CN106675722A - 一种改性粘土修饰型微乳化切削液 - Google Patents

一种改性粘土修饰型微乳化切削液 Download PDF

Info

Publication number
CN106675722A
CN106675722A CN201611157492.0A CN201611157492A CN106675722A CN 106675722 A CN106675722 A CN 106675722A CN 201611157492 A CN201611157492 A CN 201611157492A CN 106675722 A CN106675722 A CN 106675722A
Authority
CN
China
Prior art keywords
cutting fluid
stirring
clay
deionized water
modified
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611157492.0A
Other languages
English (en)
Inventor
江海涛
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tianchang Runda Metal Antirust Auxiliary Co Ltd
Original Assignee
Tianchang Runda Metal Antirust Auxiliary Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tianchang Runda Metal Antirust Auxiliary Co Ltd filed Critical Tianchang Runda Metal Antirust Auxiliary Co Ltd
Priority to CN201611157492.0A priority Critical patent/CN106675722A/zh
Publication of CN106675722A publication Critical patent/CN106675722A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/048—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M177/00—Special methods of preparation of lubricating compositions; Chemical modification by after-treatment of components or of the whole of a lubricating composition, not covered by other classes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02—Water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08—Inorganic acids or salts thereof
    • C10M2201/084—Inorganic acids or salts thereof containing sulfur, selenium or tellurium
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/10—Compounds containing silicon
    • C10M2201/102—Silicates
    • C10M2201/103—Clays; Mica; Zeolites
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
    • C10M2207/046—Hydroxy ethers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/108—Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/08—Amides
    • C10M2215/082—Amides containing hydroxyl groups; Alkoxylated derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/046—Polyamines, i.e. macromoleculars obtained by condensation of more than eleven amine monomers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2225/00—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2225/04—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of macromolecualr compounds not containing phosphorus in the monomers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/04—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions having a silicon-to-carbon bond, e.g. organo-silanes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/06—Organic compounds derived from inorganic acids or metal salts
    • C10M2227/061—Esters derived from boron
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/02—Groups 1 or 11
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/16—Antiseptic; (micro) biocidal or bactericidal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/01—Emulsions, colloids, or micelles
    • C10N2050/011—Oil-in-water

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

本发明公开了一种改性粘土修饰型微乳化切削液，由以下原料制备制成：精制矿物油、十二烷基磷酸酯三乙醇胺、烷基糖苷、椰油脂肪酸二乙醇酰胺、十二烷基丙基甜菜碱、硬脂酸丁酯、石油磺酸钠、硼酸酯、二乙醇胺、消泡剂、粘土、硅烷偶联剂kh550、油酸、过硫酸钾、茶皂素、壬基酚聚氧乙烯醚适量、苯基聚环氧乙烷磷酸酯、苯胺适量、无水乙醇适量、去离子水适量；本发明制备的微乳化切削液具有良好的润滑性和冷却性，pH值稳定性好，抑菌能力强，散热性强，能为加工件提供良好的防锈性，并能大大提高加工件的加工精度。

