CN105949918A - Oil-resistant and waterproof metal flicker paint for photo frame and preparing method of oil-resistant and waterproof metal flicker paint - Google Patents
Oil-resistant and waterproof metal flicker paint for photo frame and preparing method of oil-resistant and waterproof metal flicker paint Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
- C09D133/16—Homopolymers or copolymers of esters containing halogen atoms
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/22—Esters containing halogen
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
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- C09D7/65—Additives macromolecular
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08L2205/00—Polymer mixtures characterised by other features
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Abstract
The invention discloses an oil-resistant and waterproof metal flicker paint for a photo frame. The oil-resistant and waterproof metal flicker paint is prepared from perfluoroalkylated acrylate, fluorine-containing acrylate emulsion, a waterborne modified hydroxyl acrylic dispersoid, high-imino melamine-formaldehyde resin, N,N-dimethylethanolamine, isopropanol, propanediol butyl ether, polyamide wax, waterborne aluminum powder, cellulose acetate butyrate, methyl methacrylate, butyl acrylate, methyl acrylic dimethyl amido ethyl ester, hydroxyethyl acrylate, N,N-dimethyl-N'-(2-trifuloromethyl-1-pentafluorure ethyl), octadecyl trimethyl ammonium chloride, potassium persulfate, nano-silica, an anti-settling agent, a wetting agent, a flatting agent, an anti-flush-rust agent, a defoaming agent, a thickening agent, an anti-fog sterilizing agent, a mould-proof sterilizing agent and deionized water. The invention further provides a preparing method of the oil-resistant and waterproof metal flicker paint for a photo frame. The metal flicker paint has excellent oil resistance and waterproof performance.
Description
Technical field
The present invention relates to flash coating material, particularly relate to a kind of photo frame oil resistant water-proof metal flash coating material and system thereof
Preparation Method.
Background technology
At present, present in metal flash paint, flakey aluminium powder forms the arranged in parallel of multilamellar, energy in film
Enough ultraviolet, infrared ray and visible ray are effectively reflected, delay its aging damage to film, also can
Enough infiltrations effectively stoping water, gas and ion, because of decoration and the antiseptic effect of its this uniqueness, at photo frame table
In topcoating film, application is more and more.
When the oil resistant of metallized coating the most of the prior art and water resistance cannot meet actually used
Demand, the metallized coating therefore needing a kind of excellent oil resistant of design and water resistance badly is actually used to meet
Time demand.
Summary of the invention
For solving technical problem present in background technology, the present invention proposes a kind of photo frame oil resistant water-proof metal
Flash coating material and preparation method thereof, has the oil resistant water resistance of excellence.
A kind of photo frame oil resistant water-proof metal flash coating material that the present invention proposes, its raw material includes by weight:
Perfluoroalkyl acrylate 45-65 part, fluorinated acrylate emulsion 15-25 part, watersoluble modified hydroxy
Acid dispersion 5-15 part, high imino group melamine resin 6-12 part, N, N-dimethylethanolamine 1-6
Part, isopropanol 2-5 part, propandiol butyl ether 1-4 part, polyamide wax 3-5 part, aqueous aluminum powder 2-5 part,
Acetylbutyrylcellulose 1-4 part, methyl methacrylate 3-6 part, butyl acrylate 2-8 part, methyl-prop
Olefin(e) acid dimethyl amido ethyl ester 1-7 part, 2-(Acryloyloxy)ethanol 2-5 part, N, N-dimethyl-N '-(2-trifluoro
Methyl isophthalic acid-pentafluoroethyl group) 3-5 part, octadecyl trimethyl ammonium chloride 1-5 part, potassium peroxydisulfate 2-5 part,
Nano silicon 1-4 part, anti-settling agent 3-6 part, wetting agent 2-4 part, levelling agent 1-4 part, anti-sudden strain of a muscle rust
Agent 2-6 part, defoamer 4-6 part, thickening agent 1-4 part, Antifog bactericide 2-5 part, antimildew disinfectant 1-3
Part, deionized water 8-16 part.
Preferably, perfluoroalkyl acrylate, fluorinated acrylate emulsion, watersoluble modified hydroxy acrylic acid divide
The weight ratio of a prose style free from parallelism and high imino group melamine resin is 48-62:18-22:8-12:7-11.
Preferably, perfluoroalkyl acrylate, methyl methacrylate, butyl acrylate, methacrylic acid
Dimethyl amido ethyl ester, 2-(Acryloyloxy)ethanol, N, N-dimethyl-N '-(2-Trifluoromethyl-1-pentafluoroethyl group),
The weight ratio of octadecyl trimethyl ammonium chloride and potassium peroxydisulfate is 48-62:4-5:3-7:2-6:3-4:
3.5-4.5:2-4:3-4.
Preferably, perfluoroalkyl acrylate, nano silicon, anti-settling agent, wetting agent, levelling agent,
The weight ratio of anti-sudden strain of a muscle rust agent, defoamer, thickening agent, Antifog bactericide, antimildew disinfectant and deionized water is
48-62:2-3:4-5:2.5-3.5:2-3:3-5:4.5-5.5:2-3:3-4:1.5-2.5:9-15.
