CN106867327A - 一种耐污耐油墙纸及其制备方法 - Google Patents

一种耐污耐油墙纸及其制备方法 Download PDF

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Publication number
CN106867327A
CN106867327A CN201611200014.3A CN201611200014A CN106867327A CN 106867327 A CN106867327 A CN 106867327A CN 201611200014 A CN201611200014 A CN 201611200014A CN 106867327 A CN106867327 A CN 106867327A
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China
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parts
resistance
resistant
layer
oil
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CN201611200014.3A
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陈少明
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Anhui Easy Wallpaper Co Ltd
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Anhui Easy Wallpaper Co Ltd
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Priority to CN201611200014.3A priority Critical patent/CN106867327A/zh
Publication of CN106867327A publication Critical patent/CN106867327A/zh
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    • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
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    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
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    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
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    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1687—Use of special additives
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Abstract

本发明公开了一种耐污耐油墙纸，包括基材层、耐污层和耐油层，基材层的外周涂覆有耐污层，耐污层远离基材层的外周涂覆有耐油层，其中：耐油层的原料包括丙烯酸全氟烷基酯、醇酸树脂、聚酯树脂、全氟烷基丙烯酸酯、丙烯酸丁酯、丙烯酸羟乙酯、三聚磷酸铝、纳米硼酸锌、过硫酸钾、羟甲基纤维素、纳米氧化锌、纳米二氧化钛、硅藻土、氢氧化镁、氧化铝、有机膨润土、绢云母粉、氟化碳、磷酸铁、钼酸钠、过硫酸钠、氯化石蜡、硅烷偶联剂KH‑560、二月桂酸二丁基锡、十八烷基三甲基氯化铵、聚乙二醇、氟硅油、增稠剂、消泡剂、固化剂和改性助剂。本发明还提出一种耐污耐油墙纸的制备方法。制备的墙纸具有优异的耐污耐油性能。

Description

一种耐污耐油墙纸及其制备方法
技术领域
