CN107331697A - Gallium nitride semiconductor device and preparation method thereof - Google Patents
Gallium nitride semiconductor device and preparation method thereof Download PDFInfo
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- CN107331697A CN107331697A CN201710488978.0A CN201710488978A CN107331697A CN 107331697 A CN107331697 A CN 107331697A CN 201710488978 A CN201710488978 A CN 201710488978A CN 107331697 A CN107331697 A CN 107331697A
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- gallium nitride
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- 229910002601 GaN Inorganic materials 0.000 title claims abstract description 210
- JMASRVWKEDWRBT-UHFFFAOYSA-N Gallium nitride Chemical compound [Ga]#N JMASRVWKEDWRBT-UHFFFAOYSA-N 0.000 title claims abstract description 141
- 239000004065 semiconductor Substances 0.000 title claims abstract description 61
- 238000002360 preparation method Methods 0.000 title claims description 16
- RNQKDQAVIXDKAG-UHFFFAOYSA-N aluminum gallium Chemical compound [Al].[Ga] RNQKDQAVIXDKAG-UHFFFAOYSA-N 0.000 claims abstract description 66
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 50
- 230000004888 barrier function Effects 0.000 claims abstract description 50
- 239000000463 material Substances 0.000 claims abstract description 25
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 25
- 229910052751 metal Inorganic materials 0.000 claims description 103
- 239000002184 metal Substances 0.000 claims description 103
- 238000000151 deposition Methods 0.000 claims description 28
- 238000001312 dry etching Methods 0.000 claims description 25
- 229910045601 alloy Inorganic materials 0.000 claims description 22
- 239000000956 alloy Substances 0.000 claims description 22
- 230000008021 deposition Effects 0.000 claims description 22
- 238000005530 etching Methods 0.000 claims description 20
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 16
- 235000012239 silicon dioxide Nutrition 0.000 claims description 16
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 14
- 229910052710 silicon Inorganic materials 0.000 claims description 14
- 239000010703 silicon Substances 0.000 claims description 14
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims description 12
- 229910052733 gallium Inorganic materials 0.000 claims description 12
- WIHZLLGSGQNAGK-UHFFFAOYSA-N hafnium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Hf+4] WIHZLLGSGQNAGK-UHFFFAOYSA-N 0.000 claims description 12
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 11
- 238000001259 photo etching Methods 0.000 claims description 11
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 11
- 239000000758 substrate Substances 0.000 claims description 11
- 229910052782 aluminium Inorganic materials 0.000 claims description 10
- 239000004411 aluminium Substances 0.000 claims description 10
- 229910000449 hafnium oxide Inorganic materials 0.000 claims description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 9
- 230000015572 biosynthetic process Effects 0.000 claims description 9
- 238000000407 epitaxy Methods 0.000 claims description 5
- 229910001020 Au alloy Inorganic materials 0.000 claims description 4
- 230000008859 change Effects 0.000 claims description 4
- 229910052759 nickel Inorganic materials 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 229910003978 SiClx Inorganic materials 0.000 claims description 2
- 241000790917 Dioxys <bee> Species 0.000 claims 1
- 239000010410 layer Substances 0.000 description 230
- 238000000034 method Methods 0.000 description 40
- 239000012535 impurity Substances 0.000 description 24
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical group Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 15
- 230000008569 process Effects 0.000 description 15
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 12
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 12
- 239000010936 titanium Substances 0.000 description 12
- 229910052719 titanium Inorganic materials 0.000 description 12
- 230000015556 catabolic process Effects 0.000 description 10
- 239000011248 coating agent Substances 0.000 description 10
- 238000000576 coating method Methods 0.000 description 10
- 238000001755 magnetron sputter deposition Methods 0.000 description 10
- 239000012528 membrane Substances 0.000 description 10
- 238000004140 cleaning Methods 0.000 description 9
- 239000000126 substance Substances 0.000 description 8
- 230000005684 electric field Effects 0.000 description 7
- 239000010931 gold Substances 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 6
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 6
- 238000010586 diagram Methods 0.000 description 6
- 239000011259 mixed solution Substances 0.000 description 6
- 230000002093 peripheral effect Effects 0.000 description 6
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- 230000007797 corrosion Effects 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 4
- 229910052737 gold Inorganic materials 0.000 description 4
- CJNBYAVZURUTKZ-UHFFFAOYSA-N hafnium(iv) oxide Chemical group O=[Hf]=O CJNBYAVZURUTKZ-UHFFFAOYSA-N 0.000 description 4
- 238000005498 polishing Methods 0.000 description 4
- 230000005855 radiation Effects 0.000 description 4
- 229910017083 AlN Inorganic materials 0.000 description 3
- PIGFYZPCRLYGLF-UHFFFAOYSA-N Aluminum nitride Chemical compound [Al]#N PIGFYZPCRLYGLF-UHFFFAOYSA-N 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 238000004026 adhesive bonding Methods 0.000 description 3
- -1 aluminium copper silicon gold Chemical compound 0.000 description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 description 3
- 238000004891 communication Methods 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 238000010790 dilution Methods 0.000 description 3
- 229910001873 dinitrogen Inorganic materials 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000004070 electrodeposition Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000003628 erosive effect Effects 0.000 description 3
- 239000007792 gaseous phase Substances 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
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- 230000006378 damage Effects 0.000 description 2
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 2
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 2
- 238000002955 isolation Methods 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
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- 239000004020 conductor Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000009881 electrostatic interaction Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000002346 layers by function Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/02—Semiconductor bodies ; Multistep manufacturing processes therefor
- H01L29/06—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions
- H01L29/0603—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions characterised by particular constructional design considerations, e.g. for preventing surface leakage, for controlling electric field concentration or for internal isolations regions
- H01L29/0607—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions characterised by particular constructional design considerations, e.g. for preventing surface leakage, for controlling electric field concentration or for internal isolations regions for preventing surface leakage or controlling electric field concentration
- H01L29/0611—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions characterised by particular constructional design considerations, e.g. for preventing surface leakage, for controlling electric field concentration or for internal isolations regions for preventing surface leakage or controlling electric field concentration for increasing or controlling the breakdown voltage of reverse biased devices
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- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/02—Semiconductor bodies ; Multistep manufacturing processes therefor
- H01L29/06—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions
- H01L29/0603—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions characterised by particular constructional design considerations, e.g. for preventing surface leakage, for controlling electric field concentration or for internal isolations regions
- H01L29/0607—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions characterised by particular constructional design considerations, e.g. for preventing surface leakage, for controlling electric field concentration or for internal isolations regions for preventing surface leakage or controlling electric field concentration
- H01L29/0638—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions characterised by particular constructional design considerations, e.g. for preventing surface leakage, for controlling electric field concentration or for internal isolations regions for preventing surface leakage or controlling electric field concentration for preventing surface leakage due to surface inversion layer, e.g. with channel stopper
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- H01L29/40—Electrodes ; Multistep manufacturing processes therefor
- H01L29/402—Field plates
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- H01L29/40—Electrodes ; Multistep manufacturing processes therefor
- H01L29/41—Electrodes ; Multistep manufacturing processes therefor characterised by their shape, relative sizes or dispositions
- H01L29/417—Electrodes ; Multistep manufacturing processes therefor characterised by their shape, relative sizes or dispositions carrying the current to be rectified, amplified or switched
- H01L29/41725—Source or drain electrodes for field effect devices
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- H01L29/66446—Unipolar field-effect transistors with an active layer made of a group 13/15 material, e.g. group 13/15 velocity modulation transistor [VMT], group 13/15 negative resistance FET [NERFET]
- H01L29/66462—Unipolar field-effect transistors with an active layer made of a group 13/15 material, e.g. group 13/15 velocity modulation transistor [VMT], group 13/15 negative resistance FET [NERFET] with a heterojunction interface channel or gate, e.g. HFET, HIGFET, SISFET, HJFET, HEMT
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- H01L29/778—Field effect transistors with two-dimensional charge carrier gas channel, e.g. HEMT ; with two-dimensional charge-carrier layer formed at a heterojunction interface
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- H01L29/7783—Field effect transistors with two-dimensional charge carrier gas channel, e.g. HEMT ; with two-dimensional charge-carrier layer formed at a heterojunction interface with confinement of carriers by at least two heterojunctions, e.g. DHHEMT, quantum well HEMT, DHMODFET using III-V semiconductor material
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Abstract
Include the present invention relates to technical field of semiconductor there is provided a kind of gallium nitride semiconductor device:Epitaxial layer of gallium nitride;And, it is arranged at the dielectric layer on the epitaxial layer of gallium nitride;Source electrode, drain and gate on the dielectric layer are arranged at, the source electrode, drain and gate extend through the dielectric layer and be connected with the epitaxial layer of gallium nitride;The insulating barrier on the source electrode, drain and gate and the dielectric layer is arranged at, the material of the insulating barrier is silica.The gallium nitride semiconductor device of the present invention is less prone to the phenomenon for puncturing aluminum gallium nitride; and then the problem of avoid the electric leakage for gallium nitride semiconductor device occur and puncture; gallium nitride semiconductor device is effectively protected, the reliability of gallium nitride semiconductor device is enhanced.