Preferably, its raw material includes by weight: perfluoroalkyl acrylate 48-62 part, fluorine-containing
Ester emulsion 18-22 part, watersoluble modified hydroxyl acrylic aqueous dispersion 8-12 part, high imino group melamino-formaldehyde
Resin 8-10 part, N, N-dimethylethanolamine 2-5 part, isopropanol 3-4 part, propandiol butyl ether 2-3 part,
Polyamide wax 3.5-4.5 part, aqueous aluminum powder 3-4 part, acetylbutyrylcellulose 2-3 part, methacrylic acid
Methyl ester 4-5 part, butyl acrylate 3-7 part, dimethylaminoethyl acrylate methyl base aminoethyl 2-6 part, acrylic acid
Hydroxyl ethyl ester 3-4 part, N, N-dimethyl-N '-(2-Trifluoromethyl-1-pentafluoroethyl group) 3-5 part, octadecyl
Trimethyl ammonium chloride 2-4 part, potassium peroxydisulfate 3-4 part, nano silicon 2-3 part, anti-settling agent 4-5 part,
Wetting agent 2.5-3.5 part, levelling agent 2-3 part, anti-sudden strain of a muscle rust agent 3-5 part, defoamer 4.5-5.5 part, increasing
Thick dose of 2-3 part, Antifog bactericide 3-4 part, antimildew disinfectant 1.5-2.5 part, deionized water 9-15 part.
Preferably, its raw material includes by weight: perfluoroalkyl acrylate 55 parts, fluorinated acrylate breast
Liquid 20 parts, watersoluble modified hydroxyl acrylic aqueous dispersion 10 parts, high imino group melamine resin 9 parts,
N, N-dimethylethanolamine 3.5 parts, isopropanol 3.5 parts, propandiol butyl ether 2.5 parts, polyamide wax 4 parts,
Aqueous aluminum powder 3.5 parts, acetylbutyrylcellulose 2.5 parts, methyl methacrylate 4.5 parts, acrylic acid fourth
Ester 5 parts, dimethylaminoethyl acrylate methyl base aminoethyl 4 parts, 2-(Acryloyloxy)ethanol 3.5 parts, N, N-dimethyl
-N '-(2-Trifluoromethyl-1-pentafluoroethyl group) 4 parts, octadecyl trimethyl ammonium chloride 3 parts, potassium peroxydisulfate
3.5 parts, nano silicon 2.5 parts, anti-settling agent 4.5 parts, wetting agent 3 parts, levelling agent 2.5 parts, anti-
Dodge rust agent 4 parts, defoamer 5 parts, thickening agent 2.5 parts, Antifog bactericide 3.5 parts, antimildew disinfectant 2
Part, deionized water 12 parts.
The preparation method of a kind of photo frame oil resistant water-proof metal flash coating material of the present invention, comprises the steps:
S1, by isopropanol, propandiol butyl ether, polyamide wax and acetylbutyrylcellulose mix homogeneously, in
1500-2500r/min disperses 25-45min, is subsequently adding aqueous aluminum powder mix homogeneously, in 300-1000r/min,
Dispersion 15-25min, then adds N, N-dimethylethanolamine regulation pH to 7.5-8.5, quiet after stirring
Put 1-3h, obtain material a；
S2, by perfluoroalkyl acrylate, N, N-dimethyl-N '-(2-Trifluoromethyl-1-pentafluoroethyl group),
Octadecyl trimethyl ammonium chloride and deionized water mix homogeneously, stir 1-3h in 600-800r/min, then
Add methyl methacrylate, butyl acrylate, dimethylaminoethyl acrylate methyl base aminoethyl, acrylic acid hydroxyl second
Ester and potassium peroxydisulfate mix homogeneously, be warming up to 80-90 DEG C, is incubated 1-3h, is subsequently added into fluorinated acrylate
Emulsion, watersoluble modified hydroxyl acrylic aqueous dispersion, high imino group melamine resin, nanometer titanium dioxide
Silicon, anti-settling agent, wetting agent, levelling agent, anti-sudden strain of a muscle rust agent, defoamer, thickening agent, Antifog bactericide and anti-
Mould antibacterial mix homogeneously, stirs 45-55min in 1500-2500r/min, is cooled to room temperature and obtains photo frame use
Oil resistant water-proof metal flash coating material.
