CN107257810B - 可通过与非氟化乳化剂聚合获得的过氧化物可固化的含氟聚合物 - Google Patents

可通过与非氟化乳化剂聚合获得的过氧化物可固化的含氟聚合物 Download PDF

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Publication number
CN107257810B
CN107257810B CN201680011608.1A CN201680011608A CN107257810B CN 107257810 B CN107257810 B CN 107257810B CN 201680011608 A CN201680011608 A CN 201680011608A CN 107257810 B CN107257810 B CN 107257810B
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China
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fluorinated
emulsifiers
curable
ether
fluoropolymer
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Expired - Fee Related
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CN201680011608.1A
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Chinese (zh)
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CN107257810A (zh
Inventor
弗洛里安·D·约胡姆
克劳斯·辛策
凯·赫尔穆特·洛哈斯
哈拉尔德·卡斯帕
蒂尔曼·C·兹普利斯
赫尔穆特·特劳恩斯普格
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3M Innovative Properties Co
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3M Innovative Properties Co
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C08F214/22—Vinylidene fluoride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C08F214/22—Vinylidene fluoride
    • C08F214/222—Vinylidene fluoride with fluorinated vinyl ethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C08F214/26—Tetrafluoroethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C08F214/28—Hexyfluoropropene
    • C08F214/282—Hexyfluoropropene with fluorinated vinyl ethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F216/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • C08F216/12—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
    • C08F216/125—Monomers containing two or more unsaturated aliphatic radicals, e.g. trimethylolpropane triallyl ether or pentaerythritol triallyl ether
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F259/00—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00
    • C08F259/08—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing fluorine

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CN201680011608.1A 2015-02-23 2016-02-22 可通过与非氟化乳化剂聚合获得的过氧化物可固化的含氟聚合物 Expired - Fee Related CN107257810B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP15156170.1 2015-02-23
EP15156170.1A EP3059265B1 (en) 2015-02-23 2015-02-23 Peroxide curable fluoropolymers obtainable by polymerization with non-fluorinated emulsifiers
PCT/US2016/018845 WO2016137851A1 (en) 2015-02-23 2016-02-22 Peroxide curable fluoropolymers obtainable by polymerization with non-fluorinated emulsifiers

Publications (2)

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CN107257810A CN107257810A (zh) 2017-10-17
CN107257810B true CN107257810B (zh) 2019-12-31

