CN109610184A - A kind of organic silicon cloth of waterproof antiwear and processing technology - Google Patents
A kind of organic silicon cloth of waterproof antiwear and processing technology Download PDFInfo
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- CN109610184A CN109610184A CN201811537139.4A CN201811537139A CN109610184A CN 109610184 A CN109610184 A CN 109610184A CN 201811537139 A CN201811537139 A CN 201811537139A CN 109610184 A CN109610184 A CN 109610184A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/18—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials
- D06N3/183—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials the layers are one next to the other
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/007—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by mechanical or physical treatments
- D06N3/0077—Embossing; Pressing of the surface; Tumbling and crumbling; Cracking; Cooling; Heating, e.g. mirror finish
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0086—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0086—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
- D06N3/0088—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/10—Properties of the materials having mechanical properties
- D06N2209/105—Resistant to abrasion, scratch
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention relates to silicon cloth technical fields, more particularly to a kind of organic silicon cloth of waterproof antiwear and processing technology, including base fabric, waterproof layer, adhesive layer and wearing layer are successively coated in the base fabric from inside to outside, the waterproof layer and wearing layer are made of organic siliconresin and adjuvant material, and the waterproof layer is vinyl polysiloxane waterproof layer, the wearing layer is hexenyl silicone resin wearing layer;And its processing technology includes: the preparation of (1) waterproof layer;(2) prepared by adhesive layer;(3) prepared by wearing layer;(4) solidify.Organic silicon cloth is made with excellent waterproof antiwear performance in the present invention.
Description
Technical field
The present invention relates to silicon cloth technical fields, and in particular to a kind of organic silicon cloth of waterproof antiwear and processing technology.
Background technique
Organic silicon cloth has a wide range of applications in daily life, can be used for keeping out wind and rain, and protects the effect of article, still
During use but there is waterproof performance deficiency, the poor problem of wearability affects organic existing organic silicon cloth
The using effect of silicon cloth shortens its service life.
Therefore, the waterproof antiwear performance for how improving organic silicon cloth is current urgent problem.
(application number: a kind of waterproof, wear-resisting Compound Fabric and its preparation side 201610160590.3) are disclosed in Chinese patent
Method, above-mentioned waterproof, wear-resisting Compound Fabric, including base, composite layer;The base is by nylon 45wt%-55wt%, carboxymethyl cellulose
20wt%-30wt%, cotton fiber 15wt%-20wt% and flax fiber 5wt%-10wt% longitude and latitude are interwoven;Wherein, warp is nylon
Manufactured yarn, weft are carboxymethyl cellulose, cotton fiber and the blended manufactured yarn of flax fiber;The composite layer passes through heat
Pressure mode is respectively overlay in the upper and lower surfaces of the base.Compound Fabric, which is made, has certain waterproof, abrasion resistant effect, but
Its composite layer with waterproof antiwear is in outer layer, and so in use, the material with water-proof function is due to rubbing, scraping
Cause waterproof performance to decline, and then influences the waterproof of Compound Fabric, wear-resisting property.
Summary of the invention
In view of the above-mentioned analysis to the prior art, the present invention provides a kind of organic silicon cloth of waterproof antiwear and processing technology, system
Obtaining organic silicon cloth has excellent waterproof antiwear performance.
In order to achieve the above object, the present invention is achieved through the following technical solutions:
A kind of organic silicon cloth of waterproof antiwear, including base fabric, be successively coated in the base fabric from inside to outside waterproof layer, adhesive layer and
Wearing layer, the waterproof layer and wearing layer are made of organic siliconresin and adjuvant material.
Preferably, the waterproof layer is vinyl polysiloxane waterproof layer, it is formulated by the raw material of following parts by weight:
55-65 parts of vinyl polysiloxane;
2.5-4.5 parts of polyvinyl alcohol;
2-5 parts of microcrystalline cellulose;
Palm wax 2-4;
5-12 parts of Emulsifier EL-60;
8-15 parts of repefral;
1-3 parts of stearic acid;
0.3-0.5 parts of detergent alkylate sodium sulfonate;
1-2 parts of silane coupling agent;
0.5-1.5 parts of nano diatomite.
Preferably, the wearing layer is hexenyl silicone resin wearing layer, it is formulated by the raw material of following parts by weight:
60-70 parts of hexenyl silicone resin;
Polyamide/3-5 parts of metal quantum point material;
1-3 parts of modified Nano schmigel;
2-5 parts of sulphur;
774 5-10 parts of carbon black;
15-25 parts of carbon black N660;
1-3 parts of trioctyl trimellitate (TOTM);
3-6 parts of antimony oxide;
1-2 parts of phenyl phosphate 2-glycidyl ester;
0.5-1.5 parts of steel fibre.
Preferably, the polyamide/metal quantum point material preparation method is as follows:
(1) polyamide modified: by polyaniline ultrasonic disperse in nitration mixture, the concentration of polyamide is 1-4mg/mL, is heated to 65 DEG C
And constant temperature stirs 2h, then is washed to neutrality with distillation, dries 18h under the conditions of 55 DEG C in an oven, obtains modified polyamide;
(2) modified polyamide is sent into kneading machine, melting temperature is 130 DEG C, after being kneaded 5-10min, will account for modified polyamide
The metal quantum point of gross mass 1/10 is added in kneading machine, is kneaded 4min, discharge together;
(3) the mixture cooled to room temperature that upper step is discharged, and be sent in electron beam irradiation, in 0.8-0.9MeV
Irradiation energy under react 35-45min to get polyamide/metal quantum point composite material.
