CN107383766A - A kind of high-temperature-resistant, tensile controls CABLE MATERIALS - Google Patents
A kind of high-temperature-resistant, tensile controls CABLE MATERIALS Download PDFInfo
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- CN107383766A CN107383766A CN201710770045.0A CN201710770045A CN107383766A CN 107383766 A CN107383766 A CN 107383766A CN 201710770045 A CN201710770045 A CN 201710770045A CN 107383766 A CN107383766 A CN 107383766A
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- C—CHEMISTRY; METALLURGY
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
- C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/36—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes condensation products of phenols with aldehydes or ketones
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Abstract
The invention discloses a kind of high-temperature-resistant, tensile to control CABLE MATERIALS, its raw material includes phenolic resin, silicon rubber, butadiene rubber, alkyd resin, neoprene, epoxy resin, coumarone indene resin, trimethyl phosphate, Firebrake ZB, carbon black, vermiculite, Firebrake ZB, nanometer silicon carbide, glass fibre, nano magnesia, kodalk, wood fiber powder, antimony oxide, nano-aluminum hydroxide, isocyanates, polysiloxanes, diisooctyl phthalate, silane coupler KH 550, chlorinated paraffin, APP, styrene, vulcanizing agent DTDM, plasticizer, heat resist modification auxiliary agent and tension modified additive.The control CABLE MATERIALS of the present invention has excellent high temperature resistant and tensile property.
Description
Technical field
The present invention relates to the technical field of CABLE MATERIALS, more particularly to a kind of high-temperature-resistant, tensile control CABLE MATERIALS.
Background technology
Control cable is cable for transmission of control signals, and control cable mainly solves that transmission signal is weak, signal is done
Disturb, distorted signals the problems such as.The CABLE MATERIALS that control cable of the prior art uses is required very its high temperature resistant and tensile property
Height, it is of the prior art control CABLE MATERIALS high temperature resistant and tensile property can not meet actual use when the needs of, so needing badly
A kind of high-temperature-resistant, tensile control CABLE MATERIALS is developed to solve the problems of the prior art.
The content of the invention
To solve technical problem present in background technology, the present invention proposes a kind of high-temperature-resistant, tensile control CABLE MATERIALS, tool
There are excellent high temperature resistant and tensile property.
A kind of high-temperature-resistant, tensile control CABLE MATERIALS proposed by the present invention, its raw material include by weight：Phenolic resin 30-90
Part, silicon rubber 10-30 parts, butadiene rubber 5-15 parts, alkyd resin 2-8 parts, neoprene 3-9 parts, epoxy resin 2-5 parts, Gu
The grand resin 2-6 parts of horse, trimethyl phosphate 2-8 parts, Firebrake ZB 1-5 parts, carbon black 3-6 parts, vermiculite 3-5 parts, Firebrake ZB 1-5 parts, receive
Rice carborundum 3-5 parts, glass fibre 4-8 parts, nano magnesia 4-8 parts, kodalk 2-8 parts, wood fiber powder 1-3 parts, three
It is different pungent to aoxidize two antimony 2-4 parts, nano-aluminum hydroxide 1-5 parts, isocyanates 3-8 parts, polysiloxanes 1-6 parts, phthalic acid two
Ester 3-8 parts, silane resin acceptor kh-550 2-5 parts, chlorinated paraffin 1-4 parts, APP 3-5 parts, styrene 4-8 parts, vulcanizing agent
DTDM 2-6 parts, plasticizer 3-5 parts, heat resist modification auxiliary agent 5-15 parts, tension modified additive 8-16 parts.
Preferably, the raw material of heat resist modification auxiliary agent includes by weight：Wollastonite 5-15 parts, nano-calcium carbonate 4-8 parts,
Zinc stearate 2-5 parts, Nano zinc dioxide impact-resistant 2-5 parts, nano aluminum nitride 1-3 parts, nano silicon 3-6 parts, rare-earth stearate
2-5 parts, lightweight calcium activated 1-4 parts, nano-ceramic powder 2-6 parts, silicon rubber 1-5 parts, poly- MTES 3-6 parts, two
Dibutyl tin laurate 1-5 parts, hydroxypropyl methyl cellulose 2-5 parts, methacrylate 1-4 parts, Silane coupling reagent KH-570
3-9 parts.
Preferably, heat resist modification auxiliary agent is prepared by following technique：Wollastonite is ground into powder, is then placed in
Dried in baking oven, then add nano-calcium carbonate and zinc stearate and be well mixed, seal stirring at low speed, then with nanometer titanium dioxide
Zinc, nano aluminum nitride, nano silicon, rare-earth stearate, lightweight calcium activated and nano-ceramic powder are well mixed, and seal low speed
Stirring, is cooled to room temperature and obtains material a；Silicon rubber and poly- MTES are mixed, are subsequently added into tin dilaurate two
Distilled water is then added dropwise in butyl tin, heating, and reaction obtains material a；By material a, material b, hydroxypropyl methyl cellulose, methyl
Acrylate and Silane coupling reagent KH-570 are well mixed, and stirring, are then heated, and are cooled to room temperature and are obtained heat resist modification and help
Agent.