Description
Technical field
The present invention relates to field of semiconductor technology, more particularly to a kind of gallium nitride semiconductor device and preparation method thereof.
Background technology
Gallium nitride have big energy gap, high electron saturation velocities, high breakdown electric field, higher heat-conductivity, it is corrosion-resistant and
The advantages of radiation resistance, so as to make semi-conducting material using gallium nitride, and obtain gallium nitride semiconductor device.
In the prior art, the preparation method of gallium nitride semiconductor device is:Nitrogen is formed on the surface of epitaxial layer of gallium nitride
SiClx layer, etches on silicon nitride layer and is deposited in source contact openings and drain contact hole, source contact openings and drain contact hole
Metal, so as to form source electrode and drain electrode;The aluminum gallium nitride in etch nitride silicon layer and epitaxial layer of gallium nitride, forms one again
Groove, in a groove deposited metal layer, so as to form grid;Then deposited silicon dioxide layer and field plate metal layer so that shape
Into gallium nitride semiconductor device.
But in the prior art, because electric field density is larger, thus can cause gallium nitride semiconductor device electric leakage and
The problem of puncturing, and then gallium nitride semiconductor device can be damaged, reduce the reliability of gallium nitride semiconductor device.Further,
Gallium nitride power device is after Hi-pot test repeatedly, and the breakdown voltage of device can drift about, this nonsteady behavior and electric charge
Trap is relevant, and the reliability to device can cause harm, it should be suppressed.
The content of the invention
To solve the above problems, the present invention provides a kind of gallium nitride semiconductor device, it is characterised in that including:Gallium nitride
Epitaxial layer;And,
The dielectric layer on the epitaxial layer of gallium nitride is arranged at, the material of the dielectric layer is hafnium oxide;
Source electrode, drain and gate on the dielectric layer are arranged at, the source electrode, drain and gate, which are extended through, to be given an account of
Matter layer is connected with the epitaxial layer of gallium nitride;The drain electrode includes the first drain electrode being connected with each other and the second drain electrode;
The insulating barrier on the source electrode, drain and gate and the dielectric layer is arranged at, the material of the insulating barrier is
Silica;
Also include the field plate metal layer being arranged on the insulating barrier, the field plate metal layer runs through the insulating barrier and institute
State source electrode connection.
There is provided a nitridation for the preparation method of the invention for also providing this gallium nitride semiconductor device with inverted trapezoidal grid
Gallium epitaxial layer, wherein, the epitaxial layer of gallium nitride includes layer-of-substrate silicon, gallium nitride layer and the aluminium nitride from bottom to top set gradually
Gallium layer;
In the epitaxy of gallium nitride layer surface deposit hafnium oxides, dielectric layer is formed;
The acquisition of p-type silicon nitride layer;In epitaxy of gallium nitride layer surface deposited silicon dioxide layer, then in the silica
The second drain contact hole is used as using dry etching formation deposition hole on layer;P-type gallium nitride layer is deposited in the deposition hole, is gone
Except the silicon dioxide layer, obtain being formed the p-type gallium nitride layer on epitaxial layer of gallium nitride;
Source contact openings, the acquisition of the first drain contact hole:The dielectric layer is etched, is connect with the source electrode for forming separate
Contact hole and the first drain contact hole, the source contact openings, first drain contact hole reach described through the dielectric layer
Aluminum gallium nitride;
In the source contact openings and first drain contact hole and on the p-type silicon nitride layer, the medium
On the surface of layer, the first metal is deposited, to obtain source electrode, the first drain electrode, the second drain electrode;
Photoetching and etching are carried out to first metal, Ohm contact electrode window is formed;Now obtain first assembly;
The high temperature anneal is carried out to the first assembly, connect with to be contained in the source contact openings and the drain electrode
First metal in contact hole forms alloy and reacted with the aluminum gallium nitride;
The acquisition in gate contact hole:By the Ohm contact electrode window, to the dielectric layer and the aluminium gallium nitride alloy
Layer carries out dry etching, forms gate contact hole, wherein, the bottom in the gate contact hole and the bottom of the aluminum gallium nitride
Between have pre-determined distance;
The second metalwork is deposited in the outward flange in the gate contact hole and the gate contact hole, to obtain grid, this
When obtain the second component;
A layer insulating is deposited on the surface of second component;
Dry etching is carried out on the insulating barrier, to form perforate, the perforate is corresponding with the source contact openings;
Field plate metal layer is deposited in the perforate and the insulating barrier, the projection of the field plate metal layer is at least covered
The perforate and from the source contact openings to the region between the gate contact hole.
Beneficial effect:
The present invention applies a variety of novel materials by the dielectric layer on the surface of epitaxial layer of gallium nitride, also passes through deposition the
One metal is carrying out the high temperature anneal, to be reacted by the first metal after the etching contacted with each other with aluminum gallium nitride
Alloy is formed afterwards, to reduce the contact resistance of the first metal and aluminum gallium nitride after etching;
This embodiment introduces first drain electrode, second drain electrode structure, i.e., first drain electrode beside introduce one additionally
P-GaN areas (the second drain electrode), p-GaN areas are connected with drain electrode.In OFF state, from p-GaN areas, injected holes is effectively released
Electronics in trap, so as to completely eliminate current collapse effect.
Brief description of the drawings
Fig. 1 a are the structural representation of the gallium nitride semiconductor device of another embodiment of the present invention.
Fig. 1 b are the preparation flow schematic diagram of the gallium nitride semiconductor device of another embodiment of the present invention.
Fig. 2 a are the structural representation of the gallium nitride semiconductor device of further embodiment of this invention.
Fig. 2 b are the preparation flow schematic diagram of the gallium nitride semiconductor device of further embodiment of this invention.
Fig. 3 a are the structural representation of the gallium nitride semiconductor device of another embodiment of the present invention.
Fig. 3 b are the grid structure schematic diagram of the gallium nitride semiconductor device of another embodiment of the present invention.
Fig. 3 c are the grid structure schematic diagram of the gallium nitride semiconductor device of another embodiment of the present invention.
Fig. 3 d are the grid structure schematic diagram of the gallium nitride semiconductor device of another embodiment of the present invention.
Fig. 3 e are the preparation flow schematic diagram of the gallium nitride semiconductor device of another embodiment of the present invention.
Embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below in conjunction with the embodiment of the present invention
In accompanying drawing, the technical scheme in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is
A part of embodiment of the present invention, rather than whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art
The every other embodiment obtained under the premise of creative work is not made, belongs to the scope of protection of the invention.
As shown in Figure 1a, the embodiment of the present invention provides a kind of gallium nitride semiconductor device, and it includes from bottom to up:Gallium nitride
Epitaxial layer 210, dielectric layer 220, source electrode 231 and drain electrode 232, grid 233, insulating barrier 240, field plate metal layer 250.
Wherein, epitaxial layer of gallium nitride 210 is by silicon (Si) substrate 212, gallium nitride (GaN) layer 213 and aluminium gallium nitride alloy (AlGaN)
Layer 214 is constituted, wherein, silicon substrate 212, gallium nitride layer 213 and aluminum gallium nitride 214 are from bottom to top set gradually.
Dielectric layer 220 is arranged on the epitaxial layer of gallium nitride 210;The material of the dielectric layer 220 of the present embodiment can example
Such as it is hafnium oxide (HfO2).The hafnium oxide belongs to a kind of high-k (high-k) medium.
Source electrode 231, drain electrode 232 and grid 233 are arranged on the dielectric layer 220.Specifically, source electrode 231, drain electrode 232
It is inserted into a part as the outer image " nail " of grid 233 in the dielectric layer 220, the source electrode 231, drain electrode 232 and grid
233 extend through the dielectric layer 220 is connected with the epitaxial layer of gallium nitride 210;And a part protrudes from the dielectric layer 220
Top.The source electrode 231 and/or drain electrode 232 are made up of the first metal;First metal composition is same as the previously described embodiments.Adopt
With the first metal material formation source electrode 231, drain electrode 232, can in higher device temperature annealing process with the epitaxy of gallium nitride
Aluminum gallium nitride layer 214 in layer 210 reacts, and generates alloy, so that source electrode 231, drain electrode 232 and aluminum gallium nitride
The contact of contact surface is good, can effectively reduce source electrode 231, drain electrode 232 and the contact resistance of aluminum gallium nitride;Avoid the occurrence of
The problem of electric leakage and soft breakdown of gallium nitride semiconductor device.
Preferably, the grid 233 is down extended into the aluminum gallium nitride 214, the bottom of grid 233 to institute
State the bottom of aluminum gallium nitride 214 is preferably the half of the whole aluminum gallium nitride 214 apart from H.Grid 233 is by the second metal
Composition, second metal is Ni, Au alloy.
Preferably, a gate dielectric layer 234 is also included between the grid 233 and the epitaxial layer of gallium nitride 210, this
The material of gate dielectric layer 234 may be, for example, silicon nitride in embodiment.
Insulating barrier 240 is arranged at drain electrode 232, grid 233 and the top of a part of source electrode 231, and exposes the whole come
On dielectric layer 220, the material of the insulating barrier 240 is silica.Wherein, insulating barrier 240 is carried out on the surface of whole device
Uniform deposition, the thickness precipitated everywhere is identical.Due to source electrode 231, drain electrode 232, the presence of grid 233, so that in source electrode 231
Insulating barrier 240 between grid 233, the insulating barrier 240 between grid 233 and drain electrode 232 are, to lower recess, to pass through
Technique is polished in subsequent step so that smooth.
It can also for example include field plate metal layer 250, it is arranged on the insulating barrier 240.The field plate metal layer 250
It is connected through the insulating barrier 240 with the source electrode 231.Preferably, the material of the field plate metal layer 250 is aluminium copper silicon gold
Belong to layer.
The present invention also provides the preparation method of above-mentioned gallium nitride semiconductor device.As shown in Figure 1 b, specific steps include:
Step 201:Gallium nitride layer 213 and aluminum gallium nitride 214 are sequentially depositing on silicon substrate 212, is formed outside gallium nitride
Prolong layer 210.Gallium nitride is third generation semiconductor material with wide forbidden band, with big energy gap, high electron saturation velocities, high breakdown potential
Characteristics such as field, higher heat-conductivity, corrosion-resistant and radiation resistance and in high pressure, high frequency, high temperature, high-power and Flouride-resistani acid phesphatase ring
There is stronger advantage, so as to be the optimal material for studying shortwave opto-electronic device and high voltagehigh frequency rate high power device under the conditions of border
Material;Wherein, big energy gap is 3.4 electron-volts, and high electron saturation velocities are 2e7 centimeters per seconds, and high breakdown electric field is 1e10
~-3e10 volts per cm.
Then chemical gaseous phase electrodeposition method can be strengthened with using plasma, is sunk on the surface of epitaxial layer of gallium nitride 110
One layer of hafnium oxide (HfO of product2), form dielectric layer 120.Wherein, the thickness of hafnium oxide for example can be 2000 angstroms.
Step 202, dry etching is carried out to the dielectric layer 120, forms the source contact openings 221 being oppositely arranged and leakage
Pole contact hole 222.
In order that the source contact openings 221, the few impurity of the cleaning of drain contact hole 222 are obtained, in addition to removal step.Specifically
, after dry etching is carried out to dielectric layer 220, it can first use " DHF (dilute hydrofluoric acid)+chemical SC-1+ization
The method for learning cleaning agent SC-2 ", for example, can be first using the hydrofluoric acid solution processing apparatus after dilution, then using peroxidating
The alkaline mixed solution processing apparatus of hydrogen and aqua ammonia, then using hydrogen peroxide and the acidic mixed solution processor of hydrogen chloride
Part, and then the impurity thing on the surface of whole device can be removed.
Step 203, in the present embodiment, it is interior and dielectric layer 220 in source contact openings 221 and drain contact hole 222
The first metal is deposited on surface.
Specifically, magnetron sputtering membrane process can be used, in source contact openings and drain contact hole and dielectric layer
Surface on, the first titanium coating, aluminum metal layer, the second titanium coating and titanium nitride layer are sequentially depositing, to form the first metal;
Wherein, the thickness of the first titanium coating may be, for example, 200 angstroms, and the thickness of aluminum metal layer may be, for example, 1200 angstroms, the second titanium
The thickness of layer may be, for example, 200 angstroms, and the thickness of titanium nitride layer may be, for example, 200 angstroms.
Photoetching and etching are carried out to the first metal, Ohm contact electrode window 219 is formed.
Carry out photoetching and etching to the first metal, the program of wherein photoetching includes gluing, exposed and developed, so as to
Form an Ohm contact electrode window 219;Through Ohm contact electrode window 219, it can be seen that the part table of dielectric layer 220
Face.In this way, the first metal on source contact openings 121 constitutes the first gold medal on the source electrode 231 of device, drain contact hole 222
Category constitutes the drain electrode 232 of device.Now, in order to be able to clear expression process of the present invention, it is first to name the device now obtained
Component.
Step 204, the high temperature anneal is carried out to whole first assembly, to pass through the first gold medal after the etching contacted with each other
Category forms alloy after being reacted with aluminum gallium nitride 214.
In the present embodiment, specifically, being passed through nitrogen gas in reacting furnace, to whole in the environment of 840~850 DEG C
First assembly carries out the high temperature anneal of 30 seconds, so that the first metal after etching can turn into alloy, and contact with each other
The first metal after etching can also also form alloy after being reacted with aluminum gallium nitride 214 on its contact surface, so that
The contact resistance between the first metal and aluminum gallium nitride 214 can be reduced.That is, reduction source electrode 231, drain electrode 232 and aluminium nitride
Contact resistance between gallium layer 214.
Step 205, by Ohm contact electrode window 219, is carried out to dielectric layer 220 and aluminum gallium nitride 214 dry method quarter
Erosion, forms gate contact hole 223, wherein, the bottom in gate contact hole 223 and the bottom of aluminum gallium nitride 214 have it is default away from
From.
