CN107380404A - A kind of advanced composite material (ACM) propeller - Google Patents
A kind of advanced composite material (ACM) propeller Download PDFInfo
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- CN107380404A CN107380404A CN201710631479.2A CN201710631479A CN107380404A CN 107380404 A CN107380404 A CN 107380404A CN 201710631479 A CN201710631479 A CN 201710631479A CN 107380404 A CN107380404 A CN 107380404A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B64—AIRCRAFT; AVIATION; COSMONAUTICS
- B64C—AEROPLANES; HELICOPTERS
- B64C11/00—Propellers, e.g. of ducted type; Features common to propellers and rotors for rotorcraft
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/068—Ultra high molecular weight polyethylene
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
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- Engineering & Computer Science (AREA)
- Aviation & Aerospace Engineering (AREA)
- Reinforced Plastic Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of advanced composite material (ACM) propeller, including skeleton and skinning layer, the skeleton includes frame body, mounting hole and hollow out, and skinning layer is bonded with the hollow out；The raw material of frame body includes polystyrene, polymethyl methacrylate, polyphenyl alkene, polyvinyl chloride, polyolefin, unsaturated polyester resin, SBS, ethylene-vinyl acetate copolymer, polyflon, poly butyric ester, chopped carbon fiber, Lauxite, trimethyl phosphate, zinc stearate, dispersant, silane coupler KH 560 and rigidity reinforced auxiliary agent.The advanced composite material (ACM) propeller strength of the present invention is high, good, in light weight, the Stability Analysis of Structures of rigidity, and has excellent weatherability, extends service life.
Description
Technical field
The present invention relates to the technical field of propeller, more particularly to a kind of advanced composite material (ACM) propeller.
Background technology
At present, the material of propeller typically has wooden, aluminium alloy, composite etc., structure using solid or sandwich+covering as
It is main, the wooden and production of aluminium alloy propeller, it is that machine adds into blank on CNC milling machine, is then surface-treated to obtain into again
Product, production efficiency is relatively low, and these products are all solid, heavier-weights；Composite propeller generally use is sandwich+covering knot
Structure, Weight control are easier, but the moulding process of composite propeller is complex, typically using prepreg molding or wet
Method hand paste technique, production efficiency are low.The intensity and rigidity of composite propeller of the prior art can not meet actually to make
The demand of used time, and the toughness of skin material and weather resistance can not also meet actual use when the needs of, so needing exploitation badly
A kind of advanced composite material (ACM) propeller solves the problems of the prior art.
The content of the invention
To solve technical problem present in background technology, the present invention proposes a kind of advanced composite material (ACM) propeller, intensity
Height, good, in light weight, the Stability Analysis of Structures of rigidity, and there is excellent weatherability, extend service life.
A kind of advanced composite material (ACM) propeller proposed by the present invention, including skeleton and skinning layer, the skeleton include skeleton
Body, mounting hole and hollow out, mounting hole is provided with the center of the frame body, and the frame body is provided with and irregularly engraved
Sky, skinning layer is bonded with the hollow out；
The raw material of the frame body includes by weight：Polystyrene 50-60 parts, polymethyl methacrylate 20-30
Part, polyphenyl alkene 5-15 parts, polyvinyl chloride 4-8 parts, polyolefin 3-9 parts, unsaturated polyester resin 4-6 parts, styrene-fourth two
Alkene-styrene triblock copolymer 2-5 parts, ethylene-vinyl acetate copolymer 1-4 parts, polyflon 3-6 parts, poly- hydroxyl
Base butyrate 2-8 parts, chopped carbon fiber 3-6 parts, Lauxite 4-9 parts, trimethyl phosphate 3-9 parts, zinc stearate 2-5 parts, point
Powder 1-4 parts, silane coupler KH-560 4-8 parts, rigidity reinforced auxiliary agent 15-25 parts.
The raw material of skinning layer includes by weight：Polypropylene 30-50 parts, epoxy resin 10-20 parts, polyvinyl fluoride 4-8 parts,
Polyarylate 2-5 parts, PPG 1-4 parts, polyisocyanates 3-6 parts, aramid fiber 2-5 parts, ultra-high molecular weight polyethylene are fine
Tie up 1-4 parts, polyethylene terephthalate fiber 3-6 parts, pbo fiber 2-5 parts, paraffin oil 1-4 parts, diethyl toluene diamine 3-
9 parts, weatherability filler 15-25 parts.
Preferably, in the raw material of frame body, the raw material of rigidity reinforced auxiliary agent includes by weight：Nano carbon white 4-9
Part, nano zine oxide 2-5 parts, organosilicon 1-4 parts, Nano diamond 3-6 parts, attapulgite 1-5 parts, nanometer silicon carbide 2-4 parts,
Glass fibre 2-8 parts, nano silicon 1-4 parts, dichloroethanes 4-8 parts, thionyl chloride 2-6 parts, 2- propylene -1- alcohol 4-6 parts.
