CN107216558A - A kind of high-wearing feature fluorescent mobile phone protects cover material - Google Patents
A kind of high-wearing feature fluorescent mobile phone protects cover material Download PDFInfo
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
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- C08L2205/00—Polymer mixtures characterised by other features
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- C08L2205/00—Polymer mixtures characterised by other features
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Abstract
Cover material is protected the invention discloses a kind of high-wearing feature fluorescent mobile phone; its raw material includes polysulfonate polyethylene rubber, butadiene-styrene rubber, Lauxite, polyvinyl chloride, makrolon, low density polyethylene (LDPE), polystyrene, sulphur, barium sulfate, Firebrake ZB, tossa, talcum powder, trioctyl trimellitate (TOTM), 2, the methylphenol of 6 di-t-butyl 4, cumyl peroxide, phthalic anhydride, lubricant, foaming agent, wear-resisting reinforcer and Fluorescence Increasing auxiliary agent.The high-wearing feature fluorescent mobile phone protection cover material of the present invention has excellent anti-wear performance and fluorescence property.
Description
Technical field
The present invention relates to the technical field of mobile phone shell material, more particularly to a kind of high-wearing feature fluorescent mobile phone protective case material
Material.
Background technology
Conventional handset sheathing material mainly has PC, ABS and PC and ABS to be combined the sheathing material of three types.PC
Name makrolon, the performance characteristics of PC materials have：Intensity is high, and tensile strength and flexural strength are higher；High temperature resistant, makes for a long time
With being resistant to 130 degree celsius temperature environment；The transparency is good, nontoxic.ABS (propylene fat-butadiene-styrol copolymer) material
Performance characteristics have low intensity, and tensile strength and flexural strength are relatively low；Non-refractory, temperature, which is used for a long time, must not be higher than 60
℃；Mobility, coloring and surface spraying and plating performance compared with.Mobile phone when in use, is required the anti-wear performance of its phone housing
It is very high, and at night in use, its fluorescence property also can be mobile phone using offering convenience, so needing a kind of high-wearing feature of design badly
Fluorescent mobile phone protects cover material to solve the problems of the prior art.
The content of the invention
To solve technical problem present in background technology, the present invention proposes a kind of high-wearing feature fluorescent mobile phone protective case material
Material, with excellent anti-wear performance and fluorescence property.
A kind of high-wearing feature fluorescent mobile phone protection cover material proposed by the present invention, its raw material includes by weight：Polysulfonate
80-120 parts of polyethylene rubber, 15-35 parts of butadiene-styrene rubber, 5-15 parts of Lauxite, 6-12 parts of polyvinyl chloride, makrolon 8-16
Part, 5-15 parts of low density polyethylene (LDPE), 3-9 parts of polystyrene, 2-5 parts of sulphur, 5-15 parts of barium sulfate, 2-5 parts of Firebrake ZB, jute are fine
1-6 parts of dimension, 2-5 parts of talcum powder, 2-5 parts of trioctyl trimellitate (TOTM), 4-8 parts of 2,6 di tert butyl 4 methyl phenol, peroxidating two
2-9 parts of isopropylbenzene, 3-4 parts of phthalic anhydride, 2-6 parts of lubricant, 2-6 parts of foaming agent, wear-resisting reinforcer 12-24 parts, it is glimmering
8-16 parts of light reinforcing aids.
Preferably, the raw material of wear-resisting reinforcer includes by weight：5-15 parts of montmorillonite, 3-6 parts of multi-walled carbon nanotube,
2-5 parts of dichloroethanes, 1-4 parts of thionyl chloride, 3-6 parts of 2- propylene -1- alcohol, 2-5 parts of wood fiber powder, hollow glass micropearl 1-4
Part, 3-5 parts of silicon powder, 2-6 parts of magnesium hydroxide, 1-4 parts of methacrylate, 4-6 parts of silane resin acceptor kh-550, silicone oil 2-5
Part, 3-6 parts of styrene, 1-8 parts of butyl acrylate.
Preferably, wear-resisting reinforcer is prepared by following technique：By montmorillonite, multi-walled carbon nanotube, dichloroethanes
Well mixed with thionyl chloride, stirring then heats up, and is incubated, and is cooled to addition 2- propylene -1- alcohol after room temperature and is well mixed, connects
Heating, is incubated, is washed, centrifugation is cooled to room temperature after drying and obtains material A；By wood fiber powder, hollow glass micropearl and silicon
Micro mist is well mixed, and is sealed stirring at low speed, is added magnesium hydroxide, methacrylate, silane resin acceptor kh-550 and silicone oil
It is well mixed, heat up, then stirring adds material A, styrene and butyl acrylate and be well mixed, heat up, insulation is then stirred
Mix, be cooled to room temperature and obtain wear-resisting reinforcer.
