CN105949841A - Waterproof and stain resistant paint for building interior walls - Google Patents
Waterproof and stain resistant paint for building interior walls Download PDFInfo
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- CN105949841A CN105949841A CN201610294708.1A CN201610294708A CN105949841A CN 105949841 A CN105949841 A CN 105949841A CN 201610294708 A CN201610294708 A CN 201610294708A CN 105949841 A CN105949841 A CN 105949841A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/52—Amides or imides
- C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
- C08F220/58—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing oxygen in addition to the carbonamido oxygen, e.g. N-methylolacrylamide, N-(meth)acryloylmorpholine
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
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- Chemical & Material Sciences (AREA)
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
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Abstract
The invention discloses a waterproof and stain resistant paint for building interior walls. The raw materials include: a modified acrylic emulsion, hydroxypropyl methacrylate, dioctyl terephthalate, nano-titanium dioxide, nano zinc borate, magnesium hydroxide, talcum powder, attapulgite, white corundum micropowder, carbon fluoride, sodium persulfate, alumina, aluminum tripolyphosphate, nano barium sulfate, fluorosilicone oil, sodium molybdate, xylene, propylene glycol, an organic silicon defoamer, a dispersing agent, a titanate coupling agent NDZ-201, a wetting agent and water. The paint for building interior walls provided by the invention has excellent waterproof and stain resistant performance.
Description
Technical field
The present invention relates to paint field, particularly relate to a kind of inner wall of building water-proof stain-resistant coating.
Background technology
Along with the development of building industry, the demand of coating grows with each passing day.Coating is a kind of material, this material
Can be coated in object surface by different construction technologies, formed and adhere to firmly, there is some strength, company
Continuous solid film, the film so formed common name film, also known as paint film or coating.Object cruelly leak air it
In, by the erosion of oxygen, moisture etc., easily causing corrosion of metal, foxiness, cement elegance and talent etc. is broken
Bad phenomenon, demand when the waterproof and anti-pollution characteristic of existing building interior wall coating all cannot meet actually used,
Therefore need that exploitation is a kind of has the excellent waterproof and inner wall of building coating of anti-pollution characteristic badly.
Summary of the invention
For solving technical problem present in background technology, the present invention proposes a kind of inner wall of building water-proof stain-resistant
Coating, has the waterproof and anti-pollution characteristic of excellence.
A kind of inner wall of building water-proof stain-resistant coating that the present invention proposes, its raw material includes by weight: modified
Acrylic emulsion 80-120 part, Hydroxypropyl methacrylate 30-50 part, DOTP 10-30
Part, nano titanium oxide 2-8 part, nano-zinc borate 3-5 part, magnesium hydroxide 3-9 part, Pulvis Talci 2-6
Part, attapulgite 4-8 part, white fused alumina micropowder 6-12 part, perfluorocarbon 3-5 part, sodium peroxydisulfate 2-4 part,
Aluminium oxide 3-5 part, aluminium triphosphate 1-5 part, nano barium sulfate 2-6 part, fluorosilicon oil 1-3 part, molybdic acid
Sodium 1-5 part, dimethylbenzene 3-6 part, propylene glycol 3-8 part, organic silicon defoamer 1-3 part, dispersant 2-4
Part, titanate coupling agent NDZ-201 3-5 part, wetting agent 2-5 part, water 16-23 part.
Preferably, the raw material of modified acrylic acid emulsion includes by weight: butyl acrylate 3-9 part, methyl
Acrylic acid 2-5 part, hydroxyethyl methylacrylate 1-4 part, styrene 2-5 part, N hydroxymethyl acrylamide
3-6 part, octamethylcy-clotetrasiloxane 1-5 part, vinyltrimethoxy silane 2-4 part, sodium bicarbonate 3-6
Part, deionized water 1-7 part, Ammonium persulfate. 2-8 part, anhydrous calcium chloride 2-5 part, ammonia 1-5 part.
