CN102823705A - Preparation method of compound barbary wolfberry fruit and black garlic filled chocolate - Google Patents
Preparation method of compound barbary wolfberry fruit and black garlic filled chocolate Download PDFInfo
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Abstract
The invention discloses a preparation method of a compound barbary wolfberry fruit and black garlic filled chocolate. The chocolate is formed by matching black garlic prepared by fermenting with an extractive material with functional components including barbary wolfberry fruits, astragalus mongholicus, kudzu vine root, rhizoma polygonati, hawthorn, salviae miltiorrhizae and ginkgo leaves, and can well express officinal effects of effective components; and the compound barbary wolfberry fruit and black garlic filled chocolate has very good physiological accommodation and health care functions to people with hypertension, hyperlipemia, hyperlipidemia and hypercholesterolemia; and meanwhile, the compound barbary wolfberry fruit and black garlic filled chocolate also has very good effects of anti-oxidizing and anti-radiating, so that the compound barbary wolfberry fruit and black garlic filled chocolate is a type of health-care healthy food with a special flavor, and has a wide market prospect.
Description
Technical field
The present invention relates to food processing field, relate in particular to the preparation method of the black garlic chocolate cream of a kind of compound medlar.
Background technology
Chocolate as a kind of healthy leisure food, gift and the consumer goods of chocolate product as fashion are selected in Along with people's growth in the living standard, increasing consumption.Chocolate is the transliteration of English chocoLate, has another name called chocolate, and being one type is the special confectionery that contains of basic composition with the cocoa bean goods, and delicate mouthfeel is lubricated, and special fragrance is arranged, and caloric value is very high.The characteristic that chocolate is different from other candies is the brown outward appearance of light; Its dissimilar chocolate is of different shades; The height of cocoa component content is different and different to the shade of chocolate; That common chocolate has is brown, white and black are chocolate, also has each manufacturer to use cocoa power, cream, sugared chocolate as feedstock production etc. according to oneself select materials simultaneously.Chocolate is of a great variety, and raw material composition and processing technology are pressed in its classification, can divide two big types of plain chocolate and chocolates; And plain chocolate can be divided into three kinds of different kinds by its different material composition with production technology; The vanilla chocolate that is brown or dark brown color and luster like appearance; Have milk chocolate and above two kinds of chocolates brown or that light brown is damp and be the basic characteristic plain chocolate (like white chocolate, coffee chocolate, black tea chocolate, fruit taste chocolate etc.) for preparing; Make it to form the plain chocolate that is rich in flavour and characteristic, have difformity and special favor, enriched people's demand.
Chocolate is to utilize various candies, kernel etc. as fuse, adopts the different process method, covers dissimilar and plain chocolate kind, like chocolate cream (like whisky heart chocolate, sugared heart chocolate etc.).Nut chocolate is to use various kernels, mixes mutually with plain chocolate with certain proportion, processes chocolate and polishing chocolate such as row, piece, grain (like almond, peanut, fibert) with watering mold forming.That chocolate contains is higher fatty acid, high protein, high sugar and high heat, and the fusing point of its main component cocoa butter also contains the material of abundant vitamin and excitor nerves such as micro-theobromine, caffeine near people's body temperature in cocoa bean.In process,, make its emulsibility and good look, fragrance, so chocolate has the nutritive value of height, and be easy to digest and assimilate with height owing to repeatedly grind to form particulate.
In the prior art; Though chocolate production technology is ripe, designs and varieties are more, because sugar content is high, heat is big; A large amount of dietetic chocolates be prone to blood sugar raise, fat and limited adaptation population and sales volume; It can also be seen that from the product of market sale it is more to produce at present the chocolate product of pursuing the characteristic local flavor, to functionalization with to have the chocolate product that people are played a role in health care very few; The chocolate product that exploitation has functionalization, health should be the target of future development, can have vast market prospect.Chinese patent CN 100577024C discloses " chocolate cream of antierythrite " and had characteristics such as taste is salubrious, throat-clearing lung-moistening, overcome the sweet deficiency that is prone to cause problems such as throat discomfort, blood sugar rising after greasy, edible of chocolate mouthfeel in the prior art.Patent publication No. CN 101485375A provides " black garlic chocolate and preparation method thereof "; This invention adopts chocolate and the black garlic that accounts for the 1%-99% of product gross mass evenly to be mixed and made into; Also process various nuts, preserved fruit, milk wet goods taste simultaneously respectively; To improve palatability, raising product anti-oxidation function, hypotensive, hypoglycemic etc. has been played useful functional effect.
Along with the demand of chocolate in China market constantly increases; Can the elite composition of Chinese herbal medicine be fused in the chocolate product; Can make this product functionization, seriation; For compatriots' health obtains useful health-care efficacy in the dietetic chocolate product, will be the chocolate product direction of market development at home undoubtedly, Chinese herbal medicine is that the soul of China's medical science is precious; The Chinese herbal medicine with the active effect of biological function that can medicinally can eat again combines to prepare characteristic with chocolate; The health chocolate product that the disease-prevention health function of being healthy and strong is arranged again will make chocolate variation at local flavor, functional diversities and satisfies the demand of more consumers, also can have more vast market prospect.
Summary of the invention
The preparation method who the purpose of this invention is to provide the black garlic chocolate cream of a kind of compound medlar; This chocolate cream removes has the chocolate characteristic of conventional original flavor; Increase the fruit of Chinese wolfberry, the Radix Astragali, the root of kudzu vine, sealwort, hawthorn, the red sage root, ginkgo leaf again through extracting the core material composition of processing with black garlic; Both having satisfied the demand of people to chocolate product, and can strengthen the functional requisite of chocolate product again, is a kind of desirable health food.
