CN107311524A - One kind is floatd the quartzy stone composite material of window table color inhibition waterproof heat resistant - Google Patents
One kind is floatd the quartzy stone composite material of window table color inhibition waterproof heat resistant Download PDFInfo
- Publication number
- CN107311524A CN107311524A CN201710614536.6A CN201710614536A CN107311524A CN 107311524 A CN107311524 A CN 107311524A CN 201710614536 A CN201710614536 A CN 201710614536A CN 107311524 A CN107311524 A CN 107311524A
- Authority
- CN
- China
- Prior art keywords
- parts
- well mixed
- color inhibition
- incubated
- cooled
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/30—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Other silicon-containing organic compounds; Boron-organic compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/02—Treatment
- C04B20/023—Chemical treatment
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Floatd the quartzy stone composite material of window table color inhibition waterproof heat resistant the invention discloses one kind, its raw material includes calcining quartz stone sand, polyurethane resin, unsaturated polyester resin, epoxy resin, vinyl pyrrolidone polymer, silicone alkyd, amino resins, benzoyl peroxide, the ethylhexanate of peroxidating 2, IPDI, trimethylolpropane, dibutyl tin laurate, ethylene vinyl acetate, polyvinyl acetate, accelerator, colorant, silane coupler KH 560, color inhibition filler and water tight packing.The quartzy stone composite material of the present invention is used for the window table that floats, with excellent color inhibition waterproof heat resistant performance.
Description
Technical field
The present invention relates to the technical field of composite, more particularly to one kind is floatd window table color inhibition waterproof heat resistant quartz
Stone composite material.
Background technology
The window that floats needs that the window table that floats is carried out composite covering to improve attractive in appearance and practical performance in finishing, and the window that floats is difficult
Exempting from can be by the corrosion of rainwater and irradiating for the sun, so the composite for the window table that floats is for color inhibition, waterproof and heat-resisting
Performance requirement is very high, so it is existing to solve with the quartzy stone composite material of color inhibition waterproof heat resistant to need exploitation one kind window table that floats badly
The problem of in technology.
The content of the invention
To solve technical problem present in background technology, the present invention proposes that one kind is floatd window table color inhibition waterproof heat resistant
Quartzy stone composite material, with excellent color inhibition waterproof heat resistant performance.
One kind proposed by the present invention is floatd the quartzy stone composite material of window table color inhibition waterproof heat resistant, and its raw material is by weight
Including：90-110 parts of calcining quartz stone sand, 4-8 parts of polyurethane resin, 2-6 parts of unsaturated polyester resin, 1-5 parts of epoxy resin,
3-5 parts of vinyl pyrrolidone polymer, 2-6 parts of silicone alkyd, 1-5 parts of amino resins, benzoyl peroxide
3-6 parts, 3-6 parts of peroxide -2-ethyl hexanoic acid tert-butyl, 3-6 parts of IPDI, 2-4 parts of trimethylolpropane,
2-5 parts of dibutyl tin laurate, 2-6 parts of ethylene vinyl acetate, 2-5 parts of polyvinyl acetate, 1-5 parts of accelerator, colorant
1-5 parts, 4-6 parts of silane coupler KH-560,15-25 parts of color inhibition filler, 8-16 parts of water tight packing.
Preferably, the raw material of water tight packing includes by weight：5-15 parts of acetylbutyrylcellulose, 2-6 parts of antimony trioxide,
1-4 parts of magnetizable powder, 3-6 parts of Silane coupling reagent KH-570,2-6 parts of ethanol, 1-4 parts of paraffin, 3-5 parts of polypropylene, carbamate
2-5 parts, 1-4 parts of potassium peroxydisulfate, 3-5 parts of polytetrafluoroethylene (PTFE), 2-5 parts of aluminum stearate, 1-4 parts of aluminium hydroxide, multi-walled carbon nanotube
3-5 parts, 2-5 parts of methyl methacrylate.
Preferably, water tight packing is prepared by following technique：By acetylbutyrylcellulose, antimony trioxide, magnetizable powder, silicon
Alkane coupling agent kh-570 and ethanol are well mixed, and stirring then heats up, and is incubated, and is dried after suction filtration, dries, is cooled to room temperature and obtains
To material A；Paraffin, polypropylene and carbamate are well mixed, heat, insulation, be cooled to normal temperature, then add material A,
Potassium peroxydisulfate, polytetrafluoroethylene (PTFE) and aluminum stearate are well mixed, heat up, insulation, then ball milling, then add aluminium hydroxide, many
Wall carbon nano tube and methyl methacrylate are well mixed, heat up, and are incubated, and stir, and dry, and grinding is cooled to room temperature and prevented
Water packing.
Preferably, water tight packing is prepared by following technique：By acetylbutyrylcellulose, antimony trioxide, magnetizable powder, silicon
Alkane coupling agent kh-570 and ethanol are well mixed, stir 20-40min in 650-850r/min rotating speeds, are then warming up to 70-90
DEG C, dried after being incubated 3-5h, suction filtration, in 60-80 DEG C of dry 20-28h, be cooled to room temperature and obtain material A；By paraffin, polypropylene
It is well mixed with carbamate, 320-480 DEG C is heated to, 12-18min is incubated, is cooled to normal temperature, material A, mistake is then added
Potassium sulfate, polytetrafluoroethylene (PTFE) and aluminum stearate are well mixed, are warming up to 80-90 DEG C, are incubated 5-15min, then ball milling 20-
40min, then adds aluminium hydroxide, multi-walled carbon nanotube and methyl methacrylate and is well mixed, be warming up to 120-140 DEG C,
20-40min is incubated, 1-3h is stirred in 1500-2500r/min rotating speeds, is dried, grinding is cooled to room temperature and obtains water tight packing.
