CN107163706A - A kind of high intensity sunshade waterproof cloth and preparation method thereof - Google Patents

A kind of high intensity sunshade waterproof cloth and preparation method thereof Download PDF

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Publication number
CN107163706A
CN107163706A CN201710396845.0A CN201710396845A CN107163706A CN 107163706 A CN107163706 A CN 107163706A CN 201710396845 A CN201710396845 A CN 201710396845A CN 107163706 A CN107163706 A CN 107163706A
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China
Prior art keywords
parts
high intensity
waterproof cloth
preparation
sunshade
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Pending
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CN201710396845.0A
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Chinese (zh)
Inventor
王岳来
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Jurong Hengxin Sun Technology Co Ltd
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Jurong Hengxin Sun Technology Co Ltd
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Priority to CN201710396845.0A priority Critical patent/CN107163706A/en
Publication of CN107163706A publication Critical patent/CN107163706A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/04Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C09D127/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention provides a kind of high intensity sunshade waterproof cloth and preparation method thereof, the waterproof cloth includes base fabric and waterproof layer, and the waterproof layer is made up of following raw material:Polyvinyl chloride resin, polyvinyl alcohol, thermoplastic styrene butadiene rubber, microcrystalline cellulose, silicon carbide whisker, plasticizer, stearic acid, diatomite, coupling agent, lecithin, surfactant, water.Its preparation method includes first adding to polyvinyl chloride resin, polyvinyl alcohol, thermoplastic styrene butadiene rubber, microcrystalline cellulose, silicon carbide whisker, plasticizer, stearic acid, diatomite, coupling agent, lecithin, surfactant in water, it is scattered, grinding, then gained coating agent is coated in base fabric, drying, it is placed in after being soaked in stabiliser solution, drying is produced.The present invention waterproof cloth can be used at 30 DEG C 70 DEG C, heat-resisting cold resistance is good, with waterproof, fire-retardant, uvioresistant, high intensity stretching tear resistance.