Technical scheme of the present invention realizes by following method:
The preparation method of the black garlic chocolate cream of a kind of compound medlar is characterized in that this preparation method may further comprise the steps:
Step (one): black garlic bulblet of commodity or belt leather are deceived the clean black garlic bulblet after garlic removes epidermis, and the drip pan of packing into is sent dry 120-360 minute of 55 ℃ of-65 ℃ of drying rooms of temperature control to; Measured moisture content is at 2%-4%; Take out cooling, pack, preserve subsequent use 20 ℃ of following environment temperatures with food bag;
Step (two): select high-quality fruit of Chinese wolfberry 20g-40g, Radix Astragali 10g-30g, root of kudzu vine 10g-30g, sealwort 10g-30g, hawthorn 10g-30g, red sage root 10g-20g, ginkgo leaf 10g-20g and clean, microwave drying, pulverizing are 40 orders-60 order powder;
Step (three): the powder in the step (two) is added pure water boil extraction 3 times, add 15-20 times of water gaging first and soak 7.0-8.0h, heated and boiled is extracted 2.5h-3.5h; Add for the second time 5 times of amount pure water heated and boiled and extract 1.5h-2.5h; Add 3 times of amount pure water heated and boiled for the third time and extract 1.0h-2.0h, merge extract, after filtering with flame filter press; Filtrating with the smart filter of 0.45 μ m miillpore filter, must be filtrated again;
Step (four): the heating of the filtrating in the step (three) is condensed into the thick medicinal extract that relative density is 1.20-1.30, adds edible alcohol in the thick medicinal extract, making spirituosity concentration is 75%-85%; Leave standstill 24h in 4 ℃ of-6 ℃ of environment; Get supernatant, with 0.22 μ m filtering with microporous membrane, recovered under reduced pressure alcohol; Be condensed into 1000 gram weight and divide concentrate, subsequent use;
Step (five): the concentrate of doing in black garlic bulblet and the step (four) in the step () is pressed black garlic bulblet: concentrate=1:0.5-1.0 mixed also is preheated to 70 ℃-80 ℃, drops into vacuum tank, vacuumizes the impregnation process secondary, and the vacuum of finding time for the first time is 0.98-1.02Mpa; Retention time 80-120min slowly abolishes vacuum then, and the vacuum of finding time for the second time is 0.98-1.02Mpa; Retention time 40-60min after treating slowly to abolish vacuum, continues dipping 5h-6h; Make black garlic bulblet evenly suck concentrate and be saturation state, pick up, drain; Microwave drying, making water content is 3%-5%, promptly gets the black garlic bulblet core material of compound medlar;
Step (six): the black garlic bulblet core material of compound medlar in chocolate that will melt and the step (five) press core material content 20%-80%, sends into to be coated with in the clothing make-up machine, be coated with clothing moulding, hardening by cooling after, promptly get the sub garlic chocolate cream finished product of deceiving of compound medlar.
The preparation method of the black garlic chocolate cream of a kind of compound medlar of the present invention can also comprise xylitol 0-30% in the concentrate material in its step (four).
According to the present invention, " % " among the present invention is percentage by weight.
The black garlic chocolate cream of a kind of compound medlar of the present invention also can be made laminarly, and its characteristic is that also the preparation method of the black garlic chocolate cream of this laminar compound medlar comprises the steps:
Step (one): black garlic bulblet of commodity or belt leather are deceived the clean black garlic bulblet after garlic removes epidermis, and the drip pan of packing into is sent dry 120-360 minute of 55 ℃ of-65 ℃ of drying rooms of temperature control to; Measured moisture content is at 2%-4%; Take out cooling, pack, preserve subsequent use 20 ℃ of following environment temperatures with food bag;
Step (two): select high-quality fruit of Chinese wolfberry 20g-40g, Radix Astragali 10g-30g, root of kudzu vine 10g-30g, sealwort 10g-30g, hawthorn 10g-30g, red sage root 10g-20g, ginkgo leaf 10g-20g and clean, microwave drying, pulverizing are 40 orders-60 order powder;
Step (three): the powder in the step (two) is added pure water boil extraction 3 times, add 15-20 times of water gaging first and soak 7.0-8.0h, heated and boiled is extracted 2.5h-3.5h; Add for the second time 5 times of amount pure water heated and boiled and extract 1.5h-2.5h; Add 3 times of amount pure water heated and boiled for the third time and extract 1.0h-2.0h, merge extract, after filtering with flame filter press; Filtrating with the smart filter of 0.45 μ m miillpore filter, must be filtrated again;
Step (four): the heating of the filtrating in the step (three) is condensed into the thick medicinal extract that relative density is 1.20-1.30, adds edible alcohol in the thick medicinal extract, making spirituosity concentration is 75%-85%; Leave standstill 24h in 4 ℃ of-6 ℃ of environment; Get supernatant, with 0.22 μ m filtering with microporous membrane, recovered under reduced pressure alcohol; Be condensed into 1000 gram weight and divide concentrate, subsequent use;
Step (five): the concentrate of doing in black garlic bulblet and the step (four) in the step () is pressed black garlic bulblet: concentrate=1:0.5-1.0 mixed also is preheated to 70 ℃-80 ℃, drops into vacuum tank, vacuumizes the impregnation process secondary, and the vacuum of finding time for the first time is 0.98-1.02Mpa; Retention time 80-120min slowly abolishes vacuum then, and the vacuum of finding time for the second time is 0.98-1.02Mpa, retention time 40-60min; After treating slowly to abolish vacuum, continue dipping 5h-6h, make black garlic bulblet evenly suck concentrate and be saturation state; Pick up, drain, microwave drying; Making water content is 8%-10%, with the drum extruder material is pressed into the thin slice of uniformity again, cut into different sizes and shape as required after; Carry out drying again, making water content is 3%-5%, promptly gets the black garlic slice core material of compound medlar;
Step (six): the black garlic slice core material of compound medlar in chocolate that will melt and the step (five) press sheet core material 20%-80%, sends into to be coated with in the clothing make-up machine, be coated with clothing moulding, hardening by cooling after, promptly get the sub garlic sheet chocolate cream finished product of deceiving of compound medlar.
The preparation method of the black garlic chocolate cream of a kind of compound medlar of the present invention can also comprise xylitol 0-30% in the concentrate material in its step (four).
According to the present invention, " % " among the present invention is percentage by weight.
The black garlic chocolate cream of a kind of compound medlar of the present invention; Select known chocolate product material as basic shell material; The concentrated material that extracts with warps such as the fruit of Chinese wolfberry, the Radix Astragali, the root of kudzu vine, sealwort, hawthorn, the red sage root, ginkgo leaves is that main function material composition and black garlic are processed core; And the collaborative and humidification of each active ingredient; Enable to play useful health-care effect, particularly can strengthen effect promoting blood circulation and removing blood stasis from the cuisines of dietetic chocolate, strengthening physiological regulation function to the people that suffer from hypertension, hyperlipidemia, hyperglycaemia, high cholesterol in essence.
