CN107258833A - A kind of preparation method of rosin mixture biological pesticide - Google Patents
A kind of preparation method of rosin mixture biological pesticide Download PDFInfo
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- CN107258833A CN107258833A CN201710568364.3A CN201710568364A CN107258833A CN 107258833 A CN107258833 A CN 107258833A CN 201710568364 A CN201710568364 A CN 201710568364A CN 107258833 A CN107258833 A CN 107258833A
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- mass ratio
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- rosin mixture
- rosin
- extract solution
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/40—Liliopsida [monocotyledons]
- A01N65/42—Aloeaceae [Aloe family] or Liliaceae [Lily family], e.g. aloe, veratrum, onion, garlic or chives
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Abstract
The present invention relates to a kind of preparation method of rosin mixture biological pesticide, rosin mixture, extracts of Chinese herbal medicine, synergist and vegetable oil are added in homogenizer according to certain mass ratio, at least it is homogeneous once, produce rosin mixture biological pesticide.The present invention has obvious desinsection and antibacterial effect.Raw material sources of the present invention have the advantages that low toxicity and harmless in plant.
Description
Technical field
The present invention relates to a kind of preparation method of rosin mixture biological pesticide.
Background technology
With the improvement of living standards, people increasingly pay attention to food-safety problem.Chemical pesticide is used for a long time, to ecology
Do a lot of damage, chemical pesticide is not degradable, there is Pesticide Residue, seriously threaten the health of people.2017 " in
Number file in centre " mentions General Promotion agricultural product quality and food safety standard.Adhere to quality Xing Nong, implement agricultural standardization war
Slightly, prominent high-quality, safety, green oriented, perfect agricultural product quality and food safety standard system.
Because the agricultural chemicals that orchard is used all is acid agrichemical throughout the year, make this acid ring of growth adaptation of pest and disease damage
Border, and rosin (alkali) mixture is used, the sour environment in orchard can be improved, break the environment that pest and disease damage is adapted to, mitigate pest and disease damage
The resistance to the action of a drug.Traditional rosin mixture is to use rosin (rosin without degreasing), soda ash or caustic soda (i.e. sodium carbonate or caustic soda)
Add water a kind of dark brown strong basicity insecticide for boiling and being made.Its compatibility is very poor, it is impossible to used with synthetic organic pesticide,
Can not be mixed with Bordeaux mixture, the lime sulfur of calcic etc..Which limits the use of rosin mixture.
Market is needed to person poultry harmless, does not destroy ecological environment, the good low-toxin farm chemicals of compatibility.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of preparation method of rosin mixture biological pesticide, the present invention
With obvious desinsection and antibacterial effect, low toxicity and harmless.
In order to solve the above-mentioned technical problem, the present invention uses following technical scheme：
A kind of preparation method of rosin mixture biological pesticide, it is characterised in that follow the steps below：
By rosin mixture, extracts of Chinese herbal medicine, synergist and vegetable oil according to mass ratio 20~30:20~30:10~20:
30~50 are added in homogenizer, at least it is homogeneous once, produce rosin mixture biological pesticide；
The extracts of Chinese herbal medicine is trifoliate jewelvine extract solution, Herba Houttuyniae extract, garlic extract, orange peel extraction and Chinese cassia tree
Extract solution is according to mass ratio 40~60:20~40:10~20:5~10:10~20 composition；Extracting method is extracted for water；
The synergist is AEO-3, AEO-9, span-80, sorbierite and glycerine according to mass ratio 15~30:15~
30:5~10:25~40:10~20 composition；
The vegetable oil is the one or any ratio in palm oil, coconut oil, chinaberry seeds oil, mandarin orange oil, fruit of cubeb litsea tree oil
It is two or more.
The rosin mixture is followed the steps below：By rosin, organic base, catalyst and water according to mass ratio 10~
30:20~40:0.5~5:80~120 are added in container, and 30~90min is heated at a temperature of 80~100 DEG C, filter off impurity,
Gained filtrate is rosin mixture；
The organic base is the one or any ratio in monoethanolamine, diethanol amine, triethanolamine and caustic alcohol
It is two or more；
The catalyst is the two or more of the one or any ratio in sulfuric acid, hydrochloric acid, nitric acid and lewis acid.
