CN107651850A - A kind of heat-resisting bristol glaze of scratch resistance - Google Patents
A kind of heat-resisting bristol glaze of scratch resistance Download PDFInfo
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- CN107651850A CN107651850A CN201710846446.XA CN201710846446A CN107651850A CN 107651850 A CN107651850 A CN 107651850A CN 201710846446 A CN201710846446 A CN 201710846446A CN 107651850 A CN107651850 A CN 107651850A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/18—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing free metals
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Abstract
The invention discloses a kind of heat-resisting bristol glaze of scratch resistance, its raw material includes clay, polymethacrylates, hydroxy acryl acid resin, organic siliconresin, epoxy resin E 13, aluminium powder, nano silicon, nano titanium oxide, chrysotile, ceramic powder, butyl glycol ether, HMMM, dimethylethanolamine, isopropanol, calgon, butyl acetate, silane coupler KH 550, scratch resistance filler and heat resistance modified auxiliary agent.The bristol glaze of the present invention has excellent scratch resistance and heat resistance.
Description
Technical field
The present invention relates to the technical field of ceramic glaze material, more particularly to a kind of heat-resisting bristol glaze of scratch resistance.
Background technology
It is attached to the glassy thin layer on ceramic body surface.With raw mineral materials, (such as feldspar, quartz, kaolin and chemical industry are former
Material mixes and is finely ground into paste liquid according to a certain ratio, imposes on billet surface, is formed through high-temperature calcination.In terms of microstructure, contain
The crystal separated out when glass state material and a small amount of bubble, non-vitreous silica particle and cooling.With the physics for being analogous to glassy state
And chemical characteristic, it is waterproof, it is smooth and glossy, it is not easy to stain, and the mechanical strength, heat endurance and chemistry of product can be improved
Stability.Glaze paint can also use various decorations with the artistic effect of enhanced article.The scratch resistance of bristol glaze and heat resistance in the prior art
The needs of when be able to not can meet to actually use, so needing a kind of heat-resisting bristol glaze of scratch resistance of exploitation badly to solve of the prior art ask
Topic.
The content of the invention
To solve technical problem present in background technology, the present invention proposes a kind of heat-resisting bristol glaze of scratch resistance, has excellent
Scratch resistance and heat resistance.
The heat-resisting bristol glaze of a kind of scratch resistance proposed by the present invention, its raw material include by weight：Clay 80-120 parts, poly- methyl-prop
Olefin(e) acid ester 25-35 parts, hydroxy acryl acid resin 2-8 parts, organic siliconresin 1-5 parts, epoxy resin E-13 3-6 parts, aluminium powder 2-
5 parts, nano silicon 1-4 parts, nano titanium oxide 2-8 parts, chrysotile 3-6 parts, ceramic powder 1-8 parts, butyl glycol ether 1-3
Part, HMMM 2-6 parts, dimethylethanolamine 1-4 parts, isopropanol 2-4 parts, calgon 3-5 parts, vinegar
Acid butyl ester 1-4 parts, silane resin acceptor kh-550 2-5 parts, scratch resistance filler 10-20 parts, heat resistance modified auxiliary agent 5-15 parts.
Preferably, the raw material of scratch resistance filler includes by weight：Silane coupler KH-560 20-40 parts, distilled water 15-
25 parts, carbon black 4-8 parts, tapioca starch 3-6 parts, montmorillonite 2-5 parts, kaolin 1-4 parts, multi-walled carbon nanotube 3-6 parts, nano silicon carbide
Silicon 2-5 parts, nano silicon 4-8 parts, Nano diamond 3-6 parts, attapulgite 2-5 parts, thionyl chloride 1-5 parts, 2- propylene-
1- alcohol 2-6 parts, dichloroethanes 1-5 parts.
Preferably, scratch resistance filler is prepared by following technique：Silane coupler KH-560 and distilled water are well mixed,
Be then placed in water-bath and heat, be subsequently added into carbon black, tapioca starch, montmorillonite, kaolin, multi-walled carbon nanotube, nanometer silicon carbide,
Nano silicon, Nano diamond, attapulgite, thionyl chloride, 2- propylene -1- alcohol and dichloroethanes are well mixed, heating,
Insulation, is followed by stirring for, then adjusts pH, cools, and insulation, then carries out separation of solid and liquid, washs, distillation dehydration, then will dehydration
Powder afterwards is put into baking oven and dried, and is cooled to room temperature and obtains scratch resistance filler.