Black garlic; Be to process through hot and humid specified conditions fermentation by uncooked garlic; The physics and chemistry that its sweat produces changes, and makes original composition that very about-face take place, and wherein the content of polyphenol and free amino acid and FOS substantially exceeds uncooked garlic; Produced Ai Qiao grace S-pi-allyl-L-cysteine simultaneously; Water-soluble polyphenoils is 8.7 times of living garlic, and fat-soluble polyphenoils is 79 times of living garlic, have enhancing human immune, antiallergy, anti-ageing, anticancer, suppress artery sclerosis, steadily blood pressure, reducing blood lipid, hypoglycemic, reduce effects such as cholesterol, treatment constipation, beauty treatment.Black garlic flavour after the fermentation is sweet, eats and can not produce unpleasant garlic odour implication, more can not cause the excitant injury to coat of the stomach, processes chocolate product, and its effect meeting anti-oxidant, that remove human free radical strengthens greatly when making dietetic chocolate.
The fruit of Chinese wolfberry for the ripening fruits of matrimony vine of solanaceae plant (Lycium chintnse) or lycium barbarum (Ly cium bar barum), is famous nourishing Chinese medicine, is listed in by health ministry " be food be again the article list of medicine ".The function nourishing yin and supplementing blood, benefiting shrewd head.Shennong's Herbal is claimed: " obey hard muscles and bones for a long time, it is not old to make light of one's life by commiting suicide, cold-resistant heat "." property of medicine opinion " meaning can " be mended the vital essence various symptims and signs of deficiency, make eye bright and calm the nerves, make us long-lived ".The traditional Chinese medical science is used for soreness and weakness of waist and knees due to deficient of kidney deficiency and liver, essence and blood, dizziness and tinnitus etc.These article contain betaine (about 1%), LBP-X, carrotene, thiamines, riboflavin, Yan acid, ascorbic acid, calcium, phosphorus, iron etc.Modern pharmacological research is the result show, these article still have reducing blood lipid, step-down, effect such as hypoglycemic; And ability enhancing body immunologic function; Make the active rising of erythrocyte sod.Its polysaccharide has antioxidation, and experimental result shows that also these article are to safeguarding the somatic normal development of the elderly, improve the repair ability of DNA and impelling senile cell all to play a part useful to young direction reverse.
The Radix Astragali for the dry root of pulse family coptis plant Astragalus membranacus (Astrgalus membranaceus) etc., is the key medicine of invigorating qi for strengthening superficies in the Chinese medicine, and medicinal history is very of a specified duration.Classified as " the article list that can be used for health food " by health ministry." Mingyi Bielu " claimed: Radix Astragali ability " it is deficient to mend the husband, and the exhaustion or lesion of the five internal organs is won thin, quenches the thirst, and stomachache is let out dysentery, beneficial gas ".Essentials of Matea Medica is pointed out, " Radix Astragali is processed and used bowl spares, beneficial vigour, warm three warmers, strong taste, green blood, myogenic ".It serves to show the function that the Radix Astragali has training vigour, qi-restoratives to decrease.Pharmacological experiments shows that the Radix Astragali has the effect of enhancing body immunologic function, and can strengthen cytophagous phagocytic function, and SOD is active in the rising animal body, reduces serum lipid peroxide content.Effects such as the Radix Astragali still can have increases leucocyte, coronary artery dilating, step-down, protect the liver, antifatigue, anti-anoxic.Can be used for the empty old man's of the many bodies of disease tonic and anti-ageing.
The root of kudzu vine is the dry root of legume pueraria lobata Pueraria Lobata (willd.) ohwi.These article are the key medicine of treatment stiff nape and back.Be the plant resources of integration of drinking and medicinal herbs by Ministry of Public Health's approval.The Shennong's Herbal record: " main quenching one's thirst, high fever of the body, vomiting, all numbness plays cloudy gas, separates all poison "." Mingyi Bielu " claimed: " the cold middle wind headache of curing the wound, expelling pathogenic factors from muscles and skin is delivered, and perspires, loosing the interspaces of skin and muscles is treated metal-inflicted wound, pain relieving, side of body wind pain "." juice of taking root, treatment is quenched one's thirst, the typhoid fever high fever "." property of medicine opinion " recorded and narrated: " control a day row and go up gas, it is contrary to vomit, whetting the appetite, and main relieving alcoholism ends polydipsia.Endure bits and control metal-inflicted wound, disease is analgesic when controlling ".Its chemical composition mainly contains flavones ingredient: Puerarin, Daidzein, daidzin, Daidzein 8-O-apiose (1-6) glucoside etc.; The Coumarins composition: 6,7-dimethyl cumarin, 6-Mang ox base-7,4-dihydroxycoumarin etc.Modern pharmacological research is the result show, that the root of kudzu vine has is analgesic, improve myocardial ischemia, anti arteriosclerosis, anti-oxidant, hypoglycemic, antitumor and effect such as protect the liver.Join hawthorn and be applied to speen-kidney dificiency, the turbid blood stasis type hyperlipidemia of disease effect is better.
Sealwort is the dry rhizome of liliaceous plant sealwort (Polygonatum sibiricum), China's successive dynasties with sealwort for prolonging old and feeble medicine.Be the plant resources of integration of drinking and medicinal herbs by the health ministry approval.Compendium of Material Medica is claimed " mend all void, end fever and chills, the replenishing essence marrow "." new compilation of materia medica " claimed " flat filling blood and moisten "." Mingyi Bielu " claimed, sealwort " tonifying middle-Jiao and Qi, remove rheumatism, five viscera settling, for a long time clothes make light of one's life by commiting suicide prolong life not hungry ".Draw " angle sesame grass warp " cloud according to Li Shizhen (1518-1593 A.D.) again: " beneficial gas during sealwort is wide, it is good that the five internal organs are transferred, muscle sufficiency, marrow is strong, and its power increases doubly, and not old for many years, color is obvious, the blackening of turning white, dedentition is more living ... ".Its chemical composition mainly contains polysaccharide: sealwort compound sugar A, B, C etc.; Saponin component: huangjinoside A, B, new bus draw time diosgenin A-3-O-β-lycotetraose glycosides, Dioscin, and digitalis glycoside pulls out the chinaroot greenbrier saponin(e, asiaticosid, madecassoside etc.; Flavones ingredient: celery flavine etc.Modern pharmacological research shows, sealwort has that the immunity of raising, antifatigue, raising are remembered, effect such as anti-oxidant.Sealwort is joined the fruit of Chinese wolfberry, and its sealwort is longer than nourishing Yin and moistening lung, and the fruit of Chinese wolfberry is good at nourishing kidney and replenishing pneuma.Two medicine compatibilities can strengthen qi-restoratives and beneficial vital essence, and moistening lung and the effect of cough-relieving are applicable to the soreness of waist due to the lung deficiency of the kidney void, seminal emission, cough etc.