Trifoliate jewelvine extract solution, Herba Houttuyniae extract, garlic extract, orange peel extraction and Chinese cassia tree extract solution are according to mass ratio
50:25:15:8:15 composition；
Extract solution extracting method, which is characterized in that, to be followed the steps below：
1) not good liquor is prepared：By Chinese herbal medicine and water according to mass ratio 1:5~40 are added in container, are heated to 50~75
DEG C, 20~90min of constant temperature is cooled to 20~40 DEG C, filtering, gained filtrate is a not good liquor；Residue obtained is the dregs of a decoction；
2) two not good liquors are prepared：By the dregs of a decoction and water according to mass ratio 1:5~40 are added in container, are heated to 70~120 DEG C,
Under the conditions of pressure is 0~5MPa, 20~90min of constant temperature is cooled to 20~40 DEG C, filtering, gained filtrate is two not good liquors；
3) extract solution is prepared：By step 1) gained one not good liquor and step 2) gained two not good liquors merge, temperature be 20~90
DEG C, pressure be -5MPa~0MPa under the conditions of, concentrate 0~90min, gained concentrate is extract solution.
4th, the preparation method of rosin mixture biological pesticide as claimed in claim 1, it is characterised in that：The synergist is
AEO-3, AEO-9, span-80, sorbierite and glycerine are according to mass ratio 20:25:8:30:15 composition.
5th, the preparation method of rosin mixture biological pesticide as claimed in claim 1, it is characterised in that：The vegetable oil is
Fruit of cubeb litsea tree oil.
The organic base is triethanolamine；The catalyst is nitric acid.
The rosin mixture, extracts of Chinese herbal medicine, the mass ratio of synergist and vegetable oil are 20:30:15:35.
Homogeneous 2 times, wherein first time homogeneous pressure is 15~35MPa, and homogeneous temperature is 50~70 DEG C, and the homogeneous time is 10
~60min；Second of homogeneous pressure is 2~8PMa, and homogeneous temperature is 50~70 DEG C, and the homogeneous time is 10~60min.
Trifoliate jewelvine, belongs to pulse family liana, and climbing shrub is all bald net.Odd number winglike compound leaf.With blood stasis removing analgesic, kill
Effect of worm.Rotenone is very strong to insect and toxicity in fish, and then toxicity is very light to mammal, and dog intravenous injection lethal dose is
0.5mg/kg, and orally then need to increase 600 times；General oral 0.2g/kg will not cause death.
Cordate houttuynia (English name HERBA HOUTTUYNIAE) is the herbal medicine that Chinese Pharmacopoeia is included, and herbal medicine source is saururus chinensis
Section's plant heartleaf houttuynia (Classification system：Houttuynia cordata Thunb.) dry aerial parts.The luxuriant flower spike of summer cauline leaf
Tapped when many, remove impurity, dry.Cordate houttuynia is pungent, cold, return lung warp.Can it is clearing heat and detoxicating, detumescence treat sore, promoting urination and removing dampness,
Clearing away heat to cure dysentery, stomach strengthening and digestion promoting, are accumulated with lung carbuncle, sore swollen toxin, hemorrhoidal hemorrhage, taste that real heat, heat toxin, damp evil, disease heat are trouble is controlled
Heat etc..Modern pharmacology experiment shows that this product has the effect such as antibacterial, antiviral, raising immunity of organisms, diuresis.
Garlic (Garlic) is called garlic, garlic, giant garlic, calabash, only garlic, single clove garlic, is the general designation of garlic class plant.Half a year
Raw herbaceous plant, Liliaceae allium, is used as medicine with bulb.Spring, summer harvesting, binding hang ventilation, dry in the shade standby.Farmer's proverb, which is said, " plants
The garlic not coldest days of the year end (moon), the only head of coldest days of the year end length ", June leaf it is withered when excavate, remove silt, crust drying is dried or is baked in ventilation.Have
Middle benefit gas stomach invigorating, the effect for the qi-regulating that helps digestion.Sulfur-containing compound has strong antibacterial and anti-inflammation functions in garlic, to a variety of coccuses, bar
Bacterium, fungi and virus etc. have suppression and killing action, are antibacterial action most strong one kind in the natural plants currently found.
Tangerine peel Chinese medicine name.For being dried to for rutaceae orange Citrus reticulata Blanco and its variety
Ripe pericarp.Medicinal material is divided into " dried orange peel " and " citrus chachiensis hortorum ".Harvesting ripe fruit, strips pericarp, dries or low temperature drying.With qi-regulating
Invigorating the spleen, eliminating dampness and eliminating phlegm effect.