Preferably, the raw material of color inhibition filler includes by weight：15-25 parts of nano titanium oxide, 8-16 parts of ethanol, ten
Six 4-8 parts of alkyl trimethoxy ammonium chlorides, 2-5 parts of dimethyl silicone polymer, 1-4 parts of sodium carbonate, AEO sulphur
Sour sodium 3-5 parts, 2-5 parts of AEO, 1-4 parts of APP, 3-6 parts of propyl alcohol, silane resin acceptor kh-550 2-4
Part, 1-5 parts of isomeric alcohol polyethenoxy ether, 3-9 parts of methylcellulose.
Preferably, color inhibition filler is prepared by following technique：Nano titanium oxide and ethanol are well mixed, ultrasound
It is scattered, it is subsequently added into hexadecyl trimethoxy ammonium chloride, dimethyl silicone polymer, sodium carbonate and AEO sulphur
Sour sodium is well mixed, magnetic agitation, then adjusts pH with ammoniacal liquor, is then added AEO and is well mixed, heating,
Insulation, then to be washed to pH most neutral for centrifugation, is cooled to room temperature and obtains material a；APP and propyl alcohol are well mixed, so
After heat up, be incubated, be subsequently added into that silane resin acceptor kh-550 and isomeric alcohol polyethenoxy ether are well mixed, stirring adjusts pH, so
After heat up, be incubated, dried after washing in vacuum to constant weight, be cooled to room temperature, then add methylcellulose and material a mixing is equal
It is even, stir, heat up, insulation is cooled to room temperature and obtains color inhibition filler.
Preferably, color inhibition filler is prepared by following technique：Nano titanium oxide and ethanol are well mixed, ultrasound
Scattered 10-30min, is subsequently added into hexadecyl trimethoxy ammonium chloride, dimethyl silicone polymer, sodium carbonate and fatty alcohol polyoxy
Ethene ether sodium sulfate is well mixed, magnetic agitation 15-25min, then adjusts pH to 8.5-9.5 with ammoniacal liquor, then adds fat
Alcohol APEO is well mixed, and is warming up to 30-40 DEG C, is incubated 22-26h, and then to be washed to pH most neutral for centrifugation, is cooled to
Room temperature obtains material a；APP and propyl alcohol are well mixed, 60-80 DEG C is then heated to, 20-40min is incubated, then added
Enter silane resin acceptor kh-550 and isomeric alcohol polyethenoxy ether be well mixed, 10-30min is stirred in 650-850r/min rotating speeds,
PH is adjusted to 3.5-5.0,65-75 DEG C is then heated to, 0.5-1.5h is incubated, dried after washing in vacuum in 65-75 DEG C to perseverance
Weight, is cooled to room temperature, then adds methylcellulose and material a is well mixed, 10- is stirred in 80-120r/min rotating speeds
20min, is warming up to 150-160 DEG C, is incubated 10-20min, is cooled to room temperature and obtains color inhibition filler.
One kind of the present invention is floatd the quartzy stone composite material of window table color inhibition waterproof heat resistant, and its raw material includes calcining quartz
Stone sand, polyurethane resin, unsaturated polyester resin, epoxy resin, vinyl pyrrolidone polymer, organic-silicon-modified alkyd tree
Fat, amino resins, benzoyl peroxide, peroxide -2-ethyl hexanoic acid tert-butyl, IPDI, trihydroxy methyl
Propane, dibutyl tin laurate, ethylene vinyl acetate, polyvinyl acetate, accelerator, colorant, silane coupler KH-
560th, color inhibition filler and water tight packing.Its using calcining quartz stone sand as major ingredient, with polyurethane resin, unsaturated polyester resin,
Epoxy resin, vinyl pyrrolidone polymer, silicone alkyd and amino resins moulding resin material, with vinyl
Pyrrolidone polymer, silicone alkyd, amino resins, benzoyl peroxide, the tertiary fourth of peroxidating -2 ethyl hexanoic acid
Ester, IPDI, trimethylolpropane, dibutyl tin laurate, ethylene vinyl acetate, polyvinyl acetate
Ester, accelerator, colorant, silane coupler KH-560, color inhibition filler and water tight packing are as strengthening helping agent, obtained quartz
Composite is used for window table use of floaing, with excellent waterproof heat resistant performance.Wherein, water tight packing is by by acetate butyrate fiber
Element, antimony trioxide, magnetizable powder, Silane coupling reagent KH-570 and ethanol are well mixed, stirring, then heat up, and are incubated, and are dried in the air after suction filtration
It is dry, dry, be cooled to room temperature and obtain material A；Paraffin, polypropylene and carbamate are well mixed, heated, is incubated, cooling
To normal temperature, then add material A, potassium peroxydisulfate, polytetrafluoroethylene (PTFE) and aluminum stearate and be well mixed, heat up, be incubated, then ball
Mill, then adds aluminium hydroxide, multi-walled carbon nanotube and methyl methacrylate and is well mixed, heat up, be incubated, stir, drying,