Hawthorn is rose family may large-fruited Chinese hawthorn (crataegus PinnatiFida Var.major), fructus crataegi pinnatifidae (C.Pinnatifida) or fructus crataegi cuneatae (fructus crataegi cuneatae) fruit (C.Cuneata).Hawthorn as the existing long history of medicinal application, is classified as " be food be again the drug list of medicine " by the Ministry of Public Health in China.On the books in the Collective Notes to the Canon of Materia medica.The traditional Chinese medical science is used for helping digestion long-pending more, the hemostasis that looses, and sealing dysentery is controlled the elderly's soreness of waist and knee joint etc." Tang materia medica " recorded and narrated: " juice is obeyed main water dysentery, washes one's hair in head and the ablution sore and itches." Compendium of Material Medica claims: " and change diet, the Nei Ji wei lump in the abdomen that disappears, the full acid regurgitation of phlegm and retained fluid ruffian, stagnant blood is bloated bitterly "." book on Chinese herbal medicine is looked for the truth " claimed: " the so-called invigorating the spleen person of hawthorn because of its spleen has dyspepsia, with the salty flavor of this acid, thinks and wears down that phlegm disappears in order to do the food row, broken and the letting out of gas, meaning for strong, only belong to being good for of treatment for relieving indigestion and constipation ".Its chemical composition mainly contains organic acids composition; Citric acid, chlorogenic acid, citric acid mono-methyl, citric acid dimethyl ester, citric acid trimethyl etc.; Flavones ingredient: Quercetin, Hyperoside, Vitex negundo var cannabifolia element etc.; Three obedient constituents: ursolic acid, betulin etc.; Also contain carrotene, vitamin C, vitamin B1 etc.The modern pharmacological research result shows that these article have the active effect of stronger inhibition MAO-B, cardiac stimulant is still arranged in addition, increases coronary artery and cerebral blood flow (CBF), reduction MCO, anti-arrhythmia, hypotensive, reducing blood lipid, effect such as antibiotic.The clinical tonic medicine that is available as the elderly also is used for coronary heart disease, hyperlipemia, hypertension, indigestion, bacillary dysentery, enteritis etc.
The red sage root is the dry rhizome of the Labiatae salvia red sage root (Salvia miltionrrhiza).The red sage root is a traditional Chinese medical science key medicine promoting blood circulation and removing blood stasis.Classified as " the article list that can be used for health food " by health ministry." main trusted subordinate's perverse trend, fever and chills are gathered the diffusing lump in the abdomen of ， Po wei, end dysphoria, beneficial gas in the Shennong's Herbal record." " the southern regions of the Yunnan Province book on Chinese herbal medicine " record: " will is decided in bushing, calming heart and tranquilizing mind.Control forgetful palpitation, palpitation with fear is insomnia ".Compendium of Material Medica is claimed: " invigorate blood circulation, logical percardium is controlled colic ".Its chemical composition mainly contains the quinones composition: salvia miltiorrhiza bge I, II, II
A, II
B, III, V, VI, Isotanshinone, II
A, II
B, Cryptotanshinone, different Cryptotanshinone, methyltanshinone, hydroxyl tanshinone, miltionone, left-handed dihydrotanshinone etc.; Organic acid composition: salviandic acid A, B, danshensu, protocatechualdehyde, protocatechuic acid, Rosmarinic acid, butanedioic acid, alkannic acid mono methyl ester, alkannic acid dimethyl ester, alkannic acid A, B etc.; Fatty acid composition: linoleic acid, leukotrienes, oleic acid, palmitic acid.Modern pharmacological research shows that the red sage root has anticoagulation, antithrombotic to form, improves microcirculation, improves hemorheological property, resisting myocardial ischemia, anti-cerebral ischemia, anti-oxidant, reducing blood lipid, step-down, cardiac stimulant, anti-anoxic, calmness, analgesic, anti-inflammatory, pharmacological action such as antibacterial.The existing clinical common cerebrovascular disease that is used for the elderly, to cerebral arteriovenous malformation, ishemic stroke, cerebral thrombosis, cerebral embolism etc. have certain curative effect.Also be used for coronary heart disease, hypertension, more expiring property intravascular coagulation (DIC), vasculitis, neurasthenia, insomnia, lumbago, hepatitis, pyogenic infection etc.The red sage root and hawthorn compatibility can strengthen function of promoting blood circulation to disperse blood clots.
Ginkgo leaf, these article are the dried leaves of Ginkgoaceae plant Ginkgo biloba Ginkgo biloba L.." national Chinese herbal medicine compilation " claimed: " promoting blood circulation and stopping pain.Cure mainly coronary arteriosclerotic cardiopathy angina pectoris, the too high disease of serum cholesterol, dysentery, elephant hide is swollen ".Classified as " the article list that can be used for health food " by health ministry.Its chemical composition mainly contains flavones, flavonols and glycoside composition: Kaempferide, Quercetin, Isorhamnetin and monoglycosides thereof and bioside, three glucosides etc.; Terpene lactone compound: ginkalide A, B, C, J, M and Bilobalide etc.; Also contain polypenthylene alcohol ester, polysaccharide, organic acid etc.Modern pharmacological research shows, the active ingredient main pharmacological of ginkgo leaf: 1. remove the generation of free radical, suppress the peroxidating of cell membrane lipid, it is active to improve erythrocyte sod.2. resisting myocardial ischemia increases CF, and the cardiac disorder that myocardial ischemia is caused has protective effect.3. anti-cerebral ischemia, expansion of cerebral vascular promotes the brain blood circulation, improves the brain metabolism, increases the carotid artery flow amount.4. prevent thrombosis, platelet aggregation-against.5. reduce blood viscosity, strengthen erythrocytic deformability.6. reduce triglycerides in the blood, improve blood middle-high density lipoprotein cholesterol content.Have well anti-oxidant, Cardioprotective, expansion blood vessel, protection blood vessel endothelium, step-down, accent blood fat, antiatherosclerosis, brain protection and hypoglycemic and treatment diabetic complication, kidney protection, liver protection, lung protection, look protection, relieving asthma, the anti-ageing efficacy of drugs of waiting for a long time.Be usually used in coronary heart disease, cerebral infarction, cerebral angiospasm, the outer sequelae of brain, senile dementia, hyperlipidemia, shaking plasy, lower limbs arteritis, the dizzy syndrome of brain, chronic bronchitis etc.
