CN106750923A - A kind of Flame-Retardant and Oil-Resistant modified plastic rubber material - Google Patents
A kind of Flame-Retardant and Oil-Resistant modified plastic rubber material Download PDFInfo
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- CN106750923A CN106750923A CN201611139817.2A CN201611139817A CN106750923A CN 106750923 A CN106750923 A CN 106750923A CN 201611139817 A CN201611139817 A CN 201611139817A CN 106750923 A CN106750923 A CN 106750923A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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Abstract
The invention discloses a kind of Flame-Retardant and Oil-Resistant modified plastic rubber material, its raw material includes modified polypropylene resin, epoxy resin, Corvic, phenolic resin, zinc stearate, cerium oxide, aluminium triphosphate, aluminum stearate, magnesium hydroxide, fluorine micro mist, antimony oxide, talcum powder, high abrasion carbon black, modified additive, hexamethyl cellulose, glass fibre, silane coupler KH 560, Firebrake ZB, epoxychloropropane, trioctyl trimellitate (TOTM), pla-pcl, PLA, chlorinated paraffin, glycerine, bulking agent, trimethyl phosphate and coupling agent KH 560.Modified plastic rubber material of the invention has excellent fire-retardant and oil resistance.
Description
Technical field
The present invention relates to plastic material field, more particularly to a kind of Flame-Retardant and Oil-Resistant modified plastic rubber material.
Background technology
Plastic cement part is extensively using each field in the modern life, such as household electrical appliance, instrument and meter, electric wire electricity
Cable, construction equipment, communication electronics, auto industry, space flight and aviation, haberdashery and hardware etc..Plastic cement of the prior art it is fire-retardant and resistance to
Demand when oiliness can cannot meet actually used, therefore it is existing to solve to need a kind of Flame-Retardant and Oil-Resistant modified plastic rubber material of design badly
Problem in technology.
The content of the invention
To solve technical problem present in background technology, the present invention proposes a kind of Flame-Retardant and Oil-Resistant modified plastic rubber material, tool
There is excellent fire-retardant and oil resistance.
A kind of Flame-Retardant and Oil-Resistant modified plastic rubber material proposed by the present invention, its raw material includes by weight：Modified polypropene tree
Fat 65-85 parts, epoxy resin 35-55 parts, Corvic 5-15 parts, phenolic resin 8-16 parts, zinc stearate 4-8 parts, oxygen
Change 1-5 parts of cerium, aluminium triphosphate 1-5 parts, aluminum stearate 2-4 parts, magnesium hydroxide 3-6 parts, 3-6 parts of fluorine micro mist, antimony oxide
1-5 parts, talcum powder 2-8 parts, 2-6 parts of high abrasion carbon black, modified additive 4-8 parts, 1-9 parts of hexamethyl cellulose, glass fibre 4-
12 parts, 3-6 parts of silane coupler KH-560, Firebrake ZB 2-6 parts, epoxychloropropane 5-10 parts, trioctyl trimellitate (TOTM) 3-6 parts,
Pla-pcl 1-9 parts, PLA 2-6 parts, chlorinated paraffin 3-9 parts, glycerine 2-8 parts, bulking agent 1-6 parts, trimethyl phosphate 2-5
Part, 1-5 parts of coupling agent KH-560.
Preferably, the raw material of modified polypropylene resin includes by weight：Three 3-9 parts of polychlorostyrene hydrogen, 2-8 parts of potassium amine, hydrogen-oxygen
Change 1-5 parts, phosphoric acid 3-9 parts, acrylic resin 5-15 parts, aluminium hydroxide 3-9 parts of sodium.
Preferably, modified polypropylene resin is prepared by following technique：Three polychlorostyrene hydrogen and acetone are well mixed, then
It is put into 0-5 DEG C of ice-water bath, potassium amine and NaOH is once added dropwise, the process of dropwise addition is not stopped stirring, then heats to 50-60
DEG C, 1-3h, room temperature reaction 20-40min are incubated, acetone is then removed, with water washing is distilled 2-6 times, suction filtration is dried to obtain material
a；Material a and deionized water are well mixed, 80-90 DEG C is then heated to, 1-3h is incubated, phosphoric acid are subsequently adding and are well mixed,
120-140 DEG C is then heated to, 4-6h is incubated, suction filtration, drying obtains material b；Acrylic resin is put on plastics machine and is heated up
To 120-140 DEG C, material b and the well mixed rear slice of aluminium hydroxide are subsequently adding, in 170-190 DEG C of heat on vulcanizing press
Pressure, is cooled to room temperature, is dried to obtain modified polypropylene resin.
Preferably, the raw material of modified additive includes by weight：Concentrated sulfuric acid 80-120 parts, water 40-60 parts, bentonite 1-5
Part, blanc fixe 2-4 parts, nitrocotton 1-4 parts, zinc oxide 1-3 parts, mica powder 1-5 parts, zeolite powder 2-6 parts, ethanol water 8-
16 parts, Silane coupling reagent KH-570 5-15 parts, methyl methacrylate 1-5 parts.