本发明涉及墙纸领域，尤其涉及一种耐污耐油墙纸及其制备方法。
背景技术
墙纸通常用漂白化学木浆生产原纸，再经不同工序的加工处理，如涂布、印刷、压纹或表面覆塑，最后经裁切、包装后出厂。因为具有一定的强度、美观的外表和良好的抗水性能，广泛用于住宅、办公室、宾馆、酒店的室内装修等。现有技术中墙纸的耐污耐油性能差，无法满足实际使用时的需求，因此亟需设计一种耐污耐油墙纸来解决现有技术中的问题。
发明内容
为解决背景技术中存在的技术问题，本发明提出一种耐污耐油墙纸及其制备方法，制备得到的墙纸具有优异的耐污耐油性能。
本发明提出的一种耐污耐油墙纸，包括基材层、耐污层和耐油层，基材层的外周涂覆有耐污层，所述耐污层远离基材层的外周涂覆有耐油层，其中：
基材层为木浆纸、无纺纸、布中的任意一种；
耐污层的原料按重量份包括：氟碳树脂40-50份、醇酸树脂25-45份、氨基树脂6-12份、脂肪酸聚酰胺蜡1-5份、水性聚丙烯酸酯乳液5-15份、有机硅树脂1-5份、EVA蜡4-6份、环氧树脂E-123-6份、铝粉2-5份、有机膨润土1-6份、疏水性气相二氧化硅1-4份、蒙脱土2-4份、耐污增强剂8-16份、改性填料2-5份、乙二醇丁醚1-3份、六甲氧基甲基三聚氰胺2-6份、二甲基乙醇胺1-4份、异丙醇2-4份、六偏磷酸钠3-5份、醋酸丁酯1-4份、硅烷偶联剂KH-5602-5份、分散剂3-6份、流平剂BYK-331 2-4份、润湿剂1-4份、消泡剂3-6份、二甲苯1-4份、去离子水12-18份；
耐油层的原料按重量份包括：丙烯酸全氟烷基酯40-60份、醇酸树脂15-25份、聚酯树脂5-15份、全氟烷基丙烯酸酯4-8份、丙烯酸丁酯5-15份、丙烯酸羟乙酯2-8份、三聚磷酸铝1-5份、纳米硼酸锌2-5份、过硫酸钾1-4份、羟甲基纤维素2-6份、纳米氧化锌1-3份、纳米二氧化钛2-5份、硅藻土3-4份、氢氧化镁2-5份、氧化铝4-6份、有机膨润土2-5份、绢云母粉2-5份、氟化碳4-6份、磷酸铁3-6份、钼酸钠2-5份、过硫酸钠3-6份、氯化石蜡2-8份、硅烷偶联剂KH-560 1-4份、二月桂酸二丁基锡2-5份、十八烷基三甲基氯化铵2-5份、聚乙二醇4-8份、氟硅油1-4份、增稠剂3-8份、消泡剂2-5份、固化剂1-5份、改性助剂4-8份。
优选地，耐污层的原料中，耐污增强剂的原料按重量份包括：纳米掺锑二氧化锡粉体4-12份、硅烷偶联剂KH-570 2-8份、苯乙烯3-6份、丙烯酸丁酯1.5-4份。
优选地，耐污层的原料中，耐污增强剂按如下工艺进行制备：将苯乙烯、丙烯酸丁酯和纳米掺锑二氧化锡粉体混合均匀，然后加入硅烷偶联剂KH-570，于38-46℃搅拌20-28h，冷却至室温得到物料a；然后将物料a置于冰水浴中破碎，超声处理10-14min得到耐污增强剂。
优选地，耐污层的原料中，改性填料的原料按重量份包括：纳米二氧化钛2-8份、温石棉3-6份、陶瓷粉1-8份、纳米碳化硅1-4份、石蜡2-6份、玉石粉2-5份、硝化棉液3-5份、辛基异噻唑啉酮3-6份、硅烷偶联剂KH-570 4-8份、聚乙烯醇4-8份。
优选地，耐污层的原料中，改性填料按如下工艺进行制备：将辛基异噻唑啉酮与水混合，然后加入纳米二氧化钛、温石棉和陶瓷粉，于180-260℃保温搅拌1-3h，降温至120-140℃，然后加入纳米碳化硅、石蜡、玉石粉和硝化棉液搅拌均匀，然后加入硅烷偶联剂KH-570和聚乙烯醇，于80-100℃搅拌1.5-3.5h，烘干，研磨，过60-80目筛，得到改性填料。
优选地，耐油层的原料中，改性助剂的原料按重量份包括：浓硫酸80-120份、水40-60份、膨润土1-5份、重晶石粉2-4份、硝化棉1-4份、氧化锌1-3份、云母粉1-5份、沸石粉2-6份、乙醇水溶液8-16份、硅烷偶联剂KH-570 5-15份、甲基丙烯酸甲酯1-5份
优选地，耐油层的原料中，改性助剂按如下工艺进行制备：将浓硫酸分散于水中，搅拌均匀得酸性复合插层水溶液；将膨润土、重晶石粉、硝化棉、氧化锌、云母粉和沸石粉加入到酸性复合插层水溶液中，80-90℃高速搅拌2-4h，趁热过滤，用蒸馏水洗涤至中性，抽滤，烘干，研磨，过150-250目筛得到物料A；然后将物料A分散在乙醇水溶液中，在45-55℃水浴中超声-机械搅拌分散2-4h得到物料B，然后向物料B中添加硅烷偶联剂KH-570和甲基丙烯酸甲酯，升温至75-85℃，保温5-7h，保温的过程中通氮气，最后将反应产物倒出，加入蒸馏水，搅拌均匀，静置分层，去除上层清液，将下层反应产物进行抽滤，洗涤，750-850℃真空干燥至恒重，研磨，过150-250目筛，即得到改性助剂。