Grinding, be cooled to room temperature and obtain water tight packing, its using acetylbutyrylcellulose, antimony trioxide and magnetizable powder as filler base-material,
Using Silane coupling reagent KH-570 as surface modifier, using ethanol as mixed solvent, with paraffin, polypropylene, carbamate, over cure
Sour potassium, polytetrafluoroethylene (PTFE), aluminum stearate, aluminium hydroxide, multi-walled carbon nanotube and methyl methacrylate are obtained as strengthening helping agent
To water tight packing apply to the present invention the quartzy stone composite material of the window table color inhibition waterproof heat resistant that floats in, effectively increase
Water resistance.Wherein, color inhibition filler is by the way that nano titanium oxide and ethanol are well mixed, and ultrasonic disperse is subsequently added into ten
Six alkyl trimethoxy ammonium chlorides, dimethyl silicone polymer, sodium carbonate and sodium sulfate of polyethenoxy ether of fatty alcohol are well mixed, magnetic
Power is stirred, and then adjusts pH with ammoniacal liquor, is then added AEO and is well mixed, heats up, insulation, then centrifugal water
It is washed till pH most neutral, is cooled to room temperature and obtains material a；APP and propyl alcohol are well mixed, then heated up, is incubated, connects
Addition silane resin acceptor kh-550 and isomeric alcohol polyethenoxy ether is well mixed, stirring, adjust pH, then heat up, be incubated, wash
Wash in rear vacuum and dry to constant weight, be cooled to room temperature, then add methylcellulose and material a is well mixed, stir, heating,
Insulation, is cooled to room temperature and obtains color inhibition filler, it is using nano titanium oxide as base-material, with alcohol solvent, with cetyl three
It is methoxy ammonium chloride, dimethyl silicone polymer, sodium carbonate, sodium sulfate of polyethenoxy ether of fatty alcohol, AEO, poly-
Ammonium phosphate, silane resin acceptor kh-550 and isomeric alcohol polyethenoxy ether are strengthening helping agent, and obtained color inhibition filler applies to this
The window table that floats of invention effectively increases anti-yellowing property with the quartzy stone composite material of color inhibition waterproof heat resistant.The quartz of the present invention
Stone composite material is used for the window table that floats, with excellent color inhibition waterproof heat resistant performance.
Embodiment
The present invention is described in detail with reference to specific embodiment, it should be appreciated that embodiment is served only for illustrating this hair
It is bright, rather than for limiting the invention, any modification made on the basis of the present invention, equivalent substitution etc. are in this hair
In bright protection domain.
Embodiment 1
One kind proposed by the present invention is floatd the quartzy stone composite material of window table color inhibition waterproof heat resistant, and its raw material is by weight
Including：100 parts of calcining quartz stone sand, 6 parts of polyurethane resin, 4 parts of unsaturated polyester resin, 3 parts of epoxy resin, vinyl pyrrole
4 parts of alkanone polymer, 4 parts of silicone alkyd, 3 parts of amino resins, 4.5 parts of benzoyl peroxide, peroxidating -2- second
4.5 parts of base hecanoic acid t-butyl ester, 4.5 parts of IPDI, 3 parts of trimethylolpropane, dibutyl tin laurate 3.5
Part, 4 parts of ethylene vinyl acetate, 3.5 parts of polyvinyl acetate, 3 parts of accelerator, 3 parts of colorant, KH-5605 parts of silane coupler,
20 parts of color inhibition filler, 12 parts of water tight packing.
Water tight packing is prepared by following technique：By weight by 10 parts of acetylbutyrylcelluloses, 4 parts of antimony trioxides,
2.5 parts of magnetizable powders, 4.5 parts of Silane coupling reagent KH-570s and 4 parts of ethanol are well mixed, and are stirred 30min in 750r/min rotating speeds, are connect
And be warming up to 80 DEG C, dried after being incubated 4h, suction filtration, in 70 DEG C of dry 24h, be cooled to room temperature and obtain material A；By 2.5 parts of paraffin,
4 parts of polypropylene and 3.5 parts of carbamates are well mixed, and are heated to 400 DEG C, are incubated 15min, are cooled to normal temperature, then add
Material A, 2.5 parts of potassium peroxydisulfates, 4 parts of polytetrafluoroethylene (PTFE) and 3.5 parts of aluminum stearates are well mixed, and are warming up to 85 DEG C, insulation
10min, then ball milling 30min, then adds 2.5 parts of aluminium hydroxides, 4 parts of multi-walled carbon nanotubes and 3.5 parts of methyl methacrylates
Ester is well mixed, and is warming up to 130 DEG C, is incubated 30min, and 2h is stirred in 2000r/min rotating speeds, is dried, and grinding is cooled to room temperature and obtained
To water tight packing.