Chinese cassia tree (Classification system：Cinnamomum cassia Presl), also known as beautiful osmanthus, male osmanthus, cajaput, great Gui, peppery osmanthus,
Safety tree, cassia, are the dry bark of canella Chinese cassia tree.Bark fragrance, can make spices, taste is with originating from Sri Lanka's meat
The cassia bark in osmanthus is similar, but pepperyyer, delicious not as good as cassia bark, and thick compared with cassia bark.Complement sun, warming spleen and stomach, removing internal cold, promoting blood circulation.Control life
Door fire declines, cold weak pulse of limb, yang depletion collapse, diarrhea of suffering from abdominal pain, cold hernia run quickly globefish, waist and knee crymodynia, Amenorrhea abdominal mass, cloudy subcutaneous ulcer, streamer, and empty sun
It is floating to get over, heat in the upper and cold in the lower.Cassia oil has powerful bactericidal action, and the effect to Gram's staining is better than negative patient, because of spinosity
Swash property, seldom as antibacterials, but external application can treat stomachache, flatulence angina etc..It is for oral administration to make stomach invigorating and carminative.
There is obvious fungicidal action.
The resin that rosin, mainly pine tree or conifer trunk are secreted out of, containing rosin and turpentine oil.Also referred to as rosin, loose cream, pine
Glue, loose liquid, loose fat.It can be used as materials such as emulsion paint and adhesives, therefore resin has higher commercial value.It
It is the mixture of a variety of high-molecular compounds, so there are different fusing points.Resin can be divided into two kinds of natural resin and synthetic resin.
Itself only natural resin this is a kind of, but with the development of chemical industry, have it is many produced by artificial synthesized polymer, it is central some
The chemical property and physical property of polymer can be much like with natural resin, and therefore, polymer can be referred to as synthetic resin.In sky
It is in viscous liquid or blocks of solid in gas.Its special chemical constitution, can be as materials'uses such as emulsion paint and adhesives, therefore
With higher commercial value.
Invention has following advantageous effects：
1st, the present invention is aided with other materials, trifoliate jewelvine based on trifoliate jewelvine extract and is contained rotenone, rotenone to insect and
Toxicity in fish is very strong, and then toxicity is very light to mammal.Therefore people and animals will not be caused harm, does not destroy the ecological balance.
2nd, extract solution is extracted using water in the present invention, in the absence of problem of solvent residual, does not produce waste water and waste gas, will not be right
Environment is damaged.
3rd, the present invention is extracted using secondary water, and low molecule amount can be prevented to be dissolved in the active matter of water, is decomposed in hot environment,
It ensure that the integrality of extract.
4th, the synergist that the present invention is used can obviously reduce the surface tension of liquid, with stronger spreadability, permeability
And moisture retention, the utilization rate of agricultural chemicals can be significantly improved.
5th, the present invention uses rosin and organic base the synthetic resin acid amide under catalyst effect, compared with traditional handicraft
The corrosivity of rosin mixture is greatly reduced, the compatibility of rosin mixture is added.
6th, the present invention is secondary homogeneous to extract progress using homogenizer, makes emulsion-stabilizing, convenient use.
7th, the preferred fruit of cubeb litsea tree oil of vegetable oil of the present invention, fruit of cubeb litsea tree oil main component citral (60%~80%), methyl heptan
Ketenes (2.5%), citronellal (1.0%), australene, amphene, limonene, α-humulene, p-isopropyl methanol, geraniol, camphor.
Camphor and australene have desinsection and anthelmintic action, can substantially increase the drug effect of the present invention.
Embodiment
The present invention is further illustrated with reference to instantiation.
Embodiment 1
It is 20 by the mass ratio of rosin mixture, extracts of Chinese herbal medicine, synergist and vegetable oil:30:15:35 be added to it is homogeneous
In machine, homogeneous 2 times, wherein first time homogeneous pressure is 25MPa, and homogeneous temperature is 65 DEG C, and the homogeneous time is 20min；Second
Homogeneous pressure is 4PMa, and homogeneous temperature is 65 DEG C, and the homogeneous time is 25min, produces rosin mixture biological pesticide.
The rosin mixture is followed the steps below：By rosin, triethanolamine, nitric acid and water according to mass ratio 10:25:
2:100 are added in container, and 50min is heated at a temperature of 90 DEG C, filter off impurity, gained filtrate is rosin mixture；
The extracts of Chinese herbal medicine is trifoliate jewelvine extract solution, Herba Houttuyniae extract, garlic extract, orange peel extraction and Chinese cassia tree
Extract solution is according to mass ratio 50:25:15:8:15 composition；The synergist is AEO-3, AEO-9, span-80, sorbierite
With glycerine according to mass ratio 20:25:8:30:15 composition；The vegetable oil is fruit of cubeb litsea tree oil.
