CN107151357A - A kind of floating power station vibration resistance tension UV resistant high-low temperature resistant CABLE MATERIALS - Google Patents
A kind of floating power station vibration resistance tension UV resistant high-low temperature resistant CABLE MATERIALS Download PDFInfo
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- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
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Abstract
The invention discloses a kind of floating power station vibration resistance tension UV resistant high-low temperature resistant CABLE MATERIALS, its raw material includes nitrile rubber, silicon rubber, butadiene rubber, alkyd resin, neoprene, epoxy acrylic resin, CSM, trifluoro propyl methyl-silicone oil, Firebrake ZB, nano-graphite, carbon black, blanc fixe, polyphosphoric acids aluminium, nano silicon, mica powder, Firebrake ZB, nano-ceramic powder, glass fibre, magnesia, kodalk, isocyanates, polysiloxanes, diisooctyl phthalate, silane coupler KH 570, chlorinated paraffin, calcium carbonate, antimony oxide, APP, styrene, chlorinated paraffin, vulcanizing agent DTDM, plasticizer, high-low temperature resistant modified additive, modified filler and UV resistant modified additive.The CABLE MATERIALS of the present invention is used for floating power station, with excellent vibration resistance, tension, UV resistant and high and low temperature resistance.
Description
Technical field
The present invention relates to the technical field of CABLE MATERIALS, more particularly to a kind of floating power station are resistance to vibration resistance tension UV resistant
High/low temperature CABLE MATERIALS.
Background technology
Current floating power station application environment is more complicated, is mainly used in offshore environment.Long-term humidity is larger, and stormy waves is larger
When have spray sputtering, this outside line is strong, and winter, temperature waterborne was relatively low, and cable is directly anchored on floating body or is laid on floating body
In crane span structure.Floating power station unit has certain floating displacement (about 3~5 meters) and SEA LEVEL VARIATION, and connection cable need to be by equipment most
Big spacing length in reserve, when equipment room away from it is smaller when, cable needs to bear bending force.Cable bearing floating body can be because of wind wave action ripple
Wave rises and falls or moved left and right, and cable bends wriggling therewith, and cable is with equipment junction by drag force, and collection electric line waterborne is ashore
The bank of booster stations is excessively located, due to the change of water level, and cable can also become bent and pull.So needing a kind of floating power station of design badly
The problems of the prior art are solved with vibration resistance tension UV resistant high-low temperature resistant CABLE MATERIALS.
The content of the invention
To solve technical problem present in background technology, the present invention proposes a kind of floating power station resistance to purple of vibration resistance tension
Outside line high-low temperature resistant CABLE MATERIALS, for floating power station, with excellent vibration resistance, tension, UV resistant and high and low temperature resistance.
A kind of floating power station proposed by the present invention vibration resistance tension UV resistant high-low temperature resistant CABLE MATERIALS, its raw material is by weight
Amount part includes：30-90 parts of nitrile rubber, 10-30 parts of silicon rubber, 5-15 parts of butadiene rubber, 2-8 parts of alkyd resin, neoprene
3-9 parts, 2-5 parts of epoxy acrylic resin, 2-6 parts of CSM, 2-8 parts of trifluoro propyl methyl-silicone oil, Firebrake ZB
1-5 parts, 2-6 parts of nano-graphite, 3-6 parts of carbon black, 4-8 parts of blanc fixe, 1-5 parts of polyphosphoric acids aluminium, nano silicon 2-5
Part, 3-5 parts of mica powder, 1-5 parts of Firebrake ZB, 3-5 parts of nano-ceramic powder, 4-8 parts of glass fibre, 4-8 parts of magnesia, kodalk
2-8 parts, 3-8 parts of isocyanates, 1-6 parts of polysiloxanes, 3-8 parts of diisooctyl phthalate, Silane coupling reagent KH-570 2-
5 parts, 1-4 parts of chlorinated paraffin, 1-3 parts of calcium carbonate, 2-4 parts of antimony oxide, 3-5 parts of APP, 4-8 parts of styrene, chlorination
It is 1-5 parts of paraffin, 2-6 parts of vulcanizing agent DTDM, 3-5 parts of plasticizer, 2-5 parts of high-low temperature resistant modified additive, 1-3 parts of modified filler, resistance to
Ultraviolet modified auxiliary agent 2-6 parts.
Preferably, the raw material of high-low temperature resistant modified additive includes by weight：5-15 parts of MTES, diformazan
2-6 parts of base dimethoxysilane, 1-4 parts of glacial acetic acid, 2-5 parts of diacetone alcohol, 3-6 parts of ethanol water, 1-5 parts of sodium acetate, change
2-5 parts of polyether silicone oil of property, 1-5 parts of isopropanol, 2-4 parts of methyl acrylate, 3-6 parts of butyl acrylate, methyl methacrylate 2-6
Part, 3-4 parts of styrene, 1-4 parts of azodiisobutyronitrile, 2-6 parts of aminopropyl triethoxysilane.
