CN107237129A - 一种抗褶皱防油防水印花面料 - Google Patents

一种抗褶皱防油防水印花面料 Download PDF

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CN107237129A
CN107237129A CN201710614007.6A CN201710614007A CN107237129A CN 107237129 A CN107237129 A CN 107237129A CN 201710614007 A CN201710614007 A CN 201710614007A CN 107237129 A CN107237129 A CN 107237129A
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agent
fiber
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printed fabric
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潘学东
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Anhui Yayuan Printing And Dyeing Co Ltd
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Abstract

本发明公开了一种抗褶皱防油防水印花面料，其原料包括聚酯纤维、卡其纤维、聚氨酯弹性纤维、纤维素酯纤维、马海毛纱、壳聚糖、甲壳素纤维、绢丝、双宫线、聚乙二醇、甲基丙烯酸、醋酸乙酯、海藻纤维、玉石纤维、椰炭纤维、改性防水剂、防水增强剂和防油剂。本发明的印花面料具有优异抗褶皱、防水和防油性能。

Description

一种抗褶皱防油防水印花面料
技术领域
本发明涉及面料的技术领域，尤其涉及一种抗褶皱防油防水印花面料。
背景技术
随着科学技术的不断发展，满足人们不同需要的纺织品面料层出不穷，以满足消费者的需求，在人们的日常生活中起着越来越重要的作用。随着人们日益增长的生活水平，人们的穿着需求也越来越高，穿着的面料需要满足多种使用需要，从而使得人们能够穿着舒适。服装面料在经过人们的穿着后通常都会发生各种变化，如起球、变皱、破洞等情况，起球面料在穿着时影响相对较小，不会造成太大的负面效果，破洞面料则已经不再使用，对人们来说是不觉得可惜的。而变皱面料是人们遇到的相对尴尬的一种形式，穿出去对自己会造成负面影响，而不穿放在家里则显得比较浪费，且面料的防水防油性能也是其重要的性能之一，多功能的面料是未来面料发展的趋势。
发明内容
为解决背景技术中存在的技术问题，本发明提出一种抗褶皱防油防水印花面料，具有优异抗褶皱、防水和防油性能。
本发明提出的一种抗褶皱防油防水印花面料，其原料按重量份包括：聚酯纤维20-40份、卡其纤维5-15份、聚氨酯弹性纤维4-6份、纤维素酯纤维3-5份、马海毛纱2-6份、壳聚糖1-4份、甲壳素纤维3-5份、绢丝4-5份、双宫线3-6份、聚乙二醇2-5份、甲基丙烯酸4-6份、醋酸乙酯3-5份、海藻纤维4-6份、玉石纤维2-5份、椰炭纤维3-5份、改性防水剂2-6份、防水增强剂1-5份、防油剂3-6份。