Preferably, modified acrylic acid emulsion is prepared by following technique: by butyl acrylate, metering system
Acid, hydroxyethyl methylacrylate, styrene, N hydroxymethyl acrylamide, octamethylcy-clotetrasiloxane and second
Thiazolinyl trimethoxy silane mix homogeneously obtains material a；Sodium bicarbonate, ammonia and deionized water are mixed to get
Material b；Being added drop-wise in material b by material a, dropping limit, limit is stirred, and after completion of dropwise addition, continues stirring 10-20min
Obtain material c；Ammonium persulfate. and anhydrous calcium chloride are added in material c, is then warming up to 84-88 DEG C, protect
Temperature 1-3h, is cooled to room temperature and obtains modified acrylic acid emulsion.
Preferably, modified acrylic acid emulsion, Hydroxypropyl methacrylate, DOTP, fluorine silicon
Oil, sodium molybdate, dimethylbenzene, propylene glycol, organic silicon defoamer, dispersant, titanate coupling agent NDZ-201,
The weight ratio of wetting agent and water is 85-115:35-45:15-25:1.5-2.5:2-4:4-5:4-7:1.5-2.5:
2.5-3.5:3.5-4.5:3-4:17-22.
Preferably, modified acrylic acid emulsion, nano titanium oxide, nano-zinc borate, magnesium hydroxide, Talcum
Powder, attapulgite, white fused alumina micropowder, perfluorocarbon, sodium peroxydisulfate, aluminium oxide, aluminium triphosphate and nanometer
The weight ratio of barium sulfate is 85-115:3-7:3.5-4.5:4-8:3-5:5-7:7-11:3.5-4.5:
2.5-3.5:3.5-4.5:2-4:3-5.
Preferably, butyl acrylate, methacrylic acid, hydroxyethyl methylacrylate, styrene, N-hydroxyl first
Base acrylamide, octamethylcy-clotetrasiloxane, vinyltrimethoxy silane, Hydroxypropyl methacrylate,
The weight ratio of DOTP and fluorosilicon oil is 4-8:3-4:2-3:3-4:4-5:2-4:2.5-3.5:
35-45:15-25:1.5-2.5.
Preferably, its raw material includes by weight: modified acrylic acid emulsion 85-115 part, hydroxyethyl methacrylate
Propyl ester 35-45 part, DOTP 15-25 part, nano titanium oxide 3-7 part, nano boric acid
Zinc 3.5-4.5 part, magnesium hydroxide 4-8 part, Pulvis Talci 3-5 part, attapulgite 5-7 part, white fused alumina are micro-
Powder 8-10 part, perfluorocarbon 3.5-4.5 part, sodium peroxydisulfate 2.5-3.5 part, aluminium oxide 3.5-4.5 part, three
Poly aluminium phosphate 2-4 part, nano barium sulfate 3-5 part, fluorosilicon oil 1.5-2.5 part, sodium molybdate 2-4 part, two
Toluene 4-5 part, propylene glycol 4-7 part, organic silicon defoamer 1.5-2.5 part, dispersant 2.5-3.5 part,
Titanate coupling agent NDZ-201 3.5-4.5 part, wetting agent 3-4 part, water 17-22 part.
Preferably, its raw material includes by weight: modified acrylic acid emulsion 100 parts, methacrylic acid hydroxypropyl
Ester 40 parts, DOTP 20 parts, nano titanium oxide 5 parts, nano-zinc borate 4 parts, hydrogen
Magnesium oxide 6 parts, Pulvis Talci 4 parts, attapulgite 6 parts, white fused alumina micropowder 8 parts, perfluorocarbon 4 parts, mistake
3 parts of sodium sulfate, aluminium oxide 4 parts, aluminium triphosphate 3 parts, nano barium sulfate 4 parts, fluorosilicon oil 2 parts,
Sodium molybdate 3 parts, dimethylbenzene 4.5 parts, propylene glycol 5.5 parts, organic silicon defoamer 2 parts, dispersant 3 parts,
Titanate coupling agent NDZ-201 4 parts, wetting agent 3.5 parts, 14.5 parts of water.
Heretofore described inner wall of building water-proof stain-resistant coating can be according to conventional Paint preparation technology system
For forming.
