CN107141515A - Decorative joint mixture and preparation method thereof - Google Patents
Decorative joint mixture and preparation method thereof Download PDFInfo
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- CN107141515A CN107141515A CN201710540789.3A CN201710540789A CN107141515A CN 107141515 A CN107141515 A CN 107141515A CN 201710540789 A CN201710540789 A CN 201710540789A CN 107141515 A CN107141515 A CN 107141515A
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- Prior art keywords
- parts
- agent
- water
- gap filler
- ornamental
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- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 239000000203 mixture Substances 0.000 title abstract description 7
- 239000000843 powder Substances 0.000 claims abstract description 53
- 239000000945 filler Substances 0.000 claims abstract description 46
- 235000015112 vegetable and seed oil Nutrition 0.000 claims abstract description 39
- 239000008158 vegetable oil Substances 0.000 claims abstract description 39
- 229910052573 porcelain Inorganic materials 0.000 claims abstract description 33
- 239000002994 raw material Substances 0.000 claims abstract description 28
- 239000011347 resin Substances 0.000 claims abstract description 26
- 229920005989 resin Polymers 0.000 claims abstract description 26
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000000919 ceramic Substances 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000012188 paraffin wax Substances 0.000 claims abstract description 17
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 13
- 239000004816 latex Substances 0.000 claims abstract description 13
- 229920000126 latex Polymers 0.000 claims abstract description 13
- 239000002699 waste material Substances 0.000 claims abstract description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 82
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 22
- 230000002421 anti-septic effect Effects 0.000 claims description 18
- 229920000642 polymer Polymers 0.000 claims description 18
- 239000002904 solvent Substances 0.000 claims description 17
- 230000008859 change Effects 0.000 claims description 15
- 241000196324 Embryophyta Species 0.000 claims description 14
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 14
- 238000001354 calcination Methods 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 14
- 238000004078 waterproofing Methods 0.000 claims description 14
- 239000013078 crystal Substances 0.000 claims description 13
- 239000001993 wax Substances 0.000 claims description 13
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- 238000004040 coloring Methods 0.000 claims description 12
- 230000018044 dehydration Effects 0.000 claims description 12
- 238000006297 dehydration reaction Methods 0.000 claims description 12
- 239000000654 additive Substances 0.000 claims description 11
- 230000000996 additive effect Effects 0.000 claims description 11
- 229910052697 platinum Inorganic materials 0.000 claims description 11
- 239000003755 preservative agent Substances 0.000 claims description 11
- 230000002335 preservative effect Effects 0.000 claims description 11
- 238000001816 cooling Methods 0.000 claims description 10
- 239000011259 mixed solution Substances 0.000 claims description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 9
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000003054 catalyst Substances 0.000 claims description 6
- 239000001913 cellulose Substances 0.000 claims description 6
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 5
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
- 238000006555 catalytic reaction Methods 0.000 claims description 5
- 229920002678 cellulose Polymers 0.000 claims description 5
- 238000005260 corrosion Methods 0.000 claims description 5
- 230000007797 corrosion Effects 0.000 claims description 5
- 238000004090 dissolution Methods 0.000 claims description 5
- 229920001971 elastomer Polymers 0.000 claims description 5
- 229920001038 ethylene copolymer Polymers 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 241000411851 herbal medicine Species 0.000 claims description 5
- 239000003112 inhibitor Substances 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 5
- 239000004094 surface-active agent Substances 0.000 claims description 5
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 4
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 4
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 4
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical group [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 4
- 239000005642 Oleic acid Substances 0.000 claims description 4
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 4
- 150000004645 aluminates Chemical class 0.000 claims description 4
- 239000001110 calcium chloride Substances 0.000 claims description 4
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 4
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims description 4
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims description 4
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims description 4
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 claims description 4
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 239000003921 oil Substances 0.000 claims description 4