Preferably, scratch resistance filler is prepared by following technique：Silane coupler KH-560 and distilled water are well mixed,
It is then placed in water-bath and heats 25-35min, is subsequently added into carbon black, tapioca starch, montmorillonite, kaolin, multi-walled carbon nanotube, receives
Rice carborundum, nano silicon, Nano diamond, attapulgite, thionyl chloride, 2- propylene -1- alcohol and dichloroethanes mixing
Uniformly, 120-140 DEG C is warming up to, is incubated 20-40min, then 10-20min is stirred in 650-850r/min rotating speeds, then adjusts
PH to 2.5-3.5,80-90 DEG C is cooled to, is incubated 25-35min, then carries out separation of solid and liquid, washed, distillation dehydration, then will
Powder after dehydration, which is put into 100-120 DEG C of baking oven, dries 1-3h, is cooled to room temperature and obtains scratch resistance filler.
Preferably, the raw material of heat resistance modified auxiliary agent includes by weight：Mass fraction is 10-20% formalin 4-8
Part, urea 2-6 parts, magnesium hydroxide 3-5 parts, nylon 4-8 parts, Silane coupling reagent KH-570 3-9 parts, polyamide polyamines 2-5 parts,
Epoxychloropropane 1-5 parts, styrene 4-8 parts, methyl methacrylate 1-3 parts, divinylbenzene 2-5 parts, potassium peroxydisulfate 1-4 parts,
Aluminium hydroxide 3-6 parts, Firebrake ZB 4-8 parts.
Preferably, heat resistance modified auxiliary agent is prepared by following technique：The formalin that mass fraction is 10-20% is adjusted
PH processed, then add urea and be well mixed, heat up, insulation, then modulate pH, be then down to room temperature, add magnesium hydroxide, Buddhist nun
Dragon, Silane coupling reagent KH-570, polyamide polyamines and epoxychloropropane are well mixed, and are adjusted to pH, stirring, are cooled to room temperature and are obtained
Material A；Styrene, methyl methacrylate, material A and divinylbenzene are well mixed, heated up, insulation, then adds over cure
Sour potassium is well mixed, and continues to heat up, and insulation, then adds aluminium hydroxide and Firebrake ZB is well mixed, and is stirred, and is heated up, and insulation is cold
But to room temperature, washing, heat resistance modified auxiliary agent is obtained after drying.
Preferably, heat resistance modified auxiliary agent is prepared by following technique：The formalin that mass fraction is 10-20% is adjusted
PH processed to 9.3-9.7, then add urea and be well mixed, be warming up to 85-95 DEG C, be incubated 40-50min, then modulate pH extremely
4.5-5.5, room temperature is then down to, adds magnesium hydroxide, nylon, Silane coupling reagent KH-570, polyamide polyamines and epoxy chloropropionate
Alkane is well mixed, and is adjusted to pH to 7.2-7.7, is stirred 1-3h in 650-850r/min rotating speeds, is cooled to room temperature and obtains material A；Will
Styrene, methyl methacrylate, material A and divinylbenzene are well mixed, and are warming up to 45-55 DEG C, are incubated 5-15min, then
Add potassium peroxydisulfate to be well mixed, be continuously heating to 60-80 DEG C, be incubated 3-5h, then add aluminium hydroxide and Firebrake ZB mixing
Uniformly, 20-40min is stirred in 1500-2500r/min rotating speeds, is warming up to 65-85 DEG C, be incubated 30-50min, be cooled to room temperature,
Washing, heat resistance modified auxiliary agent is obtained after drying.