优选地，改性防水剂按如下工艺进行制备：将羟甲基纤维素和二甲基甲酰胺混合均匀，然后加入氢氧化钠调节pH至9-10，然后升温至60-80℃，保温1-2h，然后加入环氧氯丙烷混合均匀，于650-850r/min转速搅拌20-40min，抽滤，洗涤，于80-90℃干燥至恒重，冷却至室温得到改性防水剂。
优选地，改性防水剂的制备工艺中，羟甲基纤维素、二甲基甲酰胺和环氧氯丙烷的重量比为1-3：2-5：3-6。
优选地，防水增强剂按如下工艺进行制备：将含氢硅油、十六稀和乙烯基三乙氧基硅烷混合均匀，升温至80-90℃，于650-850r/min转速搅拌20-40min，接着加入氯铂酸混合均匀，升温至90-100℃，保温1-3h，接着于450-550r/min转速搅拌1-3h，冷却至室温得到防水增强剂。
优选地，防水增强剂的制备工艺中，含氢硅油、十六稀、乙烯基三乙氧基硅烷和氯铂酸的重量比为1-3：2-5：3-6。
优选地，防油剂的原料按重量份包括：纳米掺锑二氧化锡粉体4-12份、氧化锌2-5份、纳米二氧化钛4-6份、硅烷偶联剂KH-570 2-8份、苯乙烯3-6份、丙烯酸丁酯1.5-4份。
优选地，防油剂按如下工艺进行制备：将苯乙烯、丙烯酸丁酯、纳米掺锑二氧化锡粉体、氧化锌和纳米二氧化钛混合均匀，然后加入硅烷偶联剂KH-570，于38-46℃搅拌20-28h，冷却至室温得到物料a；然后将物料a置于冰水浴中破碎，超声处理10-14min得到防油剂。
本发明的一种抗褶皱防油防水印花面料，其原料包括聚酯纤维、卡其纤维、聚氨酯弹性纤维、纤维素酯纤维、马海毛纱、壳聚糖、甲壳素纤维、绢丝、双宫线、聚乙二醇、甲基丙烯酸、醋酸乙酯、海藻纤维、玉石纤维、椰炭纤维、改性防水剂、防水增强剂和防油剂。本发明的印花面料具有优异抗褶皱、防水和防油性能。其中，改性防水剂通过将羟甲基纤维素和二甲基甲酰胺混合均匀，然后加入氢氧化钠调节pH，然后升温，保温，然后加入环氧氯丙烷混合均匀，搅拌，抽滤，洗涤，干燥至恒重，冷却至室温得到改性防水剂，通过环氧氯丙烷对羟甲基纤维素进行改性，增加了分子间的交联，使其变成水不溶的物质，用做填充剂，改性后的羟甲基纤维素运用到本发明的印花面料中，使得本发明的印花面料具有优异的防水、透湿和透气性能。其中，防水增强剂通过将含氢硅油、十六稀和乙烯基三乙氧基硅烷混合均匀，升温，搅拌，接着加入氯铂酸混合均匀，升温，保温，接着搅拌，冷却至室温得到防水增强剂，通过乙烯基三乙氧基硅烷对含氢硅油进行改性，以氯铂酸和十六烯作为促进剂，得到的防水增强剂与改性防水剂配合，运用到本发明的印花面料中，能够进一步有效提高了印花面料的防水性能。其中，防油剂通过将苯乙烯、丙烯酸丁酯、纳米掺锑二氧化锡粉体、氧化锌和纳米二氧化钛混合均匀，然后加入硅烷偶联剂KH-570，搅拌，冷却至室温得到物料a；然后将物料a置于冰水浴中破碎，超声处理得到防油剂，通过硅烷偶联剂KH-570对纳米掺锑二氧化锡粉体、氧化锌和纳米二氧化钛进行接枝改性，以苯乙烯为交联剂，丙烯酸丁酯为接枝基体，得到的防油剂具有优异的防油性能。
具体实施方式
下面结合具体实施例对本发明做出详细说明，应当了解，实施例只用于说明本发明，而不是用于对本发明进行限定，任何在本发明基础上所做的修改、等同替换等均在本发明的保护范围内。
