CN105907142A - Building plate surface waterproof anticorrosion and stain-resistant paint - Google Patents
Building plate surface waterproof anticorrosion and stain-resistant paint Download PDFInfo
- Publication number
- CN105907142A CN105907142A CN201610294762.6A CN201610294762A CN105907142A CN 105907142 A CN105907142 A CN 105907142A CN 201610294762 A CN201610294762 A CN 201610294762A CN 105907142 A CN105907142 A CN 105907142A
- Authority
- CN
- China
- Prior art keywords
- parts
- styrene
- acrylate
- board surface
- ethanol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
- C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4854—Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
- C08G18/7671—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses building plate surface waterproof anticorrosion and stain-resistant paint, which is prepared from the following raw materials including modified fluorine-containing polyurethane, styrene-acrylic emulsion, perfluoroalkylated acrylate, methyl methacrylate, butyl acrylate, styrene, hydroxyethyl acrylate, sodium p-perfluorononoxy benzene sulfonate, sodium dodecyl sulfate, potassium peroxodisulfate, aluminium triphosphate, nanometer titania, zinc oxide, magnesium hydroxide, ultrafine silicon dioxide, white fused alumina powder, carbon fluoride, sodium persulfate, talcum powder, nanosilicon dioxide, xylene, stain-resistant agents, hydrophobing agents, flatting agents, titanate coupling agents NDZ-311 and diluting agents. The paint has excellent waterproof anticorrosion and stain-resistant performance.
Description
Technical field
The present invention relates to paint field, particularly relate to a kind of building board surface waterproofing anticorrosion antifouling paint.
Background technology
Building coating has decoration functions, defencive function and livability and improves function.Ratio shared by various functions
Weight is not quite similar because application target is different.Decoration functions is to improve its outward appearance by beautifying of building
The function being worth.Mainly include the structure of the concept in terms of plane color, pattern and gloss and three-dimensional pattern
Think design.But to match with the size and shape of the moulding of building itself and base material itself, could be fully
Bring into play.
Defencive function refers to protect the function that building is the most protected from environmental and destroys.Different types of protected
The content that defencive function is required by watch box is the most different.The index reached as required by indoor and outdoor application
Difference is the biggest.Some buildings to mildew-resistant, fire prevention, insulation, corrosion-resistant etc. have particular/special requirement.
In prior art, in use, surface needs to coat some functional coatings to realize plate building board
Material performance requirement under various circumstances, waterproof, the anticorrosion of sheet material coating of the prior art and resistant
Demand when performance all cannot meet actually used, therefore needs exploitation badly and has excellent waterproof, anticorrosion and resistance to
The building board surface coating of dirty performance
Summary of the invention
For solving technical problem present in background technology, the present invention proposes a kind of building board surface waterproofing and prevents
Rotten antifouling paint, has waterproof, anticorrosion and the anti-pollution characteristic of excellence.
A kind of building board surface waterproofing anticorrosion antifouling paint that the present invention proposes, its raw material includes by weight:
Modified fluoride-containing polyurethane 30-90 part, styrene-acrylic emulsion 5-15 part, perfluoroalkyl acrylate 3-9 part, methyl
Acrylic acid methyl ester. 2-6 part, butyl acrylate 1-4 part, styrene 2-5 part, 2-(Acryloyloxy)ethanol 3-6 part,
Nona oxy benzene sulfonic acid sodium salt of perfluoro 1-4 part, dodecyl sodium sulfate 2-4 part, potassium peroxydisulfate 1-5 part, trimerization
Aluminum phosphate 2-6 part, nano titanium oxide 3-5 part, zinc oxide 2-4 part, magnesium hydroxide 1-4 part, ultra-fine
Silicon dioxide 2-5 part, white fused alumina micropowder 1-4 part, perfluorocarbon 1-5 part, sodium peroxydisulfate 1-4 part, Talcum
Powder 2-6 part, nano silicon 3-5 part, dimethylbenzene 1-4 part, stain resistant agents 2-5 part, water-repelling agent 3-6
Part, levelling agent 1-4 part, titanate coupling agent NDZ-311 2-5 part, diluent 3-9 part.
Preferably, the raw material of fluorine-containing modified polyurethane includes by weight: methyl diphenylene diisocyanate 2-6
Part, PTMG 1-3 part, perfluoroalkyl ethanol 2-4 part, triethylene glycol 3-9 part, N, N-
Dimethylformamide 4-8 part, DMAC N,N' dimethyl acetamide 5-9 part, methanol 3-6 part, deionized water 1-5
Part.