Preferably, modified additive is prepared by following technique：The concentrated sulfuric acid is dispersed in water, stirs acid multiple
Close aqueous intercalation solution；Bentonite, blanc fixe, nitrocotton, zinc oxide, mica powder and zeolite powder are added to acid compound intercalation
In the aqueous solution, 80-90 DEG C of high-speed stirred 2-4h is filtered while hot, is washed with distilled water to neutrality, suction filtration, drying, grinding, mistake
150-250 mesh sieves obtain material A；Then material A is dispersed in ethanol water, ultrasound-machinery is stirred in 45-55 DEG C of water-bath
Mix dispersion 2-4h and obtain material B, then to Silane coupling reagent KH-570 and methyl methacrylate is added in material B, be warming up to
75-85 DEG C, 5-7h is incubated, nitrogen is led to during insulation, finally pour out product, add distilled water, stirred, it is quiet
Layering is put, supernatant liquor is removed, lower reaction product layer is carried out into suction filtration, washed, 750-850 DEG C is dried under vacuum to constant weight, grinding,
150-250 mesh sieves are crossed, that is, obtains modified additive.
Preferably, the weight ratio of modified polypropylene resin, modified additive and silane coupler KH-560 is 68-82：5-7：
4-5。
Preferably, its raw material includes by weight：Modified polypropylene resin 68-82 parts, epoxy resin 38-52 parts, polychlorostyrene
Vinyl 8-12 parts, phenolic resin 9-15 parts, zinc stearate 5-7 parts, cerium oxide 2-4 parts, aluminium triphosphate 2-4 parts, tristearin
Sour aluminium 2.5-3.5 parts, magnesium hydroxide 4-5 parts, 4-5 parts of fluorine micro mist, antimony oxide 2-4 parts, talcum powder 3-7 parts, high wear-resistant carbon
It is black 3-5 parts, modified additive 5-7 parts, 2-8 parts of hexamethyl cellulose, glass fibre 5-11 parts, silane coupler KH-560 4-5
Part, Firebrake ZB 3-5 parts, epoxychloropropane 6-9 parts, trioctyl trimellitate (TOTM) 4-5 parts, pla-pcl 2-8 parts, PLA 3-5 parts,
Chlorinated paraffin 4-8 parts, glycerine 3-7 parts, maleic anhydride modified polyethylene 4-8 parts, maleic anhydride grafting 2-5 parts of bulking agent, phosphoric acid
Trimethyl 3-4 parts, 2-4 parts of coupling agent KH-560.
Preferably, its raw material includes by weight：75 parts of modified polypropylene resin, 45 parts of epoxy resin, polyvinyl chloride tree
10 parts of fat, 12 parts of phenolic resin, 6 parts of zinc stearate, 3 parts of cerium oxide, 3 parts of aluminium triphosphate, 3 parts of aluminum stearate, magnesium hydroxide
4.5 parts, 4.5 parts of fluorine micro mist, 3 parts of antimony oxide, 5 parts of talcum powder, 4 parts of high abrasion carbon black, 6 parts of modified additive, hexamethyl it is fine
5 parts of dimension element, 8 parts of glass fibre, 4.5 parts of silane coupler KH-560,4 parts of Firebrake ZB, 7.5 parts of epoxychloropropane, trimellitic acid
Three 4.5 parts of monooctyl esters, 5 parts of pla-pcl, 4 parts of PLA, 6 parts of chlorinated paraffin, 5 parts of glycerine, 6 parts of maleic anhydride modified polyethylene,
3.5 parts of bulking agent of maleic anhydride grafting, 3.5 parts of trimethyl phosphate, 3 parts of coupling agent KH-560.
A kind of Flame-Retardant and Oil-Resistant modified plastic rubber material of the invention, its raw material includes modified polypropylene resin, epoxy resin, gathers
Vinyl chloride resin, phenolic resin, zinc stearate, cerium oxide, aluminium triphosphate, aluminum stearate, magnesium hydroxide, fluorine micro mist, three oxygen
Change two antimony, talcum powder, high abrasion carbon black, modified additive, hexamethyl cellulose, glass fibre, silane coupler KH-560, boric acid
Zinc, epoxychloropropane, trioctyl trimellitate (TOTM), pla-pcl, PLA, chlorinated paraffin, glycerine, bulking agent and tripotassium phosphate
Ester.Wherein with modified polypropylene resin, epoxy resin, Corvic and phenolic resin as base-material, with cerium oxide, trimerization phosphorus
Sour aluminium, aluminum stearate, magnesium hydroxide, fluorine micro mist, antimony oxide, talcum powder, high abrasion carbon black, modified additive, hexamethyl are fine
Dimension element and glass fibre are filler, with hexamethyl cellulose, glass fibre, silane coupler KH-560, Firebrake ZB, epoxy chloropropionate
Alkane, trioctyl trimellitate (TOTM), pla-pcl, PLA, chlorinated paraffin, glycerine, bulking agent and trimethyl phosphate are auxiliary agent, are passed through
The cooperation of base-material, filler and auxiliary agent, rationally control proportioning, imparts the excellent fire-retardant and oil resistance of modified plastic rubber of the present invention.
