CN106833059A - A kind of wear-resisting waterproof wallpaper and preparation method thereof - Google Patents

A kind of wear-resisting waterproof wallpaper and preparation method thereof Download PDF

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Publication number
CN106833059A
CN106833059A CN201611200003.5A CN201611200003A CN106833059A CN 106833059 A CN106833059 A CN 106833059A CN 201611200003 A CN201611200003 A CN 201611200003A CN 106833059 A CN106833059 A CN 106833059A
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China
Prior art keywords
parts
layer
wear
waterproof
agent
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Withdrawn
Application number
CN201611200003.5A
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Chinese (zh)
Inventor
陈少明
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Anhui Easy Wallpaper Co Ltd
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Anhui Easy Wallpaper Co Ltd
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Application filed by Anhui Easy Wallpaper Co Ltd filed Critical Anhui Easy Wallpaper Co Ltd
Priority to CN201611200003.5A priority Critical patent/CN106833059A/en
Publication of CN106833059A publication Critical patent/CN106833059A/en
Withdrawn legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/10—Homopolymers or copolymers of methacrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/042—Acrylic polymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/18—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D06N7/0002—Wallpaper or wall covering on textile basis
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/38—Coatings with pigments characterised by the pigments
    • D21H19/385—Oxides, hydroxides or carbonates
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/38—Coatings with pigments characterised by the pigments
    • D21H19/40—Coatings with pigments characterised by the pigments siliceous, e.g. clays
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/46—Non-macromolecular organic compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/46—Non-macromolecular organic compounds
    • D21H19/48—Diolefins, e.g. butadiene; Aromatic vinyl monomers, e.g. styrene; Polymerisable unsaturated acids or derivatives thereof, e.g. acrylic acid
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/52—Cellulose; Derivatives thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H19/58—Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/62—Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/64—Inorganic compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/80—Paper comprising more than one coating
    • D21H19/82—Paper comprising more than one coating superposed
    • D21H19/822—Paper comprising more than one coating superposed two superposed coatings, both being pigmented
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/16—Sizing or water-repelling agents
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
    • D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
    • D21H23/22—Addition to the formed paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H25/00—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
    • D21H25/04—Physical treatment, e.g. heating, irradiating
    • D21H25/06—Physical treatment, e.g. heating, irradiating of impregnated or coated paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/18—Paper- or board-based structures for surface covering
    • D21H27/20—Flexible structures being applied by the user, e.g. wallpaper
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00—Coverings or linings, e.g. for walls or ceilings
    • E04F13/002—Coverings or linings, e.g. for walls or ceilings made of webs, e.g. of fabrics, or wallpaper, used as coverings or linings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/14—Properties of the materials having chemical properties
    • D06N2209/142—Hydrophobic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/16—Properties of the materials having other properties
    • D06N2209/1685—Wear resistance
    • D—TEXTILES; PAPER
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    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00—Specially adapted uses
    • D06N2211/06—Building materials
    • D06N2211/063—Wall coverings

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Textile Engineering (AREA)
  • Architecture (AREA)
  • Inorganic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Paper (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a kind of wear-resisting waterproof wallpaper, including substrate layer, waterproof layer and wearing layer, the periphery of substrate layer is coated with waterproof layer, and the waterproof layer is coated with wearing layer away from the periphery of substrate layer, wherein：The raw material of wearing layer includes polymethacrylates, hydroxy acryl acid resin, isocyanate curing agent, organic siliconresin, epoxy resin E 13, aluminium powder, nano titanium oxide, ceramic powder, modified additive, butyl glycol ether, HMMM, dimethylethanolamine, isopropanol, calgon, butyl acetate, silane coupler KH 560, microcrystalline wax, levelling agent BYK 331, wetting agent, dimethyl silicone polymer, dimethylbenzene and deionized water.The present invention also proposes a kind of preparation method of above-mentioned wear-resisting waterproof wallpaper.The wallpaper for preparing has excellent wear-resisting water resistance.

Description

A kind of wear-resisting waterproof wallpaper and preparation method thereof
Technical field
The present invention relates to wallpaper field, more particularly to a kind of wear-resisting waterproof wallpaper and preparation method thereof.
Background technology
Wallpaper because have that color is various, pattern abundant, luxurious style, safety and environmental protection, easy construction, affordable etc. it is many The characteristics of other house decorative materials of kind institute is incomparable, increasingly popularizes, in the prior art wall in daily life Demand when the wear-resisting and water resistance of paper cannot meet actually used, therefore need a kind of design wear-resisting waterproof wallpaper badly and meet Demand when actually used.
The content of the invention
To solve technical problem present in background technology, the present invention proposes a kind of wear-resisting waterproof wallpaper and its preparation side Method, the wallpaper for preparing has excellent wear-resisting water resistance.
A kind of wear-resisting waterproof wallpaper proposed by the present invention, including substrate layer, waterproof layer and wearing layer, the periphery of substrate layer apply Waterproof layer is covered with, the waterproof layer is coated with wearing layer away from the periphery of substrate layer, wherein：
Substrate layer is any one in wood pulp paper, non-woven paper, cloth；
The raw material of waterproof layer includes by weight：Perfluoroalkyl acrylate 45-65 parts, fluorinated acrylate emulsion 15- 25 parts, watersoluble modified hydroxyl acrylic aqueous dispersion 5-15 parts, 6-12 parts of imino group melamine resin high, N, N- dimethyl Monoethanolamine 1-6 parts, isopropanol 2-5 parts, propandiol butyl ether 1-4 parts, polyamide wax 3-5 parts, aqueous aluminum powder 2-5 parts, acetate butyrate Cellulose 1-4 parts, methyl methacrylate 3-6 parts, butyl acrylate 2-8 parts, dimethylaminoethyl acrylate methyl base aminoethyl 1-7 Part, hydroxy-ethyl acrylate 2-5 parts, N, N- dimethyl-N '-(2- Trifluoromethyl-1s-pentafluoroethyl group) 3-5 parts, octadecyl front three Ammonium chloride 1-5 parts, potassium peroxydisulfate 2-5 parts, nano silicon 1-4 parts, anti-settling agent 3-6 parts, wetting agent 2-4 parts, levelling agent 1-4 parts, 2-6 parts of anti-flash rusting agent, 4-6 parts of polyoxyethylene polyoxy propyl alcohol amidogen ether, thickener 1-4 parts, Antifog bactericide 2-5 parts, it is anti- Mould bactericide 1-3 parts, deionized water 8-16 parts；
The raw material of wearing layer includes by weight：Polymethacrylates 25-35 parts, hydroxy acryl acid resin 2-8 parts, Isocyanate curing agent 3-9 parts, organic siliconresin 1-5 parts, 3-6 parts of epoxy resin E-13, aluminium powder 2-5 parts, nano titanium oxide 2-8 parts, ceramic powder 1-8 parts, modified additive 3-6 parts, butyl glycol ether 1-3 parts, HMMM 2-6 parts, two Methylethanolamine 1-4 parts, isopropanol 2-4 parts, calgon 3-5 parts, butyl acetate 1-4 parts, silane coupler KH-560 2- 5 parts, microcrystalline wax 3-6 parts, 2-4 parts of levelling agent BYK-331, wetting agent 1-4 parts, dimethyl silicone polymer 3-6 parts, dimethylbenzene 1-4 parts, deionized water 12-18 parts.