Chocolate cream of the present invention compared with prior art has following beneficial effect:
(1) cooperates with the extraction material of the fruit of Chinese wolfberry with functional component, the Radix Astragali, the root of kudzu vine, sealwort, hawthorn, the red sage root, ginkgo leaf with the black garlic of processing through fermentation; Can bring into play the medicinal efficacy of its active ingredient better; The people that suffer from hypertension, hyperlipemia, hyperglycaemia, high cholesterol are had good physiology regulate and health-care effect, play anti-oxidant and radiation protection simultaneously.
(2) with the technology of kinds of traditional Chinese medicines through water extract-alcohol precipitation; Extract its effective composition and deceive the garlic bulblet core through vacuumizing to flood active ingredient to be distributed to equably to process in the black garlic bulblet again; Unlikely and chocolate consolute and produce disagreeable taste; Can guarantee that more it incorporates the stability of active ingredient, has characteristic product.
(3) traditional Chinese medicine ingredients through water carry, alcohol precipitation; The medicinal material organic principle is fully extracted; Improve the effect of Chinese medicine in product, wherein in the leaching process repeatedly link filter, guarantee to extract the fine and closely woven degree of composition; The one, infiltration and evenly easily when being beneficial to the black garlic core of preparation, the 2nd, guarantee exquisiteness, the lubricated mouthfeel of chocolate product after edible.
(4) can select xylitol as sweetener to the needs of different crowd taste according to product; Xylitol sugariness and sucrose are suitable; Human body does not receive the influence of insulin after xylitol is absorbed, and can avoid blood sugar to raise; So diabetes patient preferably, and unlikely dental caries of xylitol and anticariogenic effect is arranged.
(5) the black garlic chocolate cream of the compound medlar antioxygenic property and the anti-oxidation function that have compiled black garlic, chocolate and Chinese medicine composition significantly improves; Its anti-immunocompetence, reducing blood lipid, norcholesterol, function such as hypotensive and hypoglycemic are remarkable; Suitable mid-aged population is edible, is more suitable for patients with diabetes mellitus.
(6) the black garlic core material mouthfeel of product of the present invention is soft, chews instant, is the popular food that integrates natural, green, cuisines, health, fashion, and is applicable to that more the elderly eats.
(7) product of the present invention, novel, unique flavor, functional abundanter is the newtype in the chocolate food, is a kind of health healthy food of characteristic local flavor, market prospects are wide.
The specific embodiment
Below further the preparation method of the black garlic chocolate cream of a kind of compound medlar is set forth through embodiment; But it is not a limitation of the present invention, to the professional and technical personnel; Any to change of the present invention, all will fall into protection scope of the present invention.
Embodiment 1
Step (one) removes the black garlic bulblet of commodity or the black garlic of belt leather to the clean black garlic bulblet behind the epidermis, and the drip pan of packing into is sent dry 360 minutes of the drying room of 55 ℃ of temperature controls to; Record water content at 2%-4%; Take out, pack, preserve subsequent use 20 ℃ of following environment temperatures with food bag;
Step (two): select high-quality fruit of Chinese wolfberry 40g, Radix Astragali 30g, root of kudzu vine 30g, sealwort 30g, hawthorn 30g, red sage root 20g, ginkgo leaf 20g and clean, microwave drying, pulverizing are 40 order powder;
Step (three): the powder in the step (two) is added 20 times of amount pure water soak 8.0h, heated and boiled is extracted 3.5h, filters; Filter residue is added 5 times of amount pure water heated and boiled extract 2.5h, filter, filter residue adds 3 times of amount pure water heated and boiled again and extracts 2.0h; Filter, merge No. three times extract, after filtering with flame filter press; With the smart filter of 0.45 μ m miillpore filter, must filtrate again;
Step (four): the heating of the filtrating in the step (three) is condensed into the thick medicinal extract that relative density is 1.20-1.30, adds edible alcohol in the thick medicinal extract, making spirituosity concentration is 85%; Leave standstill 24h in 4 ℃ of-6 ℃ of environment; Get supernatant, with 0.22 μ m filtering with microporous membrane, recovered under reduced pressure alcohol; Be condensed into 1000 gram weight and divide concentrate, subsequent use;
Step (five): the concentrate of doing in black garlic bulblet and the step (four) in the step () is pressed black garlic bulblet: concentrate=1:1.0 mixed also is preheated to 70 ℃-80 ℃, drops into vacuum tank, vacuumizes the processing secondary, and the vacuum of finding time for the first time is 1.02Mpa; Retention time 120min slowly abolishes vacuum then, and the vacuum of finding time for the second time is 0.98Mpa; Retention time 60min after treating slowly to abolish vacuum, continues dipping 6h; Make black garlic bulblet evenly suck concentrate and be saturation state, pick up, drain; Microwave drying, making water content is 3%-5%, promptly gets the black garlic bulblet core material of compound medlar;
Step (six): the black garlic bulblet core material of compound medlar in chocolate that will melt and the step (five); Chocolate by weight percentage: core material=80:20 sends into and is coated with the clothing make-up machine, is coated with clothing moulding, hardening by cooling through conventional method; Select, pack, get product.