Preferably, fluorine-containing modified polyurethane is prepared by following technique: under nitrogen protection by two Ji Jia
Alkane diisocyanate and perfluoroalkyl ethanol are dissolved in DMF, then heat to 45-55 DEG C,
Insulation 1-3h, then heats to 55-65 DEG C, adds PTMG, stirs 1-3h, is cooled to
Room temperature obtains material a；In material a, add triethylene glycol, be warming up to 70-80 DEG C, be incubated 1-4h, obtain
Material b；Then in material b, add methanol block, be subsequently added into deionized water and N, N-dimethyl
Acetamide mix homogeneously, is cooled to room temperature and obtains fluorine-containing modified polyurethane after filtration.
Preferably, modified fluoride-containing polyurethane, styrene-acrylic emulsion, perfluoroalkyl acrylate, methyl methacrylate
Ester, butyl acrylate, styrene, 2-(Acryloyloxy)ethanol, nona oxy benzene sulfonic acid sodium salt of perfluoro, dodecyl sulphur
The weight ratio of acid sodium and potassium peroxydisulfate is 35-85:8-12:4-8:3-5:2-3:3-4:4-5:2-3:2.5-3.5:
2-4。
Preferably, modified fluoride-containing polyurethane, styrene-acrylic emulsion, aluminium triphosphate, nano titanium oxide, oxidation
Zinc, magnesium hydroxide, superfine silicon dioxide, white fused alumina micropowder, perfluorocarbon, sodium peroxydisulfate, Pulvis Talci, receive
The weight ratio of rice silicon dioxide and titanate coupling agent NDZ-311 is 35-85:8-12:3-5:3.5-4.5:
2.5-3.5:2-3:3-4:2-3:2-4:2-3:3-5:3.5-4.5:3-4.
Preferably, its raw material includes by weight: modified fluoride-containing polyurethane 35-85 part, styrene-acrylic emulsion 8-12
Part, perfluoroalkyl acrylate 4-8 part, methyl methacrylate 3-5 part, butyl acrylate 2-3 part,
Styrene 3-4 part, 2-(Acryloyloxy)ethanol 4-5 part, nona oxy benzene sulfonic acid sodium salt of perfluoro 2-3 part, dodecyl
Sodium sulfonate 2.5-3.5 part, potassium peroxydisulfate 2-4 part, aluminium triphosphate 3-5 part, nano titanium oxide 3.5-4.5
Part, zinc oxide 2.5-3.5 part, magnesium hydroxide 2-3 part, superfine silicon dioxide 3-4 part, white fused alumina micropowder
2-3 part, perfluorocarbon 2-4 part, sodium peroxydisulfate 2-3 part, Pulvis Talci 3-5 part, nano silicon 3.5-4.5
Part, dimethylbenzene 2-3 part, stain resistant agents 3-4 part, water-repelling agent 4-5 part, levelling agent 2-3 part, titanate esters are occasionally
Connection agent NDZ-311 3-4 part, diluent 4-8 part.
Preferably, its raw material includes by weight: modified fluoride-containing polyurethane 60 parts, styrene-acrylic emulsion 10 parts,
Perfluoroalkyl acrylate 6 parts, methyl methacrylate 4 parts, butyl acrylate 2.5 parts, styrene 3.5
Part, 2-(Acryloyloxy)ethanol 4.5 parts, nona oxy benzene sulfonic acid sodium salt of perfluoro 2.5 parts, dodecyl sodium sulfate 3 parts,
Potassium peroxydisulfate 3 parts, aluminium triphosphate 4 parts, nano titanium oxide 4 parts, zinc oxide 3 parts, magnesium hydroxide
2.5 parts, superfine silicon dioxide 3.5 parts, white fused alumina micropowder 2.5 parts, perfluorocarbon 3 parts, sodium peroxydisulfate 2.5
Part, Pulvis Talci 4 parts, nano silicon 4 parts, dimethylbenzene 2.5 parts, stain resistant agents 3.5 parts, water-repelling agent
4.5 parts, levelling agent 2.5 parts, titanate coupling agent NDZ-311 3.5 parts, diluent 6 parts.