- 235000019198 oils Nutrition 0.000 claims description 4
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 4
- CYDQOEWLBCCFJZ-UHFFFAOYSA-N 4-(4-fluorophenyl)oxane-4-carboxylic acid Chemical compound C=1C=C(F)C=CC=1C1(C(=O)O)CCOCC1 CYDQOEWLBCCFJZ-UHFFFAOYSA-N 0.000 claims description 3
- 229920002472 Starch Polymers 0.000 claims description 3
- 239000006229 carbon black Substances 0.000 claims description 3
- OPGYRRGJRBEUFK-UHFFFAOYSA-L disodium;diacetate Chemical compound [Na+].[Na+].CC([O-])=O.CC([O-])=O OPGYRRGJRBEUFK-UHFFFAOYSA-L 0.000 claims description 3
- CWAFVXWRGIEBPL-UHFFFAOYSA-N ethoxysilane Chemical compound CCO[SiH3] CWAFVXWRGIEBPL-UHFFFAOYSA-N 0.000 claims description 3
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical group [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 claims description 3
- 229910052808 lithium carbonate Inorganic materials 0.000 claims description 3
- 239000001632 sodium acetate Substances 0.000 claims description 3
- 235000017454 sodium diacetate Nutrition 0.000 claims description 3
- 239000001540 sodium lactate Substances 0.000 claims description 3
- 235000011088 sodium lactate Nutrition 0.000 claims description 3
- 229940005581 sodium lactate Drugs 0.000 claims description 3
- 239000004334 sorbic acid Substances 0.000 claims description 3
- 235000010199 sorbic acid Nutrition 0.000 claims description 3
- 229940075582 sorbic acid Drugs 0.000 claims description 3
- 239000003549 soybean oil Substances 0.000 claims description 3
- 235000012424 soybean oil Nutrition 0.000 claims description 3
- 239000008107 starch Substances 0.000 claims description 3
- 235000019698 starch Nutrition 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- 239000002383 tung oil Substances 0.000 claims description 3
- OSNIIMCBVLBNGS-UHFFFAOYSA-N 1-(1,3-benzodioxol-5-yl)-2-(dimethylamino)propan-1-one Chemical compound CN(C)C(C)C(=O)C1=CC=C2OCOC2=C1 OSNIIMCBVLBNGS-UHFFFAOYSA-N 0.000 claims description 2
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 claims description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 2
- -1 Alkene ester Chemical class 0.000 claims description 2
- 241000165940 Houjia Species 0.000 claims description 2
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 2
- 235000019486 Sunflower oil Nutrition 0.000 claims description 2
- 235000012343 cottonseed oil Nutrition 0.000 claims description 2
- 239000002385 cottonseed oil Substances 0.000 claims description 2
- SOGIFFQYRAXTDR-UHFFFAOYSA-N diethoxy(methyl)silane Chemical compound CCO[SiH](C)OCC SOGIFFQYRAXTDR-UHFFFAOYSA-N 0.000 claims description 2
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 claims description 2
- 238000000227 grinding Methods 0.000 claims description 2
- 229920000570 polyether Polymers 0.000 claims description 2
- 239000004302 potassium sorbate Substances 0.000 claims description 2
- 235000010241 potassium sorbate Nutrition 0.000 claims description 2
- 229940069338 potassium sorbate Drugs 0.000 claims description 2
- 241000894007 species Species 0.000 claims description 2
- 239000002600 sunflower oil Substances 0.000 claims description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Natural products CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims 2
- TXDYWJDYXZCRAN-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;prop-2-enoic acid Chemical compound OC(=O)C=C.C=CC1=CC=CC=C1C=C TXDYWJDYXZCRAN-UHFFFAOYSA-N 0.000 claims 1
- 235000004443 Ricinus communis Nutrition 0.000 claims 1
- 240000000528 Ricinus communis Species 0.000 claims 1
- FVLFCWAFYBQKJS-UHFFFAOYSA-N [Ca].OC=O Chemical compound [Ca].OC=O FVLFCWAFYBQKJS-UHFFFAOYSA-N 0.000 claims 1
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 claims 1
- 229920006184 cellulose methylcellulose Polymers 0.000 claims 1
- OJURWUUOVGOHJZ-UHFFFAOYSA-N methyl 2-[(2-acetyloxyphenyl)methyl-[2-[(2-acetyloxyphenyl)methyl-(2-methoxy-2-oxoethyl)amino]ethyl]amino]acetate Chemical compound C=1C=CC=C(OC(C)=O)C=1CN(CC(=O)OC)CCN(CC(=O)OC)CC1=CC=CC=C1OC(C)=O OJURWUUOVGOHJZ-UHFFFAOYSA-N 0.000 claims 1
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 claims 1
- 239000000835 fiber Substances 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 4
- 239000004005 microsphere Substances 0.000 abstract description 4
- 239000002250 absorbent Substances 0.000 abstract description 3
- 239000003086 colorant Substances 0.000 abstract 1
- 230000007547 defect Effects 0.000 abstract 1
- 239000007787 solid Substances 0.000 description 5
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 4
- 238000005336 cracking Methods 0.000 description 4
- MYRTYDVEIRVNKP-UHFFFAOYSA-N divinylbenzene Substances C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 229920000609 methyl cellulose Polymers 0.000 description 4
- 239000001923 methylcellulose Substances 0.000 description 4
- 235000010981 methylcellulose Nutrition 0.000 description 4
- 229940117958 vinyl acetate Drugs 0.000 description 4
- CBOCVOKPQGJKKJ-UHFFFAOYSA-L Calcium formate Chemical compound [Ca+2].[O-]C=O.[O-]C=O CBOCVOKPQGJKKJ-UHFFFAOYSA-L 0.000 description 3
- 239000004281 calcium formate Substances 0.000 description 3
- 229940044172 calcium formate Drugs 0.000 description 3