本发明的一种耐污耐油墙纸的制备方法，包括如下步骤：
S1、在基材层表面通过印刷工艺在基材层上形成具有图案的印刷层，制得墙纸半成品；
S2、在墙纸半成品的正面将耐污层的原料组合物采用圆网套印工艺印制耐污层，一次干燥后，将耐油层的原料组合物采用圆网套印工艺印制在耐污层层上，形成耐油层，印刷完成后，进行二次干燥，冷却至室温得到耐污耐油墙纸。
优选地，S2中，圆网套印工艺参数均为：印刷速度为5-15m/min；烘箱温度为先用100-120℃烘干，再用160-180℃成膜形成附着效果；圆网上形成有六角网孔，六角网孔的开孔率为30-45％；成品圆网的网厚度为0.1-0.3mm。
优选地，S2中，一次干燥的温度为70-90℃，一次干燥的时间为4-6h；二次干燥的温度为55-65℃，二次干燥的时间为1-3h。
本发明的一种耐污耐油墙纸，包括基材层、耐污层和耐油层，基材层的外周涂覆有耐污层，所述耐污层远离基材层的外周涂覆有耐油层，其中：基材层为木浆纸、无纺纸、布中的任意一种；耐污层的原料包括氟碳树脂、醇酸树脂、氨基树脂、脂肪酸聚酰胺蜡、水性聚丙烯酸酯乳液、有机硅树脂、EVA蜡、环氧树脂E-12、铝粉、有机膨润土、疏水性气相二氧化硅、蒙脱土、耐污增强剂、改性填料、乙二醇丁醚、六甲氧基甲基三聚氰胺、二甲基乙醇胺、异丙醇、六偏磷酸钠、醋酸丁酯、硅烷偶联剂KH-560、分散剂、流平剂BYK-331、润湿剂、消泡剂、二甲苯和去离子水；以氟碳树脂、醇酸树脂、氨基树脂、脂肪酸聚酰胺蜡、水性聚丙烯酸酯乳液、有机硅树脂、EVA蜡和环氧树脂E-12为基料，以铝粉、有机膨润土、疏水性气相二氧化硅、蒙脱土、耐污增强剂和改性填料为填料，以乙二醇丁醚、六甲氧基甲基三聚氰胺、二甲基乙醇胺、异丙醇、六偏磷酸钠、醋酸丁酯、硅烷偶联剂KH-560、分散剂、流平剂BYK-331、润湿剂、消泡剂、二甲苯和去离子水为助剂，通过基料、填料和助剂配合，合理控制配比，得到的耐污层具有优异的耐污性能，耐污层的原料中，耐污增强剂通过将苯乙烯、丙烯酸丁酯和纳米掺锑二氧化锡粉体混合均匀，然后加入硅烷偶联剂KH-570，搅拌，冷却至室温得到物料a；然后将物料a置于冰水浴中破碎，超声处理得到耐污增强剂，进一步加强了耐污性能。耐污层的原料中，改性填料通过将辛基异噻唑啉酮与水混合，然后加入纳米二氧化钛、温石棉和陶瓷粉，保温搅拌，降温后加入纳米碳化硅、石蜡、玉石粉和硝化棉液搅拌均匀，然后加入硅烷偶联剂KH-570和聚乙烯醇，搅拌，烘干，研磨，过筛，得到改性填料，进一步加强了耐污层的耐污性能。耐油层的原料包括丙烯酸全氟烷基酯、醇酸树脂、聚酯树脂、全氟烷基丙烯酸酯、丙烯酸丁酯、丙烯酸羟乙酯、三聚磷酸铝、纳米硼酸锌、过硫酸钾、羟甲基纤维素、纳米氧化锌、纳米二氧化钛、硅藻土、氢氧化镁、氧化铝、有机膨润土、绢云母粉、氟化碳、磷酸铁、钼酸钠、过硫酸钠、氯化石蜡、硅烷偶联剂KH-560、二月桂酸二丁基锡、十八烷基三甲基氯化铵、聚乙二醇、氟硅油、增稠剂、消泡剂、固化剂和改性助剂。以丙烯酸全氟烷基酯、醇酸树脂、聚酯树脂、全氟烷基丙烯酸酯和丙烯酸丁酯为基料，以丙烯酸羟乙酯、三聚磷酸铝、纳米硼酸锌、过硫酸钾、羟甲基纤维素、纳米氧化锌、纳米二氧化钛、硅藻土、氢氧化镁、氧化铝、有机膨润土、绢云母粉、氟化碳、磷酸铁、钼酸钠、过硫酸钠和氯化石蜡为填料，以硅烷偶联剂KH-560、二月桂酸二丁基锡、十八烷基三甲基氯化铵、聚乙二醇、氟硅油、增稠剂、消泡剂、固化剂和改性助剂为助剂，通过基料、填料和助剂的配合，合理控制配比，得到的耐油层具有优异的耐油性能。耐油层的原料中，改性助剂通过将浓硫酸分散于水中，搅拌均匀得酸性复合插层水溶液；将膨润土、重晶石粉、硝化棉、氧化锌、云母粉和沸石粉加入到酸性复合插层水溶液中，高速搅拌，趁热过滤，用蒸馏水洗涤至中性，抽滤，烘干，研磨，过筛得到物料A；然后将物料A分散在乙醇水溶液中，在水浴中超声-机械搅拌分散得到物料B，然后向物料B中添加硅烷偶联剂KH-570和甲基丙烯酸甲酯，升温后保温，保温的过程中通氮气，最后将反应产物倒出，加入蒸馏水，搅拌均匀，静置分层，去除上层清液，将下层反应产物进行抽滤，洗涤，真空干燥至恒重，研磨，过筛，即得到改性助剂，进一步增强了耐油层的耐油性能。