A kind of building board surface waterproofing anticorrosion antifouling paint of the present invention, its raw material includes the poly-ammonia of modified fluoride-containing
Ester, styrene-acrylic emulsion, perfluoroalkyl acrylate, methyl methacrylate, butyl acrylate, styrene,
2-(Acryloyloxy)ethanol, nona oxy benzene sulfonic acid sodium salt of perfluoro, dodecyl sodium sulfate, potassium peroxydisulfate, tripolyphosphate
Aluminum, nano titanium oxide, zinc oxide, magnesium hydroxide, superfine silicon dioxide, white fused alumina micropowder, perfluorocarbon,
Sodium peroxydisulfate, Pulvis Talci, nano silicon, dimethylbenzene, stain resistant agents, water-repelling agent, levelling agent, metatitanic acid
Ester coupling agent NDZ-311 and diluent, wherein add using modified fluoride-containing polyurethane as film forming major ingredient, auxiliary
Styrene-acrylic emulsion, as film forming major ingredient performance reinforcement material, effectively enhances the waterproof anti-corrosion resistance to soiling of film forming major ingredient
Energy；The perfluoroalkyl acrylate added has relatively low surface tension, so it can not well be scattered in
Aqueous phase, will make it well be scattered in aqueous phase and must be added to hydrophilic monomer, on the one hand be because cation mono
The hydrophilic of body, on the other hand being by mean of its cation electrostatic interaction can preferably be bound by material surface.
Wherein hydrophilic monomer methyl methacrylate, butyl acrylate, 2-(Acryloyloxy)ethanol and styrene, entirely
Under fluorine nonyl epoxide benzene sulfonic acid sodium salt, nona oxy benzene sulfonic acid sodium salt of perfluoro and potassium peroxydisulfate effect, further increase complete
Waterproof, the anticorrosion of fluoroalkyl and anti-pollution characteristic；The modified fluoride-containing of the present invention wherein added gathers
Urethane with methyl diphenylene diisocyanate, PTMG, perfluoroalkyl ethanol, triethylene glycol,
DMF, N,N-dimethylacetamide, methanol and deionized water are raw material, and end-capping reagent draws
The mode entering fluorine has independently synthesized fluorochemical urethane, with perfluoroalkyl ethanol, methyl diphenylene diisocyanate,
PTMG and triethylene glycol are that primary raw material has synthesized fluorochemical urethane, choose N, N-dimethyl
Methanamide is synthesis reaction solvent, and separated degree is improved, and then modified fluoride-containing polyurethane is had
Excellent waterproof, anticorrosion and the performance of resistant.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail, it should be appreciated that embodiment is served only for
The bright present invention rather than be used for limiting the invention, any made on the basis of the present invention amendment,
Equivalents etc. are the most within the scope of the present invention.
In detailed description of the invention, the weight portion of modified fluoride-containing polyurethane can be 30 parts, 35 parts, 40 parts,
45 parts, 50 parts, 55 parts, 60 parts, 65 parts, 70 parts, 75 parts, 80 parts, 85 parts, 90 parts；Phenylpropyl alcohol
The weight portion of emulsion can be 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13
Part, 14 parts, 15 parts；The weight portion of perfluoroalkyl acrylate can be 3 parts, 4 parts, 5 parts, 6 parts,
7 parts, 8 parts, 9 parts；The weight portion of methyl methacrylate can be 2 parts, 3 parts, 4 parts, 5 parts, 6
Part；The weight portion of butyl acrylate can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4
Part；Cinnamic weight portion can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；
The weight portion of 2-(Acryloyloxy)ethanol can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；
The weight portion of nona oxy benzene sulfonic acid sodium salt of perfluoro can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts,
4 parts；The weight portion of dodecyl sodium sulfate can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；Over cure
The weight portion of acid potassium can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts,
5 parts；The weight portion of aluminium triphosphate can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts；Nano titanium oxide
Weight portion can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The weight portion of zinc oxide can be 2
Part, 2.5 parts, 3 parts, 3.5 parts, 4 parts；The weight portion of magnesium hydroxide can be 1 part, 1.5 parts, 2 parts,
2.5 parts, 3 parts, 3.5 parts, 4 parts；The weight portion of superfine silicon dioxide can be 2 parts, 2.5 parts, 3 parts,
3.5 parts, 4 parts, 4.5 parts, 5 parts；The weight portion of white fused alumina micropowder can be 1 part, 1.5 parts, 2 parts,
2.5 parts, 3 parts, 3.5 parts, 4 parts；The weight portion of perfluorocarbon can be 1 part, 2 parts, 3 parts, 4 parts, 5
Part；The weight portion of sodium peroxydisulfate can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；
Talcous weight portion can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts；The weight portion of nano silicon
It can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The weight portion of dimethylbenzene can be 1 part, 1.5 parts,
2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；The weight portion of stain resistant agents can be 2 parts, 2.5 parts, 3 parts,
3.5 parts, 4 parts, 4.5 parts, 5 parts；The weight portion of water-repelling agent can be 3 parts, 3.5 parts, 4 parts, 4.5
Part, 5 parts, 5.5 parts, 6 parts；The weight portion of levelling agent can be 1 part, 1.5 parts, 2 parts, 2.5 parts,
3 parts, 3.5 parts, 4 parts；The weight portion of titanate coupling agent NDZ-311 can be 2 parts, 2.5 parts, 3 parts,
3.5 parts, 4 parts, 4.5 parts, 5 parts；The weight portion of diluent can be 3 parts, 4 parts, 5 parts, 6 parts, 7
Part, 8 parts, 9 parts.