Preferably, in the raw material of frame body, rigidity reinforced auxiliary agent is prepared by following technique：By Nano carbon white,
Nano zine oxide, organosilicon, Nano diamond, attapulgite, nanometer silicon carbide, glass fibre, nano silicon and dichloro
Ethane is well mixed, and stirring, is subsequently added into thionyl chloride, is stirred, is then heated up, and is flowed back, be cooled to after room temperature add 2- propylene-
1- alcohol is well mixed, and is then heated up, and is stirred, and washing, after centrifugation, solid is dried, room temperature is cooled to and obtains rigidity reinforced
Auxiliary agent.
Preferably, in the raw material of frame body, rigidity reinforced auxiliary agent is prepared by following technique：By Nano carbon white,
Nano zine oxide, organosilicon, Nano diamond, attapulgite, nanometer silicon carbide, glass fibre, nano silicon and dichloro
Ethane is well mixed, and is stirred 1-3h in 650-850r/min rotating speeds, thionyl chloride is subsequently added into, in 850-1050r/min rotating speeds
20-40min is stirred, is then warming up to 70-80 DEG C, flowed back 5-6h, and addition 2- propylene -1- alcohol is well mixed after being cooled to room temperature,
Then 60-70 DEG C is warming up to, 5-15h is stirred, washing, after centrifugation, by solid in 50-70 DEG C of dry 10-20h, is cooled to
Room temperature obtains rigidity reinforced auxiliary agent.
Preferably, in the raw material of skinning layer, the raw material of weatherability filler includes by weight：It is zinc chloride 5-15 parts, anhydrous
Ethanol 4-9 parts, cerous nitrate 3-6 parts, water 10-20 parts, methacrylate 4-6 parts, hydroquinones 2-5 parts, silane coupler KH-
570 4-6 parts.
Preferably, in the raw material of skinning layer, weatherability filler is prepared by following technique：By zinc chloride, absolute ethyl alcohol
It is well mixed with cerous nitrate, then adds sodium hydroxide solution regulation pH, be then mixed with water, stir, then heat up, protect
Temperature, material a is dried to obtain after washing；Methacrylate and hydroquinones are stirred, are then evaporated under reduced pressure, oil bath heating is returned
Stream, heat up, insulation, then add material a and Silane coupling reagent KH-570 is well mixed, stir, heat up, insulation, be cooled to room
Temperature obtains weatherability filler.
Preferably, in the raw material of skinning layer, weatherability filler is prepared by following technique：By zinc chloride, absolute ethyl alcohol
It is well mixed with cerous nitrate, then adds sodium hydroxide solution regulation pH to 7.5-8.5, be then mixed with water, in 450-
650r/min rotating speeds stir 20-40min, then heat to 140-160 DEG C, are incubated 20-28h, wash after 55-65 DEG C of dry 2-
4h obtains material a；Methacrylate and hydroquinones are stirred into 20-40min in 850-1050r/min rotating speeds, then depressurized
Distillation, oil bath heating backflow, is warming up to 30-50 DEG C, is incubated 20-40min, then adds material a and Silane coupling reagent KH-570
It is well mixed, 20-40min is stirred in 550-850r/min rotating speeds, is warming up to 70-80 DEG C, 2-4h is incubated, is cooled to room temperature and obtains
Weatherability filler.