- 235000019255 calcium formate Nutrition 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 230000010339 dilation Effects 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- 239000006004 Quartz sand Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 241000270708 Testudinidae Species 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000003385 bacteriostatic effect Effects 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- WSWCOQWTEOXDQX-MQQKCMAXSA-N sorbic acid group Chemical group C(\C=C\C=C\C)(=O)O WSWCOQWTEOXDQX-MQQKCMAXSA-N 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
- C08L3/02—Starch; Degradation products thereof, e.g. dextrin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/02—Cellulose; Modified cellulose
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/222—Magnesia, i.e. magnesium oxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/262—Alkali metal carbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/18—Spheres
- C08L2205/20—Hollow spheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/24—Crystallisation aids
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a decorative joint mixture and a preparation method thereof, relating to the technical field of joint mixtures, and the decorative joint mixture comprises the following raw materials in parts by weight: 55-60 parts of water-absorbent resin, 45-47 parts of modified vegetable oil, 38-39 parts of waste porcelain powder, 32-33 parts of redispersible latex powder, 28-29 parts of paraffin phase-change microspheres, 21-23 parts of citric acid, 15-17 parts of plant dehydrated fibers, 12-14 parts of a coloring agent, 20-23 parts of an auxiliary agent and 57-65 parts of water. The invention has the advantages of decorative effect, certain aesthetic degree and excellent crack resistance, overcomes the defects of the existing gap filler, and prolongs the service life of the gap filler and the ceramic tile.
Description
Technical field
The present invention relates to gap filler technical field, and in particular to a kind of ornamental gap filler and preparation method thereof.
Background technology
With the development of construction industry, huge, the matched ceramic wall and floor bricks of all kinds of exterior walls, indoor floor tile consumption
Gap filler consumption is also considerable, at present, and ceramic tile has become one of principal item of China ground and wall decorative material.It is existing
There is ceramic wall and floor tile gap filler mainly to include cement base gap filler and reactive resin gap filler this two major class, but existing fill out
The easy drying shrinkage of seam agent produces crack, rain leakage is caused, while aesthetic measure is relatively low.
The content of the invention
It is an object of the invention to provide a kind of ornamental gap filler and preparation method thereof, with decoration function and certain U.S.
Sight degree, cracking resistance is excellent, overcomes the weak point of existing gap filler, extends itself and ceramic tile service life.
The invention provides following technical scheme:A kind of ornamental gap filler, includes the raw material of following part meter:Water suction tree
55 ~ 60 parts of fat, 45 ~ 47 parts of modified vegetable oil, useless 38 ~ 39 parts of porcelain powder, 32 ~ 33 parts of redispersible latex powder, wax phase change are micro-
28 ~ 29 parts of ball, 21 ~ 23 parts of citric acid, 15 ~ 17 parts of plant dehydration filament, 12 ~ 14 parts of colouring agent, 20 ~ 23 parts of auxiliary agent and water 57
~ 65 parts;
The modified vegetable oil includes the raw material that following part is counted:14 ~ 22 parts of vegetable oil, 10 ~ 12 parts of solvent, 10 ~ 13 parts of modifying agent
With 3 ~ 4 parts of platinum catalyst;
The auxiliary agent includes the raw material that following part is counted:6 ~ 7 parts of antiseptic, 5 ~ 6 parts of crystal growth agent, 5 ~ 6 parts of anticrack additive, guarantor
1 ~ 2 part of 3 ~ 4 parts of water hickener, 3 ~ 4 parts of antifreezing agent, 2 ~ 3 parts of preservative, 1 ~ 2 part of waterproofing agent and antiseptic.
Wherein, the water-absorbing resin is water-absorbent starch resins, cellulose family water-absorbing resin and the water suction of synthesized polymer species
One or more in resin, the useless porcelain powder is directly obtains or crushes waste ceramic progress from ceramic production technology, ball
Powder-grinding and obtain, the redispersible latex powder be vinylacetate and ethylene copolymer rubber powder.
Wherein, the wax phase change microballoon is made up of paraffin and hollow polymer spheroid that enclosing, and the paraffin is packaged in
In hollow polymer spheroid, the hollow polymer spheroid is polymethylacrylic acid-divinylbenzene tiny balloon.
Wherein, the vegetable oil is the one or more in tung oil, soybean oil, castor oil, cottonseed oil and sunflower oil, institute
It is the one or more in methanol, ethanol, allyl polyether and repefral to state solvent, and the modifying agent is diformazan
One or more in the Ethoxysilane of base one, monomethyl diethoxy silane and trimethoxy silane.
Wherein, the plant dehydration filament is Chinese herbal medicine dehydrated fiber silk, and the colouring agent is titanium dioxide, carbon black, oxygen
Change any of red titanium, iron oxide yellow and barba hispanica.
