exclusionism.For example, the combination comprising listed elements Thing, step, method, product or device are not necessarily limited to those key elements, but can include not expressly listed other key elements or Such a composition, step, method, product or the intrinsic key element of device.
Conjunction " Consists of " excludes any key element do not pointed out, step or component.If be used in claim, this Phrase will make claim be closed, it is not included the material in addition to the material of those descriptions, but relative normal Except rule impurity.When being rather than immediately following in the clause that phrase " Consists of " appears in claim main body after theme, It is only limited to the key element described in the clause;Other key elements are not excluded outside the claim as entirety.
Equivalent, concentration or other values or parameter are excellent with scope, preferred scope or a series of upper limit preferred values and lower limit During the Range Representation that choosing value limits, this, which is appreciated that, specifically discloses by any range limit or preferred value and any scope All scopes that any pairing of lower limit or preferred value is formed, regardless of whether the scope separately discloses.For example, when open During scope " 1 to 5 ", described scope should be interpreted as including scope " 1 to 4 ", " 1 to 3 ", " 1 to 2 ", " 1 to 2 and 4 to 5 ", " 1 to 3 and 5 " etc..When number range is described herein, unless otherwise indicated, otherwise the scope is intended to include its end Value and all integers and fraction within the range.
Singulative includes plural number and object is discussed, unless the context clearly dictates otherwise." optional " or it is " any It is a kind of " refer to that the item that describes thereafter or event may or may not occur, and the description include situation that event occurs and The situation that event does not occur.
Approximate term in specification and claims is used for modifying quantity, and it is specific to represent that the present invention is not limited to this Quantity, include the part of the amendment of the acceptable change without cause related basic function close to the quantity.Phase Answer, modify a numerical value with " about ", " about " etc., mean that the invention is not restricted to the exact numerical.It is approximate in some examples Term likely corresponds to the precision of the instrument of measured value.In present specification and claims, scope limits can be with Combine and/or exchange, these scopes include all subranges contained therebetween if not stated otherwise.
In addition, indefinite article " one kind " before key element of the present invention or component and "one" to key element or the quantitative requirement of component (i.e. occurrence number) unrestriction.Therefore "one" or " one kind " should be read as including one or at least one, and odd number The key element or component of form also include plural form, unless the obvious purport of the quantity refers to singulative.
" polymer " means by the polymerizable compound prepared by the monomer that polymerize identical or different type.Generic term " polymer " includes term " homopolymer ", " copolymer ", " terpolymer " and " EVA ".
" EVA " means the polymer prepared by polymerizeing at least two different monomers.Generic term " EVA " includes (its is general with term " terpolymer " for term " copolymer " (its typically to refer to the polymer prepared by two kinds of different monomers) To refer to the polymer prepared by three kinds of different monomers).It also includes the polymerization for planting monomer by polymerization four or more to manufacture Thing." blend " means that two or more polymer mixes the polymerization to be formed by physics or chemical method jointly Thing.
The present invention provides a kind of air freshener for being applicable northern house, and the paste air freshener is from top to bottom divided into First layer, the second layer, third layer, the 4th layer, layer 5;
The preparing raw material of the first layer includes the extract of Pistacia weinmannifolia leaf, the extract of Buddha's hand blade, cumquat juice, jasmine Jasmine essential oil;
The preparing raw material of the second layer includes beeswax, spirulina extract, the extract of asparagus, the achene of dandelion Extract, ginkgo biloba p.e, Semen sojae atricolor extract, Bitter Orang P.E, pachyman;
The preparing raw material of the third layer includes hyaluronic acid, the extract of pseudo-ginseng, the extract of betel nut, grape pip Extract, lavender extract, Semen Myristicae extract;
Described 4th layer of preparing raw material includes locust bean gum, grape skin extract, theobromine, false Soviet Union's extract, bigarabe Leaf essential oil;
The preparing raw material of the layer 5 includes aeroge, Lavender, hill gooseberry's essential oil, milkwort extract;
The aeroge is to be prepared using cellulose, plant extract mixtures as preparing raw material;The plant extract Thing mixture is Lombardy poplar tree extract, needle juniper extract, Acer palmatum extract, the mixture of licorice.
First layer
The preparing raw material of the first layer includes the extract of Pistacia weinmannifolia leaf, the extract of Buddha's hand blade, cumquat juice, jasmine Jasmine essential oil.
Pistacia weinmannifolia
Pistacia weinmannifolia is Anacardiaceae, pistache plant, evergreen shrubs or dungarunga, high 2-8 rice, and tree crown reaches 10-15 rice.By When blade is taken or rubs, there is one to be gained the name similar to the fragrant that Chinese prickly ash mixes with citrus.
The property of medicine:Acrid flavour is fragrant, nontoxic.Uncharmed bad odor, middle benefit gas profit diaphragm, pleasant analgesic, quench one's thirst of promoting the production of body fluid, and permanent tooth is dispelled halitosis, is calmed the nerves, Centering.It is used as medicine with leaf and bark, there is eliminating inflammation and expelling toxin, the effect of astringing to arrest diarrhea.Its resin can be alternative, has permanent tooth to dispel the effect of halitosis.
The leaves effect diarrhoea for having eliminating inflammation and expelling toxin and convergence that can be used as medicine is drunk with the pan-fried water of band leaf top tip branch and worked well;After leaf dries Fine ground temple of making can have permanent tooth effect for fragrant raw material, fruit containing grease.It is effective for part psoriasis.Fresh leaf is pounded pureed, The activity of tyrosinase and catalase can be suppressed, can also make melanin reduction-decolor, moreover it is possible to effective Scavenger of ROS.
The extract of Pistacia weinmannifolia leaf refers to extract the leaf of Pistacia weinmannifolia obtained extract, specific preparation method It is as follows:Take in the fresh tender leaf 200g inputs extraction kettle of incense wood leaf, be placed in high pressure extraction tank, be passed through CO2And it is forced into 500Psi, Extracting temperature are 40 DEG C, extract 80min every time, extract 3 times altogether, obtain grease 1.9g.
Buddha's hand
Buddha's hand:Fruit each carpel separation in maturation, form the fruit lobe of elongate curved, shape such as finger, therefore named Buddha's hand.Property Taste:It is pungent, bitter, sour, temperature.Return liver, spleen, lung channel.
The fruit of Buddha's hand is chocho, is a kind of cucurbitaceae vegetable kind.The clear and melodious succulence of chocho, delicious and tasty, nutrition Value is higher, can both cook, and can is eaten it raw when fruit, and a kind of stomach invigorating, the Chinese medicine of qi-regulating.Made tea with the leaf, flower, fruit of Buddha's hand Infusing drugs in wine is drunk, and has the effect of regulating qi-flowing for strengthening spleen, preventing phlegm from forming and stopping coughing, relaxing tendons and activating collaterals.Chocho fine and tender taste, the fruit of every 100 grams of chocho Contain 90-92 grams of moisture in reality, egg is from 0.9-1.2 grams of matter, 2.6-7.7 grams of carbohydrate, vitamin C 12-22 milligrams, Hu Luo The micrograms of Bu Su 20.The content of potassium is higher, and up to 190 milligrams, 0.1 milligram of riboflavin, 500 milligrams of calcium, 0 milligram of P 32, iron 40 are in the least Gram, 10 milligrams of sodium, 0.03 milligram of copper, 7 milligrams of magnesium, the microgram of zinc 8.35, the microgram of selenium 2.3.Additionally containing folic acid, pantothenic acid, nicotinic acid Deng.The seedling of chocho is also nutritious vegetables, is that various vegetables can not compare.
The extract of Buddha's hand blade refers to extract the leaf of Buddha's hand obtained extract, and specific preparation method is such as Under:Buddha's hand blade is cleaned, cut into slices, and 0.01 times of salt mixing, then add the decocting of 12 times of weight to boil 3h, by decoction liquor vacuum Dry, produce.
Cumquat juice
Cumquat, Rutaceae, belong to golden mandarin orange.Also known as golden jujube, golden mandarin orange, small orange.Evergreen shrubs.It is high 3 meters, do not have thorn typically, it is small Branch green, branch is more during nutritional sufficiency;Leaf lanceolar is to oblong, 5-9 centimeter lengths, full edge, petiole slightly wing;Spend it is small, in vain Color, fragrance, 1-3 axillary, petal 5, stamen 20-25, the Room of ovary 5;Fruit ellipse or obovate, long 2.5-3.5 centimetres, gold Yellow.Cumquat is not only attractive in appearance, and fruit contains the compositions such as abundant vitamin C, cumquat glucoside, to safeguarding cardiovascular function, prevents The diseases such as hemostatic tube hardening, hypertension have certain effect.As food therapeutic health, cumquat preserved fruit can be used for whetting the appetite, drink gold Orange juice can promote the production of body fluid to quench thirst, and add radish Juice, pear juice drink-service to control cough.Specific edibility is as follows:Cumquat to preventing angiorrhoxis, Reduce capillary fragility and permeability, slow down vascular sclerosis play the role of it is good;Cumquat can produce bidirectional modulation to blood pressure, high What blood pressure, vascular sclerosis and patients with coronary heart disease were eaten is highly profitable;Cumquat has promoting qi circulation and removing obstruction in the collateral, eliminates indigestion and phlegm, and has secretion replenishing and throat moistening to sober up Effect;Often feeding cumquat can also strengthen the cold tolerance of body, anti-to cure cold.
In the present invention, the cumquat juice refers to clean whole cumquat, after being squeezed the juice using juice extractor, stands 24 hours Afterwards, supernatant liquor is taken.
Jasmine
Jasmine, alias:Jasmine, Oleaceae, gelsemium be upright or climbing shrub, up to 3 meters.Sprig cylinder is slightly pressed It is flat-shaped, it is sometimes hollow, dredge by pubescence.Leaf is to life, Dan Ye, blade papery, circular, ellipse, ovate-elliptic or obovate, and two End circle or blunt, base portion micro-heart sometimes, above it is slightly concave enter or recessed, protruding below, thready pulse is in two sides Chang Mingxian, microprotrusion, In addition between following arteries and veins often with tuft, remaining is hairless;Sliver Long Circle is round or blunt to subcircular, tip.Fruit is spherical, in purple black Color.The month at florescence 5-8, the fruiting period 7-9 months.The Hua Jixiang of jasmine, it is famous jasmine tea raw material and important flavor of raw material;Flower, leaf medicine With controlling red eye, swell pain, and there is relieving cough and reducing sputum effect.
The extracting method of heretofore described refined jasmine oil is as follows:Jasmine 50g is taken, adds 5L deionized waters and ethanol (water Volume ratio with ethanol is 5:1) put into afterwards in boiler, after being heated to 80 DEG C, use indirect steam heating instead to boiling, condensate liquid Water-oil separating is carried out into oil water separator, collects refined jasmine oil;Add anhydrous sodium sulfate drying filtering and carry out dewater treatment, then Activated carbon is added, and is stirred 48 hours at normal temperatures, is filtrated to get the standard refined jasmine oil of dehydration and decolorization.
As one embodiment of the present invention, the preparing raw material of the first layer includes the delicate fragrance ebon of 1-8 parts by weight The extract of leaf, the extract of the Buddha's hand blade of 1-5 parts by weight, the cumquat juice of 1-10 parts by weight, the jasmine essence of 1-3 parts by weight Oil.
As a kind of preferred embodiment of the present invention, the preparing raw material of the first layer includes the Pistacia weinmannifolia leaf of 3 parts by weight Extract, the extract of Buddha's hand blade, the cumquat juice of 8 parts by weight, the refined jasmine oil of 2 parts by weight of 2 parts by weight.
The second layer
The preparing raw material of the second layer includes beeswax, spirulina extract, the extract of asparagus, the achene of dandelion Extract, ginkgo biloba p.e, Semen sojae atricolor extract, Bitter Orang P.E, pachyman.
Beeswax
Beeswax is secreted by the belly of honeybee, is the material of honeybee nesting, wax ester is its main component, and chemical constitution is: CH3(CH2)29OCO(CH2)14CH3, the molecular weight of wax ester is larger, and its space structure makes hair as a root long hair fastener, the presence of double bond The polymerization of card is overlapping, and easily forms the network structure framework configuration of 3 D stereo.
The main component of beeswax is higher fatty acids and esters, aliphatic acid and carbohydrate synthesized by monohydric alcohol, but because honeybee kind, The differences such as the sources of nectar and pollen, refinement method, its composition also have certain difference.
(1) esters:Fatty acid ester includes monoesters class and hydroxyl esters, and content is 70%~75%.There is palm fibre in monoesters class Palmitic acid acid melissa alcohol ester 23%, palmitic acid lacca ester 2%, cerinic acid melissa alcohol ester 12%, pyrogallic acid melissa alcohol ester 12%.Hydroxyl There are hydroxy-palmitic acid ceryl alcohol ester 8%~9%, dibasic acid esters 9%~9.5%, acid esters 4%~4.5% in base ester class.