A kind of advanced composite material (ACM) propeller of the present invention, including skeleton and skinning layer, the skeleton include frame body,
Mounting hole and hollow out, mounting hole are provided with the center of frame body, frame body is provided with irregular hollow out, is bonded with hollow out
Skinning layer, frame body employ intensity and rigid high composite, and its raw material, which is pressed, includes polystyrene, polymethylacrylic acid
Methyl esters, polyphenyl alkene, polyvinyl chloride, polyolefin, unsaturated polyester resin, s-B-S triblock copolymer
Thing, ethylene-vinyl acetate copolymer, polyflon, poly butyric ester, chopped carbon fiber, Lauxite, tricresyl phosphate
Methyl esters, zinc stearate, dispersant, silane coupler KH-560 and rigidity reinforced auxiliary agent.Wherein, rigidity reinforced auxiliary agent will be by that will receive
Off-white carbon black, nano zine oxide, organosilicon, Nano diamond, attapulgite, nanometer silicon carbide, glass fibre, nanometer titanium dioxide
Silicon and dichloroethanes are well mixed, and stirring, are subsequently added into thionyl chloride, are stirred, are then heated up, and are flowed back, and are added after being cooled to room temperature
Enter 2- propylene -1- alcohol to be well mixed, then heat up, stir, washing, after centrifugation, solid is dried, room temperature is cooled to and obtains
Rigidity reinforced auxiliary agent, with Nano carbon white, nano zine oxide, organosilicon, Nano diamond, attapulgite, nanometer silicon carbide, glass
Glass fiber, nano silicon, dichloroethanes, thionyl chloride and 2- propylene -1- alcohol are raw material, by thionyl chloride that nanometer is white
Carbon black, nano zine oxide, organosilicon, Nano diamond, attapulgite, nanometer silicon carbide, glass fibre and nano silicon
On hydroxyl activated, then dichloroethanes carry out chlorine atom substitution, be grafted to unsaturation in the presence of 2- propylene -1- alcohol
On polyester resin, the mechanical property of unsaturated polyester resin is effectively increased, is provided with frame body of the invention excellent
Rigidity reinforced performance.Skinning layer employs the composite having excellent weather resistance, and its raw material includes polypropylene, epoxy resin, poly- fluorine
Ethene, polyarylate, PPG, polyisocyanates, aramid fiber, superhigh molecular weight polyethylene fibers, poly terephthalic acid
Ethylene glycol fiber, pbo fiber, paraffin oil, diethyl toluene diamine and weatherability filler.Wherein weatherability filler presses following technique
Prepared：Zinc chloride, absolute ethyl alcohol and cerous nitrate are well mixed, sodium hydroxide solution regulation pH is then added, then adds
Water is well mixed, and stirring, is then heated up, and is incubated, material a is dried to obtain after washing；Methacrylate and hydroquinones are stirred
Mix, be then evaporated under reduced pressure, oil bath heating backflow, heat up, insulation, then adds material a and Silane coupling reagent KH-570 mixing is equal
It is even, stir, heat up, insulation, be cooled to room temperature and obtain weatherability filler, apply in skinning layer raw material, it is limited to improve covering
The weather resistance of layer, the advanced composite material (ACM) propeller of the present invention is formd in frame body by the way that skinning layer is bonded in, just
Good, in light weight, the Stability Analysis of Structures of property, and there is excellent weatherability, extend service life.
Brief description of the drawings
Fig. 1 is a kind of structural representation of advanced composite material (ACM) propeller middle skeleton proposed by the present invention；
Fig. 2 is a kind of structural representation of advanced composite material (ACM) propeller proposed by the present invention.
Embodiment
The present invention is described in detail with reference to specific embodiment, it should be appreciated that embodiment is served only for illustrating this hair
It is bright, rather than for limiting the invention, any modification made on the basis of the present invention, equivalent substitution etc. are in this hair
In bright protection domain.
Such as Fig. 1 and Fig. 2, Fig. 1 is a kind of structural representation of advanced composite material (ACM) propeller middle skeleton proposed by the present invention；
Fig. 2 is a kind of structural representation of advanced composite material (ACM) propeller proposed by the present invention.
Referring to Figures 1 and 2, a kind of advanced composite material (ACM) propeller proposed by the present invention, including skeleton 1 and skinning layer 2, institute
Stating skeleton 1 includes frame body 101, mounting hole 102 and hollow out 103, and mounting hole is provided with the center of the frame body 101
102, the frame body 101 is provided with irregular hollow out 103, and skinning layer 2 is bonded with the hollow out 103.
Embodiment 1
Referring to Figures 1 and 2, a kind of advanced composite material (ACM) propeller proposed by the present invention, including skeleton 1 and skinning layer 2, institute
Stating skeleton 1 includes frame body 101, mounting hole 102 and hollow out 103, and mounting hole is provided with the center of the frame body 101
102, the frame body 101 is provided with irregular hollow out 103, and skinning layer 2 is bonded with the hollow out 103.
The raw material of the frame body 101 includes by weight：55 parts of polystyrene, 25 parts of polymethyl methacrylate,
10 parts of polyphenyl alkene, 6 parts of polyvinyl chloride, 6 parts of polyolefin, 5 parts of unsaturated polyester resin, s-B-S three are embedding
It is 3.5 parts of copolymer of section, 2.5 parts of ethylene-vinyl acetate copolymer, 4.5 parts of polyflon, 5 parts of poly butyric ester, short
Cut 4.5 parts of carbon fiber, 6.5 parts of Lauxite, 6 parts of trimethyl phosphate, 3.5 parts of zinc stearate, 2.5 parts of dispersant, silane coupled
6 parts of agent KH-560,20 parts of rigidity reinforced auxiliary agent.