Preferably, high-low temperature resistant modified additive is prepared by following technique：By MTES and dimethyl
Dimethoxysilane is well mixed, and is then added glacial acetic acid, diacetone alcohol and ethanol water and is well mixed, and after heating, is continued
Heating and heat preservation, then adds sodium acetate and is well mixed, temperature rising reflux is continuously heating to distillation, then adds modified polyether silicone oil
It is well mixed with isopropanol, stir, stand, be cooled to room temperature and obtain material a, methyl acrylate, third are then added into material a
Olefin(e) acid butyl ester, methyl methacrylate and styrene are well mixed, heating and heat preservation, under nitrogen protection, add the isobutyl of azo two
Nitrile and aminopropyl triethoxysilane are well mixed, are cooled to room temperature and obtain high-low temperature resistant modified additive.
Preferably, high-low temperature resistant modified additive is prepared by following technique：By MTES and dimethyl
Dimethoxysilane be well mixed, in 650-850r/min rotating speeds stir 20-40min, then add glacial acetic acid, diacetone alcohol and
Ethanol water is well mixed, and is warming up to 30-40 DEG C, is stirred 30-50min in 850-980r/min rotating speeds, is continuously heating to 50-
60 DEG C, 1-3h is incubated, sodium acetate is then added and is well mixed, be warming up to 70-90 DEG C, flow back 2-4h, is continuously heating to 100-110
DEG C distillation 20-40min, it is well mixed then to add modified polyether silicone oil and isopropanol, and 20- is stirred in 450-550r/min rotating speeds
40min, stands 1-3h, is cooled to room temperature and obtains material a, and methyl acrylate, butyl acrylate, first are then added into material a
Base methyl acrylate and styrene are well mixed, are warming up to 70-80 DEG C, are incubated 2-4h, under nitrogen protection, add azo two different
Butyronitrile and aminopropyl triethoxysilane are well mixed, stir 3-5h in 350-450r/min rotating speeds, are cooled to room temperature and obtain resistance to
High/low temperature modified additive.
Preferably, modified filler is prepared by following technique：Talcum powder, light calcium carbonate powder, vermiculite powder and distilled water are mixed
Grinding pulp is closed, calgon is then added and hexadecane trimethyl ammonium bromide is well mixed, ultrasonically treated 20-40min,
40-60 DEG C is then heated to, 20-40min is stirred in 800-1200r/min rotating speeds, is subsequently cooled to room temperature, it is dry in 50-70 DEG C
Dry 7-9h, then grinding obtains modified filler.
Preferably, in the preparation technology of modified filler, talcum powder, light calcium carbonate powder, vermiculite powder, distilled water, calgon
Weight ratio with hexadecane trimethyl ammonium bromide is 2-5：1-3：3-6：6-12：3-5：2-4.
Preferably, UV resistant modified additive is prepared by following technique：Titanium dioxide is scattered in ethanol water
In, hexadecyl trimethoxy ammonium chloride, polyvinylpyrrolidone and six inclined sodium sulphate are then added dropwise in ultrasonic disperse 10-30min
Well mixed, magnetic agitation 15-25min then adjusts pH to 8.5-9.5 with ammoniacal liquor, then adds tetraethyl orthosilicate and ultraviolet
Absorbent UV531 is well mixed, and is warming up to 30-40 DEG C, is incubated 22-26h, and then centrifugation is washed to pH most 7, is subsequently cooled to
Room temperature obtains UV resistant modified additive.
Preferably, in the preparation technology of UV resistant modified additive, titanium dioxide, ethanol water, cetyl front three
Epoxide ammonium chloride, polyvinylpyrrolidone, six inclined sodium sulphate, tetraethyl orthosilicate and ultra-violet absorber UV531 weight ratio are
2-5：1-3：2-4：3-5：1.5-3.5：4-6：2-5.
The preparation method of the present invention, including：Mill is warming up to 165-170 DEG C, then by nitrile rubber, silicon rubber,
Butadiene rubber, alkyd resin, neoprene, epoxy acrylic resin, CSM, trifluoro propyl methyl-silicone oil,
Firebrake ZB, nano-graphite, carbon black, blanc fixe, polyphosphoric acids aluminium, nano silicon, mica powder, Firebrake ZB, nano ceramics
Powder, glass fibre, magnesia, kodalk, isocyanates, polysiloxanes, diisooctyl phthalate, silane coupler
KH-570, chlorinated paraffin, calcium carbonate, antimony oxide, APP, styrene, chlorinated paraffin, vulcanizing agent DTDM, plasticizer,
High-low temperature resistant modified additive, modified filler and UV resistant modified additive, by bag roller, eat powder, turn refining, and are cooled to room temperature, so
After park 22-26h after 175-185 DEG C, 8-12Mpa vulcanizing treatment 4-6min, be cooled to room temperature and obtain floating power station with shatter-proof
Dynamic tension UV resistant high-low temperature resistant CABLE MATERIALS.