Wherein, the crystal growth agent is lithium carbonate or calcium formate, and the anticrack additive is light calcined magnesia and diatom
Soil is according to 2 ~ 3:1 ratio is mixed, and the water-retaining admixture is methylcellulose or hydroxypropyl methyl cellulose, and viscosity is
150000~200000 cps。
Wherein, the antifreezing agent be calcium chloride or ethylene glycol, the preservative be sorbic acid, potassium sorbate, sodium lactate and
One or more in sodium Diacetate, the waterproofing agent is one in waterproofing agent of organosilicon, nano waterproof agent and aluminate water-proof agent
Plant or several.
Wherein, the antiseptic includes the raw material that following part is counted:8 ~ 11 parts of nano titanium oxide, nano zine oxide 8 ~ 11
1 ~ 2 part of part, 3 ~ 6 parts of oleic acid, 3 ~ 5 parts of polyvinyl alcohol, 1 ~ 3 part of surfactant and corrosion inhibitor
The present invention provides a kind of preparation method of ornamental gap filler, comprises the following steps:
(1), according to proportioning vegetable oil and solvent are weighed, with 200 ~ 300r/min rotating speed mixed dissolution 20 ~ 30min, Ran Houjia
Enter platinum catalyst, continue to mix 15 ~ 20min with 300 ~ 400r/min rotating speed, obtain mixed solution;
To mixed solution and dripping modifying agent, stir and heat with 100 ~ 200r/min rotating speed, heating and temperature control is 85 ~ 95
Degree Celsius, the heat time is 3 ~ 4h, and modified vegetable oil is obtained after cooling;
(2), weigh useless porcelain powder, be put into calcining furnace, under 300 ~ 500 celsius temperatures calcine 2 ~ 3h, take out, obtained after cooling
Useless porcelain powder after calcining;
(3), by step(1)Obtained modified vegetable oil and step(2)Useless porcelain powder mixing after obtained calcining, is then added to
In water-absorbing resin, 20 ~ 35min is stirred with 200 ~ 300r/min rotating speed, base-material is obtained;
(4), according to proportioning weigh surplus stock, sequentially add to step(3)In obtained base-material, with turning for 300 ~ 400r/min
Speed stirring, is uniformly dispersed, obtains the ornamental gap filler.
Beneficial effects of the present invention:With decoration function and certain aesthetics, cracking resistance is excellent, overcomes existing fill out
The weak point of agent is stitched, itself and ceramic tile service life is extended, it is specific as follows:
(1), the present invention in the feed add wax phase change microballoon, be made up of the paraffin and hollow polymer spheroid enclosed, by stone
Wax is isolated with other raw materials, the leakage problem brought when paraffin can be prevented to be converted into liquid by solid, is simultaneously effective protected
The chemical property of paraffin, and the phase change microsphere also has light weight, acid and alkali-resistance and good mechanical strength, when ambient temperature liter
Height, solid paraffin absorbs heat, is undergone phase transition after heat absorption enough, solid paraffin is converted into atoleine;When ambient temperature reduction,
Atoleine discharges heat, is undergone phase transition after release enough, and atoleine is converted into solid, the process of heat absorption and heat release, can be with
The temperature of wax phase change microsphere surface is set to keep relative constancy within a certain period of time so that gap filler of the invention also has insulation
Performance;
(2), the present invention in the feed add crystal growth agent, the fast-growth of crystalline solid can be promoted, by gap filler be used for wall
In the ceramic tile gap on face or ground, when there is crack, crystal growth agent can be played in the minute crack produced by rapid repair
The effect of moisture penetration is prevented, cracking resistance is waterproof, so as to reach the effect on protection wall or ground;
(3), the present invention add plant dehydration filament in the feed, in the ceramic tile gap that gap filler is used for metope or ground,
The thread random stripe of filament generation is had, is visually had a sense of hierarchy very much, coordinates colouring agent, collaboration improves the U.S. in gap
Sight degree;
(4), the present invention add water-retaining admixture in the feed, the effect for playing water conservation and slow setting can improve gap filler
Viscosity, extension operable time are consequently facilitating construct, and can also make gap filler will not be because doing too fast and tortoise after smearing
Split, the intensity after enhancing hardening;Citric acid is added in the feed, can effectively suppress the generation of accumulation of salt in the surface soil phenomenon;
(5), the present invention add useless porcelain powder in the feed, first, useless porcelain powder is added in the feed, by using useless porcelain powder as filling out
Agent filler is stitched, the consumption of other fillers such as quartz sand, dicalcium powder is reduced, second, useless porcelain powder is largely used as raw material,
Resource can be comprehensively utilized, environmental protection and waste utilization, the 3rd, useless porcelain powder passes through high temperature sintering, and physical and chemical performance is stable, volume
It is stable, it is close with ceramic tile dilation coefficient, using the material of same dilation coefficient as filler, reduce ceramic tile joint filling
Agent produces the possibility in crack;
(6), add antiseptic in the present invention, improve anti-microbial property, first, the nano titanium oxide and nano zine oxide of addition,
Together with its special molecular structure can be closely fitted to each raw material, the quantity of macropore and through hole in material is reduced, is formed
Very fine and close structure, the space filled up between raw material so that gap filler uniformly continuous and densification, improve aesthetic measure;
The performance such as the secondth, nano titanium oxide and nano zine oxide also have antibacterial bacteriostatic and taste of dispelling is mould proof;(7), the present invention to be to absorb water
Resin, modified vegetable oil, useless porcelain powder, redispersible latex powder are that primary raw material prepares gap filler, with excellent caking property
Can and cracking resistance, water proof anti-seepage ability is strong, oil resistant, solvent resistant, anticorrosive, nontoxicity, overcome the deficiency of existing gap filler
Part, extends itself and ceramic tile service life.