(2) aliphatic acid:Free fatty acid content is 10%~15%;Saturated fatty acid 9%~11%, wherein cerinic acid 3.3%~4.4%, lignoceric acid 1%~1.5%, melissic acid and montanic acid 2%, leaf lice acid 1.3%~1.5%, Jiao's property are not eaten Sub- acid 1.5% etc..
(3) carbohydrate:Contents of saccharide is 10%~16%, and saturated hydrocarbons is the most notable with 15~31 carbon atom chains, wherein 25 alkane Hydrocarbon 0.3%, 27 alkane 0.3%, 29 alkane 1%~2%, 31 alkane 8%~9%;Unsaturated hydrocarbons is mainly 30 alkane, is accounted for 2.5%.
(4) other compositions in beeswax:Contain fatty acid cholesterol ester, colouring agent (predominantly 1~3 pair of hydroxide in beeswax Thing flavones), W- nutmegs lactone, free alkyl alcohol etc..In addition, beeswax also contains a small amount of water and mineral matter, in beeswax ash content Carbon, hydrogen, oxygen element account for 80%, 13%, 7% respectively.
Beeswax main component can be divided into 4 major classes, i.e. esters, free acids, free alcohols and hydro carbons.Additionally containing micro Volatile oil and pigment.Have in esters myricyl palmitate (Myricyl palmitate, account for 80%, be beeswax mainly into Point), myricyl cerotate (Myricyl cerotate), myricyl hypogaeate (Myrcyl hypogaeate);In free acid Having cerinic acid in class, (15%) Cer otic acid, are accounted for, sweet tetracid (Lignoceric acid), montanic acid (Montanic Acid), melissic acid (Meli ssic acid), leaf lice acid (Psyllic acid), hypogaeic acid (Hypogaeic Acid), neocerotic acid (Neoceroticacid) is pentacosanic acid;There is positive Octacosanol (n-Octacosanol) in free alcohols, Melissyl alcohol (Myricyl alcohol);There is pentacosane (Pentacosane) in hydro carbons, heptacosane (Heptacosane), twenty Nine alkane (Nonacosane), 1 alkane (H entriacontane) and undersaturated melene (Melene).
In the present invention, the beeswax is bought from Dongguang County friend's sun beeswax products factory.
Spirulina
Spirulina (scientific name:Spirulina) it is a kind of unicellular lower eukaryote, prokaryotes, is made up of unicellular or many cells Filamentous, body is long 200-500 μm, wide 5-10 μm, cylinder, is bent in loose or close well-regulated spiral rotation shape, shaped like Clockwork feed, so gain the name.Toxicity with mitigation cancer radiation, chemotherapy, improves immunologic function, reduces the work(such as blood fat Effect.
Spirulina (60%) containing protein, mainly by isoleucine (isoleucine), leucine (leucine), rely ammonia Sour (lysine), methionine (methionine), phenylalanine (phenylalanine), threonine (threonine), color ammonia Sour (tryptophane), valine (valine) etc. composition.In addition, also fatty, carbohydrate, chlorophyll, carotenoids Element, phycocyanobilin, vitamin (vitamin) A, B1, B2, B6, B12, E, nicotinic acid (nicotinic acid), creatine (creatine), gamma-Linolenic acid (γ-linolenic acid), calcium pantothenate, folic acid (folic acid) and calcium, iron, zinc, magnesium Deng.
Spirulina polysaccharide is that carbohydrate is primarily present form in spirulina frond, content be up to dry weight 14%~ 16%.Lipoid contained by spirulina is all almost important unsaturated fatty acids, and cholesterol level is atomic.Spirulina powder Protein content be up to 60%~72%, 1.7 times equivalent to soybean, 6 times of wheat, 9.3 times of corn, the 3.1 of chicken Again, 3.5 times of beef, 3.7 times of the flesh of fish, 7 times of pork, 4.6 times of eggs, 2.9 times of whole milk powder.Spirulina is rich in dimension Raw plain B1, B2, B3, B6, B12 and vitamin E etc..It can be said that its full price concentrates the various vitamins that human body needs most.Spiral Algae or the natural treasure-house of chlorophyll, how of fine quality amount is, accounts for the 1.1% of frond, is 2~3 times of most of terrestrial plants, is general 10 times of logical vegetables.The type of chlorophyll contained by spirulina is mainly the split-phase of ferroheme ten of chlorophyll a, molecular structure and people Seemingly, it is the direct material of mankind's synthetic hemoglobin, can be rated as " green blood ", and content is up to 7600mg/kg algae powder.Spiral shell Rotation algae contains whole essential amino acids, and lysine content is up to 4%~4.8%, closest compared with animal and plant source food The proposed standard of FAO (Food and Agriculture Organization of the United Nation), and it is especially high to its absorption rate to form balancing human body.Spirulina is rich in human body Required mineral matter, calcium, phosphorus, magnesium, iron, sodium, manganese, zinc, potassium, chlorine etc. accounts for the 9% of frond mineral total amount.Wherein iron content For 20 times of general iron content food;Calcium content is 10 times of milk.And these mineral matters contained by spirulina, belong to cell biological Property in the range of alkali metal, any side effect is not produced to human body cell and histoorgan.
The preparation method of heretofore described spirulina extract is as follows:1 part of spirulina is taken, is cleaned, chopping, adds 9 parts Cocoa aqueous alkali (pH=10), 80 DEG C of Extracting temperature, 2 hours every time extraction time, extract 2 times, extraction is rapid after terminating to be added Enter 2 parts of lemon aqueous solution.
Asparagus
Asparagus scientific name hair handle money bacterium, also known as hair handle small fire mushroom, structure bacterium, plain mushroom, dried mushroom, plain wild rice, jelly bacterium, golden mushroom, intelligence Power mushroom etc., because its stem is elongated, like day lily, therefore claim asparagus, category Agaricales Bai Mo sections pin gold mushroom category, is a kind of bacterium algae lichens Class.Asparagus has very high medicinal dietary function.
It is more complete that asparagus contains essential amino acid composition, and wherein lysine and arginine content are especially abundant, and contain Zinc amount is higher, and to increasing intelligence height especially to children and intelligence development plays the role of good, person " increases intelligence mushroom ";Gold Also contain a kind of material for being Flammulin in pin mushroom, there is resist ability of the enhancing body to cancer cell, often feeding asparagus can also drop Cholesterol, prevent liver diseases and intestines and stomach ulcer, strengthen body healthy tendency, illness prevention and fitness;Asparagus can effectively strengthen body Bioactivity, promote in vivo metabolism, be advantageous to the absorption and utilization of various nutrients in food, it is also big to growing It is helpful, thus have " increasing intelligence mushroom ", the laudatory title of " one stops mushroom ";Asparagus can suppress blood fat rise, reduce cholesterol, prevent and treat heart and brain Vascular diseases;Edible asparagus has resisting fatigue, anti-inflammation, removes heavy metal salts substances, antineoplastic action;Often Edible asparagus, can not only prevent and treat hepatopathy and stomach, enteron aisle ulcer, and also be adapted for hyperpietic, overweight people Eaten with the elderly, it is a kind of hyperkalemia hyponatremia food that this, which is primarily due to it,.
Fresh Ion Absorption of Flammulina Velutipes is containing B family vitamin, vitamin C, carbohydrate, mineral matter, carrotene, several amino acids, plant Thing hemagglutinin, polysaccharide, taurine, eritadenine, tuber of dwarf lilyturf sterol, cell dissolving toxin, dried mushroom cytotoxin etc..
Asparagus is cold in nature, sweet, salty, has the effect of tonifying liver, beneficial stomach, anticancer, cures mainly hepatopathy, gastrointestinal tract inflammation, bursts The illnesss such as ulcer, tumour.Zn content is higher in asparagus, more helpful to prevention prostatic diseases.And asparagus is still Hyperkalemia hyponatremia food, hypertension can be prevented and treated, it is also beneficial to the elderly.Tonifying liver, beneficial stomach, anticancer;It is scorching to cure mainly hepatopathy, intestines and stomach The illnesss such as disease, ulcer, carcinoma, intelligence development.
The preparation method of heretofore described gold needle mushroom extract is as follows:Take 5g golden needle fungus to add 70mL water, be placed in burning 30min is soaked in cup, adjusts pH to 4.0, adds 1% cellulase enzyme liquid, after digesting 2h at 40 DEG C, is dried at 60 DEG C, It crushed 50 mesh sieves.Golden needle fungus and volume fraction are mixed to join in round-bottomed flask for 75% ethanol, carried out at microwave Reason, product centrifugal filtration then will be extracted, will be produced.
Dandelion
Dandelion (Classification system:Taraxacum mongolicum Hand.-Mazz.) composite family, Dandelion is perennial Herbaceous plant.Root is coniform, surface sepia, shrinkage, and limb edge has wave-formed mouth or a pinniform drastic crack sometimes, base portion gradually narrow Cheng Ye Often band reddish violet, scape top aubergine are close by the long pubescence of spider's thread shape white for handle, petiole and master pulse;Capitulum, involucre clock Shape, achene crineous, long pappus white, 4~October of flowering fruit bearing stage.
Dandelion herb is rich in vitamin A, vitamin C and potassium, also containing iron, calcium, vitamin B2, vitamin B1, magnesium, dimension life Plain B6, folic acid and copper.Specific constituent content is mainly moisture, every 60 grams of dandelion herb leaves moisture content 86%, protein 1.6 Gram, 5.3 grams of carbohydrate, heat there are about 108.8 kilojoules.Contain taraxol, taraxacin, courage in dandelion plant A variety of health-nutrition compositions such as alkali, organic acid, synanthrin.Nature and flavor are sweet, slight bitter, tremble with fear.Return liver, stomach.Have diuresis, laxative, removing jaundice subcutaneous ulcer, Cholagogic and other effects.Heat toxin, carbuncle swells, sore, internal carbuncle, red eye, swell pain, damp and hot, jaundice, the puckery pain of dribbling urination, furuncle swelling toxin are controlled, breast Carbuncle, scrofula, toothache, hot eyes, pharyngalgia, lung carbuncle, acute appendicitis, jaundice with damp-heat pathogen, puckery pain of heat gonorrhea.Control acute mastitis, adenolymphitis, scrofula Scrofula, boil poisonous soreness, acute conjunctivitis, cold, fever, acute tonsillitis, acute bronchitis, gastritis, hepatitis, cholecystitis, urine Road feel dye etc..Dandelion is raw-eaten, stir-fries and eats, cooks soup, is the plant of dietotherapeutic.
Dandelion herb is containing taraxasterol, choline, synanthrin, pectin etc..In root containing taraxol, taraxerol, ψ- Portugal's public affairs English sterol, taraxasterol, β-amyrin, stigmasterol, cupreol, choline, organic acid, fructose, sucrose, grape Sugared, glycoside and resin, rubber etc..Leaf containing lutein, violaxanthin, phylloquinone, vitamin C (50~70 milligrams/ 100 grams) and vitamin D (5~9 milligrams/100 grams).Contain Arnica, lutein and flavoxanthin in spending.In pollen containing β- Sitosterol, the β -ol of 5z- beans steroid -7- alkene -3, folic acid and vitamin C.Contain phylloquinone in green calyx.In scape containing cupreol and β-amyrin.The product are containing 7.7~8.8 milligrams of Coumestrol, 1.43 micro- gram gram of riboflavin and carrotene % again.
The extracting method of the achene extract of heretofore described dandelion is:The achene of dandelion is cleaned, cut into slices, is used Wheat bran is fried to there is focal spot, boils 30min with the decocting of 8 times of weight after cooling, decoction liquor is dried in vacuo, produce.
Ginkgo
Ginkgo (scientific name:Ginkgo biloba L.), it is Ginkgoaceae, Ginkgo deciduous tree.Ginkgo is fallen leaves megaphanerophyte, For the diameter of a cross-section of a tree trunk 1.3 meters above the ground up to 4 meters, treelet bark is closely smooth, light grey, the skin taupe of big tree, and irregular lobe is coarse;There are long shoot and growth Slowly away from shape brachyplast.Childhood and prime of life tree crown cone, it is always then wide avette;Branch is near verticillate, and tiltedly (bough of female plant is normal for upper stretching, extension Carry out compared with staminiferous plant).Leaf alternate, it is radial scattered on long shoot, there is elongated petiole, fan-shaped, two sides light green is hairless.In length It is scattered on branch, the fasciation on brachyplast.Its vein form is " two discrimination shape bifurcated veins ".Normal 2 split on long shoot, the wide wedge of base portion Shape.Globe daisy dioecism, unisexuality, it is born in the lepidophyllous armpit on brachyplast top, in fasciation shape.April blooms, and October is ripe, The long stalk of seed tool, it is sagging, often it is ellipse, long inverted ovoid, oval or nearly spheroidal.Kind skin and flesh matter, by white powder, exosper meat Matter, yellow or orange-yellow when ripe.