A kind of floating power station vibration resistance tension UV resistant high-low temperature resistant CABLE MATERIALS of the present invention, its raw material includes butyronitrile
Rubber, silicon rubber, butadiene rubber, alkyd resin, neoprene, epoxy acrylic resin, CSM, trifluoropropyl
Ylmethyl silicone oil, Firebrake ZB, nano-graphite, carbon black, blanc fixe, polyphosphoric acids aluminium, nano silicon, mica powder, boric acid
Zinc, nano-ceramic powder, glass fibre, magnesia, kodalk, isocyanates, polysiloxanes, diisooctyl phthalate,
Silane coupling reagent KH-570, chlorinated paraffin, calcium carbonate, antimony oxide, APP, styrene, chlorinated paraffin, vulcanizing agent
DTDM, plasticizer, high-low temperature resistant modified additive, modified filler and UV resistant modified additive.Wherein with nitrile rubber, silicon rubber
Glue, butadiene rubber, alkyd resin, neoprene, epoxy acrylic resin and CSM as rubber base-material, with
Trifluoro propyl methyl-silicone oil, Firebrake ZB, nano-graphite, carbon black, blanc fixe, polyphosphoric acids aluminium, nano silicon, mica
Powder, Firebrake ZB, nano-ceramic powder, glass fibre, magnesia, kodalk, isocyanates, polysiloxanes, phthalic acid two
Different monooctyl ester, Silane coupling reagent KH-570, chlorinated paraffin, calcium carbonate, antimony oxide, APP, styrene, chlorinated paraffin,
Vulcanizing agent DTDM, plasticizer, high-low temperature resistant modified additive, modified filler and UV resistant modified additive pass through as reinforcement material
The cooperation of rubber base-material and reinforcement material, obtained CABLE MATERIALS has excellent vibration resistance, tension, UV resistant and resistant of high or low temperature
Energy.Wherein high-low temperature resistant modified additive is by the way that MTES and dimethyldimethoxysil,ne are well mixed, so
Glacial acetic acid, diacetone alcohol and ethanol water are added afterwards well mixed, after heating, continue heating and heat preservation, then add sodium acetate
Well mixed, temperature rising reflux is continuously heating to distillation, then adds modified polyether silicone oil and isopropanol is well mixed, stirring, quiet
Put, be cooled to room temperature and obtain material a, methyl acrylate, butyl acrylate, methyl methacrylate are then added into material a
Well mixed, the heating and heat preservation with styrene, under nitrogen protection, adds azodiisobutyronitrile and aminopropyl triethoxysilane is mixed
Close uniform, be cooled to room temperature and obtain high-low temperature resistant modified additive.With MTES and dimethyldimethoxysil,ne
For monomer, polysiloxanes is prepared by cohydrolysis/polycondensation, then is blended with the acrylic resin of synthesis, cable of the present invention is applied to
In material so that hardness effectively improves, mechanical strength is improved to a certain extent, while effectively increasing cable of the present invention
The high and low temperature resistance of material.Wherein, modified filler by by talcum powder, light calcium carbonate powder, vermiculite powder and distilled water mixed grinding into
Pulpous state, then adds calgon and hexadecane trimethyl ammonium bromide is well mixed, ultrasonically treated, then heats up, stirs, so
After be cooled to room temperature, dry, then grinding obtain modified filler.Wherein, UV resistant modified additive is by the way that titanium dioxide is divided
Dissipate in ethanol water, ultrasonic disperse, hexadecyl trimethoxy ammonium chloride, polyvinylpyrrolidone and six are then added dropwise inclined
Sodium sulphate is well mixed, and magnetic agitation then adjusts pH with ammoniacal liquor, then adds tetraethyl orthosilicate and ultra-violet absorber UV531
It is well mixed, heat up, insulation, centrifugation washing is subsequently cooled to room temperature and obtains UV resistant modified additive, applies to electricity of the invention
In cable material, the anti-ultraviolet property of CABLE MATERIALS of the present invention can be effectively improved, floating power station environment is met to the resistance to purple of CABLE MATERIALS
The performance requirement of outside line.The CABLE MATERIALS of the present invention is used for floating power station, with excellent vibration resistance, tension, UV resistant and resistance to
High temperature performance.
Embodiment
The present invention is described in detail with reference to specific embodiment, it should be appreciated that embodiment is served only for illustrating this hair
It is bright, rather than for limiting the invention, any modification made on the basis of the present invention, equivalent substitution etc. are in this hair
In bright protection domain.
Embodiment 1
A kind of floating power station proposed by the present invention vibration resistance tension UV resistant high-low temperature resistant CABLE MATERIALS, its raw material is by weight
Amount part includes：60 parts of nitrile rubber, 20 parts of silicon rubber, 10 parts of butadiene rubber, 5 parts of alkyd resin, 6 parts of neoprene, epoxy third
3.5 parts of olefin(e) acid resin, 4 parts of CSM, 5 parts of trifluoro propyl methyl-silicone oil, 3 parts of Firebrake ZB, 4 parts of nano-graphite,
4.5 parts of carbon black, 6 parts of blanc fixe, 3 parts of polyphosphoric acids aluminium, 3.5 parts of nano silicon, 4 parts of mica powder, 3 parts of Firebrake ZB, receive
4 parts of ceramic powder of rice, 6 parts of glass fibre, 6 parts of magnesia, 5 parts of kodalk, 5.5 parts of isocyanates, 3.5 parts of polysiloxanes, neighbour
5.5 parts of phthalic acid di-isooctyl, 3.5 parts of Silane coupling reagent KH-570,2.5 parts of chlorinated paraffin, 2 parts of calcium carbonate, three oxidations two
3 parts of antimony, 4 parts of APP, 6 parts of styrene, 3 parts of chlorinated paraffin, 4 parts of vulcanizing agent DTDM, 4 parts of plasticizer, high-low temperature resistant are modified
3.5 parts of auxiliary agent, 2 parts of modified filler, 4 parts of UV resistant modified additive.