Description

A kind of high intensity sunshade waterproof cloth and preparation method thereof
Technical field
The invention belongs to technical field of textile fabric, and in particular to a kind of high intensity sunshade waterproof cloth and preparation method thereof.
Background technology
Waterproof cloth is a kind of new weaving face fabric, its composition by macromolecule waterproof ventilative material plus cloth it is compound and Into its major function has:Waterproof, moisture-inhibiting is breathed freely, and insulation is windproof, warming.Goods vehicle and train tarpaulin and field tent The waterproof clothes such as cloth, are not required nothing more than with higher water resistance, and are required with the performance such as sunshade, ageing-resistant, wear-resisting.It is common Although common plasticses cloth water resistance it is good, sunshade and wear no resistance, the easy aging rupture of use time length.
Traditional waterproof cloth is essentially all, using chopped fibers such as cotton, chemical fibres as raw material, to be produced by spinning, weaving Canvas makes waterproof cloth, thus product is heavier coarse, low intensity.And the water-proof function of canvas, mainly by fabric Density is realized.The water resistance of canvas is improved by Density obviously inborn deficiency, even Density is tight again, Time one is grown, and water can still infiltrate fabric, after the content of fabric fibre reclaimed water reaches saturation, and infiltration is occurred as soon as.With section The prosperity of skill, the country occurs in that using organic silicon coating to improve the waterproof ability of canvas, but organic silicon coating is also defective:The One, its less stable, easy aging is difficult nursing intolerant to greasy dirt;Second, the particle of organic silicon monomer is larger, and coating is also not Enough densifications, therefore waterproof effect is not still highly desirable.
The content of the invention
The technical problem of solution:It is an object of the invention to provide a kind of high intensity sunshade waterproof cloth and preparation method thereof, institute Waterproof cloth excellent performance is obtained, can be used at -30 DEG C -70 DEG C.
Technical scheme:A kind of high intensity sunshade waterproof cloth, including base fabric and waterproof layer, the waterproof layer is by below with weight The raw material of part meter is made:20-35 parts of polyvinyl chloride resin, 5-8 parts of polyvinyl alcohol, 3-7 parts of thermoplastic styrene butadiene rubber, microcrystalline cellulose 2-6 Part, 1-4 parts of silicon carbide whisker, 2-6 parts of plasticizer, 0.8-3.2 parts of stearic acid, 0.5-1.5 parts of diatomite, 2-4 parts of coupling agent, ovum - 3 parts of phosphatidase 1,0.4-1.2 parts of surfactant, 40-50 parts of water.
Further, the plasticizer is dibutyl phthalate.
Further, the coupling agent is silane coupler.
Further, the surfactant is neopelex.
The preparation method of above-mentioned high intensity sunshade waterproof cloth, comprises the following steps:
Step 1, by polyvinyl chloride resin, polyvinyl alcohol, thermoplastic styrene butadiene rubber, microcrystalline cellulose, silicon carbide whisker, plasticizer, Stearic acid, diatomite, coupling agent, lecithin, surfactant are added in water, are disperseed, and grinding obtains coating agent;
Step 2, step 1 gained coating agent is coated in base fabric, dried, is placed in after being soaked in stabiliser solution, drying, Produce.
Further, dispersion condition is 800-1000rpm, 20-30min in step 1.
Further, coating weight is 100-250g/m in step 22, drying temperature is 120-150 DEG C.
Further, the stabiliser solution is 20-30wt.% sodium chloride solutions.
Beneficial effect:The waterproof cloth of the present invention can be used at -30 DEG C -70 DEG C, and heat-resisting cold resistance is good, with waterproof, resistance Combustion, uvioresistant, the stretching tear resistance of high intensity.
Embodiment
Embodiment 1
A kind of high intensity sunshade waterproof cloth, including base fabric and waterproof layer, the waterproof layer is by following original in parts by weight Material is made:20 parts of polyvinyl chloride resin, 5 parts of polyvinyl alcohol, 3 parts of thermoplastic styrene butadiene rubber, 2 parts of microcrystalline cellulose, 1 part of silicon carbide whisker, 2 parts of plasticizer, 0.8 part of stearic acid, 0.5 part of diatomite, 2 parts of coupling agent, 1 part of lecithin, 0.4 part of surfactant, 40 parts of water.
Wherein, the plasticizer is dibutyl phthalate, and the coupling agent is silane coupler, the surface-active Agent is neopelex.
The preparation method of above-mentioned high intensity sunshade waterproof cloth, comprises the following steps:
