CN106366844A - High-adhesion epoxy paint with excellent mechanical properties - Google Patents
High-adhesion epoxy paint with excellent mechanical properties Download PDFInfo
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- CN106366844A CN106366844A CN201610743115.9A CN201610743115A CN106366844A CN 106366844 A CN106366844 A CN 106366844A CN 201610743115 A CN201610743115 A CN 201610743115A CN 106366844 A CN106366844 A CN 106366844A
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- zeolite powder
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- weight
- epoxy resin
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a high-adhesion epoxy paint with excellent mechanical properties. The paint comprises a material A and a material B in a weight ratio of 1:(0.3-0.4). The material A is prepared from the following raw materials in parts by weight: 20-40 parts of epoxy resin E-44, 5-15 parts of organosilicon modified epoxy resin, 25-45 parts of polyurethane modified epoxy resin, 10-20 parts of modified zeolite powder, 3-6 parts of corn starch, 6-12 parts of polypyrrole hollow sphere, 8-14 parts of kaolin, 2-5 parts of hollow glass microballoon, 5-10 parts of calcined argil, 3-5 parts of zinc oxide, 4-8 parts of aluminum silicate, 0.8-1.5 parts of silane coupling agent, 4-12 parts of polyvinyl alcohol, 3-4 parts of disproportionated rosin, 3-4 parts of wetting agent and 30-50 parts of deionized water. The material B is prepared from the following raw materials in parts by weight: 5-10 parts of m-xylylenediamine, 2-5 parts of 2,2,4-trimethyl-1,3-pentadiol monoisobutyrate, 5-8 parts of cyclohexane tricarboxylic acid anhydride and 10-30 parts of deionized water.
Description
Technical field
The present invention relates to epoxy coating technical field, the strong excellent in mechanical performance epoxy coating of more particularly, to a kind of adhesive force.
Background technology
Epoxy coating has excellent processing performance, mechanical performance and physical property, and application is quite varied.China's epoxy applies
Material development extremely rapid, its due to epoxy coating film can with the change of ambient temperature expansion or shrinkage, this heat
It is easy to crack that swollen shrinkage is easily caused film, adds that outdoor adverse circumstances such as drench with rain of exposing to the weather are easily caused film layer and are corroded, coating face
Complexion changed color, adhesive force reduce, peel off etc. disadvantage, continually developing with epoxy coating, the anti-corrosive properties of epoxy coating, adhesive force,
Elasticity and high and low temperature resistance are urgently to be resolved hurrily.
Content of the invention
The technical problem being existed based on background technology, the present invention proposes a kind of adhesive force strong excellent in mechanical performance epoxy and applies
Material, not only adhesive force is strong, excellent in mechanical performance, and decay resistance is preferably, and high and low temperature resistance is excellent.
A kind of strong excellent in mechanical performance epoxy coating of adhesive force proposed by the present invention, including material a and material b, material a with
The weight of material b is than for 1:0.3-0.4;
The raw material of material a includes by weight: epoxy resin e-44 20-40 part, modifying epoxy resin by organosilicon 5-15
Part, polyurethane modified epoxy resin 25-45 part, modified zeolite powder 10-20 part, corn starch 3-6 part, polypyrrole hollow ball 6-12
Part, Kaolin 8-14 part, hollow glass microbead 2-5 part, calcinated argil 5-10 part, zinc oxide 3-5 part, aluminium silicate 4-8 part, silane
Coupling agent 0.8-1.5 part, polyvinyl alcohol 4-12 part, disproportionated rosin 3-4 part, wetting agent 3-4 part, deionized water 30-50 part;
The raw material of material b includes by weight: m-xylene diamine 5-10 part, alcohol ester 12 2-5 part, cyclohexanetricarboxylic acid's acid anhydride
5-8 part, deionized water 10-30 part.
Preferably, modified zeolite powder adopts following technique preparation: Kaolin, sodium carbonate, potassium permanganate, water mixing are put
Put, filter, washing, add MTES, calcium lignosulfonate, ethanol mixing, microwave treatment, add zeolite powder,
Acrylamide, carboxymethyl cellulose, potassium peroxydisulfate, n, n- methylene-bisacrylamide, acrylic acid is sequentially added under stirring
Resin polyurethane, continues stirring, dry, pulverize and obtain modified zeolite powder.