A kind of photo frame oil resistant water-proof metal flash coating material of the present invention, its raw material includes perfluoroalkyl acrylic
Ester, fluorinated acrylate emulsion, watersoluble modified hydroxyl acrylic aqueous dispersion, high imino group melamino-formaldehyde
Resin, N, N-dimethylethanolamine, isopropanol, propandiol butyl ether, polyamide wax, aqueous aluminum powder, acetic acid
Cellulose butyrate, methyl methacrylate, butyl acrylate, dimethylaminoethyl acrylate methyl base aminoethyl, third
Olefin(e) acid hydroxyl ethyl ester, N, N-dimethyl-N '-(2-Trifluoromethyl-1-pentafluoroethyl group), octadecyl trimethyl chlorine
Change ammonium, potassium peroxydisulfate, nano silicon, anti-settling agent, wetting agent, levelling agent, anti-sudden strain of a muscle rust agent, froth breaking
Agent, thickening agent, Antifog bactericide, antimildew disinfectant and deionized water.Wherein with perfluoroalkyl acrylate,
Fluorinated acrylate emulsion, watersoluble modified hydroxyl acrylic aqueous dispersion and high imino group melamine resin
For base material, with aqueous aluminum powder as effect pigment, and add polyamide wax and acetylbutyrylcellulose as orientation
Arrangement agent, is effectively improved；With methyl methacrylate, butyl acrylate, dimethylaminoethyl acrylate methyl base amido
Ethyl ester, 2-(Acryloyloxy)ethanol, N, N-dimethyl-N '-(2-Trifluoromethyl-1-pentafluoroethyl group), octadecyl
Trimethyl ammonium chloride, potassium peroxydisulfate and perfluoroalkyl acrylate coordinate, with perfluoroalkyl acrylate for containing
Fluorine monomer, dimethylaminoethyl acrylate methyl base aminoethyl is cationic monomer, methyl methacrylate and acrylic acid
Butyl ester is primary raw material, with potassium peroxydisulfate as initiator, with 2-(Acryloyloxy)ethanol as cross-linking agent, at N, N-bis-
Methyl-N '-(2-Trifluoromethyl-1-pentafluoroethyl group) and the Composite Milk of octadecyl trimethyl ammonium chloride are turned into
Under with, obtain the anionic perfluoroalkyl acrylate emulsion with excellent oil resistant water resistance, and with
Fluorinated acrylate emulsion, watersoluble modified hydroxyl acrylic aqueous dispersion and high imino group melamine resin
Coordinate so that the flash coating material of the present invention has the oil resistant water resistance of excellence；Add N, N-dimethyl ethanol
Amine, isopropanol, propandiol butyl ether, nano silicon, anti-settling agent, wetting agent, levelling agent, anti-sudden strain of a muscle rust
Agent, defoamer, thickening agent, Antifog bactericide, antimildew disinfectant and deionized water are as auxiliary agent, by stirring
The metallized coating obtained after mixing dispersion has oil resistant and the water resistance of excellence.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail, it should be appreciated that embodiment is served only for
The bright present invention rather than be used for limiting the invention, any made on the basis of the present invention amendment,
Equivalents etc. are the most within the scope of the present invention.
In detailed description of the invention, the weight portion of perfluoroalkyl acrylate can be 45 parts, 46 parts, 47 parts,
48 parts, 49 parts, 50 parts, 51 parts, 52 parts, 53 parts, 54 parts, 55 parts, 56 parts, 57 parts, 58 parts,
59 parts, 60 parts, 61 parts, 62 parts, 63 parts, 64 parts, 65 parts；The weight portion of fluorinated acrylate emulsion
Can be 15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts, 21 parts, 22 parts, 23 parts, 24 parts,
25 parts；The weight portion of watersoluble modified hydroxyl acrylic aqueous dispersion can be 5 parts, 6 parts, 7 parts, 8 parts, 9
Part, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts；High imino group melamine resin
Weight portion can be 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts；N, N-dimethyl ethanol
The weight portion of amine can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5
Part, 5.5 parts, 6 parts；The weight portion of isopropanol can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts,
4.5 parts, 5 parts；The weight portion of propandiol butyl ether can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts,
3.5 parts, 4 parts；The weight portion of polyamide wax can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；Water
The weight portion of property aluminium powder can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；Acetic acid
The weight portion of cellulose butyrate can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；
The weight portion of methyl methacrylate can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6
Part；The weight portion of butyl acrylate can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts；First
The weight portion of base DMAM can be 1 part, 2 parts, 3 parts, 4 parts, 5 parts, 6 parts,
7 parts；The weight portion of 2-(Acryloyloxy)ethanol can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts,
5 parts；The weight portion of N, N-dimethyl-N '-(2-Trifluoromethyl-1-pentafluoroethyl group) can be 3 parts, 3.5
Part, 4 parts, 4.5 parts, 5 parts；The weight portion of octadecyl trimethyl ammonium chloride can be 1 part, 1.5 parts,
2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The weight portion of potassium peroxydisulfate can be 2
Part, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The weight portion of nano silicon can be
1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；The weight portion of anti-settling agent can be 3 parts,
3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The weight portion of wetting agent can be 2 parts, 2.5
Part, 3 parts, 3.5 parts, 4 parts；The weight portion of levelling agent can be 1 part, 1.5 parts, 2 parts, 2.5 parts,
3 parts, 3.5 parts, 4 parts；The anti-weight portion dodging rust agent can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts；
The weight portion of defoamer can be 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The weight portion of thickening agent can
Think 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；The weight portion of Antifog bactericide can
Think 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The weight portion of antimildew disinfectant can
Think 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts；The weight portion of deionized water can be 8 parts, 9 parts,
10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts, 16 parts.