具体实施方式中，聚酯纤维的重量份可以为20份、25份、30份、35份、40份；卡其纤维的重量份可以为5份、6份、7份、8份、9份、10份、11份、12份、13份、14份、15份；聚氨酯弹性纤维的重量份可以为4份、4.5份、5份、5.5份、6份；纤维素酯纤维的重量份可以为3份、3.5份、4份、4.5份、5份；马海毛纱的重量份可以为2份、3份、4份、5份、6份；壳聚糖的重量份可以为1份、1.5份、2份、2.5份、3份、3.5份、4份；甲壳素纤维的重量份可以为3份、3.5份、4份、4.5份、5份；绢丝的重量份可以为4份、4.1份、4.2份、4.3份、4.4份、4.5份、4.6份、4.7份、4.8份、4.9份、5份；双宫线的重量份可以为3份、3.5份、4份、4.5份、5份、5.5份、6份；聚乙二醇的重量份可以为2份、2.5份、3份、3.5份、4份、4.5份、5份；甲基丙烯酸的重量份可以为4份、4.5份、5份、5.5份、6份；醋酸乙酯的重量份可以为3份、3.5份、4份、4.5份、5份；海藻纤维的重量份可以为4份、4.5份、5份、5.5份、6份；玉石纤维的重量份可以为2份、2.5份、3份、3.5份、4份、4.5份、5份；椰炭纤维的重量份可以为3份、3.5份、4份、4.5份、5份；改性防水剂的重量份可以为2份、3份、4份、5份、6份；防水增强剂的重量份可以为1份、2份、3份、4份、5份；防油剂的重量份可以为3份、3.5份、4份、4.5份、5份、5.5份、6份。
实施例1
本发明提出的一种抗褶皱防油防水印花面料，其原料按重量份包括：聚酯纤维30份、卡其纤维10份、聚氨酯弹性纤维5份、纤维素酯纤维4份、马海毛纱4份、壳聚糖2.5份、甲壳素纤维4份、绢丝4.5份、双宫线4.5份、聚乙二醇3.5份、甲基丙烯酸5份、醋酸乙酯4份、海藻纤维5份、玉石纤维3.5份、椰炭纤维4份、改性防水剂4份、防水增强剂3份、防油剂4.5份。
改性防水剂按如下工艺进行制备：按重量份将2份羟甲基纤维素和3.5份二甲基甲酰胺混合均匀，然后加入氢氧化钠调节pH至9.5，然后升温至70℃，保温1.5h，然后加入4.5份环氧氯丙烷混合均匀，于750r/min转速搅拌30min，抽滤，洗涤，于85℃干燥至恒重，冷却至室温得到改性防水剂。
防水增强剂按如下工艺进行制备：按重量份将2份含氢硅油、3.5份十六稀和4.5份乙烯基三乙氧基硅烷混合均匀，升温至85℃，于750r/min转速搅拌30min，接着加入氯铂酸混合均匀，升温至95℃，保温2h，接着于500r/min转速搅拌2h，冷却至室温得到防水增强剂。
防油剂按如下工艺进行制备：按重量份将4.5份苯乙烯、2.75份丙烯酸丁酯、8份纳米掺锑二氧化锡粉体、3.5份氧化锌和5份纳米二氧化钛混合均匀，然后加入5份硅烷偶联剂KH-570，于42℃搅拌24h，冷却至室温得到物料a；然后将物料a置于冰水浴中破碎，超声处理12min得到防油剂。
实施例2
本发明提出的一种抗褶皱防油防水印花面料，其原料按重量份包括：聚酯纤维20份、卡其纤维15份、聚氨酯弹性纤维4份、纤维素酯纤维5份、马海毛纱2份、壳聚糖4份、甲壳素纤维3份、绢丝5份、双宫线3份、聚乙二醇5份、甲基丙烯酸4份、醋酸乙酯5份、海藻纤维4份、玉石纤维5份、椰炭纤维3份、改性防水剂6份、防水增强剂1份、防油剂6份。
改性防水剂按如下工艺进行制备：按重量份将1份羟甲基纤维素和5份二甲基甲酰胺混合均匀，然后加入氢氧化钠调节pH至9，然后升温至80℃，保温1h，然后加入6份环氧氯丙烷混合均匀，于650r/min转速搅拌40min，抽滤，洗涤，于80℃干燥至恒重，冷却至室温得到改性防水剂。
防水增强剂按如下工艺进行制备：按重量份将1份含氢硅油、5份十六稀和3份乙烯基三乙氧基硅烷混合均匀，升温至90℃，于650r/min转速搅拌40min，接着加入氯铂酸混合均匀，升温至90℃，保温3h，接着于450r/min转速搅拌3h，冷却至室温得到防水增强剂。