Description

一种改性粘土修饰型微乳化切削液
技术领域
本发明涉及微乳化切削液技术领域，尤其涉及一种改性粘土修饰型微乳化切削液。
背景技术
金属切削液是金属加工过程中重要的配套材料，其主要作用是冷却、润滑、清洗和防锈。按照介质状况分为两大类：油基型和水基型切削液，油基型切削液的主要成分通常是矿物油（也有植物油或其他合成材料），并加入油溶性防锈剂、油性剂和含活性元素的极压润滑剂调合而成，相比水基切削液，油基切削液的润滑性能和防锈性能较好，但却具有易产生油雾、易着火等缺点，水基切削液是用大量的水将浓缩液稀释后使用的，因而不具有产生油烟和引发火灾的缺点，水的比热容大，热导率高，汽化热大，是非常优良的冷却剂，切且成本低廉，另外加工后的脱脂清洗也比较简单。微乳液是一种介于乳化液和合成液之间并兼具乳化液润滑性和合成液清晰性的性能优异的切削液，成本较低，是未来加工液的主要发展方向。随着经济的快速发展，各种钢铁和铝合金的加工也飞速发展，目前国内在钢铁和铝合金的润滑方面金属切削液研究较少，主要以进口为主，我国在这方面的的研究工作起步较晚，而且主要集中在材料加工成型上，对切削加工中的润滑和防腐蚀方面的问题重视不够。近年来随着新型加工机械的不断出现，加工条件日趋苛刻，对金属切削液也提出了更高的要求。
付巧莲在《添加剂在微乳液中对铝/钢润滑性能影响的研究》一文中针对铝-钢摩擦副难于润滑的问题，以水性微乳化液为基础液，系统的研究了氯系、磷系、硫系、酯类以及聚醚类五大类润滑添加剂在微乳化液中对钢-钢摩擦副、铝-钢摩擦副的润滑特性。研究发现微乳液的最大无卡咬负荷与添加剂的种类和用量有关，其中对钢-钢摩擦副的润滑效果是多硫化物LZ5340L在水基微乳液中的响应值最好，加入量为5%时最大无卡咬负荷值为1118N，其次是氯化脂肪酸DA8527，硫化甘油三酸酯RC2411也有较好的润滑性能；在微乳化液中对铝-钢的摩擦副润滑结果为，硫系添加剂RC2411对铝-钢的摩擦副润滑效果最好，当其浓度为4%时，铝销的磨损量只有0.1mg，LZ5340L在加入量为4%时，铝销的磨损量也只有0.2mg。通过一系列试验后发现硫系添加剂对钢-钢摩擦副和铝-钢摩擦副具有较好的润滑性能，对其机理进行初步分析认为硫系添加剂能在金属表面形成一层致密的硫化膜，降低剪切应力，起到润滑作用。虽然作者系统的研究了在微乳化液中添加硫系润滑剂能够有效的提高切削液的润滑性能，但是随着加工器件日趋多元化，人们对微乳化切削液的要求越来越高，防锈蚀和使用寿命问题是切削液加工过程中不得不考虑的一个重要因素，因此对微乳化切削液必须进行改性以期获得的切削液能够提高加工效率和工件的表面质量，同时延长刀具和切削液本身的使用寿命，降低加工成本，获得最佳经济效益才是当前的研究热点。
发明内容
本发明目的就是为了弥补已有技术的缺陷，提供一种改性粘土修饰型微乳化切削液。
本发明是通过以下技术方案实现的：
一种改性粘土修饰型微乳化切削液，由以下重量份的原料制备制成：精制矿物油16-19、十二烷基磷酸酯三乙醇胺12-15、烷基糖苷3.5-4.5、椰油脂肪酸二乙醇酰胺7-9、十二烷基丙基甜菜碱3.5-4、硬脂酸丁酯2.7-3、石油磺酸钠3.3-3.5、硼酸酯6-8、二乙醇胺3-4、消泡剂0.05-0.1、粘土3-4、硅烷偶联剂kh550 0.7-1、油酸4-6、过硫酸钾11-13、茶皂素13-15、壬基酚聚氧乙烯醚适量、苯基聚环氧乙烷磷酸酯4-5、苯胺适量、无水乙醇适量、去离子水适量。
所述一种改性粘土修饰型微乳化切削液，由下列具体步骤制备制成：
（1）将粘土和油酸混合加热至60℃搅拌反应1h，硅烷偶联剂kh550用4-5倍量的无水乙醇溶解搅拌均匀，然后缓缓滴加到黏土混合物中，在60℃下恒温反应3-4h，然后置于烘箱中105℃下干燥至恒重，冷却至室温备用；
（2）将茶皂素和壬基酚聚氧乙烯醚按照质量比2:3混合搅拌均匀，加入总重量7-9倍量的去离子水搅拌均匀，再加入苯胺，搅拌均匀后加入步骤（1）制备的产物，其中苯胺与步骤（1）制备的产物质量比为2-3:1，将25%的过硫酸钾溶液以1d/s的速率滴加到上述混合溶液中，此过程保持反应在冰水浴条件下，滴加完毕后继续反应5-6h，反应结束后过滤，产物用无水乙醇和去离子水洗涤数次，然后在真空干燥中60℃下干燥至恒重；