Step 1, by polyvinyl chloride resin, polyvinyl alcohol, thermoplastic styrene butadiene rubber, microcrystalline cellulose, silicon carbide whisker, plasticizer, Stearic acid, diatomite, coupling agent, lecithin, surfactant are added in water, are disperseed, and grinding obtains coating agent;
Step 2, step 1 gained coating agent is coated in base fabric, dried, is placed in after being soaked in stabiliser solution, drying, Produce.
Wherein, dispersion condition is 800rpm, 30min in step 1;Coating weight is 100g/m in step 22, drying temperature is 120℃;The stabiliser solution is 20wt.% sodium chloride solutions.
Embodiment 2
A kind of high intensity sunshade waterproof cloth, including base fabric and waterproof layer, the waterproof layer is by following original in parts by weight Material is made:24 parts of polyvinyl chloride resin, 6 parts of polyvinyl alcohol, 4 parts of thermoplastic styrene butadiene rubber, 3 parts of microcrystalline cellulose, 2 parts of silicon carbide whisker, 3 parts of plasticizer, 1.4 parts of stearic acid, 0.8 part of diatomite, 3 parts of coupling agent, 1.7 parts of lecithin, 0.6 part of surfactant, water 42 Part.
Wherein, the plasticizer is dibutyl phthalate, and the coupling agent is silane coupler, the surface-active Agent is neopelex.
The preparation method of above-mentioned high intensity sunshade waterproof cloth, comprises the following steps:
Step 1, by polyvinyl chloride resin, polyvinyl alcohol, thermoplastic styrene butadiene rubber, microcrystalline cellulose, silicon carbide whisker, plasticizer, Stearic acid, diatomite, coupling agent, lecithin, surfactant are added in water, are disperseed, and grinding obtains coating agent;
Step 2, step 1 gained coating agent is coated in base fabric, dried, is placed in after being soaked in stabiliser solution, drying, Produce.
Wherein, dispersion condition is 900rpm, 25min in step 1;Coating weight is 180g/m in step 22, drying temperature is 140℃;The stabiliser solution is 20wt.% sodium chloride solutions.
Embodiment 3
A kind of high intensity sunshade waterproof cloth, including base fabric and waterproof layer, the waterproof layer is by following original in parts by weight Material is made:28 parts of polyvinyl chloride resin, 7 parts of polyvinyl alcohol, 5 parts of thermoplastic styrene butadiene rubber, 4 parts of microcrystalline cellulose, 3 parts of silicon carbide whisker, 4 parts of plasticizer, 2.2 parts of stearic acid, 0.9 part of diatomite, 3 parts of coupling agent, 2 parts of lecithin, 0.8 part of surfactant, 47 parts of water.
Wherein, the plasticizer is dibutyl phthalate, and the coupling agent is silane coupler, the surface-active Agent is neopelex.
The preparation method of above-mentioned high intensity sunshade waterproof cloth, comprises the following steps:
Step 1, by polyvinyl chloride resin, polyvinyl alcohol, thermoplastic styrene butadiene rubber, microcrystalline cellulose, silicon carbide whisker, plasticizer, Stearic acid, diatomite, coupling agent, lecithin, surfactant are added in water, are disperseed, and grinding obtains coating agent;
Step 2, step 1 gained coating agent is coated in base fabric, dried, is placed in after being soaked in stabiliser solution, drying, Produce.
Wherein, dispersion condition is 800rpm, 30min in step 1;Coating weight is 100g/m in step 22, drying temperature is 120℃;The stabiliser solution is 20wt.% sodium chloride solutions.
Embodiment 4
A kind of high intensity sunshade waterproof cloth, including base fabric and waterproof layer, the waterproof layer is by following original in parts by weight Material is made:35 parts of polyvinyl chloride resin, 8 parts of polyvinyl alcohol, 7 parts of thermoplastic styrene butadiene rubber, 6 parts of microcrystalline cellulose, 4 parts of silicon carbide whisker, 6 parts of plasticizer, 3.2 parts of stearic acid, 1.5 parts of diatomite, 4 parts of coupling agent, 3 parts of lecithin, 1.2 parts of surfactant, 50 parts of water.
Wherein, the plasticizer is dibutyl phthalate, and the coupling agent is silane coupler, the surface-active Agent is neopelex.
The preparation method of above-mentioned high intensity sunshade waterproof cloth, comprises the following steps:
Step 1, by polyvinyl chloride resin, polyvinyl alcohol, thermoplastic styrene butadiene rubber, microcrystalline cellulose, silicon carbide whisker, plasticizer, Stearic acid, diatomite, coupling agent, lecithin, surfactant are added in water, are disperseed, and grinding obtains coating agent;
Step 2, step 1 gained coating agent is coated in base fabric, dried, is placed in after being soaked in stabiliser solution, drying, Produce.
Wherein, dispersion condition is 1000rpm, 20min in step 1;Coating weight is 250g/m in step 22, drying temperature is 150℃;The stabiliser solution is 30wt.% sodium chloride solutions.
After testing, gained waterproof cloth can be used at -30 DEG C -70 DEG C, and heat-resisting cold resistance is good, with waterproof, fire-retardant, anti-purple Outside line, the stretching tear resistance of high intensity.