A kind of heat-resisting bristol glaze of scratch resistance of the present invention, its raw material include clay, polymethacrylates, hydroxy acryl acid tree
Fat, organic siliconresin, epoxy resin E-13, aluminium powder, nano silicon, nano titanium oxide, chrysotile, ceramic powder, second two
It is alcohol butyl ether, HMMM, dimethylethanolamine, isopropanol, calgon, butyl acetate, silane coupled
Agent KH-550, scratch resistance filler and heat resistance modified auxiliary agent.Wherein using clay as major ingredient, with polymethacrylates, hydroxyl propylene
Acid resin, organic siliconresin and epoxy resin E-13 are resin binder, with aluminium powder, nano silicon, nano titanium oxide, temperature
Asbestos and ceramic powder are filler, with butyl glycol ether, HMMM, dimethylethanolamine, isopropanol, six inclined
Sodium phosphate, butyl acetate, silane resin acceptor kh-550, scratch resistance filler and heat resistance modified auxiliary agent are modification strengthening agent, by major ingredient,
Resin binder, filler and modified reinforcing aids coordinate, and obtained bristol glaze has excellent scratch resistance and heat resistance.Wherein, scratch resistance
Filler is then placed in water-bath and heated, be subsequently added into carbon black, wood by the way that silane coupler KH-560 and distilled water are well mixed
Potato powder, montmorillonite, kaolin, multi-walled carbon nanotube, nanometer silicon carbide, nano silicon, Nano diamond, attapulgite,
Thionyl chloride, 2- propylene -1- alcohol and dichloroethanes are well mixed, and are heated up, and insulation, are followed by stirring for, are then adjusted pH, are cooled, and are protected
Temperature, separation of solid and liquid is then carried out, washed, distillation dehydration, then the powder after dehydration is put into baking oven and dried, is cooled to room temperature
Scratch resistance filler is obtained, applies in the bristol glaze of the present invention, the cooperation with major ingredient, resin binder and filler, imparts pottery of the present invention
The excellent scratch resistance performance of glaze.Wherein, heat resistance modified auxiliary agent by the formalin that mass fraction is 10-20% by modulating pH, so
Urea is added afterwards to be well mixed, and is heated up, insulation, is then modulated pH, be then down to room temperature, it is even to add magnesium hydroxide, nylon, silane
Connection agent KH-570, polyamide polyamines and epoxychloropropane are well mixed, and are adjusted to pH, are stirred, are cooled to room temperature and obtain material A；Will
Styrene, methyl methacrylate, material A and divinylbenzene are well mixed, and are heated up, insulation, then add potassium peroxydisulfate mixing
Uniformly, continue to heat up, be incubated, then add aluminium hydroxide and Firebrake ZB is well mixed, stir, heat up, insulation, be cooled to room
Temperature, washing, heat resistance modified auxiliary agent is obtained after drying, apply in the bristol glaze of the present invention, match somebody with somebody with major ingredient, resin binder and filler
Close, impart the excellent heat resistance of bristol glaze of the present invention.The bristol glaze of the present invention has excellent scratch resistance and heat resistance.
Embodiment
The present invention is described in detail with reference to specific embodiment, it should be appreciated that embodiment is served only for illustrating this hair
It is bright, rather than for limiting the invention, any modification made on the basis of the present invention, equivalent substitution etc. are in this hair
In bright protection domain.
In embodiment, the parts by weight of clay can be 80 parts, 85 parts, 90 parts, 95 parts, 100 parts, 105 parts, 110
Part, 115 parts, 120 parts；The parts by weight of polymethacrylates can be 25 parts, 26 parts, 27 parts, 28 parts, 29 parts, 30 parts, 31
Part, 32 parts, 33 parts, 34 parts, 35 parts；The parts by weight of hydroxy acryl acid resin can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts,
8 parts；The parts by weight of organic siliconresin can be 1 part, 2 parts, 3 parts, 4 parts, 5 parts；Epoxy resin E-13 parts by weight can be 3
Part, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The parts by weight of aluminium powder can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts,
4.5 parts, 5 parts；The parts by weight of nano silicon can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；Nanometer two
The parts by weight of titanium oxide can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts；The parts by weight of chrysotile can be 3 parts, 3.5
Part, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The parts by weight of ceramic powder can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts,
4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts；The parts by weight of butyl glycol ether can be 1 part, 1.5
Part, 2 parts, 2.5 parts, 3 parts；The parts by weight of HMMM can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts；Dimethyl
The parts by weight of monoethanolamine can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；The parts by weight of isopropanol can be 2
Part, 2.5 parts, 3 parts, 3.5 parts, 4 parts；The parts by weight of calgon can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；Acetic acid fourth
The parts by weight of ester can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；The parts by weight of silane resin acceptor kh-550 can
Think 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The parts by weight of scratch resistance filler can be 10 parts, 11 parts, 12 parts, 13
Part, 14 parts, 15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts；The parts by weight of heat resistance modified auxiliary agent can be 5 parts, 6 parts, 7 parts, 8
Part, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts.