(3)在反应容器中加入精制矿物油，搅拌加热至60-65℃时依次加入石油磺酸钠、硬脂酸丁酯、十二烷基磷酸酯三乙醇胺、烷基糖苷、椰油脂肪酸二乙醇酰胺和十二烷基丙基甜菜碱，每加入一种物料搅拌均匀后即可加入下一种物料，而后加入硼酸酯，搅拌溶解均匀得油相体系；
（4）在容器中加入去离子水加热到70-80℃，在搅拌下缓慢加入氯化钠和偶合稳定剂充分搅拌溶解，搅拌均匀后加入步骤(2)制备的产物超声分散均匀得水相体系；
（5）在保持60-70℃下将水相体系缓慢加到以200-300r/min转速搅拌的油相体系中，待水相体系滴加结束后控制反应温度为40-50℃，加入消泡剂得到基础浓缩液，向该浓缩液中加入其余剩余物料调成母液，用去离子水将其稀释成浓度为10%的微乳化切削液即可。
本发明的优点是：聚苯胺具有合成原料成本低廉、优异的抗划伤、抗点蚀能力等优点，能够在钢铁和铝合金的表面形成均匀致密的聚苯胺膜，起到良好的防腐防锈的作用，但是其在一般的有机溶剂中溶解性较差，因此需要对其进行掺杂改善其溶解性，聚苯胺具有优异的俘获纳米粒子的寄主能力，可以与一些活泼的无机纳米粒子共同掺杂有效的改善其溶解性及耐蚀能力，将油酸修饰粘土，并且利用硅烷偶联剂对其二次改性使其表面具备氨基，提高了粘土的反应活性、分散性和稳定性，本发明利用茶皂素和壬基酚聚氧乙烯醚对聚苯胺进行掺杂，起到接枝增溶的作用，有利于分子链的离域和舒展，降低分子链间的相互作用力，有助于提高聚苯胺乳液的流动性和分散性，并且和改性粘土形成良好的交联网络结构，在水基中具有良好的分散性和稳定性，提高了微乳化切削液的防腐蚀、耐磨、减摩等功能，本发明制备的微乳化切削液具有良好的润滑性和冷却性，pH值稳定性好，抑菌能力强，散热性强，能为加工件提供良好的防锈性，并能大大提高加工件的加工精度。
具体实施方式
一种改性粘土修饰型微乳化切削液，由以下重量份（公斤）的原料制备制成：精制矿物油16、十二烷基磷酸酯三乙醇胺12、烷基糖苷3.5、椰油脂肪酸二乙醇酰胺7、十二烷基丙基甜菜碱3.5、硬脂酸丁酯2.7、石油磺酸钠3.3、硼酸酯6、二乙醇胺3、消泡剂0.05、粘土3、硅烷偶联剂kh550 0.7、油酸4、过硫酸钾11、茶皂素13、壬基酚聚氧乙烯醚适量、苯基聚环氧乙烷磷酸酯4、苯胺适量、无水乙醇适量、去离子水适量。
所述一种改性粘土修饰型微乳化切削液，由下列具体步骤制备制成：
（1）将粘土和油酸混合加热至60℃搅拌反应1h，硅烷偶联剂kh550用4倍量的无水乙醇溶解搅拌均匀，然后缓缓滴加到黏土混合物中，在60℃下恒温反应3h，然后置于烘箱中105℃下干燥至恒重，冷却至室温备用；
（2）将茶皂素和壬基酚聚氧乙烯醚按照质量比2:3混合搅拌均匀，加入总重量7倍量的去离子水搅拌均匀，再加入苯胺，搅拌均匀后加入步骤（1）制备的产物，其中苯胺与步骤（1）制备的产物质量比为2:1，将25%的过硫酸钾溶液以1d/s的速率滴加到上述混合溶液中，此过程保持反应在冰水浴条件下，滴加完毕后继续反应5h，反应结束后过滤，产物用无水乙醇和去离子水洗涤数次，然后在真空干燥中60℃下干燥至恒重；
(3)在反应容器中加入精制矿物油，搅拌加热至60℃时依次加入石油磺酸钠、硬脂酸丁酯、十二烷基磷酸酯三乙醇胺、烷基糖苷、椰油脂肪酸二乙醇酰胺和十二烷基丙基甜菜碱，每加入一种物料搅拌均匀后即可加入下一种物料，而后加入硼酸酯，搅拌溶解均匀得油相体系；
（4）在容器中加入去离子水加热到70℃，在搅拌下缓慢加入氯化钠和偶合稳定剂充分搅拌溶解，搅拌均匀后加入步骤(2)制备的产物超声分散均匀得水相体系；
（5）在保持60℃下将水相体系缓慢加到以200r/min转速搅拌的油相体系中，待水相体系滴加结束后控制反应温度为40℃，加入消泡剂得到基础浓缩液，向该浓缩液中加入其余剩余物料调成母液，用去离子水将其稀释成浓度为10%的微乳化切削液即可。
对实施例制备的微乳化切削液进行性能测试，结果如下：
贮存安定性：无变色、无分层；消泡性（mL•10-1min-1）：＜2；腐蚀试验（55±2℃，铸铁/h）：＞48；腐蚀试验（55±2℃，铝/h）：＞12；防锈性试验（铸铁，h）＞48；最大无卡咬负和（N）：912；抗磨性（N）：＞59。