In the raw material of frame body 101, rigidity reinforced auxiliary agent is prepared by following technique：6.5 parts are received by weight
Off-white carbon black, 3.5 parts of nano zine oxides, 2.5 parts of organosilicons, 4.5 parts of Nano diamonds, 3 parts of attapulgites, 3 parts of nano silicon carbides
Silicon, 5 parts of glass fibres, 2.5 parts of nano silicons and 6 parts of dichloroethanes are well mixed, and are stirred 2h in 750r/min rotating speeds, are connect
And add 4 parts of thionyl chlorides, stir 30min in 950r/min rotating speeds, be then warming up to 75 DEG C, flow back 5.5h, is cooled to room temperature
Add 5 parts of 2- propylene -1- alcohol afterwards to be well mixed, be then warming up to 65 DEG C, stir 10h, washing, after centrifugation, by solid in
60 DEG C of dry 15h, are cooled to room temperature and obtain rigidity reinforced auxiliary agent.
The raw material of skinning layer 2 includes by weight：40 parts of polypropylene, 15 parts of epoxy resin, 6 parts of polyvinyl fluoride, polyarylate
3.5 parts, 2.5 parts of PPG, 4.5 parts of polyisocyanates, 3.5 parts of aramid fiber, superhigh molecular weight polyethylene fibers 2.5
It is part, 4.5 parts of polyethylene terephthalate fiber, 3.5 parts of pbo fiber, 2.5 parts of paraffin oil, 6 parts of diethyl toluene diamine, resistance to
20 parts of filler of time property.
In the raw material of skinning layer 2, weatherability filler is prepared by following technique：By weight by 10 parts of zinc chloride, 6.5
Part absolute ethyl alcohol and 4.5 parts of cerous nitrates are well mixed, and are then added sodium hydroxide solution regulation pH to 8.0, are then added 15 parts of water
It is well mixed, 30min is stirred in 550r/min rotating speeds, then heats to 150 DEG C, 24h is incubated, washs and obtained after 60 DEG C of dry 3h
To material a；5 parts of methacrylates and 3.5 parts of hydroquinones are stirred into 30min in 950r/min rotating speeds, are then evaporated under reduced pressure,
Oil bath heating flows back, and is warming up to 40 DEG C, is incubated 30min, then adds material a and 5 parts of Silane coupling reagent KH-570s are well mixed,
30min is stirred in 700r/min rotating speeds, is warming up to 75 DEG C, 3h is incubated, is cooled to room temperature and obtains weatherability filler.
Embodiment 2
Referring to Figures 1 and 2, a kind of advanced composite material (ACM) propeller proposed by the present invention, including skeleton 1 and skinning layer 2, institute
Stating skeleton 1 includes frame body 101, mounting hole 102 and hollow out 103, and mounting hole is provided with the center of the frame body 101
102, the frame body 101 is provided with irregular hollow out 103, and skinning layer 2 is bonded with the hollow out 103.
The raw material of the frame body 101 includes by weight：50 parts of polystyrene, 30 parts of polymethyl methacrylate,
5 parts of polyphenyl alkene, 8 parts of polyvinyl chloride, 3 parts of polyolefin, 6 parts of unsaturated polyester resin, s-B-S three are embedding
2 parts of copolymer of section, 4 parts of ethylene-vinyl acetate copolymer, 3 parts of polyflon, 8 parts of poly butyric ester, the carbon that is chopped are fine
Dimension 3 parts, 9 parts of Lauxite, 3 parts of trimethyl phosphate, 5 parts of zinc stearate, 1 part of dispersant, 8 parts of silane coupler KH-560, just
15 parts of reinforcing aids of property.
In the raw material of frame body 101, rigidity reinforced auxiliary agent is prepared by following technique：By weight by 4 parts of nanometers
White carbon, 5 parts of nano zine oxides, 1 part of organosilicon, 6 parts of Nano diamonds, 1 part of attapulgite, 4 parts of nanometer silicon carbides, 2 parts of glass
Glass fiber, 4 parts of nano silicons and 4 parts of dichloroethanes are well mixed, and are stirred 1h in 850r/min rotating speeds, are subsequently added into 6 parts
Thionyl chloride, 40min is stirred in 850r/min rotating speeds, is then warming up to 70 DEG C, flowed back 6h, and 4 parts of 2- are added after being cooled to room temperature
Propylene -1- alcohol is well mixed, and is then warming up to 70 DEG C, stirs 5h, washing, after centrifugation, by solid in 70 DEG C of dry 10h,
It is cooled to room temperature and obtains rigidity reinforced auxiliary agent.
The raw material of skinning layer 2 includes by weight：30 parts of polypropylene, 20 parts of epoxy resin, 4 parts of polyvinyl fluoride, polyarylate 5
Part, 1 part of PPG, 6 parts of polyisocyanates, 2 parts of aramid fiber, 4 parts of superhigh molecular weight polyethylene fibers, poly- terephthaldehyde
Sour 3 parts of ethylene glycol fiber, 5 parts of pbo fiber, 1 part of paraffin oil, 9 parts of diethyl toluene diamine, 15 parts of weatherability filler.