In the present embodiment, using the method for dry etching, by Ohm contact electrode window 219, to dielectric layer 220 with
And partial aluminum gallium nitride 214, carry out dry etching, and then one gate contact hole 223 of formation on the first device.Its
In, gate contact hole 223 completely breaks through dielectric layer 220, and passes through the aluminum gallium nitride 214 of part so that gate contact
The bottom in hole 223 and the bottom of aluminum gallium nitride 214 be preferably apart from H aluminum gallium nitride 214 half.
In the present embodiment, formed after a gate contact hole 223, can there is impurity, particle in gate contact hole 223
And the impurity thing such as ion, will be miscellaneous in gate contact hole 220 so as to using hydrochloric acid solution cleaning gate contact hole 220
Matter thing is got rid of.
The present embodiment is by after dry etching is carried out to dielectric layer 220, using DHF+SC1+SC2 method remover
Impurity thing on part;And formed after gate contact hole 223, the impurity thing in gate contact hole 223 is gone using hydrochloric acid solution
Remove.So as to the cleaning being effectively guaranteed in the surface and gate contact hole 223 of dielectric layer, and then it ensure that nitridation
The performance of gallium semiconductor devices.
Step 206, in the present embodiment, specifically, using magnetron sputtering membrane process, being sunk in gate contact hole 223
One layer of silicon nitride layer of product, the silicon nitride layer is not higher than the gate contact hole 223;Then again on the silicon nitride layer, with
And the outward flange deposition Ni/Au in gate contact hole 223, as the second metal, metal thickness is 0.01~0.04 μm/0.08~0.4
μm;So as to constitute grid 233.So, the grid 233 is a kind of composite construction with multiple material.
Now, in order to become apparent from expressing present invention, it is the second component to name the device now obtained.
Step 207, a layer insulating 240 is deposited on the surface of whole second component.
In the present embodiment, specifically, in the surface deposition layer of silicon dioxide (SiO of whole second component2), thickness can
For example, 5000 angstroms, form silicon dioxide layer and be used as a layer insulating 240.Wherein, silica enters on the surface of whole device
Row uniform deposition, thickness is identical everywhere, due to source electrode 231, drain electrode 232 and the presence of grid 233, so that in source electrode 231 and grid
Insulating barrier 240 between pole 233, the insulating barrier 240 between grid 233 and drain electrode 232 are to lower recess, using polishing
Technique is allowed to smooth.
Step 208, after to the progress dry etching of insulating barrier 140 of the top of source contact openings 231, perforate 241 is formed.Institute
Stating grid 233 has the protuberance 233a protruded from outside the gate contact hole 223, and the width of the perforate 241 is less than described
Protuberance 233a width.
Step 209, the insulation of the top of gate contact hole 123 is extended in perforate 241 and from source contact openings 231
Field plate metal 250 is deposited on layer 240, field plate metal layer 250 is formed.
In the present embodiment, specifically, magnetron sputtering membrane process can be used, connect in perforate 241 and from source electrode
Outer peripheral first metal of contact hole 221 is until on dielectric layer 220 above outer peripheral first metal in gate contact hole 223
Field plate metal is deposited, thickness may be, for example, 10000 angstroms, so as to form field plate metal layer 250.Field plate metal layer 250 thickness be
Uniformly, field plate metal layer 250 is at the position of perforate 241 and between source contact openings 221 and gate contact hole 223
At position is, to lower recess, to be allowed to smooth using technique is polished.
The present embodiment can be with optimised devices manufacture craft, optimised devices technique compatible with CMOS technology line, improves electric conduction
Resistance.And then the problem of avoid the electric leakage for gallium nitride semiconductor device occur and puncture, be effectively protected gallium nitride and partly lead
Body device, enhances the reliability of gallium nitride semiconductor device.The gallium nitride semiconductor device that the present embodiment is obtained can be applied to
In the technical fields such as power electronic element, wave filter, radio communication element, have a good application prospect.
As shown in Figure 2 a, the embodiment of the present invention provides a kind of gallium nitride semiconductor device, and it includes from bottom to up:Gallium nitride
Epitaxial layer 910, dielectric layer 920, source electrode 931 and drain electrode 932, grid 933, insulating barrier 940.
Wherein, epitaxial layer of gallium nitride 910 is by silicon (Si) substrate 912, gallium nitride (GaN) layer 913 and aluminium gallium nitride alloy (AlGaN)
Layer 914 is constituted, wherein, silicon substrate 912, gallium nitride layer 913 and aluminum gallium nitride 914 are from bottom to top set gradually.
Dielectric layer 920 is arranged on the epitaxial layer of gallium nitride 910;The material of the dielectric layer 920 of the present embodiment can example
Such as it is hafnium oxide (HfO2).The hafnium oxide belongs to a kind of high-k (high-k) medium.
Source electrode 931, drain electrode 932 and grid 933 are arranged on the dielectric layer 920.Specifically, source electrode 931, drain electrode 932
It is inserted into a part as the outer image " nail " of grid 933 in the dielectric layer 920, the source electrode 931, drain electrode 932 and grid
933 extend through the dielectric layer 920 is connected with the epitaxial layer of gallium nitride 910;And a part protrudes from the dielectric layer 920
Top.Further, as shown in Figure 2 a, the drain electrode 932 includes:The first drain electrode 932a being connected with each other and the second drain electrode
932b, it is described.The source electrode 931 and first drain electrode 932 by the first metal constitute and above-described embodiment shown in.Using the first metal
Material formation source electrode 931, drain electrode 932, can in higher device temperature annealing process with the epitaxial layer of gallium nitride 910
Aluminum gallium nitride layer 914 reacts, and generates alloy, so that source electrode 931, drain electrode 932 and the contact surface of aluminum gallium nitride
Contact is good, can effectively reduce source electrode 931, drain electrode 932 and the contact resistance of aluminum gallium nitride;Avoid the occurrence of gallium nitride half
The problem of electric leakage and soft breakdown of conductor device.Second drain electrode 932b is by gallium nitride layer 935, two kinds of functional layers of the first metal
Constitute.
This hole for making drain electrode form in p-type gallium nitride layer, p-type gallium nitride layer of designing can be combined with electronics,
So as to eliminate electronics, and then prevent when draining into horizontal high voltage and then produce the phenomenon of current collapse, the electricity prevented
The phenomenon of stream avalanche can damage gallium nitride semiconductor device, enhance the reliability of gallium nitride semiconductor device.
T-shape is presented in the section of grid 933 of the present embodiment, and the grid 933 can down extend into the aluminium gallium nitride alloy
In layer 914, the bottom of grid 933 to the bottom of aluminum gallium nitride 914 is preferably the whole aluminum gallium nitride apart from H
914 half.Whole grid 933 is made up of the second metal, and second metal is Ni, Au alloy.
Insulating barrier 940 is arranged at drain electrode 932, grid 933 and the top of a part of source electrode 931, and exposes the whole come
On dielectric layer 920, the material of the insulating barrier 940 is silica.Wherein, insulating barrier 940 is carried out on the surface of whole device
Uniform deposition, the thickness precipitated everywhere is identical.Due to source electrode 931, drain electrode 932, the presence of grid 933, so that in source electrode 931
Insulating barrier 940 between grid 933, the insulating barrier 940 between grid 933 and drain electrode 932 be to lower recess, can profit
It is allowed to smooth with technique is polished.
It can also for example include field plate metal layer 950, it is arranged on the insulating barrier 940.The field plate metal layer 950
It is connected through the insulating barrier 940 with the source electrode 931.Preferably, the material of the field plate metal layer 950 is aluminium copper silicon gold
Belong to layer.
