CN107312601A - 一种用于机械设备的润滑油的制备方法 - Google Patents
一种用于机械设备的润滑油的制备方法 Download PDFInfo
- Publication number
- CN107312601A CN107312601A CN201710563736.3A CN201710563736A CN107312601A CN 107312601 A CN107312601 A CN 107312601A CN 201710563736 A CN201710563736 A CN 201710563736A CN 107312601 A CN107312601 A CN 107312601A
- Authority
- CN
- China
- Prior art keywords
- parts
- lubricating oil
- mercaptan
- preparation
- plant equipment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000010687 lubricating oil Substances 0.000 title claims abstract description 35
- 238000002360 preparation method Methods 0.000 title claims abstract description 25
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical class [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000000203 mixture Substances 0.000 claims abstract description 25
- 239000007866 anti-wear additive Substances 0.000 claims abstract description 13
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 13
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 13
- 239000013556 antirust agent Substances 0.000 claims abstract description 13
- 239000002199 base oil Substances 0.000 claims abstract description 13
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 9
- 230000000994 depressogenic effect Effects 0.000 claims abstract description 9
- 239000002270 dispersing agent Substances 0.000 claims abstract description 9
- 239000003208 petroleum Substances 0.000 claims abstract description 7
- 239000003755 preservative agent Substances 0.000 claims abstract description 7
- 230000002335 preservative effect Effects 0.000 claims abstract description 7
- -1 n-amylmercaptane Chemical compound 0.000 claims description 29
- 238000002156 mixing Methods 0.000 claims description 23
- 241000196324 Embryophyta Species 0.000 claims description 18
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 9
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 8
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims description 8
- 239000004166 Lanolin Substances 0.000 claims description 8
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 8
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 8
- WQAQPCDUOCURKW-UHFFFAOYSA-N butanethiol Chemical compound CCCCS WQAQPCDUOCURKW-UHFFFAOYSA-N 0.000 claims description 8
- 239000008367 deionised water Substances 0.000 claims description 8
- 229910021641 deionized water Inorganic materials 0.000 claims description 8
- GVPWHKZIJBODOX-UHFFFAOYSA-N dibenzyl disulfide Chemical compound C=1C=CC=CC=1CSSCC1=CC=CC=C1 GVPWHKZIJBODOX-UHFFFAOYSA-N 0.000 claims description 8
- 229940039717 lanolin Drugs 0.000 claims description 8
- 235000019388 lanolin Nutrition 0.000 claims description 8
- 229910052749 magnesium Inorganic materials 0.000 claims description 8
- 239000011777 magnesium Substances 0.000 claims description 8
- YWFWDNVOPHGWMX-UHFFFAOYSA-N n,n-dimethyldodecan-1-amine Chemical compound CCCCCCCCCCCCN(C)C YWFWDNVOPHGWMX-UHFFFAOYSA-N 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 8