The modified polypropylene resin for wherein adding is well mixed by by three polychlorostyrene hydrogen and acetone, is then placed in ice-water bath, once drips
Plus potassium amine and NaOH, the process of dropwise addition do not stop stirring, is incubated after intensification, and then room temperature reaction removes acetone, use distilled water
Washing, suction filtration is dried to obtain material a；Material a and deionized water are well mixed, are then heated to, be incubated, be subsequently adding phosphorus
Acid is well mixed, is incubated after then heating up, and suction filtration, drying obtains material b；Acrylic resin is put on plastics machine and is warming up to,
Be subsequently adding material b and aluminium hydroxide it is well mixed after slice, in hot pressing on vulcanizing press, be cooled to room temperature, it is dry
To modified polypropylene resin, apply in modified plastic rubber of the invention, effectively increase the excellent Flame-Retardant and Oil-Resistant of plastic cement of the present invention
Performance.The modified additive for wherein adding is dispersed in water by by the concentrated sulfuric acid, and stir to obtain acid compound aqueous intercalation solution；Will
Bentonite, blanc fixe, nitrocotton, zinc oxide, mica powder and zeolite powder are added in acid compound aqueous intercalation solution, high-speed stirring
Mix, filter while hot, be washed with distilled water to neutrality, suction filtration, drying, grinding, sieving obtains material A；Then material A is dispersed in
In ethanol water, ultrasound-mechanical agitation dispersion obtains material B in water-bath, then to addition silane coupler KH- in material B
570 and methyl methacrylate, it is incubated after intensification, nitrogen is led to during insulation, finally product is poured out, add distillation
Water, is stirred, stratification, removes supernatant liquor, and lower reaction product layer is carried out into suction filtration, is washed, and is dried under vacuum to constant weight,
Grinding, sieving, that is, obtain modified additive, to apply to and effectively increase the fire-retardant of plastic cement of the invention in modified plastic rubber of the invention
And oil resistance.Modified plastic rubber material of the invention has excellent fire-retardant and oil resistance.
Specific embodiment
The present invention is described in detail with reference to specific embodiment, it should be appreciated that embodiment is served only for illustrating this hair
Bright, rather than for limiting the invention, any modification made on the basis of the present invention, equivalent etc. are in this hair
In bright protection domain.
In specific embodiment, the weight portion of modified polypropylene resin can be 65 parts, 70 parts, 75 parts, 80 parts, 85 parts；
The weight portion of epoxy resin can be 35 parts, 40 parts, 45 parts, 50 parts, 55 parts；The weight portion of Corvic can for 5 parts,
6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts；The weight portion of phenolic resin can for 8 parts, 9 parts,
10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts, 16 parts；The weight portion of zinc stearate can be 4 parts, 5 parts, 6 parts, 7 parts, 8 parts；
The weight portion of cerium oxide can be 1 part, 2 parts, 3 parts, 4 parts, 5 parts；The weight portion of aluminium triphosphate can for 1 part, 2 parts, 3 parts, 4
Part, 5 parts；The weight portion of aluminum stearate can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；The weight portion of magnesium hydroxide can be 3
Part, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The weight portion of fluorine micro mist can for 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts,
5.5 parts, 6 parts；The weight portion of antimony oxide can be 1 part, 2 parts, 3 parts, 4 parts, 5 parts；The weight portion of talcum powder can be 2
Part, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts；The weight portion of high abrasion carbon black can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts；It is modified to help
The weight portion of agent can be 4 parts, 5 parts, 6 parts, 7 parts, 8 parts；The weight portion of hexamethyl cellulose can for 1 part, 2 parts, 3 parts, 4
Part, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts；The weight portion of glass fibre can for 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11
Part, 12 parts；The weight portion of silane coupler KH-560 can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；Boric acid
The weight portion of zinc can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts；The weight portion of epoxychloropropane can for 5 parts, 6 parts, 7 parts, 8 parts, 9
Part, 10 parts；The weight portion of trioctyl trimellitate (TOTM) can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；It is poly- interior
The weight portion of ester can be 1 part, 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts；The weight portion of PLA can for 2 parts, 3
Part, 4 parts, 5 parts, 6 parts；The weight portion of chlorinated paraffin can be 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts；The weight portion of glycerine
It can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts；The weight portion of bulking agent can for 1 part, 2 parts, 3 parts, 4 parts, 5 parts, 6
Part；The weight portion of trimethyl phosphate can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The weight of coupling agent KH-560
Amount part can be 1 part, 2 parts, 3 parts, 4 parts, 5 parts.