Extract solution extracting method, which is characterized in that, to be followed the steps below：
1) not good liquor is prepared：By one kind and water in trifoliate jewelvine, cordate houttuynia, garlic, tangerine peel and Chinese cassia tree according to mass ratio 1:15
It is added in container, is heated to 65 DEG C, constant temperature 40min is cooled to 30 DEG C, filtering, gained filtrate is a not good liquor；It is residue obtained to be
The dregs of a decoction；
2) two not good liquors are prepared：By the dregs of a decoction and water according to mass ratio 1:12 are added in container, are heated to 95 DEG C, are in pressure
Under the conditions of 1.5MPa, constant temperature 45min is cooled to 30 DEG C, filtering, gained filtrate is two not good liquors；
3) extract solution is prepared：By step 1) gained one not good liquor and step 2) gained two not good liquors merge, temperature be 75 DEG C, pressure
Under the conditions of power is -0.8MPa, 30min is concentrated, during gained concentrate is trifoliate jewelvine, cordate houttuynia, garlic, tangerine peel and Chinese cassia tree extract solution
One kind.
Embodiment 2
It is 20 by the mass ratio of rosin mixture, extracts of Chinese herbal medicine, synergist and vegetable oil:30:15:35 be added to it is homogeneous
In machine, homogeneous 2 times, wherein first time homogeneous pressure is 25MPa, and homogeneous temperature is 65 DEG C, and the homogeneous time is 20min；Second
Homogeneous pressure is 4PMa, and homogeneous temperature is 65 DEG C, and the homogeneous time is 25min, produces rosin mixture biological pesticide.
The rosin mixture is followed the steps below：By rosin, triethanolamine, nitric acid and water according to mass ratio 10:25:
2:100 are added in container, and 50min is heated at a temperature of 90 DEG C, filter off impurity, gained filtrate is rosin mixture；
The extracts of Chinese herbal medicine is trifoliate jewelvine extract solution, Herba Houttuyniae extract, garlic extract, orange peel extraction and Chinese cassia tree
Extract solution is according to mass ratio 45:30:10:5:10 composition；The synergist is AEO-3, AEO-9, span-80, sorbierite
With glycerine according to mass ratio 20:25:8:30:15 composition；The vegetable oil is fruit of cubeb litsea tree oil.
Extract solution extracting method, which is characterized in that, to be followed the steps below：
1) not good liquor is prepared：By one kind and water in trifoliate jewelvine, cordate houttuynia, garlic, tangerine peel and Chinese cassia tree according to mass ratio 1:15
It is added in container, is heated to 65 DEG C, constant temperature 40min is cooled to 30 DEG C, filtering, gained filtrate is a not good liquor；It is residue obtained to be
The dregs of a decoction；
2) two not good liquors are prepared：By the dregs of a decoction and water according to mass ratio 1:12 are added in container, are heated to 95 DEG C, are in pressure
Under the conditions of 1.5MPa, constant temperature 45min is cooled to 30 DEG C, filtering, gained filtrate is two not good liquors；
3) extract solution is prepared：By step 1) gained one not good liquor and step 2) gained two not good liquors merge, temperature be 75 DEG C, pressure
Under the conditions of power is -0.8MPa, 30min is concentrated, during gained concentrate is trifoliate jewelvine, cordate houttuynia, garlic, tangerine peel and Chinese cassia tree extract solution
One kind.
Embodiment 3
It is 20 by the mass ratio of rosin mixture, extracts of Chinese herbal medicine, synergist and vegetable oil:30:15:35 be added to it is homogeneous
In machine, homogeneous 2 times, wherein first time homogeneous pressure is 25MPa, and homogeneous temperature is 65 DEG C, and the homogeneous time is 20min；Second
Homogeneous pressure is 4PMa, and homogeneous temperature is 65 DEG C, and the homogeneous time is 25min, produces rosin mixture biological pesticide.
The rosin mixture is followed the steps below：By rosin, triethanolamine, nitric acid and water according to mass ratio 10:25:
2:100 are added in container, and 50min is heated at a temperature of 90 DEG C, filter off impurity, gained filtrate is rosin mixture；
The extracts of Chinese herbal medicine is trifoliate jewelvine extract solution, Herba Houttuyniae extract, garlic extract, orange peel extraction and Chinese cassia tree
Extract solution is according to mass ratio 55:20:10:5:10 composition；The synergist is AEO-3, AEO-9, span-80, sorbierite
With glycerine according to mass ratio 20:25:8:30:15 composition；The vegetable oil is fruit of cubeb litsea tree oil.