The present invention also provides the preparation method of above-mentioned gallium nitride semiconductor device.As shown in Figure 2 b, specific steps include:
Step 901:Gallium nitride layer 913 and aluminum gallium nitride 914 are sequentially depositing on silicon substrate 912, is formed outside gallium nitride
Prolong layer 910.Gallium nitride is third generation semiconductor material with wide forbidden band, with big energy gap, high electron saturation velocities, high breakdown potential
Characteristics such as field, higher heat-conductivity, corrosion-resistant and radiation resistance and in high pressure, high frequency, high temperature, high-power and Flouride-resistani acid phesphatase ring
There is stronger advantage, so as to be the optimal material for studying shortwave opto-electronic device and high voltagehigh frequency rate high power device under the conditions of border
Material;Wherein, big energy gap is 3.4 electron-volts, and high electron saturation velocities are 2e7 centimeters per seconds, and high breakdown electric field is 1e10
~-3e10 volts per cm.
Step 902, p-type gallium nitride layer 935 is then deposited on the epitaxial layer of gallium nitride 910.Specifically, in gallium nitride
The surface of epitaxial layer 910 deposits a silicon dioxide layer, is then made in the silicon dioxide layer using dry etching formation deposition hole
For the second drain contact hole 922b;P-type gallium nitride layer is deposited in the deposition hole, the silicon dioxide layer is removed, obtains shape
Into the p-type gallium nitride layer 935 on epitaxial layer of gallium nitride 910.
903, then chemical gaseous phase electrodeposition method can be strengthened with using plasma, in epitaxial layer of gallium nitride 910, p-type nitrogen
Change and one layer of hafnium oxide (HfO is deposited on the surface of gallium layer2), form dielectric layer 920.Wherein, the thickness of hafnium oxide for example can be
2000 angstroms, its thickness needs the thickness more than the p-type gallium nitride layer 935.
Step 904:Dry etching is carried out to the dielectric layer 920, the source contact openings 921 that are oppositely arranged and the is formed
One drain contact hole 922a;The p-type gallium nitride layer 935 is located between the drain contact hole 922a of source contact openings 921 and first,
Deposition hole is opened up in the top of p-type gallium nitride layer 935 corresponding to former second drain contact hole 922b position again.
Step 9041, magnetron sputtering membrane process then can be used, in the drain contact hole of source contact openings 921 and first
In 922a and on the top of p-type gallium nitride layer 935, the surface of dielectric layer 920, the first titanium coating, aluminum metal are sequentially depositing
Layer, the second titanium coating and titanium nitride layer, to form the first metal;Wherein, the thickness of the first titanium coating may be, for example, 200
Angstrom, the thickness of aluminum metal layer may be, for example, 1200 angstroms, and the thickness of the second titanium coating may be, for example, 200 angstroms, the thickness of titanium nitride layer
Degree may be, for example, 200 angstroms.It is derived from the drain electrodes of drain electrode 932a and second of source electrode 931, first 932b.
In order that the source contact openings 921, drain contact hole, the few impurity of cleaning are obtained, in addition to removal step.Specifically
, after dry etching is carried out to dielectric layer 920, it can first use " DHF (dilute hydrofluoric acid)+chemical SC-1+
Chemical SC-2 " method, for example, can be first using the hydrofluoric acid solution processing apparatus after dilution, then using peroxide
Change the alkaline mixed solution processing apparatus of hydrogen and aqua ammonia, then handled using the acidic mixed solution of hydrogen peroxide and hydrogen chloride
Device, and then the impurity thing on the surface of whole device can be removed.
Photoetching and etching are carried out to the first metal, Ohm contact electrode window 919 is formed.
Carry out photoetching and etching to the first metal, the program of wherein photoetching includes gluing, exposed and developed, so as to
Form an Ohm contact electrode window 919;Through Ohm contact electrode window 919, it can be seen that the part table of dielectric layer 920
Face.In this way, the first metal on source contact openings 921 constitutes the first gold medal on the source electrode 931 of device, drain contact hole 922
Category constitutes the drain electrode 932 of device.Now, in order to be able to clear expression process of the present invention, it is first to name the device now obtained
Component.
Step 905, the high temperature anneal is carried out to whole first assembly, to pass through the first gold medal after the etching contacted with each other
Category forms alloy after being reacted with aluminum gallium nitride 914.
In the present embodiment, specifically, being passed through nitrogen gas in reacting furnace, to whole in the environment of 840~850 DEG C
First assembly carries out the high temperature anneal of 30 seconds, so that the first metal after etching can turn into alloy, and contact with each other
The first metal after etching can also also form alloy after being reacted with aluminum gallium nitride 914 on its contact surface, so that
The contact resistance between the first metal and aluminum gallium nitride 914 can be reduced.That is, reduction source electrode 931, drain electrode 932 and aluminium nitride
Contact resistance between gallium layer 914.
Step 906, by Ohm contact electrode window 919, is carried out to dielectric layer 920 and aluminum gallium nitride 914 dry method quarter
Erosion, forms gate contact hole 923, wherein, the bottom in gate contact hole 923 and the bottom of aluminum gallium nitride 914 have it is default away from
From.
In the present embodiment, using the method for dry etching, by Ohm contact electrode window 919, to dielectric layer 920 with
And partial aluminum gallium nitride 914, carry out dry etching, and then one gate contact hole 923 of formation on the first device.Its
In, gate contact hole 923 completely breaks through dielectric layer 920, and passes through the aluminum gallium nitride 914 of part so that gate contact
The bottom in hole 923 and the bottom of aluminum gallium nitride 914 be preferably apart from H aluminum gallium nitride 914 half.Further, carve
Cause gate contact hole 923 is presented one wide at the top and narrow at the bottom, inverted trapezoidal during erosion.In the present embodiment, a grid is formed to connect
After contact hole 923, there can be the impurity things such as impurity, particle and ion in gate contact hole 923, so as to molten using hydrochloric acid
Liquid cleaning gate contact hole 920, the impurity thing in gate contact hole 920 is got rid of.
The present embodiment is by after dry etching is carried out to dielectric layer 920, using DHF+SC1+SC2 method remover
Impurity thing on part;And formed after gate contact hole 923, the impurity thing in gate contact hole 923 is gone using hydrochloric acid solution
Remove.So as to the cleaning being effectively guaranteed in the surface and gate contact hole 923 of dielectric layer, and then it ensure that nitridation
The performance of gallium semiconductor devices.
Step 907, in the present embodiment, specifically, using magnetron sputtering membrane process, in gate contact hole 923 and grid
The outward flange deposition Ni/Au of pole contact hole 923 is as the second metal, and metal thickness is 0.01~0.04 μm/0.08~0.4 μm;
So as to constitute grid 933.Now, in order to become apparent from expressing present invention, it is the second component to name the device now obtained.
Step 908, a layer insulating 940 is deposited on the surface of whole second component.
In the present embodiment, specifically, in the surface deposition layer of silicon dioxide (SiO of whole second component2), thickness can
For example, 5000 angstroms, form silicon dioxide layer and be used as a layer insulating 940.Wherein, silica enters on the surface of whole device
Row uniform deposition, thickness is identical everywhere, due to source electrode 931, drain electrode 932 and the presence of grid 933, so that in source electrode 931 and grid
Insulating barrier 940 between pole 933, the insulating barrier 940 between grid 933 and drain electrode 932 are to lower recess, using polishing
Technique is allowed to smooth.
Step 909, after to the progress dry etching of insulating barrier 940 of the top of source contact openings 931, perforate 941 is formed.Institute
Stating grid 933 has the protuberance 933a protruded from outside the gate contact hole 923, and the width of the perforate 941 is less than described
Protuberance 933a width.