Preferably, heat resist modification auxiliary agent is prepared by following technique：It is powdered that wollastonite is ground into 20-30 mesh,
It is then placed in 95-105 DEG C of baking oven and dries, then adds nano-calcium carbonate and zinc stearate is well mixed, in 50-60 DEG C of temperature
Sealing stirring at low speed 10-25min, then dilute with Nano zinc dioxide impact-resistant, nano aluminum nitride, nano silicon, stearic acid under degree
Soil, lightweight calcium activated and nano-ceramic powder are well mixed, and 45-55 DEG C of sealing stirring at low speed 5-10min, are cooled to room temperature and are obtained thing
Expect a；Silicon rubber and poly- MTES are mixed, dibutyl tin laurate is subsequently added into, is warming up to 70-90 DEG C,
Then distilled water is added dropwise, reacts 6-7h at 90-100 DEG C, obtains material a；By material a, material b, hydroxypropyl methyl cellulose,
Methacrylate and Silane coupling reagent KH-570 are well mixed, and 20-40min, Ran Houyu are stirred in 650-850r/min rotating speeds
1-3h is heated at 80-200 DEG C, room temperature is cooled to and obtains heat resist modification auxiliary agent.
Preferably, the raw material of tension modified additive includes by weight：Hexamethylene diamine 5-15 parts, phenylurea 4-8 parts, acetic acid second
Ester 3-6 parts, PLLA 2-5 parts, maleic anhydride 1-4 parts, ammonium persulfate 3-5 parts, styrene 2-6 parts, stearic acid 1-5 parts,
Silane coupler KH-560 3-9 parts.
Preferably, tension modified additive is prepared by following technique：Hexamethylene diamine and phenylurea are well mixed, heated up,
Insulation, then under nitrogen protection, backflow, room temperature is subsequently cooled to, adds ethyl acetate and be well mixed, then with salt pickling
Wash, dried after rotary evaporation to constant weight, be cooled to room temperature, then add PLLA and be well mixed, dry, be then blended,
Room temperature is cooled to, maleic anhydride is then added and is well mixed, then heat up, be incubated, ammonium persulfate is then added and is well mixed, stir
Add styrene after mixing, stearic acid and silane coupler KH-560 are well mixed, and are followed by stirring for, are then heated up, extract, then in
In vacuum drying oven, dry to constant weight, be cooled to room temperature and obtain tension modified additive.
Preferably, tension modified additive is prepared by following technique：Hexamethylene diamine and phenylurea are well mixed, are warming up to
80-120 DEG C, 10-30min is incubated, then under nitrogen protection, flow back 16-20h in 100-110 DEG C, is subsequently cooled to room temperature,
Add ethyl acetate to be well mixed, then with salt acid elution, dried after rotary evaporation to constant weight, be cooled to room temperature, then add
PLLA is well mixed, and in 60-100 DEG C of dry 2-4h, 5-15min then is blended in 160-200 DEG C, is cooled to room temperature,
Then add maleic anhydride to be well mixed, then heat to 80-90 DEG C, be incubated 10-30min, then add ammonium persulfate mixing
Uniformly, addition styrene, stearic acid and silane coupler KH-560 are well mixed after stirring 5-15min, then in 850-
1250r/min rotating speeds stir 50-70min, then heat to 85-95 DEG C, extract 40-50h, then in vacuum drying oven, 65-75
DEG C dry to constant weight, be cooled to room temperature and obtain tension modified additive.
The present invention a kind of high-temperature-resistant, tensile control CABLE MATERIALS, its raw material include phenolic resin, silicon rubber, butadiene rubber,
Alkyd resin, neoprene, epoxy resin, coumarone indene resin, trimethyl phosphate, Firebrake ZB, carbon black, vermiculite, Firebrake ZB, nanometer
Carborundum, glass fibre, nano magnesia, kodalk, wood fiber powder, antimony oxide, nano-aluminum hydroxide, isocyanic acid
Ester, polysiloxanes, diisooctyl phthalate, silane resin acceptor kh-550, chlorinated paraffin, APP, styrene, vulcanization
Agent DTDM, plasticizer, heat resist modification auxiliary agent and tension modified additive, wherein with phenolic resin, silicon rubber, butadiene rubber, alcohol
Acid resin, neoprene, epoxy resin and coumarone indene resin as rubber mass, with trimethyl phosphate, Firebrake ZB, carbon black, vermiculite,
Firebrake ZB, nanometer silicon carbide, glass fibre, nano magnesia, kodalk, wood fiber powder, antimony oxide and nanometer hydrogen
Aluminum oxide is as filler, with isocyanates, polysiloxanes, diisooctyl phthalate, silane resin acceptor kh-550, chlorination stone
Wax, APP, styrene, vulcanizing agent DTDM, plasticizer, heat resist modification auxiliary agent and tension modified additive help as enhancing
Agent, by the cooperation of rubber mass, filler and reinforcing aids, impart the excellent high-temperature-resistant, tensile of present invention control CABLE MATERIALS