Preferably, modified zeolite powder adopts following technique preparation: Kaolin, sodium carbonate, potassium permanganate, water mixing are placed
60-150min, filters, and washing adds MTES, calcium lignosulfonate, ethanol mixing 40-50min, at microwave
Reason 8-16min, microwave power is 300-400w, adds zeolite powder, sequentially adds acrylamide, carboxymethyl cellulose under stirring
Element, potassium peroxydisulfate, n, n- methylene-bisacrylamide, acrylic resin polyurethane, continue stirring 80-120min, whipping temp
For 55-65 DEG C, dry, pulverize and obtain modified zeolite powder.
Preferably, modified zeolite powder adopts following technique preparation: by weight by 15-25 part Kaolin, 8-16 part carbonic acid
60-150min is placed in sodium, 5-10 part potassium permanganate, the mixing of 80-140 part water, filters, washing, adds 3-6 part methyl triethoxy
Silane, 3-5 part calcium lignosulfonate, 50-90 part ethanol mixing 40-50min, microwave treatment 8-16min, microwave power is 300-
400w, add 3-8 part zeolite powder, sequentially add under stirring 25-45 part acrylamide, 8-12 part carboxymethyl cellulose,
0.16-0.2 part potassium peroxydisulfate, 0.7-1 part n, n- methylene-bisacrylamide, 1.5-2.5 part acrylic resin polyurethane, continue
Stirring 80-120min, whipping temp is 55-65 DEG C, dry, pulverize and obtain modified zeolite powder.
Preferably, the weight of material a and material b is than for 1:0.32-0.37.
Preferably, modified zeolite powder, corn starch, polypyrrole hollow ball, Kaolin, hollow glass microbead, calcinated argil,
Zinc oxide, the weight of aluminium silicate are than for 15-17:4-5:8-10:10-12:3-4:6-8:3.5-4.5:5-7.
Preferably, epoxy resin e-44, modifying epoxy resin by organosilicon, polyurethane modified epoxy resin, modified zeolite powder
Weight than for 25-35:8-12:30-40:15-17.
The present invention adopts epoxy resin e-44, polyurethane modified epoxy resin and modifying epoxy resin by organosilicon as master
Material, and using cyclohexanetricarboxylic acid's acid anhydride, benzene dimethylamine cooperation as firming agent, not only adhesive force is strong, excellent in mechanical performance, and resistance to
Corrosive nature is preferable;And modified zeolite powder, polypyrrole hollow ball, hollow glass microbead, Kaolin, corn starch, calcinated argil
Act on each other, elasticity is good, product expands with heat and contract with cold not easy to crack, and high and low temperature resistance is excellent, and corrosion-resistant, mechanical property is excellent
Different;In the preparation process of modified zeolite powder, Kaolin through SODIUM PERCARBONATE, potassium permanganate activate after, with MTES,
With zeolite powder together as filler to be covered after calcium lignosulfonate reaction, and acrylamide and carboxymethyl cellulose are in persulfuric acid
React under the initiation conditions of potassium, under the synergism of acrylic resin polyurethane, filler to be covered is carried out organically combine bag
Cover, not only adhesion is strong each other, and elasticity is good, absorption property is excellent;Modified zeolite powder is cooperated with polypyrrole hollow ball,
There is excellent morphotropism, and resilience is good, can change with epoxy resin e-44, polyurethane modified epoxy resin, organosilicon
Property epoxy resin interact, improve impact resistance of the present invention and toughness.
Specific embodiment
Below, by specific embodiment, technical scheme is described in detail.
Embodiment 1
A kind of strong excellent in mechanical performance epoxy coating of adhesive force proposed by the present invention, including material a and material b, material a with
The weight of material b is than for 1:0.3;The raw material of material a includes by weight: 40 parts of epoxy resin e-44, silicon-modified epoxy
5 parts of resin, 45 parts of polyurethane modified epoxy resin, 10 parts of modified zeolite powder, 6 parts of corn starch, 6 parts of polypyrrole hollow ball is high
14 parts of ridge soil, 2 parts of hollow glass microbead, 10 parts of calcinated argil, 3 parts of zinc oxide, 8 parts of aluminium silicate, 0.8 part of silane coupler, gathers
12 parts of vinyl alcohol, 3 parts of disproportionated rosin, 4 parts of wetting agent, 30 parts of deionized water;The raw material of material b includes by weight: isophthalic two
10 parts of methylamine, 12 parts of alcohol ester, 8 parts of cyclohexanetricarboxylic acid's acid anhydride, 10 parts of deionized water.