Preferably, wear-resisting reinforcer is prepared by following technique：By montmorillonite, multi-walled carbon nanotube, dichloroethanes
It is well mixed with thionyl chloride, 20-40min is stirred in 450-650r/min rotating speeds, 80-90 DEG C is then warming up to, 20- is incubated
50min, is cooled to addition 2- propylene -1- alcohol after room temperature and is well mixed, be then warming up to 45-55 DEG C, be incubated 1-3h, wash, from
The heart, is cooled to room temperature after drying and obtains material A；Wood fiber powder, hollow glass micropearl and silicon powder are well mixed, 45-55
DEG C sealing stirring at low speed 5-10min, add magnesium hydroxide, methacrylate, silane resin acceptor kh-550 and silicone oil mixing
Uniformly, 110-120 DEG C is warming up to, 10-20min is stirred in 650-850r/min rotating speeds, material A, styrene and third is then added
Olefin(e) acid butyl ester is well mixed, and is warming up to 135-145 DEG C, is incubated 15-35min, then stirs 1- in 1500-2500r/min rotating speeds
2h, is cooled to room temperature and obtains wear-resisting reinforcer.
Preferably, the raw material of Fluorescence Increasing auxiliary agent includes by weight：15-25 parts of bentonite, silane coupler KH-560
4-6 parts, 2-5 parts of acetone, 1-4 parts of epoxy resin, 3-6 parts of styrene, 2-5 parts of odium stearate, 1-4 parts of sodium laureth sulfate,
3-5 parts of oxirane, 2-6 parts of ethyl acetate, 1-4 parts of three carboxyl triethylamine, 3-5 parts of diethanol amine, 1-4 parts of vitamin C, second
2-5 parts of base ether, 5-15 parts of deionized water, 2-6 parts of ethanol, 1-5 parts of pearl powder, 3-9 parts of glycerine.
Preferably, Fluorescence Increasing auxiliary agent is prepared by following technique：By bentonite, silane coupler KH-560 and acetone
Well mixed, stirring then heats up, and vibrates, and then adds epoxy resin and styrene is well mixed, stirring, then ultrasonic wave
It is scattered, room temperature is cooled to, odium stearate, sodium laureth sulfate, oxirane, ethyl acetate, the second of three carboxyl three is then added
Amine and diethanol amine are well mixed, heat up, insulation, be cooled to after room temperature add vitamin C, ethylether, deionized water, ethanol,
Pearl powder and glycerine are well mixed, and stirring is cooled to room temperature and obtains Fluorescence Increasing auxiliary agent.
Preferably, Fluorescence Increasing auxiliary agent is prepared by following technique：By bentonite, silane coupler KH-560 and acetone
It is well mixed, 1-3min is stirred in 1800-2200r/min rotating speeds, 25-35 DEG C is then warming up to, 4-6h is vibrated, then adds ring
Oxygen tree fat and styrene are well mixed, and 30-50min is stirred in 2800-3200r/min rotating speeds, and then ultrasonic wave disperses 20-
40min, is cooled to room temperature, then adds odium stearate, sodium laureth sulfate, oxirane, ethyl acetate, the second of three carboxyl three
Amine and diethanol amine are well mixed, are warming up to 50-70 DEG C, are incubated 20-40min, are cooled to after room temperature and add vitamin C, ethyl
Ether, deionized water, ethanol, pearl powder and glycerine are well mixed, stir 30-50min in 2500-3500r/min rotating speeds, are cooled to
Room temperature obtains Fluorescence Increasing auxiliary agent.
The preparation method of the present invention, including：By polysulfonate polyethylene rubber, butadiene-styrene rubber, Lauxite, polyvinyl chloride,
Makrolon, low density polyethylene (LDPE) and polystyrene are well mixed, are warming up to 110-130 DEG C, are incubated 10-20min, are subsequently added into
Barium sulfate, Firebrake ZB, tossa, talcum powder and mill reinforcer are well mixed, and 1- is stirred in 1800-2600r/min rotating speeds
3h, is subsequently added into sulphur, trioctyl trimellitate (TOTM), 2,6- di-tert-butyl-4-methy phenols, cumyl peroxide, adjacent benzene two
Formic anhydride, lubricant, foaming agent, resistance to and Fluorescence Increasing auxiliary agent are warming up to 120-140 DEG C, 10-30min are incubated, then in 1600-
3200r/min rotating speeds stir 1-3h, and room temperature is cooled to after drying to constant weight and obtains high-wearing feature fluorescent mobile phone protection cover material.