Energy.Wherein, heat resist modification auxiliary agent is then placed in baking oven and dried, then add and receive by the way that wollastonite is ground into powder
Rice calcium carbonate and zinc stearate be well mixed, seal stirring at low speed, then with Nano zinc dioxide impact-resistant, nano aluminum nitride, nanometer two
Silica, rare-earth stearate, lightweight calcium activated and nano-ceramic powder are well mixed, and are sealed stirring at low speed, are cooled to room temperature and obtain
Material a；Silicon rubber and poly- MTES are mixed, are subsequently added into dibutyl tin laurate, heats up, is then added dropwise
Distilled water, reaction obtain material a；By material a, material b, hydroxypropyl methyl cellulose, methacrylate and silane coupler
KH-570 is well mixed, and stirring, is then heated, is cooled to room temperature and obtains heat resist modification auxiliary agent, applies to the control of the present invention
In CABLE MATERIALS, the cooperation with major ingredient and filler so that cable control material of the invention has excellent resistance to elevated temperatures.Wherein,
Tension modified additive heats up, insulation, then under nitrogen protection, flowed back, then by the way that hexamethylene diamine and phenylurea are well mixed
It is cooled to room temperature, adds ethyl acetate and be well mixed, then with salt acid elution, is dried after rotary evaporation to constant weight, be cooled to room
Temperature, then add PLLA and be well mixed, dry, be then blended, be cooled to room temperature, it is equal then to add maleic anhydride mixing
It is even, then heat up, be incubated, then add ammonium persulfate and be well mixed, styrene, stearic acid and silane coupler are added after stirring
KH-560 is well mixed, and is followed by stirring for, and is then heated up, and extracting, then in vacuum drying oven, is dried to constant weight, is cooled to room temperature and obtains
To tension modified additive, apply in present invention control CABLE MATERIALS, the cooperation with rubber mass and filler so that control of the invention
CABLE MATERIALS has excellent tensile property.The control CABLE MATERIALS of the present invention has excellent high temperature resistant and tensile property.
Embodiment
The present invention is described in detail with reference to specific embodiment, it should be appreciated that embodiment is served only for illustrating this hair
It is bright, rather than for limiting the invention, any modification made on the basis of the present invention, equivalent substitution etc. are in this hair
In bright protection domain.
Embodiment 1
A kind of high-temperature-resistant, tensile control CABLE MATERIALS proposed by the present invention, its raw material include by weight：60 parts of phenolic resin,
20 parts of silicon rubber, 10 parts of butadiene rubber, 5 parts of alkyd resin, 6 parts of neoprene, 3.5 parts of epoxy resin, 4 parts of coumarone indene resin,
5 parts of trimethyl phosphate, 3 parts of Firebrake ZB, 4.5 parts of carbon black, 4 parts of vermiculite, 3 parts of Firebrake ZB, 4 parts of nanometer silicon carbide, glass fibre 6
Part, 6 parts of nano magnesia, 5 parts of kodalk, 2 parts of wood fiber powder, 3 parts of antimony oxide, 3 parts of nano-aluminum hydroxide, isocyanide
5.5 parts of acid esters, 3.5 parts of polysiloxanes, 5.5 parts of diisooctyl phthalate, 3.5 parts of silane resin acceptor kh-550, chlorination stone
It is 2.5 parts of wax, 4 parts of APP, 6 parts of styrene, 4 parts of vulcanizing agent DTDM, 4 parts of plasticizer, 10 parts of heat resist modification auxiliary agent, anti-
Draw 12 parts of modified additive.
Heat resist modification auxiliary agent is prepared by following technique：10 parts of wollastonites are ground into 25 mesh powder by weight
Shape, it is then placed in 100 DEG C of baking oven and dries, then adds 6 parts of nano-calcium carbonates and 3.5 parts of zinc stearates are well mixed,
At a temperature of 55 DEG C seal stirring at low speed 17.5min, then with 3.5 parts of Nano zinc dioxide impact-resistants, 2 parts of nano aluminum nitrides, 4.5 parts of nanometers
Silica, 3.5 parts of rare-earth stearates, 2.5 parts of lightweight calcium activateds and 4 parts of nano-ceramic powders are well mixed, 50 DEG C of sealing low speed
7.5min is stirred, room temperature is cooled to and obtains material a；3 parts of silicon rubber and 4.5 parts of poly- MTESs are mixed, then
3 parts of dibutyl tin laurates are added, 80 DEG C is warming up to, distilled water is then added dropwise, react 6.5h at 95 DEG C, obtain material a；
Material a, material b, 3.5 parts of hydroxypropyl methyl celluloses, 2.5 parts of methacrylates and 6 parts of Silane coupling reagent KH-570s are mixed
Close uniform, stir 30min in 750r/min rotating speeds, then heat 2h at 140 DEG C, be cooled to room temperature and obtain heat resist modification and help
Agent.