- WMXCDAVJEZZYLT-UHFFFAOYSA-N tert-butylthiol Chemical compound CC(C)(C)S WMXCDAVJEZZYLT-UHFFFAOYSA-N 0.000 claims description 8
- 229910052788 barium Inorganic materials 0.000 claims description 7
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical group [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 7
- 229910052802 copper Inorganic materials 0.000 claims description 7
- 239000010949 copper Substances 0.000 claims description 7
- 238000005260 corrosion Methods 0.000 claims description 7
- 239000002105 nanoparticle Substances 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 6
- 235000019270 ammonium chloride Nutrition 0.000 claims description 6
- 239000003093 cationic surfactant Substances 0.000 claims description 6
- 238000005119 centrifugation Methods 0.000 claims description 5
- XKZQKPRCPNGNFR-UHFFFAOYSA-N 2-(3-hydroxyphenyl)phenol Chemical compound OC1=CC=CC(C=2C(=CC=CC=2)O)=C1 XKZQKPRCPNGNFR-UHFFFAOYSA-N 0.000 claims description 4
- ZJCZFAAXZODMQT-UHFFFAOYSA-N 2-methylpentadecane-2-thiol Chemical compound CCCCCCCCCCCCCC(C)(C)S ZJCZFAAXZODMQT-UHFFFAOYSA-N 0.000 claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 4
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 4
- XLRXYHUUAIIBJH-UHFFFAOYSA-N CCC(CCC[PH2]=O)(CC)CC Chemical class CCC(CCC[PH2]=O)(CC)CC XLRXYHUUAIIBJH-UHFFFAOYSA-N 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- 241000158728 Meliaceae Species 0.000 claims description 4
- XQVWYOYUZDUNRW-UHFFFAOYSA-N N-Phenyl-1-naphthylamine Chemical class C=1C=CC2=CC=CC=C2C=1NC1=CC=CC=C1 XQVWYOYUZDUNRW-UHFFFAOYSA-N 0.000 claims description 4
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 4
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims description 4
- WERKSKAQRVDLDW-ANOHMWSOSA-N [(2s,3r,4r,5r)-2,3,4,5,6-pentahydroxyhexyl] (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO WERKSKAQRVDLDW-ANOHMWSOSA-N 0.000 claims description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 4
- 229910052787 antimony Inorganic materials 0.000 claims description 4
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 4
- KHSLHYAUZSPBIU-UHFFFAOYSA-M benzododecinium bromide Chemical compound [Br-].CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 KHSLHYAUZSPBIU-UHFFFAOYSA-M 0.000 claims description 4
- JBIROUFYLSSYDX-UHFFFAOYSA-M benzododecinium chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 JBIROUFYLSSYDX-UHFFFAOYSA-M 0.000 claims description 4
- WNBGYVXHFTYOBY-UHFFFAOYSA-N benzyl-dimethyl-tetradecylazanium Chemical compound CCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 WNBGYVXHFTYOBY-UHFFFAOYSA-N 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- 229960000228 cetalkonium chloride Drugs 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 239000008139 complexing agent Substances 0.000 claims description 4
- 230000007797 corrosion Effects 0.000 claims description 4
- BVXOPEOQUQWRHQ-UHFFFAOYSA-N dibutyl phosphite Chemical compound CCCCOP([O-])OCCCC BVXOPEOQUQWRHQ-UHFFFAOYSA-N 0.000 claims description 4