附图说明
图1为本发明提出的一种耐污耐油墙纸的结构示意图。
具体实施方式
下面结合具体实施例对本发明做出详细说明，应当了解，实施例只用于说明本发明，而不是用于对本发明进行限定，任何在本发明基础上所做的修改、等同替换等均在本发明的保护范围内。
实施例1
如图1所示，图1为本发明提出的一种耐污耐油墙纸的结构示意图。
参照图1，本发明提出的一种耐污耐油墙纸，包括基材层1、耐污层2和耐油层3，基材层1的外周涂覆有耐污层2，所述耐污层2远离基材层1的外周涂覆有耐油层3，其中：
基材层1为木浆纸；
耐污层2的原料按重量份包括：氟碳树脂45份、醇酸树脂35份、氨基树脂9份、脂肪酸聚酰胺蜡3份、水性聚丙烯酸酯乳液10份、有机硅树脂3份、EVA蜡5份、环氧树脂E-12 4.5份、铝粉3.5份、有机膨润土3.5份、疏水性气相二氧化硅2.5份、蒙脱土3份、耐污增强剂12份、改性填料3.5份、乙二醇丁醚2份、六甲氧基甲基三聚氰胺4份、二甲基乙醇胺2.5份、异丙醇3份、六偏磷酸钠4份、醋酸丁酯2.5份、硅烷偶联剂KH-560 3.5份、分散剂4.5份、流平剂BYK-331 3份、润湿剂25份、消泡剂4.5份、二甲苯2.5份、去离子水15份；
耐油层3的原料按重量份包括：丙烯酸全氟烷基酯50份、醇酸树脂20份、聚酯树脂10份、全氟烷基丙烯酸酯6份、丙烯酸丁酯10份、丙烯酸羟乙酯5份、三聚磷酸铝3份、纳米硼酸锌3.5份、过硫酸钾2.5份、羟甲基纤维素4份、纳米氧化锌2份、纳米二氧化钛3.5份、硅藻土3.5份、氢氧化镁3.5份、氧化铝5份、有机膨润土3.5份、绢云母粉3.5份、氟化碳5份、磷酸铁4.5 份、钼酸钠3.5份、过硫酸钠4.5份、氯化石蜡5份、硅烷偶联剂KH-560 2.5份、二月桂酸二丁基锡3.5份、十八烷基三甲基氯化铵3.5份、聚乙二醇6份、氟硅油2.5份、增稠剂5.5份、消泡剂3.5份、固化剂3份、改性助剂6份。
实施例2
如图1所示，图1为本发明提出的一种耐污耐油墙纸的结构示意图。
参照图1，本发明提出的一种耐污耐油墙纸，包括基材层1、耐污层2和耐油层3，基材层1的外周涂覆有耐污层2，所述耐污层2远离基材层1的外周涂覆有耐油层3，其中：
基材层1为无纺纸；
耐污层2的原料按重量份包括：氟碳树脂40份、醇酸树脂45份、氨基树脂6份、脂肪酸聚酰胺蜡5份、水性聚丙烯酸酯乳液5份、有机硅树脂5份、EVA蜡4份、环氧树脂E-12 6份、铝粉2份、有机膨润土6份、疏水性气相二氧化硅1份、蒙脱土4份、耐污增强剂8份、改性填料5份、乙二醇丁醚1份、六甲氧基甲基三聚氰胺6份、二甲基乙醇胺1份、异丙醇4份、六偏磷酸钠3份、醋酸丁酯4份、硅烷偶联剂KH-560 2份、分散剂6份、流平剂BYK-331 2份、润湿剂4份、消泡剂3份、二甲苯4份、去离子水12份；
耐油层3的原料按重量份包括：丙烯酸全氟烷基酯40份、醇酸树脂25份、聚酯树脂5份、全氟烷基丙烯酸酯8份、丙烯酸丁酯5份、丙烯酸羟乙酯8份、三聚磷酸铝1份、纳米硼酸锌5份、过硫酸钾1份、羟甲基纤维素6份、纳米氧化锌1份、纳米二氧化钛5份、硅藻土3份、氢氧化镁5份、氧化铝4份、有机膨润土5份、绢云母粉2份、氟化碳6份、磷酸铁3份、钼酸钠5份、过硫酸钠3份、氯化石蜡8份、硅烷偶联剂KH-560 1份、二月桂酸二丁基锡5份、十八烷基三甲基氯化铵2份、聚乙二醇8份、氟硅油1份、增稠剂8份、消泡剂2份、固化剂5份、改性助剂4份。
耐污层2的原料中，耐污增强剂按如下工艺进行制备：按重量份将3份苯乙烯、4份丙烯酸丁酯和4份纳米掺锑二氧化锡粉体混合均匀，然后加入8份硅烷偶联剂KH-570，于38℃搅拌28h，冷却至室温得到物料a；然后将物料a置于冰水浴中破碎，超声处理10min得到耐污增强剂。
耐污层2的原料中，改性填料按如下工艺进行制备：按重量份将3份辛基异噻唑啉酮与水混合，然后加入8份纳米二氧化钛、3份温石棉和8份陶瓷粉，于180℃保温搅拌3h，降温至120℃，然后加入4份纳米碳化硅、2份石蜡、5份玉石粉和3份硝化棉液搅拌均匀，然后加入8份硅烷偶联剂KH-570和4份聚乙烯醇，于100℃搅拌1.5h，烘干，研磨，过80目筛，得到改性填料。