Tension modified additive is prepared by following technique：10 parts of hexamethylene diamines and 6 parts of phenylureas are mixed by weight equal
It is even, 100 DEG C are warming up to, is incubated 20min, then under nitrogen protection, flow back 18h in 105 DEG C, is subsequently cooled to room temperature, adds
4.5 parts of ethyl acetate are well mixed, and then with salt acid elution, are dried after rotary evaporation to constant weight, are cooled to room temperature, then add
3.5 parts of PLLAs are well mixed, and in 80 DEG C of dry 3h, 10min then are blended in 180 DEG C, is cooled to room temperature, then adds
2.5 parts of maleic anhydrides are well mixed, and then heat to 85 DEG C, are incubated 20min, are then added 4 parts of ammonium persulfates and are well mixed, stir
4 parts of styrene of addition, 3 parts of stearic acid and 6 parts of silane coupler KH-560 are well mixed after mixing 10min, then in 1050r/min
Rotating speed stirs 60min, then heats to 90 DEG C, extracts 45h, then in vacuum drying oven, 70 DEG C dry to constant weight, and are cooled to room temperature
Obtain tension modified additive.
Embodiment 2
A kind of high-temperature-resistant, tensile control CABLE MATERIALS proposed by the present invention, its raw material include by weight：30 parts of phenolic resin,
30 parts of silicon rubber, 5 parts of butadiene rubber, 8 parts of alkyd resin, 3 parts of neoprene, 5 parts of epoxy resin, 2 parts of coumarone indene resin, phosphoric acid
8 parts of trimethyl, 1 part of Firebrake ZB, 6 parts of carbon black, 3 parts of vermiculite, 5 parts of Firebrake ZB, 3 parts of nanometer silicon carbide, glass fibre 8 part, nanometer
4 parts of magnesia, 8 parts of kodalk, 1 part of wood fiber powder, 4 parts of antimony oxide, 1 part of nano-aluminum hydroxide, isocyanates 8
Part, 1 part of polysiloxanes, 8 parts of diisooctyl phthalate, 2 parts of silane resin acceptor kh-550,4 parts of chlorinated paraffin, polyphosphoric acid
3 parts of ammonium, 8 parts of styrene, 2 parts of vulcanizing agent DTDM, 5 parts of plasticizer, 5 parts of heat resist modification auxiliary agent, 16 parts of tension modified additive.
Heat resist modification auxiliary agent is prepared by following technique：It is powdered that 5 parts of wollastonites are ground into 30 mesh by weight,
It is then placed in 95 DEG C of baking oven and dries, then adds 8 parts of nano-calcium carbonates and 2 parts of zinc stearates are well mixed, in 60 DEG C of temperature
The lower sealing stirring at low speed 10min of degree, then with 5 parts of Nano zinc dioxide impact-resistants, 1 part of nano aluminum nitride, 6 parts of nano silicons, 2 parts
Rare-earth stearate, 4 parts of lightweight calcium activateds and 2 parts of nano-ceramic powders are well mixed, and 55 DEG C of sealing stirring at low speed 5min, are cooled to room
Temperature obtains material a；5 parts of silicon rubber and 3 parts of poly- MTESs are mixed, are subsequently added into 5 parts of di lauric dibutyls
Tin, 70 DEG C are warming up to, distilled water is then added dropwise, react 6h at 100 DEG C, obtain material a；By material a, material b, 5 parts of hydroxypropyls
Ylmethyl cellulose, 1 part of methacrylate and 9 parts of Silane coupling reagent KH-570s are well mixed, and are stirred in 650r/min rotating speeds
40min, 3h then is heated at 80 DEG C, be cooled to room temperature and obtain heat resist modification auxiliary agent.
Tension modified additive is prepared by following technique：5 parts of hexamethylene diamines and 8 parts of phenylureas are mixed by weight equal
It is even, 80 DEG C are warming up to, is incubated 30min, then under nitrogen protection, flow back 20h in 100 DEG C, is subsequently cooled to room temperature, adds 3
Part ethyl acetate is well mixed, and then with salt acid elution, is dried after rotary evaporation to constant weight, is cooled to room temperature, then adds 5 parts
PLLA is well mixed, and in 60 DEG C of dry 4h, 15min then is blended in 160 DEG C, is cooled to room temperature, then add 1 portion of horse
Carry out acid anhydrides to be well mixed, then heat to 90 DEG C, be incubated 10min, then add 5 parts of ammonium persulfates and be well mixed, stir 5min
6 parts of styrene, 1 part of stearic acid and 9 parts of silane coupler KH-560 are added afterwards to be well mixed, and are then stirred in 850r/min rotating speeds
70min, 85 DEG C are then heated to, extract 50h, then in vacuum drying oven, 65 DEG C dry to constant weight, and are cooled to room temperature and obtain tension
Modified additive.
Embodiment 3
A kind of high-temperature-resistant, tensile control CABLE MATERIALS proposed by the present invention, its raw material include by weight：90 parts of phenolic resin,
10 parts of silicon rubber, 15 parts of butadiene rubber, 2 parts of alkyd resin, 9 parts of neoprene, 2 parts of epoxy resin, 6 parts of coumarone indene resin, phosphorus
Sour 2 parts of trimethyl, 5 parts of Firebrake ZB, 3 parts of carbon black, 5 parts of vermiculite, 1 part of Firebrake ZB, 5 parts of nanometer silicon carbide, 4 parts of glass fibre, receive
8 parts of magnesia of rice, 2 parts of kodalk, 3 parts of wood fiber powder, 2 parts of antimony oxide, 5 parts of nano-aluminum hydroxide, isocyanates 3
Part, 6 parts of polysiloxanes, 3 parts of diisooctyl phthalate, 5 parts of silane resin acceptor kh-550,1 part of chlorinated paraffin, polyphosphoric acid
5 parts of ammonium, 4 parts of styrene, 6 parts of vulcanizing agent DTDM, 3 parts of plasticizer, 15 parts of heat resist modification auxiliary agent, 8 parts of tension modified additive.