Preferably, the preparation method of the modified Nano schmigel includes:
It (1) is that 300nm corundum powder is added in dioxane solvent by granularity, the ultrasound 2.5h under 30KHz frequency forms corundum
Micro mist dispersion;
(2) diacid chloride is added in the corundum powder dispersion, and under nitrogen protection, under 150rpm revolving speed, electromagnetic agitation
5-10min forms uniformly mixed suspension;
(3) silane coupling agent is in suspension added described, stirs evenly, react 50min, filter, wash, being drying to obtain modified receive
Rice schmigel.
Preferably, the adhesive layer is phenolic resin and the phenoxy resin compound of 3:1 in mass ratio.
Preferably, the present invention also provides the processing technologys of the organic silicon cloth of above-mentioned waterproof antiwear, comprising the following steps:
(1) prepared by waterproof layer: weighing vinyl polysiloxane in proportion, crushes, sieve with 100 mesh sieve, be placed in dispersion tank, to dispersion tank
Middle polyvinyl alcohol, the quality of being added is 10 times of polyvinyl alcohol of deionized water, with the warming while stirring of 350rpm speed to 70 DEG C, so
After add microcrystalline cellulose, palm wax, Emulsifier EL-60, detergent alkylate sodium sulfonate, nano diatomite, silane coupling agent
And repefral, 50min is dispersed at 85 DEG C, is ground, is obtained waterproofing agent, waterproofing agent is coated in base fabric, is dried
It is dry, solidify to get the base fabric containing waterproof layer;
(2) prepared by adhesive layer, and the phenolic resin for forming adhesive layer and phenoxy resin are mixed by weight 3:1, reheat fusing,
Resin solution is obtained, the waterproof layer that then step (1) obtains is impregnated into resin solution, is impregnated with resin solution in waterproof layer
In, then the waterproof layer for being soaked with resin liquid is put into 150-180 DEG C of drying box and is dried, solidifies, is obtained containing adhesive layer
Base fabric;
(4) prepared by wearing layer: weighing hexenyl silicone resin in proportion, crushes, crosses 80 meshes, be placed in dispersion tank, and to dispersion
Phenyl phosphate 2-glycidyl ester and quality are added in tank as 15 times of phenyl phosphate 2-glycidyl ester of deionized water, stirring is equal
It is even, and after mixed solution is risen to 90 DEG C, polyamide/metal quantum point material is added, after stirring 10min, adds modification and receives
Rice schmigel, carbon black 774, carbon black N660 and antimony trioxide, finally add sulphur, trioctyl trimellitate (TOTM) and steel fibre, stir
It mixes uniformly, obtains anti-wear agent, anti-wear agent is coated on adhesive layer, dry to get the base fabric containing wearing layer;
(5) solidify: the base fabric containing wearing layer made from step (4) is put into vulcanizing oven solidify it is resistance to get waterproof
Grind organic silicon cloth.
Preferably, condition of cure in the step (5) are as follows: temperature control is 120-140 DEG C, curing time 15-
20min。
Compared with prior art, the present invention have it is following the utility model has the advantages that
(1) waterproof layer is arranged in base fabric according to the use characteristic of organic silicon cloth by the present invention, and wearing layer is arranged in waterproof
On layer, and by the secure bond of adhesive layer realization waterproof layer and wearing layer, such setting can solve previous organosilicon deployment
The wear-resisting problem for being in outer layer and causing waterproof antiwear performance bad of water, the wearing layer that outer layer is arranged in can enhance organic silicon cloth
Wearability, and play a protective role to the waterproof layer of internal layer, to improve the waterproof effect of waterproof layer, pass through waterproof in this way
Layer, adhesive layer and wearing layer cooperation, so that organic silicon cloth obtained has excellent waterproof antiwear performance;
(2) waterproof layer of the invention is using vinyl polysiloxane as major ingredient, and is equipped with polyvinyl alcohol, microcrystalline cellulose, palm wax, polyoxy
Ethylene castor oil, detergent alkylate sodium sulfonate, nano diatomite, silane coupling agent and repefral, to be made
Waterproof layer compactness is good, and has preferable flexibility, wherein microcrystalline cellulose, which is added, can be improved waterproof layer tear resistance, into
And improve the waterproof effect of waterproof layer, and the addition of palm wax and Emulsifier EL-60 improve it is compatible between each component
Property, the uniformity that each component disperses in waterproof layer is improved, and nano diatomite can be filled in vinylite gap, in turn
Improve the waterproof performance of waterproof layer;
(3) adhesive layer of the invention use phenolic resin and phenoxy resin, have preferable adhesive property, it can be achieved that waterproof layer with
Secure bond between wearing layer, and phenolic resin and phenoxy resin are good with having between apolar chain, with organic siliconresin
Compatibility so that waterproof layer of the invention is even closer in conjunction with wearing layer;
(4) wearing layer of the present invention is using hexenyl silicone resin as major ingredient, and is aided with polyamide/metal quantum point material, modified Nano
Schmigel, carbon black 774, carbon black N660, antimony trioxide, sulphur, trioctyl trimellitate (TOTM), steel fibre and phenyl phosphate two shrink sweet
Grease, by the coordinated of above-mentioned material, it can be achieved that preferable wear-resisting property, wherein the polyamide of addition/metal quantum point
Material have tridimensional network, can by modified Nano schmigel, carbon black 774, carbon black N660 and antimony trioxide coat wherein, from
And the wear-resisting property of wearing layer is improved, and hexenyl silicone resin can will have tridimensional network polyamide/metal quantum point material
Material is sticked together, to further increase the wear-resisting property of wearing layer.
Specific embodiment
Form by the following examples is described in further detail above content of the invention again, but should not be by this
The range for being interpreted as the above-mentioned theme of the present invention is only limitted to following embodiment, all technologies based on realization belonging to above content of the present invention
It all belongs to the scope of the present invention.