Embodiment 1
A kind of photo frame oil resistant water-proof metal flash coating material that the present invention proposes, its raw material includes by weight:
Perfluoroalkyl acrylate 55 parts, fluorinated acrylate emulsion 20 parts, watersoluble modified hydroxy acrylic acid disperse
Body 10 parts, high imino group melamine resin 9 parts, N, N-dimethylethanolamine 3.5 parts, isopropanol
3.5 parts, propandiol butyl ether 2.5 parts, polyamide wax 4 parts, aqueous aluminum powder 3.5 parts, acetylbutyrylcellulose
2.5 part, methyl methacrylate 4.5 parts, butyl acrylate 5 parts, dimethylaminoethyl acrylate methyl base aminoethyl
4 parts, 2-(Acryloyloxy)ethanol 3.5 parts, N, N-dimethyl-N '-(2-Trifluoromethyl-1-pentafluoroethyl group) 4 parts,
Octadecyl trimethyl ammonium chloride 3 parts, potassium peroxydisulfate 3.5 parts, nano silicon 2.5 parts, anti-settling agent
4.5 parts, wetting agent 3 parts, levelling agent 2.5 parts, anti-dodge rust agent 4 parts, defoamer 5 parts, thickening agent 2.5
Part, Antifog bactericide 3.5 parts, antimildew disinfectant 2 parts, deionized water 12 parts.
The preparation method of a kind of photo frame oil resistant water-proof metal flash coating material of the present invention, comprises the steps:
S1, by isopropanol, propandiol butyl ether, polyamide wax and acetylbutyrylcellulose mix homogeneously, in
2000r/min disperses 35min, is subsequently adding aqueous aluminum powder mix homogeneously, in 650r/min, disperses 20min,
Then add N, N-dimethylethanolamine regulation pH to 8.0, stand 2h after stirring, obtain material a；
S2, by perfluoroalkyl acrylate, N, N-dimethyl-N '-(2-Trifluoromethyl-1-pentafluoroethyl group),
Octadecyl trimethyl ammonium chloride and deionized water mix homogeneously, stir 2h in 700r/min, be subsequently adding first
Base acrylic acid methyl ester., butyl acrylate, dimethylaminoethyl acrylate methyl base aminoethyl, 2-(Acryloyloxy)ethanol and mistake
Potassium sulfate mix homogeneously, is warming up to 85 DEG C, is incubated 2h, is subsequently added into fluorinated acrylate emulsion, aqueous changes
Property hydroxyl acrylic aqueous dispersion, high imino group melamine resin, nano silicon, anti-settling agent,
Wetting agent, levelling agent, anti-sudden strain of a muscle rust agent, defoamer, thickening agent, Antifog bactericide and antimildew disinfectant mixing
Uniformly, stir 50min in 2000r/min, be cooled to room temperature and obtain photo frame oil resistant water-proof metal flash coating material.
Embodiment 2
A kind of photo frame oil resistant water-proof metal flash coating material that the present invention proposes, its raw material includes by weight:
Perfluoroalkyl acrylate 45 parts, fluorinated acrylate emulsion 25 parts, watersoluble modified hydroxy acrylic acid disperse
Body 5 parts, high imino group melamine resin 12 parts, N, N-dimethylethanolamine 1 part, isopropanol 5
Part, propandiol butyl ether 1 part, polyamide wax 5 parts, aqueous aluminum powder 2 parts, acetylbutyrylcellulose 4 parts,
Methyl methacrylate 3 parts, butyl acrylate 8 parts, dimethylaminoethyl acrylate methyl base aminoethyl 1 part, third
Olefin(e) acid hydroxyl ethyl ester 5 parts, N, N-dimethyl-N '-(2-Trifluoromethyl-1-pentafluoroethyl group) 3 parts, octadecyl
Trimethyl ammonium chloride 5 parts, potassium peroxydisulfate 2 parts, nano silicon 4 parts, anti-settling agent 3 parts, wetting agent 4
Part, levelling agent 1 part, anti-dodge rust agent 6 parts, defoamer 4 parts, thickening agent 4 parts, Antifog bactericide 2 parts,
Antimildew disinfectant 3 parts, deionized water 8 parts.
The preparation method of a kind of photo frame oil resistant water-proof metal flash coating material of the present invention, comprises the steps:
S1, by isopropanol, propandiol butyl ether, polyamide wax and acetylbutyrylcellulose mix homogeneously, in
1500r/min disperses 45min, is subsequently adding aqueous aluminum powder mix homogeneously, in 300r/min, disperses 25min,
Then add N, N-dimethylethanolamine regulation pH to 7.5, stand 3h after stirring, obtain material a；
S2, by perfluoroalkyl acrylate, N, N-dimethyl-N '-(2-Trifluoromethyl-1-pentafluoroethyl group),
Octadecyl trimethyl ammonium chloride and deionized water mix homogeneously, stir 3h in 600r/min, be subsequently adding first
Base acrylic acid methyl ester., butyl acrylate, dimethylaminoethyl acrylate methyl base aminoethyl, 2-(Acryloyloxy)ethanol and mistake
Potassium sulfate mix homogeneously, is warming up to 80 DEG C, is incubated 3h, is subsequently added into fluorinated acrylate emulsion, aqueous changes
Property hydroxyl acrylic aqueous dispersion, high imino group melamine resin, nano silicon, anti-settling agent,
Wetting agent, levelling agent, anti-sudden strain of a muscle rust agent, defoamer, thickening agent, Antifog bactericide and antimildew disinfectant mixing
Uniformly, stir 55min in 1500r/min, be cooled to room temperature and obtain photo frame oil resistant water-proof metal flash coating material.