Embodiment 1
A kind of building board surface waterproofing anticorrosion antifouling paint that the present invention proposes, its raw material includes by weight:
Modified fluoride-containing polyurethane 60 parts, styrene-acrylic emulsion 10 parts, perfluoroalkyl acrylate 6 parts, methacrylic acid
Methyl ester 4 parts, butyl acrylate 2.5 parts, styrene 3.5 parts, 2-(Acryloyloxy)ethanol 4.5 parts, perfluor nonyl
Epoxide benzene sulfonic acid sodium salt 2.5 parts, dodecyl sodium sulfate 3 parts, potassium peroxydisulfate 3 parts, aluminium triphosphate 4 parts,
Nano titanium oxide 4 parts, zinc oxide 3 parts, 2.5 parts of magnesium hydroxide, superfine silicon dioxide 3.5 parts, white
Corundum powder 2.5 parts, perfluorocarbon 3 parts, sodium peroxydisulfate 2.5 parts, Pulvis Talci 4 parts, nano silicon 4
Part, dimethylbenzene 2.5 parts, stain resistant agents 3.5 parts, water-repelling agent 4.5 parts, levelling agent 2.5 parts, titanate esters are occasionally
Connection agent NDZ-311 3.5 parts, diluent 6 parts.
Fluorine-containing modified polyurethane is prepared by following technique: the most by weight by 4 parts two
Dicyclohexylmethane diisocyanate and 3 parts of perfluoroalkyl ethanols are dissolved in 6 parts of DMFs, then heat up
To 50 DEG C, it is incubated 2h, then heats to 60 DEG C, add 2 parts of PTMG, stir 2h,
It is cooled to room temperature and obtains material a；In material a, add 6 parts of triethylene glycols, be warming up to 75 DEG C, be incubated 2.5h,
Obtain material b；Then in material b, add 4.5 parts of methanol block, be subsequently added into 3 parts of deionized waters
With 7 parts of N,N-dimethylacetamide mix homogeneously, it is cooled to room temperature after filtration and obtains fluorine-containing modified polyurethane.
Embodiment 2
A kind of building board surface waterproofing anticorrosion antifouling paint that the present invention proposes, its raw material includes by weight:
Modified fluoride-containing polyurethane 30 parts, styrene-acrylic emulsion 15 parts, perfluoroalkyl acrylate 3 parts, methacrylic acid
Methyl ester 6 parts, butyl acrylate 1 part, styrene 5 parts, 2-(Acryloyloxy)ethanol 3 parts, perfluor nonyl epoxide benzene
Sodium sulfonate 4 parts, dodecyl sodium sulfate 2 parts, potassium peroxydisulfate 5 parts, aluminium triphosphate 2 parts, nanometer two
Titanium oxide 5 parts, zinc oxide 2 parts, 4 parts of magnesium hydroxide, superfine silicon dioxide 2 parts, white fused alumina micropowder 4
Part, perfluorocarbon 1 part, sodium peroxydisulfate 4 parts, Pulvis Talci 2 parts, nano silicon 5 parts, dimethylbenzene 1
Part, stain resistant agents 5 parts, water-repelling agent 3 parts, levelling agent 4 parts, titanate coupling agent NDZ-311 2 parts, dilute
Release agent 9 parts.
Fluorine-containing modified polyurethane is prepared by following technique: the most by weight by 2 parts two
Dicyclohexylmethane diisocyanate and 4 parts of perfluoroalkyl ethanols are dissolved in 4 parts of DMFs, then heat up
To 55 DEG C, it is incubated 1h, then heats to 65 DEG C, add 1 part of PTMG, stir 3h,
It is cooled to room temperature and obtains material a；In material a, add 3 parts of triethylene glycols, be warming up to 80 DEG C, be incubated 1h,
Obtain material b；Then in material b add 6 parts of methanol block, be subsequently added into 1 part of deionized water and
9 parts of N,N-dimethylacetamide mix homogeneously, are cooled to room temperature and obtain fluorine-containing modified polyurethane after filtration.