Embodiment 1
The organic silicon cloth of the waterproof antiwear of the present embodiment, including base fabric are successively coated with waterproof layer, viscous in the base fabric from inside to outside
Knot layer and wearing layer, the waterproof layer and wearing layer are made of organic siliconresin and adjuvant material.
Wherein, the waterproof layer is vinyl polysiloxane waterproof layer, is formulated by the raw material of following parts by weight:
55 parts of vinyl polysiloxane;
2.5 parts of polyvinyl alcohol;
2 parts of microcrystalline cellulose;
Palm wax 2;
5 parts of Emulsifier EL-60;
8 parts of repefral;
1 part of stearic acid;
0.3 part of detergent alkylate sodium sulfonate;
1 part of silane coupling agent;
0.5 part of nano diatomite.
Wherein, the wearing layer is hexenyl silicone resin wearing layer, is formulated by the raw material of following parts by weight:
60 parts of hexenyl silicone resin;
Polyamide/3 parts of material of metal quantum point;
1 part of modified Nano schmigel;
2 parts of sulphur;
774 5 parts of carbon black;
15 parts of carbon black N660;
1 part of trioctyl trimellitate (TOTM);
3 parts of antimony oxide;
1 part of phenyl phosphate 2-glycidyl ester;
0.5 part of steel fibre.
Wherein, the polyamide/metal quantum point material preparation method is as follows:
(1) polyamide modified: by polyaniline ultrasonic disperse in nitration mixture, the concentration of polyamide is 1mg/mL, is heated to 65 DEG C simultaneously
Constant temperature stirs 2h, then is washed to neutrality with distillation, dries 18h under the conditions of 55 DEG C in an oven, obtains modified polyamide;
(2) modified polyamide is sent into kneading machine, melting temperature is 130 DEG C, after being kneaded 5min, will account for the total matter of modified polyamide
The metal quantum point of amount 1/10 is added in kneading machine, is kneaded 4min, discharge together;
(3) the mixture cooled to room temperature that upper step is discharged, and be sent in electron beam irradiation, in the spoke of 0.8MeV
According to reaction 35min under energy to get polyamide/metal quantum point composite material.
Wherein, the preparation method of the modified Nano schmigel includes:
It (1) is that 300nm corundum powder is added in dioxane solvent by granularity, the ultrasound 2.5h under 30KHz frequency forms corundum
Micro mist dispersion;
(2) diacid chloride is added in the corundum powder dispersion, and under nitrogen protection, under 150rpm revolving speed, electromagnetic agitation
5min forms uniformly mixed suspension;
(3) silane coupling agent is in suspension added described, stirs evenly, react 50min, filter, wash, being drying to obtain modified receive
Rice schmigel.
Wherein, the adhesive layer is phenolic resin and the phenoxy resin compound of 3:1 in mass ratio.
Wherein, the present invention also provides the processing technologys of the organic silicon cloth of above-mentioned waterproof antiwear, comprising the following steps:
(1) prepared by waterproof layer: weighing vinyl polysiloxane in proportion, crushes, sieve with 100 mesh sieve, be placed in dispersion tank, to dispersion tank
Middle polyvinyl alcohol, the quality of being added is 10 times of polyvinyl alcohol of deionized water, with the warming while stirring of 350rpm speed to 70 DEG C, so
After add microcrystalline cellulose, palm wax, Emulsifier EL-60, detergent alkylate sodium sulfonate, nano diatomite, silane coupling agent
And repefral, 50min is dispersed at 85 DEG C, is ground, is obtained waterproofing agent, waterproofing agent is coated in base fabric, is dried
It is dry, solidify to get the base fabric containing waterproof layer;
(2) prepared by adhesive layer, and the phenolic resin for forming adhesive layer and phenoxy resin are mixed by weight 3:1, reheat fusing,
Resin solution is obtained, the waterproof layer that then step (1) obtains is impregnated into resin solution, is impregnated with resin solution in waterproof layer
In, then the waterproof layer for being soaked with resin liquid is put into 150 DEG C of drying boxes and is dried, solidifies, obtains the base containing adhesive layer
Cloth;
(4) prepared by wearing layer: weighing hexenyl silicone resin in proportion, crushes, crosses 80 meshes, be placed in dispersion tank, and to dispersion
Phenyl phosphate 2-glycidyl ester and quality are added in tank as 15 times of phenyl phosphate 2-glycidyl ester of deionized water, stirring is equal
It is even, and after mixed solution is risen to 90 DEG C, polyamide/metal quantum point material is added, after stirring 10min, adds modification and receives
Rice schmigel, carbon black 774, carbon black N660 and antimony trioxide, finally add sulphur, trioctyl trimellitate (TOTM) and steel fibre, stir
It mixes uniformly, obtains anti-wear agent, anti-wear agent is coated on adhesive layer, dry to get the base fabric containing wearing layer;
(5) solidify: the base fabric containing wearing layer made from step (4) is put into vulcanizing oven solidify it is resistance to get waterproof
Grind organic silicon cloth.
Wherein, condition of cure in the step (5) are as follows: temperature control is 120 DEG C, curing time 15min.
Embodiment 2
The organic silicon cloth of the waterproof antiwear of the present embodiment, including base fabric are successively coated with waterproof layer, viscous in the base fabric from inside to outside
Knot layer and wearing layer, the waterproof layer and wearing layer are made of organic siliconresin and adjuvant material.
Wherein, the waterproof layer is vinyl polysiloxane waterproof layer, is formulated by the raw material of following parts by weight:
65 parts of vinyl polysiloxane;
4.5 parts of polyvinyl alcohol;
5 parts of microcrystalline cellulose;
Palm wax 4;
12 parts of Emulsifier EL-60;
15 parts of repefral;
3 parts of stearic acid;
0.5 part of detergent alkylate sodium sulfonate;
2 parts of silane coupling agent;
1.5 parts of nano diatomite.