耐油层3的原料中，改性助剂按如下工艺进行制备：按重量份将80份浓硫酸分散于60份水中，搅拌均匀得酸性复合插层水溶液；将1份膨润土、4份重晶石粉、1份硝化棉、3份氧化锌、1份云母粉和6份沸石粉加入到酸性复合插层水溶液中，80℃高速搅拌4h，趁热过滤，用蒸馏水洗涤至中性，抽滤，烘干，研磨，过150目筛得到物料A；然后将物料A分散在16份乙醇水溶液中，在45℃水浴中超声-机械搅拌分散4h得到物料B，然后向物料B中添加5份硅烷偶联剂KH-570和5份甲基丙烯酸甲酯，升温至75℃，保温7h，保温的过程中通氮气，最后将反应产物倒出，加入蒸馏水，搅拌均匀，静置分层，去除上层清液，将下层反应产物进行抽滤，洗涤，750℃真空干燥至恒重，研磨，过250目筛，即得到改性助剂。
实施例3
如图1所示，图1为本发明提出的一种耐污耐油墙纸的结构示意图。
参照图1，本发明提出的一种耐污耐油墙纸，包括基材层1、耐污层2和耐油层3，基材层1的外周涂覆有耐污层2，所述耐污层2远离基材层1的外周涂覆有耐油层3，其中：
基材层1为布；
耐污层2的原料按重量份包括：氟碳树脂50份、醇酸树脂25份、氨基树脂12份、脂肪酸聚酰胺蜡1份、水性聚丙烯酸酯乳液15份、有机硅树脂1份、EVA蜡6份、环氧树脂E-123份、铝粉5份、有机膨润土1份、疏水性气相二氧化硅4份、蒙脱土2份、耐污增强剂16份、改性填料2份、乙二醇丁醚3份、六甲氧基甲基三聚氰胺2份、二甲基乙醇胺4份、异丙醇2份、六偏磷酸钠5份、醋酸丁酯1份、硅烷偶联剂KH-560 5份、分散剂3份、流平剂BYK-331 4份、润湿剂1份、消泡剂6份、二甲苯1份、去离子水18份；
耐油层3的原料按重量份包括：丙烯酸全氟烷基酯60份、醇酸树脂15份、聚酯树脂15份、全氟烷基丙烯酸酯4份、丙烯酸丁酯15份、丙烯酸羟乙酯2份、三聚磷酸铝5份、纳米硼酸锌2份、过硫酸钾4份、羟甲基纤维素2份、纳米氧化锌3份、纳米二氧化钛2份、硅藻土4份、氢氧化镁2份、氧化铝6份、有机膨润土2份、绢云母粉5份、氟化碳4份、磷酸铁6份、钼酸钠2份、过硫酸钠3-6份、氯化石蜡2-8份、硅烷偶联剂KH-560 1-4份、二月桂酸二丁基锡5份、十八烷基三甲基氯化铵2份、聚乙二醇8份、氟硅油1份、增稠剂8份、消泡剂2份、固化剂5份、改性助剂4份。
本发明的一种耐污耐油墙纸的制备方法，包括如下步骤：
S1、在基材层表面通过印刷工艺在基材层上形成具有图案的印刷层，制得墙纸半成品；
S2、在墙纸半成品的正面将耐污层的原料组合物采用圆网套印工艺印制耐污层，一次干燥后，一次干燥的温度为90℃，一次干燥的时间为4h，将耐油层的原料组合物采用圆网套印工艺印制在耐污层层上，形成耐油层，印刷完成后，进行二次干燥，二次干燥的温度为65℃，二次干燥的时间为1h，冷却至室温得到耐污耐油墙纸，其中，圆网套印工艺参数均为：印刷速度为15m/min；烘箱温度为先用100℃烘干，再用180℃成膜形成附着效果；圆网上形成有六角网孔，六角网孔的开孔率为30％；成品圆网的网厚度为0.3mm。
实施例4
如图1所示，图1为本发明提出的一种耐污耐油墙纸的结构示意图。
参照图1，本发明提出的一种耐污耐油墙纸，包括基材层1、耐污层2和耐油层3，基材层1的外周涂覆有耐污层2，所述耐污层2远离基材层1的外周涂覆有耐油层3，其中：
基材层1为木浆纸；
耐污层2的原料按重量份包括：氟碳树脂42份、醇酸树脂42份、氨基树脂7份、脂肪酸聚酰胺蜡4份、水性聚丙烯酸酯乳液8份、有机硅树脂4份、EVA蜡4.5份、环氧树脂E-12 5份、铝粉3份、有机膨润土5份、疏水性气相二氧化硅2份、蒙脱土3.5份、耐污增强剂9份、改性填料4份、乙二醇丁醚1.5份、六甲氧基甲基三聚氰胺5份、二甲基乙醇胺2份、异丙醇3.5份、六偏磷酸钠3.5份、醋酸丁酯3份、硅烷偶联剂KH-560 3份、分散剂5份、流平剂BYK-331 2.5份、润湿剂3份、消泡剂4份、二甲苯3份、去离子水14份；
耐油层3的原料按重量份包括：丙烯酸全氟烷基酯45份、醇酸树脂22份、聚酯树脂8份、全氟烷基丙烯酸酯7份、丙烯酸丁酯8份、丙烯酸羟乙酯7份、三聚磷酸铝2份、纳米硼酸锌4份、过硫酸钾2份、羟甲基纤维素5份、纳米氧化锌1.5份、纳米二氧化钛4份、硅藻土3.2份、氢氧化镁4份、氧化铝4.5份、有机膨润土4份、绢云母粉3份、氟化碳5.5份、磷酸铁4份、钼酸钠4 份、过硫酸钠4份、氯化石蜡7份、硅烷偶联剂KH-560 2份、二月桂酸二丁基锡4份、十八烷基三甲基氯化铵3份、聚乙二醇7份、氟硅油2份、增稠剂7份、消泡剂3份、固化剂4份、改性助剂5份。