Color inhibition filler is prepared by following technique：20 parts of nano titanium oxides and 12 parts of ethanol are mixed by weight
Uniformly, ultrasonic disperse 20min, is subsequently added into 6 parts of hexadecyl trimethoxy ammonium chlorides, 3.5 parts of dimethyl silicone polymers, 2.5
Part sodium carbonate and 4 parts of sodium sulfate of polyethenoxy ether of fatty alcohol are well mixed, magnetic agitation 20min, then with ammoniacal liquor adjust pH to
9, then add 3.5 parts of AEOs and be well mixed, be warming up to 35 DEG C, be incubated 24h, then centrifugation is washed to pH extremely
For neutrality, it is cooled to room temperature and obtains material a；2.5 parts of APPs and 4.5 parts of propyl alcohol are well mixed, 70 DEG C are then heated to,
30min is incubated, 3 parts of silane resin acceptor kh-550s is subsequently added into and 3 parts of isomeric alcohol polyethenoxy ethers is well mixed, in 750r/min
Rotating speed stirs 20min, and pH is to 4.0 for regulation, then heats to 70 DEG C, is incubated 1h, is dried after washing in vacuum in 70 DEG C to constant weight,
Room temperature is cooled to, 6 parts of methylcellulose is then added and material a is well mixed, 15min, heating are stirred in 100r/min rotating speeds
To 155 DEG C, 15min is incubated, room temperature is cooled to and obtains color inhibition filler.
Embodiment 2
One kind proposed by the present invention is floatd the quartzy stone composite material of window table color inhibition waterproof heat resistant, and its raw material is by weight
Including：90 parts of calcining quartz stone sand, 8 parts of polyurethane resin, 2 parts of unsaturated polyester resin, 5 parts of epoxy resin, vinyl pyrrole
3 parts of alkanone polymer, 6 parts of silicone alkyd, 1 part of amino resins, 6 parts of benzoyl peroxide, peroxidating -2- ethyls
3 parts of hecanoic acid t-butyl ester, 6 parts of IPDI, 2 parts of trimethylolpropane, 5 parts of dibutyl tin laurate, ethene
2 parts of vinylacetate, 5 parts of polyvinyl acetate, 1 part of accelerator, 5 parts of colorant, 4 parts of silane coupler KH-560, color inhibition are filled out
Expect 25 parts, 8 parts of water tight packing.
Water tight packing is prepared by following technique：By weight by 5 parts of acetylbutyrylcelluloses, 6 parts of antimony trioxides, 1
Part magnetizable powder, 6 parts of Silane coupling reagent KH-570s and 2 parts of ethanol are well mixed, and are stirred 20min in 850r/min rotating speeds, are then risen
Temperature is dried after being incubated 3h, suction filtration to 90 DEG C, in 80 DEG C of dry 20h, is cooled to room temperature and obtains material A；4 parts of paraffin, 3 parts are gathered
Propylene and 5 parts of carbamates are well mixed, and are heated to 320 DEG C, are incubated 18min, are cooled to normal temperature, then add material A, 1
Part potassium peroxydisulfate, 5 parts of polytetrafluoroethylene (PTFE) and 2 parts of aluminum stearates are well mixed, and are warming up to 90 DEG C, are incubated 5min, then ball milling
40min, then adds 1 part of aluminium hydroxide, 5 parts of multi-walled carbon nanotubes and 2 parts of methyl methacrylates and is well mixed, be warming up to
140 DEG C, 20min is incubated, 1h is stirred in 2500r/min rotating speeds, is dried, grinding is cooled to room temperature and obtains water tight packing.
Color inhibition filler is prepared by following technique：15 parts of nano titanium oxides and 16 parts of ethanol are mixed by weight
Uniformly, ultrasonic disperse 10min, is subsequently added into 8 parts of hexadecyl trimethoxy ammonium chlorides, 2 parts of dimethyl silicone polymers, 4 parts of carbon
Sour sodium and 3 parts of sodium sulfate of polyethenoxy ether of fatty alcohol are well mixed, and magnetic agitation 25min then adjusts pH to 8.5 with ammoniacal liquor,
Then 5 parts of AEOs are added to be well mixed, 30 DEG C is warming up to, is incubated 26h, during then centrifugation is washed to pH most
Property, it is cooled to room temperature and obtains material a；1 part of APP and 6 parts of propyl alcohol are well mixed, 60 DEG C, insulation are then heated to
40min, is subsequently added into 2 parts of silane resin acceptor kh-550s and 5 parts of isomeric alcohol polyethenoxy ethers are well mixed, in 650r/min rotating speeds
30min is stirred, pH is to 3.5 for regulation, then heats to 75 DEG C, is incubated 0.5h, is dried after washing in vacuum in 75 DEG C to constant weight, cold
But to room temperature, 3 parts of methylcellulose is then added and material a is well mixed, 10min is stirred in 120r/min rotating speeds, is warming up to
160 DEG C, 10min is incubated, room temperature is cooled to and obtains color inhibition filler.
Embodiment 3
One kind proposed by the present invention is floatd the quartzy stone composite material of window table color inhibition waterproof heat resistant, and its raw material is by weight
Including：110 parts of calcining quartz stone sand, 4 parts of polyurethane resin, 6 parts of unsaturated polyester resin, 1 part of epoxy resin, vinyl pyrrole
5 parts of alkanone polymer, 2 parts of silicone alkyd, 5 parts of amino resins, 3 parts of benzoyl peroxide, peroxidating -2- ethyls
6 parts of hecanoic acid t-butyl ester, 3 parts of IPDI, 4 parts of trimethylolpropane, 2 parts of dibutyl tin laurate, ethene
6 parts of vinylacetate, 2 parts of polyvinyl acetate, 5 parts of accelerator, 1 part of colorant, 6 parts of silane coupler KH-560, color inhibition are filled out
Expect 15 parts, 16 parts of water tight packing.