In the raw material of skinning layer 2, weatherability filler is prepared by following technique：By weight by 5 parts of zinc chloride, 9 parts
Absolute ethyl alcohol and 3 parts of cerous nitrates are well mixed, and then add sodium hydroxide solution regulation pH to 8.5, and then plus 10 parts of water mix
Uniformly, 20min is stirred in 650r/min rotating speeds, then heats to 160 DEG C, be incubated 20h, wash and obtain thing after 65 DEG C of dry 2h
Expect a；6 parts of methacrylates and 2 parts of hydroquinones are stirred into 20min in 1050r/min rotating speeds, are then evaporated under reduced pressure, oil bath
It is heated to reflux, is warming up to 50 DEG C, be incubated 20min, then adds material a and 6 parts of Silane coupling reagent KH-570s are well mixed, in
550r/min rotating speeds stir 40min, are warming up to 70 DEG C, are incubated 4h, are cooled to room temperature and obtain weatherability filler.
Embodiment 3
Referring to Figures 1 and 2, a kind of advanced composite material (ACM) propeller proposed by the present invention, including skeleton 1 and skinning layer 2, institute
Stating skeleton 1 includes frame body 101, mounting hole 102 and hollow out 103, and mounting hole is provided with the center of the frame body 101
102, the frame body 101 is provided with irregular hollow out 103, and skinning layer 2 is bonded with the hollow out 103.
The raw material of the frame body 101 includes by weight：60 parts of polystyrene, 20 parts of polymethyl methacrylate,
15 parts of polyphenyl alkene, 4 parts of polyvinyl chloride, 9 parts of polyolefin, 4 parts of unsaturated polyester resin, s-B-S three are embedding
5 parts of copolymer of section, 1 part of ethylene-vinyl acetate copolymer, 6 parts of polyflon, 2 parts of poly butyric ester, the carbon that is chopped are fine
Dimension 6 parts, 4 parts of Lauxite, 9 parts of trimethyl phosphate, 2 parts of zinc stearate, 4 parts of dispersant, 4 parts of silane coupler KH-560, just
25 parts of reinforcing aids of property.
In the raw material of frame body 101, rigidity reinforced auxiliary agent is prepared by following technique：By weight by 9 parts of nanometers
White carbon, 2 parts of nano zine oxides, 4 parts of organosilicons, 3 parts of Nano diamonds, 5 parts of attapulgites, 2 parts of nanometer silicon carbides, 8 parts of glass
Glass fiber, 1 part of nano silicon and 8 parts of dichloroethanes are well mixed, and are stirred 3h in 650r/min rotating speeds, are subsequently added into 2 parts
Thionyl chloride, 20min is stirred in 1050r/min rotating speeds, is then warming up to 80 DEG C, flowed back 5h, and 6 parts of 2- are added after being cooled to room temperature
Propylene -1- alcohol is well mixed, and is then warming up to 60 DEG C, stirs 15h, washing, after centrifugation, by solid in 50 DEG C of dry 20h,
It is cooled to room temperature and obtains rigidity reinforced auxiliary agent.
The raw material of skinning layer 2 includes by weight：50 parts of polypropylene, 10 parts of epoxy resin, 8 parts of polyvinyl fluoride, polyarylate 2
Part, 4 parts of PPG, 3 parts of polyisocyanates, 5 parts of aramid fiber, 1 part of superhigh molecular weight polyethylene fibers, poly- terephthaldehyde
Sour 6 parts of ethylene glycol fiber, 2 parts of pbo fiber, 4 parts of paraffin oil, 3 parts of diethyl toluene diamine, 25 parts of weatherability filler.
In the raw material of skinning layer 2, weatherability filler is prepared by following technique：By weight by 15 parts of zinc chloride, 4 parts
Absolute ethyl alcohol and 6 parts of cerous nitrates are well mixed, and then add sodium hydroxide solution regulation pH to 7.5, and then plus 20 parts of water mix
Uniformly, 40min is stirred in 450r/min rotating speeds, then heats to 140 DEG C, be incubated 28h, wash and obtain thing after 55 DEG C of dry 4h
Expect a；4 parts of methacrylates and 5 parts of hydroquinones are stirred into 40min in 850r/min rotating speeds, are then evaporated under reduced pressure, oil bath adds
Heat backflow, is warming up to 30 DEG C, is incubated 40min, then adds material a and 4 parts of Silane coupling reagent KH-570s are well mixed, in
850r/min rotating speeds stir 20min, are warming up to 80 DEG C, are incubated 2h, are cooled to room temperature and obtain weatherability filler.
Embodiment 4
Referring to Figures 1 and 2, a kind of advanced composite material (ACM) propeller proposed by the present invention, including skeleton 1 and skinning layer 2, institute
Stating skeleton 1 includes frame body 101, mounting hole 102 and hollow out 103, and mounting hole is provided with the center of the frame body 101
102, the frame body 101 is provided with irregular hollow out 103, and skinning layer 2 is bonded with the hollow out 103.