The extracting method of ginkgo biloba p.e is to take the blade of ginkgo, and blade is cleaned, and it is small that 2 are dried at 70-80 DEG C When, grinds, 80 mesh sieves are crossed, are then boiled with decocting, the weight ratio of water and Folium Ginkgo is 10:1, boiled 3 times with decocting, decocted every time 20min is boiled, the liquid decocted out is collected, vacuum drying obtains powder, produces ginkgo biloba p.e.
Black soya bean
Black soya bean is the black seeds of legume soybean.Black soya bean also known as big shield beans, black soybean etc..Black soya bean has high protein, low The characteristic of heat, crust is black, the inside yellow or green.
Black soya bean likes warm, high temperature resistant, gives birth to 18~30 degree of thermophilic, and seeding method is bred so that particle is big and full, color and luster is black The bright person of dark hair is preferred.
In the present invention, the preparation method of the Semen sojae atricolor extract is as follows:1 portion of soybean is added in 10 parts of methanol, it is indefinite Phase stirs, and extraction filtered out methanol after 72 hours, reclaims methanol,;10 parts of methanol are added, are stirred frequently, are extracted 72 hours, filter Go out methanol, be repeated 3 times, merge methanol extract liquid, rotary evaporation, obtain Semen sojae atricolor extract.
The dried immature fruit of citron orange
The dried immature fruit of citron orange is rutaceae bitter orange Citrus aurantium L. and its variety or sweet orange Citrus Sinensis Osbeck drying young fruit.5~June collected from the fruit fallen, removes impurity, crosscutting from middle part is two halves, is shone Dry or low temperature drying, smaller directly dries or low temperature drying.Hemispherical, minority is spherical, 0.5~2.5cm of diameter.Outer fruit Skin blackish green or dark brown-green, have graininess projection and wrinkle, there is obvious style vestiges or carpopodium trace.Pericarp is slightly grand in section Rise, yellow-white or yellowish-brown, 0.3~1.2cm of thickness, there are 1~2 row grease chamber, pulp sepia in edge.Matter is hard.Gas delicate fragrance, taste It is bitter, slightly sour.
It is bitter in taste, pungent, sour, temperature.Returns spleen, stomach.With the effect of relieving stagnant Qi disperse accumulations, resolving sputum dissipates ruffian.For internal stagnation, ruffian Full distending pain, weight after rush down dysentery, constipation, the phlegm stagnant gas resistance obstruction of qi in the chest, accumulation of pathogens in chest;Gastroptosis, prolapse of the anus, the prolapse of uterus.
Bitter orange fruit skin glucoside containing inspection (hesperidin), neohesperidin (neohesperidin), outermost layer of skin glucoside (naringin), synephrine (synephrine), N- methyltyramine (N-methyltyramine).Contain shaddock ped during fruit prematurity Glucoside, rhoifolin (rhoifolin), lonicerin (lonicerin), neohesperidin, in fruit maturation, neohesperidin disappears. Pericarp also (nobiletin) containing Nobiletin is 5,6,7,8,3 ', 4 '-hexa methoxy flavones (5,6,7,8,3 ', 4 ' Hexamethoxy flavone), hesperidine, 5,6,7,8,4 '-pentamethoxyl flavones (5,6,7,8,4 '-pentamethoxy Flavone it is) tangerine produced in fujian province plain (tangeritin), 5,7,4 '-trimethoxy flavone (5,7,4 '-trimethoxy flavone), 5,6,7,3 ', 4 '-pentamethoxyl flavones are senensetin (sinensitin), 5,7,8,4 '-tetramethoxy flavones (5,7,8,4 ' - tetramethoxy flavone) and 5,7,8,4 '-pentamethoxyl flavones.Seed (limonoids) containing limonin:Preferably Prosperous orange bitter principle (ichangin), acetic acid is gone to make a noise Milin (deacetyl nomilin), limonin (limonin), Milin of making a noise (nomilin), obakunone (obacunone), deacetylnomilin acid (deacetylnomilinic acid), different lemon Buddhist nun acid (isolimonic acid), make a noise mesityl oxide (nomilinic acid) and their 17- β-D-Glucose glucoside, also hydroxyl containing 19- Deacetylnomilin acid -17- β-D-Glucose glucoside (19-hydroxydeacetylnomilinic acid-17- β-D- glucoside)。
Sweet orange fruit element containing the outermost layer of skin-Diosmin (naringenin-7-ruti-noside) is narirutin (narirutin), isosakuranetin-Diosmin (isosaku-ranetin-7-rutinoside), mountain balsam Chinese holly pattern glucoside (eriocitrin), the ' of naringenin-4-glycoside-Diosmin (naringenin-4 '-glucoside-7- Rutinoside), synephrine, N- methyltyramines.Pericarp is containing hesperidine, naringin, mandarin orange category glucoside (citrusin) A, B, C, pine and cypress Glucoside (coniferin), Syringin (syringin), dehydrodiconiferylalcohol -4- β-D-Glucose glucoside (dehydrodiconiferyl Alcohol-4- β-D-glucoside), 2 "-O-- β-xylosylvitexin (2 "-O- β-xylosylvitexin), 3- hydroxyls- 5,6,7,8,3 ', 4 '--3 β of hexa methoxy flavones-glycoside (3-hydroxy-5,6,7,8,3 ', 4 ' - Hexamethoxyflavone-3 β-glucoside) be Nobiletin -3-O- β-glycoside (nobiletin-3-O- β - Glucoside), 3,8- glucosulfones base apiolin (3,8-di-C-glucosylapigenin), 3,8- glucosulfone basic notes Leaf lignin (3,8-di-C-glucosyldiosmetin), the anti-β of carveol-6-glucopyanoside (trans-carveol-6 β-glucopyranoside), a- terpinol -8- β-D- glucopyanosides (a-terpineol-8- β-D- Glucopyranoside), -9 β of 9- hydroxyls linalool-glucopyanoside (9-hydroxylinalool-9- β - Glucopyranoside), vomiofliol -9-O-D glucopyanosides (vomifoliol-9-O- β-D- Glucopyranoside), the glucoside such as narirutin.It is also plain containing tangerine produced in fujian province, Nobiletin, 5,7,4 '-trimethoxy flavone, 5, 7,3 ', 4 '-tetramethoxy flavones and isosenensetin, mandarin orange category cyclic peptide (citrusin) II, III, IV.
Paulownia tangerine fruit contains hesperidine, naringin, neohesperidin, Poncirin (poncirin), palmitic acid (palmitic Acid), stearic acid (stearoc acid), oleic acid (oleic acid), linoleic acid (linoleic acid), leukotrienes (linolenic acid), synephrine, N- methyltyramines.Immature fruit tangerine containing structure coumarin (poncimarin), different trifoliate orange Coumarin (iso-poncimarin), 7- Geraniol base coumarins (7-geranyloxycoumarin) are auraptene (aurapten), 6- methoxyl groups auraptene (6-methyoxyaurapten), in bergapten (bergapten), Imperatoria ostruthium Ester (imperatorin).Seed contains different anise coumarin (isopimpinellin), and bolt wing sedanonic acid lactone (prangenin) is i.e. solely Lactone (heraclenin) living, bolt wing sedanonic acid lactone hydrate (prangeninhydrate), bergapten, imperatorin, Portugal Grape lactone, 6- methoxyl groups auraptene and limonin, go acetic acid to make a noise Milin, Ichang papeda bitter principle, go acetic acid to make a noise mesityl oxide, different lemon The limonoids such as lemon Buddhist nun's acid.
Pericarp (0.469%) containing volatile oil, its composition have a- firpenes (a-pinene), nopinene, laurene (myrcene), limonene (limonene), lauro lene (camphene), γ-terpinene (γ-terpinene), to P-cymene And cloves alkene (caryophyllene) (p-cymene).
The extracting method of Bitter Orang P.E is to clean the dried immature fruit of citron orange, section, is fried with wheat bran to there is focal spot, with 8 times after cooling 30min is boiled in the decocting of weight, and decoction liquor is dried in vacuo, and is produced.
Pachyman
Poria cocos, Aphyllophorales Poria cocos category mushroom, also known as beautiful spirit, Fu spirits, Wan Linggui, Fu Tu.It is to intend shelf fungus section fungi Fu The dry sclerotia of Siberian cocklebur, is often colonized on pine roots, spherical shaped like sweet potato, crust light brown or dark brown, internal pink colour or white Color.Sweet taste.It is its slightly sweet flavor, mild-natured, have the effect of eliminating dampness and diuresis, beneficial spleen and stomach, antitoxic heart-soothing and sedative, for treat difficult urination, The disease such as oedema turgor, seminal emission, stranguria with turbid discharge, palpitation with fear, forgetful.
The preparation method of heretofore described pachyman:Each place of production Indian Bread 0.5g (after drying) is weighed, puts Soxhlet 4h is respectively extracted with petroleum ether and 80% ethanol in extractor, filter residue is put in 50ml volumetric flasks, adds 1mol/L NaOH solution To scale, steeped overnight, filtering, filtrate is taken, be dried in vacuo, produce.
As one embodiment of the present invention, the preparing raw material of the second layer includes beeswax, the 1-8 of 1-10 parts by weight The spirulina extract of parts by weight, the extract of the asparagus of 5-15 parts by weight, 5-8 parts by weight dandelion achene extraction Thing, the ginkgo biloba p.e of 2-5 parts by weight, the Semen sojae atricolor extract of 0.1-1 parts by weight, 0.1-5 parts by weight Bitter Orang P.E, The pachyman of 10-15 parts by weight.
As one embodiment of the present invention, the preparing raw material of the second layer includes the beeswax of 7 parts by weight, 3 weight Part spirulina extract, the extracts of asparagus of 7 parts by weight, the achene extract of dandelion of 6 parts by weight, 4 parts by weight Ginkgo biloba p.e, the Semen sojae atricolor extract of 0.7 parts by weight, the Bitter Orang P.E of 0.8 parts by weight, the Poria cocos of 12 parts by weight gather Sugar.
As one embodiment of the present invention, the preparing raw material also beeswax comprising 1 parts by weight of the second layer is modified Hyperbranched chitosan.
The preparation method of the beeswax modified ultra-branching chitosan is as follows:
1st, 50g chitosans are dissolved in 1000mL5% aqueous acetic acid and are cooled to 4 DEG C.By 5g NaNO2It is dissolved in Above-mentioned chitosan solution is added dropwise to after 50mL water, is reacted 9 hours at 0 DEG C, the dense NaOH aqueous solution is added and is all separated out to precipitation, Filtering, and it is multiple with methanol and water washing, it is dried in vacuo the obtained low-molecular weight chitoglycan with aldehyde radical end group.Low molecule amount Product (Mw=2300, Mw/Mn=1.5, GPC/ light scattering method) of the chitosan after methanol extraction is classified is dissolved in 0.1M acetic acid (2mg/mL), be added dropwise after stirring 1 hour at 10 DEG C the 0.1M NaOH aqueous solution to pH be 5.5.Phase is added after continuing stirring 2 hours When in the NaCNBH of 1.0 times of aldehyde radical molal quantity3, same amount of NaCNBH is added after reacting 24 hours at 10 DEG C3, continue to react 72 hours.Period control ph is not higher than 6.5.Reaction solution is filtered with sand core funnel, filtrate with 3 times of methanol extractions, and with methanol, Water repeatedly washs.It is dried in vacuo at 40 DEG C of product after washing, it is standby obtains hyperbranched chitosan.
2nd, take the hyperbranched chitosans of 100g to be scattered in 200ml 20% sodium hydroxide solution, be put into refrigerator and freezed At night, added after defrosting equipped with backflow, the three neck reaction bulbs stirred, add 200ml isopropanols, stir 30 minutes at room temperature Afterwards, 5ml is added, the catalyst tetramethyl ammonium hydroxide solution of mass fraction 25%, stirs, is slowly dropped into expoxy propane 400ml, 4h is reacted in 60 DEG C, after reaction stops, with 1:1 hydrochloric acid is neutralized to pH=7, and product is filtered with acetone precipitation, uses second Alcohol solution (volume ratio 8:2) repeatedly after washing, then washed with absolute ethyl alcohol, dry modified ultra-branching chitosan.
3rd, 2g monoxones are weighed, are dissolved in 100ml H2In O, 1g beeswaxs are weighed, are dissolved in the NaOH of 10ml mass fractions 25% Solution, the chloroacetic acid solution prepared is instilled dropwise, reacts 9h at room temperature.PH to 9 is adjusted with watery hydrochloric acid, then adds methanol, is placed 12h, filtering, is dissolved in water, then adds methanol, and filtering, products therefrom is washed repeatedly with ethanol water, untill without chlorine, is dried, Obtain modified beeswax.
4th, modified ultra-branching chitosan and modified beeswax are dissolved in 50mL water, 5g EDC is dissolved in for coupling agent In 200mL water, at 3 DEG C, it is slowly dropped into solution, reacts 24h at 5 DEG C, dialysed 4 days and changed 12 times in distilled water with bag filter Water, the liquid obtained after dialysis is separated out with acetone, after repeatedly being washed with absolute ethyl alcohol, obtains beeswax modified ultra-branching chitosan.