Embodiment 2
Step (one) removes the black garlic bulblet of commodity or the black garlic of belt leather to the clean black garlic bulblet behind the epidermis, and the drip pan of packing into is sent dry 120 minutes of the drying room of 65 ℃ of temperature controls to; Record water content at 2%-4%; Take out, pack, preserve subsequent use 20 ℃ of following environment temperatures with food bag;
Step (two): select high-quality fruit of Chinese wolfberry 20g, Radix Astragali 10g, root of kudzu vine 10g, sealwort 10g, hawthorn 10g, red sage root 10g, ginkgo leaf 10g and clean, microwave drying, pulverizing are 60 order powder;
Step (three): the powder in the step (two) is added 15 times of amount pure water soak 7.0h, heated and boiled is extracted 2.5h, filters; Filter residue is added 5 times of amount pure water heated and boiled extract 1.5h, filter, filter residue adds 3 times of amount pure water heated and boiled again and extracts 1.0h; Filter, merge No. three times extract, after filtering with flame filter press; With the smart filter of 0.45 μ m miillpore filter, must filtrate again;
Step (four): the heating of the filtrating in the step (three) is condensed into the thick medicinal extract that relative density is 1.20-1.30, adds edible alcohol in the thick medicinal extract, making spirituosity concentration is 75%; Leave standstill 24h in 4 ℃ of-6 ℃ of environment; Get supernatant, with 0.22 μ m filtering with microporous membrane, recovered under reduced pressure alcohol; Be condensed into 1000 gram weight and divide concentrate, subsequent use;
Step (five): the concentrate of doing in black garlic bulblet and the step (four) in the step () is pressed black garlic bulblet: concentrate=1:0.5 mixed also is preheated to 70 ℃-80 ℃, drops into vacuum tank, vacuumizes the processing secondary, and the vacuum of finding time for the first time is 0.98Mpa; Retention time 100min slowly abolishes vacuum then, and the vacuum of finding time for the second time is 1.0Mpa; Retention time 40min after treating slowly to abolish vacuum, continues dipping 5h; Make black garlic bulblet evenly suck concentrate and be saturation state, pick up, drain; Microwave drying, making water content is 3%-5%, promptly gets the black garlic bulblet core material of compound medlar;
Step (six): the black garlic bulblet core material of compound medlar in chocolate that will melt and the step (five); Chocolate by weight percentage: core material=20:80 sends into and is coated with the clothing make-up machine, is coated with clothing moulding, hardening by cooling through conventional method; Select, pack, get product.
Embodiment 3
Step (one) removes the black garlic bulblet of commodity or the black garlic of belt leather to the clean black garlic bulblet behind the epidermis, and the drip pan of packing into is sent dry 180 minutes of the drying room of 60 ℃ of temperature controls to; Record water content at 2%-4%; Take out, pack, preserve subsequent use 20 ℃ of following environment temperatures with food bag;
Step (two): select high-quality fruit of Chinese wolfberry 40g, Radix Astragali 10g, root of kudzu vine 10g, sealwort 10g, hawthorn 10g, red sage root 10g, ginkgo leaf 10g and clean, microwave drying, pulverizing are 50 order powder;
Step (three): the powder in the step (two) is added 16 times of amount pure water soak 7.0h, heated and boiled is extracted 3.0h, filters; Filter residue is added 5 times of amount pure water heated and boiled extract 2.0h, filter, filter residue adds 3 times of amount pure water heated and boiled again and extracts 1.5h; Filter, merge No. three times extract, after filtering with flame filter press; With the smart filter of 0.45 μ m miillpore filter, must filtrate again;
Step (four): the heating of the filtrating in the step (three) is condensed into the thick medicinal extract that relative density is 1.20-1.30, adds edible alcohol in the thick medicinal extract, making spirituosity concentration is 80%; Leave standstill 24h in 4 ℃ of-6 ℃ of environment, get supernatant, with 0.22 μ m filtering with microporous membrane; Recovered under reduced pressure alcohol; Add the 150g xylitol, be condensed into 1000 gram weight and divide concentrate, subsequent use;
Step (five): the concentrate of doing in black garlic bulblet and the step (four) in the step () is pressed black garlic bulblet: concentrate=1:0.7 mixed also is preheated to 70 ℃-80 ℃, drops into vacuum tank, vacuumizes the processing secondary, and the vacuum of finding time for the first time is 0.99Mpa; Retention time 80min slowly abolishes vacuum then, and the vacuum of finding time for the second time is 1.01Mpa; Retention time 40min after treating slowly to abolish vacuum, continues dipping 5h; Make black garlic bulblet evenly suck concentrate and be saturation state, pick up, drain; Microwave drying, making water content is 3%-5%, promptly gets the black garlic bulblet core material of compound medlar;
Step (six): the black garlic bulblet core material of compound medlar in chocolate that will melt and the step (five); Chocolate by weight percentage: core material=40:60 sends into and is coated with the clothing make-up machine, is coated with clothing moulding, hardening by cooling through conventional method; Select, pack, get product.
Embodiment 4
Step (one) removes the black garlic bulblet of commodity or the black garlic of belt leather to the clean black garlic bulblet behind the epidermis, and the drip pan of packing into is sent dry 200 minutes of the drying room of 60 ℃ of temperature controls to; Record water content at 2%-4%; Take out, pack, preserve subsequent use 20 ℃ of following environment temperatures with food bag;
Step (two): select high-quality fruit of Chinese wolfberry 30g, Radix Astragali 15g, root of kudzu vine 15g, sealwort 15g, hawthorn 15g, red sage root 12g, ginkgo leaf 12g and clean, microwave drying, pulverizing are 40 order powder;
Step (three): the powder in the step (two) is added 18 times of amount pure water soak 7.5h, heated and boiled is extracted 3.0h, filters; Filter residue is added 5 times of amount pure water heated and boiled extract 2.0h, filter, filter residue adds 3 times of amount pure water heated and boiled again and extracts 1.0h; Filter, merge No. three times extract, after filtering with flame filter press; With the smart filter of 0.45 μ m miillpore filter, must filtrate again;
Step (four): the heating of the filtrating in the step (three) is condensed into the thick medicinal extract that relative density is 1.20-1.30, adds edible alcohol in the thick medicinal extract, making spirituosity concentration is 75%; Leave standstill 24h in 4 ℃ of-6 ℃ of environment; Get supernatant, with 0.22 μ m filtering with microporous membrane, recovered under reduced pressure alcohol; Be condensed into 1000 gram weight and divide concentrate, subsequent use;
Step (five): the concentrate of doing in black garlic bulblet and the step (four) in the step () is pressed black garlic bulblet: concentrate=1:0.8 mixed also is preheated to 70 ℃-80 ℃, drops into vacuum tank, vacuumizes the processing secondary, and the vacuum of finding time for the first time is 1.02Mpa; Retention time 80min slowly abolishes vacuum then, and the vacuum of finding time for the second time is 0.98Mpa; Retention time 60min after treating slowly to abolish vacuum, continues dipping 6h; Make black garlic bulblet evenly suck concentrate and be saturation state, pick up, drain; Microwave drying, making water content is 3%-5%, promptly gets the black garlic bulblet core material of compound medlar;
Step (six): the black garlic bulblet core material of compound medlar in chocolate that will melt and the step (five); Chocolate by weight percentage: core material=50:50 sends into and is coated with the clothing make-up machine, is coated with clothing moulding, hardening by cooling through conventional method; Select, pack, get product.