- DDXLVDQZPFLQMZ-UHFFFAOYSA-M dodecyl(trimethyl)azanium;chloride Chemical group [Cl-].CCCCCCCCCCCC[N+](C)(C)C DDXLVDQZPFLQMZ-UHFFFAOYSA-M 0.000 claims description 4
- GIWKOZXJDKMGQC-UHFFFAOYSA-L lead(2+);naphthalene-2-carboxylate Chemical compound [Pb+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 GIWKOZXJDKMGQC-UHFFFAOYSA-L 0.000 claims description 4
- QJAOYSPHSNGHNC-UHFFFAOYSA-N octadecane-1-thiol Chemical compound CCCCCCCCCCCCCCCCCCS QJAOYSPHSNGHNC-UHFFFAOYSA-N 0.000 claims description 4
- 239000003921 oil Substances 0.000 claims description 4
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 claims description 4
- FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 claims description 4
- 239000012188 paraffin wax Substances 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- 239000001294 propane Substances 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- 239000000344 soap Substances 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- WSFQLUVWDKCYSW-UHFFFAOYSA-M sodium;2-hydroxy-3-morpholin-4-ylpropane-1-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)CC(O)CN1CCOCC1 WSFQLUVWDKCYSW-UHFFFAOYSA-M 0.000 claims description 4
- SFVFIFLLYFPGHH-UHFFFAOYSA-M stearalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SFVFIFLLYFPGHH-UHFFFAOYSA-M 0.000 claims description 4
- 238000003786 synthesis reaction Methods 0.000 claims description 4
- GEKDEMKPCKTKEC-UHFFFAOYSA-N tetradecane-1-thiol Chemical compound CCCCCCCCCCCCCCS GEKDEMKPCKTKEC-UHFFFAOYSA-N 0.000 claims description 4
- CEYYIKYYFSTQRU-UHFFFAOYSA-M trimethyl(tetradecyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCC[N+](C)(C)C CEYYIKYYFSTQRU-UHFFFAOYSA-M 0.000 claims description 4
- 238000005406 washing Methods 0.000 claims description 4
- RAADJDWNEAXLBL-UHFFFAOYSA-N 1,2-di(nonyl)naphthalene Chemical compound C1=CC=CC2=C(CCCCCCCCC)C(CCCCCCCCC)=CC=C21 RAADJDWNEAXLBL-UHFFFAOYSA-N 0.000 claims description 3
- UENWRTRMUIOCKN-UHFFFAOYSA-N benzyl thiol Chemical compound SCC1=CC=CC=C1 UENWRTRMUIOCKN-UHFFFAOYSA-N 0.000 claims description 3
- DLNWMWYCSOQYSQ-UHFFFAOYSA-M benzyl-hexadecyl-dimethylazanium;bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 DLNWMWYCSOQYSQ-UHFFFAOYSA-M 0.000 claims description 3
- PLMFYJJFUUUCRZ-UHFFFAOYSA-M decyltrimethylammonium bromide Chemical compound [Br-].CCCCCCCCCC[N+](C)(C)C PLMFYJJFUUUCRZ-UHFFFAOYSA-M 0.000 claims description 3
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 claims description 3
- KZCOBXFFBQJQHH-UHFFFAOYSA-N octane-1-thiol Chemical compound CCCCCCCCS KZCOBXFFBQJQHH-UHFFFAOYSA-N 0.000 claims description 3
- 229940117013 triethanolamine oleate Drugs 0.000 claims description 3
- ZMRFRBHYXOQLDK-UHFFFAOYSA-N 2-phenylethanethiol Chemical compound SCCC1=CC=CC=C1 ZMRFRBHYXOQLDK-UHFFFAOYSA-N 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 230000031709 bromination Effects 0.000 claims description 2
- 238000005893 bromination reaction Methods 0.000 claims description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 2
- 239000005864 Sulphur Substances 0.000 claims 2