Embodiment 2
A kind of floating power station proposed by the present invention vibration resistance tension UV resistant high-low temperature resistant CABLE MATERIALS, its raw material is by weight
Amount part includes：30 parts of nitrile rubber, 30 parts of silicon rubber, 5 parts of butadiene rubber, 8 parts of alkyd resin, 3 parts of neoprene, propylene oxide
5 parts of acid resin, 2 parts of CSM, 8 parts of trifluoro propyl methyl-silicone oil, 1 part of Firebrake ZB, 6 parts of nano-graphite, carbon black 3
Part, 8 parts of blanc fixe, 1 part of polyphosphoric acids aluminium, 5 parts of nano silicon, 3 parts of mica powder, 5 parts of Firebrake ZB, nano-ceramic powder 3
Part, 8 parts of glass fibre, 4 parts of magnesia, 8 parts of kodalk, 3 parts of isocyanates, 6 parts of polysiloxanes, phthalic acid two are different pungent
3 parts of ester, 5 parts of Silane coupling reagent KH-570,1 part of chlorinated paraffin, 3 parts of calcium carbonate, 2 parts of antimony oxide, 5 parts of APP, benzene
4 parts of ethene, 5 parts of chlorinated paraffin, DTDM2 parts of vulcanizing agent, 5 parts of plasticizer, 2 parts of high-low temperature resistant modified additive, 3 parts of modified filler,
2 parts of UV resistant modified additive.
High-low temperature resistant modified additive is prepared by following technique：By weight by 5 parts of MTESs and 6 parts
Dimethyldimethoxysil,ne is well mixed, and 40min is stirred in 650r/min rotating speeds, then add 1 part of glacial acetic acid, 5 parts double third
Keto-alcohol and 3 parts of ethanol waters are well mixed, and are warming up to 40 DEG C, are stirred 50min in 850r/min rotating speeds, be continuously heating to 50
DEG C, 3h is incubated, 1 part of sodium acetate is then added and is well mixed, be warming up to 90 DEG C, flow back 2h, 110 DEG C of distillations are continuously heating to
20min, then adds 5 parts of modified polyether silicone oil and 1 part of isopropanol is well mixed, and stirs 20min in 550r/min rotating speeds, stands
3h, is cooled to room temperature and obtains material a, and 2 parts of methyl acrylates, 6 parts of butyl acrylates, 2 parts of methyl-props are then added into material a
E pioic acid methyl ester and 4 parts of styrene are well mixed, and are warming up to 70 DEG C, are incubated 4h, under nitrogen protection, add 1 part of isobutyl of azo two
Nitrile and 6 parts of aminopropyl triethoxysilanes are well mixed, and are stirred 5h in 350r/min rotating speeds, are cooled to room temperature and obtain high-low temperature resistant
Modified additive.
Modified filler is prepared by following technique：By weight by 2 parts of talcum powder, 3 parts of light calcium carbonate powders, 3 parts of vermiculite powders
With 12 parts of distilled water mixed grinding pulps, then add 3 parts of calgons and 4 parts of hexadecane trimethyl ammonium bromide mixing are equal
Even, ultrasonically treated 20min then heats to 60 DEG C, stirs 40min in 800r/min rotating speeds, room temperature is subsequently cooled to, in 50 DEG C
9h is dried, then grinding obtains modified filler.
UV resistant modified additive is prepared by following technique：2 parts of titanium dioxide are scattered in 3 parts of ethanol by weight
In the aqueous solution, ultrasonic disperse 10min, then be added dropwise 4 parts of hexadecyl trimethoxy ammonium chlorides, 3 parts of polyvinylpyrrolidones and
3.5 part of six inclined sodium sulphate is well mixed, and magnetic agitation 15min then adjusts pH to 9.5 with ammoniacal liquor, then adds 4 parts of positive silicic acid
Ethyl ester and 5 parts of ultra-violet absorber UV531 are well mixed, and are warming up to 30 DEG C, are incubated 26h, and then centrifugation is washed to pH most 7,
It is subsequently cooled to room temperature and obtains UV resistant modified additive.
Embodiment 3
A kind of floating power station proposed by the present invention vibration resistance tension UV resistant high-low temperature resistant CABLE MATERIALS, its raw material is by weight
Amount part includes：90 parts of nitrile rubber, 10 parts of silicon rubber, 15 parts of butadiene rubber, 2 parts of alkyd resin, 9 parts of neoprene, epoxy third
2 parts of olefin(e) acid resin, 6 parts of CSM, 2 parts of trifluoro propyl methyl-silicone oil, 5 parts of Firebrake ZB, 2 parts of nano-graphite, charcoal
Black 6 parts, 4 parts of blanc fixe, 5 parts of polyphosphoric acids aluminium, 2 parts of nano silicon, 5 parts of mica powder, 1 part of Firebrake ZB, nano ceramics
5 parts of powder, 4 parts of glass fibre, 8 parts of magnesia, 2 parts of kodalk, 8 parts of isocyanates, 1 part of polysiloxanes, phthalic acid two
Different 8 parts of monooctyl ester, 2 parts of Silane coupling reagent KH-570,4 parts of chlorinated paraffin, 1 part of calcium carbonate, 4 parts of antimony oxide, APP 3
Part, 8 parts of styrene, 1 part of chlorinated paraffin, DTDM6 parts of vulcanizing agent, 3 parts of plasticizer, 5 parts of high-low temperature resistant modified additive, modified filler
1 part, 6 parts of UV resistant modified additive.