Heat resist modification auxiliary agent is prepared by following technique：15 parts of wollastonites are ground into 20 mesh powder by weight
Shape, it is then placed in 105 DEG C of baking oven and dries, then adds 4 parts of nano-calcium carbonates and 5 parts of zinc stearates are well mixed, 50
At a temperature of DEG C seal stirring at low speed 25min, then with 2 parts of Nano zinc dioxide impact-resistants, 3 parts of nano aluminum nitrides, 3 parts of nanometer titanium dioxides
Silicon, 5 parts of rare-earth stearates, 1 part of lightweight calcium activated and 6 parts of nano-ceramic powders are well mixed, 45 DEG C of sealing stirring at low speed 10min,
It is cooled to room temperature and obtains material a；1 part of silicon rubber and 6 parts of poly- MTESs are mixed, are subsequently added into 1 part of two bay
Sour dibutyl tin, 90 DEG C are warming up to, distilled water is then added dropwise, react 7h at 90 DEG C, obtain material a；By material a, material b, 2
Part hydroxypropyl methyl cellulose, 4 parts of methacrylates and 3 parts of Silane coupling reagent KH-570s are well mixed, and are turned in 850r/min
Speed stirring 20min, then heats 1h at 200 DEG C, is cooled to room temperature and obtains heat resist modification auxiliary agent.
Tension modified additive is prepared by following technique：15 parts of hexamethylene diamines and 4 parts of phenylureas are mixed by weight equal
It is even, 120 DEG C are warming up to, is incubated 10min, then under nitrogen protection, flow back 16h in 110 DEG C, is subsequently cooled to room temperature, adds 6
Part ethyl acetate is well mixed, and then with salt acid elution, is dried after rotary evaporation to constant weight, is cooled to room temperature, then adds 2 parts
PLLA is well mixed, and in 100 DEG C of dry 2h, 5min then is blended in 200 DEG C, is cooled to room temperature, then add 4 portions of horses
Carry out acid anhydrides to be well mixed, then heat to 80 DEG C, be incubated 30min, then add 3 parts of ammonium persulfates and be well mixed, stir 15min
2 parts of styrene, 5 parts of stearic acid and 3 parts of silane coupler KH-560 are added afterwards to be well mixed, and are then stirred in 1250r/min rotating speeds
50min is mixed, then heats to 95 DEG C, extracts 40h, then in vacuum drying oven, 75 DEG C dry to constant weight, and are cooled to room temperature and are resisted
Draw modified additive.
Embodiment 4
A kind of high-temperature-resistant, tensile control CABLE MATERIALS proposed by the present invention, its raw material include by weight：35 parts of phenolic resin,
25 parts of silicon rubber, 8 parts of butadiene rubber, 7 parts of alkyd resin, 4 parts of neoprene, 4 parts of epoxy resin, 3 parts of coumarone indene resin, phosphoric acid
7 parts of trimethyl, 2 parts of Firebrake ZB, 5 parts of carbon black, 3.5 parts of vermiculite, 4 parts of Firebrake ZB, 3.5 parts of nanometer silicon carbide, 7 parts of glass fibre,
It is 5 parts of nano magnesia, 7 parts of kodalk, 1.5 parts of wood fiber powder, 3.5 parts of antimony oxide, 2 parts of nano-aluminum hydroxide, different
7 parts of cyanate, 2 parts of polysiloxanes, 7 parts of diisooctyl phthalate, 3 parts of silane resin acceptor kh-550,3 parts of chlorinated paraffin,
3.5 parts of APP, 7 parts of styrene, 3 parts of vulcanizing agent DTDM, 4.5 parts of plasticizer, 8 parts of heat resist modification auxiliary agent, tension are modified
15 parts of auxiliary agent.
Heat resist modification auxiliary agent is prepared by following technique：It is powdered that 8 parts of wollastonites are ground into 28 mesh by weight,
It is then placed in 98 DEG C of baking oven and dries, then adds 7 parts of nano-calcium carbonates and 3 parts of zinc stearates are well mixed, in 58 DEG C of temperature
The lower sealing stirring at low speed 15min of degree, then with 4 parts of Nano zinc dioxide impact-resistants, 1.5 parts of nano aluminum nitrides, 5 parts of nano silicons, 3
Part rare-earth stearate, 3 parts of lightweight calcium activateds and 3 parts of nano-ceramic powders are well mixed, and 52 DEG C of sealing stirring at low speed 6min, are cooled to
Room temperature obtains material a；4 parts of silicon rubber and 4 parts of poly- MTESs are mixed, are subsequently added into 4 parts of fourths of tin dilaurate two
Ji Xi, 75 DEG C are warming up to, distilled water is then added dropwise, react 6.2h at 98 DEG C, obtain material a；By material a, material b, 4 parts of hydroxyls
Propyl methocel, 2 parts of methacrylates and 8 parts of Silane coupling reagent KH-570s are well mixed, and are stirred in 680r/min rotating speeds
35min is mixed, then heats 2.5h at 85 DEG C, room temperature is cooled to and obtains heat resist modification auxiliary agent.