Embodiment 1
A kind of Flame-Retardant and Oil-Resistant modified plastic rubber material of the invention, its raw material includes by weight：Modified polypropylene resin 75
Part, 45 parts of epoxy resin, 10 parts of Corvic, 12 parts of phenolic resin, 6 parts of zinc stearate, 3 parts of cerium oxide, tripolyphosphate
3 parts of aluminium, 3 parts of aluminum stearate, 4.5 parts of magnesium hydroxide, 4.5 parts of fluorine micro mist, 3 parts of antimony oxide, 5 parts of talcum powder, high wear-resistant carbon
Black 4 parts, 6 parts of modified additive, 5 parts of hexamethyl cellulose, 8 parts of glass fibre, 4.5 parts of silane coupler KH-560, Firebrake ZB 4
Part, 7.5 parts of epoxychloropropane, 4.5 parts of trioctyl trimellitate (TOTM), 5 parts of pla-pcl, 4 parts of PLA, 6 parts of chlorinated paraffin, glycerine
5 parts, 6 parts of maleic anhydride modified polyethylene, maleic anhydride grafting 3.5 parts of bulking agent, 3.5 parts of trimethyl phosphate, coupling agent KH-
560 3 parts.
Embodiment 2
A kind of Flame-Retardant and Oil-Resistant modified plastic rubber material of the invention, its raw material includes by weight：Modified polypropylene resin 65
Part, 55 parts of epoxy resin, 5 parts of Corvic, 16 parts of phenolic resin, 4 parts of zinc stearate, 5 parts of cerium oxide, aluminium triphosphate
1 part, 4 parts of aluminum stearate, 3 parts of magnesium hydroxide, 6 parts of fluorine micro mist, 1 part of antimony oxide, 8 parts of talcum powder, 2 parts of high abrasion carbon black,
8 parts of modified additive, 1 part of hexamethyl cellulose, 12 parts of glass fibre, 3 parts of silane coupler KH-560,6 parts of Firebrake ZB, epoxy
5 parts of chloropropane, 6 parts of trioctyl trimellitate (TOTM), 1 part of pla-pcl, 6 parts of PLA, 3 parts of chlorinated paraffin, 8 parts of glycerine, bulking agent 1
Part, 5 parts of trimethyl phosphate, 1 part of coupling agent KH-560.
Modified polypropylene resin is prepared by following technique：3 part of three polychlorostyrene hydrogen and acetone are well mixed by weight,
It is then placed in 5 DEG C of ice-water bath, 2 parts of potassium amine and 5 parts of NaOH is once added dropwise, the process of dropwise addition does not stop stirring, Ran Housheng
Temperature is incubated 3h, room temperature reaction 20min to 50 DEG C, then removes acetone, and with water washing is distilled 6 times, suction filtration is dried to obtain material
a；Material a and deionized water are well mixed, 80 DEG C are then heated to, 3h is incubated, 3 parts of phosphoric acid are subsequently adding and are well mixed, so
After be warming up to 140 DEG C, be incubated 4h, suction filtration, drying obtains material b；15 parts of acrylic resins are put into 120 are warming up on plastics machine
DEG C, material b and 9 parts of well mixed rear slices of aluminium hydroxides are subsequently adding, in 170 DEG C of hot pressing on vulcanizing press, it is cooled to
Room temperature, is dried to obtain modified polypropylene resin.
Modified additive is prepared by following technique：80 parts of concentrated sulfuric acids are scattered in 60 parts of water by weight, stirring is equal
It is even to obtain acid compound aqueous intercalation solution；By 1 part of bentonite, 4 parts of blanc fixes, 1 part of nitrocotton, 3 parts of zinc oxide, 1 part of mica powder
It is added in acid compound aqueous intercalation solution with 6 parts of zeolite powders, 80 DEG C of high-speed stirred 4h are filtered while hot, are washed with distilled water to
Neutrality, suction filtration, drying, grinding is crossed 150 mesh sieves and obtains material A；Then material A is dispersed in 16 parts of ethanol waters, 45
Ultrasound-mechanical agitation dispersion 4h obtains material B in DEG C water-bath, then to adding 5 parts of Silane coupling reagent KH-570s and 5 in material B
Part methyl methacrylate, is warming up to 75 DEG C, is incubated 7h, and nitrogen is led to during insulation, finally pours out product, adds
Distilled water, is stirred, stratification, removes supernatant liquor, and lower reaction product layer is carried out into suction filtration, is washed, and 750 DEG C of vacuum are done
It is dry to be ground to constant weight, cross 250 mesh sieves, that is, obtain modified additive.