Embodiment 3
A kind of building board surface waterproofing anticorrosion antifouling paint that the present invention proposes, its raw material includes by weight:
Modified fluoride-containing polyurethane 90 parts, styrene-acrylic emulsion 5 parts, perfluoroalkyl acrylate 9 parts, methyl methacrylate
Ester 2 parts, butyl acrylate 4 parts, styrene 2 parts, 2-(Acryloyloxy)ethanol 6 parts, perfluor nonyl epoxide benzene sulphur
Acid 1 part of sodium, dodecyl sodium sulfate 4 parts, potassium peroxydisulfate 1 part, aluminium triphosphate 6 parts, nano-silica
Change titanium 3 parts, zinc oxide 4 parts, 1 part of magnesium hydroxide, superfine silicon dioxide 5 parts, white fused alumina micropowder 1 part,
Perfluorocarbon 5 parts, sodium peroxydisulfate 1 part, Pulvis Talci 6 parts, nano silicon 3 parts, dimethylbenzene 4 parts,
Stain resistant agents 2 parts, water-repelling agent 6 parts, levelling agent 1 part, titanate coupling agent NDZ-311 5 parts, diluent 3
Part.
Fluorine-containing modified polyurethane is prepared by following technique: the most by weight by 6 parts two
Dicyclohexylmethane diisocyanate and 2 parts of perfluoroalkyl ethanols are dissolved in 8 parts of DMFs, then heat up
To 45 DEG C, it is incubated 3h, then heats to 55 DEG C, add 3 parts of PTMG, stir 1h,
It is cooled to room temperature and obtains material a；In material a, add 9 parts of triethylene glycols, be warming up to 70 DEG C, be incubated 4h,
Obtain material b；Then in material b add 3 parts of methanol block, be subsequently added into 5 parts of deionized waters and
5 parts of N,N-dimethylacetamide mix homogeneously, are cooled to room temperature and obtain fluorine-containing modified polyurethane after filtration.
Embodiment 4
A kind of building board surface waterproofing anticorrosion antifouling paint that the present invention proposes, its raw material includes by weight:
Modified fluoride-containing polyurethane 35 parts, styrene-acrylic emulsion 12 parts, perfluoroalkyl acrylate 4 parts, methacrylic acid
Methyl ester 5 parts, butyl acrylate 2 parts, styrene 4 parts, 2-(Acryloyloxy)ethanol 4 parts, perfluor nonyl epoxide benzene
Sodium sulfonate 3 parts, dodecyl sodium sulfate 2.5 parts, potassium peroxydisulfate 4 parts, aluminium triphosphate 3 parts, nanometer
Titanium dioxide 4.5 parts, zinc oxide 2.5 parts, 3 parts of magnesium hydroxide, superfine silicon dioxide 3 parts, white fused alumina
Micropowder 3 parts, perfluorocarbon 2 parts, sodium peroxydisulfate 3 parts, Pulvis Talci 3 parts, nano silicon 4.5 parts,
Dimethylbenzene 2 parts, stain resistant agents 4 parts, water-repelling agent 4 parts, levelling agent 3 parts, titanate coupling agent NDZ-311 3
Part, diluent 8 parts.
Fluorine-containing modified polyurethane is prepared by following technique: the most by weight by 3 parts two
Dicyclohexylmethane diisocyanate and 3.5 parts of perfluoroalkyl ethanols are dissolved in 5 parts of DMFs, then rise
Temperature, to 52 DEG C, is incubated 1.5h, then heats to 62 DEG C, add 1.5 parts of PTMG, stirring
2.5h, is cooled to room temperature and obtains material a；In material a, add 4 parts of triethylene glycols, be warming up to 78 DEG C,
Insulation 2h, obtains material b；Then in material b, add 5 parts of methanol block, be subsequently added into 2 parts
Deionized water and 8 parts of N,N-dimethylacetamide mix homogeneously, be cooled to room temperature and obtain containing fluorine richness after filtration
Polyurethane.
Embodiment 5
A kind of building board surface waterproofing anticorrosion antifouling paint that the present invention proposes, its raw material includes by weight:
Modified fluoride-containing polyurethane 85 parts, styrene-acrylic emulsion 8 parts, perfluoroalkyl acrylate 8 parts, methyl methacrylate
Ester 3 parts, butyl acrylate 3 parts, styrene 3 parts, 2-(Acryloyloxy)ethanol 5 parts, perfluor nonyl epoxide benzene sulphur
Acid 2 parts of sodium, dodecyl sodium sulfate 3.5 parts, potassium peroxydisulfate 2 parts, aluminium triphosphate 5 parts, nanometer two
Titanium oxide 3.5 parts, zinc oxide 3.5 parts, 2 parts of magnesium hydroxide, superfine silicon dioxide 4 parts, white fused alumina are micro-
2 parts of powder, perfluorocarbon 4 parts, sodium peroxydisulfate 2 parts, Pulvis Talci 5 parts, nano silicon 3.5 parts, two
Toluene 3 parts, stain resistant agents 3 parts, water-repelling agent 5 parts, levelling agent 2 parts, titanate coupling agent NDZ-311 4
Part, diluent 4 parts.