耐污层2的原料中，耐污增强剂按如下工艺进行制备：按重量份将4份苯乙烯、3.9份丙烯酸丁酯和5份纳米掺锑二氧化锡粉体混合均匀，然后加入7份硅烷偶联剂KH-570，于36℃搅拌26h，冷却至室温得到物料a；然后将物料a置于冰水浴中破碎，超声处理11min得到耐污增强剂。
耐污层2的原料中，改性填料按如下工艺进行制备：按重量份将4份辛基异噻唑啉酮与水混合，然后加入7份纳米二氧化钛、4份温石棉和7份陶瓷粉，于185℃保温搅拌2.5h，降温至125℃，然后加入3份纳米碳化硅、3份石蜡、4份玉石粉和3.5份硝化棉液搅拌均匀，然后加入7份硅烷偶联剂KH-570和5-7份聚乙烯醇，于85℃搅拌3.2h，烘干，研磨，过65目筛，得到改性填料。
耐油层3的原料中，改性助剂按如下工艺进行制备：按重量份将85份浓硫酸分散于55份水中，搅拌均匀得酸性复合插层水溶液；将2份膨润土、3.5份重晶石粉、2份硝化棉、2.5份氧化锌、2份云母粉和5份沸石粉加入到酸性复合插层水溶液中，82℃高速搅拌3.5h，趁热过滤，用蒸馏水洗涤至中性，抽滤，烘干，研磨，过180目筛得到物料A；然后将物料A分散在15份乙醇水溶液中，在48℃水浴中超声-机械搅拌分散3.5h得到物料B，然后向物料B中添加8份硅烷偶联剂KH-570和4份甲基丙烯酸甲酯，升温至78℃，保温6.5h，保温的过程中通氮气，最后将反应产物倒出，加入蒸馏水，搅拌均匀，静置分层，去除上层清液，将下层反应产物进行抽滤，洗涤，780℃真空干燥至恒重，研磨，过220目筛，即得到改性助剂。
本发明的一种耐污耐油墙纸的制备方法，包括如下步骤：
S1、在基材层表面通过印刷工艺在基材层上形成具有图案的印刷层，制得墙纸半成品；
S2、在墙纸半成品的正面将耐污层的原料组合物采用圆网套印工艺印制耐污层，一次干燥后，一次干燥的温度为75℃，一次干燥的时间为5.5h，将耐油层的原料组合物采用圆网套印工艺印制在耐污层层上，形成耐油层，印刷完成后，进行二次干燥，二次干燥的温度为58℃，二次干燥的时间为2.5h，冷却至室温得到耐污耐油墙纸，其中，圆网套印工艺参数均为：印刷速度为8m/min；烘箱温度为先用115℃烘干，再用165℃成膜形成附着效果；圆网上形成有六角网孔，六角网孔的开孔率为40％；成品圆网的网厚度为0.15mm。
实施例5
如图1所示，图1为本发明提出的一种耐污耐油墙纸的结构示意图。
参照图1，本发明提出的一种耐污耐油墙纸，包括基材层1、耐污层2和耐油层3，基材层1的外周涂覆有耐污层2，所述耐污层2远离基材层1的外周涂覆有耐油层3，其中：
基材层1为无纺纸；
耐污层2的原料按重量份包括：氟碳树脂48份、醇酸树脂28份、氨基树脂11份、脂肪酸聚酰胺蜡2份、水性聚丙烯酸酯乳液12份、有机硅树脂2份、EVA蜡5.5份、环氧树脂E-12 4份、铝粉4份、有机膨润土2份、疏水性气相二氧化硅3份、蒙脱土2.5份、耐污增强剂15份、改性填料3份、乙二醇丁醚2.5份、六甲氧基甲基三聚氰胺3份、二甲基乙醇胺3份、异丙醇2.5份、六偏磷酸钠4.5份、醋酸丁酯2份、硅烷偶联剂KH-560 4份、分散剂4份、流平剂BYK-3313.5份、润湿剂2份、消泡剂5份、二甲苯2份、去离子水16份；
耐油层3的原料按重量份包括：丙烯酸全氟烷基酯55份、醇酸树脂18份、聚酯树脂12份、全氟烷基丙烯酸酯5份、丙烯酸丁酯12份、丙烯酸羟乙酯3份、三聚磷酸铝4份、纳米硼酸锌3份、过硫酸钾3份、羟甲基纤维素3份、纳米氧化锌2.5份、纳米二氧化钛3份、硅藻土3.5份、氢氧化镁3份、氧化铝5.5份、有机膨润土3份、绢云母粉4份、氟化碳4.5份、磷酸铁5份、钼酸钠3份、过硫酸钠5份、氯化石蜡3份、硅烷偶联剂KH-560 3份、二月桂酸二丁基锡3份、十八烷基三甲基氯化铵4份、聚乙二醇5份、氟硅油3份、增稠剂4份、消泡剂4份、固化剂2份、改性助剂7份。
耐污层2的原料中，耐污增强剂按如下工艺进行制备：按重量份将5份苯乙烯、1.6份丙烯酸丁酯和11份纳米掺锑二氧化锡粉体混合均匀，然后加入3份硅烷偶联剂KH-570，于45℃搅拌22h，冷却至室温得到物料a；然后将物料a置于冰水浴中破碎，超声处理13min得到耐污增强剂。
耐污层2的原料中，改性填料按如下工艺进行制备：按重量份将5份辛基异噻唑啉酮与水混合，然后加入3份纳米二氧化钛、5份温石棉和2份陶瓷粉，于255℃保温搅拌1.5h，降温至135℃，然后加入2份纳米碳化硅、5份石蜡、3份玉石粉和4.5份硝化棉液搅拌均匀，然后加入5份硅烷偶联剂KH-570和7份聚乙烯醇，于85℃搅拌3.2h，烘干，研磨，过65目筛，得到改性填料。