The raw material of the frame body 101 includes by weight：52 parts of polystyrene, 28 parts of polymethyl methacrylate,
8 parts of polyphenyl alkene, 7 parts of polyvinyl chloride, 4 parts of polyolefin, 5.5 parts of unsaturated polyester resin, s-B-S three
3 parts of block copolymer, 3 parts of ethylene-vinyl acetate copolymer, 4 parts of polyflon, 7 parts of poly butyric ester, chopped carbon
4 parts of fiber, 8 parts of Lauxite, 4 parts of trimethyl phosphate, 4 parts of zinc stearate, 2 parts of dispersant, 7 parts of silane coupler KH-560,
18 parts of rigidity reinforced auxiliary agent.
In the raw material of frame body 101, rigidity reinforced auxiliary agent is prepared by following technique：By weight by 5 parts of nanometers
White carbon, 4 parts of nano zine oxides, 2 parts of organosilicons, 5 parts of Nano diamonds, 2 parts of attapulgites, 3.5 parts of nanometer silicon carbides, 3 parts
Glass fibre, 3 parts of nano silicons and 5 parts of dichloroethanes are well mixed, and are stirred 1.5h in 820r/min rotating speeds, are subsequently added into
5 parts of thionyl chlorides, 35min is stirred in 880r/min rotating speeds, is then warming up to 72 DEG C, flow back 5.8h, is added after being cooled to room temperature
4.5 parts of 2- propylene -1- alcohol are well mixed, and are then warming up to 68 DEG C, stir 8h, and washing is dry in 65 DEG C by solid after centrifugation
Dry 12h, it is cooled to room temperature and obtains rigidity reinforced auxiliary agent.
The raw material of skinning layer 2 includes by weight：35 parts of polypropylene, 18 parts of epoxy resin, 5 parts of polyvinyl fluoride, polyarylate 4
Part, 2 parts of PPG, 5 parts of polyisocyanates, 3 parts of aramid fiber, 3 parts of superhigh molecular weight polyethylene fibers, poly- terephthaldehyde
Sour 4 parts of ethylene glycol fiber, 4 parts of pbo fiber, 2 parts of paraffin oil, 8 parts of diethyl toluene diamine, 18 parts of weatherability filler.
In the raw material of skinning layer 2, weatherability filler is prepared by following technique：By weight by 8 parts of zinc chloride, 8 parts
Absolute ethyl alcohol and 4 parts of cerous nitrates are well mixed, and then add sodium hydroxide solution regulation pH to 8.2 then plus 12 parts of water mixing are equal
It is even, 25min is stirred in 620r/min rotating speeds, then heats to 155 DEG C, 22h is incubated, washs and obtain thing after 62 DEG C of dry 2.5h
Expect a；5.5 parts of methacrylates and 3 parts of hydroquinones are stirred into 25min in 1020r/min rotating speeds, are then evaporated under reduced pressure, oil
Bath is heated to reflux, and is warming up to 45 DEG C, is incubated 25min, then adds material a and 5.5 parts of Silane coupling reagent KH-570s are well mixed,
35min is stirred in 580r/min rotating speeds, is warming up to 72 DEG C, 3.5h is incubated, is cooled to room temperature and obtains weatherability filler.
Embodiment 5
Referring to Figures 1 and 2, a kind of advanced composite material (ACM) propeller proposed by the present invention, including skeleton 1 and skinning layer 2, institute
Stating skeleton 1 includes frame body 101, mounting hole 102 and hollow out 103, and mounting hole is provided with the center of the frame body 101
102, the frame body 101 is provided with irregular hollow out 103, and skinning layer 2 is bonded with the hollow out 103.
The raw material of the frame body 101 includes by weight：58 parts of polystyrene, 22 parts of polymethyl methacrylate,
12 parts of polyphenyl alkene, 5 parts of polyvinyl chloride, 8 parts of polyolefin, 4.5 parts of unsaturated polyester resin, s-B-S three
4 parts of block copolymer, 2 parts of ethylene-vinyl acetate copolymer, 5 parts of polyflon, 3 parts of poly butyric ester, chopped carbon
5 parts of fiber, 5 parts of Lauxite, 8 parts of trimethyl phosphate, 3 parts of zinc stearate, 3 parts of dispersant, 5 parts of silane coupler KH-560,
22 parts of rigidity reinforced auxiliary agent.
In the raw material of frame body 101, rigidity reinforced auxiliary agent is prepared by following technique：By weight by 8 parts of nanometers
White carbon, 3 parts of nano zine oxides, 3 parts of organosilicons, 4 parts of Nano diamonds, 4 parts of attapulgites, 2.5 parts of nanometer silicon carbides, 7 parts
Glass fibre, 2 parts of nano silicons and 7 parts of dichloroethanes are well mixed, and are stirred 2.5h in 680r/min rotating speeds, are subsequently added into
3 parts of thionyl chlorides, 25min is stirred in 1020r/min rotating speeds, is then warming up to 78 DEG C, flow back 5.2h, is added after being cooled to room temperature
5.5 parts of 2- propylene -1- alcohol are well mixed, and are then warming up to 62 DEG C, stir 12h, washing, after centrifugation, by solid in 55 DEG C
18h is dried, room temperature is cooled to and obtains rigidity reinforced auxiliary agent.