Embodiment 3
A kind of photo frame oil resistant water-proof metal flash coating material that the present invention proposes, its raw material includes by weight:
Perfluoroalkyl acrylate 65 parts, fluorinated acrylate emulsion 15 parts, watersoluble modified hydroxy acrylic acid disperse
Body 15 parts, high imino group melamine resin 6 parts, N, N-dimethylethanolamine 6 parts, isopropanol 2
Part, propandiol butyl ether 4 parts, polyamide wax 3 parts, aqueous aluminum powder 5 parts, acetylbutyrylcellulose 1 part,
Methyl methacrylate 6 parts, butyl acrylate 2 parts, dimethylaminoethyl acrylate methyl base aminoethyl 7 parts, third
Olefin(e) acid hydroxyl ethyl ester 2 parts, N, N-dimethyl-N '-(2-Trifluoromethyl-1-pentafluoroethyl group) 5 parts, octadecyl
Trimethyl ammonium chloride 1 part, potassium peroxydisulfate 5 parts, nano silicon 1 part, anti-settling agent 6 parts, wetting agent 2
Part, levelling agent 4 parts, anti-dodge rust agent 2 parts, defoamer 6 parts, thickening agent 1 part, Antifog bactericide 5 parts,
Antimildew disinfectant 1 part, deionized water 16 parts.
The preparation method of a kind of photo frame oil resistant water-proof metal flash coating material of the present invention, comprises the steps:
S1, by isopropanol, propandiol butyl ether, polyamide wax and acetylbutyrylcellulose mix homogeneously, in
2500r/min disperses 25min, is subsequently adding aqueous aluminum powder mix homogeneously, in 1000r/min, disperses 15min,
Then add N, N-dimethylethanolamine regulation pH to 8.5, stand 1h after stirring, obtain material a；
S2, by perfluoroalkyl acrylate, N, N-dimethyl-N '-(2-Trifluoromethyl-1-pentafluoroethyl group),
Octadecyl trimethyl ammonium chloride and deionized water mix homogeneously, stir 1h in 800r/min, be subsequently adding first
Base acrylic acid methyl ester., butyl acrylate, dimethylaminoethyl acrylate methyl base aminoethyl, 2-(Acryloyloxy)ethanol and mistake
Potassium sulfate mix homogeneously, is warming up to 90 DEG C, is incubated 1h, is subsequently added into fluorinated acrylate emulsion, aqueous changes
Property hydroxyl acrylic aqueous dispersion, high imino group melamine resin, nano silicon, anti-settling agent,
Wetting agent, levelling agent, anti-sudden strain of a muscle rust agent, defoamer, thickening agent, Antifog bactericide and antimildew disinfectant mixing
Uniformly, stir 45min in 2500r/min, be cooled to room temperature and obtain photo frame oil resistant water-proof metal flash coating material.
Embodiment 4
A kind of photo frame oil resistant water-proof metal flash coating material that the present invention proposes, its raw material includes by weight:
Perfluoroalkyl acrylate 48 parts, fluorinated acrylate emulsion 22 parts, watersoluble modified hydroxy acrylic acid disperse
Body 8 parts, high imino group melamine resin 10 parts, N, N-dimethylethanolamine 2 parts, isopropanol 4
Part, propandiol butyl ether 2 parts, polyamide wax 4.5 parts, aqueous aluminum powder 3 parts, acetylbutyrylcellulose 3 parts,
Methyl methacrylate 4 parts, butyl acrylate 7 parts, dimethylaminoethyl acrylate methyl base aminoethyl 2 parts, third
Olefin(e) acid hydroxyl ethyl ester 4 parts, N, N-dimethyl-N '-(2-Trifluoromethyl-1-pentafluoroethyl group) 3 parts, octadecyl
Trimethyl ammonium chloride 4 parts, potassium peroxydisulfate 3 parts, nano silicon 3 parts, anti-settling agent 4 parts, wetting agent
3.5 parts, levelling agent 2 parts, anti-dodge rust agent 5 parts, defoamer 4.5 parts, thickening agent 3 parts, Antifog bactericide
3 parts, antimildew disinfectant 2.5 parts, deionized water 9 parts.