Embodiment
With reference to specific embodiment, the present invention is expanded on further.These embodiments be merely to illustrate the present invention and without
In limitation the scope of the present invention.
Embodiment 1
A kind of ornamental gap filler, includes the raw material of following part meter:
55 parts of water-absorbing resin, 45 parts of modified vegetable oil, useless 38 parts of porcelain powder, 32 parts of redispersible latex powder, wax phase change microballoon
57 parts of 28 parts, 21 parts of citric acid, 15 parts of plant dehydration filament, 12 parts of colouring agent, 20 parts of auxiliary agent and water;
The modified vegetable oil includes the raw material that following part is counted:14 parts of vegetable oil, 10 parts of solvent, 10 parts of modifying agent and platinum catalyst
3 parts;
The auxiliary agent includes the raw material that following part is counted:6 parts of antiseptic, 5 parts of crystal growth agent, 5 parts of anticrack additive, water-keeping thickening
1 part of 3 parts of agent, 3 parts of antifreezing agent, 2 parts of preservative, 1 part of waterproofing agent and antiseptic.
Wherein, the water-absorbing resin is water-absorbent starch resins, and the useless porcelain powder is directly to be obtained from ceramic production technology
, the redispersible latex powder is vinylacetate and ethylene copolymer rubber powder.
Wherein, the wax phase change microballoon is made up of paraffin and hollow polymer spheroid that enclosing, and the paraffin is packaged in
In hollow polymer spheroid, the hollow polymer spheroid is polymethylacrylic acid-divinylbenzene tiny balloon.
Wherein, the vegetable oil is tung oil, and the solvent is methanol, and the modifying agent is the Ethoxysilane of dimethyl one.
Wherein, the plant dehydration filament is Chinese herbal medicine dehydrated fiber silk, and the colouring agent is titanium dioxide.
Wherein, the crystal growth agent is lithium carbonate, and the anticrack additive is light calcined magnesia and diatomite according to 2:1
Ratio is mixed, and the water-retaining admixture is methylcellulose or hydroxypropyl methyl cellulose, and viscosity is 150000 cps.
Wherein, the antifreezing agent is calcium chloride or ethylene glycol, and the preservative is sorbic acid, and the waterproofing agent is organosilicon
Waterproofing agent.
Wherein, the antiseptic includes the raw material that following part is counted:8 parts of nano titanium oxide, 8 parts of nano zine oxide, oleic acid 3
Part, 3 parts of polyvinyl alcohol, 1 part of surfactant and 1 part of corrosion inhibitor
A kind of preparation method of ornamental gap filler is provided in the present embodiment, comprised the following steps:
(1), according to proportioning weigh vegetable oil and solvent, with 200r/min rotating speed mixed dissolution 20min, then add platinum catalysis
Agent, is continued to mix 15min with 300r/min rotating speed, obtains mixed solution;
To mixed solution and dripping modifying agent, stir and heat with 100r/min rotating speed, heating and temperature control is 85 ~ 95 Celsius
Degree, the heat time is to obtain modified vegetable oil after 3h, cooling;
(2), weigh useless porcelain powder, be put into calcining furnace, 2h calcined under 300 celsius temperatures, take out, obtained after cooling after calcining
Useless porcelain powder;
(3), by step(1)Obtained modified vegetable oil and step(2)Useless porcelain powder mixing after obtained calcining, is then added to
In water-absorbing resin, 20min is stirred with 200r/min rotating speed, base-material is obtained;
(4), according to proportioning weigh surplus stock, sequentially add to step(3)In obtained base-material, stirred with 300r/min rotating speed
Mix, be uniformly dispersed, obtain the ornamental gap filler.