Tension modified additive is prepared by following technique：8 parts of hexamethylene diamines and 7 parts of phenylureas are mixed by weight equal
It is even, 85 DEG C are warming up to, is incubated 25min, then under nitrogen protection, flow back 19h in 102 DEG C, is subsequently cooled to room temperature, adds 4
Part ethyl acetate is well mixed, and then with salt acid elution, is dried after rotary evaporation to constant weight, is cooled to room temperature, then adds 4 parts
PLLA is well mixed, and in 65 DEG C of dry 3.5h, 12min then is blended in 165 DEG C, is cooled to room temperature, then add 2 parts
Maleic anhydride is well mixed, and then heats to 88 DEG C, is incubated 15min, is then added 4.5 parts of ammonium persulfates and is well mixed, stirs
Add 5 parts of styrene, 2 parts of stearic acid and 8 parts of silane coupler KH-560 after 8min to be well mixed, then in 880r/min rotating speeds
65min is stirred, then heats to 88 DEG C, extracts 48h, then in vacuum drying oven, 68 DEG C dry to constant weight, and are cooled to room temperature and obtain
Tension modified additive.
Embodiment 5
A kind of high-temperature-resistant, tensile control CABLE MATERIALS proposed by the present invention, its raw material include by weight：85 parts of phenolic resin,
15 parts of silicon rubber, 12 parts of butadiene rubber, 3 parts of alkyd resin, 8 parts of neoprene, 3 parts of epoxy resin, 5 parts of coumarone indene resin, phosphorus
Sour 3 parts of trimethyl, 4 parts of Firebrake ZB, 4 parts of carbon black, 4.5 parts of vermiculite, 2 parts of Firebrake ZB, 4.5 parts of nanometer silicon carbide, glass fibre 5
Part, 7 parts of nano magnesia, 3 parts of kodalk, 2.5 parts of wood fiber powder, 2.5 parts of antimony oxide, 4 parts of nano-aluminum hydroxide,
4 parts of isocyanates, 5 parts of polysiloxanes, 4 parts of diisooctyl phthalate, 4 parts of silane resin acceptor kh-550, chlorinated paraffin 2
Part, 4.5 parts of APP, 5 parts of styrene, 5 parts of vulcanizing agent DTDM, 3.5 parts of plasticizer, 12 parts of heat resist modification auxiliary agent, tension
9 parts of modified additive.
Heat resist modification auxiliary agent is prepared by following technique：12 parts of wollastonites are ground into 22 mesh powder by weight
Shape, it is then placed in 102 DEG C of baking oven and dries, then adds 5 parts of nano-calcium carbonates and 4 parts of zinc stearates are well mixed, 52
At a temperature of DEG C seal stirring at low speed 20min, then with 3 parts of Nano zinc dioxide impact-resistants, 2.5 parts of nano aluminum nitrides, 4 parts of nanometer titanium dioxides
Silicon, 4 parts of rare-earth stearates, 2 parts of lightweight calcium activateds and 5 parts of nano-ceramic powders are well mixed, 48 DEG C of sealing stirring at low speed 9min, cold
But material a is obtained to room temperature；2 parts of silicon rubber and 5 parts of poly- MTESs are mixed, are subsequently added into 2 parts of tin dilaurates
Dibutyl tin, 85 DEG C are warming up to, distilled water is then added dropwise, react 6.8h at 92 DEG C, obtain material a；By material a, material b, 3
Part hydroxypropyl methyl cellulose, 3 parts of methacrylates and 4 parts of Silane coupling reagent KH-570s are well mixed, and are turned in 820r/min
Speed stirring 25min, then heats 1.5h at 195 DEG C, is cooled to room temperature and obtains heat resist modification auxiliary agent.
Tension modified additive is prepared by following technique：12 parts of hexamethylene diamines and 5 parts of phenylureas are mixed by weight equal
It is even, 115 DEG C are warming up to, is incubated 15min, then under nitrogen protection, flow back 17h in 108 DEG C, is subsequently cooled to room temperature, adds 5
Part ethyl acetate is well mixed, and then with salt acid elution, is dried after rotary evaporation to constant weight, is cooled to room temperature, then adds 3 parts
PLLA is well mixed, and in 95 DEG C of dry 2.5h, 8min then is blended in 195 DEG C, is cooled to room temperature, then add 3 parts
Maleic anhydride is well mixed, and then heats to 82 DEG C, is incubated 25min, is then added 3.5 parts of ammonium persulfates and is well mixed, stirs
3 parts of styrene, 4 parts of stearic acid and 4 parts of silane coupler KH-560 are added after 12min to be well mixed, and are then turned in 1220r/min
Speed stirring 55min, then heats to 92 DEG C, extracts 42h, then in vacuum drying oven, 72 DEG C dry to constant weight, and are cooled to room temperature and obtain
To tension modified additive.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.