Preferably, in the raw material of wearing layer, the raw material of modified additive includes by weight：Silane coupler KH-560 5- 15 parts, carbon black 2-6 parts, tapioca starch 6-12 parts, montmorillonite 1-5 parts, kaolin 2-4 parts, shitosan 4-8 parts, nanometer silicon carbide 3-5 Part, nano silicon 1-6 parts, Nano diamond 3-5 parts, attapulgite 4-8 parts.
Preferably, in the raw material of wearing layer, modified additive is prepared by following technique：By silane coupler KH-560 and Distilled water be well mixed, be then placed in heating 25-35min in water-bath, be subsequently added into carbon black, tapioca starch, montmorillonite, kaolin, Shitosan, nanometer silicon carbide, nano silicon, Nano diamond and attapulgite, ultrasonic disperse 10-20min, are then adjusted PH to 2.5-3.5, is then placed in heating 25-35min in water-bath, then carries out separation of solid and liquid, by the solid distillation after separation Water washing 2-4 times, being subsequently adding n-butanol carries out distillation dehydration, and then the powder after dehydration is put into 100-120 DEG C of baking oven 1-3h is dried, room temperature is cooled to and is obtained modified additive.
Preferably, the raw material of wearing layer includes by weight：Polymethacrylates 28-32 parts, hydroxy acryl acid tree Fat 3-7 parts, isocyanate curing agent 4-8 parts, organic siliconresin 2-4 parts, 4-5 parts of epoxy resin E-13, aluminium powder 3-4 parts, nanometer Titanium dioxide 3-7 parts, ceramic powder 2-7 parts, modified additive 4-5 parts, butyl glycol ether 1.5-2.5 parts, hexamethoxy methyl trimerization Cyanamide 3-5 parts, dimethylethanolamine 2-3 parts, isopropanol 2.5-3.5 parts, calgon 3.5-4.5 parts, butyl acetate 2-3 Part, 3-4 parts of silane coupler KH-560, microcrystalline wax 4-5 parts, 2.5-3.5 parts of levelling agent BYK-331, wetting agent 2-3 parts, Dimethyl silicone polymer 4-5 parts, dimethylbenzene 2-3 parts, deionized water 14-16 parts.
Preferably, the raw material of wearing layer includes by weight：30 parts of polymethacrylates, hydroxy acryl acid resin 5 Part, 6 parts of isocyanate curing agent, 3 parts of organic siliconresin, 4.5 parts of epoxy resin E-13,3.5 parts of aluminium powder, nano titanium oxide 5 Part, 4.5 parts of ceramic powder, 4.5 parts of modified additive, 2 parts of butyl glycol ether, 4 parts of HMMM, dimethyl ethanol 2.5 parts of amine, 3 parts of isopropanol, 4 parts of calgon, 2.5 parts of butyl acetate, 3.5 parts of silane coupler KH-560, microcrystalline wax 4.5 parts, 3 parts of levelling agent BYK-331,2.5 parts of wetting agent, 4.5 parts of dimethyl silicone polymer, 2.5 parts of dimethylbenzene, deionized water 15 parts.
A kind of preparation method of wear-resisting waterproof wallpaper of the invention, comprises the following steps：
S1, the figuratum printing layer of tool is formed on substrate layer by typography in base material layer surface, wallpaper half is obtained Finished product；
S2, the front of wallpaper semi-finished product by cylinder overprinting process print waterproof layer；
S3, the feedstock composition of wearing layer is printed on the layer of waterproof layer using cylinder overprinting process, forms wearing layer, It is placed in after being completed for printing in baking oven and is dried, is cooled to room temperature and obtains wear-resisting waterproof wallpaper.
Preferably, in S3, cylinder overprinting process parameter is specially：Print speed printing speed is 5-15m/min；Oven temperature is first to use 100-120 DEG C of drying, then form adhesion effect with 160-180 DEG C of film forming；It is formed with hexagonal loop on cylinder, hexagonal loop is opened Porosity is 30-45%；The thickness of net of finished product cylinder is 0.1-0.3mm.
Preferably, in S3, dry temperature is 70-90 DEG C, and the dry time is 4-6h.