耐油层3的原料中，改性助剂按如下工艺进行制备：按重量份将115份浓硫酸分散于45份水中，搅拌均匀得酸性复合插层水溶液；将4份膨润土、2.5份重晶石粉、3份硝化棉、1.5份氧化锌、4份云母粉和3份沸石粉加入到酸性复合插层水溶液中，88℃高速搅拌2.5h，趁热过滤，用蒸馏水洗涤至中性，抽滤，烘干，研磨，过220目筛得到物料A；然后将物料A分散在9份乙醇水溶液中，在52℃水浴中超声-机械搅拌分散2.5h得到物料B，然后向物料B中添加12份硅烷偶联剂KH-570和2份甲基丙烯酸甲酯，升温至82℃，保温5.5h，保温的过程中通氮气，最后将反应产物倒出，加入蒸馏水，搅拌均匀，静置分层，去除上层清液，将下层反应产物进行抽滤，洗涤，820℃真空干燥至恒重，研磨，过180目筛，即得到改性助剂。
本发明的一种耐污耐油墙纸的制备方法，包括如下步骤：
S1、在基材层表面通过印刷工艺在基材层上形成具有图案的印刷层，制得墙纸半成品；
S2、在墙纸半成品的正面将耐污层的原料组合物采用圆网套印工艺印制耐污层，一次干燥后，一次干燥的温度为85℃，一次干燥的时间为4.5h，将耐油层的原料组合物采用圆网套印工艺印制在耐污层层上，形成耐油层，印刷完成后，进行二次干燥，二次干燥的温度为62℃，二次干燥的时间为1.5h，冷却至室温得到耐污耐油墙纸，其中，圆网套印工艺参数均为：印刷速度为12m/min；烘箱温度为先用105℃烘干，再用175℃成膜形成附着效果；圆网上形成有六角网孔，六角网孔的开孔率为35％；成品圆网的网厚度为0.25mm。
以上所述，仅为本发明较佳的具体实施方式，但本发明的保护范围并不局限于此，任何熟悉本技术领域的技术人员在本发明揭露的技术范围内，根据本发明的技术方案及其发明构思加以等同替换或改变，都应涵盖在本发明的保护范围之内。

Claims (10)

1.一种耐污耐油墙纸，包括基材层(1)、耐污层(2)和耐油层(3)，基材层(1)的外周涂覆有耐污层(2)，所述耐污层(2)远离基材层(1)的外周涂覆有耐油层(3)，其特征在于，其中：
基材层(1)为木浆纸、无纺纸、布中的任意一种；
耐污层(2)的原料按重量份包括：氟碳树脂40-50份、醇酸树脂25-45份、氨基树脂6-12份、脂肪酸聚酰胺蜡1-5份、水性聚丙烯酸酯乳液5-15份、有机硅树脂1-5份、EVA蜡4-6份、环氧树脂E-123-6份、铝粉2-5份、有机膨润土1-6份、疏水性气相二氧化硅1-4份、蒙脱土2-4份、耐污增强剂8-16份、改性填料2-5份、乙二醇丁醚1-3份、六甲氧基甲基三聚氰胺2-6份、二甲基乙醇胺1-4份、异丙醇2-4份、六偏磷酸钠3-5份、醋酸丁酯1-4份、硅烷偶联剂KH-5602-5份、分散剂3-6份、流平剂BYK-331 2-4份、润湿剂1-4份、消泡剂3-6份、二甲苯1-4份、去离子水12-18份；
耐油层(3)的原料按重量份包括：丙烯酸全氟烷基酯40-60份、醇酸树脂15-25份、聚酯树脂5-15份、全氟烷基丙烯酸酯4-8份、丙烯酸丁酯5-15份、丙烯酸羟乙酯2-8份、三聚磷酸铝1-5份、纳米硼酸锌2-5份、过硫酸钾1-4份、羟甲基纤维素2-6份、纳米氧化锌1-3份、纳米二氧化钛2-5份、硅藻土3-4份、氢氧化镁2-5份、氧化铝4-6份、有机膨润土2-5份、绢云母粉2-5份、氟化碳4-6份、磷酸铁3-6份、钼酸钠2-5份、过硫酸钠3-6份、氯化石蜡2-8份、硅烷偶联剂KH-560 1-4份、二月桂酸二丁基锡2-5份、十八烷基三甲基氯化铵2-5份、聚乙二醇4-8份、氟硅油1-4份、增稠剂3-8份、消泡剂2-5份、固化剂1-5份、改性助剂4-8份。
2.根据权利要求1所述的耐污耐油墙纸，其特征在于，耐污层(2)的原料中，耐污增强剂的原料按重量份包括：纳米掺锑二氧化锡粉体4-12份、硅烷偶联剂KH-570 2-8份、苯乙烯3-6份、丙烯酸丁酯1.5-4份。
3.根据权利要求1或2所述的耐污耐油墙纸，其特征在于，耐污层(2)的原料中，耐污增强剂按如下工艺进行制备：将苯乙烯、丙烯酸丁酯和纳米掺锑二氧化锡粉体混合均匀，然后加入硅烷偶联剂KH-570，于38-46℃搅拌20-28h，冷却至室温得到物料a；然后将物料a置于冰水浴中破碎，超声处理10-14min得到耐污增强剂。