Water tight packing is prepared by following technique：By weight by 15 parts of acetylbutyrylcelluloses, 2 parts of antimony trioxides, 4
Part magnetizable powder, 3 parts of Silane coupling reagent KH-570s and 6 parts of ethanol are well mixed, and are stirred 40min in 650r/min rotating speeds, are then risen
Temperature is dried after being incubated 5h, suction filtration to 70 DEG C, in 60 DEG C of dry 28h, is cooled to room temperature and obtains material A；1 part of paraffin, 5 parts are gathered
Propylene and 2 parts of carbamates are well mixed, and are heated to 480 DEG C, are incubated 12min, are cooled to normal temperature, then add material A, 4
Part potassium peroxydisulfate, 3 parts of polytetrafluoroethylene (PTFE) and 5 parts of aluminum stearates are well mixed, and are warming up to 80 DEG C, are incubated 15min, then ball milling
20min, then adds 4 parts of aluminium hydroxides, 3 parts of multi-walled carbon nanotubes and 5 parts of methyl methacrylates and is well mixed, be warming up to
120 DEG C, 40min is incubated, 3h is stirred in 1500r/min rotating speeds, is dried, grinding is cooled to room temperature and obtains water tight packing.
Color inhibition filler is prepared by following technique：25 parts of nano titanium oxides and 8 parts of ethanol are mixed by weight
Uniformly, ultrasonic disperse 30min, is subsequently added into 4 parts of hexadecyl trimethoxy ammonium chlorides, 5 parts of dimethyl silicone polymers, 1 part of carbon
Sour sodium and 5 parts of sodium sulfate of polyethenoxy ether of fatty alcohol are well mixed, and magnetic agitation 15min then adjusts pH to 9.5 with ammoniacal liquor,
Then 2 parts of AEOs are added to be well mixed, 40 DEG C is warming up to, is incubated 22h, during then centrifugation is washed to pH most
Property, it is cooled to room temperature and obtains material a；4 parts of APPs and 3 parts of propyl alcohol are well mixed, 80 DEG C, insulation are then heated to
20min, is subsequently added into 4 parts of silane resin acceptor kh-550s and 1 part of isomeric alcohol polyethenoxy ether is well mixed, in 850r/min rotating speeds
10min is stirred, pH is to 5.0 for regulation, then heats to 65 DEG C, is incubated 1.5h, is dried after washing in vacuum in 65 DEG C to constant weight, cold
But to room temperature, 9 parts of methylcellulose is then added and material a is well mixed, 20min is stirred in 80r/min rotating speeds, is warming up to
150 DEG C, 20min is incubated, room temperature is cooled to and obtains color inhibition filler.
Embodiment 4
One kind proposed by the present invention is floatd the quartzy stone composite material of window table color inhibition waterproof heat resistant, and its raw material is by weight
Including：95 parts of calcining quartz stone sand, 7 parts of polyurethane resin, 3 parts of unsaturated polyester resin, 4 parts of epoxy resin, vinyl pyrrole
3.5 parts of alkanone polymer, 5 parts of silicone alkyd, 2 parts of amino resins, 5 parts of benzoyl peroxide, peroxidating -2- second
4 parts of base hecanoic acid t-butyl ester, 5 parts of IPDI, 2.5 parts of trimethylolpropane, 4 parts of dibutyl tin laurate,
It is 3 parts of ethylene vinyl acetate, 4 parts of polyvinyl acetate, 2 parts of accelerator, 4 parts of colorant, 4.5 parts of silane coupler KH-560, resistance to
22 parts of xanthochromia filler, 9 parts of water tight packing.
Water tight packing is prepared by following technique：By weight by 8 parts of acetylbutyrylcelluloses, 5 parts of antimony trioxides, 2
Part magnetizable powder, 5 parts of Silane coupling reagent KH-570s and 3 parts of ethanol are well mixed, and are stirred 25min in 820r/min rotating speeds, are then risen
Temperature is dried after being incubated 3.5h, suction filtration to 85 DEG C, in 75 DEG C of dry 22h, is cooled to room temperature and obtains material A；By 3 parts of paraffin, 3.5
Part polypropylene and 4 parts of carbamates are well mixed, and are heated to 325 DEG C, are incubated 17min, are cooled to normal temperature, then add material
A, 2 parts of potassium peroxydisulfates, 4.5 parts of polytetrafluoroethylene (PTFE) and 3 parts of aluminum stearates are well mixed, and are warming up to 88 DEG C, are incubated 8min, then ball
35min is ground, 2 parts of aluminium hydroxides, 4.5 parts of multi-walled carbon nanotubes and 3 parts of methyl methacrylates is then added and is well mixed, heating
To 135 DEG C, 25min is incubated, 1.5h is stirred in 2200r/min rotating speeds, is dried, grinding is cooled to room temperature and obtains water tight packing.
Color inhibition filler is prepared by following technique：18 parts of nano titanium oxides and 15 parts of ethanol are mixed by weight
Uniformly, ultrasonic disperse 15min, is subsequently added into 7 parts of hexadecyl trimethoxy ammonium chlorides, 3 parts of dimethyl silicone polymers, 3 parts of carbon
Sour sodium and 3.5 parts of sodium sulfate of polyethenoxy ether of fatty alcohol are well mixed, magnetic agitation 22min, then with ammoniacal liquor adjust pH to
8.8, then add 4 parts of AEOs and be well mixed, be warming up to 32 DEG C, be incubated 25h, then centrifugation is washed to pH extremely
For neutrality, it is cooled to room temperature and obtains material a；2 parts of APPs and 5 parts of propyl alcohol are well mixed, 65 DEG C, insulation are then heated to
35min, is subsequently added into 2.5 parts of silane resin acceptor kh-550s and 4 parts of isomeric alcohol polyethenoxy ethers are well mixed, and turns in 680r/min
Speed stirring 25min, pH is to 4.0 for regulation, then heats to 72 DEG C, is incubated 0.8h, is dried after washing in vacuum in 72 DEG C to constant weight,
Room temperature is cooled to, 4 parts of methylcellulose is then added and material a is well mixed, 12min, heating are stirred in 115r/min rotating speeds
To 158 DEG C, 12min is incubated, room temperature is cooled to and obtains color inhibition filler.