High-low temperature resistant modified additive is prepared by following technique：By weight by 15 parts of MTESs and 2
Part dimethyldimethoxysil,ne is well mixed, and 20min is stirred in 850r/min rotating speeds, then add 4 parts of glacial acetic acid, 2 parts it is double
Pyruvic alcohol and 6 parts of ethanol waters are well mixed, and are warming up to 30 DEG C, are stirred 30min in 980r/min rotating speeds, be continuously heating to 60
DEG C, 1h is incubated, 5 parts of sodium acetates is then added and is well mixed, be warming up to 70 DEG C, flow back 4h, 100 DEG C of distillations are continuously heating to
40min, then adds 2 parts of modified polyether silicone oil and 5 parts of isopropanols are well mixed, and stirs 40min in 450r/min rotating speeds, stands
1h, is cooled to room temperature and obtains material a, and 4 parts of methyl acrylates, 3 parts of butyl acrylates, 6 parts of methyl-props are then added into material a
E pioic acid methyl ester and 3 parts of styrene are well mixed, and are warming up to 80 DEG C, are incubated 2h, under nitrogen protection, add 4 parts of isobutyls of azo two
Nitrile and 2 parts of aminopropyl triethoxysilanes are well mixed, and are stirred 3h in 450r/min rotating speeds, are cooled to room temperature and obtain high-low temperature resistant
Modified additive.
Modified filler is prepared by following technique：By weight by 5 parts of talcum powder, 1 part of light calcium carbonate powder, 6 parts of vermiculite powders
With 6 parts of distilled water mixed grinding pulps, then add 5 parts of calgons and 2 parts of hexadecane trimethyl ammonium bromide mixing are equal
Even, ultrasonically treated 40min then heats to 40 DEG C, stirs 20min in 1200r/min rotating speeds, room temperature is subsequently cooled to, in 70
DEG C dry 7h, then grinding obtain modified filler.
UV resistant modified additive is prepared by following technique：5 parts of titanium dioxide are scattered in 1 part of ethanol by weight
In the aqueous solution, 2 parts of hexadecyl trimethoxy ammonium chlorides, 3-5 parts of polyvinylpyrrolidones are then added dropwise in ultrasonic disperse 30min
Well mixed with 3.5 part of six inclined sodium sulphate, magnetic agitation 15min then adjusts pH to 9.5 with ammoniacal liquor, then adds 4 parts of positive silicon
Acetoacetic ester and 5 parts of ultra-violet absorber UV531 are well mixed, and are warming up to 30 DEG C, are incubated 26h, and then centrifugation is washed to pH most
7, it is subsequently cooled to room temperature and obtains UV resistant modified additive.
Embodiment 4
A kind of floating power station proposed by the present invention vibration resistance tension UV resistant high-low temperature resistant CABLE MATERIALS, its raw material is by weight
Amount part includes：35 parts of nitrile rubber, 25 parts of silicon rubber, 8 parts of butadiene rubber, 7 parts of alkyd resin, 4 parts of neoprene, propylene oxide
4 parts of acid resin, 3 parts of CSM, 7 parts of trifluoro propyl methyl-silicone oil, 2 parts of Firebrake ZB, 5 parts of nano-graphite, carbon black 4
Part, 7 parts of blanc fixe, 2 parts of polyphosphoric acids aluminium, 4 parts of nano silicon, 3.5 parts of mica powder, 4 parts of Firebrake ZB, nano-ceramic powder
3.5 parts, 7 parts of glass fibre, 5 parts of magnesia, 7 parts of kodalk, 4 parts of isocyanates, 5 parts of polysiloxanes, phthalic acid two
Different 4 parts of monooctyl ester, 4 parts of Silane coupling reagent KH-570,2 parts of chlorinated paraffin, 2.5 parts of calcium carbonate, 2.5 parts of antimony oxide, polyphosphoric acid
4.5 parts of ammonium, 5 parts of styrene, 4 parts of chlorinated paraffin, 3 parts of vulcanizing agent DTDM, 4.5 parts of plasticizer, 3 parts of high-low temperature resistant modified additive,
2.5 parts of modified filler, 3 parts of UV resistant modified additive.
High-low temperature resistant modified additive is prepared by following technique：By weight by 8 parts of MTESs and 5 parts
Dimethyldimethoxysil,ne is well mixed, and 35min is stirred in 680r/min rotating speeds, then add 2 parts of glacial acetic acid, 4 parts double third
Keto-alcohol and 4 parts of ethanol waters are well mixed, and are warming up to 38 DEG C, are stirred 45min in 860r/min rotating speeds, be continuously heating to 52
DEG C, 2.5h is incubated, 2 parts of sodium acetates is then added and is well mixed, be warming up to 85 DEG C, flow back 2.5h, 108 DEG C of distillations are continuously heating to
25min, then adds 4 parts of modified polyether silicone oil and 2 parts of isopropanols are well mixed, and stirs 25min in 520r/min rotating speeds, stands
2.5h, is cooled to room temperature and obtains material a, and 2.5 parts of methyl acrylates, 5 parts of butyl acrylates, 3 parts of first are then added into material a
Base methyl acrylate and 3.8 parts of styrene are well mixed, and are warming up to 72 DEG C, are incubated 3.5h, under nitrogen protection, add 2 parts of idols
Nitrogen bis-isobutyronitrile and 5 parts of aminopropyl triethoxysilanes are well mixed, and are stirred 4.5h in 380r/min rotating speeds, are cooled to room temperature and obtain
To high-low temperature resistant modified additive.