Step 9010, the exhausted of the top of gate contact hole 923 is extended in perforate 941 and from source contact openings 931
Field plate metal 950 is deposited in edge layer 940, field plate metal layer 950 is formed.
In the present embodiment, specifically, magnetron sputtering membrane process can be used, connect in perforate 941 and from source electrode
Outer peripheral first metal of contact hole 921 is until on dielectric layer 920 above outer peripheral first metal in gate contact hole 923
Field plate metal is deposited, thickness may be, for example, 10000 angstroms, so as to form field plate metal layer 950.Field plate metal layer 950 thickness be
Uniformly, field plate metal layer 950 is at the position of perforate 941 and between source contact openings 921 and gate contact hole 923
At position is, to lower recess, to pass through polishing technique and can be allowed to smooth in subsequent step.
This embodiment introduces first drain electrode, second drain electrode structure, i.e., first drain electrode beside introduce one additionally
P-GaN areas (the second drain electrode), p-GaN areas are connected with drain electrode.In OFF state, from p-GaN areas, injected holes is effectively released
Electronics in trap, so as to completely eliminate current collapse effect.The gallium nitride semiconductor device that the present embodiment is obtained can be applied
In the technical fields such as power electronic element, wave filter, radio communication element, have a good application prospect.
As shown in Figure 3 a, the embodiment of the present invention provides a kind of gallium nitride semiconductor device, and it includes from bottom to up:Gallium nitride
Epitaxial layer 1010, dielectric layer 1020, source electrode 1031 and drain electrode 1032, grid 1033, insulating barrier 1040, field plate metal layer 1050,
Protective layer 1060.
Wherein, epitaxial layer of gallium nitride 1010 is by silicon (Si) substrate 1012, gallium nitride (GaN) layer 1013 and aluminium gallium nitride alloy
(AlGaN) layer 1014 is constituted, wherein, silicon substrate 1012, gallium nitride layer 1013 and aluminum gallium nitride 1014 are from bottom to top set successively
Put.
Dielectric layer 1020 is arranged on the epitaxial layer of gallium nitride 1010;The material of the dielectric layer 1020 of the present embodiment
May be, for example, hafnium oxide (HfO2).The hafnium oxide belongs to a kind of high-k (high-k) medium.
Source electrode 1031, drain electrode 1032 and grid 1033 are arranged on the dielectric layer 1020.Specifically, source electrode 1031, leakage
A part as pole 1032 and the outer image " nail " of grid 1033 is inserted into the dielectric layer 1020, the source electrode 1031, drain electrode
1032 and grid 1033 extend through the dielectric layer 1020 and be connected with the epitaxial layer of gallium nitride 1010;And a part is protruded from
The top of dielectric layer 1020.The source electrode 1031 and/or drain electrode 1032 are made up of the first metal;The group of first metal
Part is referring to shown in above-described embodiment.Using the source electrode 1031 of the first metal material formation, drain electrode 1032, it can be moved back in higher device temperature
Reacted during fire with the aluminum gallium nitride layer 1014 in the epitaxial layer of gallium nitride 1010, alloy is generated, so that source
Pole 1031,1032 contacts with the contact surface of aluminum gallium nitride of drain electrode are good, can effectively reduce source electrode 1031, drain electrode
1032 with the contact resistance of aluminum gallium nitride;The problem of avoiding the occurrence of the electric leakage and soft breakdown of gallium nitride semiconductor device.
Preferably, the grid 1033 is down extended into the aluminum gallium nitride 1014, and the bottom of grid 1033 is arrived
The bottom of aluminum gallium nitride 1014 be preferably apart from H the whole aluminum gallium nitride 1014 half.Grid 1033 is by
Two metals are constituted, and second metal is Ni, Au alloy.
Preferably, the grid 1033 has special configuration.With reference to shown in Fig. 3 b, Fig. 3 c and Fig. 3 d, the present embodiment
Grid 1033 can also have various deformation.Seen according to the observation sequence of gallium nitride semiconductor device from bottom to up, grid 1033
Transverse width gradually increases, and one " upside-down trapezoid " is presented.Further, the part of " upside-down trapezoid " of grid 1033 can be from
Just the shape (as shown in Figure 3 b) uniformly broadened from bottom to up is presented in gate contact hole 1023, has being higher by dielectric layer 1020
There is protuberance 1033a then to increase width suddenly so that gate contact hole 1023 is completely covered;Or can be in aluminum gallium nitride
The part of grid 1033 in 1014 still keeps rectangular configuration, in aluminum gallium nitride 1014 with the up to top of gate contact hole 1014
Part then uniformly broadens (as shown in Figure 3 c) from bottom to up;It can also be that composition can be just presented from gate contact hole 1023
The shape (as shown in Figure 3 d) uniformly broadened from bottom to up, being higher by the protuberance 1033a of dielectric layer 1020, then width keeps constant,
Only increase thickness.
Insulating barrier 1040 is arranged at drain electrode 1032, grid 1033 and the top of a part of source electrode 1031, and exposes what is come
On whole dielectric layers 1020, the material of the insulating barrier 1040 is silica.Wherein, table of the insulating barrier 1040 in whole device
Face carries out uniform deposition, and the thickness precipitated everywhere is identical.Due to source electrode 1031, drain electrode 1032, the presence of grid 1033, so that
Insulating barrier 1040 between source electrode 1031 and grid 1033, the insulating barrier 1040 between grid 1033 and drain electrode 1032 are downward
Depression, it is allowed to smooth using technique is polished.
It can also for example include field plate metal layer 1050, it is arranged on the insulating barrier 1040.The field plate metal layer
1050 are connected through the insulating barrier 1040 with the source electrode 1031.Preferably, the material of the field plate metal layer 1050 is aluminium
Copper silicon metal level.
Also include matcoveredn 1060, specifically, in field plate metal layer 1050, and the table of the insulating barrier 1040
There is a protective layer 1060 in face, also deposition.The protective layer 1060 includes Si setting up and down3N4Passivation layer and PETEOS oxide layers.
After the structure for increasing protective layer, impurity absorption and electrostatic can be reduced with impurity electrostatic in air-isolation and coarse sheath surface
Effect, reduces surface leakage, so that it is pressure-resistant to improve device.
The section of grid 1033 in above-mentioned gallium nitride semiconductor device is different from " T-shaped " structure of existing grid, but
" trapezoidal " construction of inversion wide at the top and narrow at the bottom is presented, the high electric field at suppressor grid edge is effectively guaranteed gallium nitride high tension apparatus
Stable blocking characteristics, make device after high pressure repeatedly, still can keep good reliability.
The present invention also provides the preparation method of above-mentioned gallium nitride semiconductor device.As shown in Figure 3 e, specific steps include:
Step 1001:Gallium nitride layer 1013 and aluminum gallium nitride 1014 are sequentially depositing on silicon substrate 1012, nitridation is formed
Gallium epitaxial layer 110.Gallium nitride is third generation semiconductor material with wide forbidden band, with big energy gap, high electron saturation velocities, high strike
Wear the characteristics such as electric field, higher heat-conductivity, corrosion-resistant and radiation resistance and in high pressure, high frequency, high temperature, high-power and anti-spoke
According to having stronger advantage under environmental condition, so as to be to study shortwave opto-electronic device and high voltagehigh frequency rate high power device most
Good material;Wherein, big energy gap is 3.4 electron-volts, and high electron saturation velocities are 2e7 centimeters per seconds, and high breakdown electric field is
1e10~-3e10 volts per cm.
Then chemical gaseous phase electrodeposition method can be strengthened with using plasma, is sunk on the surface of epitaxial layer of gallium nitride 110
One layer of hafnium oxide (HfO2) of product, forms dielectric layer 1020.Wherein, the thickness of hafnium oxide for example can be 2000 angstroms.