Extract solution extracting method, which is characterized in that, to be followed the steps below：
1) not good liquor is prepared：By one kind and water in trifoliate jewelvine, cordate houttuynia, garlic, tangerine peel and Chinese cassia tree according to mass ratio 1:15
It is added in container, is heated to 65 DEG C, constant temperature 40min is cooled to 30 DEG C, filtering, gained filtrate is a not good liquor；It is residue obtained to be
The dregs of a decoction；
2) two not good liquors are prepared：By the dregs of a decoction and water according to mass ratio 1:12 are added in container, are heated to 95 DEG C, are in pressure
Under the conditions of 1.5MPa, constant temperature 45min is cooled to 30 DEG C, filtering, gained filtrate is two not good liquors；
3) extract solution is prepared：By step 1) gained one not good liquor and step 2) gained two not good liquors merge, temperature be 75 DEG C, pressure
Under the conditions of power is -0.8MPa, 30min is concentrated, during gained concentrate is trifoliate jewelvine, cordate houttuynia, garlic, tangerine peel and Chinese cassia tree extract solution
One kind.
Embodiment 4
It is 25 by the mass ratio of rosin mixture, extracts of Chinese herbal medicine, synergist and vegetable oil:25:10:40 be added to it is homogeneous
In machine, homogeneous 2 times, wherein first time homogeneous pressure is 25MPa, and homogeneous temperature is 65 DEG C, and the homogeneous time is 20min；Second
Homogeneous pressure is 4PMa, and homogeneous temperature is 65 DEG C, and the homogeneous time is 25min, produces rosin mixture biological pesticide.
The rosin mixture is followed the steps below：By rosin, triethanolamine, nitric acid and water according to mass ratio 10:25:
2:100 are added in container, and 50min is heated at a temperature of 90 DEG C, filter off impurity, gained filtrate is rosin mixture；
The extracts of Chinese herbal medicine is trifoliate jewelvine extract solution, Herba Houttuyniae extract, garlic extract, orange peel extraction and Chinese cassia tree
Extract solution is according to mass ratio 50:25:15:8:15 composition；The synergist is AEO-3, AEO-9, span-80, sorbierite
With glycerine according to mass ratio 20:25:8:30:15 composition；The vegetable oil is fruit of cubeb litsea tree oil.
Extract solution extracting method, which is characterized in that, to be followed the steps below：
1) not good liquor is prepared：By one kind and water in trifoliate jewelvine, cordate houttuynia, garlic, tangerine peel and Chinese cassia tree according to mass ratio 1:15
It is added in container, is heated to 65 DEG C, constant temperature 40min is cooled to 30 DEG C, filtering, gained filtrate is a not good liquor；It is residue obtained to be
The dregs of a decoction；
2) two not good liquors are prepared：By the dregs of a decoction and water according to mass ratio 1:12 are added in container, are heated to 95 DEG C, are in pressure
Under the conditions of 1.5MPa, constant temperature 45min is cooled to 30 DEG C, filtering, gained filtrate is two not good liquors；
3) extract solution is prepared：By step 1) gained one not good liquor and step 2) gained two not good liquors merge, temperature be 75 DEG C, pressure
Under the conditions of power is -0.8MPa, 30min is concentrated, during gained concentrate is trifoliate jewelvine, cordate houttuynia, garlic, tangerine peel and Chinese cassia tree extract solution
One kind.
Embodiment 5
It is 30 by the mass ratio of rosin mixture, extracts of Chinese herbal medicine, synergist and vegetable oil:30:10:30 be added to it is homogeneous
In machine, homogeneous 2 times, wherein first time homogeneous pressure is 25MPa, and homogeneous temperature is 65 DEG C, and the homogeneous time is 20min；Second
Homogeneous pressure is 4PMa, and homogeneous temperature is 65 DEG C, and the homogeneous time is 25min, produces rosin mixture biological pesticide.
The rosin mixture is followed the steps below：By rosin, triethanolamine, nitric acid and water according to mass ratio 10:25:
2:100 are added in container, and 50min is heated at a temperature of 90 DEG C, filter off impurity, gained filtrate is rosin mixture；
The extracts of Chinese herbal medicine is trifoliate jewelvine extract solution, Herba Houttuyniae extract, garlic extract, orange peel extraction and Chinese cassia tree
Extract solution is according to mass ratio 50:25:15:8:15 composition；The synergist is AEO-3, AEO-9, span-80, sorbierite
With glycerine according to mass ratio 20:25:8:30:15 composition；The vegetable oil is fruit of cubeb litsea tree oil.