Embodiment 5
One kind proposed by the present invention is floatd the quartzy stone composite material of window table color inhibition waterproof heat resistant, and its raw material is by weight
Including：105 parts of calcining quartz stone sand, 5 parts of polyurethane resin, 5 parts of unsaturated polyester resin, 2 parts of epoxy resin, vinyl pyrrole
4.5 parts of alkanone polymer, 3 parts of silicone alkyd, 4 parts of amino resins, 4 parts of benzoyl peroxide, peroxidating -2- second
5 parts of base hecanoic acid t-butyl ester, 4 parts of IPDI, 3.5 parts of trimethylolpropane, 3 parts of dibutyl tin laurate,
It is 5 parts of ethylene vinyl acetate, 3 parts of polyvinyl acetate, 4 parts of accelerator, 2 parts of colorant, 5.5 parts of silane coupler KH-560, resistance to
18 parts of xanthochromia filler, 15 parts of water tight packing.
Water tight packing is prepared by following technique：By weight by 12 parts of acetylbutyrylcelluloses, 3 parts of antimony trioxides, 3
Part magnetizable powder, 4 parts of Silane coupling reagent KH-570s and 5 parts of ethanol are well mixed, and are stirred 35min in 680r/min rotating speeds, are then risen
Temperature is dried after being incubated 4.5h, suction filtration to 75 DEG C, in 65 DEG C of dry 26h, is cooled to room temperature and obtains material A；By 2 parts of paraffin, 4.5
Part polypropylene and 3 parts of carbamates are well mixed, and are heated to 475 DEG C, are incubated 13min, are cooled to normal temperature, then add material
A, 3 parts of potassium peroxydisulfates, 3.5 parts of polytetrafluoroethylene (PTFE) and 4 parts of aluminum stearates are well mixed, and are warming up to 82 DEG C, are incubated 12min, then
Ball milling 25min, then adds 3 parts of aluminium hydroxides, 3.5 parts of multi-walled carbon nanotubes and 4 parts of methyl methacrylates and is well mixed, rise
Temperature is incubated 35min to 125 DEG C, and 2.5h is stirred in 1800r/min rotating speeds, dries, and grinding is cooled to room temperature and obtains water tight packing.
Color inhibition filler is prepared by following technique：22 parts of nano titanium oxides and 9 parts of ethanol are mixed by weight
Uniformly, ultrasonic disperse 25min, is subsequently added into 5 parts of hexadecyl trimethoxy ammonium chlorides, 4 parts of dimethyl silicone polymers, 2 parts of carbon
Sour sodium and 4.5 parts of sodium sulfate of polyethenoxy ether of fatty alcohol are well mixed, magnetic agitation 18min, then with ammoniacal liquor adjust pH to
9.2, then add 3 parts of AEOs and be well mixed, be warming up to 38 DEG C, be incubated 23h, then centrifugation is washed to pH extremely
For neutrality, it is cooled to room temperature and obtains material a；3 parts of APPs and 4 parts of propyl alcohol are well mixed, 75 DEG C, insulation are then heated to
25min, is subsequently added into 3.5 parts of silane resin acceptor kh-550s and 2 parts of isomeric alcohol polyethenoxy ethers are well mixed, and turns in 820r/min
Speed stirring 15min, pH is to 4.5 for regulation, then heats to 68 DEG C, is incubated 1.2h, is dried after washing in vacuum in 68 DEG C to constant weight,
Room temperature is cooled to, 8 parts of methylcellulose is then added and material a is well mixed, stir 18min in 85r/min rotating speeds, be warming up to
152 DEG C, 18min is incubated, room temperature is cooled to and obtains color inhibition filler.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.
Claims (7)
- The window table color inhibition waterproof heat resistant quartz stone composite material 1. one kind is floatd, it is characterised in that its raw material is wrapped by weight Include：90-110 parts of calcining quartz stone sand, 4-8 parts of polyurethane resin, 2-6 parts of unsaturated polyester resin, 1-5 parts of epoxy resin, second 3-5 parts of vinyl pyrrolidone polymer, 2-6 parts of silicone alkyd, 1-5 parts of amino resins, benzoyl peroxide 3-6 Part, 3-6 parts of peroxide -2-ethyl hexanoic acid tert-butyl, 3-6 parts of IPDI, 2-4 parts of trimethylolpropane, two 2-5 parts of dibutyl tin laurate, 2-6 parts of ethylene vinyl acetate, 2-5 parts of polyvinyl acetate, 1-5 parts of accelerator, colorant 1-5 Part, 4-6 parts of silane coupler KH-560,15-25 parts of color inhibition filler, 8-16 parts of water tight packing.