Embodiment 3
A kind of Flame-Retardant and Oil-Resistant modified plastic rubber material of the invention, its raw material includes by weight：Modified polypropylene resin 85
Part, 35 parts of epoxy resin, 15 parts of Corvic, 8 parts of phenolic resin, 8 parts of zinc stearate, 1 part of cerium oxide, aluminium triphosphate
5 parts, 2 parts of aluminum stearate, 6 parts of magnesium hydroxide, 3 parts of fluorine micro mist, 5 parts of antimony oxide, 2 parts of talcum powder, 6 parts of high abrasion carbon black,
4 parts of modified additive, 9 parts of hexamethyl cellulose, 4 parts of glass fibre, 6 parts of silane coupler KH-560,2 parts of Firebrake ZB, epoxy chlorine
10 parts of propane, 3 parts of trioctyl trimellitate (TOTM), 9 parts of pla-pcl, 2 parts of PLA, 9 parts of chlorinated paraffin, 2 parts of glycerine, bulking agent 6
Part, 2 parts of trimethyl phosphate, 5 parts of coupling agent KH-560.
Modified polypropylene resin is prepared by following technique：9 part of three polychlorostyrene hydrogen and acetone are well mixed by weight,
It is then placed in 0 DEG C of ice-water bath, 8 parts of potassium amine and 1 part of NaOH is once added dropwise, the process of dropwise addition does not stop stirring, Ran Housheng
Temperature is incubated 1h, room temperature reaction 40min to 60 DEG C, then removes acetone, and with water washing is distilled 2 times, suction filtration is dried to obtain material
a；Material a and deionized water are well mixed, 90 DEG C are then heated to, 1h is incubated, 9 parts of phosphoric acid are subsequently adding and are well mixed, so
After be warming up to 120 DEG C, be incubated 6h, suction filtration, drying obtains material b；5 parts of acrylic resins are put into 140 are warming up on plastics machine
DEG C, material b and 3 parts of well mixed rear slices of aluminium hydroxides are subsequently adding, in 190 DEG C of hot pressing on vulcanizing press, it is cooled to
Room temperature, is dried to obtain modified polypropylene resin.
Modified additive is prepared by following technique：120 parts of concentrated sulfuric acids are scattered in 40 parts of water by weight, stirring is equal
It is even to obtain acid compound aqueous intercalation solution；By 5 parts of bentonites, 2 parts of blanc fixes, 4 parts of nitrocottons, 1 part of zinc oxide, 5 parts of mica powders
It is added in acid compound aqueous intercalation solution with 2 parts of zeolite powders, 90 DEG C of high-speed stirred 2h are filtered while hot, are washed with distilled water to
Neutrality, suction filtration, drying, grinding is crossed 250 mesh sieves and obtains material A；Then material A is dispersed in 8 parts of ethanol waters, 55
Ultrasound-mechanical agitation dispersion 2h obtains material B in DEG C water-bath, then to adding 15 parts of Silane coupling reagent KH-570s and 1 in material B
Part methyl methacrylate, is warming up to 85 DEG C, is incubated 5h, and nitrogen is led to during insulation, finally pours out product, adds
Distilled water, is stirred, stratification, removes supernatant liquor, and lower reaction product layer is carried out into suction filtration, is washed, and 850 DEG C of vacuum are done
It is dry to be ground to constant weight, cross 150 mesh sieves, that is, obtain modified additive.
Embodiment 4
A kind of Flame-Retardant and Oil-Resistant modified plastic rubber material of the invention, its raw material includes by weight：Modified polypropylene resin 68
Part, 52 parts of epoxy resin, 8 parts of Corvic, 15 parts of phenolic resin, 5 parts of zinc stearate, 4 parts of cerium oxide, aluminium triphosphate
2 parts, 3.5 parts of aluminum stearate, 4 parts of magnesium hydroxide, 5 parts of fluorine micro mist, 2 parts of antimony oxide, 7 parts of talcum powder, high abrasion carbon black 3
Part, 7 parts of modified additive, 2 parts of hexamethyl cellulose, 11 parts of glass fibre, 4 parts of silane coupler KH-560,5 parts of Firebrake ZB, ring
6 parts of oxygen chloropropane, 5 parts of trioctyl trimellitate (TOTM), 2 parts of pla-pcl, 5 parts of PLA, 4 parts of chlorinated paraffin, 7 parts of glycerine, Malaysia
4 parts of anhydride modified lldpe, 5 parts of bulking agent of maleic anhydride grafting, 3 parts of trimethyl phosphate, 4 parts of coupling agent KH-560.