Claims (8)

1. a kind of high intensity sunshade waterproof cloth, including base fabric and waterproof layer, it is characterised in that:The waterproof layer is by below with weight The raw material of part meter is made:20-35 parts of polyvinyl chloride resin, 5-8 parts of polyvinyl alcohol, 3-7 parts of thermoplastic styrene butadiene rubber, microcrystalline cellulose 2-6 Part, 1-4 parts of silicon carbide whisker, 2-6 parts of plasticizer, 0.8-3.2 parts of stearic acid, 0.5-1.5 parts of diatomite, 2-4 parts of coupling agent, ovum - 3 parts of phosphatidase 1,0.4-1.2 parts of surfactant, 40-50 parts of water.
2. high intensity sunshade waterproof cloth according to claim 1, it is characterised in that:The plasticizer is phthalic acid two Butyl ester.
3. high intensity sunshade waterproof cloth according to claim 1, it is characterised in that:The coupling agent is silane coupler.
4. high intensity sunshade waterproof cloth according to claim 1, it is characterised in that:The surfactant is dodecyl Benzene sulfonic acid sodium salt.
5. the preparation method of the high intensity sunshade waterproof cloth described in claim 1, it is characterised in that:Comprise the following steps:
Step 1, by polyvinyl chloride resin, polyvinyl alcohol, thermoplastic styrene butadiene rubber, microcrystalline cellulose, silicon carbide whisker, plasticizer, tristearin Acid, diatomite, coupling agent, lecithin, surfactant are added in water, are disperseed, and grinding obtains coating agent;
Step 2, step 1 gained coating agent is coated in base fabric, dried, is placed in after being soaked in stabiliser solution, drying, i.e., .
6. the preparation method of high intensity sunshade waterproof cloth according to claim 5, it is characterised in that:Disperse bar in step 1 Part is 800-1000rpm, 20-30min.
7. the preparation method of high intensity sunshade waterproof cloth according to claim 5, it is characterised in that:Coating weight in step 2 For 100-250g/m2, drying temperature is 120-150 DEG C.
8. the preparation method of high intensity sunshade waterproof cloth according to claim 5, it is characterised in that:The stabiliser solution For 20-30wt.% sodium chloride solutions.
CN201710396845.0A 2017-05-31 2017-05-31 A kind of high intensity sunshade waterproof cloth and preparation method thereof Pending CN107163706A (en)

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Application Number Priority Date Filing Date Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109610184A (en) * 2018-12-15 2019-04-12 深圳市仁义和兴塑胶五金制品有限公司 A kind of organic silicon cloth of waterproof antiwear and processing technology
CN111535042A (en) * 2020-05-29 2020-08-14 江苏万邦特种纺织发展有限公司 Double-sided plastic coating process for waterproof cloth for landscape decoration

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201099814Y (en) * 2007-10-16 2008-08-13 刘浩杰 High intensity road bed water-proof cloth
CN102936460A (en) * 2012-09-20 2013-02-20 吴江市天源塑胶有限公司 Asphalt rubber waterproof coating material
CN104510236A (en) * 2013-09-27 2015-04-15 青岛畅绿生物研究所 Nymphaea tetragona fiber health summer sleeping mat
CN106003895A (en) * 2016-05-19 2016-10-12 相里海霞 Wear-resistant waterproof cloth
CN106245348A (en) * 2016-07-29 2016-12-21 芜湖华烨工业用布有限公司 A kind of Tarpauling

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201099814Y (en) * 2007-10-16 2008-08-13 刘浩杰 High intensity road bed water-proof cloth
CN102936460A (en) * 2012-09-20 2013-02-20 吴江市天源塑胶有限公司 Asphalt rubber waterproof coating material
CN104510236A (en) * 2013-09-27 2015-04-15 青岛畅绿生物研究所 Nymphaea tetragona fiber health summer sleeping mat
CN106003895A (en) * 2016-05-19 2016-10-12 相里海霞 Wear-resistant waterproof cloth
CN106245348A (en) * 2016-07-29 2016-12-21 芜湖华烨工业用布有限公司 A kind of Tarpauling

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109610184A (en) * 2018-12-15 2019-04-12 深圳市仁义和兴塑胶五金制品有限公司 A kind of organic silicon cloth of waterproof antiwear and processing technology
CN111535042A (en) * 2020-05-29 2020-08-14 江苏万邦特种纺织发展有限公司 Double-sided plastic coating process for waterproof cloth for landscape decoration

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