A kind of wear-resisting waterproof wallpaper of the invention, including substrate layer, waterproof layer and wearing layer, the periphery of substrate layer is coated with Waterproof layer, the waterproof layer is coated with wearing layer away from the periphery of substrate layer, wherein：The raw material of waterproof layer includes perfluoroalkyl third Olefin(e) acid ester, fluorinated acrylate emulsion, watersoluble modified hydroxyl acrylic aqueous dispersion, imino group melamine resin high, N, N- dimethylethanolamines, isopropanol, propandiol butyl ether, polyamide wax, aqueous aluminum powder, acetylbutyrylcellulose, methacrylic acid Methyl esters, butyl acrylate, dimethylaminoethyl acrylate methyl base aminoethyl, hydroxy-ethyl acrylate, N, N- dimethyl-N '-(2- fluoroforms Base -1- pentafluoroethyl groups), OTAC, potassium peroxydisulfate, nano silicon, anti-settling agent, wetting agent, levelling Agent, anti-flash rusting agent, polyoxyethylene polyoxy propyl alcohol amidogen ether, thickener, Antifog bactericide, antimildew disinfectant and deionized water；With complete Fluoroalkyl, fluorinated acrylate emulsion, watersoluble modified hydroxyl acrylic aqueous dispersion and imino group melamine first high Urea formaldehyde is base-material, with N, N- dimethylethanolamines, isopropanol, propandiol butyl ether, polyamide wax, aqueous aluminum powder, acetate butyrate Cellulose, methyl methacrylate, butyl acrylate, dimethylaminoethyl acrylate methyl base aminoethyl, hydroxy-ethyl acrylate, N, N- bis- It is methyl-N '-(2- Trifluoromethyl-1s-pentafluoroethyl group), OTAC, potassium peroxydisulfate, nano silicon, anti- Heavy agent, wetting agent, levelling agent, anti-flash rusting agent, polyoxyethylene polyoxy propyl alcohol amidogen ether, thickener, Antifog bactericide, antimildew disinfectant It is auxiliary agent with deionized water, by the cooperation of base-material and auxiliary agent, rationally control is matched, and the waterproof layer for obtaining has excellent waterproof Performance.The raw material of wearing layer includes polymethacrylates, hydroxy acryl acid resin, isocyanate curing agent, organosilicon tree Fat, epoxy resin E-13, aluminium powder, nano titanium oxide, ceramic powder, modified additive, butyl glycol ether, hexamethoxy methyl trimerization Cyanamide, dimethylethanolamine, isopropanol, calgon, butyl acetate, silane coupler KH-560, microcrystalline wax, levelling agent BYK-331, wetting agent, dimethyl silicone polymer, dimethylbenzene and deionized water, with polymethacrylates, hydroxy acryl acid Resin, isocyanate curing agent, organic siliconresin and epoxy resin E-13 are base-material, with aluminium powder, nano titanium oxide, ceramic powder It is auxiliary material with modified additive, with butyl glycol ether, HMMM, dimethylethanolamine, isopropanol, six inclined phosphorus Sour sodium, butyl acetate, silane coupler KH-560, microcrystalline wax, levelling agent BYK-331, wetting agent, dimethyl silicone polymer, Dimethylbenzene and deionized water are auxiliary agent, and by the cooperation of base-material, filler and auxiliary agent, rationally control is matched, the wearing layer tool for obtaining There is excellent anti-wear performance.Wherein in the raw material of wearing layer, modified additive is mixed by by silane coupler KH-560 and distilled water Close uniform, be then placed in being heated in water-bath, be subsequently added into carbon black, tapioca starch, montmorillonite, kaolin, shitosan, nano silicon carbide Silicon, nano silicon, Nano diamond and attapulgite, ultrasonic disperse then adjust pH, are then placed in being heated in water-bath, Then separation of solid and liquid is carried out, by the distillation water washing of the solid after separation, being subsequently adding n-butanol carries out distillation dehydration, then will Powder after dehydration is put into baking oven and dries, and is cooled to room temperature and obtains modified additive, in applying to the preparation of wearing layer, further Improve the anti-wear performance of wearing layer.The wallpaper that the present invention is prepared has excellent wear-resisting water resistance.
Brief description of the drawings
Fig. 1 is a kind of structural representation of wear-resisting waterproof wallpaper proposed by the present invention.
Specific embodiment
The present invention is described in detail with reference to specific embodiment, it should be appreciated that embodiment is served only for illustrating this hair Bright, rather than for limiting the invention, any modification made on the basis of the present invention, equivalent etc. are in this hair In bright protection domain.
Embodiment 1
As shown in figure 1, Fig. 1 is a kind of structural representation of wear-resisting waterproof wallpaper proposed by the present invention.
Reference picture 1, a kind of wear-resisting waterproof wallpaper proposed by the present invention, including substrate layer 1, waterproof layer 2 and wearing layer 3, base The periphery of material layer 1 is coated with waterproof layer 2, and the waterproof layer 2 is coated with wearing layer 3 away from the periphery of substrate layer 1, wherein：
Substrate layer 1 is wood pulp paper；
The raw material of waterproof layer 2 includes by weight：55 parts of perfluoroalkyl acrylate, 20 parts of fluorinated acrylate emulsion, 10 parts of watersoluble modified hydroxyl acrylic aqueous dispersion, 9 parts of imino group melamine resin high, N, N- dimethylethanolamines 3.5 Part, 3.5 parts of isopropanol, 2.5 parts of propandiol butyl ether, 4 parts of polyamide wax, 3.5 parts of aqueous aluminum powder, 2.5 parts of acetylbutyrylcellulose, 4.5 parts of methyl methacrylate, 5 parts of butyl acrylate, 4 parts of dimethylaminoethyl acrylate methyl base aminoethyl, hydroxy-ethyl acrylate 3.5 Part, N, N- dimethyl-N ' -4 parts of (2- Trifluoromethyl-1s-pentafluoroethyl group), 3 parts of OTAC, potassium peroxydisulfate 3.5 parts, 2.5 parts of nano silicon, 4.5 parts of anti-settling agent, 3 parts of wetting agent, 2.5 parts of levelling agent, 4 parts of anti-flash rusting agent, polyoxy second 5 parts of alkene polyoxy propyl alcohol amidogen ether, 2.5 parts of thickener, 3.5 parts of Antifog bactericide, 2 parts of antimildew disinfectant, 12 parts of deionized water；
The raw material of wearing layer 3 includes by weight：30 parts of polymethacrylates, 5 parts of hydroxy acryl acid resin, isocyanide 6 parts of acid esters curing agent, 3 parts of organic siliconresin, 4.5 parts of epoxy resin E-13,3.5 parts of aluminium powder, 5 parts of nano titanium oxide, ceramics 4.5 parts of powder, 4.5 parts of modified additive, 2 parts of butyl glycol ether, 4 parts of HMMM, dimethylethanolamine 2.5 Part, 3 parts of isopropanol, 4 parts of calgon, 2.5 parts of butyl acetate, 3.5 parts of silane coupler KH-560, microcrystalline wax 4.5 Part, 3 parts of levelling agent BYK-331,2.5 parts of wetting agent, 4.5 parts of dimethyl silicone polymer, 2.5 parts of dimethylbenzene, deionized water 15 Part.