Wherein, the wearing layer is hexenyl silicone resin wearing layer, is formulated by the raw material of following parts by weight:
70 parts of hexenyl silicone resin;
Polyamide/5 parts of material of metal quantum point;
3 parts of modified Nano schmigel;
5 parts of sulphur;
774 10 parts of carbon black;
25 parts of carbon black N660;
3 parts of trioctyl trimellitate (TOTM);
6 parts of antimony oxide;
2 parts of phenyl phosphate 2-glycidyl ester;
1.5 parts of steel fibre.
Wherein, the polyamide/metal quantum point material preparation method is as follows:
(1) polyamide modified: by polyaniline ultrasonic disperse in nitration mixture, the concentration of polyamide is 4mg/mL, is heated to 65 DEG C simultaneously
Constant temperature stirs 2h, then is washed to neutrality with distillation, dries 18h under the conditions of 55 DEG C in an oven, obtains modified polyamide;
(2) modified polyamide is sent into kneading machine, melting temperature is 130 DEG C, total by modified polyamide is accounted for after being kneaded 10min
The metal quantum point of quality 1/10 is added in kneading machine, is kneaded 4min, discharge together;
(3) the mixture cooled to room temperature that upper step is discharged, and be sent in electron beam irradiation, in the spoke of 0.9MeV
According to reaction 45min under energy to get polyamide/metal quantum point composite material.
Wherein, the preparation method of the modified Nano schmigel includes:
It (1) is that 300nm corundum powder is added in dioxane solvent by granularity, the ultrasound 2.5h under 30KHz frequency forms corundum
Micro mist dispersion;
(2) diacid chloride is added in the corundum powder dispersion, and under nitrogen protection, under 150rpm revolving speed, electromagnetic agitation
10min forms uniformly mixed suspension;
(3) silane coupling agent is in suspension added described, stirs evenly, react 50min, filter, wash, being drying to obtain modified receive
Rice schmigel.
Wherein, the adhesive layer is phenolic resin and the phenoxy resin compound of 3:1 in mass ratio.
Wherein, the present invention also provides the processing technologys of the organic silicon cloth of above-mentioned waterproof antiwear, comprising the following steps:
(1) prepared by waterproof layer: weighing vinyl polysiloxane in proportion, crushes, sieve with 100 mesh sieve, be placed in dispersion tank, to dispersion tank
Middle polyvinyl alcohol, the quality of being added is 10 times of polyvinyl alcohol of deionized water, with the warming while stirring of 350rpm speed to 70 DEG C, so
After add microcrystalline cellulose, palm wax, Emulsifier EL-60, detergent alkylate sodium sulfonate, nano diatomite, silane coupling agent
And repefral, 50min is dispersed at 85 DEG C, is ground, is obtained waterproofing agent, waterproofing agent is coated in base fabric, is dried
It is dry, solidify to get the base fabric containing waterproof layer;
(2) prepared by adhesive layer, and the phenolic resin for forming adhesive layer and phenoxy resin are mixed by weight 3:1, reheat fusing,
Resin solution is obtained, the waterproof layer that then step (1) obtains is impregnated into resin solution, is impregnated with resin solution in waterproof layer
In, then the waterproof layer for being soaked with resin liquid is put into 180 DEG C of drying boxes and is dried, solidifies, obtains the base containing adhesive layer
Cloth;
(4) prepared by wearing layer: weighing hexenyl silicone resin in proportion, crushes, crosses 80 meshes, be placed in dispersion tank, and to dispersion
Phenyl phosphate 2-glycidyl ester and quality are added in tank as 15 times of phenyl phosphate 2-glycidyl ester of deionized water, stirring is equal
It is even, and after mixed solution is risen to 90 DEG C, polyamide/metal quantum point material is added, after stirring 10min, adds modification and receives
Rice schmigel, carbon black 774, carbon black N660 and antimony trioxide, finally add sulphur, trioctyl trimellitate (TOTM) and steel fibre, stir
It mixes uniformly, obtains anti-wear agent, anti-wear agent is coated on adhesive layer, dry to get the base fabric containing wearing layer;
(5) solidify: the base fabric containing wearing layer made from step (4) is put into vulcanizing oven solidify it is resistance to get waterproof
Grind organic silicon cloth.
Wherein, condition of cure in the step (5) are as follows: temperature control is 140 DEG C, curing time 20min.
Embodiment 3
The organic silicon cloth of the waterproof antiwear of the present embodiment, including base fabric are successively coated with waterproof layer, viscous in the base fabric from inside to outside
Knot layer and wearing layer, the waterproof layer and wearing layer are made of organic siliconresin and adjuvant material.
Wherein, the waterproof layer is vinyl polysiloxane waterproof layer, is formulated by the raw material of following parts by weight:
60 parts of vinyl polysiloxane;
3.5 parts of polyvinyl alcohol;
3.5 parts of microcrystalline cellulose;
Palm wax 3;
8.5 parts of Emulsifier EL-60;
11.5 parts of repefral;
2 parts of stearic acid;
0.4 part of detergent alkylate sodium sulfonate;
1.5 parts of silane coupling agent;
1 part of nano diatomite.
Wherein, the wearing layer is hexenyl silicone resin wearing layer, is formulated by the raw material of following parts by weight:
65 parts of hexenyl silicone resin;
Polyamide/4 parts of material of metal quantum point;
2 parts of modified Nano schmigel;
3.5 parts of sulphur;
774 7.5 parts of carbon black;
20 parts of carbon black N660;
2 parts of trioctyl trimellitate (TOTM);
4.5 parts of antimony oxide;
1.5 parts of phenyl phosphate 2-glycidyl ester;
1 part of steel fibre.