A kind of inner wall of building water-proof stain-resistant coating of the present invention, its raw material includes modified acrylic acid emulsion, first
Base Hydroxypropyl acrylate, DOTP, nano titanium oxide, nano-zinc borate, magnesium hydroxide,
Pulvis Talci, attapulgite, white fused alumina micropowder, perfluorocarbon, sodium peroxydisulfate, aluminium oxide, aluminium triphosphate,
Nano barium sulfate, fluorosilicon oil, sodium molybdate, dimethylbenzene, propylene glycol, organic silicon defoamer, dispersant, titanium
Acid esters coupling agent NDZ-201, wetting agent and water, with modified acrylic acid emulsion, Hydroxypropyl methacrylate and right
Dioctyl phthalate as film forming matter, and add nano titanium oxide, nano-zinc borate, magnesium hydroxide,
Pulvis Talci, attapulgite, white fused alumina micropowder, perfluorocarbon, sodium peroxydisulfate, aluminium oxide, aluminium triphosphate and
Nano barium sulfate as filler, with fluorosilicon oil, sodium molybdate, dimethylbenzene, propylene glycol, organic silicon defoamer,
Dispersant, titanate coupling agent NDZ-201, wetting agent and water are as auxiliary agent, conservative control proportioning, filler pair
The strengthening action of major ingredient modified acrylic acid emulsion, is effectively increased anti-wear performance and the water proofing property of acrylic emulsion
Can, film forming matter is coordinated by auxiliary agent, is effectively increased the combination property of coating of the present invention so that the present invention's
Coating has fire-retardant, waterproof, the resistant energy excellent properties of excellence；The modified acrylic acid emulsion added is with propylene
Acid butyl ester, methacrylic acid, hydroxyethyl methylacrylate, styrene, N hydroxymethyl acrylamide, eight first
Basic ring tetrasiloxane, vinyltrimethoxy silane, sodium bicarbonate, deionized water, Ammonium persulfate., anhydrous
Calcium chloride and ammonia, wherein the final performance of emulsion is had key as the main body of polymer, its proportioning by monomer
Effect.Butyl acrylate, styrene, hydroxyethyl methylacrylate are main monomer, have been simultaneously introduced functional
Monomer methacrylic acid and N hydroxymethyl acrylamide, conservative control proportioning, it is effectively increased the film forming of emulsion
Performance；And use octamethylcy-clotetrasiloxane and vinyltrimethoxy silane monomer to be modified, rationally
Control proportioning, be effectively increased the water proofing property of modified acrylic acid emulsion, further increase coating of the present invention
Water resistance；And add emulsifying agent sodium bicarbonate, Ammonium persulfate., anhydrous calcium chloride and ammonia so that modified
After acrylic emulsion viscosity reduce, good stability, there is relatively low water absorption rate, further increase this
The water resistance of bright coating.
Carrying out performance detection to inventing described inner wall of building water-proof stain-resistant coating, testing result is as shown in the table:
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail, it should be appreciated that embodiment is served only for
The bright present invention rather than be used for limiting the invention, any made on the basis of the present invention amendment,
Equivalents etc. are the most within the scope of the present invention.
In detailed description of the invention, the weight portion of modified acrylic acid emulsion can be 80 parts, 85 parts, 90 parts,
95 parts, 100 parts, 105 parts, 110 parts, 115 parts, 120 parts；The weight portion of Hydroxypropyl methacrylate
Can be 30 parts, 31 parts, 32 parts, 33 parts, 34 parts, 35 parts, 36 parts, 37 parts, 38 parts, 39 parts,
40 parts, 41 parts, 42 parts, 43 parts, 44 parts, 45 parts, 46 parts, 47 parts, 48 parts, 49 parts, 50 parts；
The weight portion of DOTP can be 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts,
16 parts, 17 parts, 18 parts, 19 parts, 20 parts, 21 parts, 22 parts, 23 parts, 24 parts, 25 parts, 26 parts,
27 parts, 28 parts, 29 parts, 30 parts；The weight portion of nano titanium oxide can be 2 parts, 3 parts, 4 parts,
5 parts, 6 parts, 7 parts, 8 parts；The weight portion of nano-zinc borate can be 3 parts, 3.5 parts, 4 parts, 4.5