Embodiment 5
Step (one) removes the black garlic bulblet of commodity or the black garlic of belt leather to the clean black garlic bulblet behind the epidermis, and the drip pan of packing into is sent dry 120 minutes of the drying room of 65 ℃ of temperature controls to; Record water content at 2%-4%; Take out, pack, preserve subsequent use 20 ℃ of following environment temperatures with food bag;
Step (two): select high-quality fruit of Chinese wolfberry 30g, Radix Astragali 20g, root of kudzu vine 20g, sealwort 20g, hawthorn 20g, red sage root 15g, ginkgo leaf 15g and clean, microwave drying, pulverizing are 60 order powder;
Step (three): the powder in the step (two) is added 20 times of amount pure water soak 7.0h, heated and boiled is extracted 3.5h, filters; Filter residue is added 5 times of amount pure water heated and boiled extract 2.0h, filter, filter residue adds 3 times of amount pure water heated and boiled again and extracts 2.0h; Filter, merge No. three times extract, after filtering with flame filter press; With the smart filter of 0.45 μ m miillpore filter, must filtrate again;
Step (four): the heating of the filtrating in the step (three) is condensed into the thick medicinal extract that relative density is 1.20-1.30, adds edible alcohol in the thick medicinal extract, making spirituosity concentration is 80%; Leave standstill 24h in 4 ℃ of-6 ℃ of environment; Get supernatant, with 0.22 μ m filtering with microporous membrane, recovered under reduced pressure alcohol; Be condensed into 1000 gram weight and divide concentrate, subsequent use;
Step (five): the concentrate of doing in black garlic bulblet and the step (four) in the step () is pressed black garlic bulblet: concentrate=1:0.6 mixed also is preheated to 70 ℃-80 ℃, drops into vacuum tank, vacuumizes the processing secondary, and the vacuum of finding time for the first time is 0.98Mpa; Retention time 120min slowly abolishes vacuum then, and the vacuum of finding time for the second time is 0.98Mpa, retention time 60min; After treating slowly to abolish vacuum, continue dipping 5h, make black garlic bulblet evenly suck concentrate and be saturation state; Pick up, drain, microwave drying; Making water content is 8%-10%, earlier with the drum extruder material is pressed into the thin slice of uniformity, again after cut growth 40mm, wide 25mm, the thick 2.5mm sheet; Carry out drying again, making water content is 3%-5%, promptly gets the black garlic sheet core material of compound medlar;
Step (six): the black garlic sheet core material of compound medlar in chocolate that will melt and the step (five); Chocolate by weight percentage: core material=30:70 sends into and is coated with the clothing make-up machine, is coated with clothing moulding, hardening by cooling through conventional method; Select, pack, get product.
Embodiment 6
Step (one) removes the black garlic bulblet of commodity or the black garlic of belt leather to the clean black garlic bulblet behind the epidermis, and the drip pan of packing into is sent dry 360 minutes of the drying room of 55 ℃ of temperature controls to; Record water content at 2%-4%; Take out, pack, preserve subsequent use 20 ℃ of following environment temperatures with food bag;
Step (two): select high-quality fruit of Chinese wolfberry 20g, Radix Astragali 30g, root of kudzu vine 10g, sealwort 10g, hawthorn 10g, red sage root 10g, ginkgo leaf 10g and clean, microwave drying, pulverizing are 50 order powder;
Step (three): the powder in the step (two) is added 15 times of amount pure water soak 8.0h, heated and boiled is extracted 3.0h, filters; Filter residue is added 5 times of amount pure water heated and boiled extract 2.0h, filter, filter residue adds 3 times of amount pure water heated and boiled again and extracts 1.5h; Filter, merge No. three times extract, after filtering with flame filter press; With the smart filter of 0.45 μ m miillpore filter, must filtrate again;
Step (four): the heating of the filtrating in the step (three) is condensed into the thick medicinal extract that relative density is 1.20-1.30, adds edible alcohol in the thick medicinal extract, making spirituosity concentration is 85%; Leave standstill 24h in 4 ℃ of-6 ℃ of environment; Get supernatant, with 0.22 μ m filtering with microporous membrane, recovered under reduced pressure alcohol; Be condensed into 1000 gram weight and divide concentrate, subsequent use;
Step (five): the concentrate of doing in black garlic bulblet and the step (four) in the step () is pressed black garlic bulblet: concentrate=1:0.8 mixed also is preheated to 70 ℃-80 ℃, drops into vacuum tank, vacuumizes the processing secondary; The vacuum of finding time for the first time is 0.99Mpa, and retention time 100min slowly abolishes vacuum then; The vacuum of finding time for the second time is 0.99Mpa, and retention time 50min is after treating slowly to abolish vacuum; Continue dipping 6h, make black garlic bulblet evenly suck concentrate and be saturation state, pick up; Drain, microwave drying, making water content is 8%-10%; Earlier material is pressed into the thin slice of uniformity with the drum extruder, again cut growth 80mm, wide 40mm, thick 3mm or be cut into long 25mm, wide 25mm, thick 5mm sheet after, carry out drying again; Making water content is 3%-5%, promptly gets the black garlic sheet core material of compound medlar;
Step (six): the black garlic sheet core material of compound medlar in chocolate that will melt and the step (five); Chocolate by weight percentage: core material=60:40 sends into and is coated with the clothing make-up machine, is coated with clothing moulding, hardening by cooling through conventional method; Select, pack, get product.