- 2. the quartzy stone composite material of the window table color inhibition waterproof heat resistant that floats according to claim 1, it is characterised in that anti- The raw material of water packing includes by weight：5-15 parts of acetylbutyrylcellulose, 2-6 parts of antimony trioxide, 1-4 parts of magnetizable powder, silane 3-6 parts of coupling agent kh-570,2-6 parts of ethanol, 1-4 parts of paraffin, 3-5 parts of polypropylene, 2-5 parts of carbamate, potassium peroxydisulfate 1- 4 parts, 3-5 parts of polytetrafluoroethylene (PTFE), 2-5 parts of aluminum stearate, 1-4 parts of aluminium hydroxide, 3-5 parts of multi-walled carbon nanotube, methacrylic acid 2-5 parts of methyl esters.
- 3. the quartzy stone composite material of the window table color inhibition waterproof heat resistant that floats according to claim 1 or 2, its feature exists In water tight packing is prepared by following technique：By acetylbutyrylcellulose, antimony trioxide, magnetizable powder, silane coupler KH- 570 and ethanol it is well mixed, stirring then heats up, and is incubated, and is dried after suction filtration, dries, is cooled to room temperature and obtains material A；By stone Wax, polypropylene and carbamate are well mixed, heat, and insulation is cooled to normal temperature, then add material A, potassium peroxydisulfate, gather Tetrafluoroethene and aluminum stearate are well mixed, heat up, insulation, then ball milling, then add aluminium hydroxide, multi-walled carbon nanotube and Methyl methacrylate is well mixed, and is heated up, and is incubated, and is stirred, and is dried, and grinding is cooled to room temperature and obtains water tight packing.
- 4. the quartzy stone composite material of the window table color inhibition waterproof heat resistant that floats according to claim any one of 1-3, it is special Levy and be, water tight packing is prepared by following technique：By acetylbutyrylcellulose, antimony trioxide, magnetizable powder, silane coupler KH-570 and ethanol are well mixed, and 20-40min is stirred in 650-850r/min rotating speeds, are then warming up to 70-90 DEG C, are incubated 3- Dried after 5h, suction filtration, in 60-80 DEG C of dry 20-28h, be cooled to room temperature and obtain material A；By paraffin, polypropylene and carbamic acid Ester is well mixed, and is heated to 320-480 DEG C, is incubated 12-18min, is cooled to normal temperature, is then added material A, potassium peroxydisulfate, is gathered Tetrafluoroethene and aluminum stearate are well mixed, are warming up to 80-90 DEG C, are incubated 5-15min, then ball milling 20-40min, Ran Houjia Enter aluminium hydroxide, multi-walled carbon nanotube and methyl methacrylate well mixed, be warming up to 120-140 DEG C, be incubated 20-40min, 1-3h is stirred in 1500-2500r/min rotating speeds, is dried, grinding is cooled to room temperature and obtains water tight packing.
- 5. the quartzy stone composite material of the window table color inhibition waterproof heat resistant that floats according to claim any one of 1-4, it is special Levy and be, the raw material of color inhibition filler includes by weight：15-25 parts of nano titanium oxide, 8-16 parts of ethanol, cetyl three 4-8 parts of methoxy ammonium chloride, 2-5 parts of dimethyl silicone polymer, 1-4 parts of sodium carbonate, sodium sulfate of polyethenoxy ether of fatty alcohol 3-5 Part, 2-5 parts of AEO, 1-4 parts of APP, 3-6 parts of propyl alcohol, 2-4 parts of silane resin acceptor kh-550, isomery 1-5 parts of alcohol APEO, 3-9 parts of methylcellulose.
- 6. the quartzy stone composite material of the window table color inhibition waterproof heat resistant that floats according to claim any one of 1-5, it is special Levy and be, color inhibition filler is prepared by following technique：Nano titanium oxide and ethanol are well mixed, ultrasonic disperse connects Addition hexadecyl trimethoxy ammonium chloride, dimethyl silicone polymer, sodium carbonate and sodium sulfate of polyethenoxy ether of fatty alcohol mixed Close uniform, magnetic agitation then adjusts pH with ammoniacal liquor, then add AEO and be well mixed, heat up, insulation, Then to be washed to pH most neutral for centrifugation, is cooled to room temperature and obtains material a；APP and propyl alcohol are well mixed, Ran Housheng Temperature, insulation, is subsequently added into silane resin acceptor kh-550 and isomeric alcohol polyethenoxy ether is well mixed, stirring, adjusts pH, Ran Housheng Temperature, insulation is dried to constant weight in vacuum after washing, is cooled to room temperature, then adds methylcellulose and material a is well mixed, Stirring, heats up, and insulation is cooled to room temperature and obtains color inhibition filler.