A kind of high-wearing feature fluorescent mobile phone protection cover material of the present invention, its raw material includes polysulfonate polyethylene rubber, fourth
Benzene rubber, Lauxite, polyvinyl chloride, makrolon, low density polyethylene (LDPE), polystyrene, sulphur, barium sulfate, Firebrake ZB, Huang
Flaxen fiber, talcum powder, trioctyl trimellitate (TOTM), 2,6 di tert butyl 4 methyl phenol, cumyl peroxide, O-phthalic
Acid anhydrides, lubricant, foaming agent, wear-resisting reinforcer and Fluorescence Increasing auxiliary agent.Its with polysulfonate polyethylene rubber, butadiene-styrene rubber,
Lauxite, polyvinyl chloride, makrolon, low density polyethylene (LDPE) and polystyrene are resin binder, with sulphur, barium sulfate, boron
Sour zinc, tossa, talcum powder, trioctyl trimellitate (TOTM), 2,6 di tert butyl 4 methyl phenol, cumyl peroxide, neighbour
Phthalate anhydride, lubricant, foaming agent, wear-resisting reinforcer and Fluorescence Increasing auxiliary agent are auxiliary agent, pass through rubber base-material and auxiliary agent
Cooperation, obtained mobile phone protective cover material has an excellent anti-wear performance, and with fluorescence property so that mobile phone at night can
Fluorescence is enough sent, is easy to night mobile phone to be identified.Wear-resisting reinforcer is by by montmorillonite, multi-walled carbon nanotube, dichloroethanes
Well mixed with thionyl chloride, stirring then heats up, and is incubated, and is cooled to addition 2- propylene -1- alcohol after room temperature and is well mixed, connects
Heating, is incubated, is washed, centrifugation is cooled to room temperature after drying and obtains material A；By wood fiber powder, hollow glass micropearl and silicon
Micro mist is well mixed, and is sealed stirring at low speed, is added magnesium hydroxide, methacrylate, silane resin acceptor kh-550 and silicone oil
It is well mixed, heat up, then stirring adds material A, styrene and butyl acrylate and be well mixed, heat up, insulation is then stirred
Mix, be cooled to room temperature and obtain wear-resisting reinforcer, in the high-wearing feature fluorescent mobile phone protection cover material for applying to the present invention, do not have
Improve its anti-wear performance.Fluorescence Increasing auxiliary agent is stirred by the way that bentonite, silane coupler KH-560 and acetone are well mixed,
Then heat up, vibrate, then add epoxy resin and styrene is well mixed, stirring, then ultrasonic wave disperses, and is cooled to room
Temperature, then adds odium stearate, sodium laureth sulfate, oxirane, ethyl acetate, three carboxyl triethylamines and diethanol amine mixed
Close uniform, heat up, insulation is cooled to addition vitamin C, ethylether, deionized water, ethanol, pearl powder and glycerine after room temperature mixed
Close uniform, stirring is cooled to room temperature and obtains Fluorescence Increasing auxiliary agent, applies to the high-wearing feature fluorescent mobile phone protective case material of the present invention
In material, its intentional fluorescence property is imparted.The high-wearing feature fluorescent mobile phone protection cover material of the present invention has excellent wear-resisting
Performance and fluorescence property.
Embodiment
The present invention is described in detail with reference to specific embodiment, it should be appreciated that embodiment is served only for illustrating this hair
It is bright, rather than for limiting the invention, any modification made on the basis of the present invention, equivalent substitution etc. are in this hair
In bright protection domain.
In embodiment, the parts by weight of polysulfonate polyethylene rubber can for 80 parts, 85 parts, 90 parts, 95 parts, 100
Part, 105 parts, 110 parts, 115 parts, 120 parts；The parts by weight of butadiene-styrene rubber can for 15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20
Part, 21 parts, 22 parts, 23 parts, 24 parts, 25 parts, 26 parts, 27 parts, 28 parts, 29 parts, 30 parts, 31 parts, 32 parts, 33 parts, 34 parts, 35
Part；The parts by weight of Lauxite can be 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts；It is poly-
The parts by weight of vinyl chloride can be 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts；The parts by weight of makrolon can for 8 parts,
9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts, 16 parts；The parts by weight of low density polyethylene (LDPE) can for 5 parts, 6 parts, 7 parts,
8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts；The parts by weight of polystyrene can for 3 parts, 4 parts, 5 parts, 6 parts, 7
Part, 8 parts, 9 parts；The parts by weight of sulphur can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The parts by weight of barium sulfate
It can be 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts；The parts by weight of Firebrake ZB can be 2
Part, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The parts by weight of tossa can for 1 part, 1.5 parts, 2 parts, 2.5 parts, 3
Part, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The parts by weight of talcum powder can for 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts,
4.5 parts, 5 parts；The parts by weight of trioctyl trimellitate (TOTM) can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；2,6-
The parts by weight of di-tert-butyl-4-methy phenol can be 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts；
The parts by weight of cumyl peroxide can for 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5
Part, 7 parts, 7.5 parts, 8 parts, 8.5 parts, 9 parts；The parts by weight of phthalic anhydride can for 3 parts, 3.1 parts, 3.2 parts, 3.3 parts,
3.4 parts, 3.5 parts, 3.6 parts, 3.7 parts, 3.8 parts, 3.9 parts, 4 parts；The parts by weight of lubricant can for 2 parts, 3 parts, 4 parts, 5 parts, 6
Part；The parts by weight of foaming agent can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts；The parts by weight of wear-resisting reinforcer can for 12 parts, 13
Part, 14 parts, 15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts, 21 parts, 22 parts, 23 parts, 24 parts；The weight of Fluorescence Increasing auxiliary agent
Part can be 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts, 16 parts.