Embodiment 1
The heat-resisting bristol glaze of a kind of scratch resistance proposed by the present invention, its raw material include by weight：100 parts of clay, polymethyl
30 parts of acid esters, 5 parts of hydroxy acryl acid resin, 3 parts of organic siliconresin, epoxy resin E-134.5 parts, part, nanometer two of aluminium powder 3.5
2.5 parts of silica, 5 parts of nano titanium oxide, 4.5 parts of chrysotile, 4.5 parts of ceramic powder, 2 parts of butyl glycol ether, hexa methoxy first
4 parts of base melamine, 2.5 parts of dimethylethanolamine, 3 parts of isopropanol, 4 parts of calgon, 2.5 parts of butyl acetate, silane are even
Join 3.5 parts of agent KH-550,15 parts of scratch resistance filler, 10 parts of heat resistance modified auxiliary agent.
Scratch resistance filler is prepared by following technique：By weight by 30 parts of silane coupler KH-560 and 20 parts of distilled water
It is well mixed, it is then placed in water-bath and heats 30min, is subsequently added into 6 parts of carbon blacks, 4.5 parts of tapioca starch, 3.5 parts of montmorillonites, 2.5
Part kaolin, 4.5 parts of multi-walled carbon nanotubes, 3.5 parts of nanometer silicon carbides, 6 parts of nano silicons, 4.5 parts of Nano diamonds,
3.5 parts of attapulgites, 3 parts of thionyl chlorides, 4 parts of 2- propylene -1- alcohol and 3 parts of dichloroethanes are well mixed, and are warming up to 130 DEG C, are protected
Warm 30min, 15min then is stirred in 750r/min rotating speeds, then adjust pH to 3, be cooled to 85 DEG C, be incubated 30min, then enter
Row separation of solid and liquid, washing, distillation dehydration, then the powder after dehydration is put into 110 DEG C of baking ovens and dries 2h, room temperature is cooled to and obtains
To scratch resistance filler.
Heat resistance modified auxiliary agent is prepared by following technique：By weight by 6 parts of mass fractions be 15% formalin
PH to 9.5 is modulated, 4 parts of urea is then added and is well mixed, be warming up to 90 DEG C, be incubated 45min, then modulate pH to 5, then drop
To room temperature, 4 parts of magnesium hydroxides, 6 parts of nylon, 6 parts of Silane coupling reagent KH-570s, 3.5 parts of polyamide polyamines and 3 parts of epoxy chlorine are added
Propane is well mixed, and is adjusted to pH to 7.4, is stirred 2h in 750r/min rotating speeds, is cooled to room temperature and obtains material A；By 6 parts of benzene second
Alkene, 2 parts of methyl methacrylates, material A and 3.5 parts of divinylbenzenes are well mixed, and are warming up to 50 DEG C, are incubated 10min, Ran Houjia
Enter 2.5 parts of potassium peroxydisulfates to be well mixed, be continuously heating to 70 DEG C, be incubated 4h, then add 4.5 parts of aluminium hydroxides and 6 parts of boric acid
Zinc is well mixed, and is stirred 30min in 2000r/min rotating speeds, is warming up to 75 DEG C, be incubated 40min, be cooled to room temperature, wash, dries
After obtain heat resistance modified auxiliary agent.
Embodiment 2
The heat-resisting bristol glaze of a kind of scratch resistance proposed by the present invention, its raw material include by weight：80 parts of clay, polymethylacrylic acid
35 parts of ester, 2 parts of hydroxy acryl acid resin, 5 parts of organic siliconresin, 3 parts of epoxy resin E-13,5 parts of aluminium powder, nanometer titanium dioxide
1 part of silicon, 8 parts of nano titanium oxide, 3 parts of chrysotile, 8 parts of ceramic powder, 1 part of butyl glycol ether, HMMM 6
Part, 1 part of dimethylethanolamine, 4 parts of isopropanol, 3 parts of calgon, 4 parts of butyl acetate, 2 parts of silane resin acceptor kh-550,
20 parts of scratch resistance filler, 5 parts of heat resistance modified auxiliary agent.