The preparation method of a kind of photo frame oil resistant water-proof metal flash coating material of the present invention, comprises the steps:
S1, by isopropanol, propandiol butyl ether, polyamide wax and acetylbutyrylcellulose mix homogeneously, in
1800r/min disperses 42min, is subsequently adding aqueous aluminum powder mix homogeneously, in 400r/min, disperses 22min,
Then add N, N-dimethylethanolamine regulation pH to 7.8, stand 2.5h after stirring, obtain material a；
S2, by perfluoroalkyl acrylate, N, N-dimethyl-N '-(2-Trifluoromethyl-1-pentafluoroethyl group),
Octadecyl trimethyl ammonium chloride and deionized water mix homogeneously, stir 2.5h in 650r/min, be subsequently adding
Methyl methacrylate, butyl acrylate, dimethylaminoethyl acrylate methyl base aminoethyl, 2-(Acryloyloxy)ethanol and
Potassium peroxydisulfate mix homogeneously, is warming up to 82 DEG C, is incubated 2.5h, is subsequently added into fluorinated acrylate emulsion, water
Property modified hydroxyl acrylic acid dispersion, high imino group melamine resin, nano silicon, anti-settling
Agent, wetting agent, levelling agent, anti-sudden strain of a muscle rust agent, defoamer, thickening agent, Antifog bactericide and antimildew disinfectant
Mix homogeneously, stirs 52min in 1800r/min, is cooled to room temperature and obtains the flash of light of photo frame oil resistant water-proof metal
Coating.
Embodiment 5
A kind of photo frame oil resistant water-proof metal flash coating material that the present invention proposes, its raw material includes by weight:
Perfluoroalkyl acrylate 62 parts, fluorinated acrylate emulsion 18 parts, watersoluble modified hydroxy acrylic acid disperse
Body 12 parts, high imino group melamine resin 8 parts, N, N-dimethylethanolamine 5 parts, isopropanol 3
Part, propandiol butyl ether 3 parts, polyamide wax 3.5 parts, aqueous aluminum powder 4 parts, acetylbutyrylcellulose 2 parts,
Methyl methacrylate 5 parts, butyl acrylate 3 parts, dimethylaminoethyl acrylate methyl base aminoethyl 6 parts, third
Olefin(e) acid hydroxyl ethyl ester 3 parts, N, N-dimethyl-N '-(2-Trifluoromethyl-1-pentafluoroethyl group) 5 parts, octadecyl
Trimethyl ammonium chloride 2 parts, potassium peroxydisulfate 4 parts, nano silicon 2 parts, anti-settling agent 5 parts, wetting agent
2.5 parts, levelling agent 3 parts, anti-dodge rust agent 3 parts, defoamer 5.5 parts, thickening agent 2 parts, Antifog bactericide
4 parts, antimildew disinfectant 1.5 parts, deionized water 15 parts.
The preparation method of a kind of photo frame oil resistant water-proof metal flash coating material of the present invention, comprises the steps:
S1, by isopropanol, propandiol butyl ether, polyamide wax and acetylbutyrylcellulose mix homogeneously, in
2200r/min disperses 28min, is subsequently adding aqueous aluminum powder mix homogeneously, in 900r/min, disperses 18min,
Then add N, N-dimethylethanolamine regulation pH to 8.2, stand 1.5h after stirring, obtain material a；
S2, by perfluoroalkyl acrylate, N, N-dimethyl-N '-(2-Trifluoromethyl-1-pentafluoroethyl group),
Octadecyl trimethyl ammonium chloride and deionized water mix homogeneously, stir 1.5h in 750r/min, be subsequently adding
Methyl methacrylate, butyl acrylate, dimethylaminoethyl acrylate methyl base aminoethyl, 2-(Acryloyloxy)ethanol and
Potassium peroxydisulfate mix homogeneously, is warming up to 88 DEG C, is incubated 1.5h, is subsequently added into fluorinated acrylate emulsion, water
Property modified hydroxyl acrylic acid dispersion, high imino group melamine resin, nano silicon, anti-settling
Agent, wetting agent, levelling agent, anti-sudden strain of a muscle rust agent, defoamer, thickening agent, Antifog bactericide and antimildew disinfectant
Mix homogeneously, stirs 48min in 2200r/min, is cooled to room temperature and obtains the flash of light of photo frame oil resistant water-proof metal
Coating.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention not office
Being limited to this, any those familiar with the art is in the technical scope that the invention discloses, according to this
The technical scheme of invention and inventive concept thereof in addition equivalent or change, all should contain the protection in the present invention
Within the scope of.