The weight ratio of the beeswax and hyperbranched chitosan is 1:2.
Third layer
The preparing raw material of the third layer includes hyaluronic acid, the extract of pseudo-ginseng, the extract of betel nut, grape pip Extract, lavender extract, Semen Myristicae extract.
Hyaluronic acid
Hyaluronic acid is a kind of acid mucopolysaccharide, also known as uronic acid, hyaluronic acid, and basic structure is by two dissacharide units The large-scale polysaccharide of D- glucuronic acids and N-acetyl-glucosamine composition.It is different from other mucopolysaccharides, its not sulfur-bearing.
In the present invention, the hyaluronic acid refers to the hyaluronic acid of chitin modified mistake, and specific preparation method is as follows:
1) preparation of hydroxyethyl chitosan hydrogel:Hydroxyethyl chitosan and GMA are dissolved in water It is middle to form the solution that mass concentration is 0.5%~4%, it is subsequently added into the water-soluble of hydroxyethyl chitosan quality 0.05%~0.5% Property light trigger, using ultraviolet light irradiation 0.5 minute~8 minutes after magnetic agitation is well mixed, the hydroxyl that photochemical polymerization is formed Ethyl chitosan hydrogel is freeze-dried, standby;
2) preparation of hyaluronic acid gel:The hydroxyethyl chitosan hydrogel that step 1) obtains is freezed into sample to be impregnated in In the aqueous solution of bright matter acid and water-soluble light trigger, to swelling equilibrium, implement photochemical polymerization 0.5 minute~10 minutes, obtain To hydroxyethyl chitosan/hyaluronic acid gel;Wherein, hydroxyethyl chitosan hydrogel freezes the mass ratio of sample and hyaluronic acid For 4:1~1:2, the mass concentration of hyaluronic acid is 0.5%~4%, and the quality of water-soluble light trigger is hyaluronic acid 0.05%~0.5%.
GMA is also added with the hyaluronic acid aqueous solution.
The GMA is the 50% of hydroxyethyl chitosan (or hyaluronic acid) quality.
Pseudo-ginseng
Not only pattern is gorgeous has very high ornamental value for pseudo-ginseng, and some species, which can also be used as medicine, cures the disease.Such as:The green suede of full edge Wormwood artemisia (Lijing also known as " yellow hibiscus "), Nepal's pseudo-ginseng (Lu is advised also known as " out-of-the-way mountain area bamboo shoot ") all herbal medicine, have clearing heat and detoxicating work( Effect, clearing and antitussive;Sour regurgitation in stomach is controlled in picking leaves before spending;Flower is brought down a fever emetic, anti-inflammatory, also controls injury and bone fracture.Total shape pseudo-ginseng, Xiong Dimin Race is also known as " red hair American ginseng ", " snow ginseng ", and root is used as medicine, and controls the diseases such as the deficiency of vital energy, edema, asthma, has the function that tonifying middle-Jiao and Qi.
In the present invention, the extracting method of the pseudo-ginseng is as follows:Take Nepal pseudo-ginseng 50g, add 8L deionized waters and (volume ratio of water and ethanol is 5 to ethanol:1) put into afterwards in boiler, after being heated to 75 DEG C, use indirect steam heating instead to boiling Rise, condensate liquid enters oil water separator and carries out water-oil separating, collects oil content;Anhydrous sodium sulfate drying filtering is added to carry out at dehydration Reason, activated carbon is added, and stirred 48 hours at normal temperatures, be filtrated to get Herba meconopsis integrifoliae extract.
Betel nut
Betel nut (scientific name:Areca catechu L.) Palmae Areca aiphyllium, stem is upright, arbor shape, more than high 10 Rice, reaches as high as 30 meters, there is an obvious annular leaf trace, monoecism, inflorescence multi-branched, ovary Long Circle, fruit Long Circle or Ovoid, seed is avette, the flowering fruit bearing stage 3-4 months.
Betel nut contains the nutrient and benefit materials of a variety of needed by human body, and the main component of [7] raw areca nut is 31.1% phenols, 18.7% polysaccharide, 14.0% fat, 10.8% crude fibre, 9.9% moisture, 3.0% ash content With 0.5% alkaloid.Betel nut also contains 20 various trace elements, wherein 11 kinds are the essential trace elements of the human body.Betel nut kind Son 0.3%-0.6% containing total alkaloid, predominantly arecaline, and contain a small amount of arecaidine, guvacoline, different demethyl Arecaidine, arecolidine and homarecoline etc., exist with tannic acid set.Also tannin, fat, mannitol, galactolipin, sugarcane Sugar, cachou extract, the caffein of table two, leucocyanidin, areca red, the dimer of saponin(e and a variety of former Cyanidins, tripolymer, Tetramer etc..The composition of institute's fatty acids is:Laurate 19.5%, myristic acid 46.2%, the stearic acid of palmitic acid 12.7% 1.6%th, oleic acid 6.2%, linoleic acid 5.4%, lauric acid 0.3%, tetradecenoic acid 7.2%, amino acid is contained again.Wherein dried meat ammonia Acid accounts for more than 15%.
In Areca contain a variety of needed by human body nutrient and benefit materials, such as fat, betel oil, alkaloid, The compositions such as catechin, choline.Betel nut has unique imperial miasma function, is the medicine fruit that ancient Chinese medicine doctor is cured the disease, and has again " washing miasma pellet " Alias.Because the disease of communicable subtropical diseases, typically all with diet is irregular, stagnation of the circulation of vital energy product has pass, and betel nut can descend gas, help digestion, eliminating the phlegm.
In the present invention, the extracting method of the betel nut is as follows:1 portion of betel nut is taken, is cleaned, is ground to 25 mesh, adds 5 parts of volumes Fraction is 70% ethanol, is placed in 75 DEG C of water-baths and extracts 2.5h, and decompression is filtered, and extract is obtained after freeze-drying.
Grape pip
Grape pip contains the effect of abundant several amino acids, vitamin and mineral matter etc. are with health care, beauty.
Contain polyphenols (GPS) in grape pip, mainly there is catechin and OPC class.Catechin compounds Single aggressiveness main in grape pip including catechin, epicatechin and its gallate, and OPC oligomer and The component unit of polymer.Containing abundant grease in grape pip, the 12%~15% of its weight is accounted for, is contained in oil substantial amounts of Unrighted acid, wherein linoleic content is between 58%~78%.Also contain a small amount of volatile ingredient in grape pip, These materials belong to alcohol, phenol, terpene substances mostly, all have higher bioactivity.Except containing above-mentioned a variety of in grape pip Outside material, also containing crude protein, amino acid and vitamin A, E, D, K, P and various trace elements, as calcium, zinc, iron, magnesium, copper, Potassium, sodium, manganese, cobalt etc..
The extracting method of heretofore described grape pip is as follows:1 part of grape pip is taken, cleans, 50 mesh is crushed to, through petroleum ether Degreasing and after drying, adds 20mL pH 4.0 buffer solution, regulation cellulase solution vigor to 100U/mg, 45 DEG C of enzymolysis Be brought rapidly up after 1.0h to 90 DEG C of fully inactivations, 1 500r/min centrifuge and preserve supernatant, add 70% ethanol it is molten Liquid is filtered after 50 DEG C of water-bath 30min, 70 DEG C be evaporated under reduced pressure be concentrated into no drop ooze, concentrate it is freeze-dried The extract of grape pip.
Lavender
Lavender is herbaceous plant.Rhizome is crawled, and stem is upright, has striped;Take turns umbrella inflorescence;Ovary is hairless.Peppermint is dispelled all Heat, dissipate wind sweating, refresh oneself, throat.Cure the wound wind headache, aphonia, discomfort in the throat, small hidden pain of wind infantile convulsion etc..The flower of lavender The oil yield of sequence and leaf is 0.23-1.1%, and oily composition master is pulegol, menthol and menthones.
The extracting method of heretofore described lavender extract is:Lavender is taken, is cleaned, segment, with the water of 8 times of weight 1h is decocted, decoction liquor is dried in vacuo, produced.
Nutmeg
Nutmeg is myristicaceae plant nutmeg.Remove aril maturation dry benevolence, also known as character used in proper names and in rendering some foreign names arrest Le, cardamom, Semen myristicae etc..Nutmeg is warm-natured, acrid flavour, the promoting the circulation of qi of tool middle benefit gas, the work(of relieving diarrhea with astringents, swollen for deficiency-cold in spleen and stomach, endless diarrhea, gastral cavity abdomen Bitterly, deficiency of food is vomitted.Modern study shows that nutmeg has anti-inflammatory, antibacterial, antitumor, antidiarrheal and other effects.In nutmeg mainly into It is divided into volatile oil, fat oil, Phenylpropanoid Glycosides and lignanoid etc..
The myristic fatty oily 25%-46% of benevolence, volatile oil 8%-15%, includes Toxic:Myristicin (myristicin) about 4%.Volatile oil master (sabinene) containing sabinene, α-and nopinene (pinene), pine tar -4- enols (terpinen-4ol), γ-terpinene (γ-terpinene), limonene (limonene), bornylene (bornylene), β- Phellandrene (β-phellandrene), to P-cymene (p-cymene), α-terpinolene (α-terpinolene), α-pine tar Alcohol (α-terpineol), δ-cadinene (δ-cadinene), myristicin, elemicine (elemicin), also containing lauro lene (camphene), laurene (myrcene), α-phellandrene (α-phellandrene), 3,4- dimethyl styrenes (3,4- Dimethylstyrene), linalool (linalool), cis piperitol (cis-pinperitol), trans piperitol (trans-piperitol), borneol (borneol), cis cloves alkene (cis-caryophyllene), citronellol (citronellol), to P-cymene-α -ol (p-cymen- α-ol), safrole (safrole), nerol (nerol), β- Clear eggplant oil alkene (β-cubebene), acetic acid Geraniol ester (geranylacetate), Eugenol (eugenol), methyl fourth Sesame oil phenol (methyleugenol), isoelemicine (isoelemicin).Master contains myristin in fat oil And a small amount of olein (triolein) etc. (trimyristin).Seed also contains lignanoid:1- (3,4- (methylenedioxy)s Base phenyl) -2- (4- pi-allyl -2,6- dimethoxys phenoxy group) -1- propyl alcohol (1- (3,4-methylenedioxyphenyl) - 2- (4-allyl-2,6-dimethoxyphenoxy)-propan-1-ol), 1- (3- methoxyl group -4- acetoxyl groups phenyl) -2- (4 allyl bases, 6- dimethoxy-benzenes epoxide) -1- propanol acetates (1- (3-methoxy-4-acetyloxyphenyl) -2- (4-allyl-2, dimethoxyphenoxy) propan-1-ol acetate), 1- (3,4- methylene dioxy phenyl group) -2- (4- Pi-allyl -2,6- dimethoxys phenoxy group) -1- propanol acetates (1- (3,4-methylenedioxyphenyl) -2- (4- Allyl-2,6-dimethoxyphenoxy) propan-1-ol acetate), 1- (3,4,5- trimethoxyphenyl) -2- (4- Pi-allyl -2,6- dimethoxys phenoxy group) propane (1- (3,4,5-trimethoxyphenyl) -2- (4-allyl-2,6- Dimethoxyphenoxy) propane), the isoeugenol of dehydrogenation two (dehydrodiisoeugenol) is licarin A (licarin A), the isoeugenol (5'-methoxydehydrodiisoeugenol) of 5'- methoxyl groups dehydrogenation two, 2- (3,4- Methylenedioxyphenyl) -2,3- dihydro -7- methoxyl group -3- methyl -5- (acrylic) benzofurans { 2- (3,4- methylenedioxyphenyl)-2,3-dihydro-7-methoxy-3-methyl-5〔1-(E)-propenyl〕 Benzofuran }, i.e. Licarin B (licarin B), 2- (3,4- methylene-dioxy -5- methoxyphenyls) -2,3- dihydros -7- Methoxyl group -3- methyl -5-) acrylic) benzofuran 2- (3,4-methylenedioxy-5-methoxyphenyl) -2, 3-dihydro-7-methoxy-3-methyl-5- (1- (E)-propenyl) benzofuran }, 1- (3,4- dimethoxy benzenes Base) -2- (4- pi-allyl -2,6- dimethoxys phenoxy group) -1- propyl alcohol (1- (3,4-dimethoxyphenyl) -2- (4- Allyl-2,6-dimethoxyphenoxy) propan-1-ol), 1- (3,4- Dimethoxyphenyl) -2- (4- pi-allyls -2,6- Dimethoxy phenoxy group) -1- propyl alcohol (1- (3-methoxy-4-hydroxyphenyl) -2- (4-allyl-2,6- Dimethoxyphenoxy) propan-1-ol) etc..The de- benevolence that refers to contains myristic acid (myristic acid) and triterpenoid saponin, Glucoside member is oleanolic acid (oleanolic acid).