- CXRFDZFCGOPDTD-UHFFFAOYSA-M Cetrimide Chemical compound [Br-].CCCCCCCCCCCCCC[N+](C)(C)C CXRFDZFCGOPDTD-UHFFFAOYSA-M 0.000 claims 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims 1
- 240000000528 Ricinus communis Species 0.000 claims 1
- 235000004443 Ricinus communis Nutrition 0.000 claims 1
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 claims 1
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 claims 1
- SXPWTBGAZSPLHA-UHFFFAOYSA-M cetalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SXPWTBGAZSPLHA-UHFFFAOYSA-M 0.000 claims 1
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 claims 1
- 229910052750 molybdenum Inorganic materials 0.000 claims 1
- 239000011733 molybdenum Substances 0.000 claims 1
- OEHSKKFHHQVEHY-UHFFFAOYSA-N octadecan-1-amine;phosphoric acid Chemical compound OP(O)(O)=O.CCCCCCCCCCCCCCCCCCN OEHSKKFHHQVEHY-UHFFFAOYSA-N 0.000 claims 1
- 238000006277 sulfonation reaction Methods 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 claims 1
- 238000005299 abrasion Methods 0.000 abstract description 4
- 239000010721 machine oil Substances 0.000 abstract description 3
- 238000005461 lubrication Methods 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 230000001050 lubricating effect Effects 0.000 description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 3
- OCBHHZMJRVXXQK-UHFFFAOYSA-M benzyl-dimethyl-tetradecylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 OCBHHZMJRVXXQK-UHFFFAOYSA-M 0.000 description 3
- 239000004359 castor oil Substances 0.000 description 3
- 235000019438 castor oil Nutrition 0.000 description 3
- QDYLMAYUEZBUFO-UHFFFAOYSA-N cetalkonium chloride Chemical compound CCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 QDYLMAYUEZBUFO-UHFFFAOYSA-N 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 3
- 239000000314 lubricant Substances 0.000 description 3
- 238000005555 metalworking Methods 0.000 description 3
- STMLQIACVZOCHU-UHFFFAOYSA-N octan-2-yl dihydrogen phosphate Chemical compound CCCCCCC(C)OP(O)(O)=O STMLQIACVZOCHU-UHFFFAOYSA-N 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- ICLYJLBTOGPLMC-KVVVOXFISA-N (z)-octadec-9-enoate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCC\C=C/CCCCCCCC(O)=O ICLYJLBTOGPLMC-KVVVOXFISA-N 0.000 description 2
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- UERFYFDULXZCSY-UHFFFAOYSA-N [NH4+].[Br-].C(C1=CC=CC=C1)[PH3+].[Br-] Chemical compound [NH4+].[Br-].C(C1=CC=CC=C1)[PH3+].[Br-] UERFYFDULXZCSY-UHFFFAOYSA-N 0.000 description 2
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- XLBGHUGBSRWNRI-UHFFFAOYSA-M azanium trimethyl(tetradecyl)azanium dibromide Chemical compound [Br-].C(CCCCCCCCCCCCC)[N+](C)(C)C.[NH4+].[Br-] XLBGHUGBSRWNRI-UHFFFAOYSA-M 0.000 description 2
- 150000003851 azoles Chemical class 0.000 description 2
- 125000005605 benzo group Chemical group 0.000 description 2
- 238000005660 chlorination reaction Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- JVEOCWZEOQDIIK-UHFFFAOYSA-N formic acid;molybdenum Chemical compound [Mo].OC=O JVEOCWZEOQDIIK-UHFFFAOYSA-N 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- NHLUVTZJQOJKCC-UHFFFAOYSA-N n,n-dimethylhexadecan-1-amine Chemical compound CCCCCCCCCCCCCCCCN(C)C NHLUVTZJQOJKCC-UHFFFAOYSA-N 0.000 description 2