Fluorine-containing modified polyurethane is prepared by following technique: the most by weight by 5 parts two
Dicyclohexylmethane diisocyanate and 2.5 parts of perfluoroalkyl ethanols are dissolved in 7 parts of DMFs, then rise
Temperature, to 48 DEG C, is incubated 2.5h, then heats to 58 DEG C, add 2.5 parts of PTMG, stirring
1.5h, is cooled to room temperature and obtains material a；In material a, add 8 parts of triethylene glycols, be warming up to 72 DEG C,
Insulation 3h, obtains material b；Then in material b, add 4 parts of methanol block, be subsequently added into 4 parts
Deionized water and 6 parts of N,N-dimethylacetamide mix homogeneously, be cooled to room temperature and obtain containing fluorine richness after filtration
Polyurethane.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention not office
Being limited to this, any those familiar with the art is in the technical scope that the invention discloses, according to this
The technical scheme of invention and inventive concept thereof in addition equivalent or change, all should contain the protection in the present invention
Within the scope of.
Claims (7)
1. a building board surface waterproofing anticorrosion antifouling paint, it is characterised in that its raw material wraps by weight
Include: modified fluoride-containing polyurethane 30-90 part, styrene-acrylic emulsion 5-15 part, perfluoroalkyl acrylate 3-9 part,
Methyl methacrylate 2-6 part, butyl acrylate 1-4 part, styrene 2-5 part, 2-(Acryloyloxy)ethanol 3-6
Part, nona oxy benzene sulfonic acid sodium salt of perfluoro 1-4 part, dodecyl sodium sulfate 2-4 part, potassium peroxydisulfate 1-5 part,
Aluminium triphosphate 2-6 part, nano titanium oxide 3-5 part, zinc oxide 2-4 part, magnesium hydroxide 1-4 part,
Superfine silicon dioxide 2-5 part, white fused alumina micropowder 1-4 part, perfluorocarbon 1-5 part, sodium peroxydisulfate 1-4 part,
Pulvis Talci 2-6 part, nano silicon 3-5 part, dimethylbenzene 1-4 part, stain resistant agents 2-5 part, water-repelling agent
3-6 part, levelling agent 1-4 part, titanate coupling agent NDZ-311 2-5 part, diluent 3-9 part.
Building board surface waterproofing anticorrosion antifouling paint the most according to claim 1, it is characterised in that
The raw material of fluorine-containing modified polyurethane includes by weight: methyl diphenylene diisocyanate 2-6 part, poly-tetrahydrochysene
Furan ether glycol 1-3 part, perfluoroalkyl ethanol 2-4 part, triethylene glycol 3-9 part, N, N-dimethyl formyl
Amine 4-8 part, DMAC N,N' dimethyl acetamide 5-9 part, methanol 3-6 part, deionized water 1-5 part.
Building board surface waterproofing anticorrosion antifouling paint the most according to claim 1 and 2, its feature exists
In, fluorine-containing modified polyurethane is prepared by following technique: under nitrogen protection by two methylmethane two isocyanides
Acid esters and perfluoroalkyl ethanol are dissolved in DMF, then heat to 45-55 DEG C, are incubated 1-3h,
Then heat to 55-65 DEG C, add PTMG, stir 1-3h, be cooled to room temperature and obtain thing
Material a；In material a, add triethylene glycol, be warming up to 70-80 DEG C, be incubated 1-4h, obtain material b；So
Backward material b adds methanol block, be subsequently added into deionized water and N,N-dimethylacetamide mixing
Uniformly, it is cooled to room temperature after filtration and obtains fluorine-containing modified polyurethane.
4., according to the building board surface waterproofing anticorrosion antifouling paint described in any one of claim 1-3, it is special
Levy and be, modified fluoride-containing polyurethane, styrene-acrylic emulsion, perfluoroalkyl acrylate, methyl methacrylate,
Butyl acrylate, styrene, 2-(Acryloyloxy)ethanol, nona oxy benzene sulfonic acid sodium salt of perfluoro, dodecyl sodium sulfate
It is 35-85:8-12:4-8:3-5:2-3:3-4:4-5:2-3:2.5-3.5 with the weight ratio of potassium peroxydisulfate:
2-4。
5., according to the building board surface waterproofing anticorrosion antifouling paint described in any one of claim 1-4, it is special
Levy and be, modified fluoride-containing polyurethane, styrene-acrylic emulsion, aluminium triphosphate, nano titanium oxide, zinc oxide,
Magnesium hydroxide, superfine silicon dioxide, white fused alumina micropowder, perfluorocarbon, sodium peroxydisulfate, Pulvis Talci, nanometer two
The weight ratio of silicon oxide and titanate coupling agent NDZ-311 is 35-85:8-12:3-5:3.5-4.5:
2.5-3.5:2-3:3-4:2-3:2-4:2-3:3-5:3.5-4.5:3-4.