Heretofore described myristic extracting method is as follows:Take cutability cardamom, first with proper amount of clear water soak 4 hours, so After take out and slightly dry in the air, when surface is without too many water mark, with wheat bran with putting in hot pot, heated with slow fire, to nutmeg surface in pale brown Color, when wheat bran is in coke yellow, takes out, weed out wheat bran, cool.Then the nutmeg after processing is taken, with volume fraction 75% Ethanol soaks 10h, then takes out and dries in the shade, grinds, crosses 80 mesh sieves, is boiled with decocting, and water is 8 with myristic weight ratio:1, use Decocting is boiled 4 times, and the aqueous solution decocted for the first time discards, and takes the aqueous solution of second to the 4th time, is merged, and vacuum drying, is produced.
As one embodiment of the present invention, hyaluronic acid of the preparing raw material comprising 1-5 parts by weight of the third layer, The extract of the pseudo-ginseng of 5-10 parts by weight, the extract of the betel nut of 1-4 parts by weight, 2-8 parts by weight grape pip extraction Thing, the lavender extract of 0.5-5 parts by weight, 0.8-1.5 Semen Myristicae extracts.
As one embodiment of the present invention, calculate in parts by weight, the preparing raw material of the third layer includes 3 weight Part hyaluronic acid, the extracts of pseudo-ginseng of 7 parts by weight, the extracts of betel nut of 2 parts by weight, the grape pip of 6 parts by weight Extract, the lavender extract of 1.3 parts by weight, 0.9 Semen Myristicae extract.
4th layer
Described 4th layer of preparing raw material includes locust bean gum, grape skin extract, theobromine, false Soviet Union's extract, bigarabe Leaf essential oil.
Locust bean gum
Locust bean gum also known as locust bean gum, foreign bean gum, carob, it is a kind of neutral energy storage polysaccharide.It is by locust tree plant carob Seed endosperm part, after roasting, with hot-water extraction, remove concentration after insoluble matter, dry, crush and form.Character is white Odorless or with micro- smelly to yellow-white powder, particle or flat piece, molecular weight is about 300,000 dalton.Be one kind with β-D- (1 → 4) D-MANNOSE of glucosides key connection is main chain, and a α-D- galactopyranose is connected on 1 → 6 of D-MANNOSE base, And the ratio of galactolipin and mannose is 1:4 galactomannans.
Grape skin extract
Grape Skin is exactly the epidermis of grape, and the anthocyanidin contained in Grape Skin is more than pulp, have protection tiny blood vessels, The effect of anti-inflammatory.
The extracting method of heretofore described Grape Skin is as follows:Fresh Grape Skin is rinsed well with running water, ground Crushed in alms bowl, first add a small amount of pure water, be lightly ground to exquisiteness, then be separately added into 20ml pure water and extract 3~5 (leachings every time Steep half an hour), merge leaching liquor, and be heated to obtain aubergine leaching liquor several times.
Vacation Soviet Union
Vacation Soviet Union and schizonepeta are same nouns, can merge, be Labiatae, Nepeta perennial plant.Acrid flavour;Slight bitter;Slightly warm in nature, Enter lung, Liver Channel.Containing volatile oil 1.8%, principal component is D-menthone, racemization book lotus ketone, a small amount of d-limonen in oil.
The extracting method of heretofore described false Soviet Union's extract is as follows:1 part of false Chinese medicine of reviving is milled into granularity up to 60 mesh.It will grind Thin false Soviet Union is soaked 24 hours with 2 part 80% of ethanol.Extracted 2 hours at 90-100 DEG C, refrigerated centrifuge, obtain and once extract Liquid, ethanol in proper amount extraction is added, obtains secondary leaching liquor.Merge the supernatant extracted twice.
Petitgrain
Bigarabe leaf essential oil is one of three kinds of essential oils that orange tree extracts, and two kinds are the flores aurantii essences extracted by flower in addition Oil, and the orange essential oil extracted by fruit.
Included in chemical composition:Alcohols -- Geraniol, linalool, nerol, terpinol;Aldehydes -- citral;Ester Class -- Mang ox ester, coriander grease;Terpene cigarette -- lauro lene, limonene.
Heretofore described bigarabe juice essential oil is bought from Shanghai Arabica bio tech ltd.
As one embodiment of the present invention, calculate in parts by weight, described 4th layer of preparing raw material includes 1-5 weights The amount locust bean gum of part, the grape skin extract of 6-8 parts by weight, the theobromine of 1-15 parts by weight, the false Soviet Union of 10-15 parts by weight carry Take thing, the bigarabe leaf essential oil of 7-9 parts by weight.
As one embodiment of the present invention, calculate in parts by weight, described 4th layer of preparing raw material includes 3 weight The locust bean gum of part, the grape skin extract of 7 parts by weight, the theobromine of 7 parts by weight, false Soviet Union's extract of 12 parts by weight, 8 weight The bigarabe leaf essential oil of part.
Layer 5
The preparing raw material of the layer 5 includes aeroge, Lavender, hill gooseberry's essential oil, milkwort extract;
Lavender
Lavender is to be refined to form by lavender, can be with clearing heat and detoxicating, cleaning skin, control oil, freckle removing and whitening, The tender skin of anti-wrinkle, eye haustra -dsipelling livid ring around eye, it may additionally facilitate the skin-protecting functions such as damaged tissues regeneration recovery.It can purify, pacify soul, Mitigate angry and used-up sensation, making one can be with even-tempered and good-humoured in face of life.
The Lavender is bought from A Fu essential oils limited company.
Hill gooseberry's essential oil
Hill gooseberry also known as myrtle (Myrtus communis), belong to Myrtaceae, and myrtle is grown in the torrid zone more America and Australia, myrtle are rare primary and European kinds.
Heretofore described hill gooseberry's essential oil purchase carries commerce and trade Co., Ltd from Beijing Ya Keye.
Milkwort extract
Polygala is milk wort polygala Polygala tenuifolia Willd. or ovum leaf polygala Polygala Sibirica L. dry root.Spring, the excavation of season in autumn two, remove fibrous root and silt, dry.
In cylinder, slightly curved song, long 3~15cm, 0.3~0.8cm of diameter.Surface lark to taupe brown, have it is closeer simultaneously Horizontal wrinkle, vertical wrinkle and the crackle got deeply stuck in, the horizontal wrinkle of old root is closeer more to be got deeply stuck in, slightly in nodositas.Matter is hard and crisp, frangibility, Section skin zone brown color, woody part yellow-white, skin zone easily peel off with woody part.Gas is micro-, and bitter, micro-pungent, what is chewed has throat hurt feeling.
Nature and flavor:It is bitter, pungent, warm.The thoughts of returning home, kidney, lung channel.With tranquilize the mind and promote the intelligence, the effect of eliminating phlegm and diminishing swelling.Draw for breakdown of the normal physiological coordination between the heart and the kidney The insomnia and dreamful sleep risen, forgetful palpitation with fear is wandering, and expectoration is not well, sore swollen toxin, mastosis.
Payta contains saponin, and 2 sapogenins are obtained after hydrolysis:Presenegenin (tenuigenin) A and B, also isolate thin Leaf polygala element (tenuifolin).It is near to get 7 triterpenoid saponins again:Polygalin (onjisaponin) A, B, C, D, E, F, G, Also get 5 phenolic glycosides:Polygala glucoside (tenuifoliside) A, B, C, D, and β-D- (3-O- mustard seeds acyl)-furans fruit Glycosyl-a-D- (6-O- mustard seeds acyl)-glucopyanoside [β-D- (3-O-sinapoyl)-fructofuranosyl-2-D- (6-O-sinapoyl)-glucopyranoside].Separately get 6 oligosaccharides:Polygala widow essence (tenuifoliose) A, B, C, D, E、F.Compound containing xanthone again:6- hydroxyls -1,2, and 3,7- tetramethoxy xanthones (6-hydroxy-1,2,3,7- Tetramethoxyxanthone), 1,2,3,7- tetramethoxy xanthones (1,2,3,7-tetramethoxyxanthone), 1,2,3,6,7- five Shen epoxide xanthone (1,2,3,6,7-pentamethoxyxanthone), 1,7- dihydroxy xanthone (1, 7-dihydroxyxanthone), 1,7- dimethoxys xanthone (1,7-dimethoxyxanthone), 1,7- dihydroxy -2, 3- dimethoxys xanthone (1,7-dihydroxy-2,3-dimethoxyxanthone), 1- hydroxyl -3,7- dimethoxy xanthenes Ketone (1-hydroxy-3,7-dimethoxyxanthone), 1,7- dimethoxy -2,3- methylene-dioxy xanthone (1,7- Dimethoxy-2,3-methylenedioxy-xanthone), polygala xanthone (onjixanthone) I and II, 1,6- dihydroxy Base -3,7- dimethoxy xanthone (1,6-dihydroxy-3,7-dimethoxyxanthone), 1,7- dihydroxy -3- methoxies Base xanthone (1,7-dihydroxy-3-methoxyxanthone), 1,6 dihydroxy -3,5,7- trimethoxies xanthone (1, 6-dihydroxy-3,5,7-trimethoxyxanthone), 1- hydroxyls -3,6,7- trimethoxy xanthones (1-hy-droxy- 3,6,7-trimethoxyxanthone), 1,3,6- trihydroxy -2,7- dimethoxy xanthones (1,3,6-trihydroxy- 2,7-dimethoxyxanthone).Also contain 3,4,5- trimethoxy cinnamic acids (3,4,5-trimethoxycinnamio Acid), polygalytol (polygalitol), N- acetate gucosamine (N-acetylglucosamine), tenuidine (tenuidine)。
The extracting method of milkwort extract is to clean polygala, segment, and 3h is boiled with the decocting of 5 times of weight, and decoction liquor is true Sky is dried, and is produced.
The aeroge is to be prepared using cellulose, plant extract mixtures as preparing raw material;The plant extract Thing mixture is Lombardy poplar tree extract, needle juniper extract, Acer palmatum extract, the mixture of licorice.
Lombardy poplar tree extract
Lombardy poplar alias lombardy poplar, white poplar;Medicine elementary source:For the bark or leaf of Salicaceous Plants lombardy poplar.Nature and flavor: Hardship, it is cold in nature;Major function dispelling wind and eliminating dampness;Removing pattogenic heat from the blood and toxic material from the body.Main arthralgia pain due to rheumatism;Tinea pedis swells;Hepatitis;Dysentery;Burn and scald;Mange is bald Sore.
Cortex contains rhamnetin (rhamnetin) and rhamnocitrin (rhamnocitrin).Bud dimethyl alkene containing 3,3- Propyl group-trans- caffeic acid ester (3,3-dime-thylallyl-trans-caffeate), 3,3- dimethyl-allyls-cis- coffee Acid esters (3,3-dimethylallyl-cis-caffeate), 3- iso-amylene-cis- caffeic acid ester (isopent-3-enyl- Cis-caffeate), 3- iso-amylene-trans- caffeic acid ester (isopent-3-enyl-trans-caffeate).
The extracting method of heretofore described Lombardy poplar tree extract is:Lombardy poplar tree bark is taken, by Lombardy poplar tree bark Clean, grinds, cross 80 mesh sieves, then boiled with decocting, the weight ratio of water and Lombardy poplar tree is 10:1, boil 3 times with decocting, every time 20min is decocted, the liquid decocted out is collected, vacuum drying obtains powder, produces Lombardy poplar tree extract.
Needle juniper extract
Needle juniper cone volatile oil containing 1%-2%, wherein be made up of 60 multiple compounds, including laurene, sabinene, α-with Nopinene and cineol, also containing tannin, two terpenes, carbohydrate, resin and vitamin C.Active ingredient is the isomery of rosin acid Body, there is good inhibiting effect to staphylococcus aureus.
In the present invention, the preparation method of the needle juniper extract is as follows:The branches and leaves of needle juniper are taken, the branches and leaves of 1 portion of needle juniper are put Dry 2~3 hours at a temperature of 70~80 DEG C in drying box, mill while hot immediately, granularity of milling is up to 60 mesh.Will be fine ground The branches and leaves powder of needle juniper is soaked 24 hours with 2 part 80% of ethanol, takes insoluble matter.It is water-soluble that insoluble matter is added to 10 parts of theobromines Liquid (pH=10), extracted 2 hours at 90-100 DEG C, refrigerated centrifuge, obtain a leaching liquor, add appropriate flooding, obtain two Secondary leaching liquor.Merge the supernatant extracted twice, stand, centrifuge taking precipitate.
Acer palmatum
Alias:Five jiaos of crow maples of leaflet, A Douxian, willow leaf maple;Medicine elementary source is branch, the leaf of Aceraceae plant Acer palmatum;Summer Ji Caishou branches and leaves, are dried, segment;Nature and flavor:Pungent, slight bitter, put down;Effect:Promoting qi circulation and relieving pain, removing toxicity for eliminating carbuncles, qi-stagnating abdominalgia, carbuncle swells Carbuncle on the back;Chemical composition:Leaf contains Du Jingsu, saponarin, orientin, matched moulds orientin, cyanidin monoglycoside, delphinidin list Glucoside, peonidin monose glucoside.