Part, 5 parts；The weight portion of magnesium hydroxide can be 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts；
Talcous weight portion can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts；The weight portion of attapulgite is permissible
It it is 4 parts, 5 parts, 6 parts, 7 parts, 8 parts；The weight portion of white fused alumina micropowder can be 6 parts, 7 parts, 8 parts,
9 parts, 10 parts, 11 parts, 12 parts；The weight portion of perfluorocarbon can be 3 parts, 3.5 parts, 4 parts, 4.5 parts,
5 parts；The weight portion of sodium peroxydisulfate can be 2 parts, 2.5 parts, 3.0 parts, 3.5 parts, 4 parts；Aluminium oxide
Weight portion can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The weight portion of aluminium triphosphate can be 1
Part, 2 parts, 3 parts, 4 parts, 5 parts；The weight portion of nano barium sulfate can be 2 parts, 3 parts, 4 parts, 5
Part, 6 parts；The weight portion of fluorosilicon oil can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts；Sodium molybdate
Weight portion can be 1 part, 2 parts, 3 parts, 4 parts, 5 parts；The weight portion of dimethylbenzene can be 3 parts, 3.5
Part, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The weight portion of propylene glycol can be 3 parts, 3.5 parts,
4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts；Organic silicon defoamer
Weight portion can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts；The weight portion of dispersant can be 2
Part, 2.5 parts, 3 parts, 3.5 parts, 4 parts；The weight portion of titanate coupling agent NDZ-201 can be 3 parts,
3.5 parts, 4 parts, 4.5 parts, 5 parts；The weight portion of wetting agent can be 2 parts, 2.5 parts, 3 parts, 3.5
Part, 4 parts, 4.5 parts, 5 parts；The weight portion of water can be 16 parts, 16.5 parts, 17 parts, 17.5 parts,
18 parts, 18.5 parts, 19 parts, 19.5 parts, 20 parts, 20.5 parts, 21 parts, 21.5 parts, 22 parts, 22.5
Part, 23 parts.
Embodiment 1
A kind of inner wall of building water-proof stain-resistant coating that the present invention proposes, its raw material includes by weight: modified
Acrylic emulsion 100 parts, Hydroxypropyl methacrylate 40 parts, DOTP 20 parts, nanometer
Titanium dioxide 5 parts, nano-zinc borate 4 parts, 6 parts of magnesium hydroxide, Pulvis Talci 4 parts, attapulgite 6 parts,
White fused alumina micropowder 8 parts, perfluorocarbon 4 parts, sodium peroxydisulfate 3 parts, aluminium oxide 4 parts, aluminium triphosphate 3 parts,
Nano barium sulfate 4 parts, fluorosilicon oil 2 parts, sodium molybdate 3 parts, dimethylbenzene 4.5 parts, propylene glycol 5.5 parts,
Organic silicon defoamer 2 parts, dispersant 3 parts, titanate coupling agent NDZ-201 4 parts, wetting agent 3.5 parts,
14.5 parts of water.
Modified acrylic acid emulsion is prepared by following technique: by weight by 6 parts of butyl acrylate, 3.5 parts
Methacrylic acid, 2.5 parts of hydroxyethyl methylacrylates, 3.5 parts of styrene, 4.5 parts of N-methylol acryloyls
Amine, 3 parts of octamethylcy-clotetrasiloxanes and 3 parts of vinyltrimethoxy silane mix homogeneously obtain material a；Will
4.5 parts of sodium bicarbonate, 3 parts of ammonia and 4 parts of deionized waters are mixed to get material b；Material a is added drop-wise to thing
In material b, dropping limit, limit is stirred, and after completion of dropwise addition, continues stirring 15min and obtains material c；By 5 parts of over cures
Acid ammonium and 3.5 parts of anhydrous calcium chlorides add in material c, are then warming up to 86 DEG C, are incubated 2h, are cooled to room
Temperature obtains modified acrylic acid emulsion.
Embodiment 2
A kind of inner wall of building water-proof stain-resistant coating that the present invention proposes, its raw material includes by weight: modified
Acrylic emulsion 80 parts, Hydroxypropyl methacrylate 50 parts, DOTP 10 parts, nanometer two
Titanium oxide 8 parts, nano-zinc borate 3 parts, 9 parts of magnesium hydroxide, Pulvis Talci 2 parts, attapulgite 8 parts,
White fused alumina micropowder 6 parts, perfluorocarbon 5 parts, sodium peroxydisulfate 2 parts, aluminium oxide 5 parts, aluminium triphosphate 1 part,
Nano barium sulfate 6 parts, fluorosilicon oil 1 part, sodium molybdate 5 parts, dimethylbenzene 3 parts, propylene glycol 8 parts, organic
Silicon defoaming agent 1 part, dispersant 4 parts, titanate coupling agent NDZ-201 3 parts, wetting agent 5 parts, water 16
Part.