Claims (7)
1. a photo frame oil resistant water-proof metal flash coating material, it is characterised in that its raw material includes by weight:
Perfluoroalkyl acrylate 45-65 part, fluorinated acrylate emulsion 15-25 part, watersoluble modified hydroxy
Acid dispersion 5-15 part, high imino group melamine resin 6-12 part, N, N-dimethylethanolamine 1-6
Part, isopropanol 2-5 part, propandiol butyl ether 1-4 part, polyamide wax 3-5 part, aqueous aluminum powder 2-5 part,
Acetylbutyrylcellulose 1-4 part, methyl methacrylate 3-6 part, butyl acrylate 2-8 part, methyl-prop
Olefin(e) acid dimethyl amido ethyl ester 1-7 part, 2-(Acryloyloxy)ethanol 2-5 part, N, N-dimethyl-N '-(2-trifluoro
Methyl isophthalic acid-pentafluoroethyl group) 3-5 part, octadecyl trimethyl ammonium chloride 1-5 part, potassium peroxydisulfate 2-5 part,
Nano silicon 1-4 part, anti-settling agent 3-6 part, wetting agent 2-4 part, levelling agent 1-4 part, anti-sudden strain of a muscle rust
Agent 2-6 part, defoamer 4-6 part, thickening agent 1-4 part, Antifog bactericide 2-5 part, antimildew disinfectant 1-3
Part, deionized water 8-16 part.
Photo frame oil resistant water-proof metal flash coating material the most according to claim 1, it is characterised in that complete
Fluoroalkyl, fluorinated acrylate emulsion, watersoluble modified hydroxyl acrylic aqueous dispersion and high imino group
The weight ratio of melamine resin is 48-62:18-22:8-12:7-11.
Photo frame oil resistant water-proof metal flash coating material the most according to claim 1 and 2, it is characterised in that
Perfluoroalkyl acrylate, methyl methacrylate, butyl acrylate, dimethylaminoethyl acrylate methyl base amido second
Ester, 2-(Acryloyloxy)ethanol, N, N-dimethyl-N '-(2-Trifluoromethyl-1-pentafluoroethyl group), octadecyl three
The weight ratio of ammonio methacrylate and potassium peroxydisulfate is 48-62:4-5:3-7:2-6:3-4:3.5-4.5:2-4:
3-4。
4. according to the oil resistant water-proof metal flash coating material of the photo frame described in any one of claim 1-3, its feature
It is, perfluoroalkyl acrylate, nano silicon, anti-settling agent, wetting agent, levelling agent, anti-sudden strain of a muscle rust
The weight ratio of agent, defoamer, thickening agent, Antifog bactericide, antimildew disinfectant and deionized water is 48-62:
2-3:4-5:2.5-3.5:2-3:3-5:4.5-5.5:2-3:3-4:1.5-2.5:9-15.
5. according to the oil resistant water-proof metal flash coating material of the photo frame described in any one of claim 1-4, its feature
Being, its raw material includes by weight: perfluoroalkyl acrylate 48-62 part, fluorinated acrylate emulsion
18-22 part, watersoluble modified hydroxyl acrylic aqueous dispersion 8-12 part, high imino group melamine resin 8-10
Part, N, N-dimethylethanolamine 2-5 part, isopropanol 3-4 part, propandiol butyl ether 2-3 part, polyamide wax
3.5-4.5 part, aqueous aluminum powder 3-4 part, acetylbutyrylcellulose 2-3 part, methyl methacrylate 4-5
Part, butyl acrylate 3-7 part, dimethylaminoethyl acrylate methyl base aminoethyl 2-6 part, 2-(Acryloyloxy)ethanol 3-4
Part, N, N-dimethyl-N '-(2-Trifluoromethyl-1-pentafluoroethyl group) 3-5 part, octadecyl trimethyl chlorine
Change ammonium 2-4 part, potassium peroxydisulfate 3-4 part, nano silicon 2-3 part, anti-settling agent 4-5 part, wetting agent
2.5-3.5 part, levelling agent 2-3 part, anti-sudden strain of a muscle rust agent 3-5 part, defoamer 4.5-5.5 part, thickening agent 2-3
Part, Antifog bactericide 3-4 part, antimildew disinfectant 1.5-2.5 part, deionized water 9-15 part.
6. according to the oil resistant water-proof metal flash coating material of the photo frame described in any one of claim 1-5, its feature
Being, its raw material includes by weight: perfluoroalkyl acrylate 55 parts, fluorinated acrylate emulsion 20
Part, watersoluble modified hydroxyl acrylic aqueous dispersion 10 parts, high imino group melamine resin 9 parts, N, N-
Dimethylethanolamine 3.5 parts, isopropanol 3.5 parts, propandiol butyl ether 2.5 parts, polyamide wax 4 parts, water
Property aluminium powder 3.5 parts, acetylbutyrylcellulose 2.5 parts, methyl methacrylate 4.5 parts, butyl acrylate
5 parts, dimethylaminoethyl acrylate methyl base aminoethyl 4 parts, 2-(Acryloyloxy)ethanol 3.5 parts, N, N-dimethyl-N '-
(2-Trifluoromethyl-1-pentafluoroethyl group) 4 parts, octadecyl trimethyl ammonium chloride 3 parts, potassium peroxydisulfate 3.5
Part, nano silicon 2.5 parts, anti-settling agent 4.5 parts, wetting agent 3 parts, levelling agent 2.5 parts, anti-sudden strain of a muscle
Rust agent 4 parts, defoamer 5 parts, thickening agent 2.5 parts, Antifog bactericide 3.5 parts, antimildew disinfectant 2 parts,
Deionized water 12 parts.