Claims (7)
1. a kind of high-temperature-resistant, tensile controls CABLE MATERIALS, it is characterised in that its raw material includes by weight：Phenolic resin 30-90 parts,
Silicon rubber 10-30 parts, butadiene rubber 5-15 parts, alkyd resin 2-8 parts, neoprene 3-9 parts, epoxy resin 2-5 parts, coumarone
Resin 2-6 parts, trimethyl phosphate 2-8 parts, Firebrake ZB 1-5 parts, carbon black 3-6 parts, vermiculite 3-5 parts, Firebrake ZB 1-5 parts, nano-sized carbon
SiClx 3-5 parts, glass fibre 4-8 parts, nano magnesia 4-8 parts, kodalk 2-8 parts, wood fiber powder 1-3 parts, three oxidations
Two antimony 2-4 parts, nano-aluminum hydroxide 1-5 parts, isocyanates 3-8 parts, polysiloxanes 1-6 parts, diisooctyl phthalate 3-8
Part, silane resin acceptor kh-550 2-5 parts, chlorinated paraffin 1-4 parts, APP 3-5 parts, styrene 4-8 parts, vulcanizing agent DTDM
2-6 parts, plasticizer 3-5 parts, heat resist modification auxiliary agent 5-15 parts, tension modified additive 8-16 parts.
2. high-temperature-resistant, tensile according to claim 1 controls CABLE MATERIALS, it is characterised in that the raw material of heat resist modification auxiliary agent
Include by weight：Wollastonite 5-15 parts, nano-calcium carbonate 4-8 parts, zinc stearate 2-5 parts, Nano zinc dioxide impact-resistant 2-5 parts, receive
Rice aluminium nitride 1-3 parts, nano silicon 3-6 parts, rare-earth stearate 2-5 parts, lightweight calcium activated 1-4 parts, nano-ceramic powder 2-6
Part, silicon rubber 1-5 parts, poly- MTES 3-6 parts, dibutyl tin laurate 1-5 parts, hydroxypropyl methyl cellulose
2-5 parts, methacrylate 1-4 parts, Silane coupling reagent KH-570 3-9 parts.
3. high-temperature-resistant, tensile according to claim 1 or 2 controls CABLE MATERIALS, it is characterised in that heat resist modification auxiliary agent is pressed
It is prepared by following technique：Wollastonite is ground into powder, is then placed in baking oven and dries, then add nano-calcium carbonate and
Zinc stearate is well mixed, seal stirring at low speed, then with Nano zinc dioxide impact-resistant, nano aluminum nitride, nano silicon, tristearin
Acid rare earth, lightweight calcium activated and nano-ceramic powder are well mixed, and are sealed stirring at low speed, are cooled to room temperature and obtain material a；By silicon rubber
Glue and the mixing of poly- MTES, are subsequently added into dibutyl tin laurate, heat up, distilled water is then added dropwise, react
Obtain material a；Material a, material b, hydroxypropyl methyl cellulose, methacrylate and Silane coupling reagent KH-570 are mixed equal
It is even, stirring, then heat, be cooled to room temperature and obtain heat resist modification auxiliary agent.
4. the high-temperature-resistant, tensile control CABLE MATERIALS according to claim any one of 1-3, it is characterised in that heat resist modification helps
Agent is prepared by following technique：Wollastonite is ground into 20-30 mesh is powdered, is then placed in 95-105 DEG C of baking oven and dries
It is dry, then add nano-calcium carbonate and zinc stearate is well mixed, stirring at low speed 10-25min is sealed at a temperature of 50-60 DEG C,
Then with Nano zinc dioxide impact-resistant, nano aluminum nitride, nano silicon, rare-earth stearate, lightweight calcium activated and nano-ceramic powder
It is well mixed, 45-55 DEG C of sealing stirring at low speed 5-10min, it is cooled to room temperature and obtains material a；By silicon rubber and the second of poly- methyl three
TMOS mixes, and is subsequently added into dibutyl tin laurate, is warming up to 70-90 DEG C, distilled water is then added dropwise, at 90-100 DEG C
Lower reaction 6-7h, obtains material a；By material a, material b, hydroxypropyl methyl cellulose, methacrylate and silane coupler
KH-570 is well mixed, and is stirred 20-40min in 650-850r/min rotating speeds, is then heated 1-3h at 80-200 DEG C, be cooled to
Room temperature obtains heat resist modification auxiliary agent.
5. the high-temperature-resistant, tensile control CABLE MATERIALS according to claim any one of 1-4, it is characterised in that tension modified additive
Raw material include by weight：Hexamethylene diamine 5-15 parts, phenylurea 4-8 parts, ethyl acetate 3-6 parts, PLLA 2-5 parts, horse
Come acid anhydrides 1-4 parts, ammonium persulfate 3-5 parts, styrene 2-6 parts, stearic acid 1-5 parts, silane coupler KH-560 3-9 parts.