The extracting method of Acer palmatum:Acer palmatum is cleaned, 10h is soaked with the ethanol of volume fraction 75%, then takes out the moon It is dry, grinds, 80 mesh sieves are crossed, are boiled with decocting, the weight ratio of water and dried orange peel is 8:1, boiled 4 times with decocting, the water decocted for the first time Solution discards, and takes the aqueous solution of second to the 4th time, merges, and vacuum drying, produces.
Radix glycyrrhizae
Radix glycyrrhizae is that this product is glycyrrhizic legume Glycyrrhiza uralensis Fisch., swollen fruit Radix Glycyrrhiza inflata Bat. or glycyrrhiza glabra Glycyrrhiza glabra L. dry root.Spring, season in autumn two adopt Dig, remove fibrous root, dry.Root is in cylinder, long 25~100cm, 0.6~3.5cm of diameter.Crust is elastic to differ.Surface is reddish brown Color or taupe brown, have significant vertical wrinkle, rill, hole skin and sparse radicula trace.Matter is solid, and section shows slightly fibroid, yellowish-white Color, mealiness, cambium ring is obvious, and ray irradiation shape, some has crack.For rhizome in cylinder, there is bud scar on surface, has in the middle part of section Marrow.Gas is micro-, sweet and special.It is distributed in the ground such as northeast, North China, Shaanxi, Gansu, Qinghai, Xinjiang, Shandong.With invigorating the spleen and benefiting qi, It is clearing heat and detoxicating, expelling phlegm and arresting coughing, relieving spasm to stop pain, the effect of coordinating the drug actions of a prescription.It is usually used in weakness of the spleen and the stomach, lassitude hypodynamia, palpitation, cough Cough abundant expectoration, gastral cavity abdomen, four limbs contraction, carbuncle sore tumefacting virus, alleviate drug toxicity, strong.
Root and root-like stock contain glycyrrhizin (glycyrrhizin), i.e. glycyrrhizic acid glycyrrhinic acid, C42H62O16) 6~14%, it is a kind of triterpenoid saponin for the sweet ingredient of radix glycyrrhizae.Glycyrrhizic acid hydrolysis produces a molecule enoxolone (glycyrrhetic acid are glycyrrhetinic acid, C30H46O4) and two molecule glucose aldehydic acid (glycuronic acid,C6H10O7).And (i.e. liquiritin liquiritin, C containing a small amount of liquiritin21H22O9, it is a kind of flavanols flavanone Glucoside, its glucoside member name glycyrrhizin liquiritigenin, C15H12O4With glycyramarin glycyamarin), isoliquiritin (iso-liquiritin,,C21H24O9), (dihydroxyglycyrrhetic acid are grabric to dihydroxy enoxolone acid,C30H46O5), licoricidin (licoricidin, C25H32O5, i.e. 3 ', 6- diisoamyl alkene -2 ', 4 ', 5- trihydroxies are different Flavane), glycyrol (glycyrol, C21H18O6), 5-0- methyl glycyrols (5-0-methyl glycerol, C22H20O6), it is different Glycyrol (iso-glycyrol, C21H18O6), in addition, still containing mannitol (mannite), glucose 3.8%, sucrose 2.4~ 6.5%th, malic acid, betulinic acid (betulicacid, C30H48O3), asparagine, Yan acid, life element (biotin, C10H16O3N2S) 296 micro- gram grams, trace volatile oil are the special odorous source of radix glycyrrhizae and starch etc..
The extracting method of licorice is to clean radix glycyrrhizae, grinds, adds the ether of 10 times of weight, and flow back 1.5h, Filter, the methanol of 10 times of weight is added in the dregs of a decoction, flow back 1h, filtering, residue is dissolved with water, filters, the collection aqueous solution, by water Solution is dried in vacuo, and is produced.
Aeroge
In the present invention, the preparation method of the aeroge is as follows:
1st, first with 64% (mass fraction) H2SO4Cellulose whiskers are prepared in acidolysis cotton-wool;
2nd, the Lombardy poplar tree extract being prepared, needle juniper extract, Acer palmatum extract, licorice are mixed one Rise, add excessive absolute ethyl alcohol, then mix the cellulose whiskers in step 1 and plant extracts, at 25 DEG C It is ultrasonically treated until turning into gel;
3rd, the gel of step 2 is immersed again in the mixed solution of excessive absolute ethyl alcohol and plant extracts and handles four My god, a solution is changed per 24h, obtains cellulosic ethanol gel;
4th, supercritical CO is used2Cellulosic ethanol gel is dried, obtains aeroge.
As one embodiment of the present invention, calculate in parts by weight, plant extracts mixes in the aeroge Parts by weight are:The Lombardy poplar tree extract of 1-3 parts by weight, the needle juniper extract of 1-5 parts by weight, the Acer palmatum of 1-5 parts by weight carry Take thing, the licorice of 1-5 parts by weight.
As one embodiment of the present invention, calculate in parts by weight, plant extracts mixes in the aeroge Parts by weight are:The Lombardy poplar tree extract of 2 parts by weight, the needle juniper extract of 2 parts by weight, the Acer palmatum extract of 3 parts by weight, 1 The licorice of parts by weight.
As one embodiment of the present invention, calculate in parts by weight, the preparing raw material of the layer 5 includes 1-7 weights The amount aeroge of part, the Lavender of 1-6 parts by weight, hill gooseberry's essential oil of 0.1-8 parts by weight, the polygala of 1-8 parts by weight carry Take thing.
As one embodiment of the present invention, calculate in parts by weight, the preparing raw material of the layer 5 includes 3 weight The aeroge, the Lavender of 2 parts by weight, hill gooseberry's essential oil of 1.5 parts by weight, the milkwort extract of 2 parts by weight of part.
The second aspect of the present invention provides the preparation method for the air freshener for being applicable northern house, comprises the following steps:
1st, composite glue powder being stirred well to clear solution in 90-95 DEG C of hot water, adds gel auxiliary agent, stirring is abundant, Then 60-65 DEG C is cooled to, insulated and stirred obtains A liquid;The preparing raw material of first layer, emulsifying agent and absolute ethyl alcohol are blended, stirring Uniformly obtain B liquid;B liquid is added in A liquid in stirring up to stirring, cools down, obtains delicate fragrance layer freshener;
2nd, the preparing raw material, deionized water, thickener of the second layer are mixed, system temperature gradually heats up, stirring and dissolving, so After be gradually added into emulsifying agent, stir;System temperature is down to 40-50 DEG C, and ethanol added into system, ultrasonic disperse 5-8min, Then cool down, obtain second layer freshener;
3rd, composite glue powder being stirred well to clear solution in 90-95 DEG C of hot water, adds gel auxiliary agent, stirring is abundant, Then 60-65 DEG C is cooled to, insulated and stirred obtains D liquid;The preparing raw material of third layer and absolute ethyl alcohol are blended, are uniformly mixing to obtain E liquid;E liquid is added in D liquid in stirring up to stirring, mixture F is obtained, cools down, obtain third layer freshener;
4th, the 4th layer of preparing raw material, deionized water, thickener are mixed, system temperature gradually heats up, stirring and dissolving, so After be gradually added into emulsifying agent, stir;System temperature is down to 40-50 DEG C, and ethanol added into system, ultrasonic disperse 5-8min, Then cool down, obtain the 4th layer of freshener;
5th, ionized water, emulsifying agent and thickener are removed, first thickener is gradually added into equipped with the container in deionized water, This is system 1, then heating water bath system 1, the temperature of system 1 is gradually heating to 80-100 DEG C, then with 50-100r/min Mixing speed stirring system 1, side stirring add emulsifying agent, stir, be down to 40-50 DEG C, this is system 2;By layer 5 Preparing raw material, ethanol, emulsifying agent be added to system 2, ultrasonic disperse 5-10min, obtain system 3, cool down, it is clear to obtain layer 5 New agent;
6th, by step 1~5, first layer freshener, second layer freshener, third layer freshener, the 4th layer of freshener, Five layers of freshener are poured into mould in sequence, cooling, obtain air freshener.
The third aspect of the present invention provides the application method for the air freshener for being applicable northern house, by applicable northern house Air freshener be placed on and need in the house corner that purifies.
The fourth aspect of the present invention provides application of the air freshener for being applicable northern house in the improvement of northern house.
The air freshener provided by the invention is applied to northern house, such as the provinces and cities such as Jilin, Liaoning.It is because northern Enter morning in winter, day and night temperature is generally more than south, and cools quickly, is less than south plus northern precipitation, pollutant is stagnant in an atmosphere The time stayed is relatively longer, it is easier to accumulates.Simultaneously because the sealing in house, atmosphere draught-free, northern air ambient are very poor. The present invention selects the air freshener of paste, is exclusively used in the poor environment of this air circulation in the north.Because institute in the present invention State and contain hyaluronic acid, theobromine, this kind of material of locust bean gum in air freshener, accelerate pollutants in air between material Precipitation, meanwhile, the chemical action between spirulina polysaccharide and theobromine in spirulina extract can be to harmful in air Material forms chemical action, active attack harmful substance so that it is degraded to innocuous substance, because containing polymethoxy Special Flavonoid substances, outside plus terpenoid, decompose, polymerize with pernicious gas molecule, substituting, replacing and addition etc. Chemical reaction.
The present invention is expanded on further with reference to specific embodiment.
Embodiment 1:The present embodiment provides a kind of air freshener for being applicable northern house, the paste air freshener by Up to it is divided into first layer, the second layer, third layer, the 4th layer, layer 5 down.
The preparing raw material of the first layer includes extract, the Buddha's hand blade of 2 parts by weight of the Pistacia weinmannifolia leaf of 3 parts by weight Extract, cumquat juice, the refined jasmine oil of 2 parts by weight of 8 parts by weight.
The preparing raw material of the second layer includes the beeswaxs of 7 parts by weight, the spirulina extract of 3 parts by weight, 7 parts by weight The extract of asparagus, the achene extracts of dandelion of 6 parts by weight, the ginkgo biloba p.e of 4 parts by weight, 0.7 parts by weight Semen sojae atricolor extract, the Bitter Orang P.E of 0.8 parts by weight, the pachyman of 12 parts by weight, the beeswax modified ultra-branching shell of 1 parts by weight Glycan.
The preparing raw material of the third layer include the hyaluronic acids of 3 parts by weight, 7 parts by weight pseudo-ginseng extract, 2 weights Measure the extract of betel nut, the extract of grape pip of 6 parts by weight, the lavender extract of 1.3 parts by weight, 0.9 nutmeg of part Extract.
Described 4th layer of preparing raw material includes the locust bean gum of 3 parts by weight, the grape skin extract of 7 parts by weight, 7 weight The theobromine of part, false Soviet Union's extract, the bigarabe leaf essential oil of 8 parts by weight of 12 parts by weight.
The preparing raw material of the layer 5 includes the aeroge of 3 parts by weight, the Lavender of 2 parts by weight, 1.5 parts by weight Hill gooseberry's essential oil, the milkwort extract of 2 parts by weight.
The parts by weight of plant extracts mixing are in the aeroge:The Lombardy poplar tree extract of 2 parts by weight, 2 parts by weight Needle juniper extract, Acer palmatum extract, the licorice of 1 parts by weight of 3 parts by weight.
The extract of Pistacia weinmannifolia leaf:Specific preparation method is as follows:Take the fresh tender leaf 200g inputs extraction kettle of incense wood leaf In, it is placed in high pressure extraction tank, is passed through CO2And 500Psi is forced into, Extracting temperature is 40 DEG C, extracts 80min every time, altogether extraction 3 times, obtain grease 1.9g.
The extract of Buddha's hand blade:Specific preparation method is as follows:Buddha's hand blade is cleaned, cut into slices, and 0.01 times of salt Mixing, then add the decocting of 12 times of weight to boil 3h, decoction liquor is dried in vacuo, produced.
Cumquat juice:The cumquat juice refers to clean whole cumquat, after being squeezed the juice using juice extractor, stands 24 hours Afterwards, supernatant liquor is taken.
Refined jasmine oil:The extracting method of the refined jasmine oil is as follows:Jasmine 50g is taken, adds 5L deionized waters and ethanol (water Volume ratio with ethanol is 5:1) put into afterwards in boiler, after being heated to 80 DEG C, use indirect steam heating instead to boiling, condensate liquid Water-oil separating is carried out into oil water separator, collects refined jasmine oil;Add anhydrous sodium sulfate drying filtering and carry out dewater treatment, then Activated carbon is added, and is stirred 48 hours at normal temperatures, is filtrated to get the standard refined jasmine oil of dehydration and decolorization.
Beeswax:The beeswax is bought from Dongguang County friend's sun beeswax products factory.