Step 1002, dry etching is carried out to the dielectric layer 1020, forms the source contact openings 21 being oppositely arranged and leakage
Pole contact hole 1022.
In order that the source contact openings 1021, the few impurity of the cleaning of drain contact hole 1022 are obtained, in addition to removal step.Tool
Body, after dry etching is carried out to dielectric layer 1020, it can first use " DHF (dilute hydrofluoric acid)+chemical SC-1
+ chemical SC-2 " method, for example, can be first using the hydrofluoric acid solution processing apparatus after dilution, then using peroxide
Change the alkaline mixed solution processing apparatus of hydrogen and aqua ammonia, then handled using the acidic mixed solution of hydrogen peroxide and hydrogen chloride
Device, and then the impurity thing on the surface of whole device can be removed.
Step 1003, in the present embodiment, in source contact openings 1021 and drain contact hole 1022 and dielectric layer
The first metal 1021 is deposited on 1020 surface.
Specifically, magnetron sputtering membrane process can be used, in source contact openings and drain contact hole and dielectric layer
Surface on, the first titanium coating, aluminum metal layer, the second titanium coating and titanium nitride layer are sequentially depositing, to form the first metal;
Wherein, the thickness of the first titanium coating may be, for example, 200 angstroms, and the thickness of aluminum metal layer may be, for example, 10200 angstroms, the second titanium
The thickness of layer may be, for example, 200 angstroms, and the thickness of titanium nitride layer may be, for example, 200 angstroms.
Photoetching and etching are carried out to the first metal, Ohm contact electrode window 1019 is formed.
Carry out photoetching and etching to the first metal, the program of wherein photoetching includes gluing, exposed and developed, so as to
Form an Ohm contact electrode window 1019;Through Ohm contact electrode window 1019, it can be seen that the portion of dielectric layer 1020
Divide surface.In this way, the first metal on source contact openings 1021 is constituted on the source electrode 1031 of device, drain contact hole 1022
First metal constitutes the drain electrode 1032 of device.Now, in order to be able to clear expression process of the present invention, the device now obtained is named
For first assembly.
Step 1004, the high temperature anneal is carried out to whole first assembly, to pass through first after the etching contacted with each other
Metal forms alloy after being reacted with aluminum gallium nitride 1014.
In the present embodiment, specifically, being passed through nitrogen gas in reacting furnace, to whole in the environment of 840~850 DEG C
First assembly carries out the high temperature anneal of 30 seconds, so that the first metal after etching can turn into alloy, and contact with each other
The first metal after etching can also also form alloy after being reacted with aluminum gallium nitride 1014 on its contact surface, so that
The contact resistance between the first metal and aluminum gallium nitride 1014 can be reduced.That is, reduction source electrode 1031, drain electrode 1032 and nitridation
Contact resistance between gallium aluminium layer 14.
Step 1005, by Ohm contact electrode window 1019, dielectric layer 1020 and aluminum gallium nitride 1014 are done
Method is etched, and forms gate contact hole 1023, wherein, the bottom and the bottom of aluminum gallium nitride 1014 in gate contact hole 1023 have
Pre-determined distance.
In the present embodiment, using the method for dry etching, by Ohm contact electrode window 1019, to dielectric layer 1020
And partial aluminum gallium nitride 1014, carry out dry etching, and then one gate contact hole 1023 of formation on the first device.
Wherein, gate contact hole 1023 is complete breaks through dielectric layer 1020, and passes through the aluminum gallium nitride 1014 of part so that grid
The bottom of contact hole 1023 and the bottom of aluminum gallium nitride 1014 be preferably apart from H aluminum gallium nitride 1014 half.Enter one
Step ground, causes gate contact hole 1023 is presented one wide at the top and narrow at the bottom, inverted trapezoidal during etching.In the present embodiment, one is formed
After individual gate contact hole 1023, there can be the impurity things such as impurity, particle and ion in gate contact hole 1023, so as to
Using hydrochloric acid solution cleaning gate contact hole 1020, the impurity thing in gate contact hole 1020 is got rid of.
The present embodiment using DHF+SC1+SC2 method by after dry etching is carried out to dielectric layer 1020, being removed
Impurity thing on device;And formed after gate contact hole 1023, using hydrochloric acid solution by the impurity in gate contact hole 1023
Thing is got rid of.So as to the cleaning being effectively guaranteed in the surface and gate contact hole 1023 of dielectric layer, and then ensure
The performance of gallium nitride semiconductor device.
Step 1006, in the present embodiment, specifically, using magnetron sputtering membrane process, in the He of gate contact hole 1023
The outward flange deposition Ni/Au in gate contact hole 1023 is as the second metal, and metal thickness is 0.01~0.04 μm/0.08~0.4
μm;So as to constitute grid 1033.Now, in order to become apparent from expressing present invention, it is second to name the device now obtained
Component.
Step 1007, a layer insulating 1040 is deposited on the surface of whole second component.
In the present embodiment, specifically, in the surface deposition layer of silicon dioxide (SiO2) of whole second component, thickness can
For example, 5000 angstroms, form silicon dioxide layer and be used as a layer insulating 1040.Wherein, silica enters on the surface of whole device
Row uniform deposition, thickness is identical everywhere, due to source electrode 1031, drain electrode 1032 and the presence of grid 1033, so that in source electrode 1031
Insulating barrier 1040 between grid 1033, the insulating barrier 1040 between grid 1033 and drain electrode 1032 be to lower recess,
It is allowed to smooth using technique is polished.
Step 1008, after to the progress dry etching of insulating barrier 1040 of the top of source contact openings 1031, perforate is formed
1041.The grid 1033 has the protuberance 1033a protruded from outside the gate contact hole 1023, the width of the perforate 1041
Width of the degree less than the protuberance 1033a.
Step 1009, the top of gate contact hole 1023 is extended in perforate 1041 and from source contact openings 1031
Field plate metal 1050 is deposited on insulating barrier 1040, field plate metal layer 1050 is formed.
In the present embodiment, specifically, magnetron sputtering membrane process can be used, in the perforate 1041 and from source electrode
Dielectric layer of outer peripheral first metal of contact hole 1021 above outer peripheral first metal in gate contact hole 1023
Field plate metal is deposited on 1020, thickness may be, for example, 10000 angstroms, so as to form field plate metal layer 1050.Field plate metal layer 1050
Thickness be uniform, field plate metal layer 1050 is at the position of perforate 1041 and source contact openings 1021 and gate contact
At position between hole 1023 is, to lower recess, to pass through polishing technique and can be allowed to smooth in subsequent step.
Step 1010, using magnetron sputtering membrane process field plate metal layer 1050, the surface of insulating barrier 1040 according to
One silicon nitride layer of secondary deposition and PETEOS oxide layers.
After the structure of the present embodiment increase protective layer, it can be subtracted with impurity electrostatic in air-isolation and coarse sheath surface
Few impurity absorption and electrostatic interaction, reduce surface leakage, so that it is pressure-resistant to improve device.The gallium nitride semiconductor that the present embodiment is obtained
Device can be applied in the technical fields such as power electronic element, wave filter, radio communication element, before good application
Scape.
Finally it should be noted that:The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations;Although
The present invention is described in detail with reference to the foregoing embodiments, it will be understood by those within the art that:It still may be used
To be modified to the technical scheme described in foregoing embodiments, or equivalent substitution is carried out to which part technical characteristic;
And these modification or replace, do not make appropriate technical solution essence depart from various embodiments of the present invention technical scheme spirit and
Scope.