Embodiment 1
A kind of high-wearing feature fluorescent mobile phone protection cover material proposed by the present invention, its raw material includes by weight：Polysulfonate
100 parts of polyethylene rubber, 25 parts of butadiene-styrene rubber, 10 parts of Lauxite, 9 parts of polyvinyl chloride, 12 parts of makrolon, low density polyethylene
10 parts of alkene, 6 parts of polystyrene, 3.5 parts of sulphur, 10 parts of barium sulfate, 3.5 parts of Firebrake ZB, 3.5 parts of tossa, talcum powder 3.5
Part, 3.5 parts of trioctyl trimellitate (TOTM), 6 parts of 2,6 di tert butyl 4 methyl phenol, 5.5 parts of cumyl peroxide, adjacent benzene two
3.5 parts of formic anhydride, 4 parts of lubricant, 4 parts of foaming agent, 18 parts of wear-resisting reinforcer, 12 parts of Fluorescence Increasing auxiliary agent.
Wear-resisting reinforcer is prepared by following technique：By weight by 10 parts of montmorillonites, 4.5 parts of multi-wall carbon nano-tubes
Pipe, 3.5 parts of dichloroethanes and 2.5 parts of thionyl chlorides are well mixed, and are stirred 30min in 550r/min rotating speeds, are then warming up to 85
DEG C, 35min is incubated, 4.5 parts of 2- propylene -1- alcohol of addition after room temperature is cooled to and is well mixed, be then warming up to 50 DEG C, be incubated 2h,
Washing, centrifugation is cooled to room temperature after drying and obtains material A；By 3.5 parts of wood fiber powders, 2.5 parts of hollow glass micropearls and 4 parts
Silicon powder is well mixed, 50 DEG C of sealing stirring at low speed 7.5min, add 4 parts of magnesium hydroxides, 2.5 parts of methacrylates, 5 parts
Silane resin acceptor kh-550 and 3.5 parts of silicone oil are well mixed, and are warming up to 115 DEG C, are stirred 15min in 750r/min rotating speeds, then
Add material A, 4.5 parts of styrene and 4.5 parts of butyl acrylates to be well mixed, be warming up to 140 DEG C, be incubated 25min, then in
2000r/min rotating speeds stir 1.5h, are cooled to room temperature and obtain wear-resisting reinforcer.
Fluorescence Increasing auxiliary agent is prepared by following technique：By weight by 20 parts of bentonites, 5 parts of silane coupler KH-
560 and 3.5 parts of acetone are well mixed, and 2min is stirred in 2000r/min rotating speeds, are then warming up to 30 DEG C, are vibrated 5h, are then added
2.5 parts of epoxy resin and 4.5 parts of styrene are well mixed, and stir 40min in 3000r/min rotating speeds, then ultrasonic wave disperses
30min, is cooled to room temperature, then adds 3.5 parts of odium stearate, 2.5 parts of sodium laureth sulfates, 4 parts of oxirane, 4 parts of second
Acetoacetic ester, 2.5 part of three carboxyl triethylamine and 4 parts of diethanol amine are well mixed, and are warming up to 60 DEG C, are incubated 30min, are cooled to room temperature
It is equal that 2.5 parts of vitamin Cs, 3.5 parts of ethylethers, 10 parts of deionized waters, 4 parts of ethanol, 3 parts of pearl powders and 6 parts of glycerine mixing are added afterwards
It is even, 40min is stirred in 3000r/min rotating speeds, room temperature is cooled to and obtains Fluorescence Increasing auxiliary agent.
Embodiment 2
A kind of high-wearing feature fluorescent mobile phone protection cover material proposed by the present invention, its raw material includes by weight：Polysulfonate
80 parts of polyethylene rubber, 35 parts of butadiene-styrene rubber, 5 parts of Lauxite, 12 parts of polyvinyl chloride, 8 parts of makrolon, low density polyethylene (LDPE)
15 parts, 3 parts of polystyrene, 5 parts of sulphur, 5 parts of barium sulfate, 5 parts of Firebrake ZB, 1 part of tossa, 5 parts of talcum powder, tri trimellitate
2 parts of monooctyl ester, 8 parts of 2,6 di tert butyl 4 methyl phenol, 2 parts of cumyl peroxide, 4 parts of phthalic anhydride, lubricant 2
Part, 6 parts of foaming agent, 12 parts of wear-resisting reinforcer, 16 parts of Fluorescence Increasing auxiliary agent.