In the raw material of wearing layer 3, modified additive is prepared by following technique：By weight by 10 parts of silane couplers KH-560 and distilled water are well mixed, are then placed in heating 30min in water-bath, be subsequently added into 4 parts of carbon blacks, 9 parts of tapioca starch, 3 parts Montmorillonite, 3 parts of kaolin, 6 parts of shitosans, 4 parts of nanometer silicon carbides, 3.5 parts of nano silicons, 4 parts of Nano diamonds and 6 parts Attapulgite, ultrasonic disperse 15min then adjusts pH to 3, is then placed in heating 30min in water-bath, then carries out solid-liquid point From by the solid after separation with water washing is distilled 3 times, being subsequently adding n-butanol carries out distillation dehydration, then by the powder after dehydration End dries 2h in being put into 110 DEG C of baking ovens, is cooled to room temperature and obtains modified additive.
A kind of preparation method of wear-resisting waterproof wallpaper of the invention, comprises the following steps：
S1, the figuratum printing layer of tool is formed on substrate layer by typography in base material layer surface, wallpaper half is obtained Finished product；
S2, the front of wallpaper semi-finished product by cylinder overprinting process print waterproof layer；
S3, the feedstock composition of wearing layer is printed on the layer of waterproof layer using cylinder overprinting process, forms wearing layer, It is placed in after being completed for printing in baking oven and is dried, dry temperature is 80 DEG C, and the dry time is 5h, is cooled to room temperature and obtains wear-resisting anti- Waterwall paper, wherein, cylinder overprinting process parameter is specially：Print speed printing speed is 10m/min；Oven temperature is first to be dried with 110 DEG C, Again adhesion effect is formed with 170 DEG C of film forming；Hexagonal loop is formed with cylinder, the percent opening of hexagonal loop is 37.5%；Finished product The thickness of net of cylinder is 0.2mm.
Embodiment 2
As shown in figure 1, Fig. 1 is a kind of structural representation of wear-resisting waterproof wallpaper proposed by the present invention.
Reference picture 1, a kind of wear-resisting waterproof wallpaper proposed by the present invention, including substrate layer 1, waterproof layer 2 and wearing layer 3, base The periphery of material layer 1 is coated with waterproof layer 2, and the waterproof layer 2 is coated with wearing layer 3 away from the periphery of substrate layer 1, wherein：
Substrate layer 1 is non-woven paper；
The raw material of waterproof layer 2 includes by weight：45 parts of perfluoroalkyl acrylate, 25 parts of fluorinated acrylate emulsion, 5 parts of watersoluble modified hydroxyl acrylic aqueous dispersion, 12 parts of imino group melamine resin high, N, 1 part of N- dimethylethanolamines, 5 parts of isopropanol, 1 part of propandiol butyl ether, 5 parts of polyamide wax, 2 parts of aqueous aluminum powder, 4 parts of acetylbutyrylcellulose, methacrylic acid 3 parts of methyl esters, 8 parts of butyl acrylate, 1 part of dimethylaminoethyl acrylate methyl base aminoethyl, 5 parts of hydroxy-ethyl acrylate, N, N- dimethyl- N ' -3 parts of (2- Trifluoromethyl-1s-pentafluoroethyl group), 5 parts of OTAC, 2 parts of potassium peroxydisulfate, nanometer titanium dioxide 4 parts of silicon, 3 parts of anti-settling agent, 4 parts of wetting agent, 1 part of levelling agent, 6 parts of anti-flash rusting agent, 4 parts of polyoxyethylene polyoxy propyl alcohol amidogen ether, thickening 4 parts of agent, 2 parts of Antifog bactericide, 3 parts of antimildew disinfectant, 8 parts of deionized water；
The raw material of wearing layer 3 includes by weight：25 parts of polymethacrylates, 8 parts of hydroxy acryl acid resin, isocyanide 3 parts of acid esters curing agent, 5 parts of organic siliconresin, 3 parts of epoxy resin E-13,5 parts of aluminium powder, 2 parts of nano titanium oxide, ceramic powder 8 Part, 3 parts of modified additive, 3 parts of butyl glycol ether, 2 parts of HMMM, 4 parts of dimethylethanolamine, isopropanol 2 Part, 5 parts of calgon, 1 part of butyl acetate, 5 parts of silane coupler KH-560,3 parts of microcrystalline wax, levelling agent BYK-331 4 Part, 1 part of wetting agent, 6 parts of dimethyl silicone polymer, 1 part of dimethylbenzene, 18 parts of deionized water.
In the raw material of wearing layer 3, modified additive is prepared by following technique：By weight by 5 parts of silane coupler KH- 560 and distilled water it is well mixed, be then placed in heating 35min in water-bath, be subsequently added into 2 parts of carbon blacks, 12 parts of tapioca starch, 1 part of illiteracy De- soil, 4 parts of kaolin, 4 parts of shitosans, 5 parts of nanometer silicon carbides, 1 part of nano silicon, 5 parts of Nano diamonds and 4 parts are concavo-convex Rod soil, ultrasonic disperse 20min then adjusts pH to 2.5, is then placed in heating 35min in water-bath, then carries out separation of solid and liquid, By the solid after separation with water washing is distilled 2 times, being subsequently adding n-butanol carries out distillation dehydration, then puts the powder after dehydration Enter and dry 1h in 120 DEG C of baking ovens, be cooled to room temperature and obtain modified additive.