Embodiment 2
A kind of ornamental gap filler, includes the raw material of following part meter:
60 parts of water-absorbing resin, 47 parts of modified vegetable oil, useless 39 parts of porcelain powder, 33 parts of redispersible latex powder, wax phase change microballoon
65 parts of 29 parts, 23 parts of citric acid, 17 parts of plant dehydration filament, 14 parts of colouring agent, 23 parts of auxiliary agent and water;
The modified vegetable oil includes the raw material that following part is counted:22 parts of vegetable oil, 12 parts of solvent, 13 parts of modifying agent and platinum catalyst
4 parts;
The auxiliary agent includes the raw material that following part is counted:7 parts of antiseptic, 6 parts of crystal growth agent, 6 parts of anticrack additive, water-keeping thickening
2 parts of 4 parts of agent, 4 parts of antifreezing agent, 3 parts of preservative, 2 parts of waterproofing agent and antiseptic.
Wherein, the water-absorbing resin is cellulose family water-absorbing resin, and the useless porcelain powder is that waste ceramic is carried out into broken, ball milling
Powder processed and obtain, the redispersible latex powder be vinylacetate and ethylene copolymer rubber powder.
Wherein, the wax phase change microballoon is made up of paraffin and hollow polymer spheroid that enclosing, and the paraffin is packaged in
In hollow polymer spheroid, the hollow polymer spheroid is polymethylacrylic acid-divinylbenzene tiny balloon.
Wherein, the vegetable oil is soybean oil, and the solvent is ethanol, and the modifying agent is monomethyl diethoxy silicon
Alkane.
Wherein, the plant dehydration fiber silk is Chinese herbal medicine dehydrated fiber silk, and the colouring agent is carbon black.
Wherein, the crystal growth agent is calcium formate, and the anticrack additive is light calcined magnesia and diatomite according to 3:1
Ratio is mixed, and the water-retaining admixture is methylcellulose or hydroxypropyl methyl cellulose, and viscosity is 200000 cps,
Wherein, the antifreezing agent is ethylene glycol, and the preservative is sodium lactate, and the waterproofing agent is aluminate water-proof agent.
Wherein, the antiseptic includes the raw material that following part is counted:11 parts of nano titanium oxide, 11 parts of nano zine oxide, oil
2 parts of 6 parts of acid, 5 parts of polyvinyl alcohol, 3 parts of surfactant and corrosion inhibitor
A kind of preparation method of ornamental gap filler is provided in the present embodiment, comprised the following steps:
(1), according to proportioning weigh vegetable oil and solvent, with 300r/min rotating speed mixed dissolution 30min, then add platinum catalysis
Agent, is continued to mix 20min with 400r/min rotating speed, obtains mixed solution;
To mixed solution and dripping modifying agent, stir and heat with 200r/min rotating speed, heating and temperature control is 95 degrees Celsius,
Heat time is to obtain modified vegetable oil after 4h, cooling;
(2), weigh useless porcelain powder, be put into calcining furnace, 3h calcined under 500 celsius temperatures, take out, obtained after cooling after calcining
Useless porcelain powder;
(3), by step(1)Obtained modified vegetable oil and step(2)Useless porcelain powder mixing after obtained calcining, is then added to
In water-absorbing resin, 35min is stirred with 300r/min rotating speed, base-material is obtained;
(4), according to proportioning weigh surplus stock, sequentially add to step(3)In obtained base-material, stirred with 400r/min rotating speed
Mix, be uniformly dispersed, obtain the ornamental gap filler.
Embodiment 3
A kind of ornamental gap filler, includes the raw material of following part meter:
57.5 parts of water-absorbing resin, 46 parts of modified vegetable oil, useless 38.5 parts of porcelain powder, 32.5 parts of redispersible latex powder, paraffin phase
60 parts of 28.5 parts of change microsphere, 22 parts of citric acid, 16 parts of plant dehydration filament, 13 parts of colouring agent, 21.5 parts of auxiliary agent and water;
The modified vegetable oil includes the raw material that following part is counted:18 parts of vegetable oil, 11 parts of solvent, 11.5 parts of modifying agent and platinum catalysis
3.5 parts of agent;
The auxiliary agent includes the raw material that following part is counted:6.5 parts of antiseptic, 5.5 parts of crystal growth agent, 5.5 parts of anticrack additive, guarantor
1.5 parts of 3.5 parts of water hickener, 3.5 parts of antifreezing agent, 2.5 parts of preservative, 1.5 parts of waterproofing agent and antiseptic.
Wherein, the water-absorbing resin is cellulose family water-absorbing resin, and the useless porcelain powder is direct from ceramic production technology
Obtain, the redispersible latex powder is vinylacetate and ethylene copolymer rubber powder.
Wherein, the wax phase change microballoon is made up of paraffin and hollow polymer spheroid that enclosing, and the paraffin is packaged in
In hollow polymer spheroid, the hollow polymer spheroid is polymethylacrylic acid-divinylbenzene tiny balloon.
Wherein, the vegetable oil is castor oil, and the solvent is repefral, and the modifying agent is trimethoxy
Base silane.