Wear-resisting reinforcer is prepared by following technique：By weight by 5 parts of montmorillonites, 6 parts of multi-walled carbon nanotubes, 2
Part dichloroethanes and 4 parts of thionyl chlorides are well mixed, and 40min is stirred in 450r/min rotating speeds, are then warming up to 80 DEG C, insulation
50min, is cooled to 3 parts of 2- propylene -1- alcohol of addition after room temperature and is well mixed, be then warming up to 55 DEG C, be incubated 1h, wash, centrifugation,
Room temperature is cooled to after drying and obtains material A；5 parts of wood fiber powders, 1 part of hollow glass micropearl and 5 parts of silicon powders are well mixed,
45 DEG C sealing stirring at low speed 10min, add 2 parts of magnesium hydroxides, 4 parts of methacrylates, 4 parts of silane resin acceptor kh-550s and
5 parts of silicone oil are well mixed, and are warming up to 110 DEG C, and 10min is stirred in 850r/min rotating speeds, then add material A, 6 parts of styrene and
1 part of butyl acrylate is well mixed, and is warming up to 145 DEG C, is incubated 15min, is then stirred 1h in 2500r/min rotating speeds, is cooled to
Room temperature obtains wear-resisting reinforcer.
Fluorescence Increasing auxiliary agent is prepared by following technique：By weight by 15 parts of bentonites, 6 parts of silane coupler KH-
560 and 2 parts of acetone are well mixed, and 1min is stirred in 2200r/min rotating speeds, are then warming up to 35 DEG C, are vibrated 4h, are then added 4
Part epoxy resin and 3 parts of styrene are well mixed, and 30min is stirred in 3200r/min rotating speeds, and then ultrasonic wave disperses 40min, cold
But to room temperature, then add 2 parts of odium stearate, 4 parts of sodium laureth sulfates, 3 parts of oxirane, 6 parts of ethyl acetate, 1 part three
Carboxyl triethylamine and 5 parts of diethanol amine are well mixed, and are warming up to 50 DEG C, are incubated 40min, are cooled to after room temperature and are added 1 part of dimension life
Plain C, 5 parts of ethylethers, 5 parts of deionized waters, 6 parts of ethanol, 1 part of pearl powder and 9 parts of glycerine are well mixed, in 2500r/min rotating speeds
50min is stirred, room temperature is cooled to and obtains Fluorescence Increasing auxiliary agent.
Embodiment 3
A kind of high-wearing feature fluorescent mobile phone protection cover material proposed by the present invention, its raw material includes by weight：Polysulfonate
120 parts of polyethylene rubber, 15 parts of butadiene-styrene rubber, 15 parts of Lauxite, 6 parts of polyvinyl chloride, 16 parts of makrolon, low density polyethylene
5 parts of alkene, 9 parts of polystyrene, 2 parts of sulphur, 15 parts of barium sulfate, 2 parts of Firebrake ZB, 6 parts of tossa, 2 parts of talcum powder, trimellitic acid
Three 5 parts of monooctyl esters, 4 parts of 2,6 di tert butyl 4 methyl phenol, 9 parts of cumyl peroxide, 3 parts of phthalic anhydride, lubricant
6 parts, 2 parts of foaming agent, 24 parts of wear-resisting reinforcer, 8 parts of Fluorescence Increasing auxiliary agent.
Wear-resisting reinforcer is prepared by following technique：By weight by 15 parts of montmorillonites, 3 parts of multi-walled carbon nanotubes, 5
Part dichloroethanes and 1 part of thionyl chloride are well mixed, and 20min is stirred in 650r/min rotating speeds, are then warming up to 90 DEG C, insulation
20min, is cooled to 6 parts of 2- propylene -1- alcohol of addition after room temperature and is well mixed, be then warming up to 45 DEG C, be incubated 3h, wash, centrifugation,
Room temperature is cooled to after drying and obtains material A；2 parts of wood fiber powders, 4 parts of hollow glass micropearls and 3 parts of silicon powders are well mixed,
55 DEG C of sealing stirring at low speed 5min, add 6 parts of magnesium hydroxides, 1 part of methacrylate, 6 parts of silane resin acceptor kh-550s and 2
Part silicone oil is well mixed, and is warming up to 120 DEG C, and 20min is stirred in 650r/min rotating speeds, then adds material A, 3 parts of styrene and 8
Part butyl acrylate is well mixed, and is warming up to 135 DEG C, is incubated 35min, is then stirred 2h in 1500r/min rotating speeds, is cooled to room
Temperature obtains wear-resisting reinforcer.
Fluorescence Increasing auxiliary agent is prepared by following technique：By weight by 25 parts of bentonites, 4 parts of silane coupler KH-
560 and 5 parts of acetone are well mixed, and 3min is stirred in 1800r/min rotating speeds, are then warming up to 25 DEG C, are vibrated 6h, are then added 1
Part epoxy resin and 6 parts of styrene are well mixed, and 50min is stirred in 2800r/min rotating speeds, and then ultrasonic wave disperses 20min, cold
But to room temperature, then add 5 parts of odium stearate, 1 part of sodium laureth sulfate, 5 parts of oxirane, 2 parts of ethyl acetate, 4 part three
Carboxyl triethylamine and 3 parts of diethanol amine are well mixed, and are warming up to 70 DEG C, are incubated 20min, are cooled to after room temperature and are added 4 parts of dimension lifes
Plain C, 2 parts of ethylethers, 15 parts of deionized waters, 2 parts of ethanol, 5 parts of pearl powders and 3 parts of glycerine are well mixed, in 3500r/min rotating speeds
30min is stirred, room temperature is cooled to and obtains Fluorescence Increasing auxiliary agent.