Modified polypropylene resin is prepared by following technique：4 part of three polychlorostyrene hydrogen and acetone are well mixed by weight,
It is then placed in 4 DEG C of ice-water bath, 3 parts of potassium amine and 4 parts of NaOH is once added dropwise, the process of dropwise addition does not stop stirring, Ran Housheng
Temperature is incubated 2.5h, room temperature reaction 25min to 52 DEG C, then removes acetone, and with water washing is distilled 5 times, suction filtration is dried to obtain thing
Material a；Material a and deionized water are well mixed, 82 DEG C are then heated to, 2.5h is incubated, 4 parts of phosphoric acid mixing is subsequently adding equal
It is even, 135 DEG C are then heated to, 4.5h is incubated, suction filtration, drying obtains material b；12 parts of acrylic resins are put into plastics machine to rise
Temperature is subsequently adding material b and 8 parts of well mixed rear slices of aluminium hydroxides to 125 DEG C, in 175 DEG C of hot pressing on vulcanizing press,
Room temperature is cooled to, modified polypropylene resin is dried to obtain.
Modified additive is prepared by following technique：85 parts of concentrated sulfuric acids are scattered in 55 parts of water by weight, stirring is equal
It is even to obtain acid compound aqueous intercalation solution；By 2 parts of bentonites, 3.5 parts of blanc fixes, 2 parts of nitrocottons, 2.5 parts of zinc oxide, 2 parts of clouds
Female powder and 5 parts of zeolite powders are added in acid compound aqueous intercalation solution, and 82 DEG C of high-speed stirred 3.5h are filtered while hot, use distilled water
Washing to neutrality, suction filtration, drying, grinding is crossed 180 mesh sieves and obtains material A；Then material A is dispersed in 15 parts of ethanol waters
In, ultrasound-mechanical agitation dispersion 3.5h obtains material B in 48 DEG C of water-baths, then to 8 parts of silane couplers of addition in material B
KH-570 and 4 part of methyl methacrylate, is warming up to 78 DEG C, is incubated 6.5h, and nitrogen is led to during insulation, finally produces reaction
Thing is poured out, and adds distilled water, is stirred, and stratification removes supernatant liquor, and lower reaction product layer is carried out into suction filtration, washs,
780 DEG C are dried under vacuum to constant weight, grinding, cross 220 mesh sieves, that is, obtain modified additive.
Embodiment 5
A kind of Flame-Retardant and Oil-Resistant modified plastic rubber material of the invention, its raw material includes by weight：Modified polypropylene resin 82
Part, 38 parts of epoxy resin, 12 parts of Corvic, 9 parts of phenolic resin, 7 parts of zinc stearate, 2 parts of cerium oxide, aluminium triphosphate
4 parts, 2.5 parts of aluminum stearate, 5 parts of magnesium hydroxide, 4 parts of fluorine micro mist, 4 parts of antimony oxide, 3 parts of talcum powder, high abrasion carbon black 5
Part, 5 parts of modified additive, 8 parts of hexamethyl cellulose, 5 parts of glass fibre, 5 parts of silane coupler KH-560,3 parts of Firebrake ZB, ring
9 parts of oxygen chloropropane, 4 parts of trioctyl trimellitate (TOTM), 8 parts of pla-pcl, 3 parts of PLA, 8 parts of chlorinated paraffin, 3 parts of glycerine, Malaysia
8 parts of anhydride modified lldpe, 2 parts of bulking agent of maleic anhydride grafting, 4 parts of trimethyl phosphate, 2 parts of coupling agent KH-560.
Modified polypropylene resin is prepared by following technique：8 part of three polychlorostyrene hydrogen and acetone are well mixed by weight,
It is then placed in 1 DEG C of ice-water bath, 7 parts of potassium amine and 2 parts of NaOH is once added dropwise, the process of dropwise addition does not stop stirring, Ran Housheng
Temperature is incubated 1.5h, room temperature reaction 35min to 58 DEG C, then removes acetone, and with water washing is distilled 3 times, suction filtration is dried to obtain thing
Material a；Material a and deionized water are well mixed, 88 DEG C are then heated to, 1.5h is incubated, 8 parts of phosphoric acid mixing is subsequently adding equal
It is even, 125 DEG C are then heated to, 5.5h is incubated, suction filtration, drying obtains material b；8 parts of acrylic resins are put into plastics machine to rise
Temperature is subsequently adding material b and 4 parts of well mixed rear slices of aluminium hydroxides to 135 DEG C, in 185 DEG C of hot pressing on vulcanizing press,
Room temperature is cooled to, modified polypropylene resin is dried to obtain.
Modified additive is prepared by following technique：115 parts of concentrated sulfuric acids are scattered in 45 parts of water by weight, stirring is equal
It is even to obtain acid compound aqueous intercalation solution；By 4 parts of bentonites, 2.5 parts of blanc fixes, 3 parts of nitrocottons, 1.5 parts of zinc oxide, 4 parts of clouds
Female powder and 3 parts of zeolite powders are added in acid compound aqueous intercalation solution, and 88 DEG C of high-speed stirred 2.5h are filtered while hot, use distilled water
Washing to neutrality, suction filtration, drying, grinding is crossed 220 mesh sieves and obtains material A；Then material A is dispersed in 9 parts of ethanol waters
In, ultrasound-mechanical agitation dispersion 2.5h obtains material B in 52 DEG C of water-baths, then to 12 parts of silane couplers of addition in material B
KH-570 and 2 part of methyl methacrylate, is warming up to 82 DEG C, is incubated 5.5h, and nitrogen is led to during insulation, finally produces reaction
Thing is poured out, and adds distilled water, is stirred, and stratification removes supernatant liquor, and lower reaction product layer is carried out into suction filtration, washs,
820 DEG C are dried under vacuum to constant weight, grinding, cross 180 mesh sieves, that is, obtain modified additive.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technology according to the present invention scheme and its
Inventive concept is subject to equivalent or change, should all be included within the scope of the present invention.