- 229940094933 n-dodecane Drugs 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- MPNXSZJPSVBLHP-UHFFFAOYSA-N 2-chloro-n-phenylpyridine-3-carboxamide Chemical compound ClC1=NC=CC=C1C(=O)NC1=CC=CC=C1 MPNXSZJPSVBLHP-UHFFFAOYSA-N 0.000 description 1
- KBKKKDRGKPEINH-UHFFFAOYSA-N CCCCCCCC[S] Chemical compound CCCCCCCC[S] KBKKKDRGKPEINH-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- SWLVFNYSXGMGBS-UHFFFAOYSA-N ammonium bromide Chemical compound [NH4+].[Br-] SWLVFNYSXGMGBS-UHFFFAOYSA-N 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- DSVQEUKTSCUPIO-UHFFFAOYSA-N barium;2,3-di(nonyl)naphthalene-1-sulfonic acid Chemical compound [Ba].C1=CC=C2C(S(O)(=O)=O)=C(CCCCCCCCC)C(CCCCCCCCC)=CC2=C1 DSVQEUKTSCUPIO-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- VZWMKHUMEIECPK-UHFFFAOYSA-M benzyl-dimethyl-octadecylazanium;bromide Chemical compound [Br-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 VZWMKHUMEIECPK-UHFFFAOYSA-M 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000686 essence Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- KHYKFSXXGRUKRE-UHFFFAOYSA-J molybdenum(4+) tetracarbamodithioate Chemical compound C(N)([S-])=S.[Mo+4].C(N)([S-])=S.C(N)([S-])=S.C(N)([S-])=S KHYKFSXXGRUKRE-UHFFFAOYSA-J 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- AISMNBXOJRHCIA-UHFFFAOYSA-N trimethylazanium;bromide Chemical compound Br.CN(C)C AISMNBXOJRHCIA-UHFFFAOYSA-N 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/04—Elements
- C10M2201/05—Metals; Alloys
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/18—Natural waxes, e.g. ceresin, ozocerite, bees wax, carnauba; Degras
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/024—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings having at least two phenol groups but no condensed ring
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/16—Naphthenic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2211/08—Halogenated waxes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/064—Di- and triaryl amines
- C10M2215/065—Phenyl-Naphthyl amines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/221—Six-membered rings containing nitrogen and carbon only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
- C10M2219/022—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of hydrocarbons, e.g. olefines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
- C10M2219/024—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
- C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
- C10M2219/066—Thiocarbamic type compounds
- C10M2219/068—Thiocarbamate metal salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
- C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/041—Triaryl phosphates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/043—Ammonium or amine salts thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/049—Phosphite