Scratch resistance filler is prepared by following technique：By weight by 20 parts of silane coupler KH-560 and 25 parts of distilled water
It is well mixed, it is then placed in water-bath and heats 25min, is subsequently added into 8 parts of carbon blacks, 3 parts of tapioca starch, 5 parts of montmorillonites, 1 part of kaolinite
Soil, 6 parts of multi-walled carbon nanotubes, 2 parts of nanometer silicon carbides, 8 parts of nano silicons, 3 parts of Nano diamonds, 5 parts of attapulgites, 1
Part thionyl chloride, 6 parts of 2- propylene -1- alcohol and 1 part of dichloroethanes are well mixed, and are warming up to 140 DEG C, are incubated 20min, then in
850r/min rotating speeds stir 10min, then adjust pH to 3.5, are cooled to 80 DEG C, are incubated 35min, then carry out separation of solid and liquid,
Washing, distillation dehydration, then the powder after dehydration is put into 100 DEG C of baking ovens and dries 3h, room temperature is cooled to and obtains scratch resistance filler.
Heat resistance modified auxiliary agent is prepared by following technique：By weight by 4 parts of mass fractions be 20% formalin
PH to 9.3 is modulated, then plus 6 parts of urea are well mixed, and are warming up to 85 DEG C, are incubated 50min, are then modulated pH to 4.5, are then dropped
To room temperature, 5 parts of magnesium hydroxides, 4 parts of nylon, 9 parts of Silane coupling reagent KH-570s, 2 parts of polyamide polyamines and 5 parts of epoxy chloropropionates are added
Alkane is well mixed, and is adjusted to pH to 7.2, is stirred 1h in 850r/min rotating speeds, is cooled to room temperature and obtains material A；By 8 parts of styrene, 1
Part methyl methacrylate, material A and 5 parts of divinylbenzenes are well mixed, and are warming up to 45 DEG C, are incubated 15min, then add 1 part
Potassium peroxydisulfate is well mixed, and is continuously heating to 80 DEG C, is incubated 3h, then adds 6 parts of aluminium hydroxides and 4 parts of Firebrake ZB mixing are equal
It is even, 20min is stirred in 2500r/min rotating speeds, is warming up to 85 DEG C, 30min is incubated, is cooled to room temperature, is washed, is obtained after drying resistance to
Heat modification auxiliary agent.
Embodiment 3
The heat-resisting bristol glaze of a kind of scratch resistance proposed by the present invention, its raw material include by weight：120 parts of clay, polymethyl
25 parts of acid esters, 8 parts of hydroxy acryl acid resin, 1 part of organic siliconresin, epoxy resin E-133 parts, 5 parts of aluminium powder, nanometer titanium dioxide
1 part of silicon, 8 parts of nano titanium oxide, 3 parts of chrysotile, 8 parts of ceramic powder, 1 part of butyl glycol ether, HMMM 6
Part, 1 part of dimethylethanolamine, 4 parts of isopropanol, 3 parts of calgon, 4 parts of butyl acetate, 2 parts of silane resin acceptor kh-550,
20 parts of scratch resistance filler, 5 parts of heat resistance modified auxiliary agent.
Scratch resistance filler is prepared by following technique：By weight by 40 parts of silane coupler KH-560 and 15 parts of distilled water
It is well mixed, it is then placed in water-bath and heats 35min, is subsequently added into 4 parts of carbon blacks, 6 parts of tapioca starch, 2 parts of montmorillonites, 4 parts of kaolinites
Soil, 3 parts of multi-walled carbon nanotubes, 5 parts of nanometer silicon carbides, 4 parts of nano silicons, 6 parts of Nano diamonds, 2 parts of attapulgites, 5
Part thionyl chloride, 2 parts of 2- propylene -1- alcohol and 5 parts of dichloroethanes are well mixed, and are warming up to 120 DEG C, are incubated 40min, then in
650r/min rotating speeds stir 20min, then adjust pH to 2.5, are cooled to 90 DEG C, are incubated 25min, then carry out separation of solid and liquid,
Washing, distillation dehydration, then the powder after dehydration is put into 120 DEG C of baking ovens and dries 1h, room temperature is cooled to and obtains scratch resistance filler.