Embodiment 2
A kind of strong excellent in mechanical performance epoxy coating of adhesive force proposed by the present invention, including material a and material b, material a with
The weight of material b is than for 1:0.4;The raw material of material a includes by weight: 20 parts of epoxy resin e-44, silicon-modified epoxy
15 parts of resin, 25 parts of polyurethane modified epoxy resin, 20 parts of modified zeolite powder, 3 parts of corn starch, 12 parts of polypyrrole hollow ball,
8 parts of Kaolin, 5 parts of hollow glass microbead, 5 parts of calcinated argil, 5 parts of zinc oxide, 4 parts of aluminium silicate, 1.5 parts of silane coupler, gathers
4 parts of vinyl alcohol, 4 parts of disproportionated rosin, 3 parts of wetting agent, 50 parts of deionized water;The raw material of material b includes by weight: isophthalic diformazan
5 parts of amine, 12 parts of alcohol ester, 5 parts of cyclohexanetricarboxylic acid's acid anhydride, 30 parts of deionized water.
Modified zeolite powder adopts following technique preparation: Kaolin, sodium carbonate, potassium permanganate, water mixing placed, filters,
Washing, adds MTES, calcium lignosulfonate, ethanol mixing, microwave treatment, adds zeolite powder, stirring
Under sequentially add acrylamide, carboxymethyl cellulose, potassium peroxydisulfate, n, the poly- ammonia of n- methylene-bisacrylamide, acrylic resin
Ester, continues stirring, dry, pulverize and obtain modified zeolite powder.
Embodiment 3
A kind of strong excellent in mechanical performance epoxy coating of adhesive force proposed by the present invention, including material a and material b, material a with
The weight of material b is than for 1:0.32;The raw material of material a includes by weight: 35 parts of epoxy resin e-44, organic silicon modified epoxy
8 parts of oxygen tree fat, 40 parts of polyurethane modified epoxy resin, 15 parts of modified zeolite powder, 5 parts of corn starch, 8 parts of polypyrrole hollow ball,
12 parts of Kaolin, 3 parts of hollow glass microbead, 8 parts of calcinated argil, 3.5 parts of zinc oxide, 7 parts of aluminium silicate, 1 part of silane coupler, gathers
10 parts of vinyl alcohol, 3.2 parts of disproportionated rosin, 3.8 parts of wetting agent, 35 parts of deionized water;The raw material of material b includes by weight:
8 parts of benzene dimethylamine, 12 parts of alcohol ester, 7 parts of cyclohexanetricarboxylic acid's acid anhydride, 15 parts of deionized water.
Modified zeolite powder adopts following technique preparation: by weight by 25 parts of Kaolin, 8 parts of sodium carbonate, 10 parts of permanganic acid
150min are placed in potassium, the mixing of 80 parts of water, filter, washing, add 3 parts of MTESs, 5 parts of calcium lignosulfonates, 50
Part ethanol mixing 50min, microwave treatment 8min, microwave power is 400w, adds 3 parts of zeolite powders, sequentially adds under stirring
45 parts of acrylamides, 8 parts of carboxymethyl celluloses, 0.2 part of potassium peroxydisulfate, 0.7 part of n, n- methylene-bisacrylamide, 2.5 part third
Olefin(e) acid resin polyurethane, continues stirring 80min, and whipping temp is 65 DEG C, dry, pulverize and obtain modified zeolite powder.
Embodiment 4
A kind of strong excellent in mechanical performance epoxy coating of adhesive force proposed by the present invention, including material a and material b, material a with
The weight of material b is than for 1:0.37;The raw material of material a includes by weight: 25 parts of epoxy resin e-44, organic silicon modified epoxy
12 parts of oxygen tree fat, 30 parts of polyurethane modified epoxy resin, 17 parts of modified zeolite powder, 4 parts of corn starch, polypyrrole hollow ball 10
Part, 10 parts of Kaolin, 4 parts of hollow glass microbead, 6 parts of calcinated argil, 4.5 parts of zinc oxide, 5 parts of aluminium silicate, silane coupler 1.2
Part, 6 parts of polyvinyl alcohol, 3.6 parts of disproportionated rosin, 3.4 parts of wetting agent, 45 parts of deionized water;The raw material of material b wraps by weight
Include: 6 parts of m-xylene diamine, 12 parts of alcohol ester, 6 parts of cyclohexanetricarboxylic acid's acid anhydride, 25 parts of deionized water.