Wherein, the polyamide/metal quantum point material preparation method is as follows:
(1) polyamide modified: by polyaniline ultrasonic disperse in nitration mixture, the concentration of polyamide is 2.5mg/mL, is heated to 65 DEG C
And constant temperature stirs 2h, then is washed to neutrality with distillation, dries 18h under the conditions of 55 DEG C in an oven, obtains modified polyamide;
(2) modified polyamide is sent into kneading machine, melting temperature is 130 DEG C, total by modified polyamide is accounted for after being kneaded 7.5min
The metal quantum point of quality 1/10 is added in kneading machine, is kneaded 4min, discharge together;
(3) the mixture cooled to room temperature that upper step is discharged, and be sent in electron beam irradiation, in the spoke of 0.8MeV
According to reaction 40min under energy to get polyamide/metal quantum point composite material.
Wherein, the preparation method of the modified Nano schmigel includes:
It (1) is that 300nm corundum powder is added in dioxane solvent by granularity, the ultrasound 2.5h under 30KHz frequency forms corundum
Micro mist dispersion;
(2) diacid chloride is added in the corundum powder dispersion, and under nitrogen protection, under 150rpm revolving speed, electromagnetic agitation
7.5min forms uniformly mixed suspension;
(3) silane coupling agent is in suspension added described, stirs evenly, react 50min, filter, wash, being drying to obtain modified receive
Rice schmigel.
Wherein, the adhesive layer is phenolic resin and the phenoxy resin compound of 3:1 in mass ratio.
Wherein, the present invention also provides the processing technologys of the organic silicon cloth of above-mentioned waterproof antiwear, comprising the following steps:
(1) prepared by waterproof layer: weighing vinyl polysiloxane in proportion, crushes, sieve with 100 mesh sieve, be placed in dispersion tank, to dispersion tank
Middle polyvinyl alcohol, the quality of being added is 10 times of polyvinyl alcohol of deionized water, with the warming while stirring of 350rpm speed to 70 DEG C, so
After add microcrystalline cellulose, palm wax, Emulsifier EL-60, detergent alkylate sodium sulfonate, nano diatomite, silane coupling agent
And repefral, 50min is dispersed at 85 DEG C, is ground, is obtained waterproofing agent, waterproofing agent is coated in base fabric, is dried
It is dry, solidify to get the base fabric containing waterproof layer;
(2) prepared by adhesive layer, and the phenolic resin for forming adhesive layer and phenoxy resin are mixed by weight 3:1, reheat fusing,
Resin solution is obtained, the waterproof layer that then step (1) obtains is impregnated into resin solution, is impregnated with resin solution in waterproof layer
In, then the waterproof layer for being soaked with resin liquid is put into 65 DEG C of drying boxes and is dried, solidifies, obtains the base containing adhesive layer
Cloth;
(4) prepared by wearing layer: weighing hexenyl silicone resin in proportion, crushes, crosses 80 meshes, be placed in dispersion tank, and to dispersion
Phenyl phosphate 2-glycidyl ester and quality are added in tank as 15 times of phenyl phosphate 2-glycidyl ester of deionized water, stirring is equal
It is even, and after mixed solution is risen to 90 DEG C, polyamide/metal quantum point material is added, after stirring 10min, adds modification and receives
Rice schmigel, carbon black 774, carbon black N660 and antimony trioxide, finally add sulphur, trioctyl trimellitate (TOTM) and steel fibre, stir
It mixes uniformly, obtains anti-wear agent, anti-wear agent is coated on adhesive layer, dry to get the base fabric containing wearing layer;
(5) solidify: the base fabric containing wearing layer made from step (4) is put into vulcanizing oven solidify it is resistance to get waterproof
Grind organic silicon cloth.
Wherein, condition of cure in the step (5) are as follows: temperature control is 130 DEG C, curing time 17min.
Embodiment 4
The organic silicon cloth of the waterproof antiwear of the present embodiment, including base fabric are successively coated with waterproof layer, viscous in the base fabric from inside to outside
Knot layer and wearing layer, the waterproof layer and wearing layer are made of organic siliconresin and adjuvant material.
Wherein, the waterproof layer is vinyl polysiloxane waterproof layer, is formulated by the raw material of following parts by weight:
58 parts of vinyl polysiloxane;
3.0 parts of polyvinyl alcohol;
3 parts of microcrystalline cellulose;
Palm wax 2,5;
6 parts of Emulsifier EL-60;
9 parts of repefral;
1.5 parts of stearic acid;
0.4 part of detergent alkylate sodium sulfonate;
1.3 parts of silane coupling agent;
0.8 part of nano diatomite.
Wherein, the wearing layer is hexenyl silicone resin wearing layer, is formulated by the raw material of following parts by weight:
63 parts of hexenyl silicone resin;
Polyamide/3.5 parts of material of metal quantum point;
1-3 parts of modified Nano schmigel;
3 parts of sulphur;
774 6 parts of carbon black;
18 parts of carbon black N660;
1.5 parts of trioctyl trimellitate (TOTM);
4 parts of antimony oxide;
1.3 parts of phenyl phosphate 2-glycidyl ester;
0.8 part of steel fibre.
Wherein, the polyamide/metal quantum point material preparation method is as follows:
(1) polyamide modified: by polyaniline ultrasonic disperse in nitration mixture, the concentration of polyamide is 2mg/mL, is heated to 65 DEG C simultaneously
Constant temperature stirs 2h, then is washed to neutrality with distillation, dries 18h under the conditions of 55 DEG C in an oven, obtains modified polyamide;
(2) modified polyamide is sent into kneading machine, melting temperature is 130 DEG C, after being kneaded 6min, will account for the total matter of modified polyamide
The metal quantum point of amount 1/10 is added in kneading machine, is kneaded 4min, discharge together;
(3) the mixture cooled to room temperature that upper step is discharged, and be sent in electron beam irradiation, in the spoke of 0.9MeV
According to reaction 38min under energy to get polyamide/metal quantum point composite material.