4.根据权利要求1-3任一项所述的耐污耐油墙纸，其特征在于，耐污层(2)的原料中，改性填料的原料按重量份包括：纳米二氧化钛2-8份、温石棉3-6份、陶瓷粉1-8份、纳米碳化硅1-4份、石蜡2-6份、玉石粉2-5份、硝化棉液3-5份、辛基异噻唑啉酮3-6份、硅烷偶联剂KH-570 4-8份、聚乙烯醇4-8份。
5.根据权利要求1-4任一项所述的耐污耐油墙纸，其特征在于，耐污层(2)的原料中，改性填料按如下工艺进行制备：将辛基异噻唑啉酮与水混合，然后加入纳米二氧化钛、温石棉和陶瓷粉，于180-260℃保温搅拌1-3h，降温至120-140℃，然后加入纳米碳化硅、石蜡、玉石粉和硝化棉液搅拌均匀，然后加入硅烷偶联剂KH-570和聚乙烯醇，于80-100℃搅拌1.5-3.5h，烘干，研磨，过60-80目筛，得到改性填料。
6.根据权利要求1-5任一项所述的耐污耐油墙纸，其特征在于，耐油层(3)的原料中，改性助剂的原料按重量份包括：浓硫酸80-120份、水40-60份、膨润土1-5份、重晶石粉2-4份、硝化棉1-4份、氧化锌1-3份、云母粉1-5份、沸石粉2-6份、乙醇水溶液8-16份、硅烷偶联剂KH-570 5-15份、甲基丙烯酸甲酯1-5份。
7.根据权利要求1-6任一项所述的耐污耐油墙纸，其特征在于，耐油层(3) 的原料中，改性助剂按如下工艺进行制备：将浓硫酸分散于水中，搅拌均匀得酸性复合插层水溶液；将膨润土、重晶石粉、硝化棉、氧化锌、云母粉和沸石粉加入到酸性复合插层水溶液中，80-90℃高速搅拌2-4h，趁热过滤，用蒸馏水洗涤至中性，抽滤，烘干，研磨，过150-250目筛得到物料A；然后将物料A分散在乙醇水溶液中，在45-55℃水浴中超声-机械搅拌分散2-4h得到物料B，然后向物料B中添加硅烷偶联剂KH-570和甲基丙烯酸甲酯，升温至75-85℃，保温5-7h，保温的过程中通氮气，最后将反应产物倒出，加入蒸馏水，搅拌均匀，静置分层，去除上层清液，将下层反应产物进行抽滤，洗涤，750-850℃真空干燥至恒重，研磨，过150-250目筛，即得到改性助剂。
8.一种根据权利要求1-7任一项所述的耐污耐油墙纸的制备方法，其特征在于，包括如下步骤：
S1、在基材层表面通过印刷工艺在基材层上形成具有图案的印刷层，制得墙纸半成品；
S2、在墙纸半成品的正面将耐污层的原料组合物采用圆网套印工艺印制耐污层，一次干燥后，将耐油层的原料组合物采用圆网套印工艺印制在耐污层层上，形成耐油层，印刷完成后，进行二次干燥，冷却至室温得到耐污耐油墙纸。
9.根据权利要求8所述的耐污耐油墙纸的制备方法，其特征在于，S2中，圆网套印工艺参数均为：印刷速度为5-15m/min；烘箱温度为先用100-120℃烘干，再用160-180℃成膜形成附着效果；圆网上形成有六角网孔，六角网孔的开孔率为30-45％；成品圆网的网厚度为0.1-0.3mm。
10.根据权利要求8或9所述的耐污耐油墙纸的制备方法，其特征在于，S2中，一次干燥的温度为70-90℃，一次干燥的时间为4-6h；二次干燥的温度为55-65℃，二次干燥的时间为1-3h。
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CN109024089A (zh) * 2018-08-20 2018-12-18 蚌埠市维光塑胶制品有限公司 一种耐污防褪色墙纸
CN109826046A (zh) * 2019-02-14 2019-05-31 上海慕缇装饰材料有限公司 一种无纺防污壁纸及其制备方法
TWI731558B (zh) * 2019-03-25 2021-06-21 日商阿爾卑斯阿爾派股份有限公司 可變電阻器
CN110330898A (zh) * 2019-08-06 2019-10-15 天津恒燊科技发展有限公司 一种环保纳米水性漆及其制备方法
CN112876715A (zh) * 2021-01-19 2021-06-01 科一(福建)超纤有限责任公司 一种环保tpu卡通亮面防污墙革
CN113263794A (zh) * 2021-07-06 2021-08-17 苏州华尔美特装饰材料股份有限公司 耐污耐油易擦洗墙纸的制备方法

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