The raw material of skinning layer 2 includes by weight：45 parts of polypropylene, 12 parts of epoxy resin, 7 parts of polyvinyl fluoride, polyarylate 3
Part, 3 parts of PPG, 4 parts of polyisocyanates, 4 parts of aramid fiber, 2 parts of superhigh molecular weight polyethylene fibers, poly- terephthaldehyde
Sour 5 parts of ethylene glycol fiber, 3 parts of pbo fiber, 3 parts of paraffin oil, 4 parts of diethyl toluene diamine, 22 parts of weatherability filler.
In the raw material of skinning layer 2, weatherability filler is prepared by following technique：By weight by 12 parts of zinc chloride, 5 parts
Absolute ethyl alcohol and 5 parts of cerous nitrates are well mixed, and then add sodium hydroxide solution regulation pH to 7.8 then plus 18 parts of water mixing are equal
It is even, 35min is stirred in 480r/min rotating speeds, then heats to 145 DEG C, 26h is incubated, washs and obtain thing after 58 DEG C of dry 3.5h
Expect a；4.5 parts of methacrylates and 4 parts of hydroquinones are stirred into 35min in 880r/min rotating speeds, are then evaporated under reduced pressure, oil bath
It is heated to reflux, is warming up to 35 DEG C, be incubated 35min, then adds material a and 4.5 parts of Silane coupling reagent KH-570s are well mixed, in
820r/min rotating speeds stir 25min, are warming up to 78 DEG C, are incubated 2.5h, are cooled to room temperature and obtain weatherability filler.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.
Claims (7)
- A kind of 1. advanced composite material (ACM) propeller, it is characterised in that including skeleton (1) and skinning layer (2), skeleton (1) bag Frame body (101), mounting hole (102) and hollow out (103) are included, mounting hole is provided with the center of the frame body (101) (102), the frame body (101) is provided with irregular hollow out (103), and skinning layer (2) is bonded with the hollow out (103)；The raw material of the frame body (101) includes by weight：Polystyrene 50-60 parts, polymethyl methacrylate 20-30 Part, polyphenyl alkene 5-15 parts, polyvinyl chloride 4-8 parts, polyolefin 3-9 parts, unsaturated polyester resin 4-6 parts, styrene-fourth two Alkene-styrene triblock copolymer 2-5 parts, ethylene-vinyl acetate copolymer 1-4 parts, polyflon 3-6 parts, poly- hydroxyl Base butyrate 2-8 parts, chopped carbon fiber 3-6 parts, Lauxite 4-9 parts, trimethyl phosphate 3-9 parts, zinc stearate 2-5 parts, point Powder 1-4 parts, silane coupler KH-560 4-8 parts, rigidity reinforced auxiliary agent 15-25 parts；The raw material of skinning layer (2) includes by weight：Polypropylene 30-50 parts, epoxy resin 10-20 parts, polyvinyl fluoride 4-8 parts, Polyarylate 2-5 parts, PPG 1-4 parts, polyisocyanates 3-6 parts, aramid fiber 2-5 parts, ultra-high molecular weight polyethylene are fine Tie up 1-4 parts, polyethylene terephthalate fiber 3-6 parts, pbo fiber 2-5 parts, paraffin oil 1-4 parts, diethyl toluene diamine 3- 9 parts, weatherability filler 15-25 parts.
- 2. advanced composite material (ACM) propeller according to claim 1, it is characterised in that in the raw material of frame body (101), The raw material of rigidity reinforced auxiliary agent includes by weight：Nano carbon white 4-9 parts, nano zine oxide 2-5 parts, organosilicon 1-4 parts, receive Rice diamond 3-6 parts, attapulgite 1-5 parts, nanometer silicon carbide 2-4 parts, glass fibre 2-8 parts, nano silicon 1-4 parts, Dichloroethanes 4-8 parts, thionyl chloride 2-6 parts, 2- propylene -1- alcohol 4-6 parts.
- 3. advanced composite material (ACM) propeller according to claim 1 or 2, it is characterised in that the raw material of frame body (101) In, rigidity reinforced auxiliary agent is prepared by following technique：By Nano carbon white, nano zine oxide, organosilicon, Nano diamond, Attapulgite, nanometer silicon carbide, glass fibre, nano silicon and dichloroethanes are well mixed, and stirring, are subsequently added into sulfurous Acyl chlorides, stirring, is then heated up, and flows back, and addition 2- propylene -1- alcohol is well mixed after being cooled to room temperature, is then heated up, is stirred, wash Wash, after centrifugation, solid is dried, be cooled to room temperature and obtain rigidity reinforced auxiliary agent.