6., according to the building board surface waterproofing anticorrosion antifouling paint described in any one of claim 1-5, it is special
Levying and be, its raw material includes by weight: modified fluoride-containing polyurethane 35-85 part, styrene-acrylic emulsion 8-12 part,
Perfluoroalkyl acrylate 4-8 part, methyl methacrylate 3-5 part, butyl acrylate 2-3 part, benzene second
Alkene 3-4 part, 2-(Acryloyloxy)ethanol 4-5 part, nona oxy benzene sulfonic acid sodium salt of perfluoro 2-3 part, dodecyl sodium sulfonate
Sodium 2.5-3.5 part, potassium peroxydisulfate 2-4 part, aluminium triphosphate 3-5 part, nano titanium oxide 3.5-4.5
Part, zinc oxide 2.5-3.5 part, magnesium hydroxide 2-3 part, superfine silicon dioxide 3-4 part, white fused alumina micropowder
2-3 part, perfluorocarbon 2-4 part, sodium peroxydisulfate 2-3 part, Pulvis Talci 3-5 part, nano silicon 3.5-4.5
Part, dimethylbenzene 2-3 part, stain resistant agents 3-4 part, water-repelling agent 4-5 part, levelling agent 2-3 part, titanate esters are occasionally
Connection agent NDZ-311 3-4 part, diluent 4-8 part.
7., according to the building board surface waterproofing anticorrosion antifouling paint described in any one of claim 1-6, it is special
Levying and be, its raw material includes by weight: modified fluoride-containing polyurethane 60 parts, styrene-acrylic emulsion 10 parts, perfluor
Alkyl acrylate 6 parts, methyl methacrylate 4 parts, butyl acrylate 2.5 parts, styrene 3.5 parts,
2-(Acryloyloxy)ethanol 4.5 parts, nona oxy benzene sulfonic acid sodium salt of perfluoro 2.5 parts, dodecyl sodium sulfate 3 parts, mistake
Potassium sulfate 3 parts, aluminium triphosphate 4 parts, nano titanium oxide 4 parts, zinc oxide 3 parts, magnesium hydroxide 2.5
Part, superfine silicon dioxide 3.5 parts, white fused alumina micropowder 2.5 parts, perfluorocarbon 3 parts, sodium peroxydisulfate 2.5 parts,
Pulvis Talci 4 parts, nano silicon 4 parts, dimethylbenzene 2.5 parts, stain resistant agents 3.5 parts, water-repelling agent 4.5
Part, levelling agent 2.5 parts, titanate coupling agent NDZ-311 3.5 parts, diluent 6 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610294762.6A CN105907142A (en) | 2016-05-03 | 2016-05-03 | Building plate surface waterproof anticorrosion and stain-resistant paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610294762.6A CN105907142A (en) | 2016-05-03 | 2016-05-03 | Building plate surface waterproof anticorrosion and stain-resistant paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105907142A true CN105907142A (en) | 2016-08-31 |
Family
ID=56753564
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610294762.6A Pending CN105907142A (en) | 2016-05-03 | 2016-05-03 | Building plate surface waterproof anticorrosion and stain-resistant paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105907142A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107652825A (en) * | 2017-09-30 | 2018-02-02 | 合众（佛山）化工有限公司 | A kind of fluorine-containing aqueous self-cleaning coating of atmospheric corrosion resistance |
| CN107779036A (en) * | 2017-09-30 | 2018-03-09 | 合众（佛山）化工有限公司 | A kind of fluoropolymer water-based anticorrosive paint |
| CN108015293A (en) * | 2017-12-21 | 2018-05-11 | 宁波金轮磁材技术有限公司 | A kind of dual alloy Fe-B rare-earth permanent magnet and its manufacture method |
| CN109593419A (en) * | 2018-11-14 | 2019-04-09 | 铜仁市万山区建辉新型环保建材有限公司 | A kind of roof waterproof material and preparation method thereof |
| CN111234577A (en) * | 2020-03-25 | 2020-06-05 | 天津市精志诚拉线厂 | Anticorrosive resistant dirty stay cord body |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1333315A (en) * | 2000-07-11 | 2002-01-30 | 上海惠邦特种涂料有限公司 | Elastic building paint |
| CN103013247A (en) * | 2011-09-22 | 2013-04-03 | 天津市耀新科技发展有限公司 | Water-based acrylic waterproof paint and preparation method thereof |
| CN104073137A (en) * | 2013-03-28 | 2014-10-01 | 扬州豪扬新型建筑材料有限公司 | Aqueous polyurethane waterproof paint |
-
2016