Claims (8)
1. a kind of Flame-Retardant and Oil-Resistant modified plastic rubber material, it is characterised in that its raw material includes by weight：Modified polypropylene resin
65-85 parts, epoxy resin 35-55 parts, Corvic 5-15 parts, phenolic resin 8-16 parts, zinc stearate 4-8 parts, oxidation
Cerium 1-5 parts, aluminium triphosphate 1-5 parts, aluminum stearate 2-4 parts, magnesium hydroxide 3-6 parts, 3-6 parts of fluorine micro mist, antimony oxide 1-5
Part, talcum powder 2-8 parts, 2-6 parts of high abrasion carbon black, modified additive 4-8 parts, 1-9 parts of hexamethyl cellulose, glass fibre 4-12
Part, 3-6 parts of silane coupler KH-560, Firebrake ZB 2-6 parts, epoxychloropropane 5-10 parts, trioctyl trimellitate (TOTM) 3-6 parts, it is poly-
Caprolactone 1-9 parts, PLA 2-6 parts, chlorinated paraffin 3-9 parts, glycerine 2-8 parts, bulking agent 1-6 parts, trimethyl phosphate 2-5 parts,
1-5 parts of coupling agent KH-560.
2. the Flame-Retardant and Oil-Resistant modified plastic rubber material according to right will go 1, it is characterised in that the raw material of modified polypropylene resin
Include by weight：Three 3-9 parts of polychlorostyrene hydrogen, 2-8 parts of potassium amine, NaOH 1-5 parts, phosphoric acid 3-9 parts, acrylic resin 5-15
Part, aluminium hydroxide 3-9 parts.
3. Flame-Retardant and Oil-Resistant modified plastic rubber material according to claim 1 and 2, it is characterised in that modified polypropylene resin is pressed
Following technique is prepared：Three polychlorostyrene hydrogen and acetone are well mixed, are then placed in 0-5 DEG C of ice-water bath, potassium is once added dropwise
Amine and NaOH, the process of dropwise addition do not stop stirring, then heat to 50-60 DEG C, are incubated 1-3h, room temperature reaction 20-40min,
Then acetone is removed, with water washing is distilled 2-6 times, suction filtration is dried to obtain material a；Material a and deionized water are well mixed,
80-90 DEG C is then heated to, 1-3h is incubated, phosphoric acid is subsequently adding and is well mixed, then heat to 120-140 DEG C, be incubated 4-6h,
Suction filtration, drying obtains material b；Acrylic resin is put into 120-140 DEG C is warming up on plastics machine, be subsequently adding material b and hydrogen
Slice after aluminum oxide is well mixed, in 170-190 DEG C of hot pressing on vulcanizing press, is cooled to room temperature, is dried to obtain modified poly-
Allyl resin.
4. the Flame-Retardant and Oil-Resistant modified plastic rubber material according to claim any one of 1-3, it is characterised in that the original of modified additive
Material includes by weight：Concentrated sulfuric acid 80-120 parts, water 40-60 parts, bentonite 1-5 parts, blanc fixe 2-4 parts, nitrocotton 1-4
Part, zinc oxide 1-3 parts, mica powder 1-5 parts, zeolite powder 2-6 parts, ethanol water 8-16 parts, Silane coupling reagent KH-570 5-15
Part, methyl methacrylate 1-5 parts.
5. the Flame-Retardant and Oil-Resistant modified plastic rubber material according to claim any one of 1-4, it is characterised in that modified additive is by such as
Lower technique is prepared：The concentrated sulfuric acid is dispersed in water, stir to obtain acid compound aqueous intercalation solution；Bentonite, weight is brilliant
Stone flour, nitrocotton, zinc oxide, mica powder and zeolite powder are added in acid compound aqueous intercalation solution, 80-90 DEG C of high-speed stirred 2-
4h, is filtered while hot, is washed with distilled water to neutrality, and suction filtration, drying, grinding is crossed 150-250 mesh sieves and obtains material A；Then by thing
Material A is dispersed in ethanol water, and ultrasound-mechanical agitation dispersion 2-4h obtains material B in 45-55 DEG C of water-bath, then to thing
Silane coupling reagent KH-570 and methyl methacrylate are added in material B, 75-85 DEG C is warming up to, 5-7h is incubated, during insulation
Logical nitrogen, finally pours out product, adds distilled water, stirs, stratification, removes supernatant liquor, and lower floor is anti-
Answering product carries out suction filtration, washing, and 750-850 DEG C is dried under vacuum to constant weight, and 150-250 mesh sieves are crossed in grinding, that is, obtain modified helping
Agent.