A kind of preparation method of wear-resisting waterproof wallpaper of the invention, comprises the following steps：
S1, the figuratum printing layer of tool is formed on substrate layer by typography in base material layer surface, wallpaper half is obtained Finished product；
S2, the front of wallpaper semi-finished product by cylinder overprinting process print waterproof layer；
S3, the feedstock composition of wearing layer is printed on the layer of waterproof layer using cylinder overprinting process, forms wearing layer, It is placed in after being completed for printing in baking oven and is dried, dry temperature is 70 DEG C, and the dry time is 6h, is cooled to room temperature and obtains wear-resisting anti- Waterwall paper, wherein, cylinder overprinting process parameter is specially：Print speed printing speed is 5m/min；Oven temperature is first to be dried with 120 DEG C, Again adhesion effect is formed with 160 DEG C of film forming；Hexagonal loop is formed with cylinder, the percent opening of hexagonal loop is 45%；Finished product is justified The thickness of net of net is 0.1mm.
Embodiment 3
As shown in figure 1, Fig. 1 is a kind of structural representation of wear-resisting waterproof wallpaper proposed by the present invention.
Reference picture 1, a kind of wear-resisting waterproof wallpaper proposed by the present invention, including substrate layer 1, waterproof layer 2 and wearing layer 3, base The periphery of material layer 1 is coated with waterproof layer 2, and the waterproof layer 2 is coated with wearing layer 3 away from the periphery of substrate layer 1, wherein：
Substrate layer 1 is cloth；
The raw material of waterproof layer 2 includes by weight：65 parts of perfluoroalkyl acrylate, 15 parts of fluorinated acrylate emulsion, 15 parts of watersoluble modified hydroxyl acrylic aqueous dispersion, 6 parts of imino group melamine resin high, N, 6 parts of N- dimethylethanolamines, 2 parts of isopropanol, 4 parts of propandiol butyl ether, 3 parts of polyamide wax, 5 parts of aqueous aluminum powder, 1 part of acetylbutyrylcellulose, methacrylic acid 6 parts of methyl esters, 2 parts of butyl acrylate, 7 parts of dimethylaminoethyl acrylate methyl base aminoethyl, 2 parts of hydroxy-ethyl acrylate, N, N- dimethyl- N ' -5 parts of (2- Trifluoromethyl-1s-pentafluoroethyl group), 1 part of OTAC, 5 parts of potassium peroxydisulfate, nanometer titanium dioxide 1 part of silicon, 6 parts of anti-settling agent, 2 parts of wetting agent, 4 parts of levelling agent, 2 parts of anti-flash rusting agent, 6 parts of polyoxyethylene polyoxy propyl alcohol amidogen ether, thickening 1 part of agent, 5 parts of Antifog bactericide, 1 part of antimildew disinfectant, 16 parts of deionized water；
The raw material of wearing layer 3 includes by weight：35 parts of polymethacrylates, 2 parts of hydroxy acryl acid resin, isocyanide 9 parts of acid esters curing agent, 1 part of organic siliconresin, 6 parts of epoxy resin E-13,2 parts of aluminium powder, 8 parts of nano titanium oxide, ceramic powder 1 Part, 6 parts of modified additive, 1 part of butyl glycol ether, 6 parts of HMMM, 1 part of dimethylethanolamine, isopropanol 4 Part, 3 parts of calgon, 4 parts of butyl acetate, 2 parts of silane coupler KH-560,6 parts of microcrystalline wax, levelling agent BYK-331 2 Part, 4 parts of wetting agent, 3 parts of dimethyl silicone polymer, 4 parts of dimethylbenzene, 12 parts of deionized water.
In the raw material of wearing layer 3, modified additive is prepared by following technique：By weight by 15 parts of silane couplers KH-560 and distilled water are well mixed, are then placed in heating 25min in water-bath, be subsequently added into 6 parts of carbon blacks, 6 parts of tapioca starch, 5 parts Montmorillonite, 2 parts of kaolin, 8 parts of shitosans, 3 parts of nanometer silicon carbides, 6 parts of nano silicons, 3 parts of Nano diamonds and 8 parts are recessed Convex rod soil, ultrasonic disperse 10min then adjusts pH to 3.5, is then placed in heating 25min in water-bath, then carries out solid-liquid point From by the solid after separation with water washing is distilled 4 times, being subsequently adding n-butanol carries out distillation dehydration, then by the powder after dehydration End dries 3h in being put into 100 DEG C of baking ovens, is cooled to room temperature and obtains modified additive.
A kind of preparation method of wear-resisting waterproof wallpaper of the invention, comprises the following steps：
S1, the figuratum printing layer of tool is formed on substrate layer by typography in base material layer surface, wallpaper half is obtained Finished product；
S2, the front of wallpaper semi-finished product by cylinder overprinting process print waterproof layer；
S3, the feedstock composition of wearing layer is printed on the layer of waterproof layer using cylinder overprinting process, forms wearing layer, It is placed in after being completed for printing in baking oven and is dried, dry temperature is 90 DEG C, and the dry time is 4h, is cooled to room temperature and obtains wear-resisting anti- Waterwall paper, wherein, cylinder overprinting process parameter is specially：Print speed printing speed is 15m/min；Oven temperature is first to be dried with 100 DEG C, Again adhesion effect is formed with 180 DEG C of film forming；Hexagonal loop is formed with cylinder, the percent opening of hexagonal loop is 30%；Finished product is justified The thickness of net of net is 0.3mm.
Embodiment 4
As shown in figure 1, Fig. 1 is a kind of structural representation of wear-resisting waterproof wallpaper proposed by the present invention.