Modified filler is prepared by following technique：By weight by 3 parts of talcum powder, 2.5 parts of light calcium carbonate powders, 4 parts of vermiculite powers
Body and 11 parts of distilled water mixed grinding pulps, then add 3.5 parts of calgons and 3.5 parts of hexadecane trimethyl ammonium bromides
Well mixed, ultrasonically treated 25min then heats to 55 DEG C, stirs 35min in 850r/min rotating speeds, is subsequently cooled to room temperature,
In 55 DEG C of dry 8.5h, then grinding obtains modified filler.
UV resistant modified additive is prepared by following technique：3 parts of titanium dioxide are scattered in 2.5 parts of second by weight
In alcohol solution, 3.5 parts of hexadecyl trimethoxy ammonium chlorides, 3.5 parts of polyvinyl pyrroles are then added dropwise in ultrasonic disperse 15min
Alkanone and 3.2 part of six inclined sodium sulphate are well mixed, and magnetic agitation 18min then adjusts pH to 9.2 with ammoniacal liquor, then adds 4.5
Part tetraethyl orthosilicate and 4 parts of ultra-violet absorber UV531 are well mixed, and are warming up to 32 DEG C, are incubated 25h, and then centrifugation is washed to
PH most 7, is subsequently cooled to room temperature and obtains UV resistant modified additive.
Embodiment 5
A kind of floating power station proposed by the present invention vibration resistance tension UV resistant high-low temperature resistant CABLE MATERIALS, its raw material is by weight
Amount part includes：85 parts of nitrile rubber, 15 parts of silicon rubber, 12 parts of butadiene rubber, 3 parts of alkyd resin, 8 parts of neoprene, epoxy third
3 parts of olefin(e) acid resin, 5 parts of CSM, 3 parts of trifluoro propyl methyl-silicone oil, 4 parts of Firebrake ZB, 3 parts of nano-graphite, charcoal
Black 5 parts, 5 parts of blanc fixe, 4 parts of polyphosphoric acids aluminium, 3 parts of nano silicon, 4.5 parts of mica powder, Firebrake ZB 2 part, nanometer pottery
4.5 parts of porcelain powder, 5 parts of glass fibre, 7 parts of magnesia, 3 parts of kodalk, 7 parts of isocyanates, 2 parts of polysiloxanes, O-phthalic
It is sour 7 parts of di-isooctyl, 3 parts of Silane coupling reagent KH-570,3 parts of chlorinated paraffin, 1.5 parts of calcium carbonate, 3.5 parts of antimony oxide, poly-
3.5 parts of ammonium phosphate, 7 parts of styrene, 2 parts of chlorinated paraffin, 5 parts of vulcanizing agent DTDM, 3.5 parts of plasticizer, high-low temperature resistant modified additive
4 parts, 1.5 parts of modified filler, 5 parts of UV resistant modified additive.
High-low temperature resistant modified additive is prepared by following technique：By weight by 12 parts of MTESs and 3
Part dimethyldimethoxysil,ne is well mixed, and 25min is stirred in 820r/min rotating speeds, then add 3 parts of glacial acetic acid, 3 parts it is double
Pyruvic alcohol and 5 parts of ethanol waters are well mixed, and are warming up to 32 DEG C, are stirred 35min in 970r/min rotating speeds, be continuously heating to 58
DEG C, 1.5h is incubated, 4 parts of sodium acetates is then added and is well mixed, be warming up to 75 DEG C, flow back 3.5h, 102 DEG C of distillations are continuously heating to
35min, then adds 3 parts of modified polyether silicone oil and 4 parts of isopropanols are well mixed, and stirs 35min in 480r/min rotating speeds, stands
1.5h, is cooled to room temperature and obtains material a, and 3.5 parts of methyl acrylates, 4 parts of butyl acrylates, 5 parts of first are then added into material a
Base methyl acrylate and 3.2 parts of styrene are well mixed, and are warming up to 78 DEG C, are incubated 2.5h, under nitrogen protection, add 3 parts of idols
Nitrogen bis-isobutyronitrile and 3 parts of aminopropyl triethoxysilanes are well mixed, and are stirred 3.5h in 420r/min rotating speeds, are cooled to room temperature and obtain
To high-low temperature resistant modified additive.
Modified filler is prepared by following technique：By weight by 4 parts of talcum powder, 1.5 parts of light calcium carbonate powders, 5 parts of vermiculite powers
Body and 7 parts of distilled water mixed grinding pulps, then add 4.5 parts of calgons and 2.5 parts of hexadecane trimethyl ammonium bromides
Well mixed, ultrasonically treated 35min then heats to 45 DEG C, stirs 25min in 1150r/min rotating speeds, is subsequently cooled to room
Temperature, in 65 DEG C of dry 7.5h, then grinding obtains modified filler.