Claims (3)
1. compound medlar is deceived the preparation method of garlic chocolate cream, it is characterized in that this preparation method may further comprise the steps:
Step (one): black garlic bulblet of commodity or belt leather are deceived the clean black garlic bulblet after garlic removes epidermis, and the drip pan of packing into is sent dry 120-360 minute of 55 ℃ of-65 ℃ of drying rooms of temperature control to; Measured moisture content is at 2%-4%; Take out cooling, pack, preserve subsequent use 20 ℃ of following environment temperatures with food bag;
Step (two): select high-quality fruit of Chinese wolfberry 20g-40g, Radix Astragali 10g-30g, root of kudzu vine 10g-30g, sealwort 10g-30g, hawthorn 10g-30g, red sage root 10g-20g, ginkgo leaf 10g-20g and clean, microwave drying, pulverizing are 40 orders-60 order powder;
Step (three): the powder in the step (two) is added pure water boil extraction 3 times, add 15-20 times of water gaging first and soak 7.0-8.0h, heated and boiled is extracted 2.5h-3.5h; Add for the second time 5 times of amount pure water heated and boiled and extract 1.5h-2.5h; Add 3 times of amount pure water heated and boiled for the third time and extract 1.0h-2.0h, merge extract, after filtering with flame filter press; Filtrating with the smart filter of 0.45 μ m miillpore filter, must be filtrated again;
Step (four): the heating of the filtrating in the step (three) is condensed into the thick medicinal extract that relative density is 1.20-1.30, adds edible alcohol in the thick medicinal extract, making spirituosity concentration is 75%-85%; Leave standstill 24h in 4 ℃ of-6 ℃ of environment; Get supernatant, with 0.22 μ m filtering with microporous membrane, recovered under reduced pressure alcohol; Be condensed into 1000 gram weight and divide concentrate, subsequent use;
Step (five): the concentrate of doing in black garlic bulblet and the step (four) in the step () is pressed black garlic bulblet: concentrate=1:0.5-1.0 mixed also is preheated to 70 ℃-80 ℃, drops into vacuum tank, vacuumizes the impregnation process secondary, and the vacuum of finding time for the first time is 0.98-1.02Mpa; Retention time 80-120min slowly abolishes vacuum then, and the vacuum of finding time for the second time is 0.98-1.02Mpa; Retention time 40-60min after treating slowly to abolish vacuum, continues dipping 5h-6h; Make black garlic bulblet evenly suck concentrate and be saturation state, pick up, drain; Microwave drying, making water content is 3%-5%, promptly gets the black garlic bulblet core material of compound medlar;
Step (six): the black garlic bulblet core material of compound medlar in chocolate that will melt and the step (five) press core material content 20%-80%, sends into to be coated with in the clothing make-up machine, be coated with clothing moulding, hardening by cooling after, promptly get the sub garlic chocolate cream finished product of deceiving of compound medlar.
2. compound medlar is deceived the preparation method of garlic chocolate cream, and its characteristic is that also this preparation method may further comprise the steps:
Step (one): black garlic bulblet of commodity or belt leather are deceived the clean black garlic bulblet after garlic removes epidermis, and the drip pan of packing into is sent dry 120-360 minute of 55 ℃ of-65 ℃ of drying rooms of temperature control to; Measured moisture content is at 2%-4%; Take out cooling, pack, preserve subsequent use 20 ℃ of following environment temperatures with food bag;
Step (two): select high-quality fruit of Chinese wolfberry 20g-40g, Radix Astragali 10g-30g, root of kudzu vine 10g-30g, sealwort 10g-30g, hawthorn 10g-30g, red sage root 10g-20g, ginkgo leaf 10g-20g and clean, microwave drying, pulverizing are 40 orders-60 order powder;
Step (three): the powder in the step (two) is added pure water boil extraction 3 times, add 15-20 times of water gaging first and soak 7.0-8.0h, heated and boiled is extracted 2.5h-3.5h; Add for the second time 5 times of amount pure water heated and boiled and extract 1.5h-2.5h; Add 3 times of amount pure water heated and boiled for the third time and extract 1.0h-2.0h, merge extract, after filtering with flame filter press; Filtrating with the smart filter of 0.45 μ m miillpore filter, must be filtrated again;
Step (four): the heating of the filtrating in the step (three) is condensed into the thick medicinal extract that relative density is 1.20-1.30, adds edible alcohol in the thick medicinal extract, making spirituosity concentration is 75%-85%; Leave standstill 24h in 4 ℃ of-6 ℃ of environment; Get supernatant, with 0.22 μ m filtering with microporous membrane, recovered under reduced pressure alcohol; Be condensed into 1000 gram weight and divide concentrate, subsequent use;
Step (five): the concentrate of doing in black garlic bulblet and the step (four) in the step () is pressed black garlic bulblet: concentrate=1:0.5-1.0 mixed also is preheated to 70 ℃-80 ℃, drops into vacuum tank, vacuumizes the impregnation process secondary, and the vacuum of finding time for the first time is 0.98-1.02Mpa; Retention time 80-120min slowly abolishes vacuum then, and the vacuum of finding time for the second time is 0.98-1.02Mpa, retention time 40-60min; After treating slowly to abolish vacuum, continue dipping 5h-6h, make black garlic bulblet evenly suck concentrate and be saturation state; Pick up, drain, microwave drying; Making water content is 8%-10%, with the drum extruder material is pressed into the thin slice of uniformity again, cut into different sizes and shape as required after; Carry out drying again, making water content is 3%-5%, promptly gets the black garlic slice core material of compound medlar;
Step (six): the black garlic slice core material of compound medlar in chocolate that will melt and the step (five) press sheet core material 20%-80%, sends into to be coated with in the clothing make-up machine, be coated with clothing moulding, hardening by cooling after, promptly get the sub garlic sheet chocolate cream finished product of deceiving of compound medlar.
3. according to the preparation method of claim 1, it is characterized in that, also comprise xylitol 0-30% in the concentrate material in its step (four) with the black garlic chocolate cream of 2 described a kind of compound medlar.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104126719A (en) * | 2014-07-30 | 2014-11-05 | 中国农业科学院特产研究所 | Preparation method for chocolate products with efficacy of radioresistance |
| CN105029568A (en) * | 2015-07-01 | 2015-11-11 | 天津市傲绿农副产品集团股份有限公司 | Black garlic beverage and preparation method thereof |
-
2012
- 2012-09-22 CN CN 201210354428 patent/CN102823705A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104126719A (en) * | 2014-07-30 | 2014-11-05 | 中国农业科学院特产研究所 | Preparation method for chocolate products with efficacy of radioresistance |
| CN104126719B (en) * | 2014-07-30 | 2017-01-18 | 中国农业科学院特产研究所 | Preparation method for chocolate products with efficacy of radioresistance |
| CN105029568A (en) * | 2015-07-01 | 2015-11-11 | 天津市傲绿农副产品集团股份有限公司 | Black garlic beverage and preparation method thereof |
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Application publication date: 20121219 |