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/06—Organic compounds derived from inorganic acids or metal salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/04—Detergent property or dispersant property
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/08—Resistance to extreme temperature
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
一种用于机械设备的润滑油的制备方法，包括以下制备方法：a、将改性纳米铜粉、清净剂、分散剂、防腐剂、极压抗磨剂和油性剂混合并高速搅拌，得到混合物一；b、将抗氧剂、粘度指数改进剂、防锈剂、降凝剂、抗泡剂和基础油混合均匀置于反应釜中混炼后，冷却至常温，得到混合物二；c、将混合物一、混合物二混合，加热，再经过浓缩处理，即可得到成品。本发明制备的润滑油能大幅度降低机械设备、尤其重型机械设备的摩擦功耗和磨损，减少废弃和泄漏机油对环境的污染，减少润滑油的消耗，节约不可再生的石油资源。
Description
技术领域
本发明属于机械设备技术领域，具体涉及一种用于机械设备的润滑油的制备方法。
背景技术
润滑油主要用于减少运动部件表面间的摩擦，具有润滑作用，同时对机器设备还具有防 锈、防腐、绝缘、功率传送、冷却、密封、清洗杂质和缓冲等功能，是一类在机械工业、汽车工业、精密仪器、电力工业、冶金工业、模具制造与应用工业、钢铁工业、机床工业等工业领域不可或缺的化工产品，在上述工业领域具有重要的作用。随着工业的飞速发展，装备技术的不断提升，我国对各种润滑油产品的需求量持续增长，且已成为全球第二大润滑油市场。在润滑油需求量不断上升的同时，也要求润滑油产品质量不断提高。因此，具有多功能的新型润滑剂已成为研究热点。
现有润滑材料中，润滑材料仅与金属加工工艺过程和液压传动有关，中国专利申请文件“含有聚苯乙烯的水基润滑剂及其制备技术”中，也仅指出；将该发明制备的水基润滑剂用于金属加工液中，如金属切削液、磨削液；曾获国家机械委科技进步二等奖的HG系列水基润滑、冷却、传动介质产品，也仅可代替矿物油或动、植物油做各种工艺过程润滑、冷却剂或液压、液力传动介质；还有一些水基润滑剂也只是金属拉拔、脱模、挤压等工艺过程用。
现有润滑技术中，润滑油用减摩抗磨添加剂不能脱离基础润滑油而独立应用于机械设备，必须借基础润滑油做载体而发挥作用。
经研究发现：润滑油用减摩抗磨剂，均匀分散到基础润滑油，尤其是分散到粘度较高的基础润滑油中后，作用发挥较慢而且不充分，设备摩擦功耗和磨损仍然很大的同时，设备工作温升高，废弃和泄漏的润滑油对环境污染大，润滑油消耗量也很大。
综上所述，因此需要一种更好的润滑油来改善现有技术的不足。
发明内容
本发明的目的是提供一种用于机械设备的润滑油的制备方法，本发明制备的润滑油能大幅度降低机械设备、尤其重型机械设备的摩擦功耗和磨损，同时显著降低设备工作温升，减少废弃和泄漏机油对环境的污染，减少润滑油的消耗，节约不可再生的石油资源。
本发明提供了如下的技术方案：
一种用于机械设备的润滑油的制备方法，包括以下制备方法：
a、将改性纳米铜粉、清净剂、分散剂、防腐剂、极压抗磨剂和油性剂混合并高速搅拌30-50min，搅拌速度为600-800r/min，得到混合物一；
b、将抗氧剂、粘度指数改进剂、防锈剂、降凝剂、抗泡剂和基础油混合均匀置于反应釜中，在150-180℃下混炼20-30min后，冷却至常温，得到混合物二；
c、将混合物一、混合物二混合，在80-100℃下加热，再经过浓缩处理，即可得到成品。
优选的，所述润滑油包括以下重量份的原料：改性纳米铜粉23-28份、清净剂6-8份、分散剂3-7份、防腐剂4-6份、极压抗磨剂7-9份、油性剂4-7份、抗氧剂6-8份、粘度指数改进剂5-8份、防锈剂7-10份、降凝剂8-11份、抗泡剂12-14份和基础油30-45份。
优选的，所述步骤a的改性纳米铜粉的制备方法为：依次将硫醇、阳离子表面活性剂、缓蚀剂和络合剂加入去离子水中，在频率为40-55KHz、功率为10-15kW的超声波分散作用下，搅拌40-60min后，再加入纳米铜粉，进一步在频率为30-50KHz、功率为8-15kW的超声波分散作用下，搅拌反应30-50min，然后依次经过离心分离、去离子水洗涤、离心分离、真空干燥、研磨和过筛工艺过程得到改性纳米铜粉。
优选的，所述硫醇为叔丁基硫醇、正丁基硫醇、特丁基硫醇、正戊基硫醇、正辛基硫醇、正十二烷基硫醇、叔十二烷基硫醇、十四烷基硫醇、十六烷基硫醇、十八烷基硫醇、苄基硫醇和苯乙基硫醇中的任一种或多种的混合。
优选的，所述阳离子表面活性剂为十二烷基三甲基氯化铵、十二烷基三甲基溴化铵、十二烷基二甲基苄基氯化铵、十二烷基二甲基苄基溴化铵、十四烷基三甲基氯化铵、十四烷基三甲基溴化 铵、十四烷基二甲基苄基氯化铵、十四烷基二甲基苄基溴化铵、十六烷基三甲基氯化铵、十六烷基三甲基溴化铵、十六烷基二甲基苄基氯化铵、十六烷基二甲基苄基溴化铵、十八烷基三甲基氯化铵、十八烷基三甲基溴化铵、十八烷基二甲基苄基氯化铵、十八烷基二甲基苄基溴化铵、十四烷基二甲基吡啶氯化铵和十四烷基二甲基吡啶溴化铵中的任一种或多种的混合。
优选的，所述步骤a的极压抗磨剂为氯化石蜡、酸性亚磷酸二丁酯、磷酸三甲酚酯、硫代磷酸胺盐、异辛基酸性磷酸酯十八胺盐、硫化异丁烯、二苄基二硫化物、环烷酸铅、二丁基二硫代氨 基甲酸钼、二丁基二硫代氨基甲酸锑、二丁基二硫代氨基甲酸铅和硼化油酰胺中的任一种或多种的混合。
优选的，所述步骤b的抗氧剂为2，6-二叔丁基对甲酚、4，4-亚甲基双(2，6-二叔丁基苯酚)、2，6-二叔丁基-α-二甲氨基对甲酚、N-苯基-α-萘胺、二丁基二硫化氨基甲酸锌和二酚基丙烷中的任一种或多种的混合。
优选的，所述步骤b的防锈剂为石油磺酸钡、石油磺酸钠、环烷酸锌、二壬基萘磺酸钡、苯并三氮唑、合成磺酸镁、烷基磷酸咪唑啉盐、羊毛脂镁皂、失水山梨糖醇单油酸酯、油酸三乙醇胺酯、磺化蓖麻油和羊毛脂中的任一种或多种的混合。
本发明的有益效果是：
本发明制备的润滑油能大幅度降低机械设备、尤其重型机械设备的摩擦功耗和磨损，同时显著降低设备工作温升，减少废弃和泄漏机油对环境的污染，减少润滑油的消耗，节约不可再生的石油资源。
本发明制备的润滑油中添加的改性纳米铜粉，可以大大提高了相互摩擦表面的润滑性能，大幅度降低摩擦系数，显著提高润滑作用，进而提高机械设备的有效动力，延长机械设备的使用寿命，降低机械设备的运转能耗。
本发明的改性纳米铜粉中添加的硫醇有利于进一步提高纳米铜粉在润滑油中的分散能力，显著增强了纳米铜粉在润滑油中分散稳定性、热稳定性和耐氧化性能，解决了目前纳米铜粉分散难、热稳定性差和耐氧化性能差的难题。
具体实施方式
实施例1
一种用于机械设备的润滑油的制备方法，包括以下制备方法：