6. the high-temperature-resistant, tensile control CABLE MATERIALS according to claim any one of 1-5, it is characterised in that tension modified additive
Prepared by following technique：Hexamethylene diamine and phenylurea are well mixed, heated up, insulation, then under nitrogen protection, backflow,
It is subsequently cooled to room temperature, adds ethyl acetate and be well mixed, then with salt acid elution, is dried after rotary evaporation to constant weight, cooling
To room temperature, then add PLLA and be well mixed, dry, be then blended, be cooled to room temperature, then add maleic anhydride and mix
Close uniformly, then heat up, be incubated, then add ammonium persulfate and be well mixed, it is even that styrene, stearic acid and silane are added after stirring
Connection agent KH-560 is well mixed, and is followed by stirring for, is then heated up, and is extracted, then in vacuum drying oven, is dried to constant weight, be cooled to room
Temperature obtains tension modified additive.
7. the high-temperature-resistant, tensile control CABLE MATERIALS according to claim any one of 1-6, it is characterised in that tension modified additive
Prepared by following technique：Hexamethylene diamine and phenylurea are well mixed, are warming up to 80-120 DEG C, is incubated 10-30min, then
Under nitrogen protection, flow back 16-20h in 100-110 DEG C, is subsequently cooled to room temperature, adds ethyl acetate and is well mixed, then uses
Salt acid elution, dry to constant weight after rotary evaporation, be cooled to room temperature, then add PLLA and be well mixed, in 60-100
DEG C dry 2-4h, then in 160-200 DEG C be blended 5-15min, be cooled to room temperature, then add maleic anhydride be well mixed, so
After be warming up to 80-90 DEG C, be incubated 10-30min, then add ammonium persulfate and be well mixed, benzene second is added after stirring 5-15min
Alkene, stearic acid and silane coupler KH-560 are well mixed, and then stir 50-70min in 850-1250r/min rotating speeds, then
85-95 DEG C is warming up to, extracts 40-50h, then in vacuum drying oven, 65-75 DEG C dries to constant weight, and is cooled to room temperature and obtains tension
Modified additive.
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| Publication number | Priority date | Publication date | Assignee | Title |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105802122A (en) * | 2016-05-12 | 2016-07-27 | 王尧尧 | Cable insulation material comprising nano magnesium oxide/low-density polyethylene/modified bentonite and application thereof |
| CN105860426A (en) * | 2016-05-12 | 2016-08-17 | 王尧尧 | Method for preparing cable insulating materials with nanometer magnesium oxide/low-density polyethylene/modified bentonite and application of cable insulating materials |
| CN106674882A (en) * | 2016-12-12 | 2017-05-17 | 天长市康宁塑胶科技有限公司 | Modified plastic material with high toughness, corrosion resistance and heat resistance |
-
2017
- 2017-08-31 CN CN201710770045.0A patent/CN107383766A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105802122A (en) * | 2016-05-12 | 2016-07-27 | 王尧尧 | Cable insulation material comprising nano magnesium oxide/low-density polyethylene/modified bentonite and application thereof |
| CN105860426A (en) * | 2016-05-12 | 2016-08-17 | 王尧尧 | Method for preparing cable insulating materials with nanometer magnesium oxide/low-density polyethylene/modified bentonite and application of cable insulating materials |
| CN106674882A (en) * | 2016-12-12 | 2017-05-17 | 天长市康宁塑胶科技有限公司 | Modified plastic material with high toughness, corrosion resistance and heat resistance |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108192344A (en) * | 2017-11-26 | 2018-06-22 | 天长市荣盛有机硅科技有限公司 | A kind of fire-retardant UV resistant modified silicon rubber material |
| CN108164919A (en) * | 2017-11-27 | 2018-06-15 | 安徽华星电缆集团有限公司 | A kind of computer cable jacket material |
| CN107916009A (en) * | 2017-11-28 | 2018-04-17 | 安徽华源电缆集团有限公司 | A kind of cable steel-tape armouring layer material |
| CN108164920A (en) * | 2017-11-28 | 2018-06-15 | 安徽国华电缆集团有限公司 | A kind of waterproof acid and alkali-resistance cable jacket material |
| CN108017877A (en) * | 2017-12-08 | 2018-05-11 | 浙江工业大学之江学院 | A kind of electroplating tooling arc resistant fabroil and its manufacture method |
| CN108017876A (en) * | 2017-12-08 | 2018-05-11 | 浙江工业大学之江学院 | A kind of electroplating tooling is molded powder and its manufacture method with arc resistant fabroil |
| CN108102248A (en) * | 2017-12-10 | 2018-06-01 | 长沙无道工业设计有限公司 | A kind of CABLE MATERIALS, low temperature resistant cable and low temperature resistant three cores super flexible cable |
| CN108456410A (en) * | 2018-02-05 | 2018-08-28 | 合肥市大卓电力有限责任公司 | A kind of ageing-resistant cable material and preparation method thereof |
| CN109553830A (en) * | 2018-12-06 | 2019-04-02 | 安徽荣达阀门有限公司 | A kind of preparation method of stretch-proof pipeline valve gasket seal |
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Application publication date: 20171124 |