7. one kind according to the system of oil resistant water-proof metal flash coating material of the photo frame described in any one of claim 1-6
Preparation Method, it is characterised in that comprise the steps:
S1, by isopropanol, propandiol butyl ether, polyamide wax and acetylbutyrylcellulose mix homogeneously, in
1500-2500r/min disperses 25-45min, is subsequently adding aqueous aluminum powder mix homogeneously, in
300-1000r/min, disperses 15-25min, then adds N, N-dimethylethanolamine regulation pH to 7.5-8.5,
Stand 1-3h after stirring, obtain material a；
S2, by perfluoroalkyl acrylate, N, N-dimethyl-N '-(2-Trifluoromethyl-1-pentafluoroethyl group),
Octadecyl trimethyl ammonium chloride and deionized water mix homogeneously, stir 1-3h in 600-800r/min, so
Rear addition methyl methacrylate, butyl acrylate, dimethylaminoethyl acrylate methyl base aminoethyl, acrylic acid hydroxyl
Ethyl ester and potassium peroxydisulfate mix homogeneously, be warming up to 80-90 DEG C, is incubated 1-3h, is subsequently added into fluorine-containing
Ester emulsion, watersoluble modified hydroxyl acrylic aqueous dispersion, high imino group melamine resin, nano-silica
SiClx, anti-settling agent, wetting agent, levelling agent, anti-sudden strain of a muscle rust agent, defoamer, thickening agent, Antifog bactericide and
Antimildew disinfectant mix homogeneously, stirs 45-55min in 1500-2500r/min, is cooled to room temperature and obtains phase
Frame oil resistant water-proof metal flash coating material.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610417163.9A CN105949918A (en) | 2016-06-07 | 2016-06-07 | Oil-resistant and waterproof metal flicker paint for photo frame and preparing method of oil-resistant and waterproof metal flicker paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610417163.9A CN105949918A (en) | 2016-06-07 | 2016-06-07 | Oil-resistant and waterproof metal flicker paint for photo frame and preparing method of oil-resistant and waterproof metal flicker paint |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106833059A (en) * | 2016-12-22 | 2017-06-13 | 安徽易有墙纸有限公司 | A kind of wear-resisting waterproof wallpaper and preparation method thereof |
| CN106867378A (en) * | 2016-12-22 | 2017-06-20 | 安徽易有墙纸有限公司 | A kind of tack oil resistant wallpaper high and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101077954A (en) * | 2007-06-26 | 2007-11-28 | 广东雅图化工有限公司 | Automobile metal sparkling paint and preparation method thereof |
| CN102277080A (en) * | 2011-08-27 | 2011-12-14 | 深圳市深赛尔实业有限公司 | Single-component poly urethane (PU) low-temperature cured hardware coating and preparation method |
| CN103319965A (en) * | 2013-07-02 | 2013-09-25 | 中国海洋石油总公司 | Aqueous metal glossy lacquer for cars and preparation method thereof |
| CN105086728A (en) * | 2015-08-05 | 2015-11-25 | 肇庆市彩信装饰材料有限公司 | Water-based environment-friendly matte aluminum powder metallic paint and preparing method thereof |
| CN105331234A (en) * | 2015-11-26 | 2016-02-17 | 蚌埠市禹会区贵宾装饰材料商行 | Flash photo frame |
| CN105331216A (en) * | 2015-11-26 | 2016-02-17 | 蚌埠市禹会区贵宾装饰材料商行 | Metal flashing coating applied to photo frame |
-
2016
- 2016-06-07 CN CN201610417163.9A patent/CN105949918A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101077954A (en) * | 2007-06-26 | 2007-11-28 | 广东雅图化工有限公司 | Automobile metal sparkling paint and preparation method thereof |
| CN102277080A (en) * | 2011-08-27 | 2011-12-14 | 深圳市深赛尔实业有限公司 | Single-component poly urethane (PU) low-temperature cured hardware coating and preparation method |
| CN103319965A (en) * | 2013-07-02 | 2013-09-25 | 中国海洋石油总公司 | Aqueous metal glossy lacquer for cars and preparation method thereof |
| CN105086728A (en) * | 2015-08-05 | 2015-11-25 | 肇庆市彩信装饰材料有限公司 | Water-based environment-friendly matte aluminum powder metallic paint and preparing method thereof |
| CN105331234A (en) * | 2015-11-26 | 2016-02-17 | 蚌埠市禹会区贵宾装饰材料商行 | Flash photo frame |
| CN105331216A (en) * | 2015-11-26 | 2016-02-17 | 蚌埠市禹会区贵宾装饰材料商行 | Metal flashing coating applied to photo frame |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106833059A (en) * | 2016-12-22 | 2017-06-13 | 安徽易有墙纸有限公司 | A kind of wear-resisting waterproof wallpaper and preparation method thereof |
| CN106867378A (en) * | 2016-12-22 | 2017-06-20 | 安徽易有墙纸有限公司 | A kind of tack oil resistant wallpaper high and preparation method thereof |
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Application publication date: 20160921 |