Modified acrylic acid emulsion is prepared by following technique: by weight by 3 parts of butyl acrylate, 5 parts of first
Base acrylic acid, 1 part of hydroxyethyl methylacrylate, 5 parts of styrene, 3 parts of N hydroxymethyl acrylamides, 5 parts
Octamethylcy-clotetrasiloxane and 2 parts of vinyltrimethoxy silane mix homogeneously obtain material a；By 6 parts of carbonic acid
Hydrogen sodium, 1 part of ammonia and 7 parts of deionized waters are mixed to get material b；Material a is added drop-wise in material b, limit
The stirring of dropping limit, after completion of dropwise addition, continues stirring 10min and obtains material c；By 8 parts of Ammonium persulfate .s and 2 parts
Anhydrous calcium chloride adds in material c, is then warming up to 88 DEG C, is incubated 1h, is cooled to room temperature and obtains modified third
Olefin(e) acid emulsion.
Embodiment 3
A kind of inner wall of building water-proof stain-resistant coating that the present invention proposes, its raw material includes by weight: modified
Acrylic emulsion 120 parts, Hydroxypropyl methacrylate 30 parts, DOTP 30 parts, nanometer
Titanium dioxide 2 parts, nano-zinc borate 5 parts, 3 parts of magnesium hydroxide, Pulvis Talci 6 parts, attapulgite 4 parts,
White fused alumina micropowder 12 parts, perfluorocarbon 3 parts, sodium peroxydisulfate 4 parts, aluminium oxide 3 parts, aluminium triphosphate 5 parts,
Nano barium sulfate 2 parts, fluorosilicon oil 3 parts, sodium molybdate 1 part, dimethylbenzene 6 parts, propylene glycol 3 parts, organic
Silicon defoaming agent 3 parts, dispersant 2 parts, titanate coupling agent NDZ-201 5 parts, wetting agent 2 parts, water 23
Part.
Modified acrylic acid emulsion is prepared by following technique: by weight by 9 parts of butyl acrylate, 2 parts of first
Base acrylic acid, 4 parts of hydroxyethyl methylacrylates, 2 parts of styrene, 6 parts of N hydroxymethyl acrylamides, 1 part
Octamethylcy-clotetrasiloxane and 4 parts of vinyltrimethoxy silane mix homogeneously obtain material a；By 3 parts of carbonic acid
Hydrogen sodium, 5 parts of ammonia and 1 part of deionized water are mixed to get material b；Material a is added drop-wise in material b, limit
The stirring of dropping limit, after completion of dropwise addition, continues stirring 20min and obtains material c；By 2 parts of Ammonium persulfate .s and 5 parts
Anhydrous calcium chloride adds in material c, is then warming up to 84 DEG C, is incubated 3h, is cooled to room temperature and obtains modified third
Olefin(e) acid emulsion.
Embodiment 4
A kind of inner wall of building water-proof stain-resistant coating that the present invention proposes, its raw material includes by weight: modified
Acrylic emulsion 85 parts, Hydroxypropyl methacrylate 45 parts, DOTP 15 parts, nanometer two
Titanium oxide 7 parts, nano-zinc borate 3.5 parts, 8 parts of magnesium hydroxide, Pulvis Talci 3 parts, attapulgite 7 parts,
White fused alumina micropowder 8 parts, perfluorocarbon 4.5 parts, sodium peroxydisulfate 2.5 parts, aluminium oxide 4.5 parts, tripolyphosphate
2 parts of aluminum, nano barium sulfate 5 parts, fluorosilicon oil 1.5 parts, sodium molybdate 4 parts, dimethylbenzene 4 parts, propylene glycol 7
Part, organic silicon defoamer 1.5 parts, dispersant 3.5 parts, titanate coupling agent NDZ-201 3.5 parts, wet
Profit agent 4 parts, 17 parts of water.