防油剂按如下工艺进行制备：按重量份将3份苯乙烯、4份丙烯酸丁酯、4份纳米掺锑二氧化锡粉体、5份氧化锌和4份纳米二氧化钛混合均匀，然后加入8份硅烷偶联剂KH-570，于38℃搅拌28h，冷却至室温得到物料a；然后将物料a置于冰水浴中破碎，超声处理10min得到防油剂。
实施例3
本发明提出的一种抗褶皱防油防水印花面料，其原料按重量份包括：聚酯纤维40份、卡其纤维5份、聚氨酯弹性纤维6份、纤维素酯纤维3份、马海毛纱6份、壳聚糖1份、甲壳素纤维5份、绢丝4份、双宫线6份、聚乙二醇2份、甲基丙烯酸6份、醋酸乙酯3份、海藻纤维6份、玉石纤维2份、椰炭纤维5份、改性防水剂2份、防水增强剂5份、防油剂3份。
改性防水剂按如下工艺进行制备：按重量份将3份羟甲基纤维素和2份二甲基甲酰胺混合均匀，然后加入氢氧化钠调节pH至10，然后升温至60℃，保温2h，然后加入3份环氧氯丙烷混合均匀，于850r/min转速搅拌20min，抽滤，洗涤，于90℃干燥至恒重，冷却至室温得到改性防水剂。
防水增强剂按如下工艺进行制备：按重量份将3份含氢硅油、2份十六稀和6份乙烯基三乙氧基硅烷混合均匀，升温至80℃，于850r/min转速搅拌20min，接着加入氯铂酸混合均匀，升温至100℃，保温1h，接着于550r/min转速搅拌1h，冷却至室温得到防水增强剂。
防油剂按如下工艺进行制备：按重量份将6份苯乙烯、1.5份丙烯酸丁酯、12份纳米掺锑二氧化锡粉体、2份氧化锌和6份纳米二氧化钛混合均匀，然后加入2份硅烷偶联剂KH-570，于46℃搅拌20h，冷却至室温得到物料a；然后将物料a置于冰水浴中破碎，超声处理14min得到防油剂。
实施例4
本发明提出的一种抗褶皱防油防水印花面料，其原料按重量份包括：聚酯纤维25份、卡其纤维12份、聚氨酯弹性纤维4.5份、纤维素酯纤维4.5份、马海毛纱3份、壳聚糖3份、甲壳素纤维3.5份、绢丝4.8份、双宫线4份、聚乙二醇4份、甲基丙烯酸4.5份、醋酸乙酯4.5份、海藻纤维4.5份、玉石纤维4份、椰炭纤维3.5份、改性防水剂5份、防水增强剂2份、防油剂5份。
改性防水剂按如下工艺进行制备：按重量份将1.5份羟甲基纤维素和4份二甲基甲酰胺混合均匀，然后加入氢氧化钠调节pH至9.2，然后升温至75℃，保温1.2h，然后加入5份环氧氯丙烷混合均匀，于680r/min转速搅拌35min，抽滤，洗涤，于82℃干燥至恒重，冷却至室温得到改性防水剂。
防水增强剂按如下工艺进行制备：按重量份将1.5份含氢硅油、4份十六稀和4份乙烯基三乙氧基硅烷混合均匀，升温至88℃，于680r/min转速搅拌35min，接着加入氯铂酸混合均匀，升温至92℃，保温2.5h，接着于480r/min转速搅拌2.5h，冷却至室温得到防水增强剂。
防油剂按如下工艺进行制备：按重量份将4份苯乙烯、3.5份丙烯酸丁酯、5份纳米掺锑二氧化锡粉体、4份氧化锌和4.5份纳米二氧化钛混合均匀，然后加入7份硅烷偶联剂KH-570，于39℃搅拌26h，冷却至室温得到物料a；然后将物料a置于冰水浴中破碎，超声处理11min得到防油剂。
实施例5
本发明提出的一种抗褶皱防油防水印花面料，其原料按重量份包括：聚酯纤维35份、卡其纤维8份、聚氨酯弹性纤维5.5份、纤维素酯纤维3.5份、马海毛纱5份、壳聚糖2份、甲壳素纤维4.5份、绢丝4.2份、双宫线5份、聚乙二醇3份、甲基丙烯酸5.5份、醋酸乙酯3.5份、海藻纤维5.5份、玉石纤维3份、椰炭纤维4.5份、改性防水剂3份、防水增强剂4份、防油剂4份。
改性防水剂按如下工艺进行制备：按重量份将2.5份羟甲基纤维素和3份二甲基甲酰胺混合均匀，然后加入氢氧化钠调节pH至9.8，然后升温至65℃，保温1.8h，然后加入4份环氧氯丙烷混合均匀，于820r/min转速搅拌25min，抽滤，洗涤，于88℃干燥至恒重，冷却至室温得到改性防水剂。