a、将改性纳米铜粉、清净剂、分散剂、防腐剂、极压抗磨剂和油性剂混合并高速搅拌50min，搅拌速度为600r/min，得到混合物一；
b、将抗氧剂、粘度指数改进剂、防锈剂、降凝剂、抗泡剂和基础油混合均匀置于反应釜中，在180℃下混炼20min后，冷却至常温，得到混合物二；
c、将混合物一、混合物二混合，在100℃下加热，再经过浓缩处理，即可得到成品。
润滑油包括以下重量份的原料：改性纳米铜粉23份、清净剂6份、分散剂3份、防腐剂4份、极压抗磨剂7份、油性剂7份、抗氧剂6份、粘度指数改进剂5份、防锈剂10份、降凝剂8份、抗泡剂14份和基础油35份。
步骤a的改性纳米铜粉的制备方法为：依次将硫醇、阳离子表面活性剂、缓蚀剂和络合剂加入去离子水中，在频率为40KHz、功率为15kW的超声波分散作用下，搅拌40min后，再加入纳米铜粉，进一步在频率为30KHz、功率为15kW的超声波分散作用下，搅拌反应30min，然后依次经过离心分离、去离子水洗涤、离心分离、真空干燥、研磨和过筛工艺过程得到改性纳米铜粉。
硫醇为叔丁基硫醇、正丁基硫醇、特丁基硫醇、正戊基硫醇、正辛基硫醇、正十二烷基硫醇、叔十二烷基硫醇、十四烷基硫醇、十六烷基硫醇、十八烷基硫醇、苄基硫醇和苯乙基硫醇的混合。
阳离子表面活性剂为十二烷基三甲基氯化铵、十二烷基三甲基溴化铵、十二烷基二甲基苄基氯化铵、十二烷基二甲基苄基溴化铵、十四烷基三甲基氯化铵、十四烷基三甲基溴化 铵、十四烷基二甲基苄基氯化铵、十四烷基二甲基苄基溴化铵、十六烷基三甲基氯化铵、十六烷基三甲基溴化铵、十六烷基二甲基苄基氯化铵、十六烷基二甲基苄基溴化铵、十八烷基三甲基氯化铵、十八烷基三甲基溴化铵、十八烷基二甲基苄基氯化铵、十八烷基二甲基苄基溴化铵、十四烷基二甲基吡啶氯化铵和十四烷基二甲基吡啶溴化铵的混合。
步骤a的极压抗磨剂为氯化石蜡、酸性亚磷酸二丁酯、磷酸三甲酚酯、硫代磷酸胺盐、异辛基酸性磷酸酯十八胺盐、硫化异丁烯、二苄基二硫化物、环烷酸铅、二丁基二硫代氨基甲酸钼、二丁基二硫代氨基甲酸锑、二丁基二硫代氨基甲酸铅和硼化油酰胺的混合。
步骤b的抗氧剂为2，6-二叔丁基对甲酚、4，4-亚甲基双(2，6-二叔丁基苯酚)、2，6-二叔丁基-α-二甲氨基对甲酚、N-苯基-α-萘胺、二丁基二硫化氨基甲酸锌和二酚基丙烷的混合。
步骤b的防锈剂为石油磺酸钡、石油磺酸钠、环烷酸锌、二壬基萘磺酸钡、苯并三氮唑、合成磺酸镁、烷基磷酸咪唑啉盐、羊毛脂镁皂、失水山梨糖醇单油酸酯、油酸三乙醇胺酯、磺化蓖麻油和羊毛脂的混合。
实施例2
一种用于机械设备的润滑油的制备方法，包括以下制备方法：
a、将改性纳米铜粉、清净剂、分散剂、防腐剂、极压抗磨剂和油性剂混合并高速搅拌30min，搅拌速度为800r/min，得到混合物一；
b、将抗氧剂、粘度指数改进剂、防锈剂、降凝剂、抗泡剂和基础油混合均匀置于反应釜中，在180℃下混炼30min后，冷却至常温，得到混合物二；
c、将混合物一、混合物二混合，在100℃下加热，再经过浓缩处理，即可得到成品。
润滑油包括以下重量份的原料：改性纳米铜粉28份、清净剂6份、分散剂7份、防腐剂4份、极压抗磨剂7份、油性剂7份、抗氧剂8份、粘度指数改进剂8份、防锈剂7份、降凝剂8份、抗泡剂14份和基础油30份。
步骤a的改性纳米铜粉的制备方法为：依次将硫醇、阳离子表面活性剂、缓蚀剂和络合剂加入去离子水中，在频率为55KHz、功率为15kW的超声波分散作用下，搅拌40min后，再加入纳米铜粉，进一步在频率为30KHz、功率为15kW的超声波分散作用下，搅拌反应50min，然后依次经过离心分离、去离子水洗涤、离心分离、真空干燥、研磨和过筛工艺过程得到改性纳米铜粉。
硫醇为叔丁基硫醇、正丁基硫醇、特丁基硫醇、正戊基硫醇、正辛基硫醇、正十二烷基硫醇、叔十二烷基硫醇、十四烷基硫醇、十六烷基硫醇、十八烷基硫醇、苄基硫醇和苯乙基硫醇的混合。
阳离子表面活性剂为十二烷基三甲基氯化铵、十二烷基三甲基溴化铵、十二烷基二甲基苄基氯化铵、十二烷基二甲基苄基溴化铵、十四烷基三甲基氯化铵、十四烷基三甲基溴化 铵、十四烷基二甲基苄基氯化铵、十四烷基二甲基苄基溴化铵、十六烷基三甲基氯化铵、十六烷基三甲基溴化铵、十六烷基二甲基苄基氯化铵、十六烷基二甲基苄基溴化铵、十八烷基三甲基氯化铵、十八烷基三甲基溴化铵、十八烷基二甲基苄基氯化铵、十八烷基二甲基苄基溴化铵、十四烷基二甲基吡啶氯化铵和十四烷基二甲基吡啶溴化铵的混合。
步骤a的极压抗磨剂为氯化石蜡、酸性亚磷酸二丁酯、磷酸三甲酚酯、硫代磷酸胺盐、异辛基酸性磷酸酯十八胺盐、硫化异丁烯、二苄基二硫化物、环烷酸铅、二丁基二硫代氨基甲酸钼、二丁基二硫代氨基甲酸锑、二丁基二硫代氨基甲酸铅和硼化油酰胺的混合。
步骤b的抗氧剂为2，6-二叔丁基对甲酚、4，4-亚甲基双(2，6-二叔丁基苯酚)、2，6-二叔丁基-α-二甲氨基对甲酚、N-苯基-α-萘胺、二丁基二硫化氨基甲酸锌和二酚基丙烷的混合。
步骤b的防锈剂为石油磺酸钡、石油磺酸钠、环烷酸锌、二壬基萘磺酸钡、苯并三氮唑、合成磺酸镁、烷基磷酸咪唑啉盐、羊毛脂镁皂、失水山梨糖醇单油酸酯、油酸三乙醇胺酯、磺化蓖麻油和羊毛脂的混合。
以上所述仅为本发明的优选实施例而已，并不用于限制本发明，尽管参照前述实施例对本发明进行了详细的说明，对于本领域的技术人员来说，其依然可以对前述各实施例所记载的技术方案进行修改，或者对其中部分技术特征进行等同替换。凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。
Claims (8)
1.一种用于机械设备的润滑油的制备方法，其特征在于，包括以下制备方法：
a、将改性纳米铜粉、清净剂、分散剂、防腐剂、极压抗磨剂和油性剂混合并高速搅拌30-50min，搅拌速度为600-800r/min，得到混合物一；
b、将抗氧剂、粘度指数改进剂、防锈剂、降凝剂、抗泡剂和基础油混合均匀置于反应釜中，在150-180℃下混炼20-30min后，冷却至常温，得到混合物二；
c、将混合物一、混合物二混合，在80-100℃下加热，再经过浓缩处理，即可得到成品。
2.根据权利要求1所述的一种用于机械设备的润滑油的制备方法，其特征在于，所述润滑油包括以下重量份的原料：改性纳米铜粉23-28份、清净剂6-8份、分散剂3-7份、防腐剂4-6份、极压抗磨剂7-9份、油性剂4-7份、抗氧剂6-8份、粘度指数改进剂5-8份、防锈剂7-10份、降凝剂8-11份、抗泡剂12-14份和基础油30-45份。
3.根据权利要求1所述的一种用于机械设备的润滑油的制备方法，其特征在于，所述步骤a的改性纳米铜粉的制备方法为：依次将硫醇、阳离子表面活性剂、缓蚀剂和络合剂加入去离子水中，在频率为40-55KHz、功率为10-15kW的超声波分散作用下，搅拌40-60min后，再加入纳米铜粉，进一步在频率为30-50KHz、功率为8-15kW的超声波分散作用下，搅拌反应30-50min，然后依次经过离心分离、去离子水洗涤、离心分离、真空干燥、研磨和过筛工艺过程得到改性纳米铜粉。
4.根据权利要求3所述的一种用于机械设备的润滑油的制备方法，其特征在于，所述硫醇为叔丁基硫醇、正丁基硫醇、特丁基硫醇、正戊基硫醇、正辛基硫醇、正十二烷基硫醇、叔十二烷基硫醇、十四烷基硫醇、十六烷基硫醇、十八烷基硫醇、苄基硫醇和苯乙基硫醇中的任一种或多种的混合。