Modified acrylic acid emulsion is prepared by following technique: by weight by 4 parts of butyl acrylate, 4 parts of first
Base acrylic acid, 2 parts of hydroxyethyl methylacrylates, 4 parts of styrene, 4 parts of N hydroxymethyl acrylamides, 4 parts
Octamethylcy-clotetrasiloxane and 2.5 parts of vinyltrimethoxy silane mix homogeneously obtain material a；By 5 parts of carbon
Acid hydrogen sodium, 2 parts of ammonia and 6 parts of deionized waters are mixed to get material b；Material a is added drop-wise in material b,
Dropping limit, limit is stirred, and after completion of dropwise addition, continues stirring 12min and obtains material c；By 7 parts of Ammonium persulfate .s and 3
Part anhydrous calcium chloride adds in material c, is then warming up to 87 DEG C, is incubated 1.5h, is cooled to room temperature and is changed
Property acrylic emulsion.
Embodiment 5
A kind of inner wall of building water-proof stain-resistant coating that the present invention proposes, its raw material includes by weight: modified
Acrylic emulsion 115 parts, Hydroxypropyl methacrylate 35 parts, DOTP 25 parts, nanometer
Titanium dioxide 3 parts, nano-zinc borate 4.5 parts, 4 parts of magnesium hydroxide, Pulvis Talci 5 parts, attapulgite 5
Part, white fused alumina micropowder 10 parts, perfluorocarbon 3.5 parts, sodium peroxydisulfate 3.5 parts, aluminium oxide 3.5 parts, trimerization
Aluminum phosphate 4 parts, nano barium sulfate 3 parts, fluorosilicon oil 2.5 parts, sodium molybdate 2 parts, dimethylbenzene 5 parts, third
Glycol 4 parts, organic silicon defoamer 2.5 parts, dispersant 2.5 parts, titanate coupling agent NDZ-201 4.5
Part, wetting agent 3 parts, 22 parts of water.
Modified acrylic acid emulsion is prepared by following technique: by weight by 8 parts of butyl acrylate, 3 parts of first
Base acrylic acid, 3 parts of hydroxyethyl methylacrylates, 3 parts of styrene, 5 parts of N hydroxymethyl acrylamides, 2 parts
Octamethylcy-clotetrasiloxane and 3.5 parts of vinyltrimethoxy silane mix homogeneously obtain material a；By 4 parts of carbon
Acid hydrogen sodium, 4 parts of ammonia and 2 parts of deionized waters are mixed to get material b；Material a is added drop-wise in material b,
Dropping limit, limit is stirred, and after completion of dropwise addition, continues stirring 18min and obtains material c；By 3 parts of Ammonium persulfate .s and 4
Part anhydrous calcium chloride adds in material c, is then warming up to 85 DEG C, is incubated 2.5h, is cooled to room temperature and is changed
Property acrylic emulsion.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention not office
Being limited to this, any those familiar with the art is in the technical scope that the invention discloses, according to this
The technical scheme of invention and inventive concept thereof in addition equivalent or change, all should contain the protection in the present invention
Within the scope of.
Claims (8)
1. an inner wall of building water-proof stain-resistant coating, it is characterised in that its raw material includes by weight: change
Property acrylic emulsion 80-120 part, Hydroxypropyl methacrylate 30-50 part, DOTP 10-30
Part, nano titanium oxide 2-8 part, nano-zinc borate 3-5 part, magnesium hydroxide 3-9 part, Pulvis Talci 2-6
Part, attapulgite 4-8 part, white fused alumina micropowder 6-12 part, perfluorocarbon 3-5 part, sodium peroxydisulfate 2-4 part,
Aluminium oxide 3-5 part, aluminium triphosphate 1-5 part, nano barium sulfate 2-6 part, fluorosilicon oil 1-3 part, molybdic acid
Sodium 1-5 part, dimethylbenzene 3-6 part, propylene glycol 3-8 part, organic silicon defoamer 1-3 part, dispersant 2-4
Part, titanate coupling agent NDZ-201 3-5 part, wetting agent 2-5 part, water 16-23 part.