- 4. according to the advanced composite material (ACM) propeller described in claim any one of 1-3, it is characterised in that frame body (101) Raw material in, rigidity reinforced auxiliary agent is prepared by following technique：By Nano carbon white, nano zine oxide, organosilicon, nanogold Hard rock, attapulgite, nanometer silicon carbide, glass fibre, nano silicon and dichloroethanes are well mixed, in 650-850r/ Min rotating speeds stir 1-3h, are subsequently added into thionyl chloride, stir 20-40min in 850-1050r/min rotating speeds, are then warming up to 70-80 DEG C, flowed back 5-6h, and addition 2- propylene -1- alcohol is well mixed after being cooled to room temperature, is then warming up to 60-70 DEG C, is stirred 5- 15h, washing, after centrifugation, by solid in 50-70 DEG C of dry 10-20h, is cooled to room temperature and obtains rigidity reinforced auxiliary agent.
- 5. according to the advanced composite material (ACM) propeller described in claim any one of 1-4, it is characterised in that the original of skinning layer (2) In material, the raw material of weatherability filler includes by weight：Zinc chloride 5-15 parts, absolute ethyl alcohol 4-9 parts, cerous nitrate 3-6 parts, water 10-20 parts, methacrylate 4-6 parts, hydroquinones 2-5 parts, Silane coupling reagent KH-570 4-6 parts.
- 6. according to the advanced composite material (ACM) propeller described in claim any one of 1-5, it is characterised in that the original of skinning layer (2) In material, weatherability filler is prepared by following technique：Zinc chloride, absolute ethyl alcohol and cerous nitrate are well mixed, then added Sodium hydroxide solution adjusts pH, is then mixed with water, and stirs, then heats up, and is incubated, material a is dried to obtain after washing；Will Methacrylate and hydroquinones stirring, are then evaporated under reduced pressure, and oil bath heating backflow, heat up, insulation, then add material a It is well mixed, stirs with Silane coupling reagent KH-570, heat up, insulation, is cooled to room temperature and obtains weatherability filler.
- 7. according to the advanced composite material (ACM) propeller described in claim any one of 1-6, it is characterised in that the original of skinning layer (2) In material, weatherability filler is prepared by following technique：Zinc chloride, absolute ethyl alcohol and cerous nitrate are well mixed, then added Sodium hydroxide solution adjusts pH to 7.5-8.5, is then mixed with water, and 20-40min is stirred in 450-650r/min rotating speeds, 140-160 DEG C is then heated to, 20-28h is incubated, washs and obtain material a after 55-65 DEG C of dry 2-4h；By methacrylic acid Ester and hydroquinones stir 20-40min in 850-1050r/min rotating speeds, are then evaporated under reduced pressure, and oil bath heating backflow, are warming up to 30-50 DEG C, 20-40min is incubated, then material a is added and Silane coupling reagent KH-570 is well mixed, is turned in 550-850r/min Speed stirring 20-40min, is warming up to 70-80 DEG C, is incubated 2-4h, is cooled to room temperature and obtains weatherability filler.
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107793891A (en) * | 2017-11-30 | 2018-03-13 | 安徽卓尔航空科技有限公司 | A kind of composite propeller surface coating |
| CN107793893A (en) * | 2017-11-30 | 2018-03-13 | 安徽卓尔航空科技有限公司 | A kind of propeller surfacecti proteon coating of high adhesion force |
| CN107858076A (en) * | 2017-11-30 | 2018-03-30 | 安徽卓尔航空科技有限公司 | A kind of propeller for vessels antifouling paint |
| CN107868573A (en) * | 2017-11-30 | 2018-04-03 | 安徽卓尔航空科技有限公司 | A kind of high tenacity propeller surfacecti proteon coating |
| CN107880725A (en) * | 2017-11-30 | 2018-04-06 | 安徽卓尔航空科技有限公司 | A kind of water jet propeller of ship impeller coating |
| CN107903791A (en) * | 2017-11-30 | 2018-04-13 | 安徽卓尔航空科技有限公司 | A kind of fluorocarbon coatings of propeller scratch-resistant |
| CN112026461A (en) * | 2020-08-31 | 2020-12-04 | 哈尔滨工业大学 | Paddle-leg type deformable amphibious six-legged robot |
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| CN107903791A (en) * | 2017-11-30 | 2018-04-13 | 安徽卓尔航空科技有限公司 | A kind of fluorocarbon coatings of propeller scratch-resistant |
| CN112026461A (en) * | 2020-08-31 | 2020-12-04 | 哈尔滨工业大学 | Paddle-leg type deformable amphibious six-legged robot |
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Application publication date: 20171124 |