Wherein, the preparation method of the modified Nano schmigel includes:
It (1) is that 300nm corundum powder is added in dioxane solvent by granularity, the ultrasound 2.5h under 30KHz frequency forms corundum
Micro mist dispersion;
(2) diacid chloride is added in the corundum powder dispersion, and under nitrogen protection, under 150rpm revolving speed, electromagnetic agitation
6min forms uniformly mixed suspension;
(3) silane coupling agent is in suspension added described, stirs evenly, react 50min, filter, wash, being drying to obtain modified receive
Rice schmigel.
Wherein, the adhesive layer is phenolic resin and the phenoxy resin compound of 3:1 in mass ratio.
Wherein, the present invention also provides the processing technologys of the organic silicon cloth of above-mentioned waterproof antiwear, comprising the following steps:
(1) prepared by waterproof layer: weighing vinyl polysiloxane in proportion, crushes, sieve with 100 mesh sieve, be placed in dispersion tank, to dispersion tank
Middle polyvinyl alcohol, the quality of being added is 10 times of polyvinyl alcohol of deionized water, with the warming while stirring of 350rpm speed to 70 DEG C, so
After add microcrystalline cellulose, palm wax, Emulsifier EL-60, detergent alkylate sodium sulfonate, nano diatomite, silane coupling agent
And repefral, 50min is dispersed at 85 DEG C, is ground, is obtained waterproofing agent, waterproofing agent is coated in base fabric, is dried
It is dry, solidify to get the base fabric containing waterproof layer;
(2) prepared by adhesive layer, and the phenolic resin for forming adhesive layer and phenoxy resin are mixed by weight 3:1, reheat fusing,
Resin solution is obtained, the waterproof layer that then step (1) obtains is impregnated into resin solution, is impregnated with resin solution in waterproof layer
In, then the waterproof layer for being soaked with resin liquid is put into 160 DEG C of drying boxes and is dried, solidifies, obtains the base containing adhesive layer
Cloth;
(4) prepared by wearing layer: weighing hexenyl silicone resin in proportion, crushes, crosses 80 meshes, be placed in dispersion tank, and to dispersion
Phenyl phosphate 2-glycidyl ester and quality are added in tank as 15 times of phenyl phosphate 2-glycidyl ester of deionized water, stirring is equal
It is even, and after mixed solution is risen to 90 DEG C, polyamide/metal quantum point material is added, after stirring 10min, adds modification and receives
Rice schmigel, carbon black 774, carbon black N660 and antimony trioxide, finally add sulphur, trioctyl trimellitate (TOTM) and steel fibre, stir
It mixes uniformly, obtains anti-wear agent, anti-wear agent is coated on adhesive layer, dry to get the base fabric containing wearing layer;
(5) solidify: the base fabric containing wearing layer made from step (4) is put into vulcanizing oven solidify it is resistance to get waterproof
Grind organic silicon cloth.
Wherein, condition of cure in the step (5) are as follows: temperature control is 125 DEG C, curing time 16min.
Embodiment 5
The organic silicon cloth of the waterproof antiwear of the present embodiment, including base fabric are successively coated with waterproof layer, viscous in the base fabric from inside to outside
Knot layer and wearing layer, the waterproof layer and wearing layer are made of organic siliconresin and adjuvant material.
Wherein, the waterproof layer is vinyl polysiloxane waterproof layer, is formulated by the raw material of following parts by weight:
62 parts of vinyl polysiloxane;
4.0 parts of polyvinyl alcohol;
4 parts of microcrystalline cellulose;
3.5 parts of palm wax;
6 parts of Emulsifier EL-60;
9 parts of repefral;
1.5 parts of stearic acid;
0.5 part of detergent alkylate sodium sulfonate;
1.2 parts of silane coupling agent;
0.8 part of nano diatomite.
Wherein, the wearing layer is hexenyl silicone resin wearing layer, is formulated by the raw material of following parts by weight:
68 parts of hexenyl silicone resin;
Polyamide/4.5 parts of material of metal quantum point;
2.5 parts of modified Nano schmigel;
4 parts of sulphur;
774 9 parts of carbon black;
22 parts of carbon black N660;
2.5 parts of trioctyl trimellitate (TOTM);
5 parts of antimony oxide;
1.8 parts of phenyl phosphate 2-glycidyl ester;
1.2 parts of steel fibre.
Wherein, the polyamide/metal quantum point material preparation method is as follows:
(1) polyamide modified: by polyaniline ultrasonic disperse in nitration mixture, the concentration of polyamide is 3mg/mL, is heated to 65 DEG C simultaneously
Constant temperature stirs 2h, then is washed to neutrality with distillation, dries 18h under the conditions of 55 DEG C in an oven, obtains modified polyamide;
(2) modified polyamide is sent into kneading machine, melting temperature is 130 DEG C, after being kneaded 9min, will account for the total matter of modified polyamide
The metal quantum point of amount 1/10 is added in kneading machine, is kneaded 4min, discharge together;
(3) the mixture cooled to room temperature that upper step is discharged, and be sent in electron beam irradiation, in 0.8-0.9MeV
Irradiation energy under react 42min to get polyamide/metal quantum point composite material.
Wherein, the preparation method of the modified Nano schmigel includes:
It (1) is that 300nm corundum powder is added in dioxane solvent by granularity, the ultrasound 2.5h under 30KHz frequency forms corundum
Micro mist dispersion;
(2) diacid chloride is added in the corundum powder dispersion, and under nitrogen protection, under 150rpm revolving speed, electromagnetic agitation
9min forms uniformly mixed suspension;
(3) silane coupling agent is in suspension added described, stirs evenly, react 50min, filter, wash, being drying to obtain modified receive
Rice schmigel.