UV resistant modified additive is prepared by following technique：4 parts of titanium dioxide are scattered in 1.5 parts of second by weight
In alcohol solution, 2.5 parts of hexadecyl trimethoxy ammonium chlorides, 4.5 parts of polyvinyl pyrroles are then added dropwise in ultrasonic disperse 25min
Alkanone and 1.8 part of six inclined sodium sulphate are well mixed, and magnetic agitation 22min then adjusts pH to 8.8 with ammoniacal liquor, then adds 5.5
Part tetraethyl orthosilicate and 3 parts of ultra-violet absorber UV531 are well mixed, and are warming up to 38 DEG C, are incubated 23h, and then centrifugation is washed to
PH most 7, is subsequently cooled to room temperature and obtains UV resistant modified additive.
By the vibration resistance tension UV resistant high-low temperature resistant CABLE MATERIALS progressive of the floating power station in embodiment 1- embodiments 5
It can detect, obtain data as shown in table 1.
Table 1：
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.
Claims (8)
1. a kind of floating power station vibration resistance tension UV resistant high-low temperature resistant CABLE MATERIALS, it is characterised in that its raw material is by weight
Part includes：30-90 parts of nitrile rubber, 10-30 parts of silicon rubber, 5-15 parts of butadiene rubber, 2-8 parts of alkyd resin, neoprene 3-9
Part, 2-5 parts of epoxy acrylic resin, 2-6 parts of CSM, 2-8 parts of trifluoro propyl methyl-silicone oil, Firebrake ZB 1-5
Part, 2-6 parts of nano-graphite, 3-6 parts of carbon black, 4-8 parts of blanc fixe, 1-5 parts of polyphosphoric acids aluminium, 2-5 parts of nano silicon, cloud
3-5 parts of female powder, 1-5 parts of Firebrake ZB, 3-5 parts of nano-ceramic powder, 4-8 parts of glass fibre, 4-8 parts of magnesia, kodalk 2-8
Part, 3-8 parts of isocyanates, 1-6 parts of polysiloxanes, 3-8 parts of diisooctyl phthalate, Silane coupling reagent KH-570 2-5
Part, 1-4 parts of chlorinated paraffin, 1-3 parts of calcium carbonate, 2-4 parts of antimony oxide, 3-5 parts of APP, 4-8 parts of styrene, chlorination stone
1-5 parts of wax, 2-6 parts of vulcanizing agent DTDM, 3-5 parts of plasticizer, 2-5 parts of high-low temperature resistant modified additive, 1-3 parts of modified filler, resistance to purple
2-6 parts of outside line modified additive.
2. floating power station according to claim 1 vibration resistance tension UV resistant high-low temperature resistant CABLE MATERIALS, its feature exists
In the raw material of high-low temperature resistant modified additive includes by weight：5-15 parts of MTES, dimethylformamide dimethyl epoxide silicon
2-6 parts of alkane, 1-4 parts of glacial acetic acid, 2-5 parts of diacetone alcohol, 3-6 parts of ethanol water, 1-5 parts of sodium acetate, modified polyether silicone oil 2-5
Part, 1-5 parts of isopropanol, 2-4 parts of methyl acrylate, 3-6 parts of butyl acrylate, 2-6 parts of methyl methacrylate, styrene 3-4
Part, 1-4 parts of azodiisobutyronitrile, 2-6 parts of aminopropyl triethoxysilane.
3. floating power station according to claim 1 or 2 vibration resistance tension UV resistant high-low temperature resistant CABLE MATERIALS, its feature
It is, high-low temperature resistant modified additive is prepared by following technique：By MTES and dimethylformamide dimethyl epoxide silicon
Alkane is well mixed, and is then added glacial acetic acid, diacetone alcohol and ethanol water and is well mixed, and after heating, continues heating and heat preservation, so
Sodium acetate is added afterwards to be well mixed, temperature rising reflux is continuously heating to distillation, then add modified polyether silicone oil and isopropanol mixing
Uniformly, stir, stand, be cooled to room temperature and obtain material a, methyl acrylate, butyl acrylate, first are then added into material a
Base methyl acrylate and styrene are well mixed, heating and heat preservation, under nitrogen protection, add azodiisobutyronitrile and aminopropyl three
Ethoxysilane is well mixed, and is cooled to room temperature and is obtained high-low temperature resistant modified additive.
4. the floating power station vibration resistance tension UV resistant high-low temperature resistant CABLE MATERIALS according to claim any one of 1-3,
Characterized in that, high-low temperature resistant modified additive is prepared by following technique：By MTES and dimethylformamide dimethyl
TMOS is well mixed, and 20-40min is stirred in 650-850r/min rotating speeds, then adds glacial acetic acid, diacetone alcohol and ethanol
The aqueous solution is well mixed, and is warming up to 30-40 DEG C, is stirred 30-50min in 850-980r/min rotating speeds, is continuously heating to 50-60
DEG C, 1-3h is incubated, sodium acetate is then added and is well mixed, be warming up to 70-90 DEG C, flow back 2-4h, is continuously heating to 100-110 DEG C
20-40min is distilled, modified polyether silicone oil is then added and isopropanol is well mixed, 20- is stirred in 450-550r/min rotating speeds
40min, stands 1-3h, is cooled to room temperature and obtains material a, and methyl acrylate, butyl acrylate, first are then added into material a
Base methyl acrylate and styrene are well mixed, are warming up to 70-80 DEG C, are incubated 2-4h, under nitrogen protection, add azo two different
Butyronitrile and aminopropyl triethoxysilane are well mixed, stir 3-5h in 350-450r/min rotating speeds, are cooled to room temperature and obtain resistance to
High/low temperature modified additive.