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Country Link
US (1) US10875948B2 (https=)
EP (1) EP3059265B1 (https=)
JP (1) JP6951247B2 (https=)
KR (1) KR20170120148A (https=)
CN (1) CN107257810B (https=)
WO (1) WO2016137851A1 (https=)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10590224B2 (en) 2015-07-13 2020-03-17 3M Innovative Properties Company Fluorinated block copolymers
EP3538573A1 (en) * 2016-11-09 2019-09-18 3M Innovative Properties Company Peroxide curable partially fluorinated polymers
WO2018136332A1 (en) 2017-01-18 2018-07-26 3M Innovative Properties Company Fluorinated block copolymers derived from cure-site monomers
JP2020504225A (ja) 2017-01-18 2020-02-06 スリーエム イノベイティブ プロパティズ カンパニー ニトリル硬化部位モノマーから誘導されるフッ素化ブロックコポリマー
JP2020504226A (ja) 2017-01-18 2020-02-06 スリーエム イノベイティブ プロパティズ カンパニー フッ素化ブロックコポリマー
EP3625201B1 (en) * 2017-05-19 2021-09-29 3M Innovative Properties Company Methods of making a polyfluorinated allyl ether and compounds relating to the methods
EP3722340B1 (en) * 2017-12-06 2023-10-11 AGC Inc. Fluorine-containing elastic copolymer and method for producing fluorine-containing elastic copolymer
EP3527634A1 (en) * 2018-02-15 2019-08-21 3M Innovative Properties Company Fluoropolymers and fluoropolymer dispersions
US11898006B2 (en) 2018-04-20 2024-02-13 Solvay Specialty Polymers Italy S.P.A Process for the manufacture of polyether polymers
US11591536B2 (en) 2018-06-20 2023-02-28 Solvay Speciality Polymers Italy S.P.A. (Per)fluoropolyether polymers
WO2020016719A1 (en) 2018-07-20 2020-01-23 3M Innovative Properties Company Tetrafluroethylene fluoropolymers containing perfluorinated allyl ethers
JP7277799B2 (ja) * 2018-10-03 2023-05-19 ダイキン工業株式会社 ポリテトラフルオロエチレンの製造方法
US12473386B2 (en) * 2018-10-18 2025-11-18 Daikin Industries, Ltd. Fluorine-containing elastomer, crosslinkable composition and molded article
US12071494B2 (en) * 2018-12-20 2024-08-27 Solvay Specialty Polymers Italy S.P.A. Vinylidene fluoride polymer dispersion
JP7552585B2 (ja) * 2019-03-27 2024-09-18 Ａｇｃ株式会社 含フッ素重合体の製造方法、水性分散液および含フッ素重合体組成物
EP3950827B1 (en) * 2019-03-29 2023-07-26 Kureha Corporation Vinylidene-fluoride-based polymer composition obtained using non-fluorinated surfactant and production method therefor
WO2021085423A1 (ja) * 2019-10-30 2021-05-06 Ａｇｃ株式会社 含フッ素共重合体、含フッ素共重合体組成物および架橋ゴム物品
CN114651018A (zh) * 2019-11-19 2022-06-21 大金工业株式会社 含氟聚合物的制造方法、聚四氟乙烯的制造方法、全氟弹性体的制造方法和组合物
EP4063403A4 (en) * 2019-11-19 2024-01-24 Daikin Industries, Ltd. PROCESS FOR MANUFACTURING FLUOROPOLYMER
JP7041378B2 (ja) * 2019-12-27 2022-03-24 ダイキン工業株式会社 含フッ素ポリマーの製造方法、含フッ素エラストマーおよび水性分散液
EP4194474A4 (en) * 2020-08-05 2024-08-21 Daikin Industries, Ltd. METHOD FOR PREPARING AN AQUEOUS DISPERSION OF A FLUORINE-CONTAINING ELASTOMER
WO2024115069A1 (en) * 2022-11-30 2024-06-06 Solvay Specialty Polymers Italy S.P.A. Method for manufacturing fluoroelastomers in aqueous emulsion without using fluorinated surfactants
JP7845517B2 (ja) 2023-07-19 2026-04-14 Ａｇｃ株式会社 含フッ素エラストマーの製造方法、水性分散液、固体組成物
JP7792546B1 (ja) * 2025-07-14 2025-12-25 ユニマテック株式会社 フルオロポリマー水性分散液の製造方法、フルオロモノマーの重合方法、フルオロポリマーの製造方法
JP7792545B1 (ja) * 2025-07-14 2025-12-25 ユニマテック株式会社 フルオロポリマー水性分散液の製造方法、フルオロモノマーの重合方法、フルオロポリマーの製造方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103038266A (zh) * 2010-08-02 2013-04-10 3M创新有限公司 包含改性剂和碘或溴端基的可过氧化物固化的含氟弹性体
EP2698390A1 (en) * 2011-04-11 2014-02-19 Unimatec Co., Ltd. Method for producing fluorine-containing elastomer
CN105722874A (zh) * 2013-10-30 2016-06-29 3M创新有限公司 可使用非氟化多羟基乳化剂通过聚合而获得的可用过氧化物固化的含氟聚合物