Wherein, the adhesive layer is phenolic resin and the phenoxy resin compound of 3:1 in mass ratio.
Wherein, the present invention also provides the processing technologys of the organic silicon cloth of above-mentioned waterproof antiwear, comprising the following steps:
(1) prepared by waterproof layer: weighing vinyl polysiloxane in proportion, crushes, sieve with 100 mesh sieve, be placed in dispersion tank, to dispersion tank
Middle polyvinyl alcohol, the quality of being added is 10 times of polyvinyl alcohol of deionized water, with the warming while stirring of 350rpm speed to 70 DEG C, so
After add microcrystalline cellulose, palm wax, Emulsifier EL-60, detergent alkylate sodium sulfonate, nano diatomite, silane coupling agent
And repefral, 50min is dispersed at 85 DEG C, is ground, is obtained waterproofing agent, waterproofing agent is coated in base fabric, is dried
It is dry, solidify to get the base fabric containing waterproof layer;
(2) prepared by adhesive layer, and the phenolic resin for forming adhesive layer and phenoxy resin are mixed by weight 3:1, reheat fusing,
Resin solution is obtained, the waterproof layer that then step (1) obtains is impregnated into resin solution, is impregnated with resin solution in waterproof layer
In, then the waterproof layer for being soaked with resin liquid is put into 170 DEG C of drying boxes and is dried, solidifies, obtains the base containing adhesive layer
Cloth;
(4) prepared by wearing layer: weighing hexenyl silicone resin in proportion, crushes, crosses 80 meshes, be placed in dispersion tank, and to dispersion
Phenyl phosphate 2-glycidyl ester and quality are added in tank as 15 times of phenyl phosphate 2-glycidyl ester of deionized water, stirring is equal
It is even, and after mixed solution is risen to 90 DEG C, polyamide/metal quantum point material is added, after stirring 10min, adds modification and receives
Rice schmigel, carbon black 774, carbon black N660 and antimony trioxide, finally add sulphur, trioctyl trimellitate (TOTM) and steel fibre, stir
It mixes uniformly, obtains anti-wear agent, anti-wear agent is coated on adhesive layer, dry to get the base fabric containing wearing layer;
(5) solidify: the base fabric containing wearing layer made from step (4) is put into vulcanizing oven solidify it is resistance to get waterproof
Grind organic silicon cloth.
Wherein, condition of cure in the step (5) are as follows: temperature control is 135 DEG C, curing time 19min.
Comparative example 1
In addition to removing palm wax, the Emulsifier EL-60 in waterproof layer, other raw materials and preparation step are the same as embodiment 1 one
It causes.
Comparative example 2
In addition to removing the microcrystalline cellulose in waterproof layer, other raw materials and preparation step are consistent with embodiment 1.
Comparative example 3
In addition to removing the polyamide in wearing layer/metal quantum point material, other raw materials and preparation step are the same as embodiment 1 one
It causes.
Comparative example 4
In addition to removing the modified Nano schmigel in wearing layer, other raw materials and preparation step are consistent with embodiment 1.
Test example
Waterproof antiwear prepared by the organic silicon cloth of waterproof antiwear prepared by 1-5 of the embodiment of the present invention and comparative example 3, comparative example 4
Organic silicon cloth carries out wearability, Water Resistance Test, and specific test result is shown in Table 1
Test item | Wear resistance (g/cm3) | Water pressure resistance (mmH2O) |
Embodiment 1 | 0.06 | 10000 |
Embodiment 2 | 0.05 | 11000 |
Embodiment 3 | 0.03 | 11500 |
Embodiment 4 | 0.05 | 9500 |
Embodiment 5 | 0.07 | 11200 |
Comparative example 1 | 0.09 | 8500 |
Comparative example 2 | 0.08 | 9000 |
Comparative example 3 | 0.13 | 7500 |
Comparative example 4 | 0.15 | 8000 |
As shown in Table 1, the waterproof antiwear performance of the organic silicon cloth of waterproof antiwear prepared by various embodiments of the present invention is better than comparison
Example 1-4, and by comparative example 1-4 it is found that can by the way that palm wax, Emulsifier EL-60 and microcrystalline cellulose is added in waterproof layer
To improve the water resistance of waterproof layer, and addition polyamide/metal quantum point material, modified Nano schmigel can in wearing layer
With the wear-resisting property of wearing layer.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, although referring to aforementioned reality
Applying example, invention is explained in detail, for those skilled in the art, still can be to aforementioned each implementation
Technical solution documented by example is modified or equivalent replacement of some of the technical features.It is all in essence of the invention
Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (8)
1. a kind of organic silicon cloth of waterproof antiwear, including base fabric, which is characterized in that be successively coated with from inside to outside in the base fabric anti-
Water layer, adhesive layer and wearing layer, the waterproof layer and wearing layer are made of organic siliconresin and adjuvant material.
2. the organic silicon cloth of waterproof antiwear according to claim 1, which is characterized in that the waterproof layer is vinyl polysiloxane
Waterproof layer is formulated by the raw material of following parts by weight:
55-65 parts of vinyl polysiloxane;
2.5-4.5 parts of polyvinyl alcohol;
2-5 parts of microcrystalline cellulose;
Palm wax 2-4;
5-12 parts of Emulsifier EL-60;
8-15 parts of repefral;
1-3 parts of stearic acid;
0.3-0.5 parts of detergent alkylate sodium sulfonate;
1-2 parts of silane coupling agent;
0.5-1.5 parts of nano diatomite.