- 7. the quartzy stone composite material of the window table color inhibition waterproof heat resistant that floats according to claim any one of 1-6, it is special Levy and be, color inhibition filler is prepared by following technique：Nano titanium oxide and ethanol are well mixed, ultrasonic disperse 10- 30min, is subsequently added into hexadecyl trimethoxy ammonium chloride, dimethyl silicone polymer, sodium carbonate and AEO Sodium sulphate is well mixed, magnetic agitation 15-25min, then adjusts pH to 8.5-9.5 with ammoniacal liquor, then adds fatty alcohol polyoxy Vinethene is well mixed, and is warming up to 30-40 DEG C, is incubated 22-26h, and then to be washed to pH most neutral for centrifugation, is cooled to room temperature and obtains To material a；APP and propyl alcohol are well mixed, 60-80 DEG C is then heated to, 20-40min is incubated, is subsequently added into silane Coupling agent KH-550 and isomeric alcohol polyethenoxy ether are well mixed, and 10-30min is stirred in 650-850r/min rotating speeds, adjust pH To 3.5-5.0,65-75 DEG C is then heated to, 0.5-1.5h is incubated, dried after washing in vacuum in 65-75 DEG C to constant weight, cooling To room temperature, then add methylcellulose and material a is well mixed, stir 10-20min in 80-120r/min rotating speeds, be warming up to 150-160 DEG C, 10-20min is incubated, room temperature is cooled to and obtains color inhibition filler.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710614536.6A CN107311524A (en) | 2017-07-25 | 2017-07-25 | One kind is floatd the quartzy stone composite material of window table color inhibition waterproof heat resistant |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710614536.6A CN107311524A (en) | 2017-07-25 | 2017-07-25 | One kind is floatd the quartzy stone composite material of window table color inhibition waterproof heat resistant |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107311524A true CN107311524A (en) | 2017-11-03 |
Family
ID=60179101
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710614536.6A Withdrawn CN107311524A (en) | 2017-07-25 | 2017-07-25 | One kind is floatd the quartzy stone composite material of window table color inhibition waterproof heat resistant |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107311524A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107641448A (en) * | 2017-11-10 | 2018-01-30 | 天长市优信电器设备有限公司 | A kind of aluminum charger case waterproof fireproofing coating |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104003653A (en) * | 2014-05-20 | 2014-08-27 | 深圳市国大长兴科技有限公司 | Tempered artificial quartz stone and preparation method thereof |
| CN106866030A (en) * | 2017-03-22 | 2017-06-20 | 佛山市蓝瑞欧特信息服务有限公司 | A kind of water-fast artificial quartz in lump and preparation method thereof |
-
2017
- 2017-07-25 CN CN201710614536.6A patent/CN107311524A/en not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104003653A (en) * | 2014-05-20 | 2014-08-27 | 深圳市国大长兴科技有限公司 | Tempered artificial quartz stone and preparation method thereof |
| CN106866030A (en) * | 2017-03-22 | 2017-06-20 | 佛山市蓝瑞欧特信息服务有限公司 | A kind of water-fast artificial quartz in lump and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107641448A (en) * | 2017-11-10 | 2018-01-30 | 天长市优信电器设备有限公司 | A kind of aluminum charger case waterproof fireproofing coating |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105131764B (en) | A kind of reflective insulation texture paint and preparation method thereof | |
| CN103225216B (en) | Preparation method for environment-friendly textile pigment | |
| CN101845124B (en) | Water-based hydrophobic nano-resin, glass thermal insulating coating and preparation method | |
| CN107841223A (en) | A kind of coated by titanium dioxide hollow glass micropearl insulating moulding coating and preparation method thereof | |
| CN106381709A (en) | Super-hydrophobic and anti-ultraviolet finishing agent used for textiles, and preparation method and application thereof | |
| CN107311524A (en) | One kind is floatd the quartzy stone composite material of window table color inhibition waterproof heat resistant | |
| CN110330848A (en) | A kind of mould proof temperature control type building coating of aqueous, environmental protective and preparation method thereof | |
| CN106752631A (en) | A kind of aqueous self-clean type Graphene modified nano heat-insulating reflective coating | |
| CN109897409A (en) | Nanometer environmental protection paint and preparation method thereof | |
| CN111849276A (en) | Water-resistant real stone paint and preparation method thereof | |
| CN107651850A (en) | A kind of heat-resisting bristol glaze of scratch resistance | |
| CN105885688A (en) | Preparation method of weather-resistance modified silicon resin exterior wall coating material | |
| CN109111808A (en) | A kind of solar energy heat absorbing coating and preparation method thereof | |
| CN103570861A (en) | Emulsion for waterproof paint as well as preparation method thereof | |
| CN106497257A (en) | Heat-insulated radial pattern coating of the enhanced fluorine carbon of a kind of Titanium Dioxide and preparation method thereof | |
| CN107151357A (en) | A kind of floating power station vibration resistance tension UV resistant high-low temperature resistant CABLE MATERIALS | |
| CN107698926A (en) | A kind of wear-resisting 3D printing material of building water-proof | |
| CN107446445A (en) | A kind of reflective heat-insulation paint and preparation method thereof | |
| CN108976954A (en) | A kind of preparation method of the roof insulating water-proof pad filling-modified insulating moulding coating of nano antimony tin oxide-bead | |
| CN106380948A (en) | Wear-resistant fluorocarbon heat-insulation radiation-type paint and preparation method thereof | |
| CN106497256A (en) | Heat-insulated radial pattern coating of a kind of colored fluorine carbon and preparation method thereof | |
| CN114479596B (en) | White carbon black composite supermolecule reflection heat insulation material and preparation method thereof | |
| CN106497255A (en) | Heat-insulated radial pattern coating of the fluorine carbon of a kind of glass fiber reinforcement and preparation method thereof | |
| CN110256972A (en) | A kind of Cerate special for blackwood furniture and preparation method for cerate | |
| CN106497254A (en) | Heat-insulated radial pattern coating of a kind of corrosion resistant fluorine carbon and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20171103 |
|
| WW01 | Invention patent application withdrawn after publication |