Heat resistance modified auxiliary agent is prepared by following technique：By weight by 8 parts of mass fractions be 10% formalin
PH to 9.7 is modulated, 2 parts of urea is then added and is well mixed, be warming up to 95 DEG C, be incubated 40min, then modulate pH to 5.5, then
Room temperature is down to, adds 3 parts of magnesium hydroxides, 8 parts of nylon, 3 parts of Silane coupling reagent KH-570s, 5 parts of polyamide polyamines and 1 part of epoxy chlorine
Propane is well mixed, and is adjusted to pH to 7.7, is stirred 3h in 650r/min rotating speeds, is cooled to room temperature and obtains material A；By 4 parts of benzene second
Alkene, 3 parts of methyl methacrylates, material A and 2 parts of divinylbenzenes are well mixed, and are warming up to 55 DEG C, are incubated 5min, are then added 4
Part potassium peroxydisulfate is well mixed, and is continuously heating to 60 DEG C, is incubated 5h, then adds 3 parts of aluminium hydroxides and 8 parts of Firebrake ZBs mixing are equal
It is even, 40min is stirred in 1500r/min rotating speeds, is warming up to 65 DEG C, 50min is incubated, is cooled to room temperature, is washed, is obtained after drying resistance to
Heat modification auxiliary agent.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.
Claims (7)
1. a kind of heat-resisting bristol glaze of scratch resistance, it is characterised in that its raw material includes by weight：Clay 80-120 parts, polymethyl
Acid esters 25-35 parts, hydroxy acryl acid resin 2-8 parts, organic siliconresin 1-5 parts, epoxy resin E-13 3-6 parts, aluminium powder 2-5
Part, nano silicon 1-4 parts, nano titanium oxide 2-8 parts, chrysotile 3-6 parts, ceramic powder 1-8 parts, butyl glycol ether 1-3
Part, HMMM 2-6 parts, dimethylethanolamine 1-4 parts, isopropanol 2-4 parts, calgon 3-5 parts, vinegar
Acid butyl ester 1-4 parts, silane resin acceptor kh-550 2-5 parts, scratch resistance filler 10-20 parts, heat resistance modified auxiliary agent 5-15 parts.
2. the heat-resisting bristol glaze of scratch resistance according to claim 1, it is characterised in that the raw material of scratch resistance filler includes by weight：
Silane coupler KH-560 20-40 parts, distilled water 15-25 parts, carbon black 4-8 parts, tapioca starch 3-6 parts, montmorillonite 2-5 parts, kaolinite
Native 1-4 parts, multi-walled carbon nanotube 3-6 parts, nanometer silicon carbide 2-5 parts, nano silicon 4-8 parts, Nano diamond 3-6 parts,
Attapulgite 2-5 parts, thionyl chloride 1-5 parts, 2- propylene -1- alcohol 2-6 parts, dichloroethanes 1-5 parts.
3. the heat-resisting bristol glaze of scratch resistance according to claim 1 or 2, it is characterised in that scratch resistance filler is by following technique system
It is standby：Silane coupler KH-560 and distilled water are well mixed, is then placed in water-bath and heats, be subsequently added into carbon black, tapioca starch,
Montmorillonite, kaolin, multi-walled carbon nanotube, nanometer silicon carbide, nano silicon, Nano diamond, attapulgite, thionyl
Chlorine, 2- propylene -1- alcohol and dichloroethanes are well mixed, and are heated up, and insulation, are followed by stirring for, are then adjusted pH, are cooled, insulation, then
Carry out separation of solid and liquid, washing, distillation dehydration, then by the powder after dehydration be put into baking oven dry, be cooled to room temperature obtain it is resistance to
Scrape filler.
4. the heat-resisting bristol glaze of scratch resistance according to claim any one of 1-3, it is characterised in that scratch resistance filler is entered by following technique
It is prepared by row：Silane coupler KH-560 and distilled water are well mixed, is then placed in water-bath and heats 25-35min, is subsequently added into
It is carbon black, tapioca starch, montmorillonite, kaolin, multi-walled carbon nanotube, nanometer silicon carbide, nano silicon, Nano diamond, recessed
Convex rod soil, thionyl chloride, 2- propylene -1- alcohol and dichloroethanes are well mixed, and are warming up to 120-140 DEG C, are incubated 20-40min, are connect
And stir 10-20min in 650-850r/min rotating speeds, then adjust pH to 2.5-3.5, be cooled to 80-90 DEG C, be incubated 25-
35min, separation of solid and liquid is then carried out, washed, distillation dehydration, then the powder after dehydration is put into 100-120 DEG C of baking oven and done
Dry 1-3h, it is cooled to room temperature and obtains scratch resistance filler.