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU660948B2 (en) 1990-09-28 1995-07-13 Procter & Gamble Company, The Phase transfer assisted process for glucamide detergents
JP3390991B2 (ja) 1996-10-11 2003-03-31 日本カーバイド工業株式会社 乳化重合法により得られる重合体
TW494125B (en) 1997-07-11 2002-07-11 Rohm And Haas Compary Preparation of fluorinated polymers
DE19857111A1 (de) 1998-12-11 2000-06-15 Dyneon Gmbh Wäßrige Dispersionen von Fluorpolymeren
US6512063B2 (en) 2000-10-04 2003-01-28 Dupont Dow Elastomers L.L.C. Process for producing fluoroelastomers
US6841616B2 (en) 2003-03-28 2005-01-11 Arkema Inc. Polymerization of halogen-containing monomers using siloxane surfactant
US8080621B2 (en) 2005-06-10 2011-12-20 Arkema Inc. Aqueous process for making fluoropolymers
US20060281845A1 (en) 2005-06-10 2006-12-14 Ramin Amin-Sanayei Aqueous process for making fluoropolymers
US8338518B2 (en) 2005-06-10 2012-12-25 Arkema Inc. Aqueous process for making a stable fluoropolymer dispersion
US7671112B2 (en) 2005-07-15 2010-03-02 3M Innovative Properties Company Method of making fluoropolymer dispersion
CN101243108B (zh) 2005-08-08 2012-08-22 阿科玛股份有限公司 使用非氟化的表面活性剂聚合含氟聚合物
US8124699B2 (en) 2005-08-08 2012-02-28 Arkema Inc. Polymerization of fluoropolymers using alkyl phosphonate surfactants
US9029477B2 (en) * 2006-03-03 2015-05-12 3M Innovative Properties Company Compositions comprising melt-processable thermoplastic fluoropolymers and methods of making the same
US7678859B2 (en) 2006-09-14 2010-03-16 3M Innovative Properties Company Preparation and stabilization of fluoropolymer dispersions
US7521513B2 (en) 2006-11-29 2009-04-21 Dupont Performance Elastomers Llc Semi-batch process for producing fluoroelastomers
US20080146757A1 (en) 2006-12-19 2008-06-19 Lyons Donald F Process for producing fluoroelastomers
JP2008297528A (ja) 2007-06-04 2008-12-11 Daikin Ind Ltd ビニリデンフルオライド系重合体の製造方法
WO2009126504A2 (en) 2008-04-07 2009-10-15 Arkema Inc. Polymerization of fluoropolymers using polycaprolactone
DE102009030846A1 (de) 2009-06-26 2010-12-30 Merck Patent Gmbh Fluortenside
EP2284200A1 (en) * 2009-07-31 2011-02-16 3M Innovative Properties Company Aqueous fluoropolymer dispersions containing a polyol comprising at least one long chain residue and method for producing them
RU2522749C2 (ru) 2009-07-31 2014-07-20 Зм Инновейтив Пропертиз Компани Соединения фторполимера, содержащие многоатомные соединения, и способы из производства
EP2627683B1 (en) 2010-10-15 2014-08-13 Solvay Specialty Polymers Italy S.p.A. Fluoroelastomers
EP3138875B1 (en) 2011-08-04 2019-11-20 3M Innovative Properties Company Crosslinked fluorinated polymers with manganese or cerium as additives
GB2517481A (en) 2013-08-22 2015-02-25 3M Innovative Properties Co Method of making peroxide fluoropolymers using non-fluorindated emulsifiers

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103038266A (zh) * 2010-08-02 2013-04-10 3M创新有限公司 包含改性剂和碘或溴端基的可过氧化物固化的含氟弹性体
EP2698390A1 (en) * 2011-04-11 2014-02-19 Unimatec Co., Ltd. Method for producing fluorine-containing elastomer
CN105722874A (zh) * 2013-10-30 2016-06-29 3M创新有限公司 可使用非氟化多羟基乳化剂通过聚合而获得的可用过氧化物固化的含氟聚合物

Also Published As

Publication number Publication date
JP6951247B2 (ja) 2021-10-20
JP2018505952A (ja) 2018-03-01
KR20170120148A (ko) 2017-10-30
CN107257810A (zh) 2017-10-17
EP3059265B1 (en) 2020-10-07
US10875948B2 (en) 2020-12-29
EP3059265A1 (en) 2016-08-24
WO2016137851A1 (en) 2016-09-01
US20180030182A1 (en) 2018-02-01

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