Wherein, the plant dehydration filament is Chinese herbal medicine dehydrated fiber silk, and the colouring agent is iron oxide yellow.
Wherein, the crystal growth agent is calcium formate, and the anticrack additive is light calcined magnesia and diatomite according to 2:1
Ratio is mixed, and the water-retaining admixture is methylcellulose, and viscosity is 150000 cps,
Wherein, the antifreezing agent is calcium chloride, and the preservative is sodium Diacetate, and the waterproofing agent is aluminate water-proof agent.
Wherein, the antiseptic includes the raw material that following part is counted:9 parts of nano titanium oxide, 9 parts of nano zine oxide, oleic acid 4
Part, 4 parts of polyvinyl alcohol, 2 parts of surfactant and 1.5 parts of corrosion inhibitor
A kind of preparation method of ornamental gap filler is provided in the present embodiment, comprised the following steps:
(1), according to proportioning weigh vegetable oil and solvent, with 250r/min rotating speed mixed dissolution 25min, then add platinum catalysis
Agent, is continued to mix 17min with 350r/min rotating speed, obtains mixed solution;
To mixed solution and dripping modifying agent, stir and heat with 150r/min rotating speed, heating and temperature control is 90 degrees Celsius,
Heat time is to obtain modified vegetable oil after 3.5h, cooling;
(2), weigh useless porcelain powder, be put into calcining furnace, 2.5h calcined under 400 celsius temperatures, take out, calcined after cooling
Useless porcelain powder afterwards;
(3), by step(1)Obtained modified vegetable oil and step(2)Useless porcelain powder mixing after obtained calcining, is then added to
In water-absorbing resin, 30min is stirred with 250r/min rotating speed, base-material is obtained;
(4), according to proportioning weigh surplus stock, sequentially add to step(3)In obtained base-material, stirred with 350r/min rotating speed
Mix, be uniformly dispersed, obtain the ornamental gap filler.
Claims (10)
1. a kind of ornamental gap filler, it is characterised in that the raw material counted including following part:55 ~ 60 parts of water-absorbing resin, improved plant
45 ~ 47 parts of oil, useless 38 ~ 39 parts of porcelain powder, 32 ~ 33 parts of redispersible latex powder, 28 ~ 29 parts of wax phase change microballoon, citric acid 21 ~
57 ~ 65 parts of 23 parts, 15 ~ 17 parts of plant dehydration filament, 12 ~ 14 parts of colouring agent, 20 ~ 23 parts of auxiliary agent and water;
The modified vegetable oil includes the raw material that following part is counted:14 ~ 22 parts of vegetable oil, 10 ~ 12 parts of solvent, 10 ~ 13 parts of modifying agent
With 3 ~ 4 parts of platinum catalyst;
The auxiliary agent includes the raw material that following part is counted:6 ~ 7 parts of antiseptic, 5 ~ 6 parts of crystal growth agent, 5 ~ 6 parts of anticrack additive, guarantor
1 ~ 2 part of 3 ~ 4 parts of water hickener, 3 ~ 4 parts of antifreezing agent, 2 ~ 3 parts of preservative, 1 ~ 2 part of waterproofing agent and antiseptic.
2. ornamental gap filler according to claim 1, it is characterised in that the raw material counted including following part:Water-absorbing resin
57.5 parts, 46 parts of modified vegetable oil, useless 38.5 parts of porcelain powder, 32.5 parts of redispersible latex powder, 28.5 parts of wax phase change microballoon,
60 parts of 22 parts of citric acid, 16 parts of plant dehydration filament, 13 parts of colouring agent, 21.5 parts of auxiliary agent and water;
The modified vegetable oil includes the raw material that following part is counted:18 parts of vegetable oil, 11 parts of solvent, 11.5 parts of modifying agent and platinum catalysis
3.5 parts of agent;
The auxiliary agent includes the raw material that following part is counted:6.5 parts of antiseptic, 5.5 parts of crystal growth agent, 5.5 parts of anticrack additive, guarantor
1.5 parts of 3.5 parts of water hickener, 3.5 parts of antifreezing agent, 2.5 parts of preservative, 1.5 parts of waterproofing agent and antiseptic.
3. ornamental gap filler according to claim 1, it is characterised in that the water-absorbing resin is starch water suction tree
One or more in fat, cellulose family water-absorbing resin and synthesized polymer species water-absorbing resin, the useless porcelain powder is from ceramic green
Directly obtained in production. art or waste ceramic is subjected to broken, ball powder-grinding and obtained, the redispersible latex powder is acetic acid second
Alkene ester and ethylene copolymer rubber powder.
4. ornamental gap filler according to claim 1, it is characterised in that the wax phase change microballoon is by the paraffin enclosed
It is made with hollow polymer spheroid, the paraffin is packaged in hollow polymer spheroid, the hollow polymer spheroid is poly- first
Base acrylic acid-divinylbenzene tiny balloon.