Reference picture 1, a kind of wear-resisting waterproof wallpaper proposed by the present invention, including substrate layer 1, waterproof layer 2 and wearing layer 3, base The periphery of material layer 1 is coated with waterproof layer 2, and the waterproof layer 2 is coated with wearing layer 3 away from the periphery of substrate layer 1, wherein：
Substrate layer 1 is wood pulp paper；
The raw material of waterproof layer 2 includes by weight：48 parts of perfluoroalkyl acrylate, 22 parts of fluorinated acrylate emulsion, 8 parts of watersoluble modified hydroxyl acrylic aqueous dispersion, 10 parts of imino group melamine resin high, N, 2 parts of N- dimethylethanolamines, 4 parts of isopropanol, 2 parts of propandiol butyl ether, 4.5 parts of polyamide wax, 3 parts of aqueous aluminum powder, 3 parts of acetylbutyrylcellulose, metering system 4 parts of sour methyl esters, 7 parts of butyl acrylate, 2 parts of dimethylaminoethyl acrylate methyl base aminoethyl, 4 parts of hydroxy-ethyl acrylate, N, N- diformazans Base-N ' -3.5 parts of (2- Trifluoromethyl-1s-pentafluoroethyl group), 4 parts of OTAC, part, nanometer two of potassium peroxydisulfate 3 3 parts of silica, 4 parts of anti-settling agent, 3.5 parts of wetting agent, 2 parts of levelling agent, 5 parts of anti-flash rusting agent, polyoxyethylene polyoxy propyl alcohol amidogen ether 4.5 Part, 3 parts of thickener, 3 parts of Antifog bactericide, 2.5 parts of antimildew disinfectant, 9 parts of deionized water；
The raw material of wearing layer 3 includes by weight：29 parts of polymethacrylates, 6 parts of hydroxy acryl acid resin, isocyanide 5 parts of acid esters curing agent, 3.5 parts of organic siliconresin, 4.2 parts of epoxy resin E-13,3.8 parts of aluminium powder, 4 parts of nano titanium oxide, pottery 6 parts of porcelain powder, 4.2 parts of modified additive, 2.2 parts of butyl glycol ether, 3.5 parts of HMMM, dimethylethanolamine 2.8 parts, 2.8 parts of isopropanol, 4.2 parts of calgon, 2.2 parts of butyl acetate, 3.8 parts of silane coupler KH-560, microlite 4.2 parts of wax, 3.2 parts of levelling agent BYK-331,2.2 parts of wetting agent, 4.8 parts of dimethyl silicone polymer, 2.2 parts of dimethylbenzene, go from 15.5 parts of sub- water.
In the raw material of wearing layer 3, modified additive is prepared by following technique：By weight by 8 parts of silane coupler KH- 560 and distilled water it is well mixed, be then placed in heating 32min in water-bath, be subsequently added into 3 parts of carbon blacks, 10 parts of tapioca starch, 2 parts of illiteracies De- soil, 3.5 parts of kaolin, 5 parts of shitosans, 4.5 parts of nanometer silicon carbides, 2 parts of nano silicons, 4.5 parts of Nano diamonds and 5 Part attapulgite, ultrasonic disperse 18min then adjusts pH to 2.8, is then placed in heating 32min in water-bath, then carries out solid-liquid Separate, by the solid after separation with water washing is distilled 2 times, being subsequently adding n-butanol carries out distillation dehydration, then by after dehydration Powder dries 1.5h in being put into 115 DEG C of baking ovens, is cooled to room temperature and obtains modified additive.
A kind of preparation method of wear-resisting waterproof wallpaper of the invention, comprises the following steps：
S1, the figuratum printing layer of tool is formed on substrate layer by typography in base material layer surface, wallpaper half is obtained Finished product；
S2, the front of wallpaper semi-finished product by cylinder overprinting process print waterproof layer；
S3, the feedstock composition of wearing layer is printed on the layer of waterproof layer using cylinder overprinting process, forms wearing layer, It is placed in after being completed for printing in baking oven and is dried, dry temperature is 75 DEG C, and the dry time is 5.5h, is cooled to room temperature and obtains wear-resisting Waterproof wallpaper, wherein, cylinder overprinting process parameter is specially：Print speed printing speed is 8m/min；Oven temperature is for first with 115 DEG C of bakings It is dry, then form adhesion effect with 165 DEG C of film forming；Hexagonal loop is formed with cylinder, the percent opening of hexagonal loop is 44%；Finished product The thickness of net of cylinder is 0.15mm.
Embodiment 5
As shown in figure 1, Fig. 1 is a kind of structural representation of wear-resisting waterproof wallpaper proposed by the present invention.
Reference picture 1, a kind of wear-resisting waterproof wallpaper proposed by the present invention, including substrate layer 1, waterproof layer 2 and wearing layer 3, base The periphery of material layer 1 is coated with waterproof layer 2, and the waterproof layer 2 is coated with wearing layer 3 away from the periphery of substrate layer 1, wherein：
Substrate layer 1 is wood pulp paper；
The raw material of waterproof layer 2 includes by weight：62 parts of perfluoroalkyl acrylate, 18 parts of fluorinated acrylate emulsion, 12 parts of watersoluble modified hydroxyl acrylic aqueous dispersion, 8 parts of imino group melamine resin high, N, 5 parts of N- dimethylethanolamines, 3 parts of isopropanol, 3 parts of propandiol butyl ether, 3.5 parts of polyamide wax, 4 parts of aqueous aluminum powder, 2 parts of acetylbutyrylcellulose, metering system 5 parts of sour methyl esters, 3 parts of butyl acrylate, 6 parts of dimethylaminoethyl acrylate methyl base aminoethyl, 3 parts of hydroxy-ethyl acrylate, N, N- diformazans Base-N ' -4.5 parts of (2- Trifluoromethyl-1s-pentafluoroethyl group), 2 parts of OTAC, part, nanometer two of potassium peroxydisulfate 4 2 parts of silica, 5 parts of anti-settling agent, 2.5 parts of wetting agent, 3 parts of levelling agent, 3 parts of anti-flash rusting agent, polyoxyethylene polyoxy propyl alcohol amidogen ether 5.5 Part, 2 parts of thickener, 4 parts of Antifog bactericide, 1.5 parts of antimildew disinfectant, 15 parts of deionized water；
The raw material of wearing layer 3 includes by weight：31 parts of polymethacrylates, 4 parts of hydroxy acryl acid resin, isocyanide 7 parts of acid esters curing agent, 2.5 parts of organic siliconresin, 4.8 parts of epoxy resin E-13,3.2 parts of aluminium powder, 6 parts of nano titanium oxide, pottery 3 parts of porcelain powder, 4.8 parts of modified additive, 1.8 parts of butyl glycol ether, 4.5 parts of HMMM, dimethylethanolamine 2.2 parts, 3.2 parts of isopropanol, 3.8 parts of calgon, 2.8 parts of butyl acetate, 3.2 parts of silane coupler KH-560, microlite 4.8 parts of wax, 2.8 parts of levelling agent BYK-331,2.8 parts of wetting agent, 4.2 parts of dimethyl silicone polymer, 2.8 parts of dimethylbenzene, go from 14.5 parts of sub- water.