5.根据权利要求3所述的一种用于机械设备的润滑油的制备方法，其特征在于，所述阳离子表面活性剂为十二烷基三甲基氯化铵、十二烷基三甲基溴化铵、十二烷基二甲基苄基氯化铵、十二烷基二甲基苄基溴化铵、十四烷基三甲基氯化铵、十四烷基三甲基溴化 铵、十四烷基二甲基苄基氯化铵、十四烷基二甲基苄基溴化铵、十六烷基三甲基氯化铵、十六烷基三甲基溴化铵、十六烷基二甲基苄基氯化铵、十六烷基二甲基苄基溴化铵、十八烷基三甲基氯化铵、十八烷基三甲基溴化铵、十八烷基二甲基苄基氯化铵、十八烷基二甲基苄基溴化铵、十四烷基二甲基吡啶氯化铵和十四烷基二甲基吡啶溴化铵中的任一种或多种的混合。
6.根据权利要求1所述的一种用于机械设备的润滑油的制备方法，其特征在于，所述步骤a的极压抗磨剂为氯化石蜡、酸性亚磷酸二丁酯、磷酸三甲酚酯、硫代磷酸胺盐、异辛基酸性磷酸酯十八胺盐、硫化异丁烯、二苄基二硫化物、环烷酸铅、二丁基二硫代氨 基甲酸钼、二丁基二硫代氨基甲酸锑、二丁基二硫代氨基甲酸铅和硼化油酰胺中的任一种或多种的混合。
7.根据权利要求1所述的一种用于机械设备的润滑油的制备方法，其特征在于，所述步骤b的抗氧剂为2，6-二叔丁基对甲酚、4，4-亚甲基双(2，6-二叔丁基苯酚)、2，6-二叔丁基-α-二甲氨基对甲酚、N-苯基-α-萘胺、二丁基二硫化氨基甲酸锌和二酚基丙烷中的任一种或多种的混合。
8.根据权利要求1所述的一种用于机械设备的润滑油的制备方法，其特征在于，所述步骤b的防锈剂为石油磺酸钡、石油磺酸钠、环烷酸锌、二壬基萘磺酸钡、苯并三氮唑、合成磺酸镁、烷基磷酸咪唑啉盐、羊毛脂镁皂、失水山梨糖醇单油酸酯、油酸三乙醇胺酯、磺化蓖麻油和羊毛脂中的任一种或多种的混合。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710563736.3A CN107312601A (zh) | 2017-07-12 | 2017-07-12 | 一种用于机械设备的润滑油的制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710563736.3A CN107312601A (zh) | 2017-07-12 | 2017-07-12 | 一种用于机械设备的润滑油的制备方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107312601A true CN107312601A (zh) | 2017-11-03 |
Family
ID=60177678
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710563736.3A Withdrawn CN107312601A (zh) | 2017-07-12 | 2017-07-12 | 一种用于机械设备的润滑油的制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107312601A (zh) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108970482A (zh) * | 2018-07-13 | 2018-12-11 | 桐乡凡达石油制品有限公司 | 一种搅拌桶及使用该搅拌桶的制备环保切削油的方法 |
-
2017
- 2017-07-12 CN CN201710563736.3A patent/CN107312601A/zh not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108970482A (zh) * | 2018-07-13 | 2018-12-11 | 桐乡凡达石油制品有限公司 | 一种搅拌桶及使用该搅拌桶的制备环保切削油的方法 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103773565B (zh) | 一种润滑油组合物及其制备方法 | |
| CN104830404B (zh) | 一种含离子液体、改性纳米锌粉和石墨烯的润滑油组合物的制备方法 | |
| CN103773564B (zh) | 一种含离子液体和改性纳米锡粉的润滑油组合物 | |
| CN103756754B (zh) | 一种添加改性纳米锌粉和离子液体的润滑油及其制备方法 | |
| CN105038925A (zh) | 润滑剂及其制备方法 | |
| CN106590906A (zh) | 一种含氧化石墨烯的水基金属切削液及其制备方法 | |
| CN104830413A (zh) | 一种含离子液体、改性纳米锡粉和石墨烯的润滑油组合物的制备方法 | |
| CN107312601A (zh) | 一种用于机械设备的润滑油的制备方法 | |
| CN106978236A (zh) | 一种基础油复配高温复合锂基润滑脂及其制备方法 | |
| CN105419906B (zh) | 一种复合锂基润滑脂 | |
| RU2755896C2 (ru) | Смазочная композиция | |
| CN113403121B (zh) | 一种用于聚醚润滑油的离子液体防锈抗磨添加剂 | |
| CN107858190A (zh) | 一种用于干燥设备上的润滑油的制备方法 | |
| CN104120017A (zh) | 一种渗透力强防锈性能好的水基切削液及其制备方法 | |
| CN107384558B (zh) | 以插层型层状磷酸镁作为固体润滑添加剂的润滑脂及其制备方法 | |
| CN108728223A (zh) | 一种含有铸石的润滑油及其制备方法 | |
| CN112143552A (zh) | 一种油气润滑油组合物及其制备方法 | |
| CN109401827B (zh) | 一种铝散热翅片用冲压液及其制备方法 | |
| CN106675722A (zh) | 一种改性粘土修饰型微乳化切削液 | |
| CN115820329B (zh) | 层状硼磷酸胺化合物作为添加剂的润滑油及其制备方法 | |
| CN115926876B (zh) | 以层状硼磷酸镁作为固体润滑添加剂的复合铝基润滑脂及其制备方法 | |
| CN110423639A (zh) | 一种多功能润滑油添加剂及其应用 | |
| CN115872879B (zh) | 一种羧酸类质子型离子液体及其制备方法和作为润滑油添加剂的应用 | |
| CN105886075B (zh) | 一种拉丝润滑剂及其制备方法 | |
| CN115505442B (zh) | 热轧油组合物及其制备方法与应用 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20171103 |
|
| WW01 | Invention patent application withdrawn after publication |