5. ornamental gap filler according to claim 1, it is characterised in that the vegetable oil is tung oil, soybean oil, castor-oil plant
One or more in oil, cottonseed oil and sunflower oil, the solvent is methanol, ethanol, allyl polyether and phthalic acid
One or more in dimethyl ester, the modifying agent is the Ethoxysilane of dimethyl one, monomethyl diethoxy silane and front three
One or more in TMOS.
6. ornamental gap filler according to claim 1, it is characterised in that the plant dehydration filament is de- for Chinese herbal medicine
Water cellulose silk, the colouring agent is any of titanium dioxide, carbon black, red titanium oxide, iron oxide yellow and barba hispanica.
7. ornamental gap filler according to claim 1, it is characterised in that the crystal growth agent is lithium carbonate or formic acid
Calcium, the anticrack additive is light calcined magnesia and diatomite according to 2 ~ 3:1 ratio is mixed, and the water-retaining admixture is first
Base cellulose or hydroxypropyl methyl cellulose, viscosity are 150000 ~ 200000 cps.
8. ornamental gap filler according to claim 1, it is characterised in that the antifreezing agent is calcium chloride or ethylene glycol,
The preservative is the one or more in sorbic acid, potassium sorbate, sodium lactate and sodium Diacetate, and the waterproofing agent is organosilicon
One or more in waterproofing agent, nano waterproof agent and aluminate water-proof agent.
9. ornamental gap filler according to claim 1, it is characterised in that the antiseptic includes the original that following part is counted
Material:8 ~ 11 parts of nano titanium oxide, 8 ~ 11 parts of nano zine oxide, 3 ~ 6 parts of oleic acid, 3 ~ 5 parts of polyvinyl alcohol, surfactant 1 ~ 3
1 ~ 2 part of part and corrosion inhibitor.
10. a kind of preparation method of ornamental gap filler according to any one of claim 1 ~ 9, it is characterised in that including
Following steps:
(1), according to proportioning vegetable oil and solvent are weighed, with 200 ~ 300r/min rotating speed mixed dissolution 20 ~ 30min, Ran Houjia
Enter platinum catalyst, continue to mix 15 ~ 20min with 300 ~ 400r/min rotating speed, obtain mixed solution;
To mixed solution and dripping modifying agent, stir and heat with 100 ~ 200r/min rotating speed, heating and temperature control is 85 ~ 95
Degree Celsius, the heat time is 3 ~ 4h, and modified vegetable oil is obtained after cooling;
(2), weigh useless porcelain powder, be put into calcining furnace, under 300 ~ 500 celsius temperatures calcine 2 ~ 3h, take out, obtained after cooling
Useless porcelain powder after calcining;
(3), by step(1)Obtained modified vegetable oil and step(2)Useless porcelain powder mixing after obtained calcining, is then added to
In water-absorbing resin, 20 ~ 35min is stirred with 200 ~ 300r/min rotating speed, base-material is obtained;
(4), according to proportioning weigh surplus stock, sequentially add to step(3)In obtained base-material, with turning for 300 ~ 400r/min
Speed stirring, is uniformly dispersed, obtains the ornamental gap filler.
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CN107858036A (en) * | 2017-11-02 | 2018-03-30 | 陈谓清 | A kind of gap filler and preparation method thereof |
CN109653523A (en) * | 2017-10-12 | 2019-04-19 | 蒲连影 | A kind of civil buildings exterior wall crack repairing method |
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CN102167547A (en) * | 2010-12-22 | 2011-08-31 | 北京东方雨虹防水技术股份有限公司 | Cementitious capillary crystalline waterproof material capable of quickly repairing cracks |
CN102352159A (en) * | 2011-10-28 | 2012-02-15 | 中华制漆(深圳)有限公司 | Water-based phase-change microspherical thermal-insulation paint for internal walls and preparation method thereof |
CN102775869A (en) * | 2012-08-17 | 2012-11-14 | 上海铂亨建材科技发展有限公司 | Plant herbal fiber emulsion paint |
CN103172330A (en) * | 2013-03-13 | 2013-06-26 | 厦门路桥翔通建材科技有限公司 | Environment-friendly colorful tile joint mixture and preparation method thereof |
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CN101386495A (en) * | 2008-10-29 | 2009-03-18 | 罗寅 | Thermal insulation elastic joint filling agent |
CN102167547A (en) * | 2010-12-22 | 2011-08-31 | 北京东方雨虹防水技术股份有限公司 | Cementitious capillary crystalline waterproof material capable of quickly repairing cracks |
CN102352159A (en) * | 2011-10-28 | 2012-02-15 | 中华制漆(深圳)有限公司 | Water-based phase-change microspherical thermal-insulation paint for internal walls and preparation method thereof |
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