In the raw material of wearing layer 3, modified additive is prepared by following technique：By weight by 12 parts of silane couplers KH-560 and distilled water are well mixed, are then placed in heating 28min in water-bath, be subsequently added into 5 parts of carbon blacks, 8 parts of tapioca starch, 4 parts Montmorillonite, 2.5 parts of kaolin, 7 parts of shitosans, 3.5 parts of nanometer silicon carbides, 5 parts of nano silicons, 3.5 parts of Nano diamonds With 7 parts of attapulgites, ultrasonic disperse 12min, then adjust pH to 3.2, be then placed in heating 28min in water-bath, then carry out Separation of solid and liquid, by the solid after separation with water washing is distilled 4 times, being subsequently adding n-butanol carries out distillation dehydration, then will dehydration Powder afterwards dries 2.5h in being put into 105 DEG C of baking ovens, is cooled to room temperature and obtains modified additive.
A kind of preparation method of wear-resisting waterproof wallpaper of the invention, comprises the following steps：
S1, the figuratum printing layer of tool is formed on substrate layer by typography in base material layer surface, wallpaper half is obtained Finished product；
S2, the front of wallpaper semi-finished product by cylinder overprinting process print waterproof layer；
S3, the feedstock composition of wearing layer is printed on the layer of waterproof layer using cylinder overprinting process, forms wearing layer, It is placed in after being completed for printing in baking oven and is dried, dry temperature is 85 DEG C, and the dry time is 4.5h, is cooled to room temperature and obtains wear-resisting Waterproof wallpaper, wherein, cylinder overprinting process parameter is specially：Print speed printing speed is 12m/min；Oven temperature is for first with 105 DEG C of bakings It is dry, then form adhesion effect with 175 DEG C of film forming；Hexagonal loop is formed with cylinder, the percent opening of hexagonal loop is 31%；Finished product The thickness of net of cylinder is 0.25mm.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto, Any one skilled in the art the invention discloses technical scope in, technology according to the present invention scheme and its Inventive concept is subject to equivalent or change, should all be included within the scope of the present invention.

Claims (8)

1. a kind of wear-resisting waterproof wallpaper, including substrate layer (1), waterproof layer (2) and wearing layer (3), the periphery coating of substrate layer (1) There is waterproof layer (2), the waterproof layer (2) is coated with wearing layer (3) away from the periphery of substrate layer (1), it is characterised in that wherein：
Substrate layer (1) is wood pulp paper, any one in non-woven paper, cloth；
The raw material of waterproof layer (2) includes by weight：Perfluoroalkyl acrylate 45-65 parts, fluorinated acrylate emulsion 15-25 Part, watersoluble modified hydroxyl acrylic aqueous dispersion 5-15 parts, 6-12 parts of imino group melamine resin high, N, N- dimethyl second Hydramine 1-6 parts, isopropanol 2-5 parts, propandiol butyl ether 1-4 parts, polyamide wax 3-5 parts, aqueous aluminum powder 2-5 parts, acetate butyrate fibre Dimension 1-4 parts of element, methyl methacrylate 3-6 parts, butyl acrylate 2-8 parts, 1-7 parts of dimethylaminoethyl acrylate methyl base aminoethyl, Hydroxy-ethyl acrylate 2-5 parts, N, N- dimethyl-N '-(2- Trifluoromethyl-1s-pentafluoroethyl group) 3-5 parts, octadecyl trimethyl chlorine Change 1-5 parts of ammonium, potassium peroxydisulfate 2-5 parts, nano silicon 1-4 parts, anti-settling agent 3-6 parts, wetting agent 2-4 parts, levelling agent 1-4 Part, 2-6 parts of anti-flash rusting agent, 4-6 parts of polyoxyethylene polyoxy propyl alcohol amidogen ether, thickener 1-4 parts, Antifog bactericide 2-5 parts, mould proof kill Microbial inoculum 1-3 parts, deionized water 8-16 parts；
The raw material of wearing layer (3) includes by weight：Polymethacrylates 25-35 parts, hydroxy acryl acid resin 2-8 parts, Isocyanate curing agent 3-9 parts, organic siliconresin 1-5 parts, 3-6 parts of epoxy resin E-13, aluminium powder 2-5 parts, nano titanium oxide 2-8 parts, ceramic powder 1-8 parts, modified additive 3-6 parts, butyl glycol ether 1-3 parts, HMMM 2-6 parts, two Methylethanolamine 1-4 parts, isopropanol 2-4 parts, calgon 3-5 parts, butyl acetate 1-4 parts, silane coupler KH-560 2- 5 parts, microcrystalline wax 3-6 parts, 2-4 parts of levelling agent BYK-331, wetting agent 1-4 parts, dimethyl silicone polymer 3-6 parts, dimethylbenzene 1-4 parts, deionized water 12-18 parts.
2. wear-resisting waterproof wallpaper according to claim 1, it is characterised in that in the raw material of wearing layer (3), modified additive Raw material includes by weight：5-15 parts of silane coupler KH-560, carbon black 2-6 parts, tapioca starch 6-12 parts, montmorillonite 1-5 parts, Kaolin 2-4 parts, shitosan 4-8 parts, nanometer silicon carbide 3-5 parts, nano silicon 1-6 parts, Nano diamond 3-5 parts, it is recessed Convex 4-8 parts of rod soil.
3. wear-resisting waterproof wallpaper according to claim 1 and 2, it is characterised in that in the raw material of wearing layer (3), it is modified to help Agent is prepared by following technique：Silane coupler KH-560 and distilled water are well mixed, are then placed in heating 25- in water-bath 35min, is subsequently added into carbon black, tapioca starch, montmorillonite, kaolin, shitosan, nanometer silicon carbide, nano silicon, nm of gold Hard rock and attapulgite, ultrasonic disperse 10-20min then adjust pH to 2.5-3.5, are then placed in heating 25- in water-bath 35min, then carries out separation of solid and liquid, by the solid after separation with water washing is distilled 2-4 times, is subsequently adding n-butanol and is distilled , then be put into the powder after dehydration in 100-120 DEG C of baking oven and dry 1-3h by dehydration, is cooled to room temperature and obtains modified additive.