Extract solution extracting method, which is characterized in that, to be followed the steps below：
1) not good liquor is prepared：By one kind and water in trifoliate jewelvine, cordate houttuynia, garlic, tangerine peel and Chinese cassia tree according to mass ratio 1:15
It is added in container, is heated to 65 DEG C, constant temperature 40min is cooled to 30 DEG C, filtering, gained filtrate is a not good liquor；It is residue obtained to be
The dregs of a decoction；
2) two not good liquors are prepared：By the dregs of a decoction and water according to mass ratio 1:12 are added in container, are heated to 95 DEG C, are in pressure
Under the conditions of 1.5MPa, constant temperature 45min is cooled to 30 DEG C, filtering, gained filtrate is two not good liquors；
3) extract solution is prepared：By step 1) gained one not good liquor and step 2) gained two not good liquors merge, temperature be 75 DEG C, pressure
Under the conditions of power is -0.8MPa, 30min is concentrated, during gained concentrate is trifoliate jewelvine, cordate houttuynia, garlic, tangerine peel and Chinese cassia tree extract solution
One kind.
Embodiment 6
It is 20 by the mass ratio of rosin mixture, extracts of Chinese herbal medicine, synergist and vegetable oil:20:10:50 be added to it is homogeneous
In machine, homogeneous 2 times, wherein first time homogeneous pressure is 25MPa, and homogeneous temperature is 65 DEG C, and the homogeneous time is 20min；Second
Homogeneous pressure is 4PMa, and homogeneous temperature is 65 DEG C, and the homogeneous time is 25min, produces rosin mixture biological pesticide.
The rosin mixture is followed the steps below：By rosin, triethanolamine, nitric acid and water according to mass ratio 10:25:
2:100 are added in container, and 50min is heated at a temperature of 90 DEG C, filter off impurity, gained filtrate is rosin mixture；
The extracts of Chinese herbal medicine is trifoliate jewelvine extract solution, Herba Houttuyniae extract, garlic extract, orange peel extraction and Chinese cassia tree
Extract solution is according to mass ratio 50:25:15:8:15 composition；The synergist is AEO-3, AEO-9, span-80, sorbierite
With glycerine according to mass ratio 20:25:8:30:15 composition；The vegetable oil is fruit of cubeb litsea tree oil.
Extract solution extracting method, which is characterized in that, to be followed the steps below：
1) not good liquor is prepared：By one kind and water in trifoliate jewelvine, cordate houttuynia, garlic, tangerine peel and Chinese cassia tree according to mass ratio 1:15
It is added in container, is heated to 65 DEG C, constant temperature 40min is cooled to 30 DEG C, filtering, gained filtrate is a not good liquor；It is residue obtained to be
The dregs of a decoction；
2) two not good liquors are prepared：By the dregs of a decoction and water according to mass ratio 1:12 are added in container, are heated to 95 DEG C, are in pressure
Under the conditions of 1.5MPa, constant temperature 45min is cooled to 30 DEG C, filtering, gained filtrate is two not good liquors；
3) extract solution is prepared：By step 1) gained one not good liquor and step 2) gained two not good liquors merge, temperature be 75 DEG C, pressure
Under the conditions of power is -0.8MPa, 30min is concentrated, during gained concentrate is trifoliate jewelvine, cordate houttuynia, garlic, tangerine peel and Chinese cassia tree extract solution
One kind.
Embodiment 7
It is 30 by the mass ratio of rosin mixture, extracts of Chinese herbal medicine, synergist and vegetable oil:25:15:30 be added to it is homogeneous
In machine, homogeneous 2 times, wherein first time homogeneous pressure is 25MPa, and homogeneous temperature is 65 DEG C, and the homogeneous time is 20min；Second
Homogeneous pressure is 4PMa, and homogeneous temperature is 65 DEG C, and the homogeneous time is 25min, produces rosin mixture biological pesticide.
The rosin mixture is followed the steps below：By rosin, triethanolamine, nitric acid and water according to mass ratio 10:25:
2:100 are added in container, and 50min is heated at a temperature of 90 DEG C, filter off impurity, gained filtrate is rosin mixture；
The extracts of Chinese herbal medicine is trifoliate jewelvine extract solution, Herba Houttuyniae extract, garlic extract, orange peel extraction and Chinese cassia tree
Extract solution is according to mass ratio 50:25:15:8:15 composition；The synergist is AEO-3, AEO-9, span-80, sorbierite
With glycerine according to mass ratio 30:15:7:35:13 composition；The vegetable oil is fruit of cubeb litsea tree oil.
Extract solution extracting method, which is characterized in that, to be followed the steps below：
1) not good liquor is prepared：By one kind and water in trifoliate jewelvine, cordate houttuynia, garlic, tangerine peel and Chinese cassia tree according to mass ratio 1:15
It is added in container, is heated to 55 DEG C, constant temperature 50min is cooled to 32 DEG C, filtering, gained filtrate is a not good liquor；It is residue obtained to be
The dregs of a decoction；
2) two not good liquors are prepared：By the dregs of a decoction and water according to mass ratio 1:12 are added in container, are heated to 95 DEG C, are in pressure
Under the conditions of 1.5MPa, constant temperature 45min is cooled to 35 DEG C, filtering, gained filtrate is two not good liquors；
3) extract solution is prepared：By step 1) gained one not good liquor and step 2) gained two not good liquors merge, temperature be 75 DEG C, pressure
Under the conditions of power is -0.8MPa, 30min is concentrated, during gained concentrate is trifoliate jewelvine, cordate houttuynia, garlic, tangerine peel and Chinese cassia tree extract solution
One kind.