Spirulina extract:The preparation method of the spirulina extract is as follows:1 part of spirulina is taken, is cleaned, chopping, is added Enter 9 parts of cocoa aqueous alkalis (pH=10), 80 DEG C of Extracting temperature, 2 hours every time extraction time, extract 2 times, after extraction terminates It is rapidly added 2 parts of lemon aqueous solution.
The extract of asparagus:The preparation method of the gold needle mushroom extract is as follows:5g golden needle fungus is taken to add 70mL water, It is placed in beaker and soaks 30min, adjust pH to 4.0, add 1% cellulase enzyme liquid, after digesting 2h at 40 DEG C, at 60 DEG C Lower drying, crushed 50 mesh sieves.Golden needle fungus and volume fraction are mixed to join in round-bottomed flask for 75% ethanol, carried out Microwave treatment, product centrifugal filtration then will be extracted, will be produced.
The achene extract of dandelion:The extracting method of the achene extract of the dandelion is:By the achene of dandelion Clean, section, fried with wheat bran to there is focal spot, boil 30min with the decocting of 8 times of weight after cooling, decoction liquor is dried in vacuo, i.e., .
Ginkgo biloba p.e:The extracting method of ginkgo biloba p.e is to take the blade of ginkgo, blade is cleaned, in 70-80 Dried 2 hours at DEG C, grinds, cross 80 mesh sieves, then boiled with decocting, the weight ratio of water and Folium Ginkgo is 10:1, use decocting Boil 3 times, decoct 20min every time, the liquid decocted out is collected, vacuum drying obtains powder, produces ginkgo biloba p.e.
Semen sojae atricolor extract:The preparation method of the Semen sojae atricolor extract is as follows:1 portion of soybean is added in 10 parts of methanol, no Periodic agitation, extraction filtered out methanol after 72 hours, reclaimed methanol,;10 parts of methanol are added, are stirred frequently, extraction 72 is small When, methanol is filtered out, is repeated 3 times, merges methanol extract liquid, rotary evaporation, obtains Semen sojae atricolor extract.
Bitter Orang P.E:The extracting method of Bitter Orang P.E is to clean the dried immature fruit of citron orange, section, is fried with wheat bran to there is focal spot, 30min is boiled with the decocting of 8 times of weight after cooling, decoction liquor is dried in vacuo, is produced.
Pachyman:The preparation method of the pachyman:Each place of production Indian Bread 0.5g (after drying) is weighed, puts Soxhlet 4h is respectively extracted with petroleum ether and 80% ethanol in extractor, filter residue is put in 50ml volumetric flasks, adds 1mol/L NaOH solution To scale, steeped overnight, filtering, filtrate is taken, be dried in vacuo, produce.
Beeswax modified ultra-branching chitosan:1st, 50g chitosans are dissolved in 1000mL5% aqueous acetic acid and are cooled to 4 ℃.By 5g NaNO2Above-mentioned chitosan solution is added dropwise to after being dissolved in 50mL water, is reacted 9 hours at 0 DEG C, adds dense NaOH water Solution filters to all precipitations are precipitated, and multiple with methanol and water washing, is dried in vacuo low point obtained with aldehyde radical end group Son amount chitosan.(Mw=2300, Mw/Mn=1.5, GPC/ light dissipate product of the low-molecular weight chitoglycan after methanol extraction is classified Penetrate method) be dissolved in 0.1M acetic acid (2mg/mL), after being stirred 1 hour at 10 DEG C be added dropwise the 0.1M NaOH aqueous solution to pH be 5.5.After Continuous stirring adds NaCNBH of 1.0 times equivalent to aldehyde radical molal quantity after 2 hours3, added after reacting 24 hours at 10 DEG C identical The NaCNBH of amount3, continue reaction 72 hours.Period control ph is not higher than 6.5.Reaction solution is filtered with sand core funnel, and filtrate is with 3 Times methanol extraction, and repeatedly washed with methanol, water.It is dried in vacuo at 40 DEG C of product after washing, it is standby obtains hyperbranched chitosan With.
2nd, take the hyperbranched chitosans of 100g to be scattered in 200ml 20% sodium hydroxide solution, be put into refrigerator and freezed At night, added after defrosting equipped with backflow, the three neck reaction bulbs stirred, add 200ml isopropanols, stir 30 minutes at room temperature Afterwards, 5ml is added, the catalyst tetramethyl ammonium hydroxide solution of mass fraction 25%, stirs, is slowly dropped into expoxy propane 400ml, 4h is reacted in 60 DEG C, after reaction stops, with 1:1 hydrochloric acid is neutralized to pH=7, and product is filtered with acetone precipitation, uses second Alcohol solution (volume ratio 8:2) repeatedly after washing, then washed with absolute ethyl alcohol, dry modified ultra-branching chitosan.
3rd, 2g monoxones are weighed, are dissolved in 100ml H2In O, 1g beeswaxs are weighed, are dissolved in the NaOH of 10ml mass fractions 25% Solution, the chloroacetic acid solution prepared is instilled dropwise, reacts 9h at room temperature.PH to 9 is adjusted with watery hydrochloric acid, then adds methanol, is placed 12h, filtering, is dissolved in water, then adds methanol, and filtering, products therefrom is washed repeatedly with ethanol water, untill without chlorine, is dried, Obtain modified beeswax.
4th, modified ultra-branching chitosan and modified beeswax are dissolved in 50mL water, 5g EDC is dissolved in for coupling agent In 200mL water, at 3 DEG C, it is slowly dropped into solution, reacts 24h at 5 DEG C, dialysed 4 days and changed 12 times in distilled water with bag filter Water, the liquid obtained after dialysis is separated out with acetone, after repeatedly being washed with absolute ethyl alcohol, obtains beeswax modified ultra-branching chitosan.
The weight ratio of the beeswax and hyperbranched chitosan is 1:2.
Hyaluronic acid:The hyaluronic acid refers to the hyaluronic acid of chitin modified mistake, and specific preparation method is as follows:
1) preparation of hydroxyethyl chitosan hydrogel:Hydroxyethyl chitosan and GMA are dissolved in water It is middle to form the solution that mass concentration is 2%, it is subsequently added into the water-soluble light trigger of hydroxyethyl chitosan quality 0.06%, magnetic force Ultraviolet light irradiation is utilized after being uniformly mixed 7 minutes, the hydroxyethyl chitosan hydrogel that photochemical polymerization is formed is chilled dry It is dry, it is standby;
2) preparation of hyaluronic acid gel:The hydroxyethyl chitosan hydrogel that step 1) obtains is freezed into sample to be impregnated in In the aqueous solution of bright matter acid and water-soluble light trigger, to swelling equilibrium, implement photochemical polymerization 8 minutes, obtain ethoxy shell Glycan/hyaluronic acid gel;Wherein, it is 3 that hydroxyethyl chitosan hydrogel, which freezes sample and the mass ratio of hyaluronic acid,:1, thoroughly The mass concentration of bright matter acid is 1%, and the quality of water-soluble light trigger is the 0.06% of hyaluronic acid.
GMA is also added with the hyaluronic acid aqueous solution.
The GMA is the 50% of hydroxyethyl chitosan (or hyaluronic acid) quality.
The extract of pseudo-ginseng:Nepal pseudo-ginseng 50g is taken, adds 8L deionized waters and the ethanol (volume of water and ethanol Than for 5:1) put into afterwards in boiler, after being heated to 75 DEG C, use indirect steam heating instead to seething with excitement, condensate liquid divides into profit Water-oil separating is carried out from device, collects oil content;Add anhydrous sodium sulfate drying filtering and carry out dewater treatment, add activated carbon, and Stir 48 hours at normal temperatures, be filtrated to get Herba meconopsis integrifoliae extract.
The extract of betel nut:The extracting method of the betel nut is as follows:1 portion of betel nut is taken, is cleaned, is ground to 25 mesh, adds 5 The ethanol that part volume fraction is 70%, is placed in 75 DEG C of water-baths and extracts 2.5h, and decompression filters, and is extracted after freeze-drying Thing.
The extract of grape pip:1 part of grape pip is taken, cleans, is crushed to 50 mesh, after petroleum ether degreasing and drying, is added 20mL pH 4.0 buffer solution, regulation cellulase solution vigor are brought rapidly up to 90 DEG C after 45 DEG C of enzymolysis 1.0h to 100U/mg Fully inactivation, 1 500r/min centrifuges and preserves supernatant, adds 70% ethanol solution after 50 DEG C of water-bath 30min Filtered, 70 DEG C be evaporated under reduced pressure be concentrated into no drop ooze, concentrate it is freeze-dried grape pip extract.
Lavender extract:Lavender is taken, is cleaned, segment, is boiled 1h with the decocting of 8 times of weight, decoction liquor is dried in vacuo, Produce.
Semen Myristicae extract:Cutability cardamom is taken, is first soaked 4 hours with proper amount of clear water, is then taken out and slightly dry in the air, treat surface without too During more water marks, with wheat bran with putting in hot pot, heated with slow fire, be in brown color to nutmeg surface, when wheat bran is in coke yellow, take Go out, weed out wheat bran, cool.Then the nutmeg after processing is taken, 10h is soaked with the ethanol of volume fraction 75%, then takes out Dry in the shade, grinds, cross 80 mesh sieves, boiled with decocting, water is 8 with myristic weight ratio:1, boiled 4 times with decocting, decocted for the first time The aqueous solution discard, take the aqueous solution of second to the 4th time, merge, vacuum drying, produce.
Locust bean gum:Buy from Shanghai Le Xiang bio tech ltd.
Grape skin extract:Fresh Grape Skin is rinsed well with running water, crushed in mortar, is first added on a small quantity Pure water, it is lightly ground to exquisiteness, then is separately added into 20ml pure water extraction 3~5 times (soaking half an hour every time), merging extracts several times Liquid, and be heated to obtain aubergine leaching liquor.
Theobromine:Buy from Guangzhou Tong Zhe bio tech ltd.
Vacation Soviet Union extract:The extracting method of false Soviet Union's extract is as follows:1 part of false Chinese medicine of reviving is milled into granularity up to 60 mesh. Fine ground false Soviet Union is soaked 24 hours with 2 part 80% of ethanol.Extracted 2 hours at 95 DEG C, refrigerated centrifuge, obtain and once extract Liquid, ethanol in proper amount extraction is added, obtains secondary leaching liquor.Merge the supernatant extracted twice.
Bigarabe leaf essential oil:Heretofore described bigarabe juice essential oil is bought from Shanghai Arabica bio tech ltd.
Lavender:The Lavender is bought from A Fu essential oils limited company.
Hill gooseberry's essential oil:Heretofore described hill gooseberry's essential oil purchase carries commerce and trade Co., Ltd from Beijing Ya Keye.
Milkwort extract:The extracting method of milkwort extract is to clean polygala, segment, is boiled with the decocting of 5 times of weight 3h, decoction liquor is dried in vacuo, produced.
Lombardy poplar tree extract:The extracting method of the Lombardy poplar tree extract is:Lombardy poplar tree bark is taken, by Lombardy poplar Tree bark is cleaned, and grinds, is crossed 80 mesh sieves, is then boiled with decocting, and the weight ratio of water and Lombardy poplar tree is 10:1, boil 3 with decocting It is secondary, 20min is decocted every time, the liquid decocted out is collected, and vacuum drying obtains powder, produces Lombardy poplar tree extract.
Needle juniper extract:The preparation method of the needle juniper extract is as follows:The branches and leaves of needle juniper are taken, by the branches and leaves of 1 portion of needle juniper It is placed in drying box and is dried 2 hours at a temperature of 75 DEG C, milled while hot immediately, granularity of milling is up to 60 mesh.By fine ground needle juniper Branches and leaves powder soaked 24 hours with 2 part 80% of ethanol, take insoluble matter.Insoluble matter is added to 10 parts of cocoa aqueous alkalis (pH=10), extracted 2 hours at 95 DEG C, refrigerated centrifuge, obtain a leaching liquor, add appropriate flooding, obtain secondary extraction Liquid.Merge the supernatant extracted twice, stand, centrifuge taking precipitate.
Acer palmatum:Acer palmatum is cleaned, 10h is soaked with the ethanol of volume fraction 75%, then takes out and dry in the shade, grinds, 80 mesh sieves are crossed, are boiled with decocting, the weight ratio of water and dried orange peel is 8:1, boiled 4 times with decocting, the aqueous solution decocted for the first time discards, and takes The aqueous solution of second to the 4th time, merge, vacuum drying, produce.
Licorice:The extracting method of licorice is to clean radix glycyrrhizae, grinds, adds the second of 10 times of weight Ether, flowed back 1.5h, filtering, and the methanol of 10 times of weight is added in the dregs of a decoction, and flow back 1h, filtering, residue is dissolved with water, filters, and receives Collect the aqueous solution, the aqueous solution is dried in vacuo, produced.