4. the wear-resisting waterproof wallpaper according to claim any one of 1-3, it is characterised in that the raw material of wearing layer (3) is by weight Amount part includes：Polymethacrylates 28-32 parts, hydroxy acryl acid resin 3-7 parts, isocyanate curing agent 4-8 parts, it is organic Silicones 2-4 parts, 4-5 parts of epoxy resin E-13, aluminium powder 3-4 parts, nano titanium oxide 3-7 parts, ceramic powder 2-7 parts, modified help Agent 4-5 parts, butyl glycol ether 1.5-2.5 parts, HMMM 3-5 parts, dimethylethanolamine 2-3 parts, isopropyl Alcohol 2.5-3.5 parts, calgon 3.5-4.5 parts, butyl acetate 2-3 parts, 3-4 parts of silane coupler KH-560, microcrystalline wax 4-5 parts, 2.5-3.5 parts of levelling agent BYK-331, wetting agent 2-3 parts, dimethyl silicone polymer 4-5 parts, dimethylbenzene 2-3 parts, go Ionized water 14-16 parts.
5. the wear-resisting waterproof wallpaper according to claim any one of 1-4, it is characterised in that the raw material of wearing layer (3) is by weight Amount part includes：30 parts of polymethacrylates, 5 parts of hydroxy acryl acid resin, 6 parts of isocyanate curing agent, organic siliconresin 3 Part, 4.5 parts of epoxy resin E-13,3.5 parts of aluminium powder, 5 parts of nano titanium oxide, 4.5 parts of ceramic powder, 4.5 parts of modified additive, second 2 parts of glycol butyl ether, 4 parts of HMMM, 2.5 parts of dimethylethanolamine, 3 parts of isopropanol, calgon 4 Part, 2.5 parts of butyl acetate, 3.5 parts of silane coupler KH-560,4.5 parts of microcrystalline wax, 3 parts of levelling agent BYK-331, wetting 2.5 parts of agent, 4.5 parts of dimethyl silicone polymer, 2.5 parts of dimethylbenzene, 15 parts of deionized water.
6. the preparation method of a kind of wear-resisting waterproof wallpaper according to claim any one of 1-5, it is characterised in that including such as Lower step：
S1, the figuratum printing layer of tool is formed on substrate layer by typography in base material layer surface, wallpaper semi-finished product are obtained；
S2, the front of wallpaper semi-finished product by cylinder overprinting process print waterproof layer；
S3, the feedstock composition of wearing layer is printed on the layer of waterproof layer using cylinder overprinting process, forms wearing layer, printing After the completion of be placed in baking oven dry, be cooled to room temperature and obtain wear-resisting waterproof wallpaper.
7. the preparation method of wear-resisting waterproof wallpaper according to claim 6, it is characterised in that in S3, cylinder overprinting process Parameter is specially：Print speed printing speed is 5-15m/min；Oven temperature for first with 100-120 DEG C of drying, then with 160-180 DEG C of film forming Form adhesion effect；Hexagonal loop is formed with cylinder, the percent opening of hexagonal loop is 30-45%；The thickness of net of finished product cylinder It is 0.1-0.3mm.
8. the preparation method of the wear-resisting waterproof wallpaper according to claim 6 or 7, it is characterised in that in S3, dry temperature It it is 70-90 DEG C, the dry time is 4-6h.
CN201611200003.5A 2016-12-22 2016-12-22 A kind of wear-resisting waterproof wallpaper and preparation method thereof Withdrawn CN106833059A (en)

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CN107987712A (en) * 2017-12-21 2018-05-04 珠海智星荟科技服务有限公司 There is aqueous epoxy floor coating of anti-corrosive antibacterial and preparation method thereof
CN108193565A (en) * 2018-02-05 2018-06-22 合肥华盖光伏科技有限公司 A kind of preparation method of novel and multifunctional wallpaper
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CN109610184A (en) * 2018-12-15 2019-04-12 深圳市仁义和兴塑胶五金制品有限公司 A kind of organic silicon cloth of waterproof antiwear and processing technology
CN110872790A (en) * 2019-11-12 2020-03-10 浙江上峰包装新材料有限公司 Waterproof corrugated board and production process
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CN116144258A (en) * 2023-04-19 2023-05-23 昱垠科技有限公司 Super wear-resistant modified polyurethane floor coating and preparation process thereof

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CN107386007B (en) * 2017-07-07 2019-07-19 广东玉兰集团股份有限公司 A kind of anti-pollution wallpaper and preparation method thereof
CN107386007A (en) * 2017-07-07 2017-11-24 广东玉兰集团股份有限公司 A kind of anti-soil wallpaper and preparation method thereof
CN107558292A (en) * 2017-07-28 2018-01-09 安徽安大华泰新材料有限公司 A kind of water-proof stain-resistant modified adhesive for papermaking processing and preparation method thereof
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CN107987712A (en) * 2017-12-21 2018-05-04 珠海智星荟科技服务有限公司 There is aqueous epoxy floor coating of anti-corrosive antibacterial and preparation method thereof
CN107987712B (en) * 2017-12-21 2020-06-02 珠海智星荟科技服务有限公司 Water-based epoxy floor coating with anticorrosion and antibacterial functions and preparation method thereof
CN108316020A (en) * 2018-01-24 2018-07-24 合肥市大卓电力有限责任公司 A kind of Environment-friendlywallpaper wallpaper and preparation method thereof of purification air
CN108193565A (en) * 2018-02-05 2018-06-22 合肥华盖光伏科技有限公司 A kind of preparation method of novel and multifunctional wallpaper
CN108625221A (en) * 2018-03-30 2018-10-09 句容市茂源织造厂 A kind of preparation method of hydrophobic wrapping paper
CN109267370A (en) * 2018-10-09 2019-01-25 南京哈昵特户外用品有限公司 A kind of Wear-resistant waterproof fabric manufacture craft
CN109610184A (en) * 2018-12-15 2019-04-12 深圳市仁义和兴塑胶五金制品有限公司 A kind of organic silicon cloth of waterproof antiwear and processing technology
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