5. the floating power station vibration resistance tension UV resistant high-low temperature resistant CABLE MATERIALS according to claim any one of 1-4,
Characterized in that, modified filler is prepared by following technique：Talcum powder, light calcium carbonate powder, vermiculite powder and distilled water are mixed and ground
Pulpous state is worn into, calgon is then added and hexadecane trimethyl ammonium bromide is well mixed, ultrasonically treated 20-40min, then
40-60 DEG C is warming up to, 20-40min is stirred in 800-1200r/min rotating speeds, room temperature is subsequently cooled to, in 50-70 DEG C of dry 7-
9h, then grinding obtains modified filler.
6. the floating power station vibration resistance tension UV resistant high-low temperature resistant CABLE MATERIALS according to claim any one of 1-5,
Characterized in that, in the preparation technology of modified filler, talcum powder, light calcium carbonate powder, vermiculite powder, distilled water, calgon and ten
The weight ratio of six alkane trimethylammonium bromides is 2-5：1-3：3-6：6-12：3-5：2-4.
7. the floating power station vibration resistance tension UV resistant high-low temperature resistant CABLE MATERIALS according to claim any one of 1-6,
Characterized in that, UV resistant modified additive is prepared by following technique：Titanium dioxide is scattered in ethanol water, surpassed
Sound disperses 10-30min, and hexadecyl trimethoxy ammonium chloride, polyvinylpyrrolidone and six inclined sodium sulphate mixing are then added dropwise
Uniformly, magnetic agitation 15-25min then adjusts pH to 8.5-9.5 with ammoniacal liquor, then adds tetraethyl orthosilicate and ultraviolet radiation absorption
Agent UV531 is well mixed, and is warming up to 30-40 DEG C, is incubated 22-26h, and then centrifugation is washed to pH most 7, is subsequently cooled to room temperature
Obtain UV resistant modified additive.
8. the floating power station vibration resistance tension UV resistant high-low temperature resistant CABLE MATERIALS according to claim any one of 1-7,
Characterized in that, in the preparation technology of UV resistant modified additive, titanium dioxide, ethanol water, hexadecyl trimethoxy
Ammonium chloride, polyvinylpyrrolidone, six inclined sodium sulphate, tetraethyl orthosilicate and ultra-violet absorber UV531 weight ratio are 2-5：
1-3：2-4：3-5：1.5-3.5：4-6：2-5.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108178902A (en) * | 2017-12-29 | 2018-06-19 | 定远县丹宝树脂有限公司 | A kind of UV resistant epoxy resin and preparation method thereof |
| CN108395590A (en) * | 2018-02-28 | 2018-08-14 | 天长市荣盛有机硅科技有限公司 | A kind of composite silicone rubber material applied widely |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102911409A (en) * | 2012-09-18 | 2013-02-06 | 铜陵市铜都特种线缆厂 | Environment-friendly tensile high-temperature-resistant control cable material and preparation method thereof |
| CN104558716A (en) * | 2015-01-14 | 2015-04-29 | 四川大学 | Efficient halogen-free flame retardant rubber system as well as preparation method thereof |
| CN105111536A (en) * | 2015-08-27 | 2015-12-02 | 江苏易成电力器材有限公司 | High-toughness power cable sheath and preparation method thereof |
| CN106009102A (en) * | 2016-06-20 | 2016-10-12 | 河南省亚安绝缘材料厂有限公司 | Insulating material for nuclear power plant and production technology thereof |
-
2017
- 2017-04-19 CN CN201710257698.9A patent/CN107151357A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102911409A (en) * | 2012-09-18 | 2013-02-06 | 铜陵市铜都特种线缆厂 | Environment-friendly tensile high-temperature-resistant control cable material and preparation method thereof |
| CN104558716A (en) * | 2015-01-14 | 2015-04-29 | 四川大学 | Efficient halogen-free flame retardant rubber system as well as preparation method thereof |
| CN105111536A (en) * | 2015-08-27 | 2015-12-02 | 江苏易成电力器材有限公司 | High-toughness power cable sheath and preparation method thereof |
| CN106009102A (en) * | 2016-06-20 | 2016-10-12 | 河南省亚安绝缘材料厂有限公司 | Insulating material for nuclear power plant and production technology thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108178902A (en) * | 2017-12-29 | 2018-06-19 | 定远县丹宝树脂有限公司 | A kind of UV resistant epoxy resin and preparation method thereof |
| CN108395590A (en) * | 2018-02-28 | 2018-08-14 | 天长市荣盛有机硅科技有限公司 | A kind of composite silicone rubber material applied widely |
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