In the present invention, the preparation method of the aeroge is as follows:
1st, first with 64% (mass fraction) H2SO4Cellulose whiskers are prepared in acidolysis cotton-wool;
2nd, the Lombardy poplar tree extract being prepared, needle juniper extract, Acer palmatum extract, licorice are mixed one Rise, add excessive absolute ethyl alcohol, then mix the cellulose whiskers in step 1 and plant extracts, at 25 DEG C It is ultrasonically treated until turning into gel;
3rd, the gel of step 2 is immersed again in the mixed solution of excessive absolute ethyl alcohol and plant extracts and handles four My god, a solution is changed per 24h, obtains cellulosic ethanol gel;
4th, supercritical CO is used2Cellulosic ethanol gel is dried, obtains aeroge.
The preparation method of the air freshener in northern house is applicable, is comprised the following steps:
1st, composite glue powder is stirred well to clear solution in 95 DEG C of hot water, adds gel auxiliary agent, stirring is abundant, then 65 DEG C are cooled to, insulated and stirred obtains A liquid;The preparing raw material of first layer, emulsifying agent and absolute ethyl alcohol are blended, are uniformly mixing to obtain B liquid;B liquid is added in A liquid in stirring up to stirring, cools down, obtains delicate fragrance layer freshener;
2nd, the preparing raw material, deionized water, thickener of the second layer are mixed, system temperature gradually heats up, stirring and dissolving, so After be gradually added into emulsifying agent, stir;System temperature is down to 50 DEG C, and ethanol is added into system, ultrasonic disperse 8min, Ran Houleng But, second layer freshener is obtained;
3rd, composite glue powder is stirred well to clear solution in 95 DEG C of hot water, adds gel auxiliary agent, stirring is abundant, then 65 DEG C are cooled to, insulated and stirred obtains D liquid;The preparing raw material of third layer and absolute ethyl alcohol are blended, are uniformly mixing to obtain E liquid;By E Liquid is added in D liquid in stirring up to stirring, and is obtained mixture F, is cooled down, obtain third layer freshener;
4th, the 4th layer of preparing raw material, deionized water, thickener are mixed, system temperature gradually heats up, stirring and dissolving, so After be gradually added into emulsifying agent, stir;System temperature is down to 50 DEG C, and ethanol is added into system, ultrasonic disperse 8min, Ran Houleng But, the 4th layer of freshener is obtained;
5th, ionized water, emulsifying agent and thickener are removed, first thickener is gradually added into equipped with the container in deionized water, This is system 1, then heating water bath system 1, the temperature of system 1 is gradually heating to 90 DEG C, then the stirring speed with 80r/min Stirring system 1 is spent, side stirring adds emulsifying agent, stirs, be down to 40-50 DEG C, this is system 2;The preparation of layer 5 is former Material, ethanol, emulsifying agent are added to system 2, ultrasonic disperse 10min, obtain system 3, cooling, obtain layer 5 freshener;
6th, by step 1~5, first layer freshener, second layer freshener, third layer freshener, the 4th layer of freshener, Five layers of freshener are poured into mould in sequence, cooling, obtain air freshener.
In the step 1, the composite glue powder is that gellan gum and carragheen according to weight part ratio are 1:1 mixture.
The gel auxiliary agent is calcium lactate.The emulsifying agent is Tween-80.
In the step 2, the thickener is leukotrienes.The emulsifying agent is Tween-80.
In the step 3, the gel auxiliary agent is calcium lactate.
In the step 4, the thickener is leukotrienes.The emulsifying agent is Tween-80.
In the step 5, the emulsifying agent is Tween-80.The thickener is leukotrienes.
In the step 6, the first layer freshener, second layer freshener, third layer freshener, the 4th layer of freshener, The weight ratio of layer 5 freshener is 1:2:2:3:2.
Embodiment 2:Difference with embodiment 1 is that the air freshener does not include beeswax modified ultra-branching chitosan.
Embodiment 3:Difference with embodiment 2 is that the air freshener does not include the second layer.
Embodiment 4:Difference with embodiment 2 is that the air freshener does not include third layer.
Embodiment 5:Difference with embodiment 2 is that the air freshener does not include the 4th layer.
Embodiment 6:Difference with embodiment 2 is that the air freshener does not include layer 5.
Embodiment 7:Difference with embodiment 2 is that the second layer does not include spirulina extract.
Embodiment 8:Difference with embodiment 2 is that the second layer does not include beeswax.
Embodiment 9:Difference with embodiment 2 is that the second layer does not include the extract of asparagus.
Embodiment 10:Difference with embodiment 2 is that the second layer does not include pachyman.
Embodiment 11:Difference with embodiment 2 is that the third layer does not include fucoidan.
Embodiment 12:Difference with embodiment 2 is that described 4th layer does not include theobromine.
Embodiment 13:Difference with embodiment 2 is that the layer 5 does not include aeroge.
Embodiment 14:Difference with embodiment 2 is that the preparation method of the spirulina extract is as follows:Take 1 part of spiral Algae, clean, chopping, add 9 parts of cocoa aqueous alkalis (pH=10), 80 DEG C of Extracting temperature, 2 hours every time extraction time, extraction 2 Secondary, extraction is rapidly added 2 parts of distilled water solutions after terminating.
Embodiment 15:Difference with embodiment 2 is that the preparation method of the gold needle mushroom extract is as follows:Take 5g acupuncture needles Mushroom powder is dried at 60 DEG C, crushed 50 mesh sieves.Golden needle fungus and volume fraction are mixed to join round bottom for 75% ethanol In flask, microwave treatment is carried out, product centrifugal filtration then will be extracted, and produce.
Embodiment 16:Difference with embodiment 2 is that the hyaluronic acid is without modified hyaluronic acid.
Embodiment 17:Difference with embodiment 2 is that the extracting method of the grape pip is as follows:1 part of grape pip is taken, is washed Only, 50 mesh are crushed to, then be separately added into 20ml pure water extraction 5 times (soaking half an hour every time), merge several times leaching liquor, 70 DEG C subtract Pressure distillation and concentration to no drop oozes, the freeze-dried extract for obtaining grape pip of concentrate.
Test:
1. stability
Embodiment 1-16 is sealed in transparent vessel respectively, is placed in insulating box and preserves, the temperature of insulating box is set It is set to 25 DEG C, 4 DEG C, preserves three months, see whether to go bad, A is designated as without going bad within three months, two months to three Occur the moon going bad being designated as B, occur within one month to two months going bad being designated as C, appearance is rotten within one month is designated as D.
2. haze removes test
Burning cigarette simulates haze in haze environment simulation case, after cigarette combustion gasification in haze environment simulation case Concentration is 550 μ g/m3.20cm is placed into haze environment simulation case3Embodiment 1-16, required for record purge haze when Between, unit min.Control group 1 places 20cm3Activated carbon, control group 2 do not place any reagent.
3. radon removes test
In an experimental box, the concentration of Radon is 1000 Bakes/cubic meter in case before test, by the air Freshener is placed in experimental box 8 hours, and test removes radon rate.
Except radon rate=(1000- residues radon contents)/1000 × 100%
4. air sterillization experiment 1
In about 50m3In the laboratory in northeast (Gregorian calendar March), freshly prepared air freshener is placed in the lab Acted on 48 hours with natural bacteria, average bacterium before sterilizing rate=experiment of (average bacterium number after average bacterium number-experiment before experiment) × 100/ Number.
5. air sterillization experiment 2
In about 50m3In the laboratory in northeast (Gregorian calendar March), released after obtained air freshener is placed 2880 hours Put and acted on 48 hours with natural bacteria in atmosphere, the sterilizing rate=examination of (average bacterium number after average bacterium number-experiment before experiment) × 100/ Average bacterium number before testing.
Foregoing example is merely illustrative, some features of the feature for explaining the disclosure.Appended claim It is intended to require the scope as wide as possible being contemplated that, and embodiments as presented herein is only according to all possible embodiment Combination selection embodiment explanation.Therefore, the purpose of applicant is appended claim not by the explanation present invention Feature example selectional restriction.And the progress in science and technology will not formed due to the inaccuracy of language performance and not The possible equivalent or son being presently considered are replaced, and these changes should also be interpreted by appended in the conceived case Claim covers.

Claims (10)

1. a kind of air freshener for being applicable northern house, it is characterised in that the paste air freshener is from top to bottom divided into First layer, the second layer, third layer, the 4th layer, layer 5;
The preparing raw material of the first layer includes the extract of Pistacia weinmannifolia leaf, the extract of Buddha's hand blade, cumquat juice, jasmine essence Oil;
The preparing raw material of the second layer includes the achene extraction of beeswax, spirulina extract, the extract of asparagus, dandelion Thing, ginkgo biloba p.e, Semen sojae atricolor extract, Bitter Orang P.E, pachyman;
The preparing raw material of the third layer includes the extraction of hyaluronic acid, the extract of pseudo-ginseng, the extract of betel nut, grape pip Thing, lavender extract, Semen Myristicae extract;
Described 4th layer of preparing raw material includes locust bean gum, grape skin extract, theobromine, false Soviet Union's extract, bigarabe folic acid Oil;
The preparing raw material of the layer 5 includes aeroge, Lavender, hill gooseberry's essential oil, milkwort extract;
The aeroge is to be prepared using cellulose, plant extract mixtures as preparing raw material;The plant extracts mixes Compound is Lombardy poplar tree extract, needle juniper extract, Acer palmatum extract, the mixture of licorice.
2. the air freshener for being applicable northern house described in claim 1, it is characterised in that calculate in parts by weight, it is described The extraction of the extract of Pistacia weinmannifolia leaf of the preparing raw material of first layer comprising 1-8 parts by weight, the Buddha's hand blade of 1-5 parts by weight Thing, the cumquat juice of 1-10 parts by weight, the refined jasmine oil of 1-3 parts by weight.
3. the air freshener for being applicable northern house described in claim 1, it is characterised in that calculate in parts by weight, it is described Extract, 8 weights of the extract of Pistacia weinmannifolia leaf of the preparing raw material of first layer comprising 3 parts by weight, the Buddha's hand blade of 2 parts by weight Measure the cumquat juice, the refined jasmine oil of 2 parts by weight of part.
4. the air freshener for being applicable northern house described in claim 1, it is characterised in that calculate in parts by weight, it is described The preparing raw material of the second layer includes the beeswax of 1-10 parts by weight, the spirulina extract of 1-8 parts by weight, the acupuncture needle of 5-15 parts by weight The extract of mushroom, the achene extract of dandelion of 5-8 parts by weight, the ginkgo biloba p.e of 2-5 parts by weight, 0.1-1 parts by weight Semen sojae atricolor extract, Bitter Orang P.E, the pachyman of 10-15 parts by weight of 0.1-5 parts by weight.
5. the air freshener for being applicable northern house described in claim 1, it is characterised in that calculate in parts by weight, it is described The preparing raw material of the second layer include the beeswax of 7 parts by weight, the spirulina extract of 3 parts by weight, 7 parts by weight asparagus extraction Thing, the achene extract of dandelion of 6 parts by weight, the ginkgo biloba p.e of 4 parts by weight, 0.7 parts by weight Semen sojae atricolor extract, The pachyman of the Bitter Orang P.E of 0.8 parts by weight, 12 parts by weight.
6. the air freshener for being applicable northern house described in claim 1, it is characterised in that calculate in parts by weight, it is described The preparing raw material of third layer includes the hyaluronic acids of 1-5 parts by weight, the extract of pseudo-ginseng of 5-10 parts by weight, 1-4 parts by weight The extract of betel nut, the extract of grape pip of 2-8 parts by weight, the lavender extract of 0.5-5 parts by weight, 0.8-1.5 meat Fructus Amomi Rotundus extract.
7. the air freshener for being applicable northern house described in claim 1, it is characterised in that calculate in parts by weight, it is described The preparing raw material of third layer includes the hyaluronic acids of 3 parts by weight, the extracts of pseudo-ginseng of 7 parts by weight, the betel nut of 2 parts by weight Extract, the extract of grape pip of 6 parts by weight, the lavender extract of 1.3 parts by weight, 0.9 Semen Myristicae extract.
8. the air freshener for being applicable northern house described in claim 1, it is characterised in that calculate in parts by weight, it is described 4th layer of preparing raw material includes the locust bean gum of 1-5 parts by weight, the grape skin extract of 6-8 parts by weight, 1-15 parts by weight False Soviet Union's extract, the bigarabe leaf essential oil of 7-9 parts by weight of theobromine, 10-15 parts by weight.
9. the air freshener for being applicable northern house described in claim 1, it is characterised in that calculate in parts by weight, it is described 4th layer of preparing raw material include the locust bean gum of 3 parts by weight, the grape skin extract of 7 parts by weight, 7 parts by weight theobromine, False Soviet Union's extract, the bigarabe leaf essential oil of 8 parts by weight of 12 parts by weight.
10. the air freshener for being applicable northern house described in claim 1, it is characterised in that calculate in parts by weight, it is described The preparing raw material of layer 5 includes the aeroge of 1-7 parts by weight, the Lavender of 1-6 parts by weight, the peach gold of 0.1-8 parts by weight The milkwort extract of ma's essential oil, 1-8 parts by weight.
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