Embodiment 8
It is 20 by the mass ratio of rosin mixture, extracts of Chinese herbal medicine, synergist and vegetable oil:30:15:35 be added to it is homogeneous
In machine, homogeneous 1 time, homogeneous pressure is 25MPa, and homogeneous temperature is 65 DEG C, and the homogeneous time is 30min, produces rosin mixture biological
Agricultural chemicals.
The rosin mixture is followed the steps below：By rosin, triethanolamine, nitric acid and water according to mass ratio 20:40:
3:120 are added in container, and 60min is heated at a temperature of 100 DEG C, filter off impurity, gained filtrate is rosin mixture；
The extracts of Chinese herbal medicine is trifoliate jewelvine extract solution, Herba Houttuyniae extract, garlic extract, orange peel extraction and Chinese cassia tree
Extract solution is according to mass ratio 50:25:15:8:15 composition；The synergist is AEO-3, AEO-9, span-80, sorbierite
With glycerine according to mass ratio 30:15:7:35:13 composition；The vegetable oil is fruit of cubeb litsea tree oil and palm oil according to quality
Than 1:1 composition.
Extract solution extracting method, which is characterized in that, to be followed the steps below：
1) not good liquor is prepared：By one kind and water in trifoliate jewelvine, cordate houttuynia, garlic, tangerine peel and Chinese cassia tree according to mass ratio 1:25
It is added in container, is heated to 65 DEG C, constant temperature 40min is cooled to 30 DEG C, filtering, gained filtrate is a not good liquor；It is residue obtained to be
The dregs of a decoction；
2) two not good liquors are prepared：By the dregs of a decoction and water according to mass ratio 1:15 are added in container, are heated to 85 DEG C, constant temperature
45min, is cooled to 30 DEG C, filtering, gained filtrate is two not good liquors；
3) extracts of Chinese herbal medicine is prepared：By step 1) gained one not good liquor and step 2) gained two not good liquors merge, gained merge
Liquid is one kind in trifoliate jewelvine, cordate houttuynia, garlic, tangerine peel and Chinese cassia tree extract solution.
Beneficial effects of the present invention are further illustrated with reference to experimental data：
Experiment one：
1st, material to be tested is tested
1 materials and methods：
1.1 test site：Yantai Qixia City Su Jiadian towns.
1.2 experimental subjects：6 mu of Fuji apple orchards, the age of tree is all 10 years.
1.3 material to be tested：It is (other to make and embodiment 1 in addition to using traditional rosin mixture for water spray, common process
Unanimously) do effect with embodiment 1 and compare.
1.4 experimental design：Test and set 3 processing, 2 repetitions, one mu is a processing, respectively water spray, common process
(in addition to using traditional rosin mixture, other to make consistent with embodiment 1) and embodiment 1.Handle, sprayed using blade face in five times
Apply, 600 times of dilution per treatment, first was handled once inferior on May 8th, 2016, and on June 10th, 2016 is processed as the second time,
Third time is processed as on July 8th, 2016, is processed as in August, 2016 for the 4th time 7, is processed as in September, 2016 for the 5th time 6.Apple
Fruit plucking time is on October 15th, 2016.Apple development situation and insect pest situation after each processing are observed, each processing yield is counted.
This experiment other management in addition to experiment is different with processing are consistent.
2 results and analysis
Water spray, common process (in addition to using traditional rosin mixture, other to make consistent with embodiment 1) and the phase of embodiment 1
Than data are shown in Table 1.
Table 1 respectively handles the influence to wheat growth situation, insect pest and yield
Table 1
Present invention effect in terms of pre- disease prevention and insect pest is protruded it can be seen from data above, and wherein embodiment 1 is pre-
Best results in terms of disease prevention and insect pest, apple is not under the influence of disease and insect pest is received, and yield can also highest.As can be seen here
The present invention has obvious desinsection and antibacterial effect.
Experiment two：
Each 5g of rosin mixture in the rosin mixture and the present invention of Traditional Method production is weighed respectively, is added separately to two appearances
In device, 1g calcium nitrate, and each addition 100ml water into two containers are then added into two containers respectively, phenomenon is observed.