3. the organic silicon cloth of waterproof antiwear according to claim 1, which is characterized in that the wearing layer is hexenyl silicone resin
Wearing layer is formulated by the raw material of following parts by weight:
60-70 parts of hexenyl silicone resin;
Polyamide/3-5 parts of metal quantum point material;
1-3 parts of modified Nano schmigel;
2-5 parts of sulphur;
774 5-10 parts of carbon black;
15-25 parts of carbon black N660;
1-3 parts of trioctyl trimellitate (TOTM);
3-6 parts of antimony oxide;
1-2 parts of phenyl phosphate 2-glycidyl ester;
0.5-1.5 parts of steel fibre.
4. the organic silicon cloth of waterproof antiwear according to claim 3, which is characterized in that the polyamide/metal quantum point material
Preparation method for material is as follows:
(1) polyamide modified: by polyaniline ultrasonic disperse in nitration mixture, the concentration of polyamide is 1-4mg/mL, is heated to 65 DEG C
And constant temperature stirs 2h, then is washed to neutrality with distillation, dries 18h under the conditions of 55 DEG C in an oven, obtains modified polyamide;
(2) modified polyamide is sent into kneading machine, melting temperature is 130 DEG C, after being kneaded 5-10min, will account for modified polyamide
The metal quantum point of gross mass 1/10 is added in kneading machine, is kneaded 4min, discharge together;
(3) the mixture cooled to room temperature that upper step is discharged, and be sent in electron beam irradiation, in 0.8-0.9MeV
Irradiation energy under react 35-45min to get polyamide/metal quantum point composite material.
5. the organic silicon cloth of waterproof antiwear according to claim 3, which is characterized in that the preparation of the modified Nano schmigel
Method includes:
It (1) is that 300nm corundum powder is added in dioxane solvent by granularity, the ultrasound 2.5h under 30KHz frequency forms corundum
Micro mist dispersion;
(2) diacid chloride is added in the corundum powder dispersion, and under nitrogen protection, under 150rpm revolving speed, electromagnetic agitation
5-10min forms uniformly mixed suspension;
(3) silane coupling agent is in suspension added described, stirs evenly, react 50min, filter, wash, being drying to obtain modified receive
Rice schmigel.
6. the organic silicon cloth of waterproof antiwear according to claim 1, which is characterized in that the adhesive layer is phenolic resin and benzene
The oxygen resin compound of 3:1 in mass ratio.
7. the processing technology of the organic silicon cloth of waterproof antiwear according to claim 1-6, which is characterized in that including with
Lower step:
(1) prepared by waterproof layer: weighing vinyl polysiloxane in proportion, crushes, sieve with 100 mesh sieve, be placed in dispersion tank, to dispersion tank
Middle polyvinyl alcohol, the quality of being added is 10 times of polyvinyl alcohol of deionized water, with the warming while stirring of 350rpm speed to 70 DEG C, so
After add microcrystalline cellulose, palm wax, Emulsifier EL-60, detergent alkylate sodium sulfonate, nano diatomite, silane coupling agent
And repefral, 50min is dispersed at 85 DEG C, is ground, is obtained waterproofing agent, waterproofing agent is coated in base fabric, is dried
It is dry, solidify to get the base fabric containing waterproof layer;
(2) prepared by adhesive layer, and the phenolic resin for forming adhesive layer and phenoxy resin are mixed by weight 3:1, reheat fusing,
Resin solution is obtained, the waterproof layer that then step (1) obtains is impregnated into resin solution, is impregnated with resin solution in waterproof layer
In, then the waterproof layer for being soaked with resin liquid is put into 150-180 DEG C of drying box and is dried, solidifies, is obtained containing adhesive layer
Base fabric;
(3) prepared by wearing layer: weighing hexenyl silicone resin in proportion, crushes, crosses 80 meshes, be placed in dispersion tank, and to dispersion
Phenyl phosphate 2-glycidyl ester and quality are added in tank as 15 times of phenyl phosphate 2-glycidyl ester of deionized water, stirring is equal
It is even, and after mixed solution is risen to 90 DEG C, polyamide/metal quantum point material is added, after stirring 10min, adds modification and receives
Rice schmigel, carbon black 774, carbon black N660 and antimony trioxide, finally add sulphur, trioctyl trimellitate (TOTM) and steel fibre, stir
It mixes uniformly, obtains anti-wear agent, anti-wear agent is coated on adhesive layer, dry to get the base fabric containing wearing layer;
(4) solidify: the base fabric containing wearing layer made from step (3) is put into vulcanizing oven solidify it is resistance to get waterproof
Grind organic silicon cloth.
8. the processing technology of the organic silicon cloth of waterproof antiwear according to claim 7, which is characterized in that in the step (5)
Condition of cure are as follows: temperature control is 120-140 DEG C, curing time 15-20min.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN116200949A (en) * | 2023-02-07 | 2023-06-02 | 江西米丝美织造有限公司 | Wear-resistant elastic rib fabric and preparation method thereof |
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CN106833059A (en) * | 2016-12-22 | 2017-06-13 | 安徽易有墙纸有限公司 | A kind of wear-resisting waterproof wallpaper and preparation method thereof |
CN107163706A (en) * | 2017-05-31 | 2017-09-15 | 句容市恒鑫遮阳科技有限公司 | A kind of high intensity sunshade waterproof cloth and preparation method thereof |
CN108799647A (en) * | 2018-06-27 | 2018-11-13 | 张洪红 | A kind of fuel rubber pipe and preparation method thereof |
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EP0329411A2 (en) * | 1988-02-16 | 1989-08-23 | Micropore | Waterproof breathable microporous membrane with cellular foam adhesive |
CN106833059A (en) * | 2016-12-22 | 2017-06-13 | 安徽易有墙纸有限公司 | A kind of wear-resisting waterproof wallpaper and preparation method thereof |
CN107163706A (en) * | 2017-05-31 | 2017-09-15 | 句容市恒鑫遮阳科技有限公司 | A kind of high intensity sunshade waterproof cloth and preparation method thereof |
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