防水增强剂按如下工艺进行制备：按重量份将2.5份含氢硅油、3份十六稀和5份乙烯基三乙氧基硅烷混合均匀，升温至82℃，于820r/min转速搅拌25min，接着加入氯铂酸混合均匀，升温至98℃，保温1.5h，接着于520r/min转速搅拌1.5h，冷却至室温得到防水增强剂。
防油剂按如下工艺进行制备：按重量份将5份苯乙烯、2.0份丙烯酸丁酯、11份纳米掺锑二氧化锡粉体、3份氧化锌和5.5份纳米二氧化钛混合均匀，然后加入3份硅烷偶联剂KH-570，于45℃搅拌22h，冷却至室温得到物料a；然后将物料a置于冰水浴中破碎，超声处理13min得到防油剂。
以上所述，仅为本发明较佳的具体实施方式，但本发明的保护范围并不局限于此，任何熟悉本技术领域的技术人员在本发明揭露的技术范围内，根据本发明的技术方案及其发明构思加以等同替换或改变，都应涵盖在本发明的保护范围之内。

Claims (7)

1.一种抗褶皱防油防水印花面料，其特征在于，其原料按重量份包括：聚酯纤维20-40份、卡其纤维5-15份、聚氨酯弹性纤维4-6份、纤维素酯纤维3-5份、马海毛纱2-6份、壳聚糖1-4份、甲壳素纤维3-5份、绢丝4-5份、双宫线3-6份、聚乙二醇2-5份、甲基丙烯酸4-6份、醋酸乙酯3-5份、海藻纤维4-6份、玉石纤维2-5份、椰炭纤维3-5份、改性防水剂2-6份、防水增强剂1-5份、防油剂3-6份。
2.根据权利要求1所述的抗褶皱防油印花面料，其特征在于，改性防水剂按如下工艺进行制备：将羟甲基纤维素和二甲基甲酰胺混合均匀，然后加入氢氧化钠调节pH至9-10，然后升温至60-80℃，保温1-2h，然后加入环氧氯丙烷混合均匀，于650-850r/min转速搅拌20-40min，抽滤，洗涤，于80-90℃干燥至恒重，冷却至室温得到改性防水剂。
3.根据权利要求1或2所述的抗褶皱防油印花面料，其特征在于，改性防水剂的制备工艺中，羟甲基纤维素、二甲基甲酰胺和环氧氯丙烷的重量比为1-3：2-5：3-6。
4.根据权利要求1-3任一项所述的抗褶皱防油印花面料，其特征在于，防水增强剂按如下工艺进行制备：将含氢硅油、十六稀和乙烯基三乙氧基硅烷混合均匀，升温至80-90℃，于650-850r/min转速搅拌20-40min，接着加入氯铂酸混合均匀，升温至90-100℃，保温1-3h，接着于450-550r/min转速搅拌1-3h，冷却至室温得到防水增强剂。
5.根据权利要求1-4任一项所述的抗褶皱防油印花面料，其特征在于，防水增强剂的制备工艺中，含氢硅油、十六稀、乙烯基三乙氧基硅烷和氯铂酸的重量比为1-3：2-5：3-6。
6.根据权利要求1-5任一项所述的抗褶皱防油印花面料，其特征在于，防油剂的原料按重量份包括：纳米掺锑二氧化锡粉体4-12份、氧化锌2-5份、纳米二氧化钛4-6份、硅烷偶联剂KH-570 2-8份、苯乙烯3-6份、丙烯酸丁酯1.5-4份。
7.根据权利要求1-6任一项所述的抗褶皱防油印花面料，其特征在于，防油剂按如下工艺进行制备：将苯乙烯、丙烯酸丁酯、纳米掺锑二氧化锡粉体、氧化锌和纳米二氧化钛混合均匀，然后加入硅烷偶联剂KH-570，于38-46℃搅拌20-28h，冷却至室温得到物料a；然后将物料a置于冰水浴中破碎，超声处理10-14min得到防油剂。
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Application publication date: 20171010