Inner wall of building water-proof stain-resistant coating the most according to claim 1, it is characterised in that modified third
The raw material of olefin(e) acid emulsion includes by weight: butyl acrylate 3-9 part, methacrylic acid 2-5 part, methyl
2-(Acryloyloxy)ethanol 1-4 part, styrene 2-5 part, N hydroxymethyl acrylamide 3-6 part, prestox ring four
Siloxanes 1-5 part, vinyltrimethoxy silane 2-4 part, sodium bicarbonate 3-6 part, deionized water 1-7
Part, Ammonium persulfate. 2-8 part, anhydrous calcium chloride 2-5 part, ammonia 1-5 part.
Inner wall of building water-proof stain-resistant coating the most according to claim 1 and 2, it is characterised in that change
Property acrylic emulsion is prepared by following technique: by butyl acrylate, methacrylic acid, methacrylic acid
Hydroxyl ethyl ester, styrene, N hydroxymethyl acrylamide, octamethylcy-clotetrasiloxane and vinyl trimethoxy silicon
Alkane mix homogeneously obtains material a；Sodium bicarbonate, ammonia and deionized water are mixed to get material b；By material
A is added drop-wise in material b, and dropping limit, limit is stirred, and after completion of dropwise addition, continues stirring 10-20min and obtains material
c；Ammonium persulfate. and anhydrous calcium chloride are added in material c, are then warming up to 84-88 DEG C, be incubated 1-3h,
It is cooled to room temperature and obtains modified acrylic acid emulsion.
4. according to the inner wall of building water-proof stain-resistant coating described in any one of claim 1-3, it is characterised in that
Modified acrylic acid emulsion, Hydroxypropyl methacrylate, DOTP, fluorosilicon oil, sodium molybdate,
Dimethylbenzene, propylene glycol, organic silicon defoamer, dispersant, titanate coupling agent NDZ-201, wetting agent and
The weight ratio of water is 85-115:35-45:15-25:1.5-2.5:2-4:4-5:4-7:1.5-2.5:
2.5-3.5:3.5-4.5:3-4:17-22.
5. according to the inner wall of building water-proof stain-resistant coating described in any one of claim 1-4, it is characterised in that
Modified acrylic acid emulsion, nano titanium oxide, nano-zinc borate, magnesium hydroxide, Pulvis Talci, attapulgite,
The weight ratio of white fused alumina micropowder, perfluorocarbon, sodium peroxydisulfate, aluminium oxide, aluminium triphosphate and nano barium sulfate
For 85-115:3-7:3.5-4.5:4-8:3-5:5-7:7-11:3.5-4.5:2.5-3.5:3.5-4.5:
2-4:3-5.
6. according to the inner wall of building water-proof stain-resistant coating described in any one of claim 1-5, it is characterised in that
Butyl acrylate, methacrylic acid, hydroxyethyl methylacrylate, styrene, N hydroxymethyl acrylamide,
Octamethylcy-clotetrasiloxane, vinyltrimethoxy silane, Hydroxypropyl methacrylate, p-phthalic acid two
The weight ratio of monooctyl ester and fluorosilicon oil is 4-8:3-4:2-3:3-4:4-5:2-4:2.5-3.5:35-45:
15-25:1.5-2.5.
7. according to the inner wall of building water-proof stain-resistant coating described in any one of claim 1-6, it is characterised in that
Its raw material includes by weight: modified acrylic acid emulsion 85-115 part, Hydroxypropyl methacrylate 35-45 part,
DOTP 15-25 part, nano titanium oxide 3-7 part, nano-zinc borate 3.5-4.5 part,
Magnesium hydroxide 4-8 part, Pulvis Talci 3-5 part, attapulgite 5-7 part, white fused alumina micropowder 8-10 part, fluorination
Carbon 3.5-4.5 part, sodium peroxydisulfate 2.5-3.5 part, aluminium oxide 3.5-4.5 part, aluminium triphosphate 2-4 part,
Nano barium sulfate 3-5 part, fluorosilicon oil 1.5-2.5 part, sodium molybdate 2-4 part, dimethylbenzene 4-5 part, the third two
Alcohol 4-7 part, organic silicon defoamer 1.5-2.5 part, dispersant 2.5-3.5 part, titanate coupling agent NDZ-201
3.5-4.5 part, wetting agent 3-4 part, water 17-22 part.