6. the Flame-Retardant and Oil-Resistant modified plastic rubber material according to claim any one of 1-5, it is characterised in that modified polypropene tree
The weight ratio of fat, modified additive and silane coupler KH-560 is 68-82：5-7：4-5.
7. the Flame-Retardant and Oil-Resistant modified plastic rubber material according to claim any one of 1-6, it is characterised in that its raw material is by weight
Part includes：Modified polypropylene resin 68-82 parts, epoxy resin 38-52 parts, Corvic 8-12 parts, phenolic resin 9-15
Part, zinc stearate 5-7 parts, cerium oxide 2-4 parts, aluminium triphosphate 2-4 parts, aluminum stearate 2.5-3.5 parts, magnesium hydroxide 4-5 parts,
4-5 parts of fluorine micro mist, antimony oxide 2-4 parts, talcum powder 3-7 parts, 3-5 parts of high abrasion carbon black, modified additive 5-7 parts, hexamethyl
Cellulose 2-8 parts, glass fibre 5-11 parts, 4-5 parts of silane coupler KH-560, Firebrake ZB 3-5 parts, epoxychloropropane 6-9
Part, trioctyl trimellitate (TOTM) 4-5 parts, pla-pcl 2-8 parts, PLA 3-5 parts, chlorinated paraffin 4-8 parts, glycerine 3-7 parts, Malaysia
Anhydride modified lldpe 4-8 parts, maleic anhydride grafting 2-5 parts of bulking agent, trimethyl phosphate 3-4 parts, coupling agent KH-560 2-4
Part.
8. the Flame-Retardant and Oil-Resistant modified plastic rubber material according to right will go any one of 1-7, it is characterised in that its raw material is by weight
Part includes：75 parts of modified polypropylene resin, 45 parts of epoxy resin, 10 parts of Corvic, 12 parts of phenolic resin, zinc stearate
6 parts, 3 parts of cerium oxide, 3 parts of aluminium triphosphate, 3 parts of aluminum stearate, 4.5 parts of magnesium hydroxide, 4.5 parts of fluorine micro mist, antimony oxide 3
Part, 5 parts of talcum powder, 4 parts of high abrasion carbon black, 6 parts of modified additive, 5 parts of hexamethyl cellulose, 8 parts of glass fibre, silane coupler
4.5 parts of KH-560,4 parts of Firebrake ZB, 7.5 parts of epoxychloropropane, 4.5 parts of trioctyl trimellitate (TOTM), 5 parts of pla-pcl, PLA
4 parts, 6 parts of chlorinated paraffin, 5 parts of glycerine, 6 parts of maleic anhydride modified polyethylene, maleic anhydride grafting 3.5 parts of bulking agent, tricresyl phosphate
3.5 parts of methyl esters, 3 parts of coupling agent KH-560.
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Cited By (7)
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| CN107380404A (en) * | 2017-07-28 | 2017-11-24 | 安徽卓尔航空科技有限公司 | A kind of advanced composite material (ACM) propeller |
| CN107418077A (en) * | 2017-07-28 | 2017-12-01 | 安徽卓尔航空科技有限公司 | One kind injection frame construction composite propeller |
| CN107987485A (en) * | 2017-12-29 | 2018-05-04 | 定远县丹宝树脂有限公司 | A kind of acid and alkali-resistance epoxy resin and preparation method thereof |
| CN108102371A (en) * | 2017-11-26 | 2018-06-01 | 天长市荣盛有机硅科技有限公司 | A kind of oil resistance anticorrosion modified silicon rubber material |
| CN108102355A (en) * | 2017-12-29 | 2018-06-01 | 定远县丹宝树脂有限公司 | A kind of high cold-resistant polyamide and preparation method thereof |
| CN108164897A (en) * | 2017-12-27 | 2018-06-15 | 安徽省二邦化工有限公司 | A kind of oil resistant synthetic resin and preparation method thereof |
| CN108587050A (en) * | 2018-05-08 | 2018-09-28 | 苏州国立塑料制品有限公司 | A kind of preparation method of electrical accessorie composite material |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107987485A (en) * | 2017-12-29 | 2018-05-04 | 定远县丹宝树脂有限公司 | A kind of acid and alkali-resistance epoxy resin and preparation method thereof |
| CN108102355A (en) * | 2017-12-29 | 2018-06-01 | 定远县丹宝树脂有限公司 | A kind of high cold-resistant polyamide and preparation method thereof |
| CN108587050A (en) * | 2018-05-08 | 2018-09-28 | 苏州国立塑料制品有限公司 | A kind of preparation method of electrical accessorie composite material |
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