Claims (2)

1.一种改性粘土修饰型微乳化切削液，其特征在于，由以下重量份的原料制备制成：精制矿物油16-19、十二烷基磷酸酯三乙醇胺12-15、烷基糖苷3.5-4.5、椰油脂肪酸二乙醇酰胺7-9、十二烷基丙基甜菜碱3.5-4、硬脂酸丁酯2.7-3、石油磺酸钠3.3-3.5、硼酸酯6-8、二乙醇胺3-4、消泡剂0.05-0.1、粘土3-4、硅烷偶联剂kh550 0.7-1、油酸4-6、过硫酸钾11-13、茶皂素13-15、壬基酚聚氧乙烯醚适量、苯基聚环氧乙烷磷酸酯4-5、苯胺适量、无水乙醇适量、去离子水适量。
2.根据权利要求1所述一种改性粘土修饰型微乳化切削液，其特征在于，由下列具体步骤制备制成：
（1）将粘土和油酸混合加热至60℃搅拌反应1h，硅烷偶联剂kh550用4-5倍量的无水乙醇溶解搅拌均匀，然后缓缓滴加到黏土混合物中，在60℃下恒温反应3-4h，然后置于烘箱中105℃下干燥至恒重，冷却至室温备用；
（2）将茶皂素和壬基酚聚氧乙烯醚按照质量比2:3混合搅拌均匀，加入总重量7-9倍量的去离子水搅拌均匀，再加入苯胺，搅拌均匀后加入步骤（1）制备的产物，其中苯胺与步骤（1）制备的产物质量比为2-3:1，将25%的过硫酸钾溶液以1d/s的速率滴加到上述混合溶液中，此过程保持反应在冰水浴条件下，滴加完毕后继续反应5-6h，反应结束后过滤，产物用无水乙醇和去离子水洗涤数次，然后在真空干燥中60℃下干燥至恒重；
(3)在反应容器中加入精制矿物油，搅拌加热至60-65℃时依次加入石油磺酸钠、硬脂酸丁酯、十二烷基磷酸酯三乙醇胺、烷基糖苷、椰油脂肪酸二乙醇酰胺和十二烷基丙基甜菜碱，每加入一种物料搅拌均匀后即可加入下一种物料，而后加入硼酸酯，搅拌溶解均匀得油相体系；
（4）在容器中加入去离子水加热到70-80℃，在搅拌下缓慢加入氯化钠和偶合稳定剂充分搅拌溶解，搅拌均匀后加入步骤(2)制备的产物超声分散均匀得水相体系；
（5）在保持60-70℃下将水相体系缓慢加到以200-300r/min转速搅拌的油相体系中，待水相体系滴加结束后控制反应温度为40-50℃，加入消泡剂得到基础浓缩液，向该浓缩液中加入其余剩余物料调成母液，用去离子水将其稀释成浓度为10%的微乳化切削液即可。
CN201611157492.0A 2016-12-15 2016-12-15 一种改性粘土修饰型微乳化切削液 Pending CN106675722A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611157492.0A CN106675722A (zh) 2016-12-15 2016-12-15 一种改性粘土修饰型微乳化切削液