- 2016-05-03 CN CN201610294762.6A patent/CN105907142A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1333315A (en) * | 2000-07-11 | 2002-01-30 | 上海惠邦特种涂料有限公司 | Elastic building paint |
| CN103013247A (en) * | 2011-09-22 | 2013-04-03 | 天津市耀新科技发展有限公司 | Water-based acrylic waterproof paint and preparation method thereof |
| CN104073137A (en) * | 2013-03-28 | 2014-10-01 | 扬州豪扬新型建筑材料有限公司 | Aqueous polyurethane waterproof paint |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107652825A (en) * | 2017-09-30 | 2018-02-02 | 合众（佛山）化工有限公司 | A kind of fluorine-containing aqueous self-cleaning coating of atmospheric corrosion resistance |
| CN107779036A (en) * | 2017-09-30 | 2018-03-09 | 合众（佛山）化工有限公司 | A kind of fluoropolymer water-based anticorrosive paint |
| CN107652825B (en) * | 2017-09-30 | 2019-09-17 | 合众（佛山）化工有限公司 | A kind of fluorine-containing aqueous self-cleaning coating of atmospheric corrosion resistance |
| CN107779036B (en) * | 2017-09-30 | 2019-12-17 | 中山市钧纬新材料科技有限公司 | Fluorine-containing polymer water-based anticorrosive paint |
| CN108015293A (en) * | 2017-12-21 | 2018-05-11 | 宁波金轮磁材技术有限公司 | A kind of dual alloy Fe-B rare-earth permanent magnet and its manufacture method |
| CN109593419A (en) * | 2018-11-14 | 2019-04-09 | 铜仁市万山区建辉新型环保建材有限公司 | A kind of roof waterproof material and preparation method thereof |
| CN111234577A (en) * | 2020-03-25 | 2020-06-05 | 天津市精志诚拉线厂 | Anticorrosive resistant dirty stay cord body |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105907142A (en) | Building plate surface waterproof anticorrosion and stain-resistant paint | |
| CN102757710B (en) | A kind of water-borne coatings | |
| CN105925026A (en) | Building board surface waterproof, oil-resistant and anti-fouling coating | |
| CN106634511B (en) | Resistance to water-white particle cross-linking type water-in-water multicolor coating | |
| US20070088121A1 (en) | Emulsion for vibration damping materials | |
| CN105199591A (en) | Water-resistant acrylate modified waterborne polyurethane emulsion paint | |
| CN105331226A (en) | Fireproof emulsion paint | |
| CN105949842A (en) | Waterproof and ultraviolet resistant paint for building exterior walls | |
| CN102702866A (en) | Environmental-friendly thermal insulation waterproof nanometer water-based coating | |
| CN109370346A (en) | A kind of Multifunctional superthin steel structure fireproofing anticorrosion water-soluble coating and construction method | |
| CN105131769A (en) | Special dull finish paint for sand textured external wall coating and preparation method of special dull finish paint | |
| CN105949841A (en) | Waterproof and stain resistant paint for building interior walls | |
| CN107083088A (en) | A kind of organic fluorine silicon hybrid inorganic silicate coating and its preparation method and application | |
| KR100867682B1 (en) | Eco-heavy duty coating system with high weatherability a method for preventing contamination | |
| CN106566328B (en) | High damping properties damping paint | |
| CN106833249A (en) | A kind of water super-thin steel structure fire-proof paint and preparation method thereof | |
| CN102337062A (en) | Water-based thermal insulation coating and preparation method thereof | |
| CN109593433A (en) | A kind of expansion fire-proof, anti-corrosion steel structural traverse and preparation method thereof | |
| CN107189605B (en) | Reflective heat-insulating water-in-water multicolor paint and preparation method thereof | |
| CN105037614A (en) | High-solid-content leather finishing agent prepared on basis of miniemulsion polymerization method and method thereof | |
| CN108987650A (en) | Battery separator and preparation method thereof and battery | |
| CN102558992A (en) | Anti-ageing waterproof coating | |
| CN104356841A (en) | Self-cleaning acrylic coating | |
| CN106433355B (en) | high temperature resistant damping paint | |
| JP5576107B2 (en) | Thermal insulation structure |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160831 |
|
| RJ01 | Rejection of invention patent application after publication |