Substantial amounts of floccule is produced in the container of wherein traditional rosin mixture, bottom is sunken to after 8 minutes；And in the present invention
In the container of rosin mixture, produce floccule substantially less, illustrate that the rosin mixture in the present invention exists compared with the rosin mixture of Traditional Method
Had been improved in terms of compatibility.
Claims (8)
1. a kind of preparation method of rosin mixture biological pesticide, it is characterised in that follow the steps below：
By rosin mixture, extracts of Chinese herbal medicine, synergist and vegetable oil according to mass ratio 20~30:20~30:10~20:30~
50 are added in homogenizer, at least it is homogeneous once, produce rosin mixture biological pesticide；
The extracts of Chinese herbal medicine is that trifoliate jewelvine extract solution, Herba Houttuyniae extract, garlic extract, orange peel extraction and Chinese cassia tree are extracted
Liquid is according to mass ratio 40~60:20~40:10~20:5~10:10~20 composition；Extracting method is extracted for water；
The synergist is AEO-3, AEO-9, span-80, sorbierite and glycerine according to mass ratio 15~30:15~30:5~
10:25~40:10~20 composition；
The vegetable oil is palm oil, coconut oil, chinaberry seeds oil, mandarin orange oil, two of one or any ratio in fruit of cubeb litsea tree oil
More than kind.
2. the preparation method of rosin mixture biological pesticide as claimed in claim 1, it is characterised in that：The rosin mixture according to
Following steps are carried out：By rosin, organic base, catalyst and water according to mass ratio 10~30:20~40:0.5~5:80~120 add
Enter into container, 30~90min is heated at a temperature of 80~100 DEG C, filter off impurity, gained filtrate is rosin mixture；
The organic base is two kinds of the one or any ratio in monoethanolamine, diethanol amine, triethanolamine and caustic alcohol
More than；
The catalyst is the two or more of the one or any ratio in sulfuric acid, hydrochloric acid, nitric acid and lewis acid.
3. the preparation method of rosin mixture biological pesticide as claimed in claim 1, it is characterised in that：Trifoliate jewelvine extract solution, fish raw meat
Careless extract solution, garlic extract, orange peel extraction and Chinese cassia tree extract solution are according to mass ratio 50:25:15:8:15 composition；
Extract solution extracting method, which is characterized in that, to be followed the steps below：
1）Prepare a not good liquor：By Chinese herbal medicine and water according to mass ratio 1:5~40 are added in container, are heated to 50~75 DEG C, perseverance
20~90min of temperature, is cooled to 20~40 DEG C, filtering, gained filtrate is a not good liquor；Residue obtained is the dregs of a decoction；
2）Prepare two not good liquors：By the dregs of a decoction and water according to mass ratio 1:5~40 are added in container, are heated to 70~120 DEG C, in pressure
Power is under the conditions of 0~5MPa, 20~90min of constant temperature is cooled to 20~40 DEG C, filtering, gained filtrate is two not good liquors；
3）Prepare extract solution：By step 1）The not good liquor of gained one and step 2）The not good liquor of gained two merges, and is 20~90 DEG C in temperature, pressure
Power be -5MPa~0MPa under the conditions of, concentrate 0~90min, gained concentrate is extract solution.
4. the preparation method of rosin mixture biological pesticide as claimed in claim 1, it is characterised in that：The synergist is AEO-
3rd, AEO-9, span-80, sorbierite and glycerine are according to mass ratio 20:25:8:30:15 composition.
5. the preparation method of rosin mixture biological pesticide as claimed in claim 1, it is characterised in that：The vegetable oil is that mountain is grey
Seed oil.
6. the preparation method of rosin mixture biological pesticide as claimed in claim 1 or 2, it is characterised in that：The organic base is
Triethanolamine；The catalyst is nitric acid.
7. the preparation method of rosin mixture biological pesticide as claimed in claim 1, it is characterised in that：The rosin mixture, in
The mass ratio of herbal medicine extract solution, synergist and vegetable oil is 20:30:15:35.
8. the preparation method of rosin mixture biological pesticide as claimed in claim 1, it is characterised in that：Homogeneous 2 times, wherein first
Secondary homogeneous pressure is 15~35MPa, and homogeneous temperature is 50~70 DEG C, and the homogeneous time is 10~60min；Second of homogeneous pressure be
2~8PMa, homogeneous temperature is 50~70 DEG C, and the homogeneous time is 10~60min.
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| CN110786340A (en) * | 2019-11-15 | 2020-02-14 | 韩友利生物科技(上海)有限公司 | Method for preparing water-soluble liquid turpentine sulfur and using method thereof |
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