8. according to the inner wall of building water-proof stain-resistant coating described in any one of claim 1-7, it is characterised in that
Its raw material includes by weight: modified acrylic acid emulsion 100 parts, Hydroxypropyl methacrylate 40 parts, to benzene
Dioctyl phthalate dioctyl ester 20 parts, nano titanium oxide 5 parts, nano-zinc borate 4 parts, 6 parts of magnesium hydroxide, cunning
Stone powder 4 parts, attapulgite 6 parts, white fused alumina micropowder 8 parts, perfluorocarbon 4 parts, sodium peroxydisulfate 3 parts, oxygen
Change 4 parts of aluminum, aluminium triphosphate 3 parts, nano barium sulfate 4 parts, fluorosilicon oil 2 parts, sodium molybdate 3 parts, two
Toluene 4.5 parts, propylene glycol 5.5 parts, organic silicon defoamer 2 parts, dispersant 3 parts, titanate coupling agent
NDZ-201 4 parts, wetting agent 3.5 parts, 14.5 parts of water.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610294708.1A CN105949841A (en) | 2016-05-03 | 2016-05-03 | Waterproof and stain resistant paint for building interior walls |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610294708.1A CN105949841A (en) | 2016-05-03 | 2016-05-03 | Waterproof and stain resistant paint for building interior walls |
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| CN201610294708.1A Pending CN105949841A (en) | 2016-05-03 | 2016-05-03 | Waterproof and stain resistant paint for building interior walls |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106820812A (en) * | 2016-12-22 | 2017-06-13 | 安徽三农草制品有限公司 | A kind of health care straw mat for strengthening immunologic function with fire-proof and water-proof |
| CN107641353A (en) * | 2017-11-02 | 2018-01-30 | 叠彩区千牛起重设备经营部 | One kind can scribble interior wall coating |
| CN107711035A (en) * | 2017-08-31 | 2018-02-23 | 兰溪市奥而特农业科技有限公司 | Energy-efficient water chestnut harvester |
| CN110066597A (en) * | 2017-10-17 | 2019-07-30 | 中国科学院宁波材料技术与工程研究所 | A kind of dedicated silicone hydrogels antifouling paint of fishing gear, its preparation method and application |
| CN111363428A (en) * | 2020-03-23 | 2020-07-03 | 苏州鼎奕通材料科技有限公司 | Fingerprint-preventing and pollution-preventing environment-friendly coating and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102453412A (en) * | 2010-10-29 | 2012-05-16 | 徐贵才 | Antifouling latex paint for inner wall and production process thereof |
| CN104610828A (en) * | 2014-12-25 | 2015-05-13 | 三棵树涂料股份有限公司 | Double-function aqueous emulsion paint and preparation method thereof |
| CN105255283A (en) * | 2015-11-05 | 2016-01-20 | 苏州明轩地坪涂料有限公司 | Latex paint for interior walls |
-
2016
- 2016-05-03 CN CN201610294708.1A patent/CN105949841A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102453412A (en) * | 2010-10-29 | 2012-05-16 | 徐贵才 | Antifouling latex paint for inner wall and production process thereof |
| CN104610828A (en) * | 2014-12-25 | 2015-05-13 | 三棵树涂料股份有限公司 | Double-function aqueous emulsion paint and preparation method thereof |
| CN105255283A (en) * | 2015-11-05 | 2016-01-20 | 苏州明轩地坪涂料有限公司 | Latex paint for interior walls |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106820812A (en) * | 2016-12-22 | 2017-06-13 | 安徽三农草制品有限公司 | A kind of health care straw mat for strengthening immunologic function with fire-proof and water-proof |
| CN107711035A (en) * | 2017-08-31 | 2018-02-23 | 兰溪市奥而特农业科技有限公司 | Energy-efficient water chestnut harvester |
| CN110066597A (en) * | 2017-10-17 | 2019-07-30 | 中国科学院宁波材料技术与工程研究所 | A kind of dedicated silicone hydrogels antifouling paint of fishing gear, its preparation method and application |
| CN107641353A (en) * | 2017-11-02 | 2018-01-30 | 叠彩区千牛起重设备经营部 | One kind can scribble interior wall coating |
| CN111363428A (en) * | 2020-03-23 | 2020-07-03 | 苏州鼎奕通材料科技有限公司 | Fingerprint-preventing and pollution-preventing environment-friendly coating and preparation method thereof |
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Application publication date: 20160921 |