Claims (10)
1. a kind of gallium nitride semiconductor device, it is characterised in that including:Epitaxial layer of gallium nitride;And,
The dielectric layer on the epitaxial layer of gallium nitride is arranged at, the dielectric layer material is hafnium oxide;
Source electrode, drain and gate on the dielectric layer are arranged at, the source electrode, drain electrode, grid extend through the dielectric layer
It is connected with the epitaxial layer of gallium nitride;Wherein, the drain electrode includes the first drain electrode being connected with each other and the second drain electrode;
The insulating barrier on the source electrode, drain and gate and the dielectric layer is arranged at, the material of the insulating barrier is dioxy
SiClx;
Also include the field plate metal layer being arranged on the insulating barrier, the field plate metal layer is through the insulating barrier and the source
Pole is connected.
2. gallium nitride semiconductor device according to claim 1, it is characterised in that the epitaxial layer of gallium nitride includes silicon lining
Bottom, and be arranged at the gallium nitride layer of the surface of silicon, be arranged at the aluminum gallium nitride on the gallium nitride layer surface.
3. gallium nitride semiconductor device according to claim 2, it is characterised in that second drain electrode includes and the nitridation
The p-type silicon nitride layer of gallium aluminium layer connection.
4. gallium nitride semiconductor device according to claim 2, it is characterised in that the gate bottom to the aluminium gallium nitride alloy
The distance of layer bottom is the half of the aluminum gallium nitride.
5. according to the gallium nitride semiconductor device of claim 1 or 2 or 3 or described, it is characterised in that the thickness of the dielectric layer is
2000 angstroms.
6. a kind of preparation method of gallium nitride semiconductor device, it is characterised in that comprise the following steps:
One epitaxial layer of gallium nitride is provided, wherein, the epitaxial layer of gallium nitride includes layer-of-substrate silicon, the nitrogen from bottom to top set gradually
Change gallium layer and aluminum gallium nitride;
In the epitaxy of gallium nitride layer surface deposit hafnium oxides, dielectric layer is formed;
The acquisition of p-type silicon nitride layer;In epitaxy of gallium nitride layer surface deposited silicon dioxide layer, then in the silicon dioxide layer
Second drain contact hole is used as using dry etching formation deposition hole;P-type gallium nitride layer is deposited in the deposition hole, institute is removed
Silicon dioxide layer is stated, obtains being formed the p-type gallium nitride layer on epitaxial layer of gallium nitride;
Source contact openings, the acquisition of the first drain contact hole:The dielectric layer is etched, to form separate source contact openings
With the first drain contact hole, the source contact openings, first drain contact hole reach the nitridation through the dielectric layer
Gallium aluminium layer;
In the source contact openings and first drain contact hole and on the p-type silicon nitride layer, the dielectric layer
On surface, the first metal is deposited, to obtain source electrode, the first drain electrode, the second drain electrode;
Photoetching and etching are carried out to first metal, Ohm contact electrode window is formed;Now obtain first assembly;
The high temperature anneal is carried out to the first assembly, to be contained in the source contact openings and the drain contact hole
Interior first metal forms alloy and reacted with the aluminum gallium nitride;
The acquisition in gate contact hole:By the Ohm contact electrode window, the dielectric layer and the aluminum gallium nitride are entered
Row dry etching, forms gate contact hole, wherein, the gate contact hole is through the dielectric layer and stretches into the aluminium gallium nitride alloy
In layer;
The second metalwork is deposited in the outward flange in the gate contact hole and the gate contact hole, to obtain grid, is now obtained
Obtain the second component;
A layer insulating is deposited on the surface of second component;
Dry etching is carried out on the insulating barrier, to form perforate, the perforate is corresponding with the source contact openings;
Field plate metal layer is deposited in the perforate and the insulating barrier, the projection of the field plate metal layer at least covers described
Perforate and from the source contact openings to the region between the gate contact hole.
7. the preparation method of gallium nitride semiconductor device according to claim 6, it is characterised in that the width of the perforate is small
The protuberance width above the gate contact hole is protruded from the grid.
8. the preparation method of gallium nitride semiconductor device according to claim 6, it is characterised in that the high temperature anneal
Step is:Under protection atmosphere, kept for 30~60 seconds at a temperature of 840~850 DEG C.
9. the preparation method of gallium nitride semiconductor device according to claim 6, it is characterised in that the gate bottom to institute
The distance for stating aluminum gallium nitride bottom is the half of the aluminum gallium nitride.
10. the preparation method of gallium nitride semiconductor device according to claim 6, it is characterised in that the grid is by second
Metal is constituted, and second metal is Ni, Au alloy.
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WO2018233660A1 (en) * | 2017-06-23 | 2018-12-27 | 深圳市晶相技术有限公司 | Gallium nitride semiconductor device and manufacturing method thereof |
CN112038336A (en) * | 2020-06-15 | 2020-12-04 | 厦门市三安集成电路有限公司 | Nitride device, ESD protection structure thereof and manufacturing method |
WO2021189182A1 (en) * | 2020-03-23 | 2021-09-30 | 英诺赛科(珠海)科技有限公司 | Semiconductor device and manufacturing method therefor |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20130175537A1 (en) * | 2012-01-10 | 2013-07-11 | National Chiao Tung University | HIGH ELECTRON MOBILITY GaN-BASED TRANSISTOR STRUCTURE |
CN104934476A (en) * | 2014-03-19 | 2015-09-23 | 株式会社东芝 | Semiconductor device and manufacturing method for the same |
CN105720097A (en) * | 2016-04-28 | 2016-06-29 | 中国科学院半导体研究所 | Enhanced-mode high electron mobility transistor, preparation method thereof, and semiconductor device |
CN106601809A (en) * | 2015-10-15 | 2017-04-26 | 北京大学 | Gallium-nitride field effect transistor and manufacturing method therefor |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8624296B1 (en) * | 2012-08-09 | 2014-01-07 | Taiwan Semiconductor Manufacturing Company, Ltd. | High electron mobility transistor including an embedded flourine region |
JP6276150B2 (en) * | 2014-09-16 | 2018-02-07 | 株式会社東芝 | Semiconductor device |
CN107331697A (en) * | 2017-06-23 | 2017-11-07 | 深圳市晶相技术有限公司 | Gallium nitride semiconductor device and preparation method thereof |
-
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Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20130175537A1 (en) * | 2012-01-10 | 2013-07-11 | National Chiao Tung University | HIGH ELECTRON MOBILITY GaN-BASED TRANSISTOR STRUCTURE |
CN104934476A (en) * | 2014-03-19 | 2015-09-23 | 株式会社东芝 | Semiconductor device and manufacturing method for the same |
CN106601809A (en) * | 2015-10-15 | 2017-04-26 | 北京大学 | Gallium-nitride field effect transistor and manufacturing method therefor |
CN105720097A (en) * | 2016-04-28 | 2016-06-29 | 中国科学院半导体研究所 | Enhanced-mode high electron mobility transistor, preparation method thereof, and semiconductor device |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2018233660A1 (en) * | 2017-06-23 | 2018-12-27 | 深圳市晶相技术有限公司 | Gallium nitride semiconductor device and manufacturing method thereof |
WO2021189182A1 (en) * | 2020-03-23 | 2021-09-30 | 英诺赛科(珠海)科技有限公司 | Semiconductor device and manufacturing method therefor |
US11502170B2 (en) | 2020-03-23 | 2022-11-15 | Innoscience (Zhuhai) Technology Co., Ltd. | Semiconductor device and manufacturing method thereof |
CN112038336A (en) * | 2020-06-15 | 2020-12-04 | 厦门市三安集成电路有限公司 | Nitride device, ESD protection structure thereof and manufacturing method |
CN112038336B (en) * | 2020-06-15 | 2023-03-24 | 湖南三安半导体有限责任公司 | Nitride device, ESD protection structure thereof and manufacturing method |
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