Embodiment 4
A kind of high-wearing feature fluorescent mobile phone protection cover material proposed by the present invention, its raw material includes by weight：Polysulfonate
85 parts of polyethylene rubber, 32 parts of butadiene-styrene rubber, 8 parts of Lauxite, 11 parts of polyvinyl chloride, 9 parts of makrolon, low density polyethylene (LDPE)
12 parts, 4 parts of polystyrene, 4 parts of sulphur, 8 parts of barium sulfate, 4 parts of Firebrake ZB, 2 parts of tossa, 4 parts of talcum powder, tri trimellitate
3 parts of monooctyl ester, 7 parts of 2,6 di tert butyl 4 methyl phenol, 3 parts of cumyl peroxide, 3.8 parts of phthalic anhydride, lubricant
3 parts, 5 parts of foaming agent, 14 parts of wear-resisting reinforcer, 15 parts of Fluorescence Increasing auxiliary agent.
Wear-resisting reinforcer is prepared by following technique：By weight by 8 parts of montmorillonites, 5 parts of multi-walled carbon nanotubes, 3
Part dichloroethanes and 3 parts of thionyl chlorides are well mixed, and 35min is stirred in 480r/min rotating speeds, are then warming up to 82 DEG C, insulation
45min, is cooled to 4 parts of 2- propylene -1- alcohol of addition after room temperature and is well mixed, be then warming up to 52 DEG C, be incubated 1.5h, wash, from
The heart, is cooled to room temperature after drying and obtains material A；4 parts of wood fiber powders, 2 parts of hollow glass micropearls and 4.5 parts of silicon powders are mixed
Uniformly, 48 DEG C of sealing stirring at low speed 9min, add 3 parts of magnesium hydroxides, 3 parts of methacrylates, 4.5 parts of silane couplers
KH-550 and 4 part of silicone oil is well mixed, and is warming up to 112 DEG C, and 12min is stirred in 820r/min rotating speeds, then add material A, 5 parts
Styrene and 2 parts of butyl acrylates are well mixed, and are warming up to 142 DEG C, are incubated 18min, are then stirred in 2200r/min rotating speeds
1.2h, is cooled to room temperature and obtains wear-resisting reinforcer.
Fluorescence Increasing auxiliary agent is prepared by following technique：By weight by 18 parts of bentonites, 5.5 parts of silane couplers
KH-560 and 3 part of acetone is well mixed, and 1.5min is stirred in 2150r/min rotating speeds, is then warming up to 32 DEG C, vibrates 4.5h, so
3 parts of epoxy resin are added afterwards and 4 parts of styrene are well mixed, and stir 35min in 3100r/min rotating speeds, then ultrasonic wave disperses
35min, is cooled to room temperature, then adds 3 parts of odium stearate, 3 parts of sodium laureth sulfates, 3.5 parts of oxirane, 5 parts of acetic acid
Ethyl ester, 2 part of three carboxyl triethylamine and 4.5 parts of diethanol amine are well mixed, and are warming up to 55 DEG C, are incubated 35min, are cooled to after room temperature
2 parts of vitamin Cs, 4 parts of ethylethers, 8 parts of deionized waters, 5 parts of ethanol, 2 parts of pearl powders and 8 parts of glycerine are added to be well mixed, in
2800r/min rotating speeds stir 45min, are cooled to room temperature and obtain Fluorescence Increasing auxiliary agent.
Embodiment 5
A kind of high-wearing feature fluorescent mobile phone protection cover material proposed by the present invention, its raw material includes by weight：Polysulfonate
115 parts of polyethylene rubber, 18 parts of butadiene-styrene rubber, 12 parts of Lauxite, 7 parts of polyvinyl chloride, 15 parts of makrolon, low density polyethylene
8 parts of alkene, 8 parts of polystyrene, 3 parts of sulphur, 12 parts of barium sulfate, 3 parts of Firebrake ZB, 5 parts of tossa, 3 parts of talcum powder, trimellitic acid
Three 4 parts of monooctyl esters, 5 parts of 2,6 di tert butyl 4 methyl phenol, 8 parts of cumyl peroxide, 3.2 parts of phthalic anhydride, lubrication
5 parts of agent, 3 parts of foaming agent, 22 parts of wear-resisting reinforcer, 9 parts of Fluorescence Increasing auxiliary agent.