Modified zeolite powder adopts following technique preparation: by weight by 15 parts of Kaolin, 16 parts of sodium carbonate, 5 parts of permanganic acid
60min are placed in potassium, the mixing of 140 parts of water, filter, washing, add 6 parts of MTESs, 3 parts of calcium lignosulfonates, 90
Part ethanol mixing 40min, microwave treatment 16min, microwave power is 300w, adds 8 parts of zeolite powders, sequentially adds under stirring
25 parts of acrylamides, 12 parts of carboxymethyl celluloses, 0.16 part of potassium peroxydisulfate, 1 part of n, n- methylene-bisacrylamide, 1.5 part third
Olefin(e) acid resin polyurethane, continues stirring 120min, and whipping temp is 55 DEG C, dry, pulverize and obtain modified zeolite powder.
Embodiment 5
A kind of strong excellent in mechanical performance epoxy coating of adhesive force proposed by the present invention, including material a and material b, material a with
The weight of material b is than for 1:0.35;The raw material of material a includes by weight: 30 parts of epoxy resin e-44, organic silicon modified epoxy
10 parts of oxygen tree fat, 35 parts of polyurethane modified epoxy resin, 16 parts of modified zeolite powder, 4.5 parts of corn starch, polypyrrole hollow ball 9
Part, 11 parts of Kaolin, 3.5 parts of hollow glass microbead, 7 parts of calcinated argil, 4 parts of zinc oxide, 6 parts of aluminium silicate, silane coupler 1.1
Part, 8 parts of polyvinyl alcohol, 3.4 parts of disproportionated rosin, 3.6 parts of wetting agent, 40 parts of deionized water;The raw material of material b wraps by weight
Include: 7 parts of m-xylene diamine, 12 parts of alcohol ester, 6.7 parts of cyclohexanetricarboxylic acid's acid anhydride, 20 parts of deionized water.
Modified zeolite powder adopts following technique preparation: 100min is placed in Kaolin, sodium carbonate, potassium permanganate, water mixing,
Filter, washing, add MTES, calcium lignosulfonate, ethanol mixing 45min, microwave treatment 12min, microwave
Power is 350w, adds zeolite powder, sequentially adds acrylamide, carboxymethyl cellulose, potassium peroxydisulfate, n under stirring, and n- is sub-
Bisacrylamide, acrylic resin polyurethane, continue stirring 100min, and whipping temp is 60 DEG C, dry, pulverize and changed
Property zeolite powder.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto,
Any those familiar with the art the invention discloses technical scope in, technology according to the present invention scheme and its
Inventive concept equivalent or change in addition, all should be included within the scope of the present invention.
Claims (7)
1. a kind of strong excellent in mechanical performance epoxy coating of adhesive force is it is characterised in that include material a and material b, material a and thing
The weight ratio of material b is for 1:0.3-0.4;
The raw material of material a includes by weight: epoxy resin e-44 20-40 part, modifying epoxy resin by organosilicon 5-15 part, gathers
Urethane modified epoxy 25-45 part, modified zeolite powder 10-20 part, corn starch 3-6 part, polypyrrole hollow ball 6-12 part, high
Ridge soil 8-14 part, hollow glass microbead 2-5 part, calcinated argil 5-10 part, zinc oxide 3-5 part, aluminium silicate 4-8 part is silane coupled
Agent 0.8-1.5 part, polyvinyl alcohol 4-12 part, disproportionated rosin 3-4 part, wetting agent 3-4 part, deionized water 30-50 part;
The raw material of material b includes by weight: m-xylene diamine 5-10 part, alcohol ester 12 2-5 part, cyclohexanetricarboxylic acid acid anhydride 5-8
Part, deionized water 10-30 part.
2. according to claim 1 adhesive force strong excellent in mechanical performance epoxy coating it is characterised in that modified zeolite powder adopt
Following technique preparation: Kaolin, sodium carbonate, potassium permanganate, water mixing are placed, filters, washing, add methyltriethoxy silane
Alkane, calcium lignosulfonate, ethanol mixing, microwave treatment, add zeolite powder, under stirring, sequentially add acrylamide, carboxylic first
Base cellulose, potassium peroxydisulfate, n, n- methylene-bisacrylamide, acrylic resin polyurethane, continue stirring, dry, pulverize
To modified zeolite powder.