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611157492.0A CN106675722A (zh) 2016-12-15 2016-12-15 一种改性粘土修饰型微乳化切削液

Publications (1)

Publication Number Publication Date
CN106675722A true CN106675722A (zh) 2017-05-17

Family

ID=58868049

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611157492.0A Pending CN106675722A (zh) 2016-12-15 2016-12-15 一种改性粘土修饰型微乳化切削液

Country Status (1)

Country Link
CN (1) CN106675722A (zh)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113150886A (zh) * 2021-04-25 2021-07-23 广东环凯生物技术有限公司 酱油加工设备碱性清洗剂及其应用和制备方法
CN116445146A (zh) * 2023-04-18 2023-07-18 庆阳东祥石油科技有限公司 一种酸化解堵剂及其制备方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104277900A (zh) * 2014-09-25 2015-01-14 巢湖广丰金属制品有限公司 一种高抗磨切削液

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104277900A (zh) * 2014-09-25 2015-01-14 巢湖广丰金属制品有限公司 一种高抗磨切削液

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
赵炳桢等: "《现代刀具设计与应用》", 30 September 2014 *
马贤智等: "《实用机械加工手册》", 28 February 2015 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113150886A (zh) * 2021-04-25 2021-07-23 广东环凯生物技术有限公司 酱油加工设备碱性清洗剂及其应用和制备方法
CN116445146A (zh) * 2023-04-18 2023-07-18 庆阳东祥石油科技有限公司 一种酸化解堵剂及其制备方法
CN116445146B (zh) * 2023-04-18 2023-10-03 庆阳东祥石油科技有限公司 一种酸化解堵剂及其制备方法

Similar Documents

Publication Publication Date Title
CN101747988A (zh) 铜铝拉丝油及其制备方法和使用方法
CN104164283A (zh) 微乳金属切削液
CN101747987A (zh) 水基铜铝拉丝油组合物及其制备方法
CN102676277A (zh) 水溶性防锈液及其制备方法和使用方法
CN105695042B (zh) 润滑剂组合物及其制备方法和用该组合物制备微量切削液
CN102876435B (zh) 一种以三羟甲基丙烷油酸酯为基础油的半合成金属切削液及其制备方法
CN102604723B (zh) 一种润滑脂组合物及制备方法
CN101613634B (zh) 一种高性能水基乳化切削液组合物
CN104450120A (zh) 一种半合成金属拉丝润滑液及制备方法
CN106590906A (zh) 一种含氧化石墨烯的水基金属切削液及其制备方法
CN102311864A (zh) 一种数控机床专用切削液
CN104073321A (zh) 一种微乳化切削液、切削稀释液及其制备和使用方法
CN103923725A (zh) 一种扩径油组合物
CN106590907A (zh) 一种含石墨烯的金属切削液及其制备方法
CN106675722A (zh) 一种改性粘土修饰型微乳化切削液
CN103555392A (zh) 一种含有离子液体的微乳化金属切削液及其制备方法和应用
CN105950268A (zh) 一种含石墨烯添加剂的金属加工多功能润滑剂及其制备方法
CN106675739A (zh) 一种添加乳化二氧化钛光催化杀菌型微乳化切削液
CN106635267B (zh) 一种铜板带轧制微乳液及其制备方法
CN106675736A (zh) 多功能切削液组合物
CN106675740A (zh) 一种硬脆材料加工用微乳化切削液
CN106675721A (zh) 一种添加草木灰的微乳化切削液
CN106635355A (zh) 一种果胶修饰的微乳化切削液
CN106635336A (zh) 一种耐磨抗压纳米金刚石型微乳化切削液
CN101948711A (zh) 一种水溶性切削液及其制备方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20170517