Wear-resisting reinforcer is prepared by following technique：By weight by 12 parts of montmorillonites, 4 parts of multi-walled carbon nanotubes, 4
Part dichloroethanes and 2 parts of thionyl chlorides are well mixed, and 25min is stirred in 620r/min rotating speeds, are then warming up to 88 DEG C, insulation
25min, is cooled to 5 parts of 2- propylene -1- alcohol of addition after room temperature and is well mixed, be then warming up to 48 DEG C, be incubated 2.5h, wash, from
The heart, is cooled to room temperature after drying and obtains material A；3 parts of wood fiber powders, 3 parts of hollow glass micropearls and 3.5 parts of silicon powders are mixed
Uniformly, 52 DEG C of sealing stirring at low speed 6min, add 5 parts of magnesium hydroxides, 2 parts of methacrylates, 5.5 parts of silane couplers
KH-550 and 3 part of silicone oil is well mixed, and is warming up to 118 DEG C, and 18min is stirred in 680r/min rotating speeds, then add material A, 4 parts
Styrene and 7 parts of butyl acrylates are well mixed, and are warming up to 138 DEG C, are incubated 32min, are then stirred in 1800r/min rotating speeds
1.8h, is cooled to room temperature and obtains wear-resisting reinforcer.
Fluorescence Increasing auxiliary agent is prepared by following technique：By weight by 22 parts of bentonites, 4.5 parts of silane couplers
KH-560 and 4 part of acetone is well mixed, and 2.5min is stirred in 1850r/min rotating speeds, is then warming up to 28 DEG C, vibrates 5.5h, so
2 parts of epoxy resin are added afterwards and 5 parts of styrene are well mixed, and stir 45min in 2900r/min rotating speeds, then ultrasonic wave disperses
25min, is cooled to room temperature, then adds 4 parts of odium stearate, 2 parts of sodium laureth sulfates, 4.5 parts of oxirane, 3 parts of acetic acid
Ethyl ester, 3 part of three carboxyl triethylamine and 3.5 parts of diethanol amine are well mixed, and are warming up to 65 DEG C, are incubated 25min, are cooled to after room temperature
3 parts of vitamin Cs, 3 parts of ethylethers, 12 parts of deionized waters, 3 parts of ethanol, 4 parts of pearl powders and 4 parts of glycerine are added to be well mixed, in
3200r/min rotating speeds stir 35min, are cooled to room temperature and obtain Fluorescence Increasing auxiliary agent.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.
Claims (7)
1. a kind of high-wearing feature fluorescent mobile phone protects cover material, it is characterised in that its raw material includes by weight：The poly- second of polysulfonateization
80-120 parts of alkene rubber, 15-35 parts of butadiene-styrene rubber, 5-15 parts of Lauxite, 6-12 parts of polyvinyl chloride, 8-16 parts of makrolon,
5-15 parts of low density polyethylene (LDPE), 3-9 parts of polystyrene, 2-5 parts of sulphur, 5-15 parts of barium sulfate, 2-5 parts of Firebrake ZB, tossa
1-6 parts, 2-5 parts of talcum powder, 2-5 parts of trioctyl trimellitate (TOTM), 4-8 parts of 2,6 di tert butyl 4 methyl phenol, peroxidating two it is different
2-9 parts of propyl benzene, 3-4 parts of phthalic anhydride, 2-6 parts of lubricant, 2-6 parts of foaming agent, wear-resisting reinforcer 12-24 parts, fluorescence
8-16 parts of reinforcing aids.
2. high-wearing feature fluorescent mobile phone according to claim 1 protects cover material, it is characterised in that wear-resisting reinforcer
Raw material includes by weight：5-15 parts of montmorillonite, 3-6 parts of multi-walled carbon nanotube, 2-5 parts of dichloroethanes, 1-4 parts of thionyl chloride,
3-6 parts of 2- propylene -1- alcohol, 2-5 parts of wood fiber powder, 1-4 parts of hollow glass micropearl, 3-5 parts of silicon powder, 2-6 parts of magnesium hydroxide,
1-4 parts of methacrylate, 4-6 parts of silane resin acceptor kh-550,2-5 parts of silicone oil, 3-6 parts of styrene, butyl acrylate 1-8
Part.
3. high-wearing feature fluorescent mobile phone according to claim 1 or 2 protects cover material, it is characterised in that wear-resisting enhancing is filled out
Material is prepared by following technique：Montmorillonite, multi-walled carbon nanotube, dichloroethanes and thionyl chloride are well mixed, stirs, connects
Heating, is incubated, addition 2- propylene -1- alcohol after room temperature is cooled to and is well mixed, then heat up, be incubated, wash, centrifuge, it is dry
After be cooled to room temperature and obtain material A；Wood fiber powder, hollow glass micropearl and silicon powder are well mixed, stirring at low speed is sealed,
Add magnesium hydroxide, methacrylate, silane resin acceptor kh-550 and silicone oil well mixed, heat up, then stirring adds
Material A, styrene and butyl acrylate are well mixed, heat up, and insulation is followed by stirring for, and are cooled to room temperature and obtain wear-resisting enhancing and fill out
Material.