3. the strong excellent in mechanical performance epoxy coating of adhesive force according to claim 1 or claim 2 is it is characterised in that modified zeolite powder
Using the preparation of following technique: 60-150min is placed in Kaolin, sodium carbonate, potassium permanganate, water mixing, filters, washing, add
MTES, calcium lignosulfonate, ethanol mixing 40-50min, microwave treatment 8-16min, microwave power is 300-
400w, adds zeolite powder, sequentially adds acrylamide, carboxymethyl cellulose, potassium peroxydisulfate, n, n- di-2-ethylhexylphosphine oxide under stirring
Acrylamide, acrylic resin polyurethane, continue stirring 80-120min, and whipping temp is 55-65 DEG C, dry, pulverize and changed
Property zeolite powder.
4. the strong excellent in mechanical performance epoxy coating of adhesive force according to any one of claim 1-3 is it is characterised in that modified boil
Stone powder adopts following technique preparation: by weight by 15-25 part Kaolin, 8-16 part sodium carbonate, 5-10 part potassium permanganate, 80-
60-150min is placed in 140 parts of water mixing, filters, washing, adds 3-6 part MTES, 3-5 part lignin sulfonic acid
Calcium, 50-90 part ethanol mixing 40-50min, microwave treatment 8-16min, microwave power is 300-400w, adds 3-8 part zeolite
Powder, sequentially add under stirring 25-45 part acrylamide, 8-12 part carboxymethyl cellulose, 0.16-0.2 part potassium peroxydisulfate,
0.7-1 part n, n- methylene-bisacrylamide, 1.5-2.5 part acrylic resin polyurethane, continue stirring 80-120min, stirring
Temperature is 55-65 DEG C, dry, pulverize and obtains modified zeolite powder.
5. the strong excellent in mechanical performance epoxy coating of adhesive force according to any one of claim 1-4 is it is characterised in that material a
With the weight of material b than for 1:0.32-0.37.
6. the strong excellent in mechanical performance epoxy coating of adhesive force according to any one of claim 1-5 is it is characterised in that modified boil
Stone powder, corn starch, polypyrrole hollow ball, Kaolin, hollow glass microbead, calcinated argil, zinc oxide, the weight ratio of aluminium silicate
For 15-17:4-5:8-10:10-12:3-4:6-8:3.5-4.5:5-7.
7. the strong excellent in mechanical performance epoxy coating of adhesive force according to any one of claim 1-6 is it is characterised in that asphalt mixtures modified by epoxy resin
Fat e-44, modifying epoxy resin by organosilicon, polyurethane modified epoxy resin, the weight of modified zeolite powder are than for 25-35:8-12:
30-40:15-17.
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CN201610743115.9A CN106366844A (en) | 2016-08-27 | 2016-08-27 | High-adhesion epoxy paint with excellent mechanical properties |
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CN201610743115.9A CN106366844A (en) | 2016-08-27 | 2016-08-27 | High-adhesion epoxy paint with excellent mechanical properties |
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Cited By (3)
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CN107964335A (en) * | 2017-10-30 | 2018-04-27 | 合肥林邦门业有限公司 | A kind of wood furniture extinguishing waterborn preparation method for coating |
WO2020253732A1 (en) * | 2019-06-17 | 2020-12-24 | Ppg Coatings (Kunshan) Co., Ltd. | Insulating coating composition |
CN112625541A (en) * | 2020-12-08 | 2021-04-09 | 沈阳化工大学 | Hierarchical-pore nano-zeolite modified epoxy flame-retardant coating |
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CN105062313A (en) * | 2015-08-05 | 2015-11-18 | 天长市开林化工有限公司 | Waterborne epoxy resin coating for ships |
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CN105062313A (en) * | 2015-08-05 | 2015-11-18 | 天长市开林化工有限公司 | Waterborne epoxy resin coating for ships |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107964335A (en) * | 2017-10-30 | 2018-04-27 | 合肥林邦门业有限公司 | A kind of wood furniture extinguishing waterborn preparation method for coating |
WO2020253732A1 (en) * | 2019-06-17 | 2020-12-24 | Ppg Coatings (Kunshan) Co., Ltd. | Insulating coating composition |
CN112625541A (en) * | 2020-12-08 | 2021-04-09 | 沈阳化工大学 | Hierarchical-pore nano-zeolite modified epoxy flame-retardant coating |
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Application publication date: 20170201 |