5. the heat-resisting bristol glaze of scratch resistance according to claim any one of 1-4, it is characterised in that the raw material of heat resistance modified auxiliary agent is pressed
Parts by weight include：Mass fraction is 10-20% formalin 4-8 parts, urea 2-6 parts, magnesium hydroxide 3-5 parts, nylon 4-8
Part, Silane coupling reagent KH-570 3-9 parts, polyamide polyamines 2-5 parts, epoxychloropropane 1-5 parts, styrene 4-8 parts, methyl-prop
E pioic acid methyl ester 1-3 parts, divinylbenzene 2-5 parts, potassium peroxydisulfate 1-4 parts, aluminium hydroxide 3-6 parts, Firebrake ZB 4-8 parts.
6. the heat-resisting bristol glaze of scratch resistance according to claim any one of 1-5, it is characterised in that heat resistance modified auxiliary agent presses following work
It is prepared by skill：The formalin that mass fraction is 10-20% is modulated into pH, urea is then added and is well mixed, heat up, protect
Temperature, pH is then modulated, be then down to room temperature, add magnesium hydroxide, nylon, Silane coupling reagent KH-570, polyamide polyamines and ring
Oxygen chloropropane is well mixed, and is adjusted to pH, stirring, is cooled to room temperature and is obtained material A；By styrene, methyl methacrylate, material
A and divinylbenzene are well mixed, and are heated up, insulation, are then added potassium peroxydisulfate and are well mixed, continue to heat up, are incubated, then add
Aluminium hydroxide and Firebrake ZB are well mixed, and are stirred, and are heated up, and insulation, are cooled to room temperature, are washed, and heat resistance modified help is obtained after drying
Agent.
7. the heat-resisting bristol glaze of scratch resistance according to claim any one of 1-6, it is characterised in that heat resistance modified auxiliary agent presses following work
It is prepared by skill：The formalin that mass fraction is 10-20% is modulated into pH to 9.3-9.7, urea is then added and is well mixed,
85-95 DEG C is warming up to, is incubated 40-50min, then modulates pH to 4.5-5.5, is then down to room temperature, adds magnesium hydroxide, Buddhist nun
Dragon, Silane coupling reagent KH-570, polyamide polyamines and epoxychloropropane are well mixed, and pH to 7.2-7.7 are adjusted to, in 650-
850r/min rotating speeds stir 1-3h, are cooled to room temperature and obtain material A；By styrene, methyl methacrylate, material A and diethyl
Alkene benzene is well mixed, and is warming up to 45-55 DEG C, is incubated 5-15min, is then added potassium peroxydisulfate and is well mixed, is continuously heating to 60-
80 DEG C, 3-5h is incubated, then aluminium hydroxide is added and Firebrake ZB is well mixed, 20- is stirred in 1500-2500r/min rotating speeds
40min, 65-85 DEG C is warming up to, is incubated 30-50min, is cooled to room temperature, washed, heat resistance modified auxiliary agent is obtained after drying.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108359331A (en) * | 2018-02-05 | 2018-08-03 | 崇义恒毅陶瓷复合材料有限公司 | The method and coating of coating are formed on ceramic matric composite surface |
| CN108529884A (en) * | 2018-07-09 | 2018-09-14 | 界首市伟盛古窑彩陶制作发展有限公司 | A kind of preparation method of unleaded glaze |
| CN113149437A (en) * | 2021-06-24 | 2021-07-23 | 广东欧文莱陶瓷有限公司 | High-hardness digital protective glaze |
-
2017
- 2017-09-19 CN CN201710846446.XA patent/CN107651850A/en not_active Withdrawn
Non-Patent Citations (1)
| Title |
|---|
| 地质矿产部地质辞典办公室: "《地质大辞典（二）矿物、岩石、地球化学分册》", 30 June 2005 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108359331A (en) * | 2018-02-05 | 2018-08-03 | 崇义恒毅陶瓷复合材料有限公司 | The method and coating of coating are formed on ceramic matric composite surface |
| CN108359331B (en) * | 2018-02-05 | 2020-05-22 | 崇义恒毅陶瓷复合材料有限公司 | Method for forming coating on surface of ceramic matrix composite material and coating |
| CN108529884A (en) * | 2018-07-09 | 2018-09-14 | 界首市伟盛古窑彩陶制作发展有限公司 | A kind of preparation method of unleaded glaze |
| CN113149437A (en) * | 2021-06-24 | 2021-07-23 | 广东欧文莱陶瓷有限公司 | High-hardness digital protective glaze |
| CN113149437B (en) * | 2021-06-24 | 2021-09-17 | 广东欧文莱陶瓷有限公司 | High-hardness digital protective glaze |
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