4. the high-wearing feature fluorescent mobile phone protection cover material according to claim any one of 1-3, it is characterised in that wear-resisting increasing
Strong filler is prepared by following technique：Montmorillonite, multi-walled carbon nanotube, dichloroethanes and thionyl chloride are well mixed, in
450-650r/min rotating speeds stir 20-40min, are then warming up to 80-90 DEG C, are incubated 20-50min, are cooled to after room temperature and add
2- propylene -1- alcohol is well mixed, and is then warming up to 45-55 DEG C, is incubated 1-3h, is washed, centrifugation, and being cooled to room temperature after drying obtains
Material A；Wood fiber powder, hollow glass micropearl and silicon powder are well mixed, 45-55 DEG C of sealing stirring at low speed 5-10min, then
Add magnesium hydroxide, methacrylate, silane resin acceptor kh-550 and silicone oil well mixed, be warming up to 110-120 DEG C, in
650-850r/min rotating speeds stir 10-20min, then add material A, styrene and butyl acrylate and are well mixed, are warming up to
135-145 DEG C, 15-35min is incubated, then 1-2h is stirred in 1500-2500r/min rotating speeds, is cooled to room temperature and obtains wear-resisting increasing
Strong filler.
5. the high-wearing feature fluorescent mobile phone protection cover material according to claim any one of 1-4, it is characterised in that fluorescence increases
The raw material of strong auxiliary agent includes by weight：15-25 parts of bentonite, 4-6 parts of silane coupler KH-560,2-5 parts of acetone, epoxy
1-4 parts of resin, 3-6 parts of styrene, 2-5 parts of odium stearate, 1-4 parts of sodium laureth sulfate, 3-5 parts of oxirane, acetic acid second
2-6 parts of ester, 1-4 parts of three carboxyl triethylamine, 3-5 parts of diethanol amine, 1-4 parts of vitamin C, 2-5 parts of ethylether, deionized water 5-
15 parts, 2-6 parts of ethanol, 1-5 parts of pearl powder, 3-9 parts of glycerine.
6. the high-wearing feature fluorescent mobile phone protection cover material according to claim any one of 1-5, it is characterised in that fluorescence increases
Strong auxiliary agent is prepared by following technique：Bentonite, silane coupler KH-560 and acetone are well mixed, stirs, then rises
Temperature, vibration, then adds epoxy resin and styrene is well mixed, stirring, and then ultrasonic wave disperses, and is cooled to room temperature, then
Add odium stearate, sodium laureth sulfate, oxirane, ethyl acetate, three carboxyl triethylamines and diethanol amine well mixed,
Heating, insulation is cooled to addition vitamin C, ethylether, deionized water, ethanol, pearl powder and glycerine after room temperature and is well mixed,
Stirring, is cooled to room temperature and obtains Fluorescence Increasing auxiliary agent.
7. the high-wearing feature fluorescent mobile phone protection cover material according to claim any one of 1-6, it is characterised in that fluorescence increases
Strong auxiliary agent is prepared by following technique：Bentonite, silane coupler KH-560 and acetone are well mixed, in 1800-
2200r/min rotating speeds stir 1-3min, are then warming up to 25-35 DEG C, vibrate 4-6h, then add epoxy resin and styrene is mixed
Close uniform, 30-50min is stirred in 2800-3200r/min rotating speeds, then ultrasonic wave disperses 20-40min, is cooled to room temperature, so
It is equal that odium stearate, sodium laureth sulfate, oxirane, ethyl acetate, three carboxyl triethylamines and diethanol amine mixing are added afterwards
It is even, 50-70 DEG C is warming up to, 20-40min is incubated, is cooled to after room temperature and adds vitamin C, ethylether, deionized water, ethanol, treasure
Pearl powder and glycerine are well mixed, and 30-50min is stirred in 2500-3500r/min rotating speeds, are cooled to room temperature and obtain Fluorescence Increasing and help
Agent.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710579993.6A CN107216558A (en) | 2017-07-17 | 2017-07-17 | A kind of high-wearing feature fluorescent mobile phone protects cover material |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107935495A (en) * | 2017-11-17 | 2018-04-20 | 定远县明友墙体材料有限责任公司 | A kind of high-toughness wear-resistant pressure knot brick |
| GB2587330A (en) * | 2019-09-12 | 2021-03-31 | Design Blue Ltd | Protective cover for a 5G wireless telecommunications device and methods for reducing signal attenuation using the same |
-
2017
- 2017-07-17 CN CN201710579993.6A patent/CN107216558A/en not_active Withdrawn
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107935495A (en) * | 2017-11-17 | 2018-04-20 | 定远县明友墙体材料有限责任公司 | A kind of high-toughness wear-resistant pressure knot brick |
| GB2587330A (en) * | 2019-09-12 | 2021-03-31 | Design Blue Ltd | Protective cover for a 5G wireless telecommunications device and methods for reducing signal attenuation using the same |
| GB2587330B (en) * | 2019-09-12 | 2024-04-10 | Design Blue Ltd | Protective cover for a 5G wireless telecommunications device and methods for reducing signal attenuation using the same |
| US12068772B2 (en) | 2019-09-12 | 2024-08-20 | Design Blue Limited | Protective cover for a 5G wireless telecommunications device and methods for reducing signal attenuation using the same |
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Application publication date: 20170929 |